WO2014001153A1 - Compositions de colorants appropriées à la consommation humaine - Google Patents
Compositions de colorants appropriées à la consommation humaine Download PDFInfo
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- WO2014001153A1 WO2014001153A1 PCT/EP2013/062638 EP2013062638W WO2014001153A1 WO 2014001153 A1 WO2014001153 A1 WO 2014001153A1 EP 2013062638 W EP2013062638 W EP 2013062638W WO 2014001153 A1 WO2014001153 A1 WO 2014001153A1
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- 239000000203 mixture Substances 0.000 title claims abstract description 91
- 238000004040 coloring Methods 0.000 title claims abstract description 14
- 239000000284 extract Substances 0.000 claims abstract description 62
- 235000000346 sugar Nutrition 0.000 claims abstract description 56
- 239000011248 coating agent Substances 0.000 claims abstract description 38
- 239000012141 concentrate Substances 0.000 claims abstract description 35
- 235000013736 caramel Nutrition 0.000 claims abstract description 25
- 235000013311 vegetables Nutrition 0.000 claims abstract description 25
- 238000000576 coating method Methods 0.000 claims abstract description 24
- GXCLVBGFBYZDAG-UHFFFAOYSA-N N-[2-(1H-indol-3-yl)ethyl]-N-methylprop-2-en-1-amine Chemical compound CN(CCC1=CNC2=C1C=CC=C2)CC=C GXCLVBGFBYZDAG-UHFFFAOYSA-N 0.000 claims abstract description 19
- -1 caramel sugars Chemical class 0.000 claims abstract description 18
- 235000010208 anthocyanin Nutrition 0.000 claims abstract description 17
- 239000004410 anthocyanin Substances 0.000 claims abstract description 17
- 229930002877 anthocyanin Natural products 0.000 claims abstract description 16
- 150000004636 anthocyanins Chemical class 0.000 claims abstract description 16
- 235000009508 confectionery Nutrition 0.000 claims abstract description 15
- 150000008442 polyphenolic compounds Chemical class 0.000 claims abstract description 14
- 235000013824 polyphenols Nutrition 0.000 claims abstract description 14
- 150000003839 salts Chemical class 0.000 claims abstract description 12
- MIDXCONKKJTLDX-UHFFFAOYSA-N 3,5-dimethylcyclopentane-1,2-dione Chemical compound CC1CC(C)C(=O)C1=O MIDXCONKKJTLDX-UHFFFAOYSA-N 0.000 claims abstract description 11
- DHHFDKNIEVKVKS-FMOSSLLZSA-N Betanin Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1OC(C(=C1)O)=CC(C[C@H]2C([O-])=O)=C1[N+]2=C\C=C\1C=C(C(O)=O)N[C@H](C(O)=O)C/1 DHHFDKNIEVKVKS-FMOSSLLZSA-N 0.000 claims abstract description 11
- DHHFDKNIEVKVKS-MVUYWVKGSA-N Betanin Natural products O=C(O)[C@@H]1NC(C(=O)O)=C/C(=C\C=[N+]/2\[C@@H](C(=O)[O-])Cc3c\2cc(O)c(O[C@H]2[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O2)c3)/C1 DHHFDKNIEVKVKS-MVUYWVKGSA-N 0.000 claims abstract description 11
- 235000012677 beetroot red Nutrition 0.000 claims abstract description 11
- 239000001654 beetroot red Substances 0.000 claims abstract description 11
- 235000002185 betanin Nutrition 0.000 claims abstract description 11
- 239000003086 colorant Substances 0.000 claims abstract description 10
- 239000006174 pH buffer Substances 0.000 claims abstract description 8
- 150000001875 compounds Chemical class 0.000 claims abstract description 7
- 235000013305 food Nutrition 0.000 claims description 47
- 239000000419 plant extract Substances 0.000 claims description 46
- 241000196324 Embryophyta Species 0.000 claims description 34
- 235000019219 chocolate Nutrition 0.000 claims description 17
- 235000021028 berry Nutrition 0.000 claims description 10
- 239000004615 ingredient Substances 0.000 claims description 9
- 235000014647 Lens culinaris subsp culinaris Nutrition 0.000 claims description 8
- 229940112822 chewing gum Drugs 0.000 claims description 7
- 235000015218 chewing gum Nutrition 0.000 claims description 7
- 235000013373 food additive Nutrition 0.000 claims description 7
- 239000002778 food additive Substances 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 239000003674 animal food additive Substances 0.000 claims description 6
- 239000008298 dragée Substances 0.000 claims description 6
- 239000000825 pharmaceutical preparation Substances 0.000 claims description 6
- 235000015872 dietary supplement Nutrition 0.000 claims description 5
- 235000013399 edible fruits Nutrition 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 235000021537 Beetroot Nutrition 0.000 claims description 4
- 240000006365 Vitis vinifera Species 0.000 claims description 4
- 235000014787 Vitis vinifera Nutrition 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 235000011301 Brassica oleracea var capitata Nutrition 0.000 claims description 3
- 244000178937 Brassica oleracea var. capitata Species 0.000 claims description 3
- 244000000626 Daucus carota Species 0.000 claims description 3
- 235000002767 Daucus carota Nutrition 0.000 claims description 3
- 235000005206 Hibiscus Nutrition 0.000 claims description 3
- 235000007185 Hibiscus lunariifolius Nutrition 0.000 claims description 3
- 244000284380 Hibiscus rosa sinensis Species 0.000 claims description 3
- 244000017020 Ipomoea batatas Species 0.000 claims description 3
- 235000002678 Ipomoea batatas Nutrition 0.000 claims description 3
- 244000088415 Raphanus sativus Species 0.000 claims description 3
- 235000006140 Raphanus sativus var sativus Nutrition 0.000 claims description 3
- 244000151637 Sambucus canadensis Species 0.000 claims description 3
- 235000018735 Sambucus canadensis Nutrition 0.000 claims description 3
- 235000007123 blue elder Nutrition 0.000 claims description 3
- 235000007124 elderberry Nutrition 0.000 claims description 3
- 235000008995 european elder Nutrition 0.000 claims description 3
- 235000009754 Vitis X bourquina Nutrition 0.000 claims description 2
- 235000012333 Vitis X labruscana Nutrition 0.000 claims description 2
- 235000013618 yogurt Nutrition 0.000 claims description 2
- 244000043158 Lens esculenta Species 0.000 claims 3
- 241001465754 Metazoa Species 0.000 abstract description 5
- 235000012730 carminic acid Nutrition 0.000 abstract description 4
- 239000000975 dye Substances 0.000 description 78
- 235000008504 concentrate Nutrition 0.000 description 25
- 241000220225 Malus Species 0.000 description 14
- 239000000243 solution Substances 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 238000002360 preparation method Methods 0.000 description 10
- 241000219739 Lens Species 0.000 description 9
- 239000007787 solid Substances 0.000 description 7
- 239000008199 coating composition Substances 0.000 description 6
- 239000010410 layer Substances 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 239000013543 active substance Substances 0.000 description 5
- 150000002215 flavonoids Chemical class 0.000 description 5
- 239000008194 pharmaceutical composition Substances 0.000 description 5
- 229930006000 Sucrose Natural products 0.000 description 4
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
- 229930003935 flavonoid Natural products 0.000 description 4
- 235000017173 flavonoids Nutrition 0.000 description 4
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 4
- 239000005720 sucrose Substances 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 3
- 231100001261 hazardous Toxicity 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- CTMLKIKAUFEMLE-FTNGGYTGSA-N (2s)-4-[(e)-2-[(2s)-2-carboxy-6-hydroxy-5-[(2s,3r,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-2,3-dihydroindol-1-yl]ethenyl]-2,3-dihydropyridine-2,6-dicarboxylic acid Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1OC(C(=C1)O)=CC2=C1N(\C=C\C=1C[C@H](N=C(C=1)C(O)=O)C(O)=O)[C@H](C(O)=O)C2 CTMLKIKAUFEMLE-FTNGGYTGSA-N 0.000 description 2
- XLSZMDLNRCVEIJ-UHFFFAOYSA-N 4-methylimidazole Chemical compound CC1=CNC=N1 XLSZMDLNRCVEIJ-UHFFFAOYSA-N 0.000 description 2
- 241000283690 Bos taurus Species 0.000 description 2
- 240000009088 Fragaria x ananassa Species 0.000 description 2
- 244000081841 Malus domestica Species 0.000 description 2
- 229930182559 Natural dye Natural products 0.000 description 2
- 244000269722 Thea sinensis Species 0.000 description 2
- 240000001717 Vaccinium macrocarpon Species 0.000 description 2
- 235000012545 Vaccinium macrocarpon Nutrition 0.000 description 2
- 235000002118 Vaccinium oxycoccus Nutrition 0.000 description 2
- 208000018756 Variant Creutzfeldt-Jakob disease Diseases 0.000 description 2
- 241000219094 Vitaceae Species 0.000 description 2
- 238000011481 absorbance measurement Methods 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 239000004125 ammonia caramel Substances 0.000 description 2
- 235000012706 ammonia caramel Nutrition 0.000 description 2
- 235000021016 apples Nutrition 0.000 description 2
- 230000008033 biological extinction Effects 0.000 description 2
- 208000005881 bovine spongiform encephalopathy Diseases 0.000 description 2
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- 239000005417 food ingredient Substances 0.000 description 2
- 235000021021 grapes Nutrition 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000978 natural dye Substances 0.000 description 2
- 229910000027 potassium carbonate Inorganic materials 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 238000001694 spray drying Methods 0.000 description 2
- 235000021012 strawberries Nutrition 0.000 description 2
- 150000008163 sugars Chemical class 0.000 description 2
- 239000004124 sulphite ammonia caramel Substances 0.000 description 2
- 235000012707 sulphite ammonia caramel Nutrition 0.000 description 2
- 235000013616 tea Nutrition 0.000 description 2
- 244000291564 Allium cepa Species 0.000 description 1
- 235000002732 Allium cepa var. cepa Nutrition 0.000 description 1
- 241000978499 Brunnichia ovata Species 0.000 description 1
- 239000004267 EU approved acidity regulator Substances 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 240000004670 Glycyrrhiza echinata Species 0.000 description 1
- 235000001453 Glycyrrhiza echinata Nutrition 0.000 description 1
- 235000006200 Glycyrrhiza glabra Nutrition 0.000 description 1
- 235000017382 Glycyrrhiza lepidota Nutrition 0.000 description 1
- 241001446187 Kermes Species 0.000 description 1
- 238000013494 PH determination Methods 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 238000006887 Ullmann reaction Methods 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 235000019730 animal feed additive Nutrition 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 239000001049 brown dye Substances 0.000 description 1
- 235000019846 buffering salt Nutrition 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001860 citric acid derivatives Chemical class 0.000 description 1
- 239000000701 coagulant Substances 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 description 1
- 229910000396 dipotassium phosphate Inorganic materials 0.000 description 1
- 235000019797 dipotassium phosphate Nutrition 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 235000011869 dried fruits Nutrition 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 235000002864 food coloring agent Nutrition 0.000 description 1
- 239000000576 food coloring agent Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 235000020344 instant tea Nutrition 0.000 description 1
- 229960004903 invert sugar Drugs 0.000 description 1
- 235000021579 juice concentrates Nutrition 0.000 description 1
- 238000011005 laboratory method Methods 0.000 description 1
- 229940010454 licorice Drugs 0.000 description 1
- 239000008239 natural water Substances 0.000 description 1
- 238000001139 pH measurement Methods 0.000 description 1
- 230000008447 perception Effects 0.000 description 1
- 239000000546 pharmaceutical excipient Substances 0.000 description 1
- 229940124531 pharmaceutical excipient Drugs 0.000 description 1
- 229940127557 pharmaceutical product Drugs 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004122 plain caramel Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000009495 sugar coating Methods 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000006188 syrup Substances 0.000 description 1
- 235000020357 syrup Nutrition 0.000 description 1
- 150000003892 tartrate salts Chemical class 0.000 description 1
- 235000019222 white chocolate Nutrition 0.000 description 1
- 235000008939 whole milk Nutrition 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/30—Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/305—Products for covering, coating, finishing, decorating
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/30—Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/50—Cocoa products, e.g. chocolate; Substitutes therefor characterised by shape, structure or physical form, e.g. products with an inedible support
- A23G1/54—Composite products, e.g. layered laminated, coated, filled
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L5/00—Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
- A23L5/40—Colouring or decolouring of foods
- A23L5/42—Addition of dyes or pigments, e.g. in combination with optical brighteners
- A23L5/43—Addition of dyes or pigments, e.g. in combination with optical brighteners using naturally occurring organic dyes or pigments, their artificial duplicates or their derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K9/00—Medicinal preparations characterised by special physical form
- A61K9/20—Pills, tablets, discs, rods
- A61K9/2072—Pills, tablets, discs, rods characterised by shape, structure or size; Tablets with holes, special break lines or identification marks; Partially coated tablets; Disintegrating flat shaped forms
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L19/00—Products from fruits or vegetables; Preparation or treatment thereof
- A23L19/09—Mashed or comminuted products, e.g. pulp, purée, sauce, or products made therefrom, e.g. snacks
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23P—SHAPING OR WORKING OF FOODSTUFFS, NOT FULLY COVERED BY A SINGLE OTHER SUBCLASS
- A23P20/00—Coating of foodstuffs; Coatings therefor; Making laminated, multi-layered, stuffed or hollow foodstuffs
- A23P20/10—Coating with edible coatings, e.g. with oils or fats
Definitions
- the present invention relates to dye compositions suitable for human consumption comprising components (A), (B) and (C) wherein (A) is selected from the group consisting of plant extracts, caramel sugars, sugar coulters, malt extracts and mixtures thereof, wherein the plant extracts consist of one or more plant extracts containing one or more polyphenols, (B) one or more plant extracts and / or plant concentrates containing one or more compounds selected from the group consisting of anthocyanins and betanin and (C) selected from the group consisting of pH buffer salts and mixtures thereof, wherein (A) in an amount of 10 to 99 wt .-%, (B) in an amount of 0.5 to 89 wt .-% and (C) in a Amount of 0.5 to 10 wt .-% is contained, and wherein the caramelized sugars are contained in a maximum amount of up to 95 wt .-%, the Zuckercouleure contained in a maximum amount of up to 75 wt .-
- the present invention further relates to coating compositions containing these dye compositions, foods, food additives, pharmaceutical excipients, feeds, feed additives, and in particular confectionery.
- the present invention also relates to foodstuffs containing in the coating such dye compositions suitable for human consumption, for example coated confectionery.
- chocolate lenses and chewing gum pads having coatings comprising such dye compositions are part of the present invention.
- Dye compositions suitable for consumption are available in a wide variety of colors.
- the main field of use is food and pharmaceutical products, but also in toys or other articles intended for children or for the handling of children, in pet food and the like, there are dyes and coloring matter suitable for consumption.
- Another object of the present invention is to provide dye compositions suitable for human consumption which have a red, reddish-brown or brown color and possess high opacity. Further, it is an object of the present invention to provide dye compositions suitable for human consumption which have high resistance to aging and which do not influence or alter the food as little as possible. With respect to “caramel dyes” and “sugar liquor dyes”, the present invention is intended to provide a natural, marketable alternative, and / or to provide the opportunity to reduce the amounts of these dyes to be used.
- dye compositions suitable for human consumption comprising components (A), (B) and (C), wherein
- (C) selected from the group consisting of pH buffer salts and mixtures thereof,
- the dye composition may also consist of the aforementioned components (A), (B) and (C).
- a plant extract is a mixture of substances which is obtained by enrichment of components of plants or parts thereof using extractants.
- plant concentrates Mixtures of substances obtained by squeezing out plants or parts thereof. As a rule, they are thickened after drying by removing the water or dried.
- the plant extracts containing one or more polyphenols, the caramel sugar, the sugar caramel and the malt extracts give the dye compositions a hue having sufficient color strength and brilliance.
- the plant extracts and plant concentrates containing one or more compounds selected from the group of anthocyanins and betanin also contribute to the color strength and brilliance, but give the dye compositions, especially a darker color and in particular a high opacity.
- the opacity is the ability of a dye or pigment to cover the color of the object to be colored, that is to make invisible.
- Plant extracts often contain pH-active substances, ie substances which, upon contact with water, generate oxonium ions (H 3 O + ) or hydroxydiones (OH) and thus influence the pH of the water or of the aqueous solution.
- the water may include residual water in dried plant extracts or plant concentrates or the natural water content of foods or ingested air humidity.
- the nature of these ingredients and the pH they impart depend on the type of plant, the parts of the plant used in the extraction, the method of extraction and other factors.
- the dyes contained in the plant extract may also be pH-active substances. The resulting pH may therefore depend on their chemical structure.
- the pH-active substances may influence various properties of the dye compositions and the foods to be colored therewith. You can, for example, influence the color, since, for example, the color of anthocyanins can be pH-dependent.
- the brown color of the extract mixture can be shifted in the direction of a deep chocolate brown. This is possible due to the pH sensitivity of anthocyanins and betanin. Furthermore, the pH inversion salts can prevent the sugar inversion of residual sugars present in the extracts.
- the pH can be adjusted to the value necessary for the respective foodstuff. The person skilled in the art is aware of the appropriate pH for the individual foods or can easily be determined by methods known to him. Furthermore, those skilled in the art, the necessary methods for pH determination are known and as necessary given in the examples.
- a level of from 0.5% to 10% by weight of the pH buffering salt is particularly suitable for controlling the pH of water in contact with the dye compositions.
- the pH-adjusting effect is usually too low, and at higher levels, the coloring properties of the dye compositions may suffer.
- dye compositions as described above comprising or consisting of (A) in an amount of 30 to 95 wt .-%, (B) in an amount of 0.5 to 40 wt .-% and (C) in an amount from 0.5 to 8% by weight.
- Particularly preferred are dye compositions as described above, comprising or consisting of (A) in an amount of 50 to 95 wt .-%, (B) in an amount of 0.5 to 15 wt .-% and (C) in one Amount of 0.5 to 6 wt .-%.
- dye compositions as described above comprising or consisting of (A) in an amount of 70 to 98.5 wt .-%, (B) in an amount of 1 to 30 wt .-% and (C) in in an amount of 0.5 to 3 wt .-%.
- dye compositions as described above wherein the caramel sugars are contained in a maximum amount of up to 90 wt .-%, the Zuckercouleure are contained in a maximum amount of up to 70 wt .-% and / or the malt extracts in a maximum amount up to 70 wt .-% are included.
- Particular preference is given to dye compositions as described above in which the caramel sugars are contained in a maximum amount of up to 85% by weight, the sugar clays are contained in a maximum of up to 65% by weight and / or the malt extracts are not more than one up to 65 wt .-% are included.
- coloring properties, color brilliance, color brilliance, color strength, hiding power, etc. are usually the most favorable and the mutual influences of foods and dye mixtures can be kept low.
- Dye compositions having a pH between 4.5 to 8 are preferred.
- the pH is measured in a 1% (w / v) aqueous solution, that is, in an amount of one gram of the solid per 100 ml of the solution.
- the dye composition assumes the desired hues and suppresses the sugar inversion sufficiently.
- the skilled person decides on the basis of the specific conditions of the food preparation form, which pH should be adjusted.
- the color intensity can be determined as described in Commission Directive 2008/128 / EC of 22 December 2008 laying down specific purity criteria for food colors, for example sugar 07 (E150a).
- E150a sugar egg (E150a)
- the color intensity for the constituents of component (A) namely polyphenol-containing plant extracts, caramel sugar, sugar caramel and malt extracts, this is done by measuring the adsorption of a solution in water with a mass concentration of 0.1%.
- polyphenol-containing plant extracts which have a color intensity of 0.05 bi
- the caramel sugars to be used preferably have a color intensity in a range from 0.01 to 0.1
- the sugar coulters preferably have a color intensity in a range from 0.2 to 0.5
- the malt extracts preferably have one Color intensity in a range of 0.05 to 0.2.
- betanin-containing plant extracts and plant concentrates with an extinction value El% in a range of 3 to 30.
- Used natural dyes and components which have these color intensities usually have in addition to a sufficient color intensity, other particularly favorable coloring properties, for example in terms of hue, color brilliance, etc., and in particular in terms of color strength and opacity. Furthermore, by maintaining these color intensities, the reproducibility of the properties of the products in different batches is improved.
- component (A) contains flavonoids.
- apple extracts are particularly suitable for the present invention. Therefore, preferred are dye compositions as described in this patent application, wherein (A) comprises or consists of one or more apple extracts. Very particular preference is given to those dye compositions in which (A) consists of one or more apple extracts. Apple extracts are commercially available, particularly preferred are apple extracts of apple pomace (pulp). However, for example, apple instant tea is also suitable. Apple extracts are inexpensive and give the dye mixtures of the present invention a red, reddish brown or brown color, which often can not be obtained by other vegetable dyes or not in the necessary quality. Quality means all aspects that reflect consumer satisfaction with the product. The consumer is increasingly demanding higher quality features, such. B. taste, texture and appearance. Therefore, the manufacturers strive to produce the products in all aspects in a satisfactory and uniform quality. The exact shade depends on the raw materials on the mixing ratio of the components and other factors. He is reproducible.
- anthocyanins occur in almost all higher plants, mostly in the flowers and fruits, but also in the leaves and roots.
- Suitable for use in the dye compositions of the present invention are, for example, vegetable extracts, vegetable concentrates, berry concentrates and floral extracts. Preferred are therefore dye compositions as described herein, especially those as described immediately above, wherein (B) comprises one or more plant extracts selected from the group consisting of vegetable extracts, vegetable concentrates, berry concentrates and flower extracts.
- Particularly suitable vegetables are, for example, black carrots, sweet potatoes, red cabbage and radishes.
- Betanine for example, can be obtained from beetroot. It is preferably used as a plant concentrate that is obtained by pressing and subsequent drying of the beetroot.
- the invention can also be carried out with other compounds selected from the group of betalaine.
- these dye compositions are preferred if they additionally contain at least one apple extract.
- Particularly suitable berry concentrates and flower extracts are, for example, extracts of elderberry, grapes and hibiscus.
- these dye compositions are particularly preferred if they additionally contain at least one apple extract.
- Such combinations give an ideal color shade with very good opacity.
- dye compositions as described herein, wherein (A) consists of one or more apple extracts and is present in an amount of 70 to 98.5 wt .-%, (B) one or more plant extracts selected from the group consisting of vegetable extracts and Berry extracts and is present in a total amount of 1 to 30 wt .-% and (C) in an amount of 0.5 to 3 wt .-% is present.
- Another object of the present invention are foods, food additives, pharmaceutical formulations, feed, Feed additives or coating compositions comprising a dye composition according to the invention, in particular those containing apple extracts or other preferred components or otherwise comprising preferred embodiments of the dye compositions according to the invention.
- Coating compositions comprising a dye composition according to the invention are particularly preferred.
- the coating agents may be sugar-containing or sugar-free coating agents.
- Coagulants are used for coating, that is to say, the coating of solid bodies, for example confectionery, for example chocolate lentils or chewing gum pillows, or of pharmaceutical preparation forms, for example tablets.
- the production of the wrapper is also called coating.
- Coating methods for coating cores of, for example, chocolate with a hard sugar layer are known per se (for example, Ullmanns Enzyklopadie der ischen Chemie 3rd edition, volume 4, page 10 and volume 19, page 260).
- Coating agents which contain a dye composition according to the invention and have a pH of between 4.5 and 8, measured by direct immersion of a pH electrode in the coating compositions, are preferred.
- the dye composition assumes the desired hues and suppresses the sugar inversion sufficiently.
- the skilled person decides on the basis of the specific conditions, for example the holding time and the temperature, which pH value should be set.
- the pH of the coating solution is determined by means of a calibrated laboratory pH meter. It uses a pH electrode with KCl as the electrolyte, which can be dipped directly into the coating solution.
- Another object of the present invention are foods, food additives, pharmaceutical formulations, feed or animal feed additives comprising a dye composition according to the invention.
- Particularly preferred are such foods.
- preferred foods are confectionery and dietary supplements.
- Particularly preferred are foods as described above, wherein the food is selected from the group consisting of confectionery and Fruit yoghurts.
- Most preferred are foods as described above, wherein the food is selected from the group consisting of chocolate lentils, chewing gum pillows, fruit sweets, coated nuts, coated dried fruits such as raisins, coated licorice and dietary supplements in the form of dragees.
- a preferred subject of the present invention are foods, food additives, pharmaceutical formulations, feeds, feed additives comprising a coating or a coating comprising a dye composition according to the invention.
- the foods are particularly preferred, for example in the form of dragees.
- foods which contain a coating or a coating which comprises a dye composition according to the invention are preferred, for example sweets, such as chocolate lentils or chewing gum pillows, or dietary supplements in the form of dragees.
- the most preferred foods are chocolate lentils.
- a chocolate is a lentil-shaped candy whose core consists of whole milk, bitter or even white chocolate and which has a mostly colored sugar coating, which firmly adheres to the core. To make the chocolate, the chocolate core must be provided with the wrapper.
- chewing gum sticks are also preferred foods.
- Another object of the present invention are pharmaceutical formulations comprising a dye composition according to the invention.
- Particularly preferred pharmaceutical formulations are tablets.
- Another object of the present invention is the use of a dye composition according to the invention or a coating agent according to the invention for the preparation of a food or a pharmaceutical preparation, in particular the use for the production of chocolate lenses and tablets.
- Another object of the present invention is a process for the preparation of a dye composition according to the invention, comprising the steps: i. Providing a component (A) selected from the group consisting of plant extracts, caramel sugars, sugar coulters, malt extracts and mixtures thereof, wherein the plant extracts consist of one or more plant extracts containing one or more polyphenols,
- component (C) which is selected from the group consisting of pH buffer salts and mixtures thereof and
- an embodiment of the present invention is a process for the preparation of a dye composition according to the invention, comprising the steps: i. Providing a component (A) as described above, ii. Providing a component (B) as described above, iii. Providing a component (C) as described above and iv. Mixing the ingredients wherein the components (A), (B) and (C) and their components are used in the above amounts.
- the pH of the coating solution is determined using a Mettler Toledo MP120 calibrated laboratory pH meter with automatic temperature compensation.
- a conventional pH electrode with KCl as the electrolyte is immersed directly in the coating solution or mixture.
- the same apparatus is used and the pH electrode is immersed in an aqueous solution containing one gram of the solid per 100 ml of the solution (1%). (w / v)).
- the insoles were first wetted completely with drageeing agent and then dried with air until the dragees had run dusty (about 5 minutes).
- the room temperature was about 20 ° C, the relative humidity about 50%.
- the coating agent for each layer was added in such an amount that, although fully wetted, the deposits were not too wet to prevent sticking together.
- the total time for applying the layers was about 2.5 h, the order amount was 200 g per kg deposits.
- a total of 200 g of coating agent was applied in 20 layers.
- composition of the invention To prepare a composition of the invention, the components are combined and stirred as described above for the coating agent, but optionally without the sugar solution, if the addition of a sugar solution is not necessary for the desired application. If necessary, water or another solvent can also be added.
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- Chemical & Material Sciences (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Pharmacology & Pharmacy (AREA)
- Medicinal Chemistry (AREA)
- Nutrition Science (AREA)
- Epidemiology (AREA)
- Animal Behavior & Ethology (AREA)
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- Coloring Foods And Improving Nutritive Qualities (AREA)
- Confectionery (AREA)
Abstract
L'invention concerne des compositions de colorants appropriées à la consommation humaine, lesdites compositions présentant une couleur rouge, rouge brunâtre ou brune et possédant un pouvoir couvrant élevé, ainsi qu'un enrobage destiné à des confiseries enrobées, ledit enrobage étant exempt de colorants artificiels et présentant un coloris vif de type brun - rouge brunâtre sans avoir recours aux colorants de type carmin d'origine animale et présentant en outre des propriétés d'application avantageuses, à base d'extraits et de concentrés végétaux, les compositions de colorants appropriées à la consommation humaine selon l'invention comprenant les constituants (A), (B) et (C), (A) étant choisi dans le groupe constitué d'extraits végétaux, de sucres caramélisés, de colorants caramel, d'extraits de malt et de leurs mélanges, lesdits extraits végétaux étant constitués d'un ou de plusieurs extraits végétaux contenant un ou plusieurs polyphénols, (B) étant constitué d'un ou de plusieurs extraits végétaux et/ou concentrés de végétaux contenant un ou plusieurs composés choisis dans le groupe constitué d'anthocyanes et de bétanine, et (C) étant choisi dans le groupe constitué des sels à effet tampon sur le pH et de leurs mélanges, (A) y étant contenu dans une quantité comprise entre 10 et 99 % en poids, (B) dans une quantité comprise entre 0,5 et 89 % en poids et (C) dans une quantité comprise entre 0,5 et 10 % en poids, et les sucres caramélisés y étant contenus dans une quantité inférieure ou égale à 95 % en poids, les colorants caramel y étant contenus dans une quantité inférieure à 75 % en poids et les extraits de malt y étant contenus sont contenus dans une quantité inférieure ou égale à 90 % en poids.
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DE102012105514.9A DE102012105514A1 (de) | 2012-06-25 | 2012-06-25 | Zum menschlichen Verzehr geeignete Farbstoffzusammensetzungen |
DE102012105514.9 | 2012-06-25 |
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WO2014001153A1 true WO2014001153A1 (fr) | 2014-01-03 |
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PCT/EP2013/062638 WO2014001153A1 (fr) | 2012-06-25 | 2013-06-18 | Compositions de colorants appropriées à la consommation humaine |
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WO (1) | WO2014001153A1 (fr) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN108740267A (zh) * | 2018-06-07 | 2018-11-06 | 益家元品实业(厦门)有限公司 | 一种保健蜜饯的生产方法 |
US20210395547A1 (en) * | 2018-10-22 | 2021-12-23 | Ripples Ltd. | Article of manufacture, formulation and method for printing on a foamed beverage |
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WO2021234528A1 (fr) * | 2020-05-16 | 2021-11-25 | Ripples Ltd. | Appareil, procédé et article de fabrication permettant de produire une image à base d'encre multicolore comestible |
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US4118516A (en) * | 1977-05-26 | 1978-10-03 | International Flavors & Fragrances Inc. | Use of caramel color for augmenting or enhancing or intensifying the color of natural red dyestuffs |
US20080226797A1 (en) * | 2007-03-14 | 2008-09-18 | Concentrate Manufacturing Company Of Ireland | Natural Beverage Products |
WO2012033536A2 (fr) * | 2010-09-09 | 2012-03-15 | Kalamazoo Holdings, Inc. | Compositions de radis rouge et romarin ayant une stabilité de couleur améliorée et son utilisation dans les aliments, les boissons, les cosmétiques et les agents pharmaceutiques |
Family Cites Families (1)
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DE102010013205A1 (de) * | 2010-03-29 | 2011-09-29 | Vion N.V. | Fleischzusammensetzung, enthaltend texturiertes pflanzliches Protein, Verfahren zu deren Herstellung, sowie Fleischersatzprodukt |
-
2012
- 2012-06-25 DE DE102012105514.9A patent/DE102012105514A1/de active Pending
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2013
- 2013-06-18 WO PCT/EP2013/062638 patent/WO2014001153A1/fr active Application Filing
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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US4118516A (en) * | 1977-05-26 | 1978-10-03 | International Flavors & Fragrances Inc. | Use of caramel color for augmenting or enhancing or intensifying the color of natural red dyestuffs |
US20080226797A1 (en) * | 2007-03-14 | 2008-09-18 | Concentrate Manufacturing Company Of Ireland | Natural Beverage Products |
WO2012033536A2 (fr) * | 2010-09-09 | 2012-03-15 | Kalamazoo Holdings, Inc. | Compositions de radis rouge et romarin ayant une stabilité de couleur améliorée et son utilisation dans les aliments, les boissons, les cosmétiques et les agents pharmaceutiques |
Non-Patent Citations (3)
Title |
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"Ullmanns Enzyklopädie der technischen Chemie", vol. 4, pages: 10 |
DOWNHAM A ET AL: "Colouring our Foods in the last and next Millennium", INTERNATIONAL JOURNAL OF FOOD SCIENCE AND TECHNOLOGY, BLACKWELL SCIENTIFIC PUBLICATIONS, OXFORD, GB, vol. 35, 22 February 2000 (2000-02-22), pages 5 - 22, XP002694151, ISSN: 0950-5423, [retrieved on 20011225], DOI: 10.1046/J.1365-2621.2000.00373.X * |
HERRMANN, K.: "Anthocyanine als Farbstoffe unserer Obstarten", ERWERBSOBSTBAU, vol. 39, 1997, Berlin, pages 11 - 14, XP009173228, ISSN: 0014-0309 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108740267A (zh) * | 2018-06-07 | 2018-11-06 | 益家元品实业(厦门)有限公司 | 一种保健蜜饯的生产方法 |
US20210395547A1 (en) * | 2018-10-22 | 2021-12-23 | Ripples Ltd. | Article of manufacture, formulation and method for printing on a foamed beverage |
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