WO2013191804A3 - Refractory metal boride ceramics and methods of making thereof - Google Patents

Refractory metal boride ceramics and methods of making thereof Download PDF

Info

Publication number
WO2013191804A3
WO2013191804A3 PCT/US2013/037559 US2013037559W WO2013191804A3 WO 2013191804 A3 WO2013191804 A3 WO 2013191804A3 US 2013037559 W US2013037559 W US 2013037559W WO 2013191804 A3 WO2013191804 A3 WO 2013191804A3
Authority
WO
WIPO (PCT)
Prior art keywords
metal
refractory
nanoparticles
composition
refractory metal
Prior art date
Application number
PCT/US2013/037559
Other languages
French (fr)
Other versions
WO2013191804A9 (en
WO2013191804A2 (en
Inventor
Teddy M. Keller
Andrew SAAB
Matthew Laskoski
Syed B. Qadri
Original Assignee
The Government Of The United States Of America, As Represented By The Secretary Of The Navy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US13/749,794 external-priority patent/US8822023B2/en
Priority claimed from US13/768,219 external-priority patent/US8865301B2/en
Application filed by The Government Of The United States Of America, As Represented By The Secretary Of The Navy filed Critical The Government Of The United States Of America, As Represented By The Secretary Of The Navy
Priority to JP2015510315A priority Critical patent/JP6236195B2/en
Priority to EP13806734.3A priority patent/EP2844627A4/en
Priority to KR1020147032251A priority patent/KR20150013173A/en
Publication of WO2013191804A2 publication Critical patent/WO2013191804A2/en
Publication of WO2013191804A3 publication Critical patent/WO2013191804A3/en
Publication of WO2013191804A9 publication Critical patent/WO2013191804A9/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/62605Treating the starting powders individually or as mixtures
    • C04B35/62645Thermal treatment of powders or mixtures thereof other than sintering
    • C04B35/6267Pyrolysis, carbonisation or auto-combustion reactions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00Nanotechnology for materials or surface science, e.g. nanocomposites
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/515Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
    • C04B35/52Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbon, e.g. graphite
    • C04B35/522Graphite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/515Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
    • C04B35/52Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbon, e.g. graphite
    • C04B35/524Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbon, e.g. graphite obtained from polymer precursors, e.g. glass-like carbon material
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/515Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
    • C04B35/56Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides
    • C04B35/563Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides based on boron carbide
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/628Coating the powders or the macroscopic reinforcing agents
    • C04B35/62802Powder coating materials
    • C04B35/62828Non-oxide ceramics
    • C04B35/62836Nitrides
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/628Coating the powders or the macroscopic reinforcing agents
    • C04B35/62802Powder coating materials
    • C04B35/62828Non-oxide ceramics
    • C04B35/62839Carbon
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/71Ceramic products containing macroscopic reinforcing agents
    • C04B35/74Ceramic products containing macroscopic reinforcing agents containing shaped metallic materials
    • C04B35/76Fibres, filaments, whiskers, platelets, or the like
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/71Ceramic products containing macroscopic reinforcing agents
    • C04B35/78Ceramic products containing macroscopic reinforcing agents containing non-metallic materials
    • C04B35/80Fibres, filaments, whiskers, platelets, or the like
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/71Ceramic products containing macroscopic reinforcing agents
    • C04B35/78Ceramic products containing macroscopic reinforcing agents containing non-metallic materials
    • C04B35/80Fibres, filaments, whiskers, platelets, or the like
    • C04B35/83Carbon fibres in a carbon matrix
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38Non-oxide ceramic constituents or additives
    • C04B2235/3817Carbides
    • C04B2235/3821Boron carbides
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38Non-oxide ceramic constituents or additives
    • C04B2235/3852Nitrides, e.g. oxynitrides, carbonitrides, oxycarbonitrides, lithium nitride, magnesium nitride
    • C04B2235/386Boron nitrides
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/42Non metallic elements added as constituents or additives, e.g. sulfur, phosphor, selenium or tellurium
    • C04B2235/421Boron
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/46Gases other than oxygen used as reactant, e.g. nitrogen used to make a nitride phase
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/48Organic compounds becoming part of a ceramic after heat treatment, e.g. carbonising phenol resins
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/52Constituents or additives characterised by their shapes
    • C04B2235/5284Hollow fibers, e.g. nanotubes
    • C04B2235/5288Carbon nanotubes
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/54Particle size related information
    • C04B2235/5418Particle size related information expressed by the size of the particles or aggregates thereof
    • C04B2235/5454Particle size related information expressed by the size of the particles or aggregates thereof nanometer sized, i.e. below 100 nm
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
    • C04B2235/6562Heating rate
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/658Atmosphere during thermal treatment
    • C04B2235/6581Total pressure below 1 atmosphere, e.g. vacuum
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/658Atmosphere during thermal treatment
    • C04B2235/6586Processes characterised by the flow of gas
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/74Physical characteristics
    • C04B2235/78Grain sizes and shapes, product microstructures, e.g. acicular grains, equiaxed grains, platelet-structures
    • C04B2235/781Nanograined materials, i.e. having grain sizes below 100 nm
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/80Phases present in the sintered or melt-cast ceramic products other than the main phase
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/95Products characterised by their size, e.g. microceramics
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
    • C04B2235/9646Optical properties
    • C04B2235/9661Colour

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Composite Materials (AREA)
  • Nanotechnology (AREA)
  • Combustion & Propulsion (AREA)
  • Thermal Sciences (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Ceramic Products (AREA)
  • Compositions Of Oxide Ceramics (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

A composition having nanoparticles of a refractory-metal boride and a carbonaceous matrix. The composition is not in the form of a powder. A composition comprising a metal component, boron, and an organic component. The metal component is nanoparticles or particles of a refractory metal or a refractory-metal compound capable of decomposing into refractory metal nanoparticles. The organic component is an organic compound having a char yield of at least 60% by weight or a thermoset made from the organic compound. A method of combining particles of a refractory metal or a refractory-metal compound capable of reacting or decomposing into refractory-metal nanoparticles, boron, and an organic compound having a char yield of at least 60% by weight to form a precursor mixture. A composition having nanoparticles of a refractory-metal boride that is not in the form of a powder.
PCT/US2013/037559 2012-05-01 2013-04-22 Refractory metal boride ceramics and methods of making thereof WO2013191804A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP2015510315A JP6236195B2 (en) 2012-05-01 2013-04-22 Refractory metal boride ceramic and method for producing the same
EP13806734.3A EP2844627A4 (en) 2012-05-01 2013-04-22 Refractory metal boride ceramics and methods of making thereof
KR1020147032251A KR20150013173A (en) 2012-05-01 2013-04-22 Refractory metal boride ceramics and methods of making thereof

Applications Claiming Priority (10)

Application Number Priority Date Filing Date Title
US201261640744P 2012-05-01 2012-05-01
US61/640,744 2012-05-01
US201261669201P 2012-07-09 2012-07-09
US61/669,201 2012-07-09
US201261693930P 2012-08-28 2012-08-28
US61/693,930 2012-08-28
US13/749,794 2013-01-25
US13/749,794 US8822023B2 (en) 2012-01-26 2013-01-25 Refractory metal ceramics and methods of making thereof
US13/768,219 US8865301B2 (en) 2012-01-26 2013-02-15 Refractory metal boride ceramics and methods of making thereof
US13/768,219 2013-02-15

Publications (3)

Publication Number Publication Date
WO2013191804A2 WO2013191804A2 (en) 2013-12-27
WO2013191804A3 true WO2013191804A3 (en) 2014-03-13
WO2013191804A9 WO2013191804A9 (en) 2014-07-03

Family

ID=49514706

Family Applications (2)

Application Number Title Priority Date Filing Date
PCT/US2013/028122 WO2013165538A1 (en) 2012-05-01 2013-02-28 Formation of boron carbide-boron nitride carbon compositions
PCT/US2013/037559 WO2013191804A2 (en) 2012-05-01 2013-04-22 Refractory metal boride ceramics and methods of making thereof

Family Applications Before (1)

Application Number Title Priority Date Filing Date
PCT/US2013/028122 WO2013165538A1 (en) 2012-05-01 2013-02-28 Formation of boron carbide-boron nitride carbon compositions

Country Status (4)

Country Link
EP (2) EP2852552A4 (en)
JP (1) JP6236195B2 (en)
KR (1) KR20150013173A (en)
WO (2) WO2013165538A1 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT16480U1 (en) * 2018-04-20 2019-10-15 Plansee Composite Mat Gmbh Target and method of making a target

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4582553A (en) * 1984-02-03 1986-04-15 Commonwealth Aluminum Corporation Process for manufacture of refractory hard metal containing plates for aluminum cell cathodes
US4937101A (en) * 1988-11-07 1990-06-26 Rohr Industries, Inc. Prereacted inhibitor powder for carbon-carbon composites
WO1994020651A2 (en) * 1993-03-09 1994-09-15 Moltech Invent Sa The bonding of bodies of refractory hard materials to carbonaceous supports
US20030006269A1 (en) * 2001-07-06 2003-01-09 General Atomics Reaction brazing of tungsten or molybdenum body to carbonaceous support
US20050202282A1 (en) * 2002-07-30 2005-09-15 Eads Space Transportation Sa Manufacturing process for a refractory material, protective coating that can be obtained with this process and uses of this process and this coating
US7722851B2 (en) * 2001-12-10 2010-05-25 The United States Of America As Represented By The Secretary Of The Navy Bulk synthesis of carbon nanotubes from metallic and ethynyl compounds

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5832224B2 (en) * 1978-09-27 1983-07-12 住友電気工業株式会社 Microcrystalline sintered body for tools and its manufacturing method
NO822739L (en) * 1981-08-31 1983-03-01 Battelle Memorial Institute SINTERIZATION COMPOSITION ON TITANBORIDE BASIS AND ITS USE FOR PREPARING SINTERED GOODS
US4512946A (en) * 1983-09-06 1985-04-23 General Electric Company Microcomposite of metal boride and ceramic particles
JPS62158169A (en) * 1985-12-27 1987-07-14 工業技術院長 Simultaneous synthesization and formation of high melting point inorganic compound
JPS62167261A (en) * 1986-01-21 1987-07-23 大阪大学長 Synthetic simultaneous sintering process for zirconium borate base composite ceramic
JPH01286968A (en) * 1988-05-11 1989-11-17 Agency Of Ind Science & Technol Production of silicon carbide fiber-reinforced group iv and v transition metal boride and carbide composition sintered form
JPH0369567A (en) * 1989-08-08 1991-03-25 Natl Inst For Res In Inorg Mater Production of particle dispersion type ceramics
JP3608669B2 (en) * 1993-10-01 2005-01-12 三菱レイヨン株式会社 Method for producing electrode substrate
JPH0812438A (en) * 1994-06-30 1996-01-16 Mitsubishi Materials Corp Boride ceramic composite material and its production
JP2818859B2 (en) * 1995-09-05 1998-10-30 工業技術院長 Method for producing carbon-boride ceramic spherical composite
JP2003191900A (en) * 2001-12-26 2003-07-09 Mitsubishi Heavy Ind Ltd Heat resisting material for space shuttle, hot structure member, space shuttle and manufacturing method for heat resisting material for space shuttle
US20060057050A1 (en) * 2002-01-11 2006-03-16 The Trustees Of Boston College Synthesis of boron carbide nanoparticles
JP5168690B2 (en) * 2007-03-23 2013-03-21 独立行政法人産業技術総合研究所 Boron nanoparticles or boron-containing nanoparticles and method for producing the same
FR2936517B1 (en) * 2008-09-29 2011-07-29 Snecma Propulsion Solide METHOD FOR MANUFACTURING THERMOSTRUCTURAL COMPOSITE MATERIAL PARTS

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4582553A (en) * 1984-02-03 1986-04-15 Commonwealth Aluminum Corporation Process for manufacture of refractory hard metal containing plates for aluminum cell cathodes
US4937101A (en) * 1988-11-07 1990-06-26 Rohr Industries, Inc. Prereacted inhibitor powder for carbon-carbon composites
WO1994020651A2 (en) * 1993-03-09 1994-09-15 Moltech Invent Sa The bonding of bodies of refractory hard materials to carbonaceous supports
US20030006269A1 (en) * 2001-07-06 2003-01-09 General Atomics Reaction brazing of tungsten or molybdenum body to carbonaceous support
US7722851B2 (en) * 2001-12-10 2010-05-25 The United States Of America As Represented By The Secretary Of The Navy Bulk synthesis of carbon nanotubes from metallic and ethynyl compounds
US20050202282A1 (en) * 2002-07-30 2005-09-15 Eads Space Transportation Sa Manufacturing process for a refractory material, protective coating that can be obtained with this process and uses of this process and this coating

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP2844627A4 *

Also Published As

Publication number Publication date
WO2013165538A1 (en) 2013-11-07
WO2013191804A9 (en) 2014-07-03
JP2015521150A (en) 2015-07-27
WO2013191804A2 (en) 2013-12-27
EP2844627A2 (en) 2015-03-11
JP6236195B2 (en) 2017-11-22
KR20150013173A (en) 2015-02-04
EP2852552A4 (en) 2016-03-09
EP2844627A4 (en) 2016-07-06
EP2852552A1 (en) 2015-04-01

Similar Documents

Publication Publication Date Title
WO2013112784A8 (en) Refractory metal ceramics and methods of making thereof
WO2011080336A3 (en) Graphite-containing moulded body and method for the production thereof
WO2012027194A3 (en) Boron nitride with attached mettalic particles, methods of making, and uses thereof
WO2015008406A8 (en) Mixed powder for powder metallurgy, method of manufacturing same, and method of manufacturing iron-based powder sintered body
CA2832433C (en) Vanadium-containing powder metallurgical powders and methods of their use
BR112012026123A2 (en) method of producing sinter
CA2593594A1 (en) Ceramic proppant with low specific weight
UA105539C2 (en) Polyamide resistant to heat aging
MX2013003734A (en) Light weight proppant with improved strength and methods of making same.
NZ598651A (en) Edible surface-modifying particles and methods for their manufacture
WO2014180951A3 (en) Copper alloy, use of a copper alloy, bearing having a copper alloy, and method for producing a bearing composed of a copper alloy
WO2009074679A3 (en) Improved coated fertilizer
WO2014184145A3 (en) Spinel forming refractory compositions, their method of production and use thereof
WO2015112582A8 (en) Fine particle size activated carbon
WO2014042406A3 (en) Iron chalcogenide nanocomposite and method for preparing same
MX345277B (en) Method for producing a sintered composite body.
MX2013014421A (en) Process for the preparation of a metal complex in an oily organic matrix.
WO2012035283A8 (en) Pharmaceutical composition
CL2014001312A1 (en) Production process of pellets with iron and molybdenum, which includes the mixing of a powder containing iron, molybdenum oxide powder and a carbonaceous powder, the addition to the mixture of a liquid and the reduction of humidity to less than 10% by weight; and pellets
MX2015016977A (en) Composition comprising one or more calcium-magnesium compounds in the form of compacts.
UA107953C2 (en) Method for producing graphite articles
WO2012128506A3 (en) Method for producing aluminum matrix composites, and aluminum matrix composites produced by the method
WO2013059523A3 (en) Carbonaceous material for purifying lignocellulosic oligomers
WO2013140810A8 (en) Method for adjusting precursor powder for sintered ore, and precursor powder for sintered ore
WO2013191804A3 (en) Refractory metal boride ceramics and methods of making thereof

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 13806734

Country of ref document: EP

Kind code of ref document: A2

ENP Entry into the national phase

Ref document number: 2015510315

Country of ref document: JP

Kind code of ref document: A

NENP Non-entry into the national phase

Ref country code: DE

ENP Entry into the national phase

Ref document number: 20147032251

Country of ref document: KR

Kind code of ref document: A

WWE Wipo information: entry into national phase

Ref document number: 2013806734

Country of ref document: EP