WO2013188404A3 - Catalytic pyrolysis of biomass in an auger reactor - Google Patents

Catalytic pyrolysis of biomass in an auger reactor Download PDF

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Publication number
WO2013188404A3
WO2013188404A3 PCT/US2013/045181 US2013045181W WO2013188404A3 WO 2013188404 A3 WO2013188404 A3 WO 2013188404A3 US 2013045181 W US2013045181 W US 2013045181W WO 2013188404 A3 WO2013188404 A3 WO 2013188404A3
Authority
WO
WIPO (PCT)
Prior art keywords
biomass
pyrolysis
catalytic pyrolysis
intermediates
auger
Prior art date
Application number
PCT/US2013/045181
Other languages
French (fr)
Other versions
WO2013188404A2 (en
Inventor
Daren E. Daugaard
Samuel T. Jones
Alexandru Platon
Kening Gong
Edgar Lotero
Original Assignee
Phillips 66 Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US13/914,146 external-priority patent/US20130327626A1/en
Application filed by Phillips 66 Company filed Critical Phillips 66 Company
Publication of WO2013188404A2 publication Critical patent/WO2013188404A2/en
Publication of WO2013188404A3 publication Critical patent/WO2013188404A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B7/00—Coke ovens with mechanical conveying means for the raw material inside the oven
    • C10B7/10—Coke ovens with mechanical conveying means for the raw material inside the oven with conveyor-screws
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B49/00—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated
    • C10B49/16—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B49/00—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated
    • C10B49/16—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form
    • C10B49/20—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form in dispersed form
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/02—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B57/00—Other carbonising or coking processes; Features of destructive distillation processes in general
    • C10B57/04—Other carbonising or coking processes; Features of destructive distillation processes in general using charges of special composition
    • C10B57/06—Other carbonising or coking processes; Features of destructive distillation processes in general using charges of special composition containing additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/08—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal with moving catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y02P20/145—Feedstock the feedstock being materials of biological origin
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

The present invention relates generally to the thermal conversion of biomass. Processes are disclosed for converting algal biomass to condensable vapor intermediates such as pyrolysis oil by means of pyrolysis in a reactor comprising at least one auger. The intermediates may be further processed for production of renewable hydrocarbon fuels. The disclosed processes assist in preventing premature devolatization of algal biomass during pyrolysis, thereby increasing efficiency and commercial feasibility.
PCT/US2013/045181 2012-06-12 2013-06-11 Catalytic pyrolysis of biomass in an auger reactor WO2013188404A2 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US201261658513P 2012-06-12 2012-06-12
US61/658,513 2012-06-12
US13/914,146 2013-06-10
US13/914,146 US20130327626A1 (en) 2012-06-12 2013-06-10 Catalytic pyrolysis of biomass in an auger reactor

Publications (2)

Publication Number Publication Date
WO2013188404A2 WO2013188404A2 (en) 2013-12-19
WO2013188404A3 true WO2013188404A3 (en) 2014-02-27

Family

ID=49714404

Family Applications (2)

Application Number Title Priority Date Filing Date
PCT/US2013/045181 WO2013188404A2 (en) 2012-06-12 2013-06-11 Catalytic pyrolysis of biomass in an auger reactor
PCT/US2013/045366 WO2013188515A1 (en) 2012-06-12 2013-06-12 Catalytic biomass pyrolysis in an auger reactor

Family Applications After (1)

Application Number Title Priority Date Filing Date
PCT/US2013/045366 WO2013188515A1 (en) 2012-06-12 2013-06-12 Catalytic biomass pyrolysis in an auger reactor

Country Status (2)

Country Link
US (1) US20130327627A1 (en)
WO (2) WO2013188404A2 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015013957A1 (en) * 2013-08-01 2015-02-05 中国科学技术大学 Method for preparing nitrogen-containing aromatic compound through catalytic pyrolysis from organic materials
US10144875B2 (en) * 2014-01-10 2018-12-04 Proton Power, Inc. Systems, and devices for liquid hydrocarbon fuel production, hydrocarbon chemical production, and aerosol capture
MX2017006543A (en) * 2014-11-17 2017-08-09 Anellotech Inc Processes for handling char in a catalytic fast pyrolysis process and char compositions.
US10280377B1 (en) * 2016-03-24 2019-05-07 Helge Carl Nestler Pyrolysis and steam cracking system
CN108253423A (en) * 2016-12-28 2018-07-06 赵钧永 The method for pyrolysis of solid waste and special pyrolysis system
EP3980511A4 (en) * 2019-06-06 2023-07-19 Hermal Bio Energy International Pty Ltd Production of products from biomass
EP3786356A1 (en) * 2019-09-02 2021-03-03 Huntsman International LLC A process for manufacturing an upgraded bio-oil from black liquor

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6387221B1 (en) * 1998-06-25 2002-05-14 James D. Schoenhard Processing method and system to convert garbage to oil
EP1964876A1 (en) * 2005-12-06 2008-09-03 Yuji Kohara Waste plastic liquefaction plant and waste plastic liquefaction process
US20110011721A1 (en) * 2009-07-16 2011-01-20 Champagne Gary E Vacuum Pyrolytic Gasification And Liquefaction To Produce Liquid And Gaseous Fuels From Biomass
US20110258914A1 (en) * 2011-05-15 2011-10-27 Avello Bioenergy, Inc. Methods for integrated fast pyrolysis processing of biomass
WO2012122351A2 (en) * 2011-03-08 2012-09-13 Mississippi State University Thermal transfer mechanisms for an auger pyrolysis reactor

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4097367A (en) 1977-07-25 1978-06-27 Mobil Oil Corporation Conversion of olefinic naphtha
FR2858570B1 (en) * 2003-08-04 2006-11-17 Gerard Poulleau PROCESS FOR THE THERMOLYSIS AND / OR DRYING OF ORGANIC WASTE USING A BALL OVEN
US7578927B2 (en) 2006-08-31 2009-08-25 Uop Llc Gasoline and diesel production from pyrolytic lignin produced from pyrolysis of cellulosic waste
EP2199364A3 (en) * 2008-12-10 2010-10-06 KiOR, Inc. Counter-current process for biomass conversion

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6387221B1 (en) * 1998-06-25 2002-05-14 James D. Schoenhard Processing method and system to convert garbage to oil
EP1964876A1 (en) * 2005-12-06 2008-09-03 Yuji Kohara Waste plastic liquefaction plant and waste plastic liquefaction process
US20110011721A1 (en) * 2009-07-16 2011-01-20 Champagne Gary E Vacuum Pyrolytic Gasification And Liquefaction To Produce Liquid And Gaseous Fuels From Biomass
WO2012122351A2 (en) * 2011-03-08 2012-09-13 Mississippi State University Thermal transfer mechanisms for an auger pyrolysis reactor
US20110258914A1 (en) * 2011-05-15 2011-10-27 Avello Bioenergy, Inc. Methods for integrated fast pyrolysis processing of biomass

Also Published As

Publication number Publication date
WO2013188515A1 (en) 2013-12-19
WO2013188404A2 (en) 2013-12-19
US20130327627A1 (en) 2013-12-12

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