WO2013171651A3 - Composant de type chromino-formeur, utilisation d'un tel composant dans une atmosphere riche en vapeur d'eau, interconnecteur d'electrolyseur eht - Google Patents

Composant de type chromino-formeur, utilisation d'un tel composant dans une atmosphere riche en vapeur d'eau, interconnecteur d'electrolyseur eht Download PDF

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Publication number
WO2013171651A3
WO2013171651A3 PCT/IB2013/053870 IB2013053870W WO2013171651A3 WO 2013171651 A3 WO2013171651 A3 WO 2013171651A3 IB 2013053870 W IB2013053870 W IB 2013053870W WO 2013171651 A3 WO2013171651 A3 WO 2013171651A3
Authority
WO
WIPO (PCT)
Prior art keywords
component
steam
chromia
interconnector
rich atmosphere
Prior art date
Application number
PCT/IB2013/053870
Other languages
English (en)
Other versions
WO2013171651A2 (fr
Inventor
Aude BREVET
Clara DESGRANGES
Richard Laucournet
Emmanuel Rigal
Valérie PARRY
Sébastien CHEVALIER
Maria Rosa ARDIGO
Ioana Popa
Richard Bousquet
Pauline GIRARDON
Frédéic PERRY
Original Assignee
Commissariat A L'energie Atomique Et Aux Energies Alternatives
Universite De Bourgogne
Aperam Stainless France
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Commissariat A L'energie Atomique Et Aux Energies Alternatives, Universite De Bourgogne, Aperam Stainless France filed Critical Commissariat A L'energie Atomique Et Aux Energies Alternatives
Publication of WO2013171651A2 publication Critical patent/WO2013171651A2/fr
Publication of WO2013171651A3 publication Critical patent/WO2013171651A3/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/08—Oxides
    • C23C14/088—Oxides of the type ABO3 with A representing alkali, alkaline earth metal or Pb and B representing a refractory or rare earth metal
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/60—Constructional parts of cells
    • C25B9/65—Means for supplying current; Electrode connections; Electric inter-cell connections
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/70—Assemblies comprising two or more cells
    • C25B9/73—Assemblies comprising two or more cells of the filter-press type
    • C25B9/77—Assemblies comprising two or more cells of the filter-press type having diaphragms
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0204—Non-porous and characterised by the material
    • H01M8/0206—Metals or alloys
    • H01M8/0208—Alloys
    • H01M8/021—Alloys based on iron
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0204—Non-porous and characterised by the material
    • H01M8/0215—Glass; Ceramic materials
    • H01M8/0217—Complex oxides, optionally doped, of the type AMO3, A being an alkaline earth metal or rare earth metal and M being a metal, e.g. perovskites
    • H01M8/0219—Chromium complex oxides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0204—Non-porous and characterised by the material
    • H01M8/0223—Composites
    • H01M8/0228—Composites in the form of layered or coated products
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M2008/1293—Fuel cells with solid oxide electrolytes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • General Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Composite Materials (AREA)
  • Fuel Cell (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Electrochromic Elements, Electrophoresis, Or Variable Reflection Or Absorption Elements (AREA)

Abstract

L'invention a pour objet un composant en alliage métallique (8), de type chromino-formeur, dont l'élément de base est du Fer (Fe) ou du Nickel (Ni), et dont au moins une partie de la surface est revêtue d'un unique oxyde (11) MOx apte à être réduit au moins partiellement dans l'atmosphère réductrice, riche en vapeur d'eau H2O, à faible pO2 équivalente, d'un traitement thermique qu'il subit ultérieurement. L'invention a trait également à l'utilisation d'un tel composant dans une atmosphère riche en vapeur d'eau, à un interconnecteur d'électrolyseur EHT et un procédé de traitement de surface associés.
PCT/IB2013/053870 2012-05-15 2013-05-13 Composant de type chromino-formeur, utilisation d'un tel composant dans une atmosphere riche en vapeur d'eau, interconnecteur d'electrolyseur eht WO2013171651A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1254467A FR2990700A1 (fr) 2012-05-15 2012-05-15 Composant en alliage metallique, de type chromimo-formeur, utilisation d'un tel composant dans une atmosphere riche en vapeur d'eau, interconnecteur d'electrolyseur eht et procede de traitement de surface associes.
FR1254467 2012-05-15

Publications (2)

Publication Number Publication Date
WO2013171651A2 WO2013171651A2 (fr) 2013-11-21
WO2013171651A3 true WO2013171651A3 (fr) 2014-02-20

Family

ID=48699882

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB2013/053870 WO2013171651A2 (fr) 2012-05-15 2013-05-13 Composant de type chromino-formeur, utilisation d'un tel composant dans une atmosphere riche en vapeur d'eau, interconnecteur d'electrolyseur eht

Country Status (2)

Country Link
FR (1) FR2990700A1 (fr)
WO (1) WO2013171651A2 (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20200049825A (ko) * 2017-09-08 2020-05-08 하스콜리 아이슬란드 전이 금속 산화물 촉매를 사용한 전해 암모니아 생성
KR102529914B1 (ko) * 2018-03-22 2023-05-08 현대자동차주식회사 연료전지용 단위 셀
AU2020315120A1 (en) * 2019-07-17 2022-02-24 Haldor Topsøe A/S A method for chromium upgrading of ferritic steel interconnects for solid oxide cell stack applications
FR3104324B1 (fr) * 2019-12-10 2021-12-03 Commissariat A L Energie Atomique Et Aux Energies Alternatives Procédé de réalisation amélioré d’un composant constituant un interconnecteur d’électrolyseur EHT ou de pile à combustible SOFC.

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4950562A (en) * 1988-04-21 1990-08-21 Toa Nenryo Kogyo Kabushiki Kaisha Solid electrolyte type fuel cells
US20030194592A1 (en) * 2002-04-10 2003-10-16 Hilliard Donald Bennett Solid oxide electrolytic device
DE10306649A1 (de) * 2003-02-18 2004-09-02 Forschungszentrum Jülich GmbH Schutzschicht für hochtemperaturbelastete Substrate, sowie Verfahren zur Herstellung derselben
WO2009094289A2 (fr) * 2008-01-24 2009-07-30 Battelle Memorial Institute Nouvelle approche pour une stabilité et une efficacité améliorées d'interconnexions métalliques de pile à combustible à oxyde solide (sofc)

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19547699C2 (de) 1995-12-20 2000-01-13 Forschungszentrum Juelich Gmbh Bipolare Platte mit selektiver Beschichtung
US6326096B1 (en) 1998-02-04 2001-12-04 Gas Research Institute Solid oxide fuel cell interconnector
US6054231A (en) 1998-07-24 2000-04-25 Gas Research Institute Solid oxide fuel cell interconnector
EP1850412A1 (fr) 2006-04-26 2007-10-31 Technical University of Denmark Un retêvement multicouche
ATE502409T1 (de) 2007-01-09 2011-04-15 Univ Denmark Tech Dtu Herstellungsverfahren für eine mehrlagige sperrschichtstruktur für eine festoxidbrennstoffzelle

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4950562A (en) * 1988-04-21 1990-08-21 Toa Nenryo Kogyo Kabushiki Kaisha Solid electrolyte type fuel cells
US20030194592A1 (en) * 2002-04-10 2003-10-16 Hilliard Donald Bennett Solid oxide electrolytic device
DE10306649A1 (de) * 2003-02-18 2004-09-02 Forschungszentrum Jülich GmbH Schutzschicht für hochtemperaturbelastete Substrate, sowie Verfahren zur Herstellung derselben
WO2009094289A2 (fr) * 2008-01-24 2009-07-30 Battelle Memorial Institute Nouvelle approche pour une stabilité et une efficacité améliorées d'interconnexions métalliques de pile à combustible à oxyde solide (sofc)

Also Published As

Publication number Publication date
FR2990700A1 (fr) 2013-11-22
WO2013171651A2 (fr) 2013-11-21

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