WO2013166225A2 - Procédés de production d'une biomasse à haute densité d'énergie et de sucres ou de dérivés du sucre, par hydrolyse et torréfaction intégrées - Google Patents

Procédés de production d'une biomasse à haute densité d'énergie et de sucres ou de dérivés du sucre, par hydrolyse et torréfaction intégrées Download PDF

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Publication number
WO2013166225A2
WO2013166225A2 PCT/US2013/039175 US2013039175W WO2013166225A2 WO 2013166225 A2 WO2013166225 A2 WO 2013166225A2 US 2013039175 W US2013039175 W US 2013039175W WO 2013166225 A2 WO2013166225 A2 WO 2013166225A2
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Prior art keywords
biomass
solids
produce
energy
cellulose
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PCT/US2013/039175
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WO2013166225A3 (fr
Inventor
Theodora Retsina
Vesa Pylkkanen
Ryan O'connor
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Api Intellectual Property Holdings, Llc
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Priority to BR112014027055A priority Critical patent/BR112014027055A2/pt
Publication of WO2013166225A2 publication Critical patent/WO2013166225A2/fr
Publication of WO2013166225A3 publication Critical patent/WO2013166225A3/fr

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00—Solid fuels
    • C10L5/40—Solid fuels essentially based on materials of non-mineral origin
    • C10L5/44—Solid fuels essentially based on materials of non-mineral origin on vegetable substances
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B1/00—Preparatory treatment of cellulose for making derivatives thereof, e.g. pre-treatment, pre-soaking, activation
    • C08B1/003—Preparation of cellulose solutions, i.e. dopes, with different possible solvents, e.g. ionic liquids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08H—DERIVATIVES OF NATURAL MACROMOLECULAR COMPOUNDS
    • C08H8/00—Macromolecular compounds derived from lignocellulosic materials
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00—Solid fuels
    • C10L5/40—Solid fuels essentially based on materials of non-mineral origin
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L9/00—Treating solid fuels to improve their combustion
    • C10L9/08—Treating solid fuels to improve their combustion by heat treatments, e.g. calcining
    • C10L9/083—Torrefaction
    • C—CHEMISTRY; METALLURGY
    • C13—SUGAR INDUSTRY
    • C13K—SACCHARIDES OBTAINED FROM NATURAL SOURCES OR BY HYDROLYSIS OF NATURALLY OCCURRING DISACCHARIDES, OLIGOSACCHARIDES OR POLYSACCHARIDES
    • C13K1/00—Glucose; Glucose-containing syrups
    • C13K1/02—Glucose; Glucose-containing syrups obtained by saccharification of cellulosic materials
    • C—CHEMISTRY; METALLURGY
    • C13—SUGAR INDUSTRY
    • C13K—SACCHARIDES OBTAINED FROM NATURAL SOURCES OR BY HYDROLYSIS OF NATURALLY OCCURRING DISACCHARIDES, OLIGOSACCHARIDES OR POLYSACCHARIDES
    • C13K13/00—Sugars not otherwise provided for in this class
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/02—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
    • F23G5/027—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/02—Combustion or pyrolysis
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/04—Gasification
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/26—Composting, fermenting or anaerobic digestion fuel components or materials from which fuels are prepared
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/28—Cutting, disintegrating, shredding or grinding
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/30—Pressing, compressing or compacting
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/54—Specific separation steps for separating fractions, components or impurities during preparation or upgrading of a fuel
    • C10L2290/544—Extraction for separating fractions, components or impurities during preparation or upgrading of a fuel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel

Definitions

  • the present invention generally relates to processes for preparing energy-dense biomass for combustion, while also recovering fermentable sugars from the biomass.
  • Wood and biomass burning is making a comeback after over century of domination by coal, petroleum, and natural gas for power generation.
  • the availability of energy-dense fossil fuels and efficient transportation networks made centralized power production the technology of choice.
  • biomass heat and power plants and district heating are enjoying a renaissance. This popularity is driven in part by the carbon-neutral nature of most biomass (i.e., no net C0 2 emissions).
  • renewable-energy portfolio mandates require that utilities construct renewable power plants.
  • One challenge to combusting biomass is its high moisture content.
  • Living and freshly cut biomass typically contains moisture between 40% and 60%. In loose storage, the biomass dryness can reach air-dry moisture of about 10%>. This drying of wood is slow, typically requiring at least a full summer season. This necessitates double handling and increases procurement cost. It can be advantageous to first pelletize biomass, which can drive moisture out of the biomass, by using part of the biomass energy, waste heat, or a fossil fuel. The final moisture from pelletizing is typically 5-7%, which is similar to moisture of coal. Boiler efficiencies increase approximately half a percent with each percentage removal of moisture.
  • biomass In biomass, cellulose and hemicellulose each have about half of the calorific heat value of coal, because of high oxygen content of polymeric sugar constituents. Lignin has a similar calorific heat value to coal, but sulfur is nearly absent.
  • the combined energy content of biomass is typically 8,000-9,000 Btu/lb, as compared to 10,000-14,000 Btu/lb in coal.
  • the boiler efficiency for biomass firing typically ranges from 50- 65%. A large portion of heat generated in combustion escapes as steam through the stack. Therefore, converting coal-burning boilers to biomass firing may reduce boiler capacity by as much as 60%. There is a need to maximize utilization of these assets, and therefore more energy-dense biomass is desired.
  • Feeding irregularly shaped biomass also represents a challenge.
  • Pelletizing can produce uniformly sized material that does not bridge or lodge easily in a storage silo. On the other hand, the pelletized material can absorb moisture, if stored loosely outdoors.
  • Ash content of biomass typically varies between 0.4%> and 15%.
  • Hardwood and softwood stem and forest trimmings contain only 0.4% to 0.8% ash that is rich in calcium and potassium.
  • Other biomass materials including pulp and paper sludge, paper waste, recycled paper and construction waste, can contain up to 30%> ash.
  • Such ash includes minerals in plant capillaries, dirt on the surface, and coating in the paper.
  • the wood exposed to salt water contains elevated levels of sodium and chlorides.
  • Agricultural residues of annual plants such as corn stover, corn fiber, wheat straw, sugarcane bagasse, rice straw, oat straw, barley straw, and miscanthus can contain up to 10% or more ash that is rich in silica, potassium, and chlorine.
  • the agricultural residue material is very lean in sulfur, typically less than 0.1%, versus coal sulfur content of 0.5-7.5%.
  • Significant minerals in these annual agricultural residues include potassium, sodium, silica, calcium, and corrosive halogens such as chlorides.
  • the present invention addresses the aforementioned needs in the art.
  • the invention provides a process for producing energy-dense biomass and fermentable sugars from cellulosic biomass, the process comprising:
  • step (d) utilizes hydrotorrefaction.
  • Hydrotorrefaction may alternatively, or additionally, be incorporated earlier in the process, such as in step (b).
  • the extraction solution may include pressurized hot water under hydrotorrefaction conditions.
  • the extraction solution further contains sulfur dioxide, sulfurous acid, sulfuric acid, or any combination thereof.
  • step (c) includes washing the cellulose-rich solids using an aqueous wash solution, to produce a wash filtrate; and optionally combining at least some of the wash filtrate with the extract liquor.
  • step (c) further includes pressing the cellulose-rich solids to produce the dewatered cellulose-rich solids and a press filtrate; and optionally combining at least some of the press filtrate with the extract liquor.
  • the process may further comprise refining or milling the dewatered cellulose-rich solids prior to step (d).
  • Step (e) may employ a dilute acid for hydrolyzing the hemicellulosic oligomers.
  • the dissolved lignin may be recovered from the extract liquor.
  • the process further comprises pelletizing the intermediate solids, to produce biomass pellets, in some embodiments.
  • the biomass pellets may have an energy content from about 8,500 Btu/lb to about 12,000 Btu/lb on a dry basis, such as at least 9,000 Btu/lb or at least 10,000 Btu/lb on a dry basis.
  • the energy-dense biomass may be combusted to produce power and/or heat.
  • the process further comprises a step of fermenting the fermentable sugars to a fermentation product, such as ethanol, 1- butanol, or isobutanol.
  • a fermentation product such as ethanol, 1- butanol, or isobutanol.
  • torrefying e.g., hydrotorrefying
  • the process may include pelletizing the energy-dense biomass.
  • the energy-dense biomass may be directly combusted or co-combusted with another solid fuel, or gasified or co-gasified with another carbonaceous material.
  • the process includes hydrolyzing the hemicelluloses into fermentable sugars, which may then be fermented to ethanol, for example. In other embodiments, the process includes converting at least a portion of the hemicelluloses into furfural. The furfural may be recovered. In some embodiments,
  • step (d) is configured to co-produce (along with energy-dense biomass) 5-hydroxymethylfurfural and/or levulinic acid from part of the intermediate solids.
  • the process further comprises pelletizing the energy-dense biomass.
  • the energy-dense biomass may be directly or indirectly combusted or gasified, without being pelletized.
  • the hemicelluloses may be hydrolyzed into fermentable sugars.
  • At least a portion of the hemicelluloses may be intentionally converted into furfural.
  • the furfural may be recovered as a product, or it may further react to produce a solid char (containing humic acids) and recovered with the energy-dense biomass.
  • Step (b) may be configured to co-produce 5- hydroxymethylfurfural and/or levulinic acid from part of the feedstock.
  • the present invention also provides systems and apparatus to carry out the processes described.
  • FIG. 1 is a simplified block-flow diagram depicting the process of some embodiments of the present invention. Dashed lines indicate optional streams. DETAILED DESCRIPTION OF EMBODIMENTS OF THE INVENTION
  • phase consisting of excludes any element, step, or ingredient not specified in the claim.
  • phrase consists of (or variations thereof) appears in a clause of the body of a claim, rather than immediately following the preamble, it limits only the element set forth in that clause; other elements are not excluded from the claim as a whole.
  • phase consisting essentially of limits the scope of a claim to the specified elements or method steps, plus those that do not materially affect the basis and novel characteristic(s) of the claimed subject matter.
  • the present invention is premised, at least in part, on the realization that pretreatment of biomass may be utilized to remove hemicellulose and cellulose from the biomass, and thereby significantly increase the energy density of the biomass.
  • the pretreated biomass will also be cleaned of ash components, to reduce particulate emissions upon combustion of the biomass.
  • the extract may be further treated to make fermentable sugars, and optionally fermentation products.
  • unused solids or other combustible components recovered at any point may be co-combusted with the pretreated biomass, or separately recovered.
  • Biomass for purposes of this disclosure, shall be construed as any biogenic feedstock or mixture of a biogenic and non-biogenic feedstock.
  • biomass includes at least carbon, hydrogen, and oxygen.
  • the methods and apparatus of the invention can accommodate a wide range of feedstocks of various types, sizes, and moisture contents.
  • Biomass includes, for example, plant and plant-derived material, vegetation, agricultural waste, forestry waste, wood waste, paper waste, animal- derived waste, poultry-derived waste, and municipal solid waste.
  • the biomass feedstock may include one or more materials selected from: softwood chips, hardwood chips, timber harvesting residues, tree branches, tree stumps, knots, leaves, bark, sawdust, off-spec paper pulp, cellulose, corn, corn stover, wheat straw, rice straw, sugarcane, sugarcane bagasse, switchgrass, miscanthus, animal manure, municipal garbage, municipal sewage, commercial waste, grape pumice, almond shells, pecan shells, coconut shells, coffee grounds, grass pellets, hay pellets, wood pellets, cardboard, paper,
  • Selection of a particular feedstock or feedstocks is not regarded as technically critical, but is carried out in a manner that tends to favor an economical process. Typically, regardless of the feedstocks chosen, there can be (in some embodiments) screening to remove undesirable materials.
  • the feedstock can optionally be dried prior to processing.
  • the feedstock employed may be provided or processed into a wide variety of particle sizes or shapes.
  • the feed material may be a fine powder, or a mixture of fine and coarse particles.
  • the feed material may be in the form of large pieces of material, such as wood chips or other forms of wood (e.g., round, cylindrical, square, etc.).
  • the feed material comprises pellets or other agglomerated forms of particles that have been pressed together or otherwise bound, such as with a binder.
  • the binder may be a lignin derivative, a sugar-degradation product (e.g., furfural), or a component released from the starting biomass, such as acetic acid or an acetate salt thereof.
  • the process starts as biomass is received or reduced to approximately 1 ⁇ 4" thickness.
  • the biomass chips are fed to a pressurized extraction vessel operating continuously or in batch mode.
  • the chips may be steamed or water-washed to remove dirt and entrained air.
  • the chips are immersed with aqueous liquor or saturated vapor and heated to a temperature between about 100°C to about 250°C, for example 150°C, 160°C, 170°C,
  • the chips are heated to about 180°C to
  • the pressure in the pressurized vessel may be adjusted to maintain the aqueous liquor as a liquid, a vapor, or a combination thereof.
  • Exemplary pressures are about 1 atm to about 30 atm, such as about 3 atm, 5 atm, 10 atm, or 15 atm.
  • the aqueous liquor may contain acidifying compounds, such as (but not limited to) sulfuric acid, sulfurous acid, sulfur dioxide, acetic acid, formic acid, or oxalic acid, or combinations thereof.
  • the dilute acid concentration can range from 0.01% to 10% as necessary to improve solubility of particular minerals, such as potassium, sodium, or silica.
  • the acid concentration is selected from about 0.01% to 4%, such as 0.1%, 0.5%, 1%, 1.5%, 2%, 2.5%, 3%, or 3.5%.
  • a second step may include depressurization of the extracted chips.
  • the vapor can be used for heating the incoming woodchips or cooking liquor, directly or indirectly.
  • the volatilized organic acids e.g., acetic acid
  • the volatilized organic acids which are generated or included in the cooking step, may be recycled back to the cooking.
  • a third step may include washing the extracted chips.
  • the washing may be accomplished with water, recycled condensates, recycled permeate, or combination thereof.
  • a liquid biomass extract is produced.
  • a countercurrent configuration may be used to maximize the biomass extract concentration. Washing typically removes most of the dissolved material, including hemicelluloses and minerals.
  • the final consistency of the dewatered cellulose-rich solids may be increased to 30%> or more, preferably to 50%> or more, using a mechanical pressing device.
  • the third step, or an additional step prior to drying (below), may include further hydrolyzing the extracted chips with enzymes or an acid to extract some of the cellulose as fermentable glucose.
  • the removal of cellulose increases the heating value of the remaining lignin-rich solids.
  • the heating value of the remaining solids can approach that of lignin, i.e. in the range of about 10,000 to 12,000 Btu/lb.
  • the additional hydrolysis is mild hydrolysis that leaves a substantial portion of cellulose in the extracted solids.
  • the mild hydrolysis can take advantage of the initial extraction (first step) of most or all of the hemicellulosic material, leaving a somewhat hollow structure.
  • the hollow structure can increase the effectiveness of cellulose hydrolysis, such as by reducing mass-transfer limitations of enzymes or acids in solution.
  • the enzymes are preferably cellulase enzymes. Enzymes may be introduced to the extracted chips along with the wash solution, e.g. water, recycled condensates, recycled permeate, or combinations thereof. Alternatively, or additionally, enzymatic hydrolysis may be carried out following washing and removal of hemicelluloses, minerals, and other soluble material.
  • the wash solution e.g. water, recycled condensates, recycled permeate, or combinations thereof.
  • enzymatic hydrolysis may be carried out following washing and removal of hemicelluloses, minerals, and other soluble material.
  • Enzymes may be added to the extracted chips before or after mechanical pressing. That is, enzymatic hydrolysis may be carried out and then the solids pressed to final consistency; or, the solids may be pressed to high consistency (e.g., 30% or more) and then enzymes introduced to carry out cellulose hydrolysis. It may be beneficial to conduct refining or milling of the dewatered cellulose-rich solids prior to the enzymatic hydrolysis.
  • the enzymatic hydrolysis may be achieved in a separate unit, such as between washing and drying, or as an integrated part of washing.
  • at least a portion of enzymes are recycled in a batch or continuous process.
  • the acid may be selected from sulfuric acid, sulfurous acid, sulfur dioxide, formic acid, acetic acid, oxalic acid, or combinations thereof. Dilute-acid hydrolysis is preferred, to avoid sugar degradation. In some embodiments, sulfur dioxide is preferred for so enable better downstream acid recovery. Acids may be introduced to the extracted chips along with the wash solution, e.g. water, recycled condensates, recycled permeate, or combinations thereof. Alternatively, or additionally, acid hydrolysis may be carried out following washing and removal of hemicelluloses, minerals, and other soluble material.
  • Acids may be added to the extracted chips before or after mechanical pressing. That is, acid hydrolysis may be carried out and then the solids pressed to final consistency; or, the solids may be pressed to high consistency (e.g., 30% or more) and then acids introduced to carry out cellulose hydrolysis. It may be beneficial to conduct refining or milling of the dewatered cellulose-rich solids prior to the acid hydrolysis.
  • the acid hydrolysis may be achieved in a separate unit, such as between washing and drying, or as an integrated part of washing. In some embodiments, at least a portion of the acid is recycled in a batch or continuous process.
  • a fourth step may include drying of the extracted solids to a desired final moisture.
  • the heat necessary for drying may be derived from combusting part of the starting biomass. Alternatively, or additionally, the heat for drying may be provided by other means, such as a natural gas boiler or other auxiliary fossil fuel, or from a waste heat source.
  • a fifth step may include preparing the biomass for combustion.
  • This step may include refining, milling, fluidizing, compacting, torrefying, carbonizing, and/or pelletizing the extracted biomass.
  • the biomass may be fed to a boiler in the form of fine powder, loose fiber, pellets, briquettes, extrudates, or any other suitable form.
  • pellets of extracted biomass (“biomass pellets") are preferred.
  • biomass may be extruded through a pressurized chamber to form uniformly sized pellets or briquettes. Mild refining using a blow unit may be employed to disrupt the fibers and reduce particle size, since it may be beneficial to avoid longer fibers in pellets.
  • the energy-dense biomass will generally have higher energy density compared to a process that does not extract hemicellulosic sugars from the feedstock prior to combustion. Depleting the biomass of both hemicellulose and cellulose enriches the remaining material in lignin, which has a higher energy density than hemicellulose or cellulose.
  • the extracted solids are fed to a torrefaction unit.
  • Torrefaction is a form of mild pyrolysis at temperatures typically ranging between 200°C to 325°C. During torrefaction, biomass properties are changed to obtain better fuel quality for combustion and gasification applications.
  • Torrefaction of biomass particles is well-known and is a process in which biomass particles are heated in a low-oxygen or oxygen-free environment. Volatile compounds within the particles are released, including water, and the cellular structure of the particles is degraded, resulting in a partial loss of mass and an increase in friability. Friability means the ability of a solid substance to be reduced to smaller pieces. Torrefaction also can enhance the moisture resistance of the solids. Torrefied particles have an enhanced energy value when measured in terms of heat energy per unit of weight. Torrefaction of biomass also can improve the grindability. This leads to more efficient co-firing in existing coal-fired power stations or entrained-flow gasification for the production of chemicals and transportation fuels.
  • the degree of torrefaction of biomass particles depends on several factors, including the level of heat applied, the length of time the heat is applied, and surrounding gas conditions (particularly with respect to oxygen level).
  • Known biomass-torrefaction systems control the variables of heat, residence time, and oxygen levels to achieve consistent torrefied particles, typically employing mechanical means to convey the particles, such as rotating trays or screws.
  • the energy density of the biomass pellet is from about 8,500 Btu/lb to about 12,000 Btu/lb on a dry basis, such as at least 9,000 Btu/lb or at least 10,000 Btu/lb on a dry basis.
  • a sixth step is combustion of the biomass, which in some
  • biomass pellets e.g. following torrefaction.
  • the biomass pellets are fed to a boiler and combusted, preferably with excess air, using well-known combustion apparatus.
  • Boiler bottom may be fixed, moving, or fluidized for the best efficiency.
  • the flue gas is cooled and fly ash is collected into gravity collectors.
  • the energy-dense biomass has lower inorganic emissions potential compared to the original cellulosic biomass, in preferred embodiments.
  • the reason is that the energy-dense biomass will contain lower ash content compared to a process that does not extract inorganic components from the feedstock prior to combustion, in the manner disclosed herein.
  • the extracted biomass is sufficiently low in ash such that when the extracted biomass is combusted, particulate matter emissions are very low.
  • the particulate matter emissions are so low as to avoid the need for any additional cleaning device, and associated control system, in order to meet current emission regulations.
  • a seventh step may include treatment of the biomass extract to form a hydrolysate comprising fermentable hemicellulose sugars.
  • the biomass extract is hydrolyzed using dilute acidic conditions at temperatures between about 100°C and 190°C, for example about 120°C, 130°C, 140°C, 150°C, 160°C, or 170°C, and preferably from 120°C to 150°C.
  • the acid may be selected from sulfuric acid, sulfurous acid, or sulfur dioxide. Alternatively, or additionally, the acid may include formic acid, acetic acid, or oxalic acid from the cooking liquor or recycled from previous hydrolysis.
  • hemicellulase enzymes may be used instead of acid hydrolysis.
  • the lignin from this step may be separated and recovered, or recycled to increase the heating value of the pellets, or sent directly to the boiler.
  • An eighth step may include evaporation of hydro lysate to remove some or most of the volatile acids.
  • the evaporation may include flashing or stripping to remove sulfur dioxide, if present, prior to removal of volatile acids.
  • the evaporation step is preferably performed below the acetic acid dissociation pH of 4.8, and most preferably a pH selected from about 1 to about 2.5.
  • the dissolved solids are concentrated, such as to about 10% to about 40% to optimize fermentable
  • Saccharomyces Cerevisiae fermentation can withstand dissolved solids concentrations of 30-50%), while Clostridia Acetobutylicum fermentation is viable at 10-20% concentrations only, for example.
  • additional evaporation steps may be employed.
  • These additional evaporation steps may be conducted at different conditions (e.g., temperature, pressure, and pH) relative to the first evaporation step.
  • some or all of the organic acids evaporated may be recycled, as vapor or condensate, to the first step (cooking step) and/or third step (washing step) to remove assist in the removal of minerals from the biomass.
  • This recycle of organic acids, such as acetic acid may be optimized along with process conditions that may vary depending on the amount recycled, to improve the cooking and/or washing effectiveness.
  • Some embodiments of the invention enable processing of "agricultural residues," which for present purposes is meant to include lignocellulosic biomass associated with food crops, annual grasses, energy crops, or other annually renewable feedstocks.
  • exemplary agricultural residues include, but are not limited to, corn stover, corn fiber, wheat straw, sugarcane bagasse, rice straw, oat straw, barley straw, miscanthus, energy cane, or combinations thereof.
  • the agricultural residue is sugarcane bagasse.
  • Certain variations of the invention provide a process for producing biomass pellets and fermentable sugars from cellulosic biomass, the process comprising:
  • the hemicellulosic sugars are combined with the fermentable sugars derived from step (g), to form a combined biomass-sugars stream.
  • the hemicellulosic sugars are separately recovered from the fermentable sugars derived from step (g).
  • the fermentable hemicellulose sugars are recovered from solution, in purified form.
  • the fermentable hemicellulose sugars are fermented to produce of biochemicals or bio fuels such as (but by no means limited to) ethanol, 1-butanol, isobutanol, acetic acid, lactic acid, or any other fermentation products.
  • a purified fermentation product may be produced by distilling the fermentation product, which will also generate a distillation bottoms stream containing residual solids.
  • a bottoms evaporation stage may be used, to produce residual solids.
  • residual solids such as distillation bottoms
  • residual solids may be recovered, or burned in solid or slurry form, or recycled to be combined into the biomass pellets.
  • Use of the fermentation residual solids may require further removal of minerals.
  • any leftover solids may be used for burning as additional liquefied biomass, after concentration of the distillation bottoms.
  • Part or all of the residual solids may be co-combusted with the energy- dense biomass, if desired.
  • the process may include recovering the residual solids as a fermentation co-product in solid, liquid, or slurry form.
  • the fermentation co-product may be used as a fertilizer or fertilizer component, since it will typically be rich in potassium, nitrogen, and/or phosphorous.
  • the process may include co-combusting the recovered lignin with the energy-dense biomass, to produce power.
  • the recovered lignin may be combined with the energy-dense biomass prior to combustion, or they may be co- fired as separate streams.
  • the lignin can act as a pellet binder.
  • Part or all of the residual solids may be co-combusted with the energy- dense biomass, if desired.
  • the process may include recovering the residual solids as a fermentation co-product in solid, liquid, or slurry form.
  • the fermentation co-product may be used as a fertilizer or fertilizer component, since it will typically be rich in potassium, nitrogen, and/or phosphorous.
  • the process further comprises combining, at a pH of about 4.8 to 10 or higher, a portion of the vaporized acetic acid with an alkali oxide, alkali hydroxide, alkali carbonate, and/or alkali bicarbonate, wherein the alkali is selected from the group consisting of potassium, sodium, magnesium, calcium, and combinations thereof, to convert the portion of the vaporized acetic acid to an alkaline acetate.
  • the alkaline acetate may be recovered. If desired, purified acetic acid may be generated from the alkaline acetate, such as through electrolytic reduction to acetic acid.
  • Green Power+ ® technology commonly assigned with the assignee of this patent application, may be employed or modified as taught in one or more co-pending patent applications, U.S. Patent App. Nos. 12/474,267;
  • hydrothermal torrefaction is equivalent to hydrothermal torrefaction," “hydrothermal carbonization,” “wet torrefaction,” “wet carbonization,” “aqueous torrefaction,” “hydrothermal pretreatment,” and the like.
  • hydrotorrefaction is conducted with a substantial amount of hot water on intimate contact with the solids.
  • the ratio of hot water to solids may vary widely, such as from about 1 to about 20 (ratio of water to biomass, by weight). In some embodiments, the water:biomass weight ratio is about 4, 5, 6, 8, or 10.
  • hydrotorrefaction requires water, it is not necessary to dry the solids following the previous step(s). Thus, wet biomass may be used directly. Additionally if there is any aqueous pretreatment or upstream aqueous processing prior to hydrotorrefaction, the water does not need to be removed until after the hydrotorrefaction has been performed.
  • the water:biomass weight ratio is less than 1, such as about 0.8, about 0.5, about 0.2, about 0.1, about 0.05, about 0.02, about 0.01, or less, including substantially no water added or present.
  • hydrotorrefaction is carried out at a temperature selected from about 150°C to about 300°C, such as about 200°C to about 275°C.
  • a temperature selected from about 150°C to about 300°C, such as about 200°C to about 275°C.
  • higher temperatures lead to higher energy density in the final solid product.
  • Temperatures above about 300°C are undesired for hydrotorrefaction because other chemical reactions will occur, such as pyrolysis, decomposition, or steam reforming of the solids.
  • hydrotorrefaction is carried out at a residence time (or reaction time for a batch reactor) of about 2 minutes to about 60 minutes, such as about 5 minutes to about 15 minutes. Generally, lower reaction times will require higher reaction temperatures, and vice-versa.
  • hydrotorrefaction is carried out at a pressure from about 100 psia to about 1,000 psia, such as from about 200 psia to about 800 psia.
  • the hydrotorrefaction pressure is not independently controlled but is determined by the equilibrium pressure at the selected temperature.
  • the equilibrium pressure may be the static (closed system), saturated pressure within the reactor, for example.
  • the hydrotorrefaction pressure may be controlled to a certain level if desired, such as by introducing an inert gas (e.g., N 2 or C0 2 ) into the reactor.
  • the hydrotorrefaction pressure is controlled or adjusted by withdrawing material from the hydrotorrefaction reactor, which may be periodic or continuous.
  • hydrotorrefied solids from hydrotorrefaction can be characterized, in various embodiments, as solids with modest fuel densification (e.g., 10-50% increase in energy density), significant oxygen elimination, and increased friability.
  • the hydrotorrefied solids are hydrophobic, or at least have an increased fuel densification (e.g., 10-50% increase in energy density), significant oxygen elimination, and increased friability.
  • the hydrotorrefied solids are hydrophobic, or at least have an increased
  • hydrophobicity relative to the starting material so that the solids are suitable for storage and transportation.
  • the hydrotorrefied solids can be pelletized, with or without added binder.
  • Components that are present may serve as a binder— including lignin, furans, resins, and humic acids.
  • biomass is first extracted with steam or hot water, such as described previously, to produce a stream with hemicelluloses and extracted solids.
  • the hemicelluloses may be separately processed to produce fermentable sugars, which then may be fermented to ethanol, 1-butanol, isobutanol, or other fermentation products.
  • the extracted solids may be fed, optionally without any intermediate drying, to a hydrotorrefaction unit operated under suitable conditions, such as described above.
  • the hydrotorrefied solids may then be pelletized, without any external binders, to produced pellets.
  • the pellets may be used in combustion to produce heat and/or power.
  • biomass is first extracted with steam or hot water, such as described previously, to produce a stream with hemicelluloses and extracted solids.
  • the hemicelluloses may be separately processed to produce fermentable sugars, which then may be fermented to ethanol, 1-butanol, isobutanol, or other fermentation products.
  • the extracted solids may be fed, optionally without any intermediate drying, to a hydrotorrefaction unit operated under suitable conditions, such as described above.
  • the hydrotorrefied solids may then be fed directly to a combustion unit to produce heat and/or power.
  • the hydrotorrefied solids may be co-fed with another solid fuel, such as coal, raw biomass, untorrefied biomass, dry- torrefied biomass, or lignin.
  • hydrotorrefied solids may be fed to a gasification unit to produce syngas (H 2 and CO).
  • the syngas may then be used to produce heat and/or power.
  • the syngas may be used to produce fuels and chemicals, such as methanol or alcohols, hydrocarbons, olefins, or organic acids, by chemical catalysis or fermentation.
  • biomass is first extracted with steam or hot water, such as described previously, to produce a stream with hemicelluloses and extracted solids.
  • the hemicelluloses may be separately processed to maximize production of furfural, 5-hydroxymethylfurfural, and/or levulinic acid (see further discussion below with respect to these sugar derivatives).
  • the extracted solids may be fed, optionally without any intermediate drying, to a hydrotorrefaction unit operated under suitable conditions.
  • the hydrotorrefied solids may then be pelletized, without any external binders, to produced pellets.
  • the pellets may be used in combustion to produce heat and/or power.
  • biomass is first extracted with steam or hot water, such as described previously, to produce a stream with hemicelluloses and extracted solids.
  • the hemicelluloses may be separately processed to maximize production of furfural, 5-hydroxymethylfurfural, and/or levulinic acid (see further discussion below with respect to these sugar derivatives).
  • the extracted solids may be fed, optionally without any intermediate drying, to a hydrotorrefaction unit operated under suitable conditions, such as described above.
  • the hydrotorrefied solids may then be fed directly to a combustion unit to produce heat and/or power.
  • the hydrotorrefied solids may be co-fed with another solid fuel, such as coal, raw biomass, untorrefied biomass, dry-torrefied biomass, or lignin.
  • extracted solids may be fed, optionally without any intermediate drying, to a hydrotorrefaction unit operated under conditions for, and configured for, producing two main products: hydrotorrefied solids (char), and levulinic acid.
  • the hydrotorrefaction unit is optimized to hydrolyze cellulose to C 6 sugars (e.g., glucose), followed by conversion of the C 6 to 5-hydroxymethylfurfural and then to levulinic acid, without allowing significant reactions of levulinic acid to carbonaceous solids.
  • a separation unit may be in operable communication with the hydrotorrefaction unit, to separate levulinic acid as a distinct product.
  • the hydrotorrefied solids may then be pelletized, without any external binders, to produced pellets.
  • the pellets may be used in combustion to produce heat and/or power.
  • the hydrotorrefied solids may be fed directly to a combustion unit to produce heat and/or power, or co-combusted with another solid fuel.
  • biomass is first extracted with steam or hot water, such as described previously, to produce a stream with hemicelluloses and extracted solids.
  • the extracted solids may be fed, optionally without any intermediate drying, to a hydrotorrefaction unit operated under conditions for, and configured for, producing two main products: hydrotorrefied solids (char), and levulinic acid.
  • the hydrotorrefied solids may be pelletized.
  • the hemicelluloses may be separately processed to produce fermentable sugars, which then may be fermented to ethanol, 1- butanol, isobutanol, or other fermentation products.
  • products from an integrated process may include energy-dense pellets, ethanol, and levulinic acid.
  • biomass is first extracted with steam or hot water, such as described previously, to produce a stream with hemicelluloses and extracted solids.
  • the extracted solids may be fed, optionally without any intermediate drying, to a hydrotorrefaction unit operated under conditions for, and configured for, producing two main products: hydrotorrefied solids (char), and levulinic acid.
  • the hydrotorrefied solids may be pelletized.
  • the hemicelluloses may be separately processed to maximize production of furfural, 5-hydroxymethylfurfural, and/or levulinic acid.
  • products from an integrated process may include energy-dense pellets, furfural, and levulinic acid.
  • hydrotorrefaction be integrated downstream of biomass extraction/hydrolysis, but it can alternatively be integrated upstream, or in connection with, biomass
  • biomass is fed to an extraction reactor operated under hydrotorrefaction conditions, with pressurized hot water.
  • the liquid hot water may include process condensate from one or more downstream steps.
  • Hemicelluloses are removed during hydrotorrefaction.
  • the hemicelluloses further react to sugar monomers.
  • these sugar monomers are allowed to react to furfural, 5-HMF, and/or levulinic acid.
  • the extracted solids undergo hydrotorrefaction, in the same unit or a separate unit.
  • the hydrotorrefied solids may then be pelletized, without any external binders, to produced pellets.
  • the pellets may be used in combustion to produce heat and/or power, for example. Or, the hydrotorrefied solids may be combusted or gasified directly.
  • biomass is fed to an extraction reactor operated under hydrotorrefaction conditions, with pressurized hot water.
  • the liquid hot water may include process condensate from one or more downstream steps.
  • Hemicelluloses are removed during hydrotorrefaction.
  • the hemicelluloses further react to sugar monomers.
  • these sugar monomers are separately fermented to ethanol or another fermentation product.
  • the extracted solids undergo hydrotorrefaction, in the same unit or a separate unit.
  • the hydrotorrefied solids may then be pelletized, without any external binders, to produced pellets.
  • the pellets may be used in combustion to produce heat and/or power, for example. Or, the hydrotorrefied solids may be combusted or gasified directly.
  • the product profile may be adjusted by varying the reaction conditions as well as the reactor configuration.
  • a continuous countercurrent reactor may be employed to optimize the release of hemicelluloses and conversion to sugars, while allowing the solid material to continue hydrotorrefaction.
  • the system may be configured to capture
  • process conditions that may be adjusted to promote furfural, 5-hydromethylfurfural, and/or levulinic acid include, in one or more reaction steps, temperature, pH or acid concentration, reaction time, catalysts or other additives (e.g. FeS0 4 ), reactor flow patterns, and control of engagement between liquid and vapor phases. Conditions may be optimized specifically for furfural, or specifically for 5-hydromethylfurfural, or specifically for levulinic acid, or for any combination thereof.
  • the hemicelluloses that were initially extracted may then be processed to produce furfural and 5-hydroxymethylfurfural (HMF), in one or more steps. Some furfural and HMF may be produced during the initial extraction itself, under suitable conditions.
  • the hemicellulose-containing liquor is fed to a unit for production of furfural directly from C 5 monomers and oligomers and HMF directly from C 6 monomers and oligomers.
  • the hemicelluloses are first subject to a step to further hydrolyze the oligomers into monomers. This step may be performed with acids or enzymes. Depending on the feedstock, the hydro lyzed hemicelluloses will contain various quantities of C 5 sugars (e.g., xylose) and C 6 sugars (e.g., glucose).
  • C 5 sugars e.g., xylose
  • C 6 sugars e.g., glucose
  • a reaction step is optimized to produce furfural.
  • a reaction step is optimized instead to produce HMF.
  • a reaction step is configured to produce both furfural and HMF, which may be then separated or may be further processed together.
  • the liquid may be further processed to convert at least some of the HMF into levulinic acid, with or without intermediate separation of furfural.
  • a reaction step is optimized to produce furfural, which is then recovered, followed by production of levulinic acid, which is separately recovered.
  • a single step is configured to produce both furfural and levulinic acid, which may be recovered together in a single liquid or may be separated from each other and then recovered. Conversion of HMF to levulinic acid also produces formic acid, which may be separately recovered, recycled, or purged.
  • the furfural is further reacted, in the same reactor or in a downstream unit, to one or more acids such as succinic acid, maleic acid, fumaric acid, or humic acid.
  • acids such as succinic acid, maleic acid, fumaric acid, or humic acid.
  • conditions are selected to maximize conversion of furfural to succinic acid.
  • the furfural reacts to humic acid or char, in the hydrotorrefied solids or another solid stream.
  • the process is configured to produce, in crude or purified form, one or more products selected from the group consisting of levulinic acid, furfural, 5-hydroxymethylfurfural, formic acid, succinic acid, maleic acid, fumaric acid, and acetic acid. Mixtures of any of the foregoing are possible. Any of these acids may be recycled in the process, such as to enhance the initial extraction of hemicelluloses or to enhance secondary hydrolysis of hemicellulose oligomers to monomers. Thus in some embodiments, acetic acid, formic acid, or other acids may be recovered and recycled.
  • Reaction conditions for producing furfural, HMF, and levulinic acid may vary widely (see, for example, U.S. Patent Nos. 3,701,789 and 4,897,497 for some conditions that may be used). Temperatures may vary, for example, from about 120°C to about 275°C, such as about 200°C to about 230°C. Reaction times may vary from less than 1 minute to more than 1 hour, including about 1, 2, 3, 5, 10, 15, 20, 30, 45, and 60 minutes.
  • the quantity of acid may vary widely, depending on other conditions, such as from about 0.1% to about 10% by weight, e.g. about 0.5%>, about 1%), or about 2% acid.
  • the acid may include sulfuric acid, sulfurous acid, sulfur dioxide, formic acid, levulinic acid, succinic acid, maleic acid, fumaric acid, acetic acid, or lignosulfonic acid, for example.
  • the residence times of the reactors may vary. There is an interplay of time and temperature, so that for a desired amount of hydrolysis or dehydration, higher temperatures may allow for lower reaction times, and vice versa.
  • the residence time in a continuous reactor is the volume divided by the volumetric flow rate.
  • the residence time in a batch reactor is the batch reaction time, following heating to reaction temperature.
  • the mode of operation for the reactor, and overall system may be continuous, semi-continuous, batch, or any combination or variation of these.
  • the reactor is a continuous, countercurrent reactor in which solids and liquid flow substantially in opposite directions.
  • the reactor may also be operated in batch but with simulated countercurrent flow.
  • the conditions of the second stage may be the same as in the first stage, or may be more or less severe. If furfural is removed, at least in part, a quantity of acid may also be removed (e.g. by evaporation) in which case it may be necessary to introduce an additional amount of acid to the second stage.

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Abstract

Cette invention concerne des procédés pour convertir une biomasse en une biomasse à haute densité d'énergie pour une combustion, seule ou en combinaison avec un autre combustible solide. Dans certaines variantes, la biomasse est extraite pour produire une liqueur d'extrait contenant des oligomères hémicellulosiques et des matières solides riches en cellulose ; les oligomères hémicellulosiques sont retirés ; et les matières solides riches en cellulose sont torréfiées pour produire une biomasse à haute densité d'énergie. Dans certains modes de réalisation, une hydrotorréfaction est utilisée pour produire une biomasse hydrophobe, à haute densité d'énergie dans un procédé économe en énergie qui évite un séchage intermédiaire entre l'extraction/hydrolyse et la torréfaction. La biomasse à haute densité d'énergie peut être mise sous la forme de pastilles ou directement brûlée ou gazéifiée. Les oligomères hémicellulosiques peuvent être hydrolysés en sucres fermentables, puis fermentés en éthanol ou autres produits, ou mis à réagir encore pour produire du furfural ou autres produits.
PCT/US2013/039175 2012-05-02 2013-05-02 Procédés de production d'une biomasse à haute densité d'énergie et de sucres ou de dérivés du sucre, par hydrolyse et torréfaction intégrées WO2013166225A2 (fr)

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