WO2013134078A1 - Electrolytic cell including a three-phase interface to react carbon-based gases in an aqueous electrolyte - Google Patents
Electrolytic cell including a three-phase interface to react carbon-based gases in an aqueous electrolyte Download PDFInfo
- Publication number
- WO2013134078A1 WO2013134078A1 PCT/US2013/028748 US2013028748W WO2013134078A1 WO 2013134078 A1 WO2013134078 A1 WO 2013134078A1 US 2013028748 W US2013028748 W US 2013028748W WO 2013134078 A1 WO2013134078 A1 WO 2013134078A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- catalyst
- aqueous electrolyte
- carbon
- reaction
- gaseous feedstock
- Prior art date
Links
- 239000007789 gas Substances 0.000 title claims abstract description 76
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 54
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 38
- 239000003792 electrolyte Substances 0.000 title claims description 90
- 238000006243 chemical reaction Methods 0.000 claims abstract description 97
- 238000000034 method Methods 0.000 claims abstract description 92
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 32
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 32
- 239000007788 liquid Substances 0.000 claims abstract description 19
- 150000002894 organic compounds Chemical class 0.000 claims abstract description 11
- 230000004048 modification Effects 0.000 claims abstract description 10
- 238000012986 modification Methods 0.000 claims abstract description 10
- 229910002090 carbon oxide Inorganic materials 0.000 claims abstract description 8
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000003054 catalyst Substances 0.000 claims description 64
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 45
- 229910052802 copper Inorganic materials 0.000 claims description 43
- 239000010949 copper Substances 0.000 claims description 43
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 34
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical group [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 20
- 238000009792 diffusion process Methods 0.000 claims description 20
- 230000002209 hydrophobic effect Effects 0.000 claims description 20
- 229910052751 metal Inorganic materials 0.000 claims description 19
- 239000002184 metal Substances 0.000 claims description 19
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 claims description 19
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 18
- 229910052709 silver Inorganic materials 0.000 claims description 18
- 239000004332 silver Substances 0.000 claims description 18
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 16
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 claims description 16
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 15
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 14
- 239000001569 carbon dioxide Substances 0.000 claims description 14
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 14
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 13
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 11
- 239000001103 potassium chloride Substances 0.000 claims description 10
- 235000011164 potassium chloride Nutrition 0.000 claims description 10
- 235000002639 sodium chloride Nutrition 0.000 claims description 10
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 9
- 230000005501 phase interface Effects 0.000 claims description 9
- 239000011949 solid catalyst Substances 0.000 claims description 9
- 239000004215 Carbon black (E152) Substances 0.000 claims description 8
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical group [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 8
- 150000004820 halides Chemical class 0.000 claims description 8
- 229910052763 palladium Inorganic materials 0.000 claims description 8
- 239000011780 sodium chloride Substances 0.000 claims description 8
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 7
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 7
- 239000011248 coating agent Substances 0.000 claims description 7
- 238000000576 coating method Methods 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 7
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 7
- 229910052737 gold Inorganic materials 0.000 claims description 7
- 239000010931 gold Substances 0.000 claims description 7
- 229910052742 iron Inorganic materials 0.000 claims description 7
- 229910052697 platinum Inorganic materials 0.000 claims description 7
- 229910052702 rhenium Inorganic materials 0.000 claims description 7
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims description 7
- 229910052707 ruthenium Inorganic materials 0.000 claims description 7
- 239000000243 solution Substances 0.000 claims description 7
- 229910052718 tin Inorganic materials 0.000 claims description 7
- 239000011135 tin Substances 0.000 claims description 7
- 229910052725 zinc Inorganic materials 0.000 claims description 7
- 239000011701 zinc Substances 0.000 claims description 7
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 5
- 239000011230 binding agent Substances 0.000 claims description 5
- 239000006185 dispersion Substances 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- 239000012267 brine Substances 0.000 claims description 4
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 4
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 4
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 4
- 229910052759 nickel Inorganic materials 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- 239000002002 slurry Substances 0.000 claims description 4
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 claims description 4
- 239000003513 alkali Substances 0.000 claims description 3
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 claims description 3
- KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 claims description 3
- 229940112669 cuprous oxide Drugs 0.000 claims description 3
- 238000000151 deposition Methods 0.000 claims description 3
- 230000005611 electricity Effects 0.000 claims description 3
- 238000003487 electrochemical reaction Methods 0.000 claims description 3
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- 230000003213 activating effect Effects 0.000 claims description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 2
- 238000009713 electroplating Methods 0.000 claims description 2
- 239000012528 membrane Substances 0.000 claims description 2
- 150000002823 nitrates Chemical class 0.000 claims description 2
- 150000002826 nitrites Chemical class 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 claims description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 2
- 229940009188 silver Drugs 0.000 claims 8
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 claims 4
- 229910000041 hydrogen chloride Inorganic materials 0.000 claims 4
- 238000007747 plating Methods 0.000 claims 3
- 239000003638 chemical reducing agent Substances 0.000 claims 2
- 229910017053 inorganic salt Inorganic materials 0.000 claims 2
- 229920000557 Nafion® Polymers 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 229910052747 lanthanoid Inorganic materials 0.000 claims 1
- 150000002602 lanthanoids Chemical class 0.000 claims 1
- 238000010422 painting Methods 0.000 claims 1
- 230000008569 process Effects 0.000 abstract description 25
- -1 chain lengthening Chemical class 0.000 abstract description 10
- 150000001298 alcohols Chemical class 0.000 abstract description 7
- 239000012071 phase Substances 0.000 description 20
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 17
- 239000000047 product Substances 0.000 description 17
- 210000004027 cell Anatomy 0.000 description 12
- 239000011244 liquid electrolyte Substances 0.000 description 10
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 9
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 150000002739 metals Chemical class 0.000 description 7
- 230000009467 reduction Effects 0.000 description 7
- 239000005977 Ethylene Substances 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
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- 150000002500 ions Chemical class 0.000 description 5
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- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- 229960003280 cupric chloride Drugs 0.000 description 4
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 4
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- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 3
- PRNCMAKCNVRZFX-UHFFFAOYSA-N 3,7-dimethyloctan-1-ol Chemical compound CC(C)CCCC(C)CCO PRNCMAKCNVRZFX-UHFFFAOYSA-N 0.000 description 3
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Natural products OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 3
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- 229910021591 Copper(I) chloride Inorganic materials 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
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- 239000011668 ascorbic acid Substances 0.000 description 3
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 description 3
- 229940045803 cuprous chloride Drugs 0.000 description 3
- 238000011161 development Methods 0.000 description 3
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- 239000003345 natural gas Substances 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- GQEZCXVZFLOKMC-UHFFFAOYSA-N 1-hexadecene Chemical compound CCCCCCCCCCCCCCC=C GQEZCXVZFLOKMC-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
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- HFJRKMMYBMWEAD-UHFFFAOYSA-N dodecanal Chemical compound CCCCCCCCCCCC=O HFJRKMMYBMWEAD-UHFFFAOYSA-N 0.000 description 2
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- CATSNJVOTSVZJV-UHFFFAOYSA-N heptan-2-one Chemical compound CCCCCC(C)=O CATSNJVOTSVZJV-UHFFFAOYSA-N 0.000 description 2
- NGAZZOYFWWSOGK-UHFFFAOYSA-N heptan-3-one Chemical compound CCCCC(=O)CC NGAZZOYFWWSOGK-UHFFFAOYSA-N 0.000 description 2
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- 229910000497 Amalgam Inorganic materials 0.000 description 1
- BSYNRYMUTXBXSQ-UHFFFAOYSA-N Aspirin Chemical compound CC(=O)OC1=CC=CC=C1C(O)=O BSYNRYMUTXBXSQ-UHFFFAOYSA-N 0.000 description 1
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- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
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- 101150034459 Parpbp gene Proteins 0.000 description 1
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- 239000003963 antioxidant agent Substances 0.000 description 1
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- 235000006708 antioxidants Nutrition 0.000 description 1
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- 230000015572 biosynthetic process Effects 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
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- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 1
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- XAMUDJHXFNRLCY-UHFFFAOYSA-N phenthoate Chemical compound CCOC(=O)C(SP(=S)(OC)OC)C1=CC=CC=C1 XAMUDJHXFNRLCY-UHFFFAOYSA-N 0.000 description 1
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- 229910052723 transition metal Inorganic materials 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
- C25B11/03—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form perforated or foraminous
- C25B11/031—Porous electrodes
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
- C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
- C25B11/075—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of a single catalytic element or catalytic compound
- C25B11/081—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of a single catalytic element or catalytic compound the element being a noble metal
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B3/00—Electrolytic production of organic compounds
- C25B3/20—Processes
- C25B3/23—Oxidation
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B3/00—Electrolytic production of organic compounds
- C25B3/20—Processes
- C25B3/25—Reduction
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T156/00—Adhesive bonding and miscellaneous chemical manufacture
- Y10T156/10—Methods of surface bonding and/or assembly therefor
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
RU2014139975A RU2014139975A (en) | 2012-03-03 | 2013-03-01 | ELECTROLYTIC CELL, INCLUDING A THREE-PHASE SECTION BORDER, FOR CARRYING OUT GAS RESPONSE ON THE BASIS OF CARBON IN WATER ELECTROLYTE |
CA2866306A CA2866306A1 (en) | 2012-03-03 | 2013-03-01 | Electrolytic cell including a three-phase interface to react carbon-based gases in an aqueous electrolyte |
CN201380012374.9A CN104428449A (en) | 2012-03-03 | 2013-03-01 | Electrolytic cell including a three-phase interface to react carbon-based gases in an aqueous electrolyte |
EP13757822.5A EP2823091A4 (en) | 2012-03-03 | 2013-03-01 | Electrolytic cell including a three-phase interface to react carbon-based gases in an aqueous electrolyte |
Applications Claiming Priority (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201261606398P | 2012-03-03 | 2012-03-03 | |
US61/606,398 | 2012-03-03 | ||
US201261608583P | 2012-03-08 | 2012-03-08 | |
US61/608,583 | 2012-03-08 | ||
US201261639544P | 2012-04-27 | 2012-04-27 | |
US61/639,544 | 2012-04-27 | ||
US201261713487P | 2012-10-13 | 2012-10-13 | |
US61/713,487 | 2012-10-13 | ||
US13/783,102 US20130228470A1 (en) | 2012-03-03 | 2013-03-01 | Method and apparatus for an electrolytic cell including a three-phase interface to react carbon-based gases in an aqueous electrolyte |
US13/783,102 | 2013-03-01 |
Publications (1)
Publication Number | Publication Date |
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WO2013134078A1 true WO2013134078A1 (en) | 2013-09-12 |
Family
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PCT/US2013/028748 WO2013134078A1 (en) | 2012-03-03 | 2013-03-01 | Electrolytic cell including a three-phase interface to react carbon-based gases in an aqueous electrolyte |
Country Status (6)
Country | Link |
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US (1) | US20130228470A1 (en) |
EP (1) | EP2823091A4 (en) |
CN (1) | CN104428449A (en) |
CA (1) | CA2866306A1 (en) |
RU (1) | RU2014139975A (en) |
WO (1) | WO2013134078A1 (en) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
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US10329676B2 (en) * | 2012-07-26 | 2019-06-25 | Avantium Knowledge Centre B.V. | Method and system for electrochemical reduction of carbon dioxide employing a gas diffusion electrode |
KR20150129672A (en) * | 2013-03-14 | 2015-11-20 | 에드 첸 | Method and apparatus for the electrical activation of a catalyst |
WO2015051211A2 (en) * | 2013-10-03 | 2015-04-09 | Brown University | Electrochemical reduction of co2 at copper nanofoams |
CN106521544B (en) * | 2015-09-15 | 2018-07-13 | 中国科学院大连化学物理研究所 | Carbon dioxide electrochemical reduction porous electrode complex and its preparation and application |
US10774430B2 (en) | 2016-10-04 | 2020-09-15 | Johna Leddy | Carbon dioxide reduction and carbon compound electrochemistry in the presence of lanthanides |
US10675681B2 (en) | 2017-02-02 | 2020-06-09 | Honda Motor Co., Ltd. | Core shell |
DE102017204096A1 (en) * | 2017-03-13 | 2018-09-13 | Siemens Aktiengesellschaft | Production of gas diffusion electrodes with ion transport resins for the electrochemical reduction of CO2 to chemical recyclables |
US11613819B2 (en) | 2017-06-21 | 2023-03-28 | The Governing Council Of The University Of Toronto | Catalysts with sharp reaction interface for electrochemical CO2 reduction with enhanced selectivity |
DE102018201287A1 (en) * | 2018-01-29 | 2019-08-01 | Siemens Aktiengesellschaft | Porous electrode for the electrochemical conversion of organic compounds into two immiscible phases in an electrochemical flux reactor |
US11299811B2 (en) | 2018-01-29 | 2022-04-12 | Board Of Regents, The University Of Texas System | Continuous flow reactor and hybrid electro-catalyst for high selectivity production of C2H4 from CO2 and water via electrolysis |
CN109811364B (en) * | 2019-01-10 | 2020-10-27 | 北京化工大学 | Ruthenium/cuprous oxide electro-catalytic material and preparation method thereof |
US11686004B2 (en) * | 2019-10-22 | 2023-06-27 | University Of Cincinnati | Gas diffusion electrodes with segmented catalyst layers for CO2 reduction |
WO2021243199A1 (en) * | 2020-05-29 | 2021-12-02 | Newchem21 Inc. | Process for electrochemical oxidation of hydrocarbons |
WO2022184905A2 (en) * | 2021-03-04 | 2022-09-09 | Totalenergies Onetech | Co2 electroreduction to multi-carbon products in strong acid |
CN113151849B (en) * | 2021-03-24 | 2024-01-19 | 厦门大学 | Method for preparing lactic acid by using propane |
CN114373940A (en) * | 2021-12-16 | 2022-04-19 | 清华大学 | Gas diffusion electrode and preparation method and application thereof |
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2013
- 2013-03-01 CA CA2866306A patent/CA2866306A1/en not_active Abandoned
- 2013-03-01 CN CN201380012374.9A patent/CN104428449A/en active Pending
- 2013-03-01 EP EP13757822.5A patent/EP2823091A4/en not_active Withdrawn
- 2013-03-01 WO PCT/US2013/028748 patent/WO2013134078A1/en active Application Filing
- 2013-03-01 US US13/783,102 patent/US20130228470A1/en not_active Abandoned
- 2013-03-01 RU RU2014139975A patent/RU2014139975A/en not_active Application Discontinuation
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Also Published As
Publication number | Publication date |
---|---|
EP2823091A1 (en) | 2015-01-14 |
CA2866306A1 (en) | 2013-09-12 |
US20130228470A1 (en) | 2013-09-05 |
EP2823091A4 (en) | 2016-04-20 |
CN104428449A (en) | 2015-03-18 |
RU2014139975A (en) | 2016-04-20 |
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