WO2013126364A3 - Two-zone, close-coupled, dual-catalytic heavy oil hydroconversion process utilizing improved hydrotreating - Google Patents
Two-zone, close-coupled, dual-catalytic heavy oil hydroconversion process utilizing improved hydrotreating Download PDFInfo
- Publication number
- WO2013126364A3 WO2013126364A3 PCT/US2013/026789 US2013026789W WO2013126364A3 WO 2013126364 A3 WO2013126364 A3 WO 2013126364A3 US 2013026789 W US2013026789 W US 2013026789W WO 2013126364 A3 WO2013126364 A3 WO 2013126364A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- zone
- catalytic
- products
- thermo
- hydrotreating
- Prior art date
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Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/22—Non-catalytic cracking in the presence of hydrogen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/002—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal in combination with oil conversion- or refining processes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/06—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by destructive hydrogenation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/06—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by destructive hydrogenation
- C10G1/065—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by destructive hydrogenation in the presence of a solvent
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/24—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions with moving solid particles
- C10G47/26—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions with moving solid particles suspended in the oil, e.g. slurries
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
- C10G65/10—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only cracking steps
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
- C10G65/12—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including cracking steps and other hydrotreatment steps
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/4081—Recycling aspects
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
A process for hydroconversion of heavy oil feedstocks that effectively controls asphaltene condensation by utilization of a combination of dispersed coal, dispersed catalyst using a two- zone close-coupled thermo-catalytic reactor/catalytic-hydrotreating reactor configuration. The process converts heavy hydrocarbonaceous feed-stocks, a significant portion of which boils above 540°C, to high yields of high quality products boiling below 540°C. The first zone of the process is a thermo-catalytic zone, in which the feedstock is substantially converted to lower boiling products. The product of the thermo-catalytic zone is cooled somewhat and passed directly, without substantial loss of hydrogen partial pressure, into a catalytic-hydrotreating zone, where the thermo- catalytic zone effluent is hydrotreated to produce hydrotreated products suitable for further treatment into transportation fuels and other products. The catalytic-hydrotreating zone is comprised of two sub-zones, one before and one after a hot separator. The first treating sub-zone accomplishes the immediate hydrogenation of unstable molecules. The hot separator removes light products and gases providing a heavy product stream that can be more efficiently treated with higher purity recycle and make-up hydrogen-rich streams.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201261601344P | 2012-02-21 | 2012-02-21 | |
US61/601,344 | 2012-02-21 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2013126364A2 WO2013126364A2 (en) | 2013-08-29 |
WO2013126364A3 true WO2013126364A3 (en) | 2013-11-28 |
Family
ID=47755075
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2013/026789 WO2013126364A2 (en) | 2012-02-21 | 2013-02-20 | Two-zone, close-coupled, dual-catalytic heavy oil hydroconversion process utilizing improved hydrotreating |
Country Status (2)
Country | Link |
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AR (1) | AR090102A1 (en) |
WO (1) | WO2013126364A2 (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
MX345342B (en) | 2012-08-20 | 2017-01-24 | Inst Mexicano Del Petróleo | Process for improving heavy and extra heavy crude oil. |
US11680028B2 (en) | 2019-01-29 | 2023-06-20 | Sabic Global Technologies B.V. | Methods and systems for upgrading crude oils, heavy oils, and residues |
WO2020157631A1 (en) | 2019-01-29 | 2020-08-06 | Sabic Global Technologies B.V. | Conversion of heavy ends of crude oil or whole crude oil to high value chemicals using a combination of thermal hydroprocessing, hydrotreating with steam crackers under high severity conditions to maximize ethylene, propylene, butenes and benzene |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4559130A (en) * | 1984-08-27 | 1985-12-17 | Chevron Research Company | Metals-impregnated red mud as a first-stage catalyst in a two-stage, close-coupled thermal catalytic hydroconversion process |
US5246570A (en) * | 1992-04-09 | 1993-09-21 | Amoco Corporation | Coal liquefaction process using soluble molybdenum-containing organophosphorodithioate catalyst |
US5871638A (en) * | 1996-02-23 | 1999-02-16 | Hydrocarbon Technologies, Inc. | Dispersed anion-modified phosphorus-promoted iron oxide catalysts |
US5968347A (en) * | 1994-11-25 | 1999-10-19 | Kvaerner Process Technology Limited | Multi-step hydrodesulfurization process |
US20100155301A1 (en) * | 2008-12-18 | 2010-06-24 | Ifp | Hydrodemetallization and hydrodesulphurization catalysts, and use in a single formulation in a concatenated process |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4391699A (en) | 1976-12-27 | 1983-07-05 | Chevron Research Company | Coal liquefaction process |
US4422922A (en) | 1976-12-27 | 1983-12-27 | Chevron Research Company | Coal liquefaction and hydroprocessing of petroleum oils |
US4354920A (en) | 1976-12-27 | 1982-10-19 | Chevron Research Company | Coal liquefaction process |
US4330393A (en) | 1979-02-14 | 1982-05-18 | Chevron Research Company | Two-stage coal liquefaction process with petroleum-derived coal solvents |
US4564439A (en) | 1984-06-29 | 1986-01-14 | Chevron Research Company | Two-stage, close-coupled thermal catalytic hydroconversion process |
US4761220A (en) | 1984-10-31 | 1988-08-02 | Chevron Research Company | Hydroprocessing catalyst fines as a first-stage catalyst in a two-stage, close-coupled thermal catalytic hydroconversion process |
DE3634275A1 (en) | 1986-10-08 | 1988-04-28 | Veba Oel Entwicklungs Gmbh | METHOD FOR HYDROGENATING CONVERSION OF HEAVY AND RESIDUAL OILS |
CN1098337C (en) | 2000-11-02 | 2003-01-08 | 中国石油天然气股份有限公司 | Novel normal-pressure heavy oil suspension bed hydrogenation process adopting multi-metal liquid catalyst |
JP2008163097A (en) | 2006-12-27 | 2008-07-17 | Kobe Steel Ltd | Method for hydrocracking heavy oil |
-
2013
- 2013-02-20 WO PCT/US2013/026789 patent/WO2013126364A2/en active Application Filing
- 2013-02-21 AR ARP130100515 patent/AR090102A1/en unknown
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4559130A (en) * | 1984-08-27 | 1985-12-17 | Chevron Research Company | Metals-impregnated red mud as a first-stage catalyst in a two-stage, close-coupled thermal catalytic hydroconversion process |
US5246570A (en) * | 1992-04-09 | 1993-09-21 | Amoco Corporation | Coal liquefaction process using soluble molybdenum-containing organophosphorodithioate catalyst |
US5968347A (en) * | 1994-11-25 | 1999-10-19 | Kvaerner Process Technology Limited | Multi-step hydrodesulfurization process |
US5871638A (en) * | 1996-02-23 | 1999-02-16 | Hydrocarbon Technologies, Inc. | Dispersed anion-modified phosphorus-promoted iron oxide catalysts |
US20100155301A1 (en) * | 2008-12-18 | 2010-06-24 | Ifp | Hydrodemetallization and hydrodesulphurization catalysts, and use in a single formulation in a concatenated process |
Also Published As
Publication number | Publication date |
---|---|
AR090102A1 (en) | 2014-10-22 |
WO2013126364A2 (en) | 2013-08-29 |
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