WO2013126364A3 - Two-zone, close-coupled, dual-catalytic heavy oil hydroconversion process utilizing improved hydrotreating - Google Patents

Two-zone, close-coupled, dual-catalytic heavy oil hydroconversion process utilizing improved hydrotreating Download PDF

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Publication number
WO2013126364A3
WO2013126364A3 PCT/US2013/026789 US2013026789W WO2013126364A3 WO 2013126364 A3 WO2013126364 A3 WO 2013126364A3 US 2013026789 W US2013026789 W US 2013026789W WO 2013126364 A3 WO2013126364 A3 WO 2013126364A3
Authority
WO
WIPO (PCT)
Prior art keywords
zone
catalytic
products
thermo
hydrotreating
Prior art date
Application number
PCT/US2013/026789
Other languages
French (fr)
Other versions
WO2013126364A2 (en
Inventor
Dennis R. Cash
Forder J. GRAHAM
David S. MITCHELL
Joel W. ROSENTHAL
Original Assignee
4CRGroup LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 4CRGroup LLC filed Critical 4CRGroup LLC
Publication of WO2013126364A2 publication Critical patent/WO2013126364A2/en
Publication of WO2013126364A3 publication Critical patent/WO2013126364A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/22—Non-catalytic cracking in the presence of hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/002—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal in combination with oil conversion- or refining processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/06—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by destructive hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/06—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by destructive hydrogenation
    • C10G1/065—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by destructive hydrogenation in the presence of a solvent
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/24—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions with moving solid particles
    • C10G47/26—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions with moving solid particles suspended in the oil, e.g. slurries
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/10—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only cracking steps
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/12—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including cracking steps and other hydrotreatment steps
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4081—Recycling aspects

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

A process for hydroconversion of heavy oil feedstocks that effectively controls asphaltene condensation by utilization of a combination of dispersed coal, dispersed catalyst using a two- zone close-coupled thermo-catalytic reactor/catalytic-hydrotreating reactor configuration. The process converts heavy hydrocarbonaceous feed-stocks, a significant portion of which boils above 540°C, to high yields of high quality products boiling below 540°C. The first zone of the process is a thermo-catalytic zone, in which the feedstock is substantially converted to lower boiling products. The product of the thermo-catalytic zone is cooled somewhat and passed directly, without substantial loss of hydrogen partial pressure, into a catalytic-hydrotreating zone, where the thermo- catalytic zone effluent is hydrotreated to produce hydrotreated products suitable for further treatment into transportation fuels and other products. The catalytic-hydrotreating zone is comprised of two sub-zones, one before and one after a hot separator. The first treating sub-zone accomplishes the immediate hydrogenation of unstable molecules. The hot separator removes light products and gases providing a heavy product stream that can be more efficiently treated with higher purity recycle and make-up hydrogen-rich streams.
PCT/US2013/026789 2012-02-21 2013-02-20 Two-zone, close-coupled, dual-catalytic heavy oil hydroconversion process utilizing improved hydrotreating WO2013126364A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201261601344P 2012-02-21 2012-02-21
US61/601,344 2012-02-21

Publications (2)

Publication Number Publication Date
WO2013126364A2 WO2013126364A2 (en) 2013-08-29
WO2013126364A3 true WO2013126364A3 (en) 2013-11-28

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2013/026789 WO2013126364A2 (en) 2012-02-21 2013-02-20 Two-zone, close-coupled, dual-catalytic heavy oil hydroconversion process utilizing improved hydrotreating

Country Status (2)

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AR (1) AR090102A1 (en)
WO (1) WO2013126364A2 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MX345342B (en) 2012-08-20 2017-01-24 Inst Mexicano Del Petróleo Process for improving heavy and extra heavy crude oil.
US11680028B2 (en) 2019-01-29 2023-06-20 Sabic Global Technologies B.V. Methods and systems for upgrading crude oils, heavy oils, and residues
WO2020157631A1 (en) 2019-01-29 2020-08-06 Sabic Global Technologies B.V. Conversion of heavy ends of crude oil or whole crude oil to high value chemicals using a combination of thermal hydroprocessing, hydrotreating with steam crackers under high severity conditions to maximize ethylene, propylene, butenes and benzene

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4559130A (en) * 1984-08-27 1985-12-17 Chevron Research Company Metals-impregnated red mud as a first-stage catalyst in a two-stage, close-coupled thermal catalytic hydroconversion process
US5246570A (en) * 1992-04-09 1993-09-21 Amoco Corporation Coal liquefaction process using soluble molybdenum-containing organophosphorodithioate catalyst
US5871638A (en) * 1996-02-23 1999-02-16 Hydrocarbon Technologies, Inc. Dispersed anion-modified phosphorus-promoted iron oxide catalysts
US5968347A (en) * 1994-11-25 1999-10-19 Kvaerner Process Technology Limited Multi-step hydrodesulfurization process
US20100155301A1 (en) * 2008-12-18 2010-06-24 Ifp Hydrodemetallization and hydrodesulphurization catalysts, and use in a single formulation in a concatenated process

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4391699A (en) 1976-12-27 1983-07-05 Chevron Research Company Coal liquefaction process
US4422922A (en) 1976-12-27 1983-12-27 Chevron Research Company Coal liquefaction and hydroprocessing of petroleum oils
US4354920A (en) 1976-12-27 1982-10-19 Chevron Research Company Coal liquefaction process
US4330393A (en) 1979-02-14 1982-05-18 Chevron Research Company Two-stage coal liquefaction process with petroleum-derived coal solvents
US4564439A (en) 1984-06-29 1986-01-14 Chevron Research Company Two-stage, close-coupled thermal catalytic hydroconversion process
US4761220A (en) 1984-10-31 1988-08-02 Chevron Research Company Hydroprocessing catalyst fines as a first-stage catalyst in a two-stage, close-coupled thermal catalytic hydroconversion process
DE3634275A1 (en) 1986-10-08 1988-04-28 Veba Oel Entwicklungs Gmbh METHOD FOR HYDROGENATING CONVERSION OF HEAVY AND RESIDUAL OILS
CN1098337C (en) 2000-11-02 2003-01-08 中国石油天然气股份有限公司 Novel normal-pressure heavy oil suspension bed hydrogenation process adopting multi-metal liquid catalyst
JP2008163097A (en) 2006-12-27 2008-07-17 Kobe Steel Ltd Method for hydrocracking heavy oil

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4559130A (en) * 1984-08-27 1985-12-17 Chevron Research Company Metals-impregnated red mud as a first-stage catalyst in a two-stage, close-coupled thermal catalytic hydroconversion process
US5246570A (en) * 1992-04-09 1993-09-21 Amoco Corporation Coal liquefaction process using soluble molybdenum-containing organophosphorodithioate catalyst
US5968347A (en) * 1994-11-25 1999-10-19 Kvaerner Process Technology Limited Multi-step hydrodesulfurization process
US5871638A (en) * 1996-02-23 1999-02-16 Hydrocarbon Technologies, Inc. Dispersed anion-modified phosphorus-promoted iron oxide catalysts
US20100155301A1 (en) * 2008-12-18 2010-06-24 Ifp Hydrodemetallization and hydrodesulphurization catalysts, and use in a single formulation in a concatenated process

Also Published As

Publication number Publication date
AR090102A1 (en) 2014-10-22
WO2013126364A2 (en) 2013-08-29

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