WO2013123324A1 - Agent gélifiant en vue d'une utilisation dans des compositions cosmétiques - Google Patents

Agent gélifiant en vue d'une utilisation dans des compositions cosmétiques Download PDF

Info

Publication number
WO2013123324A1
WO2013123324A1 PCT/US2013/026334 US2013026334W WO2013123324A1 WO 2013123324 A1 WO2013123324 A1 WO 2013123324A1 US 2013026334 W US2013026334 W US 2013026334W WO 2013123324 A1 WO2013123324 A1 WO 2013123324A1
Authority
WO
WIPO (PCT)
Prior art keywords
composition
oil
gelling agent
clear
cosmetic
Prior art date
Application number
PCT/US2013/026334
Other languages
English (en)
Inventor
Wei Yu
Vijay Kumar Joshi
Original Assignee
Revlon
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Revlon filed Critical Revlon
Priority to EP13749649.3A priority Critical patent/EP2814448A4/fr
Priority to CA2868015A priority patent/CA2868015A1/fr
Priority to AU2013221395A priority patent/AU2013221395A1/en
Publication of WO2013123324A1 publication Critical patent/WO2013123324A1/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/42—Amides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8105—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • A61K8/8111—Homopolymers or copolymers of aliphatic olefines, e.g. polyethylene, polyisobutene; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q15/00—Anti-perspirants or body deodorants

Definitions

  • the present invention generally relates to a novel composition which is highly wearable transfer-resistant with excellent long wearing properties which, until now, could only be achieved through the use of traditional gelling agents, such as, natural and synthetic waxes. Moreover, the present invention relates to a composition that is easily and uniformly deposited and spread onto a keratinous substrate, having a unique texture and feel.
  • compositions especially cosmetic compositions
  • Many compositions have been developed for easy and comfortable application onto a targeted substrate.
  • many of these compositions are in fact difficult to apply and do not possess a smooth feel upon application.
  • compositions often times have the undesirable characteristics of stickiness, poor flexibility, and hardness (too soft or too hard).
  • traditional gelling agents do not provide a clear base which is desirable for cosmetic compositions. The undesirable characteristics and lack of clarity can be linked to the use of traditional gelling agents.
  • Cosmetic compositions have been formulated substituting polyamides for natural or synthetic waxes but this substitution does not yield the unique creamy texture and feel, or a clear base, having exceptional application properties sought in a cosmetic composition.
  • the present invention is directed to a composition
  • a composition comprising a gelling agent and an at least one oil, wherein the oil and gelling agent are in a ratio of about 2 to about 16.
  • the best oil to gelling agent ratio is about 4 to about 10.
  • the gelling agent(s) is a compound having a structure of (I):
  • R 2 , R 3 , R 4 , R 5 which are the same or different are selected from a hydrogen, a Ci - C 24 alkyl group;
  • X is selected from a heteroatom, C 2 to C 24 alkyl
  • Ri and R 6 which are the same or different are selected from a hydrogen, a C-i - C 24 alkyi group, a heteroatom.
  • the preferred gelling agent is 1 -[1 -Methyl-2-(1 -methyl-2- tridecyloxy-ethoxy)-ethyl]-3-(6- ⁇ 3-[1-methyl-2- ⁇ 1-methyl-2-tridecyloxy-ethoxy)-ethyl]- ureido ⁇ -hexyl)-urea.
  • the above-identified gelling agent is present in a concentration of about 6 to 14 weight percent of the composition
  • the preferred composition of the present invention is a cosmetic composition.
  • the composition can be anhydrous or an emulsion.
  • the water phase and oil phase have a matched refractive index.
  • the composition has a base comprised of a combination of gelling agent and oil. Additional ingredients can be added to the base and include for example, at least one additive chosen from an antioxidant, a filler, a film-former, a preserving agent, a fragrance, a neutralizing agent, a thickener, a cosmetic composition active agent, an emollient, a solvent, a pigment, a dye, or a stain and mixtures thereof.
  • the combination of the oil and gelling agent forms a clear gel which is used as a base composition to which other ingredients are added.
  • the composition can take the form of a stick, for example, a lipstick.
  • the stick can be a uniform color or can have a pigmented core surrounded by a clear shell.
  • composition using the oil and gelling agents disclosed herein has a flexibility of > about 30%, a stickiness of ⁇ about -10 grams, and a hardness of ⁇ about 100 grams.
  • Figure 1 compares hardness of the gelling agent and oil combination found in Example 1 and Example 2.
  • the points on the line are the various ratios of oil/gallant.
  • the y axis is the hardness value.
  • Figure 2 compares stickiness of the gelling agent and oil combination found in Example 1 and Example 2.
  • the points on the line are the various ratios of oil/gallant.
  • the y axis is the stickiness value.
  • the present invention is directed to a composition
  • a composition comprising a gelling agent and an at least one oil, wherein the oil and gelling agent are in a ratio of about 2 to about 16.
  • the best oil to gelling agent ratio is about 4 to about 10.
  • Film former or "film forming agent” or “film forming resin” as used herein means a polymer which, after dissolution in at least one solvent (such as, for example, water and organic solvents), leaves a film on the substrate to which it is applied, for example, once the at least one solvent evaporates, absorbs and/or dissipates on the substrate.
  • solvent such as, for example, water and organic solvents
  • Keratinous substrates include but are not limited to, skin, hair and nails.
  • ratio is used to express the relationship in quantity or amount of the oil and gelling agent.
  • anhydrous means a composition has little or no water.
  • An anhydrous composition is a composition having ⁇ 1% water.
  • the expression “at least one” means one or more and thus includes individual components as well as mixtures/combinations.
  • Long wear compositions refers to compositions where color remains the same or substantially the same as at the time of application, as viewed by the naked eye, after an extended period of time.
  • Long wear properties may be evaluated by any method known in the art for evaluating such properties. For example, long wear may be evaluated by a test involving the application of a composition to human hair, skin or lips and evaluating the color of the composition after an extended period of time. For example, the color of a composition may be evaluated immediately following application to hair, skin or lips and these characteristics may then be re-evaluated and compared after a certain amount of time. Further, these characteristics may be evaluated with respect to other compositions, such as commercially available compositions.
  • Transfer resistance refers to the quality exhibited by compositions that are not readily removed by contact with another material, such as, for example, a glass, an item of clothing or the skin, for example, when eating or drinking. Transfer resistance may be evaluated by any method known in the art for evaluating such. For example, transfer resistance of a composition may be evaluated by a "kiss" test.
  • the "kiss" test may involve application of the composition to human keratin material such as hair, skin or lips followed by rubbing a material, for example, a sheet of paper, against the hair, skin or lips after expiration of a certain amount of time following application, such as 2 minutes after application,
  • transfer resistance of a composition may be evaluated by the amount of product transferred from a wearer to any other substrate, such as transfer from the hair, skin or lips of an individual to a collar when putting on clothing after the expiration of a certain amount of time following application of the composition to the hair, skin or lips,
  • the amount of composition transferred to the substrate e.g., collar, or paper
  • the substrate e.g., collar, or paper
  • a composition may be transfer resistant if a majority of the product is left on the wearer's hair, skin or lips. Further, the amount transferred may be compared with that transferred by other compositions, such as commercially available compositions. In a preferred embodiment of the present invention, little or no composition is transferred to the substrate from the hair, skin or lips.
  • the composition may also comprise at least one coloring agent chosen from pigments and dyes or a combination of pigments and dyes.
  • pigments refer to colored solid particles at 25° C. that are not soluble in the liquid fatty phase.
  • Pigments may include nacreous pigments ⁇ i.e., nacres), and pearling agents.
  • the at least one coloring agent may be chosen, for example, in order to obtain make-up compositions which give good coverage, in other words, which do not leave a significant amount of the at least one keratin material to which it is applied showing through.
  • the coloring agent may also reduce the sticky feel of the compositions.
  • Representative oil soluble dyes which may be used include, but are not limited to, Sudan red, DC Red 17, DC Green 6, ⁇ -carotene, soybean oil, Sudan brown, DC Yellow 11 , DC Violet 2, DC Orange 5, annatto, and quinoiine yellow and natural oil soluble dyes.
  • the liposoluble dyes when present, may have a concentration ranging up to 20% by weight of the total weight of the composition, such as from 0.01% to 6%.
  • Representative water soluble dyes which may be used include, but are not limited to DC red 33, red 22, red 28, blue 1 , yellow 5, yellow 6, red 40, yellow 10, green 3, green 5, green 8 and natural water soluble dyes.
  • the water soluble dyes, when present, may have a concentration ranging up to 20% by weight of the total weight of the composition, such as from 0.01 % to 6%.
  • the pigments may be chosen from white, colored, mineral, organic, coated and uncoated pigments.
  • mineral pigments include, but are not limited to, titanium dioxide, which may be optionally surface-treated, zirconium oxide, zinc oxide, cerium oxide, iron oxides, chromium oxides, manganese violet, ultramarine blue, chromium hydrate and ferric blue.
  • organic pigments include, but are not limited to, carbon black, pigments of D & C type, and lakes based on cochineal carmine, barium, strontium, calcium and aluminum.
  • the pigments may have a concentration ranging up to 40% by weight of the total weight of the composition, and for example from 1 % to 35%, and further such as from 2% to 25%.
  • the pigments, including nacreous pigments may, for example, represent up to 50% by weight of the composition.
  • the nacreous pigments ⁇ or nacres may be chosen from white nacreous pigments such as mica coated with titanium or with bismuth oxychloride; colored nacreous pigments such as titanium mica with iron oxides, titanium mica with ferric blue or chromium oxide, and titanium mica with an organic pigment chosen from those mentioned above; and nacreous pigments based on bismuth oxychloride.
  • the nacres if present, may have a concentration ranging up to 30% by weight of the total weight of the composition, such as from 0.1 % to 20%.
  • silicone chain and wherein the groups each comprise from 2 to 24 carbon atoms; phenylsi!icones such as phenyl trimethicones, phenyl dimethicones, phenyl trimethylsiloxy diphenylsiloxanes, diphenyl dimethicones, diphenyl methyldiphenyl trisi!oxanes and 2-phenylethyl trimethylsiloxysilicates; hydrocarbons chosen from linear and branched, volatile and nonvolatile hydrocarbons of synthetic and mineral origin, such as volatile liquid paraffins (such as isoparaffins and ssododecane) or non-volatile liquid paraffins and derivatives thereof; and liquid petrolatum, liquid lanolin, polydecenes, hydrogenated polyisobutene such as hydrogenated polybutene, e.g., PARLEAM from Nippon Oil Fats and squalane.
  • phenylsi!icones such as phenyl trim
  • the cosmetic composition is non-tinted, e.g., in a form of a clear lipstick or antiperspirant/deodorant in another embodiment, the cosmetic composition is tinted and comprises a coloring agent chosen from pigments and dyes.
  • pigments refer to colored solid particles at 25° C. that are not soluble in the liquid fatty phase. Pigments may include nacreous pigments (i.e., nacres), and pearling agents.
  • Representative oil soluble dyes which may be used include, but are not limited to, Sudan red, DC Red 17, DC Green 6, ⁇ -carotene, soybean oil, Sudan brown, DC Yellow 11 , DC Violet 2, DC Orange 5, annatto, and quinoline yellow and natural oil soluble dyes.
  • the liposoiuble dyes when present, may have a concentration ranging up to 20% by weight of the total weight of the composition, such as from 0.01 % to 6%.
  • Representative water soluble dyes which may be used include, but are not limited to DC red 33, red 22, red 28, blue 1, yellow 5, yellow 6, red 40, yellow 10, green 3, green 5, green 8 and natural water soluble dyes.
  • the water soluble dyes, when present, may have a concentration ranging up to 20% by weight of the total weight of the composition, such as from 0.01% to 6%.
  • cosmetic composition is understood to mean a composition suitable for application to the human body.
  • a cosmetic composition is typically applied to the body for beautifying, cleansing, moisturizing or otherwise treating the external surface of the body, including by cleansing, coloring, conditioning, or protecting the external surface of the body part such as, for example, the skin, nails, lips, or hair.
  • cosmetic compositions in which the present compounds can be used include a mascara, lipstick, lip-gloss, lip- balm, and antiperspirant/deodorant.
  • a gelling agent is limited to compounds having the following structure (I):
  • R 2, R 3 R 4 , R 5I which are the same or different are selected from a hydrogen, a C-, - C 4 alkyl group;
  • X is selected from a heteroatom, C 2 to C 24 alkyl
  • R T and R 6 which are the same or different are selected from a hydrogen, a d - C 24 alkyl group, a heteroatom.
  • An example of a gelling agent includes but is not limited to 1-[1-Methyl-2-(1- methyl-2-tridecyloxy-ethoxy)-ethyl]-3-(6- ⁇ 3-[1-methyl-2-(1-methyl-2-tridecyioxy-ethoxy)- ethyl]-ureido ⁇ -hexyl)-urea which is known as MT800.
  • alkyl refers to the radical of saturated aliphatic groups, including straight-chain alkyl groups, branched-chain alkyl groups, cycioalkyl (aticyclic) groups, alkyl substituted cycioalkyl groups, and cycioalkyl substituted alkyl groups.
  • a straight chain or branched chain alkyl has 24 or fewer carbon atoms in its backbone.
  • alkyl can be used alone or as part of a chemical name as in for example, "trialkylorthoformate".
  • alkyl portion of the alkyl, alkoxy, alkanoyloxy, alkoxymethyl, alkanoyloxymethyl, alkylsuiphinyl, alkylsulphonyl, alkylsulfonamido, carboalkoxy, carboalkyl, alkanoylamino aminoalkyl, alkylaminoalkyl, N,N- dicycloalkylaminoaikyl, hydroxyalkyl, and aikoxyaikyl substituents include both straight chain as well as branched carbon chains.
  • alkyl as used throughout the specification and claims is intended to include both “unsubstituted alkyls” and “substituted alkyls”, the latter of which refers to alkyl moieties having substituents replacing a hydrogen on one or more carbons of the hydrocarbon backbone.
  • Such substituents can include, for example, a halogen, a hydroxyl, a carbonyl (such as a carboxyl, an ester, a formyl, or a ketone), a thiocarbonyl (such as a thioester, a thioacetate, or a thioformate), an alkoxyl, a phosphoryl, a phosphonate, a phosphinate, an amino, an amido, an amidine, an imine, a cyano, a nitro, an azido, a sulfhydryl, an alkylthio, a sulfate, a sulfonate, a sulfamoyl, a sulfonamido, a sulfonyl, a heterocyciyl, an aralkyl, or an aromatic or heteroarotnatic moiety.
  • a halogen such as a carb
  • the moieties substituted on the hydrocarbon chain can themselves be substituted, if appropriate.
  • the substituents of a substituted alkyl may include substituted and unsubstituted forms of amino, azido, imino, amido, phosphoryl (including phosphonate and phosphinate), sulfonyl (including sulfate, sulfonamido, sulfamoyl and sulfonate), and sily! groups, as well as ethers, alkylthios, carbonyls (including ketones, aldehydes, carboxylates, and esters), -CF, -CN and the like.
  • carbon carbon bonds may be single, double, or triple bonds.
  • heteroatom as used herein means an atom of any element other than carbon or hydrogen and include for example nitrogen, oxygen, sulfur, phosporus, and selenium.
  • oil refers to an ester, a volatile solvent, a non-volatile oil, and a volatile oil.
  • the preferred oi!(s) used are oils that when combined with the gelling agents disclosed herein form a crystal clear firm gel that can be used as a base for a cosmetic composition.
  • an ester refers to the group -OC ⁇ 0)(C1-C6 alkyl).
  • a “volatile” solvent is a compound capable of evaporating from the skin or lips in less than an hour. Volatile solvents include hydrocarbons such as isododecane.
  • the expression “volatile solvent” or “volatile oil” refers to any non-aqueous medium capable of evaporating on contact with the skin or the lips in less than one hour at room temperature and atmospheric pressure.
  • An aspect of the present disclosure includes one or more volatile solvents chosen from organic solvents, such as volatile cosmetic oils that are liquid at room temperature and have a non-zero vapor pressure, at room temperature and atmospheric pressure, ranging from 10 -2 to 300 mm Hg (1.33 to 40,000 Pa), such as greater than 0.03 mmHg (4 Pa), and further such as greater than 0.3 mmHg (40 Pa).
  • volatile solvents chosen from organic solvents, such as volatile cosmetic oils that are liquid at room temperature and have a non-zero vapor pressure, at room temperature and atmospheric pressure, ranging from 10 -2 to 300 mm Hg (1.33 to 40,000 Pa), such as greater than 0.03 mmHg (4 Pa), and further such as greater than 0.3 mmHg (40 Pa).
  • non-volatile oil refers to oil that remains on the skin or the lips at room temperature and atmospheric pressure for at least several hours, such as those having a vapor pressure of less than 10 -2 mmHg (1.33 Pa).
  • the hydrocarbon-based oil refers to an oil comprising carbon and hydrogen atoms, optionally with at least one group chosen from hydroxyl, ester, carboxyl, or ether groups.
  • cetearyl octanoate clear clear firm gel linseed oil clear clear firm gel soybean oil clear clear firm gel slightly
  • stickiness refers to the negative peak force of the compression as measured by a texture analyzer ⁇ . ⁇ 2 ⁇ Texture Analyzer (Texture Technologies Corp., Scarsdale, NY).
  • flexibility refers to the amount of work returned by the sample as compressive strain is removed to the work required for compression, measurement of the elastic recovery of the sample as measured by the texture analyzer.
  • hardness refers to the peak force of the compression as measured by the texture analyzer.
  • the texture analyzer is an instrument that applies controlled forces to a cosmetic composition and records a measureable response (deformation, recovery, and time) to the applied force and translates that response into values for stickiness, flexibility, and hardness of the cosmetic composition. Stickiness, flexibility, and hardness are properties that translate to human sensory perception of cosmetic compositions.
  • Example 2 Lipstick made with oil and MT800 as the gelling agent
  • Wax is a composition of Tribehenin/Carnauba/Synthetic Wax in a ratio of 4/7/5
  • Example 3 Antiperspirant Deodorant made with MT800 as the gelling agent

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Emergency Medicine (AREA)
  • Cosmetics (AREA)

Abstract

La présente invention concerne une composition cosmétique de type gel transparent comprenant un agent gélifiant à base de bis-urée et au moins une huile, l'huile et l'agent gélifiant étant présents dans un rapport d'environ 2 à environ 16, ladite composition étant utile dans la production d'anti-transpirant/déodorant et de produits pour lèvres. La composition est très facile à porter, résistante au transfert et a d'excellentes propriétés de tenue longue durée.
PCT/US2013/026334 2012-02-17 2013-02-15 Agent gélifiant en vue d'une utilisation dans des compositions cosmétiques WO2013123324A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP13749649.3A EP2814448A4 (fr) 2012-02-17 2013-02-15 Agent gélifiant en vue d'une utilisation dans des compositions cosmétiques
CA2868015A CA2868015A1 (fr) 2012-02-17 2013-02-15 Agent gelifiant en vue d'une utilisation dans des compositions cosmetiques
AU2013221395A AU2013221395A1 (en) 2012-02-17 2013-02-15 Gelling agent for use in cosmetic compositions

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201261600087P 2012-02-17 2012-02-17
US61/600,087 2012-02-17

Publications (1)

Publication Number Publication Date
WO2013123324A1 true WO2013123324A1 (fr) 2013-08-22

Family

ID=48984746

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2013/026334 WO2013123324A1 (fr) 2012-02-17 2013-02-15 Agent gélifiant en vue d'une utilisation dans des compositions cosmétiques

Country Status (4)

Country Link
EP (1) EP2814448A4 (fr)
AU (1) AU2013221395A1 (fr)
CA (1) CA2868015A1 (fr)
WO (1) WO2013123324A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10092489B2 (en) 2016-03-14 2018-10-09 The Procter & Gamble Company Hydrophobically modified urea ethers as structurants for hydrophobic systems
US10653610B2 (en) 2017-04-28 2020-05-19 L'oreal Essentially anhydrous hair-treatment compositions comprising a bis-urea derivative and silica aerogel

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5587153A (en) * 1990-10-04 1996-12-24 The Gillette Company Clear, gelled aluminum and zirconium salt containing antiperspirant formulation
US20010002253A1 (en) * 1998-09-16 2001-05-31 L'oreal Nail enamel composition containing a urea-modified thixotropic agent
US20070098658A1 (en) * 2005-10-24 2007-05-03 L'oreal Cosmetic composition textured with a bis-urea derivative with a liquid fatty phase textured with a bis-urea compound
US20110182834A1 (en) * 2009-12-17 2011-07-28 Avon Products, Inc. Clear or Translucent Composition

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8003086B2 (en) * 2006-05-09 2011-08-23 L'oreal S.A. Bis-urea compounds and compositions and method of cosmetic treatment
FR2900819B1 (fr) * 2006-05-09 2010-10-15 Oreal Compose de type bis-uree, composition le comprenant, utilisation et procede de traitement cosmetique
FR2910809B1 (fr) * 2006-12-29 2009-02-13 Oreal Composition cosmetique comprenant un derive de bis uree.
FR2910807A1 (fr) * 2006-12-29 2008-07-04 Oreal Composition cosmetique comprenant un derive de bis uree.
WO2009080956A2 (fr) * 2007-12-05 2009-07-02 L'oreal Procédé cosmétique de maquillage et/ou de soin utilisant une résine de siloxane et une charge

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5587153A (en) * 1990-10-04 1996-12-24 The Gillette Company Clear, gelled aluminum and zirconium salt containing antiperspirant formulation
US20010002253A1 (en) * 1998-09-16 2001-05-31 L'oreal Nail enamel composition containing a urea-modified thixotropic agent
US20070098658A1 (en) * 2005-10-24 2007-05-03 L'oreal Cosmetic composition textured with a bis-urea derivative with a liquid fatty phase textured with a bis-urea compound
US20110182834A1 (en) * 2009-12-17 2011-07-28 Avon Products, Inc. Clear or Translucent Composition

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP2814448A4 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10092489B2 (en) 2016-03-14 2018-10-09 The Procter & Gamble Company Hydrophobically modified urea ethers as structurants for hydrophobic systems
EP3219743B1 (fr) * 2016-03-14 2020-01-08 Procter & Gamble International Operations SA Éthers d'urée modifiés hydrophobiquement comme agents structurants pour systèmes hydrophobes
US10653610B2 (en) 2017-04-28 2020-05-19 L'oreal Essentially anhydrous hair-treatment compositions comprising a bis-urea derivative and silica aerogel

Also Published As

Publication number Publication date
EP2814448A4 (fr) 2015-11-04
AU2013221395A1 (en) 2014-08-21
CA2868015A1 (fr) 2013-08-22
EP2814448A1 (fr) 2014-12-24

Similar Documents

Publication Publication Date Title
EP2356981B1 (fr) Mascara comprenant une dispersion aqueuse de polyuréthane et une cire dure
US10980733B2 (en) Cosmetic compositions containing acrylic thickener
US8920787B2 (en) Mascara containing an aqueous dispersion of polyurethane and an acrylic film former
US8388940B2 (en) Mascara compositions
KR101288737B1 (ko) 유성 화장료
EP2729218B1 (fr) Compositions cosmétiques résistant au transfert, longue tenue, confortables à effet brillant et non collant
EP2104487B1 (fr) Compositions donnant du volume
CA2899608A1 (fr) Rouge a levres brillant de longue duree
KR20000011549A (ko) 필름형성중합체를포함하는화장용조성물
JP2012526100A (ja) ケラチン物質をメイクアップする及び／又はケアするための化粧用セット
US9649270B2 (en) Color cosmetic compositions
CN108348782B (zh) 赋予自然肤色和健康外观效果的美容组合物
WO2017116567A1 (fr) Compositions contenant un copolymère d'acrylate de silicone alkylé
US20170181954A1 (en) Compositions containing at least two alkylated silicone acrylate copolymers
US20170181958A1 (en) Compositions containing an alkylated silicone acrylate copolymer and a silicone plasticizer
EP2814448A1 (fr) Agent gélifiant en vue d'une utilisation dans des compositions cosmétiques
US20230000729A1 (en) Lipsticks having natural oil, fatty alcohol wax and filler particles
US20210338543A1 (en) Water-in-oil emulsions containing latex and siloxysilicate resin
US20160151262A1 (en) Gelling Agents For Use In Cosmetic Compositions
US20160175204A1 (en) Solid cosmetic compositions
EP4363060A1 (fr) Rouges à lèvres ayant une huile naturelle, une cire d'alcool gras et des particules de charge
WO2023099242A1 (fr) Composition aqueuse de soin et/ou de maquillage comprenant un monoester d'acide gras, un tensioactif anionique neutralisé, un copolymère vp/eïcosène et un colorant
KR20230110586A (ko) 적어도 하나의 지방 알코올, 비-이온성 당 에스테르, 에틸셀룰로오스를 포함하는 역상 에멀젼 및 이를 사용하는 방법

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 13749649

Country of ref document: EP

Kind code of ref document: A1

ENP Entry into the national phase

Ref document number: 2868015

Country of ref document: CA

NENP Non-entry into the national phase

Ref country code: DE

WWE Wipo information: entry into national phase

Ref document number: 2013749649

Country of ref document: EP

ENP Entry into the national phase

Ref document number: 2013221395

Country of ref document: AU

Date of ref document: 20130215

Kind code of ref document: A