WO2013082852A1 - 一种天然染发剂组合物及其制备方法 - Google Patents

一种天然染发剂组合物及其制备方法 Download PDF

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WO2013082852A1
WO2013082852A1 PCT/CN2012/000310 CN2012000310W WO2013082852A1 WO 2013082852 A1 WO2013082852 A1 WO 2013082852A1 CN 2012000310 W CN2012000310 W CN 2012000310W WO 2013082852 A1 WO2013082852 A1 WO 2013082852A1
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hair dye
ultrasonic
natural
dye composition
natural hair
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PCT/CN2012/000310
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English (en)
French (fr)
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曾庆桂
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Zeng Qinggui
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9755Gymnosperms [Coniferophyta]
    • A61K8/9767Pinaceae [Pine family], e.g. pine or cedar
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9783Angiosperms [Magnoliophyta]
    • A61K8/9789Magnoliopsida [dicotyledons]
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9783Angiosperms [Magnoliophyta]
    • A61K8/9794Liliopsida [monocotyledons]
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/98Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of animal origin
    • A61K8/987Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of animal origin of species other than mammals or birds
    • A61K8/988Honey; Royal jelly, Propolis
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/06Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A61Q5/065Preparations for temporary colouring the hair, e.g. direct dyes
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K36/00Medicinal preparations of undetermined constitution containing material from algae, lichens, fungi or plants, or derivatives thereof, e.g. traditional herbal medicines

Definitions

  • the present invention relates to a hair dye composition in the field of hair beauty, and more particularly to a nano-natural hair dye composition and a preparation method thereof.
  • the patent application 201010572862.3 discloses a Chinese medicine hair dyeing formula.
  • the formula consists of ginger, Polygonum, white peony, haina powder, barley, dried pine, black coffee, etc., and is pulverized to a powder of 1-5 microns, and is mixed with water before use.
  • the traditional Chinese medicine hair dyeing formula is an all-natural Chinese medicine product, which has good hair dyeing effect, has auxiliary protection hair, and improves scalp capillary microcirculation.
  • the distribution in the above patent application has obvious deficiencies.
  • the hair dyeing formula contains Henna powder, which is an imported plant material. The source has limitations and is irritating to the skin. The use effect has caused a lot of controversy.
  • the hair dye composition of the present invention is a natural material as a raw material, can be quickly attached, and can be attached to the hair within 10 to 20 minutes without heating. And it has strong adhesion and it is not easy to elute from the hair with ordinary detergent.
  • Another object of the present invention is to provide a process for the preparation of the above natural hair dye composition.
  • the natural hair dye composition of the present invention is a hair dye prepared from the following raw materials in a weight ratio: natural melanin 22.0-25.0%
  • the above composition has a particle size of less than 0.1 ⁇ m.
  • the above natural melanin is black sesame or black coffee.
  • the hair dye composition of the present invention contains no imported and controversial Henna powder, and all the raw materials are taken from the domestic market, and have the characteristics of easy material extraction, low cost, and raw materials for both medicine and food.
  • the composition of the composition does not contain
  • composition of the present invention has a natural preservative (honeycomb extract) for long-term preservation.
  • the book also contains nano-scale (100-200 angstroms) carbon molecular sieve adsorbent with strong adsorption.
  • the hair dye composition of the present invention adheres quickly, can adhere to the hair within 10-20 minutes, and does not require heating. It has strong adhesion and is not easy to elute from the hair with ordinary detergent. It lasts for more than 4 weeks on the hair.
  • the composition has a protective effect on the hair, maintaining or increasing and maintaining the brightness. It can promote microcirculation metabolism and improve hair follicle and skin capillary microcirculation.
  • the method of preparing the hair dye composition of the present invention is sequentially composed of the following steps:
  • the ultrasonic-microwave dynamic extraction process is employed in the hair dye preparation method of the present invention.
  • Conventional thermal extraction is carried out from the outside to the inside by means of heat conduction, heat radiation, etc., while ultrasonic-microwave dynamic extraction is simultaneous heating inside and outside, no high-temperature heat source, eliminating the thermal gradient, thereby greatly improving the extraction quality and effectively protecting the functional components.
  • the extraction temperature is low, it is not easy to gelatinize, the ultrasonic-microwave extraction has no thermal inertia, it is easy to control, all parameters can be digitized, and it can fully meet the requirements of modern pharmaceutical production.
  • ultrasonic-microwave dynamic multi-function extraction tanks have the following advantages: low extraction temperature, high speed, high extraction efficiency, good extract quality, no gelatinization, low solvent consumption, low operating cost and strong controllability. , no pollution, save plant area and other advantages.
  • the hair dye composition of the present invention directly acts on the material by using ultrasonic waves, and maximizes the extraction rate of the active ingredient without any chemical solvent, thereby reducing oxidative damage and loss.
  • the microwave dynamic high-pressure colloid mill technology is used to fully combine the natural ingredients to form a new high-efficiency hair care hair dye. Concentrate under vacuum or freeze at the critical point to further maximize the heat-sensitive (active) active ingredient in the material and to achieve high standards of hygiene.
  • the method of preparing the hair dye composition is in turn consisting of the following steps:
  • Carbon molecular sieve 1.1 Carbon molecular sieve 1.1.
  • the method for preparing the hair dye composition refers to the above steps, followed by the following steps:
  • a vertical colloid mill is used in the colloid mill process. Process conditions: Speed > 8000 rev / min; grinding hardness HV > 1400 ; line speed > 20 m / s; coaxiality error ⁇ 0.05 mm; temperature control 90-125 ° C.
  • the ultrasonic-microwave dynamic extraction process is extracted by an ultrasonic-microwave cooperative countercurrent extraction unit.
  • the ultrasonic parameters are: frequency 28khz, power 1200w X 2; microwave parameters are: frequency is 2450mhz, power is 850wX 4; maximum productivity of the unit is up to
  • the ultrasonic-microwave dynamic extraction process parameters are: liquid-solid ratio 3: 1, extraction temperature 60 ° C, extraction time 60 min, ultrasonic treatment (60 min) in the extraction process, microwave treatment 20 min in the initial extraction.
  • Special water (polar) is the medium. Contains no chemical solvents.
  • Vacuum ultrasonic filtration process conditions fineness ⁇ 0.1 um (95%);
  • the product is a dark black paste, which can be used by diluting it with an appropriate amount of warm water.
  • Carbon molecular sieve 0.6 Carbon molecular sieve 0.6.
  • a vertical colloid mill is used in the colloid mill process. Process conditions: speed > 8000 rev / min; grinding hardness HV > 1400 ; line speed > 20m / s; coaxiality error ⁇ 0.05mm; temperature control 90 ⁇ ;
  • Ultrasonic-microwave dynamic extraction process was extracted by ultrasonic-microwave cooperative countercurrent extraction unit.
  • the ultrasonic parameters are: frequency 28khz, power 1200w X 2; microwave parameters are: frequency is 2450mhz, power is 850w X 4; unit maximum productivity reaches 10kg/h »
  • the ultrasonic-microwave dynamic extraction process parameters are: liquid-solid ratio 3:1, extraction temperature 100 ° C, extraction time 60 miii, ultrasonic treatment (60 min) in the extraction process, microwave treatment 20 min in the initial extraction stage.
  • Special water (polar) is the medium. Contains no chemical solvents.
  • Vacuum ultrasonic filtration process conditions fineness ⁇ 0.1 um (95%);
  • the product is a dark brown paste and can be used by diluting it with warm water.
  • the hair dye composition was prepared in accordance with the method and procedure of Example 1.
  • the obtained product is a light brown paste and can be used by diluting it with warm water.

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Abstract

一种天然染发剂,由如下原料按重量百分比制成:天然黑色素22-25%,何首乌14-16.5%,干姜14-16.5%,白笈14-16.5%,青黛7-11%,甘松7-11%,蜂巢提取物1.5-5.5%,碳素分子筛0.6-1.1%。天然染发剂的制备方法包括以下步骤:(a)将干燥的原料按比例混合后用胶体磨研磨;(b)超声-微波动态提取;(c)用胶体磨再次研磨;(b)真空条件减压浓缩或临界点冷冻干燥;(e)真空超声波过滤得到产品。

Description

说 明 书 一种天然染发剂组合物及其制备方法 技术领域
[0001] 本发明涉及一种乌发美容领域的染发剂组合物, 尤其涉及一种纳米级纯天然的染发 剂组合物及其制备方法。
背景技术
[0002] 当今染发已经成为一种时尚, 然而目前市面上大多数染发剂中的化学成分中都含有 致癌物质, 长期使用会增加患癌症的几率。 经常染发的人也常常会遇到过敏、 伤发、 褪色等 问题。 因为化学染发剂中的主要成分 "对苯二胺", 不仅容易引起过密, 还会导致头晕、 头 痛、 眼疾、 贫血等症状, 严重时还会引发细胞突变等疾病。 然而天然的中药染发剂克服了上 述的缺点, 并且具有深层次滋养发根的作用。
[0003] 为了解决上述问题, 专利申请 201010572862.3 公开一种中药染发配方。 该配方由干 姜、 何首乌、 白笈、 海娜粉、 青黛、 干松、 黑咖啡等量组成, 粉碎至 1-5微米的粉状物, 使 用前铁锅加水熬成。 该中药染发配方是一种全天然中药产品, 有良好的染发效果, 有辅助保 护头发, 改善头皮毛细血管微循环作用。 但上述专利申请中的配发有明显的不足之处。 (1 ) 配方中没有天然防腐成分, 不利于保存, 容易受到微生物污染, 所以不利于预先制成可以长 久储存的产品; (2 ) 该产品颗粒太大 U -5 微米), 不利于附着, 在毛发表面保留时间不够 长; (3 ) 虽然染发配方对毛发有一定的保护作用, 但因为颗粒大、 各天然成分之间没有很好 的相互促进作用, 其护发效果不够理想。 此外, 该染发配方中含海娜粉, 这是一种进口植物 原料, 来源具有局限性, 且对皮肤有刺激性, 其使用效果已经引发很多争议。
发明内容
【0004】 本发明的目的是提供一种天然染发剂组合物, 以解决现有技术中存在的上述问题。 本发明的这种染发剂组合物以纯天然物质为原料, 能够快速附着, 能够在 10-20分钟内附着 在毛发上, 不用加热。 并且附着力强, 用普通洗涤剂不容易从毛发上洗脱掉。
[0005] 本发明的另一个目的是提供一种上述天然染发剂组合物的制备方法。
[0006] 本发明的天然染发剂组合物, 是由下述按重量百分比配比的原料制成的染发剂: 天然黑色素 22.0-25.0%
何首乌 14.0-16.5%
千姜 14.0-16.5%
白笈 14.0-16.5% 青黛 7.0-11.0%
甘松 7.0-11.0%
蜂巢提取物 1.5-5.5%
碳素分子筛 0.6-1.1%。
[00071 上述组合物的颗粒尺寸小于 0.1微米。 其中上述天然黑色素是黑芝麻或黑咖啡。
[0008] 本发明的染发剂组合物原料中不含进口且效果有争议的海娜粉, 所有原材料取自于 国内, 具有取材容易、 成本低、 原材料均为药食两用植物的特性。 本组合物配方中不含有有 说
重金属、 化学溶剂 (对苯二胺、 间苯二酚、 丙二醇等)、 显色剂 (双氧水等)、 芳香胺及任何 人工化学合成物, 所以不会对皮肤产生不良刺激反应。 本发明的组合物配方中有天然防腐剂 (蜂巢提取物), 起到长久保存的作用。 此外配书方中还含有吸附力极强的纳米级 (100-200 埃) 碳素分子筛吸附剂。
[0009] 本发明的染发剂组合物附着快速, 能够在 10-20分钟内, 附着在毛发上, 且不需要加 热。 附着力强, 不容易用普通洗涤剂从毛发上洗脱掉,. 维持在毛发上的时间超过 4 周。 此 外, 该组合物对毛发有保护作用, 有保持或增加及维护光亮度作用。 能够促进微循环代谢, 有改善毛囊及皮肤毛细血管微循环作用。
[0010] 制备本发明的染发剂组合物的方法依次由以下步骤组成:
( a) 将干燥的天然黑色素、 何首乌、 干姜、 白笈、 青黛 、 甘松、 蜂巢提取物和碳素分子筛 按上述比例混合后用胶体磨研磨, 控制温度为 90-125 Ό ;
( b ) 超声波动态提取;
( c) 用胶体磨再次研磨, 控制温度为 90-125°C ;
( d) 真空条件减压浓缩或临界点冷冻干燥;
( e) 真空超声波过滤, 过滤得到细度小于 0.1微米的产品。
[0011] 本发明的染发剂制备方法中采用超声-微波动态提取工艺。 传统热萃取是以热传导、 热辐射等方式由外向里进行, 而超声 -微波动态萃取是里外同时加热, 没有高温热源, 消除 了热梯度, 从而使萃取质量大大提高, 有效地保护功能成份。 萃取温度低, 不易糊化, 超 声-微波萃取没有热惯性, 易控制, 所有参数均可数据化, 完全能和制药现代化生产要求接 轨。 超声 -微波动态多功能提取罐和常规提取罐相比有: 提取温度低、 速度快、 提净效率 高、 提取物质量好、 不易糊化、 溶媒用量少、 运行成本低、 可控性强、 无污染、 节省厂房面 积等优点。
[0012] 上述超声-微波动态提取工艺是在以水为介质、 温度 60-100Ό的条件下, 先同时施加 说 明 书
超声波和微波提取 20分钟, 再单独施加超声波提取 40分钟; 所施加的超声波的频率为 30- 80KHz„
[0013] 本发明的染发剂组合物采用超声波直接作用于物料, 在没有任何化学溶剂下, 实现 有效成分提取率最大化, 减少了氧化破坏与流失。 采用微波动态高压胶体磨技术, 充分把各 天然成分有机结合在一起, 形成全新的高效护发染发剂。 在真空条件下浓缩、 或在临界点冷 冻千燥, 进一步使物料中的热敏性 (活性) 有效成分最大程度保留, 同时更容易达到高标准 卫生要求。
具体实施方式
[0014] 制备 100千克染发剂, 按下述比例称取并混合原料 (千克):
天然黑色素 22.0-25.0
何首乌 14.0-16.5
干姜 14.0-16.5
白笈 14.0-16.5
青黛 7.0-11.0
甘松 7.0-11.0
蜂巢提取物 1.5-5.5
碳素分子筛 0.6-1.1
制备该染发剂组合物的方法依次由以下步骤组成:
( a) 将干燥的天然黑色素、 何首乌、 干姜、 白笈、 青黛 、 甘松、 蜂巢提取物和碳素分子筛 按上述比例混合后用胶体磨研磨, 控制温度为 90-125Ό ;
(b ) 超声-微波动态提取;
( c) 用胶体磨再次研磨, 控制温度为 90-125°C ;
(d) 真空条件减压浓缩或临界点冷冻干燥;
( e) 真空超声波过滤, 过滤得到细度小于 0.1微米的产品。
[0015] 实施例 1 :
按下述比例称取并混合原料 (千克):
野生黑芝麻 (烤焦) 25.0
何首乌 16.5
干姜 16.5
白笈 16.5 青黛 11.0
甘松 11.0
蜂巢提取物 5.5
碳素分子筛 1.1。
[0016] 制备该染发剂组合物的方法参考上述步骤, 依次按照如下步骤:
物料清洗 -- 烘干 粗粉碎 -- 称料 -- 第 1 次胶体磨细磨 ― 超声-微波动态提取 -- 第 2 次胶体磨细磨 -- 真空减压浓缩 -- 真空超声波过滤 -- 检验 -- 包装。
[0017] 在胶体磨工艺中采用立式胶体磨。 工艺条件: 转速 >8000 转 /分; 磨齿硬度 HV>1400; 线速 >20m/s; 同轴度误差 <0.05mm; 温度控制 90-125°C。
[0018] 超声 -微波动态提取工艺采用超声-微波协同逆流提取机组提取。 超声波参数为: 频率 28khz, 功率 1200w X 2; 微波参数为: 频率为 2450mhz, 功率为 850wX 4;机组最大生产率达
[0019] 超声-微波动态提取工艺参数为: 液固比 3 : 1、 提取温度 60°C、 提取时间 60min、 提 取过程中一直使用超声波处理 (60min)、 在提取初期使用微波处理 20 min。 特殊水 (极性) 为介质。 不含化学溶剂。
[0020] 真空超声波过滤工艺条件: 细度 < 0.1 um (95%);
产品为深黑色膏状体, 用适量温开水稀释即可使用。
[0021] 实施例 2:
按下述比例称取并混合原料 (千克):
黑咖啡 (炒半焦) 22.0
何首乌 14.0
干姜 14.0
白笈 14.0
青黛 7.0
甘松 7.0
蜂巢提取物 1.;
碳素分子筛 0.6。
[0022] 制备该染发剂组合物的方法依次按照以下步骤:
物料清洗 -- 烘干 -- 粗粉碎 -- 称料 --第 1 次胶体磨细磨 -- 超声-微波动态提取 -- 第 2 次胶体磨细磨 -- 临界点冷冻干燥 -- 真空超声波过滤 -- 检验 -- 包装。 说 明 书
[0023] 在胶体磨工艺中采用立式胶体磨。 工艺条件: 转速 >8000 转 /分; 磨齿硬度 HV>1400; 线速 >20m/s; 同轴度误差 <0.05mm; 温度控制 90Ό ;
超声 -微波动态提取工艺采用超声-微波协同逆流提取机组提取。 超声波参数为: 频率 28khz, 功率 1200w X 2; 微波参数为: 频率为 2450mhz, 功率为 850w X 4;机组最大生产率达 10kg/h»
[0024] 超声-微波动态提取工艺参数为: 液固比 3 : 1、 提取温度 100°C、 提取时间 60miii、 提取过程中一直使用超声波处理 (60min)、 在提取初期使用微波处理 20 min。 特殊水 (极 性) 为介质。 不含化学溶剂。
[0025] 真空超声波过滤工艺条件: 细度 < 0.1 um (95%);
产品为深褐色膏状体, 用温开水稀释即可使用。
[0026] 实施例 3:
'按下述比例称取并混合原料 (千克):
黑咖啡 (烘烤至深褐) 24.0
何首乌 15.0
干姜 15.0
白笈 15.0
青黛 10.0
甘松 10.0
蜂巢提取物 5.0
碳素分子筛 1.0
按照实施例 1 中的方法和步骤制备该染发剂组合物。 得到的产品为浅褐色膏状体, 用温开水 稀释即可使用。
[0027] 可以理解, 很多细节的变化是可能的, 但这并不因此违背本发明的范围和精神, 任 何所属技术领域的普通技术人员对其所做的适当变化, 皆应视为不脱离本发明专利的范畴。

Claims

1. 一种天然染发剂组合物, 其特征在于它是由下述按重量百分比配比的原料制成的染发 剂:
天然黑色素 22.0-25.0%
何首乌 14.0-16.5%
干姜 14.0-16.5%
白笈 14.0-16.5%
青黛 7.0-11.0%
甘松 7.0-11.0%
蜂巢提取物 1.5-5.5%
碳素分子筛 0.6-1.1%。
2. 根据权利要求 1所述的天然染发剂组合物, 其中该组合物的颗粒尺寸小于 0.1微米。
3. 根据权利要求 1所述的天然染发剂组合物, 其中天然黑色素是黑芝麻或黑咖啡。
4. 权利要求 1所述的天然染发剂组合物的制备方法, 其特征在于该方法包括以下步骤:
(a) 将干燥的天然黑色素、 何首乌、 干姜、 白笈、 青黛 、 甘松、 蜂巢提取物和碳素分子筛 按比例混合后用胶体磨研磨, 控制温度为 90-125Ό ;
(b) 超声-微波动态提取;
(c) 用胶体磨再次研磨, 控制温度为 90- 125'C ;
(d) 真空条件减压浓缩或临界点冷冻干燥;
(e) 真空超声波过滤, 过滤得到细度小于 0.1微米的产品。
5. 根据权利要求 4所述的天然染发剂组合物的制备方法, 其特征在于:
所述超声 -微波动态提取是在以水为介质、 温度 60-100°C的条件下, 先同时施加超声波和微 波提取 20分钟, 再单独施加超声波提取 40分钟。
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