WO2013074984A1 - Neutral, stable and transparent photocatalytic titanium dioxide sols - Google Patents
Neutral, stable and transparent photocatalytic titanium dioxide sols Download PDFInfo
- Publication number
- WO2013074984A1 WO2013074984A1 PCT/US2012/065616 US2012065616W WO2013074984A1 WO 2013074984 A1 WO2013074984 A1 WO 2013074984A1 US 2012065616 W US2012065616 W US 2012065616W WO 2013074984 A1 WO2013074984 A1 WO 2013074984A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- titanium dioxide
- dioxide sol
- stable
- neutral
- acid
- Prior art date
Links
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 title claims abstract description 568
- 239000004408 titanium dioxide Substances 0.000 title claims abstract description 232
- 230000001699 photocatalysis Effects 0.000 title claims abstract description 103
- 230000007935 neutral effect Effects 0.000 title claims abstract description 77
- 238000000034 method Methods 0.000 claims abstract description 90
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 45
- 239000002245 particle Substances 0.000 claims abstract description 38
- 230000003472 neutralizing effect Effects 0.000 claims abstract description 9
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 90
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 80
- 230000000844 anti-bacterial effect Effects 0.000 claims description 80
- 150000001875 compounds Chemical class 0.000 claims description 77
- 239000010936 titanium Substances 0.000 claims description 67
- 229910052719 titanium Inorganic materials 0.000 claims description 64
- 239000002253 acid Substances 0.000 claims description 58
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 56
- 238000012360 testing method Methods 0.000 claims description 53
- 239000000203 mixture Substances 0.000 claims description 44
- 238000000576 coating method Methods 0.000 claims description 42
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 37
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 claims description 34
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 34
- 239000000758 substrate Substances 0.000 claims description 26
- 239000011248 coating agent Substances 0.000 claims description 23
- 230000001580 bacterial effect Effects 0.000 claims description 22
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 20
- 241000894006 Bacteria Species 0.000 claims description 18
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 18
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 18
- 229910052751 metal Inorganic materials 0.000 claims description 18
- 239000002184 metal Substances 0.000 claims description 18
- -1 titanium alkoxide Chemical class 0.000 claims description 18
- 239000006185 dispersion Substances 0.000 claims description 16
- 239000002738 chelating agent Substances 0.000 claims description 14
- 150000007524 organic acids Chemical class 0.000 claims description 14
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 13
- 239000011707 mineral Substances 0.000 claims description 13
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 12
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical group [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 claims description 12
- 239000000908 ammonium hydroxide Substances 0.000 claims description 9
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 8
- 229910017604 nitric acid Inorganic materials 0.000 claims description 8
- 125000001453 quaternary ammonium group Chemical group 0.000 claims description 8
- JGFZNNIVVJXRND-UHFFFAOYSA-N N,N-Diisopropylethylamine (DIPEA) Chemical compound CCN(C(C)C)C(C)C JGFZNNIVVJXRND-UHFFFAOYSA-N 0.000 claims description 7
- 238000009835 boiling Methods 0.000 claims description 6
- 235000015165 citric acid Nutrition 0.000 claims description 6
- 235000006408 oxalic acid Nutrition 0.000 claims description 6
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims description 6
- 125000005270 trialkylamine group Chemical group 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 5
- DCKVFVYPWDKYDN-UHFFFAOYSA-L oxygen(2-);titanium(4+);sulfate Chemical compound [O-2].[Ti+4].[O-]S([O-])(=O)=O DCKVFVYPWDKYDN-UHFFFAOYSA-L 0.000 claims description 5
- 230000001376 precipitating effect Effects 0.000 claims description 5
- 229910000348 titanium sulfate Inorganic materials 0.000 claims description 5
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims description 4
- KDSNLYIMUZNERS-UHFFFAOYSA-N 2-methylpropanamine Chemical compound CC(C)CN KDSNLYIMUZNERS-UHFFFAOYSA-N 0.000 claims description 4
- XFVGXQSSXWIWIO-UHFFFAOYSA-N chloro hypochlorite;titanium Chemical compound [Ti].ClOCl XFVGXQSSXWIWIO-UHFFFAOYSA-N 0.000 claims description 4
- 239000003456 ion exchange resin Substances 0.000 claims description 4
- 229920003303 ion-exchange polymer Polymers 0.000 claims description 4
- BMFVGAAISNGQNM-UHFFFAOYSA-N isopentylamine Chemical compound CC(C)CCN BMFVGAAISNGQNM-UHFFFAOYSA-N 0.000 claims description 4
- 229910052709 silver Inorganic materials 0.000 claims description 4
- 238000005406 washing Methods 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 3
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 3
- 229910001424 calcium ion Inorganic materials 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims description 3
- 229960004889 salicylic acid Drugs 0.000 claims description 3
- 229910001415 sodium ion Inorganic materials 0.000 claims description 3
- 239000011975 tartaric acid Substances 0.000 claims description 3
- 235000002906 tartaric acid Nutrition 0.000 claims description 3
- 229910052718 tin Inorganic materials 0.000 claims description 3
- ADVORQMAWLEPOI-XHTSQIMGSA-N (e)-4-hydroxypent-3-en-2-one;oxotitanium Chemical compound [Ti]=O.C\C(O)=C/C(C)=O.C\C(O)=C/C(C)=O ADVORQMAWLEPOI-XHTSQIMGSA-N 0.000 claims description 2
- 125000001664 diethylamino group Chemical group [H]C([H])([H])C([H])([H])N(*)C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 239000000706 filtrate Substances 0.000 claims description 2
- JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 claims description 2
- YBRBMKDOPFTVDT-UHFFFAOYSA-N tert-butylamine Chemical compound CC(C)(C)N YBRBMKDOPFTVDT-UHFFFAOYSA-N 0.000 claims description 2
- 150000005622 tetraalkylammonium hydroxides Chemical class 0.000 claims description 2
- 150000003973 alkyl amines Chemical class 0.000 claims 3
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 claims 2
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 81
- 229910002089 NOx Inorganic materials 0.000 description 32
- 235000011007 phosphoric acid Nutrition 0.000 description 32
- 239000000243 solution Substances 0.000 description 30
- 235000011054 acetic acid Nutrition 0.000 description 26
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 25
- 239000002585 base Substances 0.000 description 21
- 230000000694 effects Effects 0.000 description 21
- 239000011521 glass Substances 0.000 description 21
- 230000009467 reduction Effects 0.000 description 18
- 238000006722 reduction reaction Methods 0.000 description 18
- 239000000523 sample Substances 0.000 description 18
- 238000001556 precipitation Methods 0.000 description 15
- 239000000725 suspension Substances 0.000 description 12
- 150000003608 titanium Chemical class 0.000 description 12
- 230000005855 radiation Effects 0.000 description 11
- 238000006386 neutralization reaction Methods 0.000 description 10
- 241000191967 Staphylococcus aureus Species 0.000 description 9
- 238000007792 addition Methods 0.000 description 9
- 238000006460 hydrolysis reaction Methods 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 239000002244 precipitate Substances 0.000 description 9
- 239000002904 solvent Substances 0.000 description 9
- 230000007062 hydrolysis Effects 0.000 description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 7
- 239000003344 environmental pollutant Substances 0.000 description 7
- 239000003960 organic solvent Substances 0.000 description 7
- 239000003973 paint Substances 0.000 description 7
- 231100000719 pollutant Toxicity 0.000 description 7
- 239000011734 sodium Substances 0.000 description 7
- 206010001497 Agitation Diseases 0.000 description 6
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 description 6
- 238000013019 agitation Methods 0.000 description 6
- 150000001298 alcohols Chemical class 0.000 description 6
- 238000003556 assay Methods 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- 238000001935 peptisation Methods 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 229910052708 sodium Inorganic materials 0.000 description 6
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 239000011575 calcium Substances 0.000 description 5
- 238000004140 cleaning Methods 0.000 description 5
- 150000002500 ions Chemical class 0.000 description 5
- 230000000813 microbial effect Effects 0.000 description 5
- 235000010755 mineral Nutrition 0.000 description 5
- 150000003016 phosphoric acids Chemical class 0.000 description 5
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 description 5
- 239000002023 wood Substances 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 4
- 150000001243 acetic acids Chemical class 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 229910052791 calcium Inorganic materials 0.000 description 4
- 239000013068 control sample Substances 0.000 description 4
- 239000008367 deionised water Substances 0.000 description 4
- 238000011534 incubation Methods 0.000 description 4
- 238000011081 inoculation Methods 0.000 description 4
- 239000002054 inoculum Substances 0.000 description 4
- 150000007530 organic bases Chemical class 0.000 description 4
- 239000011941 photocatalyst Substances 0.000 description 4
- 241000894007 species Species 0.000 description 4
- 238000007669 thermal treatment Methods 0.000 description 4
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 230000010757 Reduction Activity Effects 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 239000003125 aqueous solvent Substances 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 3
- 150000005690 diesters Chemical class 0.000 description 3
- 125000000524 functional group Chemical group 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000010979 pH adjustment Methods 0.000 description 3
- 239000002243 precursor Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 3
- 239000012266 salt solution Substances 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- BBMCTIGTTCKYKF-UHFFFAOYSA-N 1-heptanol Chemical compound CCCCCCCO BBMCTIGTTCKYKF-UHFFFAOYSA-N 0.000 description 2
- MGWGWNFMUOTEHG-UHFFFAOYSA-N 4-(3,5-dimethylphenyl)-1,3-thiazol-2-amine Chemical compound CC1=CC(C)=CC(C=2N=C(N)SC=2)=C1 MGWGWNFMUOTEHG-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- 241000195493 Cryptophyta Species 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- RJQXTJLFIWVMTO-TYNCELHUSA-N Methicillin Chemical compound COC1=CC=CC(OC)=C1C(=O)N[C@@H]1C(=O)N2[C@@H](C(O)=O)C(C)(C)S[C@@H]21 RJQXTJLFIWVMTO-TYNCELHUSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000003957 anion exchange resin Substances 0.000 description 2
- 230000000845 anti-microbial effect Effects 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000013522 chelant Substances 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 125000006165 cyclic alkyl group Chemical group 0.000 description 2
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 description 2
- 125000004989 dicarbonyl group Chemical group 0.000 description 2
- 125000005594 diketone group Chemical group 0.000 description 2
- WEHWNAOGRSTTBQ-UHFFFAOYSA-N dipropylamine Chemical compound CCCNCCC WEHWNAOGRSTTBQ-UHFFFAOYSA-N 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- LIWAQLJGPBVORC-UHFFFAOYSA-N ethylmethylamine Chemical compound CCNC LIWAQLJGPBVORC-UHFFFAOYSA-N 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000005357 flat glass Substances 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 229960003085 meticillin Drugs 0.000 description 2
- 239000002105 nanoparticle Substances 0.000 description 2
- 239000000123 paper Substances 0.000 description 2
- 230000036961 partial effect Effects 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 230000004083 survival effect Effects 0.000 description 2
- 150000003609 titanium compounds Chemical class 0.000 description 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 2
- 239000012855 volatile organic compound Substances 0.000 description 2
- RYSXWUYLAWPLES-MTOQALJVSA-N (Z)-4-hydroxypent-3-en-2-one titanium Chemical compound [Ti].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O RYSXWUYLAWPLES-MTOQALJVSA-N 0.000 description 1
- ITWBWJFEJCHKSN-UHFFFAOYSA-N 1,4,7-triazonane Chemical compound C1CNCCNCCN1 ITWBWJFEJCHKSN-UHFFFAOYSA-N 0.000 description 1
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 1
- YRAJNWYBUCUFBD-UHFFFAOYSA-N 2,2,6,6-tetramethylheptane-3,5-dione Chemical compound CC(C)(C)C(=O)CC(=O)C(C)(C)C YRAJNWYBUCUFBD-UHFFFAOYSA-N 0.000 description 1
- LTMRRSWNXVJMBA-UHFFFAOYSA-N 2,2-diethylpropanedioic acid Chemical class CCC(CC)(C(O)=O)C(O)=O LTMRRSWNXVJMBA-UHFFFAOYSA-N 0.000 description 1
- VJROPLWGFCORRM-UHFFFAOYSA-N 2-methylbutan-1-amine Chemical compound CCC(C)CN VJROPLWGFCORRM-UHFFFAOYSA-N 0.000 description 1
- GELMWIVBBPAMIO-UHFFFAOYSA-N 2-methylbutan-2-amine Chemical compound CCC(C)(C)N GELMWIVBBPAMIO-UHFFFAOYSA-N 0.000 description 1
- GRWPYGBKJYICOO-UHFFFAOYSA-N 2-methylpropan-2-olate;titanium(4+) Chemical compound [Ti+4].CC(C)(C)[O-].CC(C)(C)[O-].CC(C)(C)[O-].CC(C)(C)[O-] GRWPYGBKJYICOO-UHFFFAOYSA-N 0.000 description 1
- ZNNXJRURXWWGLN-UHFFFAOYSA-N 3-oxopentanal Chemical compound CCC(=O)CC=O ZNNXJRURXWWGLN-UHFFFAOYSA-N 0.000 description 1
- HVCNXQOWACZAFN-UHFFFAOYSA-N 4-ethylmorpholine Chemical compound CCN1CCOCC1 HVCNXQOWACZAFN-UHFFFAOYSA-N 0.000 description 1
- KKOFYQBBUSZDKJ-UHFFFAOYSA-N 4-oxohexanal Chemical compound CCC(=O)CCC=O KKOFYQBBUSZDKJ-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 208000034309 Bacterial disease carrier Diseases 0.000 description 1
- ROFVEXUMMXZLPA-UHFFFAOYSA-N Bipyridyl Chemical compound N1=CC=CC=C1C1=CC=CC=N1 ROFVEXUMMXZLPA-UHFFFAOYSA-N 0.000 description 1
- REIYHFWZISXFKU-UHFFFAOYSA-N Butyl acetoacetate Chemical compound CCCCOC(=O)CC(C)=O REIYHFWZISXFKU-UHFFFAOYSA-N 0.000 description 1
- FIPWRIJSWJWJAI-UHFFFAOYSA-N Butyl carbitol 6-propylpiperonyl ether Chemical compound C1=C(CCC)C(COCCOCCOCCCC)=CC2=C1OCO2 FIPWRIJSWJWJAI-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- HTJDQJBWANPRPF-UHFFFAOYSA-N Cyclopropylamine Chemical compound NC1CC1 HTJDQJBWANPRPF-UHFFFAOYSA-N 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 241000124008 Mammalia Species 0.000 description 1
- WRQNANDWMGAFTP-UHFFFAOYSA-N Methylacetoacetic acid Chemical compound COC(=O)CC(C)=O WRQNANDWMGAFTP-UHFFFAOYSA-N 0.000 description 1
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- DGEZNRSVGBDHLK-UHFFFAOYSA-N [1,10]phenanthroline Chemical compound C1=CN=C2C3=NC=CC=C3C=CC2=C1 DGEZNRSVGBDHLK-UHFFFAOYSA-N 0.000 description 1
- 229910052768 actinide Inorganic materials 0.000 description 1
- 150000001255 actinides Chemical class 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000000843 anti-fungal effect Effects 0.000 description 1
- 239000012296 anti-solvent Substances 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 239000003637 basic solution Substances 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 230000009920 chelation Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- VDQQXEISLMTGAB-UHFFFAOYSA-N chloramine T Chemical compound [Na+].CC1=CC=C(S(=O)(=O)[N-]Cl)C=C1 VDQQXEISLMTGAB-UHFFFAOYSA-N 0.000 description 1
- IFMWVBVPVXRZHE-UHFFFAOYSA-M chlorotitanium(3+);propan-2-olate Chemical compound [Cl-].[Ti+4].CC(C)[O-].CC(C)[O-].CC(C)[O-] IFMWVBVPVXRZHE-UHFFFAOYSA-M 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- KZZKOVLJUKWSKX-UHFFFAOYSA-N cyclobutanamine Chemical compound NC1CCC1 KZZKOVLJUKWSKX-UHFFFAOYSA-N 0.000 description 1
- VXVVUHQULXCUPF-UHFFFAOYSA-N cycloheptanamine Chemical compound NC1CCCCCC1 VXVVUHQULXCUPF-UHFFFAOYSA-N 0.000 description 1
- HSOHBWMXECKEKV-UHFFFAOYSA-N cyclooctanamine Chemical compound NC1CCCCCCC1 HSOHBWMXECKEKV-UHFFFAOYSA-N 0.000 description 1
- NISGSNTVMOOSJQ-UHFFFAOYSA-N cyclopentanamine Chemical compound NC1CCCC1 NISGSNTVMOOSJQ-UHFFFAOYSA-N 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- VJDVOZLYDLHLSM-UHFFFAOYSA-N diethylazanide;titanium(4+) Chemical compound [Ti+4].CC[N-]CC.CC[N-]CC.CC[N-]CC.CC[N-]CC VJDVOZLYDLHLSM-UHFFFAOYSA-N 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000002296 dynamic light scattering Methods 0.000 description 1
- HHFAWKCIHAUFRX-UHFFFAOYSA-N ethoxide Chemical compound CC[O-] HHFAWKCIHAUFRX-UHFFFAOYSA-N 0.000 description 1
- XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 description 1
- OUDSFQBUEBFSPS-UHFFFAOYSA-N ethylenediaminetriacetic acid Chemical compound OC(=O)CNCCN(CC(O)=O)CC(O)=O OUDSFQBUEBFSPS-UHFFFAOYSA-N 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 125000001072 heteroaryl group Chemical group 0.000 description 1
- NDOGLIPWGGRQCO-UHFFFAOYSA-N hexane-2,4-dione Chemical compound CCC(=O)CC(C)=O NDOGLIPWGGRQCO-UHFFFAOYSA-N 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000001027 hydrothermal synthesis Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 150000007529 inorganic bases Chemical class 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 230000002147 killing effect Effects 0.000 description 1
- 229910052747 lanthanoid Inorganic materials 0.000 description 1
- 150000002602 lanthanoids Chemical class 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 229910052808 lithium carbonate Inorganic materials 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 150000002690 malonic acid derivatives Chemical class 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- ITNVWQNWHXEMNS-UHFFFAOYSA-N methanolate;titanium(4+) Chemical compound [Ti+4].[O-]C.[O-]C.[O-]C.[O-]C ITNVWQNWHXEMNS-UHFFFAOYSA-N 0.000 description 1
- NBTOZLQBSIZIKS-UHFFFAOYSA-N methoxide Chemical compound [O-]C NBTOZLQBSIZIKS-UHFFFAOYSA-N 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- QHCCDDQKNUYGNC-UHFFFAOYSA-N n-ethylbutan-1-amine Chemical compound CCCCNCC QHCCDDQKNUYGNC-UHFFFAOYSA-N 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 238000003921 particle size analysis Methods 0.000 description 1
- IGEIPFLJVCPEKU-UHFFFAOYSA-N pentan-2-amine Chemical compound CCCC(C)N IGEIPFLJVCPEKU-UHFFFAOYSA-N 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 238000007540 photo-reduction reaction Methods 0.000 description 1
- 229960005235 piperonyl butoxide Drugs 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000011736 potassium bicarbonate Substances 0.000 description 1
- 235000015497 potassium bicarbonate Nutrition 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 235000011181 potassium carbonates Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- GVIIRWAJDFKJMJ-UHFFFAOYSA-N propan-2-yl 3-oxobutanoate Chemical compound CC(C)OC(=O)CC(C)=O GVIIRWAJDFKJMJ-UHFFFAOYSA-N 0.000 description 1
- 230000004224 protection Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- BHRZNVHARXXAHW-UHFFFAOYSA-N sec-butylamine Chemical compound CCC(C)N BHRZNVHARXXAHW-UHFFFAOYSA-N 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- MNWRORMXBIWXCI-UHFFFAOYSA-N tetrakis(dimethylamido)titanium Chemical compound CN(C)[Ti](N(C)C)(N(C)C)N(C)C MNWRORMXBIWXCI-UHFFFAOYSA-N 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- JMXKSZRRTHPKDL-UHFFFAOYSA-N titanium ethoxide Chemical compound [Ti+4].CC[O-].CC[O-].CC[O-].CC[O-] JMXKSZRRTHPKDL-UHFFFAOYSA-N 0.000 description 1
- HDUMBHAAKGUHAR-UHFFFAOYSA-J titanium(4+);disulfate Chemical class [Ti+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O HDUMBHAAKGUHAR-UHFFFAOYSA-J 0.000 description 1
- 238000004627 transmission electron microscopy Methods 0.000 description 1
- 125000005259 triarylamine group Chemical group 0.000 description 1
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
- YFTHZRPMJXBUME-UHFFFAOYSA-N tripropylamine Chemical compound CCCN(CCC)CCC YFTHZRPMJXBUME-UHFFFAOYSA-N 0.000 description 1
- MBYLVOKEDDQJDY-UHFFFAOYSA-N tris(2-aminoethyl)amine Chemical compound NCCN(CCN)CCN MBYLVOKEDDQJDY-UHFFFAOYSA-N 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/063—Titanium; Oxides or hydroxides thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of zinc, cadmium or mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/50—Silver
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0235—Nitrogen containing compounds
- B01J31/0237—Amines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0235—Nitrogen containing compounds
- B01J31/0239—Quaternary ammonium compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
- B01J31/38—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
-
- B01J35/30—
-
- B01J35/39—
-
- B01J35/393—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/036—Precipitation; Co-precipitation to form a gel or a cogel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/04—Mixing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
Abstract
Description
Claims
Priority Applications (17)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SG11201402330WA SG11201402330WA (en) | 2011-11-16 | 2012-11-16 | Neutral, stable and transparent photocatalytic titanium dioxide sols |
JP2014542505A JP6146822B2 (en) | 2011-11-16 | 2012-11-16 | Method for preparing a stable transparent photocatalytic titanium dioxide sol having a pH of 7 to 9.5 |
AU2012340198A AU2012340198B2 (en) | 2011-11-16 | 2012-11-16 | Neutral, stable and transparent photocatalytic titanium dioxide sols |
SI201231883T SI2780108T1 (en) | 2011-11-16 | 2012-11-16 | Method for preparing a neutral, stable and transparent photocatalytic titanium dioxide sol |
MX2014005975A MX2014005975A (en) | 2011-11-16 | 2012-11-16 | Neutral, stable and transparent photocatalytic titanium dioxide sols. |
NZ625870A NZ625870B2 (en) | 2011-11-16 | 2012-11-16 | Neutral, stable and transparent photocatalytic titanium dioxide sols |
BR112014011860-4A BR112014011860B1 (en) | 2011-11-16 | 2012-11-16 | METHOD FOR PREPARING A PHOTOCATALYTIC TITANIUM DIOXIDE SUN, NEUTRAL, STABLE AND TRANSPARENT |
CN201280064925.1A CN104010724B (en) | 2011-11-16 | 2012-11-16 | neutral, stable and transparent photocatalyst titanium oxide sol |
PL12849280T PL2780108T3 (en) | 2011-11-16 | 2012-11-16 | Method for preparing a neutral, stable and transparent photocatalytic titanium dioxide sol |
EP12849280.8A EP2780108B1 (en) | 2011-11-16 | 2012-11-16 | Method for preparing a neutral, stable and transparent photocatalytic titanium dioxide sol |
CA2856095A CA2856095C (en) | 2011-11-16 | 2012-11-16 | Neutral, stable and transparent photocatalytic titanium dioxide sols |
UAA201406459A UA114187C2 (en) | 2011-11-16 | 2012-11-16 | Neutral, stable and transparent photocatalytic titanium dioxide sols |
DK12849280.8T DK2780108T3 (en) | 2011-11-16 | 2012-11-16 | PROCEDURE FOR PREPARING A NEUTRAL, STABLE AND TRANSPARENT PHOTOCATALYTIC TITANIUM DIOXIDE SUN |
ES12849280T ES2860931T3 (en) | 2011-11-16 | 2012-11-16 | Method for preparing a transparent, stable and neutral photocatalytic titanium dioxide sol |
KR1020147016257A KR101968367B1 (en) | 2011-11-16 | 2012-11-16 | Neutral, stable and transparent photocatalytic titanium dioxide sols |
PH12014501105A PH12014501105A1 (en) | 2011-11-16 | 2014-05-16 | Neutral, stable and transparent photocatalytic titanium dioxide sols |
ZA2014/04097A ZA201404097B (en) | 2011-11-16 | 2014-06-05 | Neutral, stable and transparent photocatalytic titanium dioxide sols |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201161560669P | 2011-11-16 | 2011-11-16 | |
US61/560,669 | 2011-11-16 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2013074984A1 true WO2013074984A1 (en) | 2013-05-23 |
Family
ID=48280861
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2012/065616 WO2013074984A1 (en) | 2011-11-16 | 2012-11-16 | Neutral, stable and transparent photocatalytic titanium dioxide sols |
Country Status (21)
Country | Link |
---|---|
US (2) | US9352299B2 (en) |
EP (1) | EP2780108B1 (en) |
JP (1) | JP6146822B2 (en) |
KR (1) | KR101968367B1 (en) |
CN (1) | CN104010724B (en) |
AU (1) | AU2012340198B2 (en) |
BR (1) | BR112014011860B1 (en) |
CA (1) | CA2856095C (en) |
DK (1) | DK2780108T3 (en) |
ES (1) | ES2860931T3 (en) |
MX (1) | MX2014005975A (en) |
MY (1) | MY167566A (en) |
PH (1) | PH12014501105A1 (en) |
PL (1) | PL2780108T3 (en) |
PT (1) | PT2780108T (en) |
SG (1) | SG11201402330WA (en) |
SI (1) | SI2780108T1 (en) |
TW (1) | TWI604889B (en) |
UA (1) | UA114187C2 (en) |
WO (1) | WO2013074984A1 (en) |
ZA (1) | ZA201404097B (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2014118371A1 (en) * | 2013-02-03 | 2014-08-07 | Joma International A/S | A catalytic substrate surface containing particles |
WO2014118372A1 (en) * | 2013-02-02 | 2014-08-07 | Joma International A/S | An aqueous dispersion comprising tio2 particles |
US9352299B2 (en) | 2011-11-16 | 2016-05-31 | Cristal Usa Inc. | Neutral, stable and transparent photocatalytic titanium dioxide sols |
JP2017509727A (en) * | 2013-12-18 | 2017-04-06 | ダブリン インスティテュート オブ テクノロジー | Surface coating |
WO2017070507A1 (en) * | 2015-10-21 | 2017-04-27 | Cristal Usa Inc. | Nox reducing coatings and methods for reducing nox therewith |
EP3896041A1 (en) * | 2020-04-17 | 2021-10-20 | Mursall Active Coating GmbH | Coating and method for applying a coating to a glass surface |
Families Citing this family (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11166458B2 (en) | 2011-04-15 | 2021-11-09 | Allied Bioscience, Inc. | Wet wipes comprising antimicrobial coating compositions |
CN103635626A (en) | 2011-04-15 | 2014-03-12 | 联合生物科学服务股份有限公司 | Composition and method to form self-decontaminating surface |
US9528009B2 (en) * | 2011-04-15 | 2016-12-27 | Craig Grossman | Composition and method to form a self decontaminating surface |
US20130266370A1 (en) * | 2012-03-16 | 2013-10-10 | Intecrete, Llc | Multi-layered cement compositions containing photocatalyst particles and method for creating multi-layered cement compositions containing photocatalyst particles |
CN104626680B (en) * | 2015-03-03 | 2016-09-07 | 中国科学院上海硅酸盐研究所 | A kind of composite black titanium deoxid film and preparation method thereof |
BR112018010044A2 (en) * | 2015-11-20 | 2018-11-21 | Cristal Usa Inc | titanium dioxide compositions and their use as depollutants |
JP2019501774A (en) * | 2015-12-10 | 2019-01-24 | クリスタル・ユー・エス・エー・インコーポレイテッド | Concentrated photoactive neutral titanium dioxide sol |
WO2017156372A1 (en) * | 2016-03-10 | 2017-09-14 | Cristal Usa Inc. | Photocatalytic coating compositions |
KR101856971B1 (en) | 2016-12-20 | 2018-05-15 | (주) 클레어 | Method for preparing Sickhouse Syndrome Remover by combining with Photocatalyst and Fermented Acid |
CN107352579A (en) * | 2017-07-17 | 2017-11-17 | 上海友兰科技有限公司 | A kind of preparation method of superhydrophilic self-cleaning TiO 2 sol |
CN107917351A (en) * | 2017-10-27 | 2018-04-17 | 中山市汉庭照明科技有限公司 | A kind of LED light bulbs and preparation method having except effect of formaldehyde |
IT201800003836A1 (en) * | 2018-03-21 | 2019-09-21 | Andrea Gaglianone | COMPOSITION AND SANITATION METHOD FOR THE SANITIZATION-PURIFICATION OF SURFACES AND ENVIRONMENTS |
US11951221B2 (en) | 2018-06-19 | 2024-04-09 | Northwestern University | Silver and titanium dioxide based optically transparent antimicrobial coatings and related methods |
CN108967442B (en) * | 2018-07-24 | 2020-06-05 | 广东省生态环境技术研究所 | Ferrous modified selenium sol for inhibiting cadmium and arsenic accumulation of rice and preparation method and application thereof |
EP3894484A1 (en) * | 2018-12-10 | 2021-10-20 | Kastus Technologies DAC | P-doped surface coatings and process of preparation thereof |
TWI779203B (en) * | 2018-12-10 | 2022-10-01 | 愛爾蘭商卡斯特斯科技公司 | P-doped surface coatings and process of preparation thereof |
PL428604A1 (en) * | 2019-01-16 | 2020-07-27 | Bolix Spółka Akcyjna | Method of protecting a newly constructed facade against microbiological contamination and method of renovation of a building facade affected by microbiological contamination |
CN110090571A (en) * | 2019-04-01 | 2019-08-06 | 江苏奥净嘉环保科技有限公司 | A kind of preparation method of nano titanium oxide dispersion |
CN112246262A (en) * | 2020-10-27 | 2021-01-22 | 长春工业大学 | Preparation of transition metal Zn and Ag modified catalyst |
US11253842B1 (en) * | 2021-04-02 | 2022-02-22 | TiCoat, Inc. | Titanium dioxide containing peroxo titanium complex and methods of manufacturing and application of the same |
CN114604947A (en) * | 2022-03-21 | 2022-06-10 | 衡阳市建衡实业有限公司 | Titanium-containing composite ferric polysulfate flocculant and preparation method and application thereof |
KR102632414B1 (en) * | 2022-10-21 | 2024-02-05 | (재)한국건설생활환경시험연구원 | Smart Road Management System Using Piezoelectric Element and photocatalytic modifier |
CN117380172B (en) * | 2023-10-11 | 2024-04-16 | 齐鲁工业大学(山东省科学院) | Photocatalytic self-cleaning metal hydroxide/TiO with amphiphilic structure 2 Hydrosol and preparation method and application thereof |
Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5049309A (en) * | 1986-09-22 | 1991-09-17 | Ishihara Sangyo Kaisha, Ltd. | Titania sol |
US5403513A (en) * | 1987-10-07 | 1995-04-04 | Catalyst & Chemical Industries, Co., Ltd. | Titanium oxide sol and process for preparation thereof |
JP2002179949A (en) * | 2000-12-11 | 2002-06-26 | Hitachi Chem Co Ltd | Liquid for forming titania film, method of forming titania film, titania film and member made by using titania film |
US6569920B1 (en) * | 2000-08-16 | 2003-05-27 | Millennium Inorganic Chemicals, Inc. | Titanium dioxide slurries having improved stability |
US20060228476A1 (en) | 1996-08-13 | 2006-10-12 | Pilkington Pllc | Method for depositing tin oxide and titanium oxide coatings on flat glass and the resulting coated glass |
US20070167551A1 (en) | 2004-01-30 | 2007-07-19 | Millennium Chemicals | Coating composition having surface depolluting properties |
US20070195259A1 (en) * | 2006-02-22 | 2007-08-23 | Microban Products Company | Antimicrobial spectacle |
US20080081758A1 (en) | 2006-09-28 | 2008-04-03 | Taketoshi Kuroda | Photocatalytic titanium oxide sol, and coating composition and member using the same |
US20090209665A1 (en) | 2008-02-14 | 2009-08-20 | Guoyi Fu | Colloidal titanium dioxide sols |
US7605186B2 (en) * | 2003-04-03 | 2009-10-20 | Sunhanmnt Co., Ltd. | Non-acidic, non-basic colloid solution containing dispersed titanium dioxide method of manufacturing the same, and coating material comprising the colloid solution |
JP2010148999A (en) * | 2008-12-24 | 2010-07-08 | Taki Chem Co Ltd | Photocatalytic titanium oxide sol and method of manufacturing the same |
US7763565B2 (en) | 2007-08-31 | 2010-07-27 | Millennium Inorganic Chemicals, Inc. | Transparent, stable titanium dioxide sols |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB8300554D0 (en) * | 1983-01-10 | 1983-02-09 | Atomic Energy Authority Uk | Catalyst preparation |
JPS63215520A (en) * | 1987-03-03 | 1988-09-08 | Ishihara Sangyo Kaisha Ltd | Neutral titania and production thereof |
JP3109101B2 (en) | 1994-10-05 | 2000-11-13 | 東陶機器株式会社 | Antimicrobial solid, method for producing the same, and method for using the same |
US6387844B1 (en) * | 1994-10-31 | 2002-05-14 | Akira Fujishima | Titanium dioxide photocatalyst |
EP0737513B1 (en) | 1994-10-31 | 2002-05-29 | Kanagawa Academy Of Science And Technology | Titanium oxide photocatalyst structure and method of manufacturing the same |
US5897958A (en) * | 1995-10-26 | 1999-04-27 | Asahi Glass Company Ltd. | Modified titanium oxide sol, photocatalyst composition and photocatalyst composition-forming agent |
ATE316422T1 (en) * | 1998-05-14 | 2006-02-15 | Showa Denko Kk | TITANIUM DIOXIDE SOL, THIN FILM AND METHOD FOR THE PRODUCTION THEREOF |
JP4521795B2 (en) * | 2000-11-08 | 2010-08-11 | 多木化学株式会社 | Titanium oxide sol composition |
US7060643B2 (en) * | 2000-12-28 | 2006-06-13 | Showa Denko Kabushiki Kaisha | Photo-functional powder and applications thereof |
KR20030043536A (en) * | 2001-11-28 | 2003-06-02 | 티오켐 주식회사 | Synthesis of highly active photocatalytic TiO2-sol by hydrothermal method |
FR2838734B1 (en) | 2002-04-17 | 2005-04-15 | Saint Gobain | SELF-CLEANING COATING SUBSTRATE |
CN1218634C (en) | 2002-04-30 | 2005-09-14 | 香港中文大学 | Method of preparing mesoporous titanium dioxide film with high disinfecting photoactivity |
US7521039B2 (en) | 2002-11-08 | 2009-04-21 | Millennium Inorganic Chemicals, Inc. | Photocatalytic rutile titanium dioxide |
JP4540971B2 (en) * | 2003-12-05 | 2010-09-08 | 石原産業株式会社 | Neutral titanium oxide sol and method for producing the same |
JP4522082B2 (en) * | 2003-12-05 | 2010-08-11 | 石原産業株式会社 | Photocatalyst liquid composition and photocatalyst formed using the same |
DE102005036427A1 (en) | 2005-08-03 | 2007-02-08 | Schott Ag | Substrate, comprising at least one fully or partially macrostructured layer, process for their preparation and their use |
JP4606385B2 (en) * | 2006-06-05 | 2011-01-05 | 多木化学株式会社 | Method for producing alkali-type titanium oxide sol |
PL1935929T3 (en) | 2006-12-19 | 2012-04-30 | Evonik Degussa Gmbh | Sol gel process for producing protective films for polymeric substrates |
KR100935512B1 (en) * | 2008-05-15 | 2010-01-06 | 경북대학교 산학협력단 | Manufacturing method of TiO2 photocatalyst and TiO2 photocatalyst manufactured by the same |
JP2011190152A (en) * | 2010-03-16 | 2011-09-29 | Tayca Corp | Amorphous titania sol and method for producing the same |
CN104010724B (en) | 2011-11-16 | 2016-12-28 | 水晶美国股份公司 | neutral, stable and transparent photocatalyst titanium oxide sol |
-
2012
- 2012-11-16 CN CN201280064925.1A patent/CN104010724B/en active Active
- 2012-11-16 PT PT128492808T patent/PT2780108T/en unknown
- 2012-11-16 ES ES12849280T patent/ES2860931T3/en active Active
- 2012-11-16 CA CA2856095A patent/CA2856095C/en active Active
- 2012-11-16 EP EP12849280.8A patent/EP2780108B1/en active Active
- 2012-11-16 SG SG11201402330WA patent/SG11201402330WA/en unknown
- 2012-11-16 US US13/679,252 patent/US9352299B2/en active Active
- 2012-11-16 BR BR112014011860-4A patent/BR112014011860B1/en active IP Right Grant
- 2012-11-16 PL PL12849280T patent/PL2780108T3/en unknown
- 2012-11-16 WO PCT/US2012/065616 patent/WO2013074984A1/en active Application Filing
- 2012-11-16 DK DK12849280.8T patent/DK2780108T3/en active
- 2012-11-16 TW TW101142963A patent/TWI604889B/en active
- 2012-11-16 JP JP2014542505A patent/JP6146822B2/en active Active
- 2012-11-16 AU AU2012340198A patent/AU2012340198B2/en active Active
- 2012-11-16 UA UAA201406459A patent/UA114187C2/en unknown
- 2012-11-16 KR KR1020147016257A patent/KR101968367B1/en active IP Right Grant
- 2012-11-16 SI SI201231883T patent/SI2780108T1/en unknown
- 2012-11-16 MY MYPI2014701243A patent/MY167566A/en unknown
- 2012-11-16 MX MX2014005975A patent/MX2014005975A/en unknown
-
2014
- 2014-05-16 PH PH12014501105A patent/PH12014501105A1/en unknown
- 2014-06-05 ZA ZA2014/04097A patent/ZA201404097B/en unknown
-
2016
- 2016-04-21 US US15/134,854 patent/US20160228850A1/en not_active Abandoned
Patent Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5049309A (en) * | 1986-09-22 | 1991-09-17 | Ishihara Sangyo Kaisha, Ltd. | Titania sol |
US5403513A (en) * | 1987-10-07 | 1995-04-04 | Catalyst & Chemical Industries, Co., Ltd. | Titanium oxide sol and process for preparation thereof |
US20060228476A1 (en) | 1996-08-13 | 2006-10-12 | Pilkington Pllc | Method for depositing tin oxide and titanium oxide coatings on flat glass and the resulting coated glass |
US6569920B1 (en) * | 2000-08-16 | 2003-05-27 | Millennium Inorganic Chemicals, Inc. | Titanium dioxide slurries having improved stability |
JP2002179949A (en) * | 2000-12-11 | 2002-06-26 | Hitachi Chem Co Ltd | Liquid for forming titania film, method of forming titania film, titania film and member made by using titania film |
US7605186B2 (en) * | 2003-04-03 | 2009-10-20 | Sunhanmnt Co., Ltd. | Non-acidic, non-basic colloid solution containing dispersed titanium dioxide method of manufacturing the same, and coating material comprising the colloid solution |
US20070167551A1 (en) | 2004-01-30 | 2007-07-19 | Millennium Chemicals | Coating composition having surface depolluting properties |
US20070195259A1 (en) * | 2006-02-22 | 2007-08-23 | Microban Products Company | Antimicrobial spectacle |
US20080081758A1 (en) | 2006-09-28 | 2008-04-03 | Taketoshi Kuroda | Photocatalytic titanium oxide sol, and coating composition and member using the same |
US7763565B2 (en) | 2007-08-31 | 2010-07-27 | Millennium Inorganic Chemicals, Inc. | Transparent, stable titanium dioxide sols |
US20090209665A1 (en) | 2008-02-14 | 2009-08-20 | Guoyi Fu | Colloidal titanium dioxide sols |
JP2010148999A (en) * | 2008-12-24 | 2010-07-08 | Taki Chem Co Ltd | Photocatalytic titanium oxide sol and method of manufacturing the same |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9352299B2 (en) | 2011-11-16 | 2016-05-31 | Cristal Usa Inc. | Neutral, stable and transparent photocatalytic titanium dioxide sols |
WO2014118372A1 (en) * | 2013-02-02 | 2014-08-07 | Joma International A/S | An aqueous dispersion comprising tio2 particles |
WO2014118371A1 (en) * | 2013-02-03 | 2014-08-07 | Joma International A/S | A catalytic substrate surface containing particles |
US10029236B2 (en) | 2013-02-03 | 2018-07-24 | Joma International A/S | Catalytic substrate surface |
JP2017509727A (en) * | 2013-12-18 | 2017-04-06 | ダブリン インスティテュート オブ テクノロジー | Surface coating |
WO2017070507A1 (en) * | 2015-10-21 | 2017-04-27 | Cristal Usa Inc. | Nox reducing coatings and methods for reducing nox therewith |
CN108603049A (en) * | 2015-10-21 | 2018-09-28 | 克里斯特尔美国有限公司 | The method for reducing the coating of NOX and reducing NOX with it |
US10639614B2 (en) | 2015-10-21 | 2020-05-05 | Tronox Llc | NOx reducing coatings and methods for reducing NOx therewith |
EP3896041A1 (en) * | 2020-04-17 | 2021-10-20 | Mursall Active Coating GmbH | Coating and method for applying a coating to a glass surface |
Also Published As
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CA2856095C (en) | Neutral, stable and transparent photocatalytic titanium dioxide sols | |
TWI353881B (en) | ||
AU2008292827B2 (en) | Transparent, stable titanium dioxide sols | |
US20110159109A1 (en) | Titania dispersion and method for making | |
JP4169163B1 (en) | Photocatalytic titanium oxide sol and coating composition using the same | |
JP2010148999A (en) | Photocatalytic titanium oxide sol and method of manufacturing the same | |
EP1904594A1 (en) | Suspensions of titanium dioxide and method for obtaining them | |
NZ713282B2 (en) | Neutral, stable and transparent photocatalytic titanium dioxide sols | |
NZ625870B2 (en) | Neutral, stable and transparent photocatalytic titanium dioxide sols |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 12849280 Country of ref document: EP Kind code of ref document: A1 |
|
ENP | Entry into the national phase |
Ref document number: 2014542505 Country of ref document: JP Kind code of ref document: A Ref document number: 2856095 Country of ref document: CA |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
WWE | Wipo information: entry into national phase |
Ref document number: 12014501105 Country of ref document: PH Ref document number: MX/A/2014/005975 Country of ref document: MX |
|
ENP | Entry into the national phase |
Ref document number: 20147016257 Country of ref document: KR Kind code of ref document: A |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2012849280 Country of ref document: EP |
|
ENP | Entry into the national phase |
Ref document number: 2012340198 Country of ref document: AU Date of ref document: 20121116 Kind code of ref document: A |
|
REG | Reference to national code |
Ref country code: BR Ref legal event code: B01A Ref document number: 112014011860 Country of ref document: BR |
|
ENP | Entry into the national phase |
Ref document number: 112014011860 Country of ref document: BR Kind code of ref document: A2 Effective date: 20140516 |
|
REG | Reference to national code |
Ref country code: BR Ref legal event code: B01E Ref document number: 112014011860 Country of ref document: BR Kind code of ref document: A2 Free format text: APRESENTE NOVA VIA DO FORMULARIO FQ003 CORRIGINDO O NUMERO DA PRIORIDADE REQUERIDA, OUTROSSIM, APRESENTE CESSAO DA PRIORIDADE REIVINDICADA US 61/560,669, UMA VEZ QUE SO FOI APRESENTADA A DA PRIORIDADE 13/679,252. |
|
ENP | Entry into the national phase |
Ref document number: 112014011860 Country of ref document: BR Kind code of ref document: A2 Effective date: 20140516 |