WO2013066456A2 - Articles comprenant des films en polymère réticulé structurés pour détection électronique d'explosifs nitroaromatiques - Google Patents

Articles comprenant des films en polymère réticulé structurés pour détection électronique d'explosifs nitroaromatiques Download PDF

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Publication number
WO2013066456A2
WO2013066456A2 PCT/US2012/049460 US2012049460W WO2013066456A2 WO 2013066456 A2 WO2013066456 A2 WO 2013066456A2 US 2012049460 W US2012049460 W US 2012049460W WO 2013066456 A2 WO2013066456 A2 WO 2013066456A2
Authority
WO
WIPO (PCT)
Prior art keywords
article
interest
nitroaromatic
manufacture
tnt
Prior art date
Application number
PCT/US2012/049460
Other languages
English (en)
Other versions
WO2013066456A3 (fr
Inventor
Howard Edan Katz
Hoyoul KONG
Sun JIA
Jasmine Sinha
Original Assignee
The Johns Hopkins University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Johns Hopkins University filed Critical The Johns Hopkins University
Priority to US14/235,520 priority Critical patent/US20140220704A1/en
Publication of WO2013066456A2 publication Critical patent/WO2013066456A2/fr
Publication of WO2013066456A3 publication Critical patent/WO2013066456A3/fr

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Classifications

    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/22—Fuels, explosives
    • G01N33/227—Explosives, e.g. combustive properties thereof
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/02—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance
    • G01N27/04—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance
    • G01N27/12—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance of a solid body in dependence upon absorption of a fluid; of a solid body in dependence upon reaction with a fluid, for detecting components in the fluid
    • G01N27/125—Composition of the body, e.g. the composition of its sensitive layer
    • G01N27/126—Composition of the body, e.g. the composition of its sensitive layer comprising organic polymers
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/0004—Gaseous mixtures, e.g. polluted air
    • G01N33/0009—General constructional details of gas analysers, e.g. portable test equipment
    • G01N33/0027—General constructional details of gas analysers, e.g. portable test equipment concerning the detector
    • G01N33/0036—Specially adapted to detect a particular component
    • G01N33/0057—Specially adapted to detect a particular component for warfare agents or explosives

Abstract

La présente invention se rapporte à des dispositifs et à des articles de fabrication comprenant un polymère fonctionnant à basse-tension, très sensible et à réaction sélective pour la détection de composés nitroaromatiques, comprenant des explosifs. Des dispositifs résistifs ont été fabriqués par un simple revêtement par centrifugation sur des substrats flexibles et transparents ainsi que des substrats de silicium, et étaient stables à des niveaux d'oxygène et à température ambiants avant exposition aux nitroaromatiques. Après exposition à du 2,4,6-trinitrotoluène (TNT), les dispositifs ont montré une conductance accrue, même avec des quantités pg de TNT, s'accompagnant d'un changement de couleur de confirmation, passant du transparent au rouge intense. L'augmentation de conductance relative par unité d'exposition est jusqu'à maintenant la plus élevée rapportée par le TNT. Les sels d'anions aromatiques, par contre, n'ont produit aucune réponse électronique. L'invention décrit également des procédés et des dispositifs de fabrication des articles, et leur utilisation.
PCT/US2012/049460 2011-08-03 2012-08-03 Articles comprenant des films en polymère réticulé structurés pour détection électronique d'explosifs nitroaromatiques WO2013066456A2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US14/235,520 US20140220704A1 (en) 2011-08-03 2012-08-03 Articles comprising templated crosslinked polymer films for electronic detection of nitroaromatic explosives

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US201161514647P 2011-08-03 2011-08-03
US61/514,647 2011-08-03
US201161526484P 2011-08-23 2011-08-23
US61/526,484 2011-08-23

Publications (2)

Publication Number Publication Date
WO2013066456A2 true WO2013066456A2 (fr) 2013-05-10
WO2013066456A3 WO2013066456A3 (fr) 2013-07-11

Family

ID=48192980

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PCT/US2012/049460 WO2013066456A2 (fr) 2011-08-03 2012-08-03 Articles comprenant des films en polymère réticulé structurés pour détection électronique d'explosifs nitroaromatiques

Country Status (2)

Country Link
US (1) US20140220704A1 (fr)
WO (1) WO2013066456A2 (fr)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104181216A (zh) * 2014-09-16 2014-12-03 湖南农业大学 基于纳米材料复合物的溶胶凝胶分子印迹电化学传感器检测丙烯酰胺的方法
GB2548540A (en) * 2013-06-03 2017-09-27 Inst Chemmii Fizycznej Polskiej Akademii Nauk New bis(2, 2'-bithienyl)methane derivative and method of producing thereof, molecularly imprinted polymer film, method of producing therof and its use
WO2018025887A1 (fr) * 2016-08-02 2018-02-08 Quantum Biosystems Inc. Dispositifs et procédés pour la création et l'étalonnage d'une paire de nanoélectrodes
US10202644B2 (en) 2010-03-03 2019-02-12 Quantum Biosystems Inc. Method and device for identifying nucleotide, and method and device for determining nucleotide sequence of polynucleotide
US10261066B2 (en) 2013-10-16 2019-04-16 Quantum Biosystems Inc. Nano-gap electrode pair and method of manufacturing same
US10413903B2 (en) 2014-05-08 2019-09-17 Osaka University Devices, systems and methods for linearization of polymers
US10438811B1 (en) 2014-04-15 2019-10-08 Quantum Biosystems Inc. Methods for forming nano-gap electrodes for use in nanosensors
US10557167B2 (en) 2013-09-18 2020-02-11 Quantum Biosystems Inc. Biomolecule sequencing devices, systems and methods

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IL232696B (en) 2014-05-19 2018-08-30 Technion Res & Dev Foundation Compound and method for detecting molecules of interest
JP6622166B2 (ja) 2016-09-20 2019-12-18 株式会社東芝 分子検出器、分子検出方法、分子検出器、および有機物プローブ

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6872786B2 (en) * 2000-04-10 2005-03-29 The Johns Hopkins University Molecularly imprinted polymeric sensor for the detection of explosives
US20080038832A1 (en) * 2004-10-12 2008-02-14 Mip Technologies Ab Method for Producing Molecularly Imprinted Polymers for the Recognition of Target Molecules
WO2010078426A1 (fr) * 2008-12-31 2010-07-08 Raptor Detection, Inc. Matières polymères à empreinte moléculaire pour la détection visuelle d'explosifs

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6872786B2 (en) * 2000-04-10 2005-03-29 The Johns Hopkins University Molecularly imprinted polymeric sensor for the detection of explosives
US20080038832A1 (en) * 2004-10-12 2008-02-14 Mip Technologies Ab Method for Producing Molecularly Imprinted Polymers for the Recognition of Target Molecules
WO2010078426A1 (fr) * 2008-12-31 2010-07-08 Raptor Detection, Inc. Matières polymères à empreinte moléculaire pour la détection visuelle d'explosifs

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
ALIZADEH ET AL.: 'A new molecularly imprinted polymer(MIP)-based electrochemical sensor for monitoring 2,4,6-trinitrotoluene (TNT) in matural waters and soil samples' BIOSENSORS AND BIOELECTRONICS vol. 25, no. ISSUE, 2010, pages 16166 - 1172, XP026808914 *
MCCLUSKEY ET AL.: 'Molecularly imprinted polymers(MIPs): sensing an explosive new opportunity?' ORGANIC & BIOMOLECULAR CHEMISTRY vol. 5, no. ISSUE, 2007, pages 3233 - 3244, XP055000148 *

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10202644B2 (en) 2010-03-03 2019-02-12 Quantum Biosystems Inc. Method and device for identifying nucleotide, and method and device for determining nucleotide sequence of polynucleotide
US10876159B2 (en) 2010-03-03 2020-12-29 Quantum Biosystems Inc. Method and device for identifying nucleotide, and method and device for determining nucleotide sequence of polynucleotide
GB2548540A (en) * 2013-06-03 2017-09-27 Inst Chemmii Fizycznej Polskiej Akademii Nauk New bis(2, 2'-bithienyl)methane derivative and method of producing thereof, molecularly imprinted polymer film, method of producing therof and its use
GB2548540B (en) * 2013-06-03 2020-03-04 Inst Chemmii Fizycznej Polskiej Akademii Nauk Bis(2,2-bithienyl)methane derivate; molecularly imprinted polymer film; and associated methods of production and use thereof
US10557167B2 (en) 2013-09-18 2020-02-11 Quantum Biosystems Inc. Biomolecule sequencing devices, systems and methods
US10261066B2 (en) 2013-10-16 2019-04-16 Quantum Biosystems Inc. Nano-gap electrode pair and method of manufacturing same
US10466228B2 (en) 2013-10-16 2019-11-05 Quantum Biosystems Inc. Nano-gap electrode pair and method of manufacturing same
US10438811B1 (en) 2014-04-15 2019-10-08 Quantum Biosystems Inc. Methods for forming nano-gap electrodes for use in nanosensors
US10413903B2 (en) 2014-05-08 2019-09-17 Osaka University Devices, systems and methods for linearization of polymers
CN104181216A (zh) * 2014-09-16 2014-12-03 湖南农业大学 基于纳米材料复合物的溶胶凝胶分子印迹电化学传感器检测丙烯酰胺的方法
CN104181216B (zh) * 2014-09-16 2015-06-10 湖南农业大学 基于纳米材料复合物的溶胶凝胶分子印迹电化学传感器检测丙烯酰胺的方法
WO2018025887A1 (fr) * 2016-08-02 2018-02-08 Quantum Biosystems Inc. Dispositifs et procédés pour la création et l'étalonnage d'une paire de nanoélectrodes

Also Published As

Publication number Publication date
WO2013066456A3 (fr) 2013-07-11
US20140220704A1 (en) 2014-08-07

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