WO2013046232A1 - Water purification compositions of magnesium oxide and applications thereof - Google Patents
Water purification compositions of magnesium oxide and applications thereof Download PDFInfo
- Publication number
- WO2013046232A1 WO2013046232A1 PCT/IN2012/000644 IN2012000644W WO2013046232A1 WO 2013046232 A1 WO2013046232 A1 WO 2013046232A1 IN 2012000644 W IN2012000644 W IN 2012000644W WO 2013046232 A1 WO2013046232 A1 WO 2013046232A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- weight
- composition
- magnesium oxide
- oxide component
- binder
- Prior art date
Links
- 239000000395 magnesium oxide Substances 0.000 title claims abstract description 115
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 title claims abstract description 115
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical group [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 title claims abstract description 110
- 239000000203 mixture Substances 0.000 title claims abstract description 103
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 79
- 238000000746 purification Methods 0.000 title claims abstract description 36
- 239000011230 binding agent Substances 0.000 claims abstract description 68
- IQDXNHZDRQHKEF-UHFFFAOYSA-N dialuminum;dicalcium;dioxido(oxo)silane Chemical compound [Al+3].[Al+3].[Ca+2].[Ca+2].[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O IQDXNHZDRQHKEF-UHFFFAOYSA-N 0.000 claims abstract description 32
- -1 polyethylene Polymers 0.000 claims abstract description 17
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims abstract description 16
- 239000004926 polymethyl methacrylate Substances 0.000 claims abstract description 16
- 239000004698 Polyethylene Substances 0.000 claims abstract description 7
- 229920000573 polyethylene Polymers 0.000 claims abstract description 7
- 239000008187 granular material Substances 0.000 claims description 27
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 23
- 239000000463 material Substances 0.000 claims description 15
- 229910052596 spinel Inorganic materials 0.000 claims description 12
- 229910026161 MgAl2O4 Inorganic materials 0.000 claims description 11
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 5
- 229910052785 arsenic Inorganic materials 0.000 description 32
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 31
- 238000000034 method Methods 0.000 description 27
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 18
- 238000001179 sorption measurement Methods 0.000 description 10
- 239000002002 slurry Substances 0.000 description 9
- 239000003463 adsorbent Substances 0.000 description 7
- 239000000347 magnesium hydroxide Substances 0.000 description 7
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
- 238000011109 contamination Methods 0.000 description 6
- 239000003651 drinking water Substances 0.000 description 6
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 239000003960 organic solvent Substances 0.000 description 6
- 239000008096 xylene Substances 0.000 description 6
- 239000004604 Blowing Agent Substances 0.000 description 5
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 239000011148 porous material Substances 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 238000007750 plasma spraying Methods 0.000 description 4
- 239000008213 purified water Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 235000012206 bottled water Nutrition 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 239000000356 contaminant Substances 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 230000001419 dependent effect Effects 0.000 description 3
- 235000020188 drinking water Nutrition 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 229910001385 heavy metal Inorganic materials 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000005979 thermal decomposition reaction Methods 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000003673 groundwater Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229910001410 inorganic ion Inorganic materials 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical class CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- NZZMNINUUFWWNR-UHFFFAOYSA-N CCCCC.CCC(C)C Chemical compound CCCCC.CCC(C)C NZZMNINUUFWWNR-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 208000008839 Kidney Neoplasms Diseases 0.000 description 1
- 206010058467 Lung neoplasm malignant Diseases 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
- 208000000453 Skin Neoplasms Diseases 0.000 description 1
- 241000024109 Spiris Species 0.000 description 1
- 229910052770 Uranium Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- GSWGDDYIUCWADU-UHFFFAOYSA-N aluminum magnesium oxygen(2-) Chemical compound [O--].[Mg++].[Al+3] GSWGDDYIUCWADU-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- LULLIKNODDLMDQ-UHFFFAOYSA-N arsenic(3+) Chemical compound [As+3] LULLIKNODDLMDQ-UHFFFAOYSA-N 0.000 description 1
- HAYXDMNJJFVXCI-UHFFFAOYSA-N arsenic(5+) Chemical compound [As+5] HAYXDMNJJFVXCI-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000002666 chemical blowing agent Substances 0.000 description 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 208000004042 dental fluorosis Diseases 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000010612 desalination reaction Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 230000037406 food intake Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 210000003734 kidney Anatomy 0.000 description 1
- 201000010982 kidney cancer Diseases 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 210000004072 lung Anatomy 0.000 description 1
- 201000005202 lung cancer Diseases 0.000 description 1
- 201000005296 lung carcinoma Diseases 0.000 description 1
- 208000020816 lung neoplasm Diseases 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 238000007885 magnetic separation Methods 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000003701 mechanical milling Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 239000013335 mesoporous material Substances 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical group 0.000 description 1
- 239000012229 microporous material Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 239000011858 nanopowder Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
- 238000005325 percolation Methods 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000011002 quantification Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000012087 reference standard solution Substances 0.000 description 1
- 238000005067 remediation Methods 0.000 description 1
- 238000001223 reverse osmosis Methods 0.000 description 1
- 239000011669 selenium Substances 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 208000025636 skeletal fluorosis Diseases 0.000 description 1
- 208000017520 skin disease Diseases 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 230000002110 toxicologic effect Effects 0.000 description 1
- 231100000027 toxicology Toxicity 0.000 description 1
- DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 description 1
- 210000003932 urinary bladder Anatomy 0.000 description 1
- 201000005112 urinary bladder cancer Diseases 0.000 description 1
- 239000012855 volatile organic compound Substances 0.000 description 1
- 238000003260 vortexing Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 150000003738 xylenes Chemical class 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/288—Treatment of water, waste water, or sewage by sorption using composite sorbents, e.g. coated, impregnated, multi-layered
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
- B01J20/041—Oxides or hydroxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
- B01J20/043—Carbonates or bicarbonates, e.g. limestone, dolomite, aragonite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
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- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/2803—Sorbents comprising a binder, e.g. for forming aggregated, agglomerated or granulated products
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- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
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- B01J2220/62—In a cartridge
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/285—Treatment of water, waste water, or sewage by sorption using synthetic organic sorbents
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/66—Treatment of water, waste water, or sewage by neutralisation; pH adjustment
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/103—Arsenic compounds
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/12—Halogens or halogen-containing compounds
- C02F2101/14—Fluorine or fluorine-containing compounds
Definitions
- the present disclosure relates to compositions of magnesium oxide and at least one polymer, methods of water purification using such compositions, and methods of preparing the same.
- Contamination of potable water and inadequate access to purified potable water fit for human consumption is an alarming issue across the world.
- Contamination of potable water with inorganic ions and heavy metals, such as arsenic contamination and fluoride contamination is especially harmful.
- Arsenic and fluoride contaminations which are usually of geological origins, are mainly prevalent with ground water. Arsenic contamination through drinking water may cause cancer of skin, lungs, urinary bladder, and kidney, as well as other skin diseases.
- the current applicable regulations of the U.S. Environmental Protection Agency set the maximum limits of arsenic at 10 parts per billion (ppb) in drinking water, although compared to the rest of the United States, western states have more systems with arsenic levels greater than this standard.
- High fluoride concentration in ground water beyond the permissible limit of 1.5 parts per million (ppm) is an acute toxicological problem. Prolonged ingestion of high quantities of fluoride can lead to dental or skeletal fluorosis.
- Some purification means must be employed to remove arsenic and control the level of fluoride in drinking water prior to consumption.
- the problem is compounded by the presence of minerals, including carbonates, which interfere with many purification schemes and systems. Particularly with water obtained from areas with geologic evidence of volcanic activity, both high arsenic levels and high mineral content, including carbonates, are typical.
- MgO Magnesium Oxide
- MgO is used for water purification as MgO is proven to be very effective in adsorbing arsenic and fluoride ions when these ions come in contact with the surface of MgO " Further, MgO is also abundant in nature, thereby making it easily available at affordable prices. While MgO is effective for arsenic and fluoride removal from water, its tendency to form paste or slurry, due to formation of magnesium hydroxide when contacted with water, is one of the main drawbacks in water purification applications. Hence when MgO is used for purifying water in a purifying system or a medium, the flow rate of the purified water decreases slowly and stops eventually requiring that the MgO be removed from the system.
- a water purification composition containing a magnesium oxide component and a binder.
- the binder is selected from the group consisting of a polymeric binder, calcium aluminum silicate, and combinations of these.
- the polymeric binder is selected from the group consisting of polymethyl methacrylate, polyethylene, and combinations of these, and is present in the composition in an amount of from about 12% to about 20% by weight.
- the binder contains calcium aluminum silicate in an amount of from about 1% to about 15% by weight.
- the magnesium oxide component includes MgO, a pH regulator, and an additional water purifying material.
- the pH regulator can include CaC0 3
- the additional water purifying material can be selected from the group consisting of Fe 2 0 3 , MgAl 2 0 4 , and combinations of these.
- compositions provided by the present disclosure are in the form of porous granules having a diameter of from about 0.2 to about 1 mm, and a surface area of from about 10 m /g to about 200 m /g.
- the present disclosure also provides a method of purifying water using the water purification compositions described herein.
- Yet another aspect of the present disclosure is an apparatus configured to purify water containing the compositions described herein.
- the present disclosure provides a composition for purifying water comprising a magnesium oxide component and a binder.
- the magnesium oxide component includes magnesium oxide, a pH regulator, and an additional water purifying material.
- the binder can be an organic polymer, an inorganic binder, or a combination of both. Applicants have found that such compositions effectively remove arsenic and fluoride ions from water, without causing any decrease in the flow rate of the purified water through conventional filtration procedures.
- magnesium oxide reacts with water to form Mg(OH) 2 .
- the resulting Mg(OH) 2 is a strong adsorbent of arsenic and fluoride.
- the complex consisting of arsenic adsorbed on Mg(OH) 2 can be subsequently removed from the water by conventional means, including filtration, settling, skimming, vortexing, centrifugation, magnetic separation, or other well-known separation systems.
- removal of the arsenic-Mg(OH) 2 complex is difficult by convention means because of the tendency to become a paste or slurry in water.
- the binder allows for the selection of parameters optimizing the adsorption of arsenic and fluoride, while simultaneously preventing the formation of a paste or slurry once MgO is contacted with water.
- the binder allows for the formation of granules with large surface areas that increase the rate of arsenic and fluoride adsorption.
- Other parameters effecting the rate of adsorption include the number of active sites present in the granules, such as corners and edges, the presence and type of pores, and the types of surface planes exposed to the arsenic and fluoride.
- Applicants have also surprisingly found that when the magnesium oxide component is combined with a binder in an amount effective to remove arsenic and fluoride from pre- treated water in a purification medium or system, the utilization of such compositions in the medium or system results in an adequate flow rate of water that is greater than the flow rate in an analogous medium or system in which the binder is not present.
- the binder attaches to the magnesium oxide component to reduce the formation of a paste or slurry, which maintains the desired flow rate of water through the relevant water purification system.
- An optimized binder will provide the required porosity and binding strength to hold the structure of the magnesium oxide component in place, rather than forming a paste or slurry, thereby maintaining the desired flow rate of water and adsorption properties. Accordingly, the presence of the binder obviates the problem associated with prior compositions and methods in which the medium or system becomes clogged.
- the binder comprises a polymeric binder.
- the organic binder is selected from the group consisting of methacrylates, polyethylene, acrylates, polypropylene, and combinations thereof.
- the polymeric binder is selected from the group consisting of polymethyl methacrylate, polyethylene, and combinations thereof.
- suitable polymeric binders are readily apparent and known to those skilled in the art.
- the polymeric binder is present in an amount of from about 10% to about 20% by weight, preferably 12% to about 18% by weight, and more preferably from about 14% to about 16% by weight.
- the inventive compositions including the polymeric binder can be prepared by dissolving the binder in an organic solvent and adding it to the magnesium oxide component.
- suitable organic solvents include, and are not limited to aromatic solvents, such as toluene, benzene, mixed xylenes, and aliphatic solvents such as hexanes, octanes, paraffins, mineral oils, ketones such as acetone, esters such as ethyl acetate, amides such as N-methyl-2-pyrrolidone (NMP), and combinations thereof.
- the organic solvent includes xylene.
- suitable organic solvents are readily apparent and known to those skilled in the art. Methods of preparing such compositions are discussed in further detail below.
- the binder includes an aluminum calcium silicate binder.
- suitable inorganic binders include, but are not limited to, aluminum silicates such as sodium, magnesium, and barium aluminum silicates. Applicants have found that in such embodiments, the need for an organic solvent in preparing the inventive composition is obviated because the aluminum silicate binder uniformly disperses in an aqueous solution containing the magnesium oxide component. Methods of preparing such compositions are discussed in further detail below.
- the calcium aluminum silicate binder is present in an amount of from about 1% to about 15% by weight, preferably from about 1% to about 10% by weight, and more preferably of from about 1% to about 5% by weight, and even more preferably about 2% to about 4% by weight.
- the magnesium oxide component comprises MgO which reacts with water to form Mg(OH) 2 , a strong adsorbent for arsenic and fluoride.
- the magnesium oxide component is present in the inventive composition in an amount of from about 80% to about 90% by weight, preferably from about 82% to about 88% by weight, and even more preferably about 84% to about 86% by weight.
- the magnesium oxide component is present in an amount of from about 85% to about 99% by weight, preferably 87% to about 95% by weight, and more preferably from about 89% to about 91 % by weight.
- the magnesium oxide component includes MgO, a pH regulator, and an additional water purifying material.
- the MgO can be obtained from any commercially available source.
- the magnesium oxide component consists essentially of MgO.
- the magnesium oxide component contains MgO in an amount of from about 40% to about 100% by weight, preferably from about 40% to about 60% by weight, and more preferably about 45% to about 50% by weight.
- the magnesium oxide component contains MgO in an amount of from about 10% to about 40% by weight, preferably from about 15% to about 35% by weight, and more preferably from about 20% to about 30% by weight.
- the magnesium oxide component includes a pH regulator.
- a pH regulator in accordance with the present disclosure is a compound that changes the pH of water when added, to provide water having a pH that is suitable for human consumption, such as a pH less than about 8. Accordingly, in certain embodiments the pH regulator decreases the pH of water when added.
- the pH regulator is CaC0 3 . While the presence of CaC0 3 typically caused the conversion of Mg(OH) 2 to MgC0 3 , Applicants have surprisingly found that CaC0 3 as used in the present disclosure, does not adversely affect the adsorption of arsenic or fluoride by the magnesium oxide component.
- the pH regulator may include natural zeolites. Examples of such zeolites are described in A. Filippidis & N. Kantiranis, Experimental Neutralization of Lake and Stream Waters from N. Greece using Domestic HEU-type Rich Natural Zeolitic Material, Desalination 213 (2007) 47-55, the contents of which are incorporated herein by reference. Other examples of suitable pH regulators are readily apparent and known to those skilled in the art.
- the pH regulator is present in an amount of from about 5% to about 25% by weight, preferably from about 7% to about 20% by weight, and more preferably about 9% to about 15% by weight.
- the magnesium oxide component contains CaC0 3 in an amount of from about 8% by weight to about 20% by weight, and preferably from about 9% to about 10% by weight.
- the magnesium oxide component contains CaC0 3 in an amount of from about 7% by weight to about 10% by weight, and preferably from about 8% to about 9% by weight.
- the present disclosure provides in one embodiment a water purification composition containing from about 80% to about 88% by weight of a magnesium oxide component and a polymeric binder in an amount of from about 12% to about 20% by weight of the composition.
- the magnesium oxide component contains CaC0 3 in an amount of from about 9% to about 20% of by the weight of the magnesium oxide component.
- the magnesium oxide component contains about 9% by weight of calcium carbonate by weight of the magnesium oxide component.
- the present disclosure provides a water purification composition containing about 90% by weight of a magnesium oxide component and about 2% by weight of a calcium aluminum silicate binder.
- the magnesium oxide component contains CaC0 3 in an amount of about 7% by weight of the magnesium oxide component.
- the magnesium oxide component in the composition contains at least one water purifying material that can render water free from contaminants, such as inorganic ions and/or heavy metals.
- Contaminants that may be removed by the additional water purifying material include, but are not limited to, copper, uranium, manganese, mercury, nickel, chromium, selenium, cadmium, iron, zinc, cobalt, lead, aluminum, barium, bismuth, antimony, chromate, nitrate, silica, perchlorate, phosphate, chloride, fluoride, and cyanide.
- the additional water purifying material contains ferric oxide (Fe 2 0 3 ), titanium dioxide (Ti0 2 ), magnesium aluminum oxide (spinel, MgAl 2 0 4 ), or combinations of these.
- the magnesium oxide component contains Fe 2 0 3 in an amount of from about 30% to about 50% by weight, preferably 35% to about 45% by weight, and more preferably from about 39% to about 41% by weight.
- the magnesium oxide component contains Fe 2 0 3 in an amount of from about 60% to about 70% by weight.
- the magnesium oxide component of the inventive composition contains MgAl 2 0 4 in an amount of from about 1% to about 5% by weight, and preferably from about 1% to about 2% by weight.
- MgO or the other ingredients present in the composition of the present subject matter vary depending on reaction conditions present in the purification system or method. The rate of chemical reactions involving solid substances is dependent on parameters such as surface area, number of active sites like corners and edges, and the presence and type of pores including type of surface planes exposed to the reactant. Accordingly, the size of MgO or the other ingredients of the composition is such that it facilitates in providing effective adsorption and removal of arsenic (III) and/or (V) and fluoride ions from the water.
- MgO of a suitable particle size can be prepared by a rapid thermal decomposition, plasma spraying, combustion, or any other process resulting in high surface area powders.
- Suitable rapid thermal decomposition, plasma spraying, and combustion processes are readily apparent and known to those skilled in the art.
- Such thermal decomposition processes include those described in P.P. Fedorov et al., Preparation of MgO Nanopa tides, Inorganic Materials, 2007, Vol. 43, No. 5, pp. 502-504, the contents of which are incorporated herein by reference.
- Suitable plasma spraying processes include those described in L. Marcinauska, Deposition of Alumina Coatings from Nanopowders by Plasma Spraying, Materials Science, 2010, Vol. 16, No. 1, the contents of which are incorporated herein by reference.
- Suitable combustion processes include those described in B. Nagappa and G.T.
- the magnesium oxide component of the water purification composition contains MgO with a diameter in the submicron range.
- the MgO has a diameter of from about 200 nm to about 1.0 mm, more preferably from about 200 nm to about 800 nm, more preferably from about 200 nm to about 400 nm, and even more preferably from about 200 nm to about 300 nm.
- the composition of the present disclosure can be formulated in various forms including powder and granule form.
- the composition is in the form of granules.
- the surface area of the granules formed from the magnesium oxide component and binder is in the range of from about 10 m 2 /g to about 200 m 2 /g, more preferably from about 100 m /g to about 200 m /g, and even more preferably from about 150 m 2 /g to about 200 m 2 /g.
- the present disclosure provides a water purification composition containing about 85% by weight of a magnesium oxide component and about 15% by weight of polymethyl methacrylate.
- the magnesium oxide component contains about 50% by weight of MgO, about 41% by weight of Fe 2 0 3 , and about 9% by weight of CaC0 3 .
- the composition is in the form of granules having an average diameter in the range of from about 0.4 mm to about 0.8 mm.
- the present disclosure provides a water purification composition containing about 85% by weight of a magnesium oxide component and about 15%) by weight of polymethyl methacrylate.
- the magnesium oxide component contains about 50% by weight of MgO, about 40%» by weight of Fe 2 0 3 , about 1% by weight of MgAl 2 0 4 , and about 9% by weight of CaC0 3 .
- the composition is in the form of granules having an average diameter in the range of from about 0.4 mm to about 0.8 mm.
- the present disclosure provides a water purification composition containing about 90%» by weight of a magnesium oxide component and about 2% by weight of a calcium aluminum silicate.
- the magnesium oxide component contains about 30% by weight of MgO, about 60% by weight of Fe 2 0 3 , about 1% by weight of MgAl 2 0 4 ; and about 7% by weight of CaC0 3 .
- the composition is in the form of granules having an average diameter in the range of from about 0.2 mm to about 1.0 mm, preferably from about 0.3 mm to about 0.7 mm, and more preferably about 0.4 mm.
- the inventive water purification compositions may be prepared by mixing together a magnesium oxide component and a polymeric binder, wherein the magnesium oxide component is present in an amount of from about 80% to about 88% by weight and the polymeric binder is present in an amount of from about 12% to about 20% by weight.
- the magnesium oxide component is prepared by mixing from about 90% to about 92% by weight of MgO and from about 8% to about 10% by weight of calcium carbonate to form a magnesium oxide component.
- the magnesium oxide component is prepared by mixing from about 40% to about 50% by weight of MgO, from about 30% to about 40% by weight of Fe 2 0 3 , and from about 20% to about 10% by weight of CaC0 3 .
- the polymeric binder is prepared by dissolving a predetermined amount of polymer in an organic solvent (such as, for example, xylene).
- the polyme includes at least one polymer selected from polymethyl methacrylate, polyethylene, or combination thereof.
- the composition which is in the form of a slurry, ii formed into flake- like structures by drying in an oven at a temperature of from about 160°C to about 200°C, preferably 170°C to about 190°C, and more preferably about 180°C for abou 30 minutes to about 60 minutes, more preferably about 45 minutes, at ambient pressure.
- Th ⁇ flakes may then be converted into granules having an average diameter of from about 0.4 mir to about 0.8 mm, for example, by the process of mechanical milling, or any other appropriate process which would be readily apparent to one skilled in the art.
- the granules thus preparec may then be filled in filter cartridges to accommodate a required quantity of the compositior to remove arsenic and fluoride ions.
- filters include, but are not limited to cylindrical cartridges having a length of about 80 mm and a diameter of about 90 mm accommodating of from about 250 to about 260 grams of granulated material.
- Suc cartridges are suitable for filtering about 1,500 L of water.
- the quantity of the compositior utilized in the filter is dependent on the contaminant level of the water being purified. Foi example, about 50 g of granulated material can be used to adequately filter water containing about 50 ppb arsenic.
- the inventive water purification compositions may be prepared by mixing a magnesium oxide component with a calcium aluminum silicate binder, wherein the magnesium oxide component is presenl in an amount of about 90% and the calcium aluminum silicate component is present in an amount of from about 1% to about 5% by weight.
- the magnesium oxide component contains from about 20% to about 30% by weight of MgO, from about 60% to about 70% by weighl of Fe 2 0 3 , from about 8% to about 10% by weight of CaC0 3 . In certain other embodiments. the magnesium oxide component also contains from about 1% to about 2% by weight oi MgAl 2 0 4 .
- the calcium aluminum silicate is dispersed in water and added to the magnesium oxide component. The resulting composition is subsequently formed into a flake-like structure and granules as described above.
- the composition prior to formation of the flake-like structure, can be mixed with a sufficient quantity of an inorganic or organic blowing agent in the range of from about 1% to about 10% by weight.
- the blowing agent is released by heating the granules at a temperature of from about 180°C to about 200°C for about 30 to about 45 minutes. Release of the blowing agent results in granules having sufficient pores to maximize the surface area of the granule coming into contact with th ⁇ contaminated water.
- a blowing agent is a substance which is capable of producing a structure via ; foaming, gas release, or related mechanisms to create pores in a matrix, thereby producing cellular material.
- blowing agent suitable for use with the inventiv ⁇ compositions include, but are not limited to, organic hydrocarbons, such as pentane isopentane, and cyclopentane, liquid C0 2 , and other chemical blowing agents, such a; hydrazine and other nitrogen-based materials, and sodium bicarbonate.
- the granules thus prepared may then be filled in filter cartridges to accommodate i required quantity of the composition to remove arsenic and fluoride ions.
- the present disclosure provides a method for treating water said method comprising contacting a pre-determined volume of contaminated water with ⁇ pre-determined amount of the composition of the present subject matter.
- the disclosure provides a water purification device or ar apparatus configured to purify water, comprising a composition in accordance with the present disclosure.
- Suitable apparatuses include, but are not limited to, a cylindrical cartridge filled with the water purification composition.
- the cylindrical cartridge has a length of from about 80 mm to about 160 mm, and a diameter of from aboul 90 mm to about 50 mm.
- the cylindrical cartridge is about 80 mm long with a diameter of about 90 mm and can be filled with about 250 g to about 270 g of the water purification composition.
- he cylindrical cartridge is about IOC mm long with a diameter of about 80 mm can be filled with about 135 g to about 140 g of the water purification material.
- the cylindrical cartridge is about 16C mm long with a diameter of about 50 mm can accommodate about 135 g to about 150 g ol the water purification composition.
- Such cartridges are capable of removing arsenic from reference samples containing arsenic at levels of about 350 ppb to levels below 10 ppb levels for volumes of about 1500 L to 1000 L.
- Example Compositions 1-3 were prepared by using the amounts and ratios described in Table 1 below.
- the polymethyl methacrylate (PMMA) was completely dissolved in Xylene resulting in a viscous media by heating the solution at a temperature of about 60°C to about 65°C.
- various binder ratios ranging from 10 percent to 20 percent by weight were used to estimate optimum binder ratio.
- the MgO was blended with the PMMA/Xylene solution to form a paste.
- the paste was dried at about 175°C to about 180°C for about 45 min at ambient pressure to remove Xylene from the MgO/PMMA slurry. This resulted in a non-uniform flake-like structure.
- the resulting flakes of various sizes were converted into a coarse powder by mechanical grinding, using a standard mixer, resulting in a granular structured media having an average diameter of from about 0.4 mm to about 0.8 mm.
- the granular composition was further blended with Fe 2 0 3 and calcium carbonate per the ratios specified above. Table 1 below indicates the blend composition loading structure for 100 grams of media.
- the inventive water purification compositions are prepared by mixing a magnesium oxide component with a calcium aluminum silicate binder.
- the magnesium oxide component contains from about 20% to about 30% by weight of MgO, from about 60% to about 70% by weight of Fe 2 0 3 , and from about 8% to about 10% by weight of CaC0 3 . In certain other embodiments, the magnesium oxide component also contains from about 1% to about 2% by weight o MgAl 2 0 4 .
- Example Composition 4 was prepared by blending 20 grams of MgO, 70 grams o Fe 2 03, and 10 grams of CaC0 3 . An additional 3 grams of calcium aluminum silicate wa added to the mixture. The entire composition was loaded into a granulation drum and wate was added at approximately 5 minute intervals to create a uniform slurry. After obtaining thi required uniformity, the slurry was passed through a sieve of known diameter and dried a room temperature. The dried granules were subjected to a high temperature of about 200°( to remove volatile organic compounds.
- Example Composition 5 was prepared by the same process as Example Compositioi
- Example Composition 6 was prepared by the same process as Example Compositioi 4, except that 10 grams of calcium aluminum silicate was added to the mixture.
- Example Composition 7 was prepared by the same process as Example Compositio: 4, except that 5 grams of calcium aluminum silicate was added to the mixture.
- Example Composition 8 was prepared by the same process as Example Compositior 4, except that 2 grams of calcium aluminum silicate was added to the mixture.
- Example Composition 9 was prepared by the same process as Example Compositioi 4, except that 1 grams of calcium aluminum silicate was added to the mixture.
- Example 10 Analysis of Flow Rate of Contaminated Water and As and F remova Efficiencies of Example Compositions 1-9.
- Example Compositions 1-9 The analysis of the flow rate of the contaminated water and the arsenic and fluoride removal efficiency of Example Compositions 1-9 was carried out as follows.
- Adsorption isotherm experiments The batch experiments of adsorption isotherm: were carried out using reference water samples spiked with 50 ppb of As(III) and 500 ppb ol As(V) in accordance with the NSF53 reference standard solution preparation method, usin ⁇ distilled water at 25 ⁇ 2°C. 300 mL of the above reference samples were added intc polyethylene bottles and different doses of adsorbent media (blend composition) was added For example, in the set of experiments, the adsorbent doses used for the isotherm study were 0.1 g/L to 1.0 g/L.
- the fixed-bed column study was conducted using a column of 60 mm diameter an ⁇ 700 mm length.
- the column was packed with Example Composition 4 for a depth of abou 120 mm to about 150 mm.
- the column was charged with arsenic bearing reference wate (prepared in accordance with the NSF530 standard with 50ppb of As(III) and 300 ppb o As(V) and with other competing ions) in the down flow mode with a volumetric flow rate o 2 to 2.5 L/hour.
- the current flow rate was optimized to obtain necessary contact time of thi sample with the adsorbent.
- the samples were collected at certain time intervals and wen analyzed for the residual arsenic concentrations.
- adsorbent blend media with geometrical meai sizes of 0.1 mm to 1.0 mm were tested. It was determined that the maximum adsorptioi capability could be achieved with a mean particle diameter ranging from about 0.4 mm t( about 0.8 mm.
- Example Compositions 1 -3 containing a PMMA organic binder are se forth in Table 2.
- the results for Example Compositions 4-9 containing a calcium aluminun silicate binder with different granule sizes and binder percentages are set forth in Table 3
- the results of the fixed-bed column study are set forth in Table 4.
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- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Hydrology & Water Resources (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Physics & Mathematics (AREA)
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- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
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Abstract
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AU2012317175A AU2012317175A1 (en) | 2011-09-26 | 2012-09-26 | Water purification compositions of magnesium oxide and applications thereof |
MX2014003589A MX361835B (en) | 2011-09-26 | 2012-09-26 | Water purification compositions of magnesium oxide and applications thereof. |
EP12835910.6A EP2744756A4 (en) | 2011-09-26 | 2012-09-26 | Water purification compositions of magnesium oxide and applications thereof |
US14/235,206 US9422169B2 (en) | 2011-09-26 | 2012-09-26 | Water purification compositions of magnesium oxide and applications thereof |
CN201280056446.5A CN104039711B (en) | 2011-09-26 | 2012-09-26 | Water purification composition containing magnesia and its application |
ZA2014/02153A ZA201402153B (en) | 2011-09-26 | 2014-03-19 | Water purification compositions of magnesium oxide and applications thereof |
US15/097,610 US20160229707A1 (en) | 2011-09-26 | 2016-04-13 | Water purification compositions of magnesium oxide and applications thereof |
AU2017206276A AU2017206276A1 (en) | 2011-09-26 | 2017-07-21 | Water purification compositions of magnesium oxide and applications thereof |
US16/265,076 US20200002188A1 (en) | 2011-09-26 | 2019-02-01 | Water purification compositions of magnesium oxide and applications thereof |
AU2019204568A AU2019204568A1 (en) | 2011-09-26 | 2019-06-27 | Water purification compositions of magnesium oxide and applications thereof |
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US15/097,610 Division US20160229707A1 (en) | 2011-09-26 | 2016-04-13 | Water purification compositions of magnesium oxide and applications thereof |
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EP (1) | EP2744756A4 (en) |
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CN105344332A (en) * | 2015-11-04 | 2016-02-24 | 苏州书瑞环保科技有限公司 | Water treatment arsenic adsorption material and preparation method thereof |
WO2020007869A1 (en) * | 2018-07-02 | 2020-01-09 | Lhoist Recherche Et Développement S.A. | Formed body based on magnesium oxide and calcium carbonate and method for its preparation |
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CN104039711B (en) * | 2011-09-26 | 2017-03-29 | 霍尼韦尔国际公司 | Water purification composition containing magnesia and its application |
CN105621571B (en) * | 2016-02-03 | 2019-01-04 | 北京家美科技有限公司 | The sponge of dephosphorization denitrification is used in sewage treatment process |
CN105883999A (en) * | 2016-04-26 | 2016-08-24 | 大连汇新钛设备开发有限公司 | Calcium oxide sustained-release block for regulating pH value of recirculating aquaculture system and preparation method of calcium oxide sustained-release block for regulating pH value of recirculating aquaculture system |
CN107055635A (en) * | 2017-02-16 | 2017-08-18 | 河南教育学院 | It is a kind of to increase the clean reagent in drinking water of dearsenification defluorination effect |
CN110038616A (en) * | 2019-04-23 | 2019-07-23 | 襄阳先创环保科技有限公司 | A kind of municipal sewage treatment agent |
CN113842871B (en) * | 2021-10-19 | 2022-05-31 | 山东建筑大学 | Preparation method of anti-interference defluorination adsorbent |
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WO2020007869A1 (en) * | 2018-07-02 | 2020-01-09 | Lhoist Recherche Et Développement S.A. | Formed body based on magnesium oxide and calcium carbonate and method for its preparation |
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AU2019204568A1 (en) | 2019-07-18 |
CN104039711B (en) | 2017-03-29 |
US20160229707A1 (en) | 2016-08-11 |
MX361835B (en) | 2018-12-18 |
AU2012317175A1 (en) | 2014-04-10 |
AU2017206276A1 (en) | 2017-08-10 |
US20140374650A1 (en) | 2014-12-25 |
CN104039711A (en) | 2014-09-10 |
CN107029662A (en) | 2017-08-11 |
CN106976925A (en) | 2017-07-25 |
US20200002188A1 (en) | 2020-01-02 |
MX2014003589A (en) | 2015-01-16 |
US9422169B2 (en) | 2016-08-23 |
EP2744756A4 (en) | 2015-07-15 |
ZA201402153B (en) | 2016-01-27 |
EP2744756A1 (en) | 2014-06-25 |
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