WO2013043882A1

WO2013043882A1 - Low thermal transmission building material

Info

Publication number: WO2013043882A1
Application number: PCT/US2012/056356
Authority: WO
Inventors: Susnata Samanta; Hubert Francis
Original assignee: Georgia-Pacific Gypsum Llc
Priority date: 2011-09-23
Filing date: 2012-09-20
Publication date: 2013-03-28
Also published as: US20130074737A1; EP2758354A1; AU2012312313A1; US8691007B2; CA2849492A1; AU2012312313B2

Abstract

A wallboard, a method of preparing a wallboard, and a method of making a gypsum slurry to prepare a wallboard are provided. The wallboard includes a set gypsum dihydrate derived substantially from a non-fibrous form of calcium sulfate and selected from the group consisting of anhydrous gypsum and gypsum hemihydrate. The wallboard also includes an aerogel dispersed in the gypsum dihydrate.

Description

LOW THERMAL TRANSMISSION BUILDING MATERIAL

CROSS REFERENCE TO RELATED APPLICATIONS [0001} This application claims priority to U.S. Provisional Patent Application No. 61 /538,660 filed on September 23, 20 ) 1 and to U.S. Provisional Patent Application No. 61/550,714 filed on October 24, 201 1 , the disclosures of which are incorporated in full herein by reference, TECHNICAL FIELD

[Θ002] A gypsum composition is described. More particularly, the gypsum composition comprises a low density component and may he used in waliboards to reduce thermal conductivity, decrease weight, and improve ftre performance. BACKGROUND

[0003 j Various products containing the naturally-occurring mineral, gypsum, have been developed for the building trades. Especially notable are various gypsum walSboard products, e.g., sheet materials typically faced with material such as paper, non-woven glass fiber, or the like. In producing gypsum building products, calcined gypsum, i.e., anhydrous or hemihydrate (CaSO^HI-LO), known also as stucco, plaster of Paris, molding plaster, building plaster, and the like, typically in a slurry, is cast, molded, and dried. During the course of this process, the calcined gypsum is further hydra ted,- yielding hydra ted gypsum (CaSOv 2¾0). [Θ004] Gypsum building materials generally are held i high regard for use in fire-resistant construction. The spread of fire and the penetration, of .flame through set gypsum structures are delayed, because impinging heat initially operates to reverse the hydration reaction, recalcmmg gypsum, and liberatin water. The liberated water is an additional energy sink, absorbing its beat of vaporization. Although gypsum doesn't burn, it shrinks and cracks when heated in a flame.

[0005} Although conventional gypsum may be fire resistant, gypsum with greater fire resistance properties and lower thermal conducti vity is desirable. SUMMARY OF INVENTION

[0006) la one aspect; a waliboard is provided. The waliboard includes a set gypsum dihydrate derived substantially from a non-fibrous form of calcium sulfate. The calcium 5 sulfate is selected from the group consisting of anhydrous gypsum and gypsum hemihydrate.

The wailboard further includes an aerogel dispersed in the set gypsum hydrate.

jOOuTj in another aspect, a method of preparing a waliboard is provided. The method includes forming a slurr composition. The slurry composition includes a gypsum dihydrate derived substantially from a non-fibrous form of calcium sulfate and selected from the group

10 consisting of anhydrous gypsum and gypsum hemihydrate. The slurry composition also includes an aerogel dispersed in the gypsum dihydrate. The slurry is applied to a lower facing material to form a core layer and an upper lacing material is applied to an upper surface of the core layer. The core layer and the upper and lower facing materials are sufficiently heated to dry the core layer and to dry the upper and lower facing materials, thus forming the

I S wailboard.

[0008] In yet another aspect, a method of making a gypsum slurr is provided. The method includes mixing water, a non-fibrous form of calcium sulfate selected from the group consisting of anhydrous gypsum .and gypsum hemihydrate, and an aerogel to form the gypsum slurry.

20 j^'O0O9^'j Additional aspects will be set forth in part, in the description that .follows, and in part will be obvious from the description, or may be learned by practice of the aspects described below. The advantages described below will be realized and attained by means of the elements and combinations particularly pointed out in the appended claims, it is to be understood that both the foregoing general description and the following detailed description

25 are exemplary and explanatory only and are not restrictive.

BRIEF .DESCRIPTION OF DRAWINGS

[Θ010} These and other features, aspects, and advantages of the present invention will become better understood when the following detailed description is read with reference to 30 the accompanying drawings., wherein; [ΘΟί ί ] FIG. 1 is a graph, of temperature (°F) vs. time (mm.\ as measured from the non- exposed sides of gypsum waiiboards exposed to a muffle furnace, in accordance with embodiments of the present disclosure.

{_.0012] FIG . 2 is another graph of temperature (°F) vs. time (min.), as measured from the non-exposed sides of gypsum waiiboards exposed to a muffle furnace, in accordance with embodiments of the present disclosure,

DETAILED DESCRIPTION OF INVENTION

[0013) In the following description, numerous specific details are given to provide a thorough understanding of embodiments. The embodiments can be practiced without one or more of die specific details, or with other methods, components, materials, etc. In other instances, well-known structures, materials, or operations are not shown or described in detail to avoid obscuring aspects of the embodiments.

J0M4] Reference throughout this specification to "one embodiment ' "an embodiment," or "embodiments" means that a particular feature, structure, or characteristic described in connection with the embodiment is included in at least one embodiment. Thus, the appearances of the phrases "in one embodiment" or "in an embodiment" in various places throughout this specification are not necessarily all referrin to the same embodiment, f urthermore, the particular features, structures, or characteristics may be combined in. any suitable manner in one or more embodiments.

J0015 The term "parts" is used to define quantitative amounts. The term is intended to define parts by weight unless indicated to the contrary. The term "(w w)^** means weight percent.

Gypsum Compos; t ions

[0016) An essentia! constituent comprising the products of the present disclosur is calcium sulfate dihydrate. This constituent is derived from the hydration of any form of calcium sulfate which is in non-fibrous form and which is capable of reacting with water for form set gypsum, that is, calcium sulfate dihydrate. Thus, the calcium sulfate may be in anhydrous form or in the hemihydrate form. The hemihydrate may be produced from the naturaily- occurring gypsum material by heating, or calcining, the dihydrate. As used herein, the hemihydrate form of gypsum may be referred to as "st ucco."

[0017) Another essential constituent comprising the products of the present disclosure is water. Water is added to the process to hydrate the stucco and to provide fluidity. Water may be added to form the calcium sulfate dihydrate in amounts in the range of about 30 parts per 100 parts of stucco to about 90 parts per 1 0 parts of stucco,

[0038} In some embodiments of the present disclosure, a gypsum composition is provided. The gypsum composition may comprise a gypsum dibydrate derived substantially from a non-fibrous form of calcium sulfate selected from the group consisting of anhy drous gypsum arid gypsum heroihydrate (i.e.. stucco). The gypsum composition may further compose an aerogel dispersed i the gypsum dibydrate.

10819} Aerogels describe a class of material based upon their structure, namely low density, open cell structures, large surface areas, and nanometer scale pore sizes. For instance, low density aerogels based on silica are excellent insulators, with thermal conductivities of about 14 mSV/m- and below at 100 °F and at atmospheric pressure. Aerogels junction as thermal insulators primarily by minimising conduction, convection, and radiation.

[Θ020] In some embodiments, the aerogel may be dispersed substantially throughout the gypsum dibydrate. In other embodiments, the aerogel may be dispersed homogenously in the gypsum dihydrate.

10821 ) In some embodiments, the aerogel may comprise a carbon aerogel. In some embodiments, the carbon aerogel may comprise, for instance, a cured phenolic aerogel, a cured resorcinol formaldehyde aerogel, and the like. In some embodiments, the carbon aerogel is characterized as having a particle size in the range from about 5 microns to about 4000 microns, from about 5 microns to about 1200 microns, .from about 5 microns to about 500 microns, from about. 5 microns to about 15 micron, o from about 5 microns to about .1 microns,

[0822} In some embodiments, the aerogel may comprise a silica aerogel, in some embodiments, the silica aerogel may comprise a Cryoge!™ and/or Pyrogel™ material (Pacor, Inc., Cinnaminson, NJ). in some embodiments, the silica aerogel is characterized as having a particle siz in the range from about 5 microns to about 4000 microns, from about 5 microns to aboui 1200 microns, from about 5 microns io about 500 microns, from about 5 microns to about. 15 microns, or from about 5 microns to about 10 microns.

[0823} In. embodiments, the aerogel may be present in the gypsum composition in an amount from about 0.1% to about 25% (w/w), about 0.1% to about 20% (w/w), about 0,1% to about 15% (w/w), about 0.1 % to aboui 10% (w/w), aboui 0.1% to about 5% (w/w), about 0.5% to about 4% (w/w), about 0.5% to about 3% (w w), about 0.5% to about 2% (w/w), about 0.5% to about 1 % (w/w), or about 0, 1% to about 0,5% (w/w) of the gypsum composition.

[ΘΘ24] In still, other embodiments, the gypsum composition may further comprise a surfactant. The surfactant may be an ionic surfactan or a non-ionic surfactant in some embodiments, the surfactant may be Hyonicf* PFM 10, PFM 15, and/or PFM 33 (Geo Specialty Chemical, Lafayette, IN), in. embodiments, the surfactant may be present in the gypsum composition in an amount from about 0.1 % to about 2% (w/w), 0.1% to about 1 % (w/^' ), or about 0.1 % to about 0.5% (w/w) of the gypsum composition.

[0025) While clay is naturally found in stucco, it may also be added to gypsum compositions. For instance, clay may be added to improve the flame ref.arda.ncy of gypsum products. Suitable clay includes smectite, bentonite, ilUte, kaolimte, vernticulite, raontmorillonite, hectorite, and the like, and mixtures thereof In some embodiments, cla may be present in an amount within the range of about 0.01 wt% to about 10 wt%, from about 0.05 wt% to about 5 wt%, or from about 0.1 wt% to about 2.0 wt.% of the gypsum composition.

[0026] In some embodiments, a method of making a gypsum composition is pro vided. The method comprises mixing water, a non-fibrous form of calcium sulfate selected from the group consisting of anhydrous gypsum and gypsum hemihydrafe, and an aerogel to form a slurry. In some embodiments, the aerogel may be dispersed substantially throughout the slurry. In other embodiments, the aerogel may be dispersed homogeneously in the slurry.

[0027J In some embodiments, the method of making the gypsum composition comprises dry blending the calcium sulfate with the aerogel before the addition of water to form the slurry. In some embodiments, the step of dry blending the calcium sulfate with the aerogel may further comprise the use of a surfactant to facilitate the coating of the calcium sulfate onto the aerogel particles.

(0028] Water is used i n the preparation of the sl urry . Water may be obtained from a variety of sources including but not limited to tap water, distilled water, purified water, rain water, and the like. In some embodiments, the weight ratio of water to calcium sulfate that is used to prepare the slurry in the in range of about. 0.5 to about 4.0, about 0.5 to about 3.0, about 0.5 to about 2.0, about 0.5 to about 1 .5, about 0.5 to about 1 .2, or about 0.5 to about 1.0,

[ΘΘ29) In some embodiments, the method of making the gypsum composition may further comprise castin a product from the slurry, heating the product, and then drying the product. Irs some embodiments, the product may be a waliboard. {0030] In some embodiments, (he aerogel used in the method of making the gypsum composition may comprise a silica aerogel. In some embodiments, the walJboard formed from the method of making the gypsum composition may be characterized a ha ving a weight of less than about 3800 pounds per msf iess than about 2100 pounds per msf, or less than about 1800 pounds per msf. As used herein, the term ''msf means 1000 square feet.

(60311 Additionally, the gypsum composition, made according to the disclosed methods of making the gypsum composition, may include any of the parameters listed above for the gypsum compositions .

G y psuro Wa I lboar ds

(6032) The gypsum compositions described above may be incorporated into gypsum wallboards. In some embodiments, a wall board is provided. The wallboard comprises a set gypsum dihydrate derived from substantially a non-fibrous form of calcium sulfate selected from the group consisting of anhydrous gypsum and gypsum hemihydrate. The wallboard further comprises an aerogel dispersed in the set gypsum dihydrate core.

[Θ933] hi some embodiments, the aerogel may be dispersed substantially throughout the set gypsum dihydrate. In other embodiments, the aerogel may be dispersed homogenous! y in the set gypsum dihydrate.

[0034] in some embodiments, the aerogel may comprise a carbon aerogel. In some embodiments, the carbon aerogel may comprise, for instance, a cured phenolic aerogel, a cured resorcino! formaldehyde aerogel, and the like. In some embodiments, the carbon aerogel is characterized as having a panicle size in the range from about 5 microns to about 4000 microns, from about 5 microns to about 1200 microns, from about 5 microns to about 500 microns, from about 5 microns to about 1 5 microns, or from about 5 microns to about 10 ^"microns.

(0935] in some embodiments, the aerogel may comprise a silica aerogel, in some embodiments, the silica aerogel may comprise a Cryogel™ and/or Pyrogel^m material (Pacor, Inc., Cinna ninson, NJ). in some embodiments, the silica aerogel is characterized as having a particle size in the range from about 5 microns to about 4000 microns, from about 5 microns to about {200 microns, from about 5 microns to about 500 microns, from about 5 microns to about 15 microns, or front about 5 microns to about 10 microns.

[0936) In embodiments, the aerogel may be present i the gypsum composition in an amount from, about 0.1% to about. 25% (w/w), about 0.1 % to about. 20% (w/w), about 0.1% to about .15% (w w), about 0. 1% to about 10% (w/w), about 0.1 % to about 5% (w w), about 0,5% to about 4% (w/w), about 0.5% to about 3% (w/w), about 0.5% to aboal 2% (w/w), about 0.5% to about 1% (w/w), or about 0.1% to about 0.5% (w/w) of the gypsum composition.

[0037] in still other embodiments, the set gypsum dihydrate may further comprise a surfactant The surfactant may be an ionic surfactant or a non-ionic surfactant. In some embodiments, the surfactant may be Hyonic® PFM 10, PFM 15, and/or PFM 33 (Geo Specialty Chemical. Lafayette, IN), in embodiments, the surfactant may be present irt the gypsum composition in an amount from about 0.1 % to about 2% (w/w), 0.1 % to about 1% (w/w), or about 0.1% to abou t 0.5% (w/w) of the set gypsum dihydrate.

[01138] While clay is naturally found in stucco, it. may also be added, to the set gypsum dihydrate. For instance, clays may be added to improve the flame retardancy of gypsum, products. Suitable clay includes smectite, bentonite, il^' te, kaolinile, ver iculiie, moirtmoiillonite, heeterite, and the like, and mixtures thereof, in some embodiments, clay is present in an amount within the range of about. 0. 1 wt% to about 10 wt%, from about 0.05 wi.% to about 5 wt%, or from about 0.1 wt% to about 2.0 wt% of the set gypsum dihydrate. [Θ039| Also considered as falling within the scope of the present disclosure are the presence of any of the following additives which are commonly used in the manufacture of gypsum based building materials: polymeric binders, dispersants, set retarders, set accelerators, foaming agents, defoamers, biocides, paper fibers, particulate fillers and aggregates, water reducers and dispersants., starch and facing papers, and fire resistance additives.

[0040] Exemplary polymeric binders include acrylic latexes and other vinyl homopolyrners and copolymers, including polyvinyl acetate and a copolymer of vinyl acetate with another vinyl monomer such as ethylene.

[00411 Set accelerators may enhance the setting reaction of the gypsum compositions. Suitable accelerators include, for example, potassium sulfate, finel ground gypsum, CaCl- , NajCC , NaOH, CaO, CafOHh, and the like. Set accelerators may be present in the gypsum core in an amount from about 0.000 i wt% to about .1 wt% based on the stucco weight of the composition.

[0042} Set reorders may be used to slightly delay the setting reactions until after the stucco/water slurry has been formed into a sheet. Suitable retarders may include, for example, sodium citrate, sodium phosphate, proteins, and the like. Another class of set retarders that may be used comprises divalent or trivalent metal compounds, including but not limited to magnesium oxide, zinc oxide, calcium carbonate, magnesium carbonate, zinc sulfate, zinc stearate, and combinations thereof. Set retarders may be present in the gypsum core in an amount from about 0.0001 t% to about 0.001 wt% or from about 0.0005 wt% to about 0.0008 wt% based on die stucco weight of the composition.

[0043] Exemplary foaming agents may include various soaps. The foaming agents, when present, may be used in an amount from about 0.0001 wt% to about i wl% based on the stucco weight in the composition.

[0044] Biocides, i.e. for mold and mildew resistance, may also be present in amounts known to be effective. Exemplar)'^' biocides include zinc thiocarbamates and the like. The biocide, when present, may be used in an amount from, about 0.0001 wt% to 1 wt% based on the stucco weigji.t in the composition.

|0045] Various fillers may also be present, such as cenospheres (hollow ceramic microspheres), diatomite, woUastonite, ground rice hulls, ground perlite, chopped glass fibers, or the like. These and other fillers may be used to provide additional benefits. For example, calcium carbonates or alumina hydrates may improve sandahiliiy and flexibility. The acoustic/thermal insulation properties may be improved by adding rubber particles, vermiculite, periite, and shredded or expanded polystyrene. Fly ash, colloidal silica, fumed silica, and colloidal alumina may also be used. Fly ash is defined as solid powders having a chemical composition similar to or the same as the composition of material that is produced during combustion of powdered coal, i.e., 25 wt% to 60 wt% silica, 10 wt% to 30 wt% aluminum oxide, 5 wt% to 25 wt% iron oxide, 0 wt to 20 wt calcium oxide, and 0 wt% to 5 wt% magnesium oxide. Filler, when present, may be used, in an amount from about 1 wi% to about 30 wt%, about 5 wt% to about 30 wt%, about 1 wt to about 25 wt%, or about 15 to about 20 wt% based on the weight of the stucco in the composition,

[0046] Water reducers may also be used and may also be referred to as dispersants. As used herein, the term "water reducer" means a substance which is generally used in. gypsum to improve the flo properties so that the gypsum slurries may be pumped or effectively poured. The water reducers, also commonly referred to as superplastici/ers, may be used to make gypsum compositions with reduced water content which still retain adequate flow properties. Examples of suitable water reducers for use in this disclosure include, for example, lignosulfonates, sodium naphthalene sulfonate formaldehyde condensates, napthalene sulfonate, polycarboxylates, and the like. The dispersant, when present, may be used in an amount of abou O.OOO i wt% to about 1 .0 wt%, about 0.1 wl% to about 0.7 wt%, or about 0.1 wt% to about 0.4 wt% based on the stucco weight of the composition. {0047] Defoamers may be added to board edges to create denser strong regions for handling.

10048] Exemplary fire resistance additives include but are not limited to perlite, vermicuhte, and boric acid. Additional fire retardants may include mineral oxides, mineral hydroxides, clays, metal oxides, metal hydroxides, and metal carbonates such as niagnesite. The fire retardant, when present, may be in an amount from about 5 wt% to about 30 wi%, about 10 wt% to about 25 wt%, or about 15 wt% io about 20 t% based on the tola! weight of the stucco in the composition.

[0049) Wallboards for interior use ma contain wax or a wax emulsion as an additive to improve water resistance of the gypsum core. The disclosure is not limited thereby, however, and examples of other materials which have been reported as being effective for improving the water-resistant properties of gypsum products include the following; poiyi vin l alcohol), with or without a minor amount of polyvinyl acetate); metallic resmates; wax or asphalt or mixtures thereof sometimes as an emulsion; a mixture of wax and/or asphalt and also cornflower and potassium permanganate; water insoluble thermoplastics such as petroleum and natural asphalt, coal tar, and thermoplastic synthetic resins such as poiyi vinyl acetate), poly (vinyl chloride), and a copoiymer of vinyl acelate and vinyl, chloride and acrylic resins; a mixture of metal rosin soap, a water soluble alkaline earth metal salt, and residual fuel oil; a mixture of petroleum wax in the form of an emulsion and either residual fuel oil, pine tar or coal tar; a mixture comprising residual fuel oil and rosin; aromatic isocyauates and diisocyanates; organohydorgenpolysiloxanes; siliconates; a was emulsion and a wa -asphalt emulsion each with or without such materials as potassium sulfate, alkali and. alkaline earth aluminates, and Portland cement; a wax-asphalt emulsion prepared by adding to a blend of molten wax and asphalt an oil-soluble, water dispersing emulsifying agent, and admixing the aforementioned solution of casein which contains, as a dispersing agent, an alkali sulfonate of a po!yarylmethylene condensation product. Mixtures of these additives may also be used. }0050| Species of wax emulsions and wax-asphalt emulsions used to improve wallboard water resistance are commercially available. The wax portion of these emulsions may preferably be a paraffin or microcrystaJIme wax, but other waxes may also be used. The total amount of wax and wax-asphalt in the aqueous emulsions may generally comprise about 50 wt% to about 60 wt% of the aqueous emulsion. In the case of wax-asphalt emulsions, the weight ratio of asphalt to wax may vary from about. 1 to about i or from about 1.0 to about 1 . The amount of wax emulsion used to provide water resistant characteristics to the gypsum core may be within the range of about 3 wt% to about 10 wt% or about 5 wt% to about 7 wl%₅ based on the total weight of the ingredients of the composition from which the set gypsum core is made, the ingredients including the water of the wax or wax-asphalt emulsion, but not including additional amounts of water that are added to the gypsum composition for forming an aqueous slurry thereof.

10651] As used herein, the term ""facing materia!" may comprise facing papers, non-woven glass fibers, and other suitable materials for forming a layer over a gypsum core.

[0052} When the end product to be manufactured is wallboard, facing papers, or other facing materials such as non-woven glass fibers may be used to cover the two exterior faces of the gypsum slum-' or core. In. practice, specially selected paper is used to confer the appropriate appearance and strength to the wallboard. A starch binder for adhering the facing paper to the gypsum slurry may also be used.

}0053J In some embodiments, an additi e may be used to promote the adhesion between the set gypsum core and the adjacent facing raaterial(s). In. some embodiments, starch may be used to promote adhesion. In still other embodiments, polyvinyl alcohol, may be used as a binder,

[0054} The paper backing used in making the gypsum wallboard may be made up of any type of thick paper or paperboard material such as, for example, unbleached Kraft paperboard, recycled paperboard, semichemicai paperboard, or solid bleached paperboard. Typically, this thick paper or paperboard may have a thickness of about 0.010 inches ( 10 mils), about 0.012 inches (.12 mils), about 0.014 inches (1.4 mils), about 0.016 inches ( 16 mils), or about 0,020 inches (20 mils). The use of multi-ply paper may also be possible. Multi-ply paper used for the feeing sheet of gypsum board products typically has a basis weight from about 50 pounds per 1000 square feet to about 60 pounds per 1000 square feet, an overall caliper of about. 250 microns to abou 350 microns, and a Gurley porosity from about 15 seconds to about 145 seconds. Often, different types of paper are used for each gypsum board surface. For example, raantia paper is frequently used on one side, while .news liner is used on the opposite side. Paper and cardboard facing materials are normally made from recycled fibers (e.g., used corrugated paper, kraft cuttings, or waste newsprint), but they also may be partially or wholly made from virgin fibers. Other natural or synthetic fibrous materials may be used, including those derived from metals or glass (e.g., fiberglass mat, chopped or continuous strand mat, or glass roving, both woven and non-woven). Other useful materials for the facing sheets include filament forming synthetic organic polymers (e.g., nylon, polyesters, polypropylene, polyethylene, rayon, and cellulosics), ceramics, cotton, cloth, hair, felt, arid the like. Multiple layers of fibrous materials, for a composite sheet of a glass mat and feraft paper, may also be used.

10055] When a fibrous mat is used for either or both facing materials, the mat preferably is coated to make it resistant to moisture. Such a. coating should be sufficiently porous, however, to permit water in the aqueous gypsum slurry from which the gypsum core is made to evaporate during manufacture of the board. Fibrous mats should also contain material thai is capable of forming a strong bond with, th set gypsum comprising the core of the gypsum board.

j_.0056] Examples of such fibrous materials include (1.) a mineral-type material such, as glass fibers; (2) synthetic resi fibers; and (3) mixtures of such fibers. The mat may comprise continuous or discrete strands or fibers may be woven or non oven in form. Nonwoven mats such as made from chopped strands and continuous strands may be used. The strands of such mats typically are bonded together to form a unitary structure by a suitable adhesive. The fiber mat can range in thickness, from about 10 mils to about 40 rails, about 15 mils to about 35 mils, or from about 20 mils to about 30 mils.

[0057] The fibrous mats may be a pre-coated glass fiber mat, wherein the outer surface of the mat is coated with a coating that comprises a mixture of predominantly a mineral pigment, an inorganic hinder, and a latex polymer binder.

J0058] A mineral pigment may be a component of the coating composition. Examples of mineral pigments suitable for making the coated mats include, but are not limited to, ground limestone, clay, sand, mica, talc, gypsum, aluminum trihydrate, antimony oxide, or a combination of two or more of these substances.

[0059] The inorganic binder may be an inorganic compound such as calcium oxide, calcium silicate, calcium sulfate, magnesium oxychloride, magnesium oxysuHate, or aluminum hydroxide. Alternatively, the .inorganic binder may be an inherent component in the mineral pigment component as in the case wherein the mineral pigment, includes aluminum trihydrate. calcium carbonate, calcium sulfate, magnesium oxide, or some clays and sands. [Θ060] In some embodiments, a. method of preparing a wallboard is also provided. The method comprises forming a slurry comprising a gypsum dihydrate derived substantially from a non-fibrous .form of calcium sulfate selected from the group consisting of anhydrous gypsum and gypsum hemihydrate. The slurry further comprises an aerogel that is dispersed in the gypsum dihydrate. The slurry is mixed and is then, applied to a lower facing material to

I I form a core layer. An upper facing material is then applied to an upper face of tire core layer, and the core layer and the upper and lower facing materials are heated sufficiently to dry ihe core layer and the upper and lower facing materials to form the wallboard. The method of preparing a wailboard may also include the use of any of the additional components described¹ above for wallboards. Additionally, the method of preparin a waliboard may also incorpora te any of the above-listed parameters for gypsum, cores of wallboards, including but not limited to the use of aerogels and/or surfactants.

[θί ϊΙ j As used herein, the term "core layer" means a layer of slurry that has been or will be sandwiched between an upper and a lower lacing material.

θί½2 j In an exemplary continuous manufacturing process, two reels of facing maierial are simultaneously unwound. One reel: of a lower facing maierial. unwinds below the mixer that forms the slurry, such that the slurry is applied to this material An u per lacing material from a second reel is then brought into contact with the slurry from above, thereby sandwiching the slurry. The "sandwich" of slurry and adjacent facing materials is then passed through a mold or other forming device for establishing the thickness of the gypsum board. The slurry is then allowed to set and form the gypsum core by hydration of the stucco. During mis setting process, the core hardens as the gypsum mineral (calcium sulfate dihydraie) is formed.

[0063] in another embodiment, a relatively thin layer of slurry comprising stucco and an aerogel may be applied to ihe first side of the iower face and/or the first side of ihe upper face. These thin layers of slurry may be made to have a higher density by reducing the water to stucco ratio or fay eliminating the foam, component from a slurry, in an exemplary continuous manufacturing process, two reels of facing material are simultaneously unwound. A relatively thin layer of slurry comprising stucco and an aerogel is applied to the first side of a lower facing material as it unwinds ahead of the mixer. The lower face which contains a relatively thin layer of slurry continues below the mixer that forms the slurry, such that another slurry which does not contain an aerogel or contains a reduced amount of an aerogel is applied onto this thin layer. An additional ihin layer of slurry comprising stucco and an aerogel can then be applied to the first side of the upper facing material from a second reel . The upper face which contains a relatively thin layer of slurry is then brought into contact with the slurr from above, thereby sandwiching the slurry. The "sandwich" of slurry and adjacent feeing materials containing a thin layer of slurry is then passed through a mold or other forming device for establishing the thickness of the wailboard. The slurry is then allowed to set and form the gypsum core by hydration of the stucco. During this setting process, the core hardens as the gypsum materia! (calcium sulfate dihydrate) is formed.

[0064] In another embodiment, a relatively thin layer of slurry comprising stucco and an aerogel may be applied to the first side of the lower face and/or the first side of the upper face. These thin layers of slurry may be made to have a. higher density by reducing the water to stucco ratio. In an exemplary continuous manufacturing process, two reels of facing material are simultaneousl unwound. A .relatively lain, layer of slurry comprising stucco and an aerogel is applied to the first side of a lower facing material as it unwinds ahead of the mixer. The lower lace which contains a relatively thin layer of slurry continues below the mixer that ^"forms the slurry, such that another slurry which compri ses stucco and an aerogel is applied, onto this thin layer. An additional thin layer of slurry comprising stucco, and an aerogel can then be applied to the first side of the upper lacing material from a second reel. The upper face which contains a relatively thin layer of slurry is then brought into contact with the slurry from above, thereby sandwiching the slurry. The "sandwich" of slurry and adjacent facing materials containing a thin layer of slurry is then pass through a mold or other forming device for establishing the thickness of the waliboard. The slurry is then allowed to set and form the gypsum core by hydration of the stucco. During this setting process, the core hardens as the gypsum material (calcium, sulfate dihydrate) is formed.

JO Sj As used herein, the term "slate coat" refers to the relatively thin, layer of slurry comprising stucco and an aerogel and further having a higher density as compared with the density of the remainder of the slurry that forms the gypsum core. As described above, one or more slate coats may be applied to a gypsum core. In some embodiments, the slate coats may be applied to opposite sides or faces of the gypsum core. In still other embodiments, one or more slate coals may be applied to a single side or face of a gypsum core. In still other embodiments, one or more slate coats may ^'be applied to each opposite side or face of the gypsum core.

[0066! The slurry generally contains more water than necessary solely to reconstitute the gypsum from the stucco. This extra water is used in the board forming stage to reduce the stucco slurry viscosity sufficiently to allow for its even distribution (e.g., by using a forming roll) across and between the facing sheets at a desired thickness. As a result of the used of excess water, the gypsum board remains wet after hydration. Therefore, the formed board is usually dried. {0067] The drying operation typically involves applying heat by circulating hot air (e.g., a drying oven) around the wet gypsum board to evaporate the excess water, it is necessary, therefore, that the facing sheet materials be sufficiently porous to allow this excess water to readily evaporate without adverse effects such as delamination, tearing, bursting, etc. of the facing sheet ^'materials. The ability of the facing sheet materials to easily allow the escape of water vapor also promotes a uniform, degree of dryness. This improves overall board quality, since insufficiently dried gypsum board presents storage problems, while overdrymg leads to calcination and causes loss of mechanical strength. Typical drying conditions involve maintaining an ambient or surrounding hot air temperature from about 200 °F to about 600 ^CF or from, about. 250 °F to about 500 *F, for a drying time from about 10 minutes to about. 2 hours, irom about. 30 minutes to .1 hour, or j om. about 30 minutes to 45 minutes, and with a line speed from about 70 feet/minute to about 250 feet/minute or irom about 100 feet mimite to about 200 feet'minuie.

Examples

Gypsum_.C mpos_.tipns

[Θ068] Gypsum compositions comprising silica aerogels were prepared with the formulations as defined in Table I. All of the formulations were prepared using stucco (calcium sulfate hemihydrate; CaSC HiO). A control, gypsum composition (Formulation 1) did not contain silica aerogels. The stucco was obtained from Georgia Pacific LLC (Atlanta, GA), The silica aerogels were obtained from Cabot Corporation (Boston, MA).

TABLE I

_.Wallboard _.Preparation

[0069] To prepare the gypsum compositions, commercially available aerogels were dry blended with stucco according to one of two methods. {0070] Method One, An appropriate amount of stucco and an appropriate amount of aerogel were dry blended in a Hobert mixer (KitchenAid®, Si. Joseph, ΜΪ) until a significant amount of the aerogel component was observed to be physically coated on the stucco particles.

J_.0 71J Method Two, An appropriate amount of stucco and an appropriate amount of aerogel were combined with 0.1 wt% - 0.5 wt% of a surfactant (Hyonic# PFM 15; Geo Specialty Chemical, Lafayette, IN). The combination was then dry biended m a Hobert mixer until a significant amount of the aerogel component wa observed to be physicaily coated on the stucco particles.

[00721 Aerogel blended stucco, obtained from either method one or method two, was mixed with water at different water to stucco ratios (see Table I). After two minutes of stirring, the water stucco slurry was poured into a 4 inch x 4 inch mold having a 0.5 inch thickness. The samples were removed from the mold after 30 minutes, permitted to cool, to ambient temperature, and then dried in an oven at 1 10 °F until no further weight loss was observed. The samples were then cooled to ambient temperature under controlled humidity conditions.

[Θ073] Each sample was subsequently tested for fire performance using a muffle furnace test. The samples were each placed directly hieing the muffle furnace, completely covering the opening of the muffle furnace heating chamber. One surface of each sample was exposed to a temperature of 1 00 ^t;F and the thermal transmission of the sample was evaluated by .measuring the change in temperature on the other (non-exposed) side of the sample using a thermocouple. The temperature change as a function of time was then plotted for each sample. The complete data is presented in FIGS, 1 -2 and summarized in ^'Fable Π.

TABLE 11

{0074] As can be seen from the data in TABLE Π, the inclosion of silica aerogels into the core of gypsum wallboards significantly reduced the thermal transmission through ihe gypsum wallboard. Additionally, it should be noted that gypsum wallboards that were considerably lighter than the control gypsum wallboard were also able to provide a reduced thermal trail amission.

(6075] The data was normalized as .follows: Four inch by four inch wallboard. samples wiih a one-half inch thickness were prepared. The weight of each wallboard sample was measured . Using this measurement, a calculated weight for each wallboard sample was obtained with, a thickness of 0.625 inches and the same square dimensions. From this, the .1000 square foot (MSF) board weight was calculated, as presented in TABLE 11.

10076] it should he apparent tha the foregoing relates only to the preferred embodiments of the present invention and that numerous changes and modifications may be made herein without departing from the spirit and the scope of the invention as defined by the following claims and equivalents thereof.

Claims

1. A wallboard comprising:

a set gypsum dihydrate, the set gypsum dihydraie derived substantially from a oo«- fibrous form of calc um sulfate selected from the group consisting of anhydrous gypsum and gypsum .hemihydrate; and

art aerogel dispersed in the set gypsum dihydrate.

2. The wallboard of any one of claims i , wherein, the aerogel comprises a. carbon aerogel. or a silica aerogel.

3. The wallboard of claim 1 , wherein the aerogel is characterised as having a particle size in the range from 5 microns to 4000 microns,

4. The wallboard of claim L wherein the aerogel is present in. the wallboard in an amount from 0.5% to 4% (w/w) of the set gypsum dihydrate,

5. The wallboard of claim 1 , further comprising a surfactant, wherein the surfactant is present in the wallboard in an amount from 0.1% to 1% (w/w ) of the gypsu m dihydrate.

6. A method of preparing a wallboard comprising:

forming a slurr comprising

a gypsum dihydrate derived substantially from a non-fibrous form of calcium sulfate and selected from the group consisting of anhydrous gypsum and gypsum

hemihydrate; and

an aerogel dispersed in the gypsum dihydraie;

applying the slurry to a lower facing material to form a core layer;

applying an upper facing material to an upper surface of the core layer; and heating the core layer and the upper and lower facing .materials sufficiently to dry the core layer and the upper and lower facing materials to form the wallboard..

7. The method of claim 6, wherein the aerogel comprises a carbon aerogel or a silica aerogel.

8. The method of claim 6, wherein the aerogel is charac terized as having a particle size in the range from 5 to 4000 microns.

9. The method of claim 6, wherein the aerogel is present in the waliboard in an amount from 0.5% to 4% (w/w) of the set. gypsum dihydrate.

10. The method of claim 6, wherein the slurry further comprises a surfactant.

11. The method of claim 6, wherein a surfactant is present In the waliboard in an amount from 0.1% to 1% (w/w) of the gypsum dihydrate.

12. The method of claim 6, further comprising applying at least one slate coat to a surface of the core layer.

13. A method of making a gypsum slurry, the method comprising mixing water, a non- fibrous form of calcium sulfate selected from the group consisting of anhydrous gypsum and gypsum hemihydrate, arid an aerogel to form the gypsum slurry.

14. The method of claim 13, wherein the aerogel comprises a carbon aerogel or a silica aerogel.

15. The method of claim 13, wherein the calcium sulfate and the aerogel are dry blended before the addition of water to form the gypsum slurry.

16. The method of claim 15, wherein the step of dry blendi ng further comprises adding a surfactant.

17. The method of claim 13, wherein the weight ratio of water to calcium sulfate used to prepare the gypsum slurry is in the range from 0.5 to 2.0.

18. The method of claim 13, further comprising casting a product .from the gypsum slurry, heating the product, and drying the product.

19, The method of claim 18, whereiii the product is a wai!board.

20. The method of claim 1.9.. wherein the wallboard is characterized as .havinst a weieht of less than 2100 pounds per onsf.