WO2013040796A1 - Textile fabric having insect-proofing function and production method thereof - Google Patents

Textile fabric having insect-proofing function and production method thereof Download PDF

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Publication number
WO2013040796A1
WO2013040796A1 PCT/CN2011/080132 CN2011080132W WO2013040796A1 WO 2013040796 A1 WO2013040796 A1 WO 2013040796A1 CN 2011080132 W CN2011080132 W CN 2011080132W WO 2013040796 A1 WO2013040796 A1 WO 2013040796A1
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Prior art keywords
yarn
textile fabric
insecticide
insect
fabric
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PCT/CN2011/080132
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French (fr)
Chinese (zh)
Inventor
杨晓蓉
Original Assignee
Yang Xiaorong
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Publication date
Priority claimed from CN2011102836885A external-priority patent/CN102383258A/en
Priority claimed from CN2011102837017A external-priority patent/CN102444020A/en
Application filed by Yang Xiaorong filed Critical Yang Xiaorong
Publication of WO2013040796A1 publication Critical patent/WO2013040796A1/en

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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/165Ethers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/345Nitriles
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/35Heterocyclic compounds
    • D06M13/352Heterocyclic compounds having five-membered heterocyclic rings
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/35Heterocyclic compounds
    • D06M13/355Heterocyclic compounds having six-membered heterocyclic rings
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402Amides imides, sulfamic acids
    • D06M13/432Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic

Definitions

  • the present invention relates to a textile technique, and more particularly to a textile fabric having an insect control function and a method of producing the same. Background technique
  • mosquitoes can spread diseases, and different types of mosquitoes can spread different diseases. Recently, epidemic diseases such as Japanese encephalitis (called "JE") and dengue fever have been prevalent in parts of China, and the main routes of transmission of these diseases are through mosquitoes.
  • Mosquitoes are a kind of harmful insects that are very common in summer and autumn. The harm to the human body is that they will transmit pathogens to healthy people after they bite a diseased animal or human body.
  • Polyethylene is classified into high density polyethylene (HDPE) and low density polyethylene (LDPE).
  • High-density polyethylene has good water washing performance, and the dry cleaning performance is slightly poor. It must be at a higher temperature and a higher pressure to obtain a better bonding effect. According to these characteristics, it is widely used as a male village.
  • Low-density polyethylene has poor water-washing and dry-cleaning resistance, but it can be bonded at a lower temperature and has a good bonding strength, so it is widely used for temporarily bonding village cloth.
  • Terylene is an important variety in synthetic fibers and is the trade name of polyester fiber in China. It is based on purified terephthalic acid (PTA) or methyl terephthalate. Ester (DMT) and ethylene glycol (EG) are fiber-forming polymers obtained by esterification or transesterification and polycondensation, polyethylene terephthalate (PET), spinning and Post-processed fibers.
  • PTA purified terephthalic acid
  • DMT methyl terephthalate
  • EG ethylene glycol
  • the technical problem solved by the present invention is to provide a textile surface having an insect-repellent function, which has a long-lasting insect repellent function.
  • a textile fabric having an insect-repellent function the textile fabric containing an insecticide. Further, the textile fabric comprises a pharmaceutical yarn, and the insecticide is contained in the pharmaceutical yarn, wherein the ratio of the medicine to the total mass is 1% to 80%, and the high density polyethylene HDPE accounts for the total mass. The ratio is 1% ⁇ 90%, and the ratio of low density polyethylene LDPE to total mass is 1 ⁇ 30%.
  • the medicine comprises a color masterbatch of 1 to 30% by weight, an anti-aging agent of 1-28% by weight, a weight percentage of 1 to 26% of a flame retardant, and a weight percentage 1 ⁇
  • the textile fabric is added to the textile fabric by spraying, coating or soaking the insecticide coating on the outer surface of the polyester yarn, the polyethylene PE yarn or the textile fabric;
  • the medicament comprises cypermethrin, fluorine Cypermethrin, cypermethrin, deltamethrin, etofenproxil, cyhalothrin, chloroether ester, methrin, dextromethrin or methamphetamine in a ratio of 1 to 30 g/kg.
  • the textile fabric comprises a pharmaceutical yarn
  • the insecticide is contained in a pharmaceutical yarn which is prepared by injecting a pesticide into a polyester yarn at a temperature of 100 to 200 ° C.
  • the foam is formed in 1 ⁇ 2 hours
  • the medicament includes cypermethrin, cyfluthrin, cypermethrin, deltamethrin, etofenrin, cyhalothrin, chloroether ester, methrin, dextromethrin or methamphetamine.
  • the addition ratio is 1 ⁇ 30 g / kg.
  • Another technical problem to be solved by the present invention is to provide a method for producing a textile fabric having an insect-repellent function, and the textile fabric has a long-lasting insect repellent function.
  • a method for producing a textile fabric having an insect-repellent function comprising: adding a textile fabric to a medicinal treatment, and the treated textile fabric contains an insecticide.
  • the textile fabric production process includes:
  • Generating a drug yarn mixing the drug yarn into a polyethylene P E yarn containing no drug, and generating a pesticide-containing PE yarn;
  • a polyethylene PE yarn containing the drug yarn and a polyester yarn are blended to form a textile fabric.
  • the insecticide is contained in the PE yarn and the polyester yarn, and the production process includes: immersing the PE yarn and the polyester yarn in the insecticide for 1 to 2 hours, and the temperature is between 100 and 200 °C. Generating a drug yarn;
  • the pharmaceutical yarn is blended with a polyester yarn containing no insecticide to form a textile fabric having an insect-repellent function.
  • the insecticide is contained in the polyester yarn, and the polyethylene PE yarn is free of medicine, and the production process includes:
  • polyester yarn into the insecticide for 1 ⁇ 2 hours, and the temperature is between 100 ⁇ 200 °C to produce the drug yarn;
  • the pharmaceutical yarn and the PE yarn not containing the insecticide are blended to form a textile fabric having an insect-repellent function. Further: attaching the insecticide to the textile fabric by spraying or coating the outer layer of the polyester yarn, the polyethylene PE yarn or the textile fabric, coating the insecticide coating, or directly immersing the textile fabric in the insecticide preparation on.
  • the textile fabric produced by the technical scheme of the invention has the characteristics of soft hand feeling, strong tensile strength and durability, and the textile fabric has long-term deworming function. Since the textile fabric of the present invention is medicated before weaving, and then weaved into a finished product by a blending process, the textile has a soft hand feeling, and in practical application, it can withstand a tensile force of more than 410 KPA, washable more than 20 times, and the mosquito mortality rate still reaches 100%, the service period is more than 5 years; after washing 20 times, the knockdown rate and mortality rate of mosquitoes can reach more than 85%.
  • the textile fabric of the present invention is widely used and can be used as a conventional textile fabric.
  • the technical scheme of the present invention is different from the general anti-mosquito method, and is more convenient to use, clean and environmentally friendly, and has no harm to the human body and is safe to use.
  • the textile fabric produced by the technical scheme of the present invention can effectively knock down and drive out mosquitoes, and the product is safe for users and detergents, and can be widely used in people's lives.
  • Figure 1 is a cross-sectional view showing a textile yarn containing an insecticide in the present invention. Preferred embodiment of the invention
  • the textile fabric having the long-lasting insect repellent function is composed of PE containing insecticide.
  • Yarn and polyester yarns are woven by a blending process, which is warp-knitted and blended; the insect-repellent function is achieved by adding pesticides to PE yarns or polyester yarns.
  • the PE yarn contains 1% ⁇ 80% by weight of insecticide (mosquito repellent), and the insect repellent uses the insecticide recommended by the World Health Organization (World Health Organization), including: cypermethrin, Cyfluthrin, cypermethrin, deltamethrin, cypermethrin, cyhalothrin and chloroether ester.
  • the pyrethroids selected for domestic mosquito repellents include: methrin, dextromethrin and methotrexate.
  • Adding pesticides to textile fabrics can be done in the following three ways:
  • the insecticide is contained in the drug yarn, and the polyester yarn contains no drug;
  • Insecticides are contained in pharmaceutical yarns and polyester yarns;
  • the textile yarn comprises a pharmaceutical yarn 1 1 (which may be a PE yarn or a polyester yarn containing an insecticide) and a polyester yarn 12 containing no medicine, a pharmaceutical yarn 11 and a polyester yarn.
  • the wires 12 are mixed with each other to form a textile yarn.
  • Method 2 The pesticide is contained in the PE yarn and the polyester yarn.
  • the production process is as follows:
  • Insecticides can be selected from: cypermethrin, cyfluthrin, cypermethrin, deltamethrin, etofenproxil, cyhalothrin, chloroether ester, methrin, dextromethrin, methamphate, etc.
  • the addition ratio is 1 ⁇ 30 g / kg.
  • Insecticides may also be selected from deltamethrin 1.8 g/kg or cypermethrin 5.5 g/kg.
  • Method 3 The insecticide is contained in the polyester yarn, and the PE yarn is free of medicine.
  • the production process is as follows:
  • Insecticides can be selected from: cypermethrin, cyfluthrin, cypermethrin, deltamethrin, etofenproxil, cyhalothrin, chloroether ester, methrin, dextromethrin, methamphate, etc.
  • the addition ratio is 1 ⁇ 30 g / kg.
  • Insecticides may also be selected from deltamethrin 1.8 g/kg or cypermethrin 5.5 g/kg.
  • Method 4 Blend the drug yarn 11 with the PE yarn without insecticide to produce a textile fabric with insect-proof function.
  • the insecticide is attached to the textile fabric by spraying or coating the outer layer of the polyester yarn, the PE yarn or the textile fabric with the coating of the insecticidal preparation, or directly immersing the textile fabric in the insecticide preparation.
  • the selection of pesticides refer to method three.
  • the above process is repeated at least 20 times.
  • the sensitive species raised in the laboratory are Aedes albopictus (female) 2 to 5 day old adults.
  • the insecticides in the textile fabric with insect-proof function have a washing resistance of 30 to 35 times and a mosquito mortality rate of more than 100%.
  • the test results show that the textile fabric with insect-proof function of the invention has the characteristics of washing resistance, durability, high mosquito knockdown rate and long duration of action of the insecticide.
  • the textile fabric produced by the technical scheme of the invention has the characteristics of soft hand feeling, strong tensile strength and durability, and the textile fabric has a long-lasting insect repellent function.
  • the textile fabric produced by the technical solution of the present invention can effectively knock down and repel mosquitoes, and the product is safe for users and detergents, and can be widely used in people's lives.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Biochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

Provided is a textile fabric having an insect-proofing function, wherein the textile fabric contains an insecticide. Also provided is a method for producing the textile fabric having an insect-proofing function. The fabric produced by the method has the features of good feel, softness, high tensile strength and durability, and the fabric has a long-term insect-repellent function. As the textile fabric is treated by dosing before knitting and then knitted into fabric by means of a blending or warp knitting process, or the surface of the fabric is sprayed with insect-proofing and mosquito-repellent drugs, the fabric has a soft feel and in practice, the textile fabric can resist a tensile force of above 410 KPA and withstand 20-35 washes, while still having a mortality rate of mosquitoes and insects of above 80% and a service life of more than 3-5 years.

Description

具有防虫功能的纺织面料及其生产方法 技术领域  Textile fabric with insect proof function and production method thereof
本发明涉及一种纺织技术, 具体说, 涉及具有防虫功能的纺织 面料及其生产方法。 背景技术  The present invention relates to a textile technique, and more particularly to a textile fabric having an insect control function and a method of producing the same. Background technique
现在常用的纺织品, 如衣服、 蚊帐、 被单等都不具备驱蚊驱虫 功能, 人们日常活动往往会受到蚊虫的严重影响。 由于蚊帐没有驱 蚊功能, 晚上睡觉时, 蚊子会飞进去叮咬人体, 使人不能入睡; 由 于衣服没有驱蚊功能, 人体会被蚊子不停叮咬, 严重影响人的工作 和生活。  Today's commonly used textiles, such as clothes, mosquito nets, and sheets, do not have the function of mosquito repellent, and people's daily activities are often seriously affected by mosquitoes. Since the mosquito net does not have the function of repelling mosquitoes, when sleeping at night, the mosquitoes will fly in and bite the human body, so that people cannot fall asleep; because the clothes do not have mosquito repellent function, the human body will be bitten by mosquitoes, which seriously affects people's work and life.
另外,蚊子还会传播疾病, 不同种类的蚊子可传播不同的疾病。 最近以来, 我国部分地区乙型脑炎 (筒称 "乙脑" ) 、 登革热等传 染病流行, 这些疾病的传染途径主要是通过蚊子。 蚊子是夏秋季节 非常多见的一种有害昆虫, 它对人体的危害在于, 其叮咬有病的动 物或人体后, 会将病原体传染给健康人。  In addition, mosquitoes can spread diseases, and different types of mosquitoes can spread different diseases. Recently, epidemic diseases such as Japanese encephalitis (called "JE") and dengue fever have been prevalent in parts of China, and the main routes of transmission of these diseases are through mosquitoes. Mosquitoes are a kind of harmful insects that are very common in summer and autumn. The harm to the human body is that they will transmit pathogens to healthy people after they bite a diseased animal or human body.
聚乙烯 ( PE ) 分为高密度聚乙烯 ( HDPE ) 和低密度聚乙烯 ( LDPE ) 。 高密度聚乙烯有很好的水洗性能, 干洗性能略差, 它 必须在较高的温度和较大的压力下才能获得较好的粘合效果, 根据 它的这些特性, 广泛用来做男村衫粘合村。 低密度聚乙烯的耐水洗 和耐干洗性能均较差, 但它可以在较低温度下粘合并且有较好的粘 合强度, 故广泛用于暂时性粘合村布。  Polyethylene (PE) is classified into high density polyethylene (HDPE) and low density polyethylene (LDPE). High-density polyethylene has good water washing performance, and the dry cleaning performance is slightly poor. It must be at a higher temperature and a higher pressure to obtain a better bonding effect. According to these characteristics, it is widely used as a male village. Shirt bonding village. Low-density polyethylene has poor water-washing and dry-cleaning resistance, but it can be bonded at a lower temperature and has a good bonding strength, so it is widely used for temporarily bonding village cloth.
涤纶 ( Terylene ) 是合成纤维中的一个重要品种, 是我国聚酯 纤维的商品名称。 它是以精对苯二甲酸 ( PTA ) 或对苯二甲酸二甲 酯 ( DMT) 和乙二醇 ( EG) 为原料经酯化或酯交换和缩聚反应而 制得的成纤高聚物——聚对苯二甲酸乙二醇酯 ( PET) , 经纺丝和 后处理制成的纤维。 Terylene is an important variety in synthetic fibers and is the trade name of polyester fiber in China. It is based on purified terephthalic acid (PTA) or methyl terephthalate. Ester (DMT) and ethylene glycol (EG) are fiber-forming polymers obtained by esterification or transesterification and polycondensation, polyethylene terephthalate (PET), spinning and Post-processed fibers.
现在缺少一种既能防虫并能有效杀虫的纺织面料, 从而实现长 效地主动驱虫驱蚊。 发明内容  There is a lack of a textile fabric that is both insect-resistant and effective in killing insects, enabling long-lasting active insect repellents. Summary of the invention
本发明所解决的技术问题是提供一种具有防虫功能的纺织面 料, 具有长效驱虫功能。  The technical problem solved by the present invention is to provide a textile surface having an insect-repellent function, which has a long-lasting insect repellent function.
技术方案如下:  The technical solutions are as follows:
一种具有防虫功能的纺织面料, 所述纺织面料含有杀虫剂。 进一步: 纺织面料包含有药品纱线, 所述杀虫剂含在药品纱线 内, 所述药品纱线中, 药品占总质量的比例是 1%~ 80%, 高密度聚 乙烯 HDPE占总质量的比例是 1% ~ 90%, 低密度 聚乙烯 LDPE占 总质量的比例是 1 ~ 30%。  A textile fabric having an insect-repellent function, the textile fabric containing an insecticide. Further, the textile fabric comprises a pharmaceutical yarn, and the insecticide is contained in the pharmaceutical yarn, wherein the ratio of the medicine to the total mass is 1% to 80%, and the high density polyethylene HDPE accounts for the total mass. The ratio is 1% ~ 90%, and the ratio of low density polyethylene LDPE to total mass is 1 ~ 30%.
进一步: 所述药品包括重量百分比 1 ~ 30%的色母、 重量百分 比 1-28%的防老化剂、重量百分比 1 ~ 26%阻燃剂和重量百分比 1 ~ Further, the medicine comprises a color masterbatch of 1 to 30% by weight, an anti-aging agent of 1-28% by weight, a weight percentage of 1 to 26% of a flame retardant, and a weight percentage 1 ~
16%杀虫剂。 16% pesticide.
进一步: 所述纺织面料通过在涤纶丝、 聚乙烯 PE 纱线或纺织 面料外表层喷撒、 涂覆或者浸泡杀虫剂涂层将杀虫剂加入到纺织面 料中; 药剂包括顺式氯氰菊酯、 氟氯氰菊酯、 氯氰菊酯、 溴氰菊酯、 醚菊酯、 三氟氯氰菊酯、 氯醚酯、 丙烯菊酯、 富右旋丙烯菊酯或者 甲醚菊酯, 添加比例为 1 ~ 30 g/kg。  Further: the textile fabric is added to the textile fabric by spraying, coating or soaking the insecticide coating on the outer surface of the polyester yarn, the polyethylene PE yarn or the textile fabric; the medicament comprises cypermethrin, fluorine Cypermethrin, cypermethrin, deltamethrin, etofenproxil, cyhalothrin, chloroether ester, methrin, dextromethrin or methamphetamine in a ratio of 1 to 30 g/kg.
进一步: 纺织面料包含有药品纱线, 所述杀虫剂含在药品纱线 内,所述药品纱线是通过对涤纶纱线放入温度 100 ~ 200°C杀虫剂浸 泡 1 ~ 2 小时生成, 药剂包括顺式氯氰菊酯、 氟氯氰菊酯、 氯氰菊 酯、 溴氰菊酯、 醚菊酯、 三氟氯氰菊酯、 氯醚酯、 丙烯菊酯、 富右 旋丙烯菊酯或者甲醚菊酯, 添加比例为 1 ~ 30 g/kg。 Further: the textile fabric comprises a pharmaceutical yarn, and the insecticide is contained in a pharmaceutical yarn which is prepared by injecting a pesticide into a polyester yarn at a temperature of 100 to 200 ° C. The foam is formed in 1 ~ 2 hours, and the medicament includes cypermethrin, cyfluthrin, cypermethrin, deltamethrin, etofenrin, cyhalothrin, chloroether ester, methrin, dextromethrin or methamphetamine. , the addition ratio is 1 ~ 30 g / kg.
本发明所解决的另一个技术问题是提供一种具有防虫功能的 纺织面料的生产方法, 纺织面料具有长效驱虫功能。  Another technical problem to be solved by the present invention is to provide a method for producing a textile fabric having an insect-repellent function, and the textile fabric has a long-lasting insect repellent function.
技术方案如下:  The technical solutions are as follows:
一种具有防虫功能的纺织面料的生产方法, 包括: 将纺织面料 进行加药处理, 处理后的纺织面料含有杀虫剂。  A method for producing a textile fabric having an insect-repellent function, comprising: adding a textile fabric to a medicinal treatment, and the treated textile fabric contains an insecticide.
进一步, 所述纺织面料生产过程包括:  Further, the textile fabric production process includes:
生成药品纱线,将所述药品纱线混入到不含有药品的聚乙烯 P E 纱线中, 生成含杀虫剂的 PE纱线;  Generating a drug yarn, mixing the drug yarn into a polyethylene P E yarn containing no drug, and generating a pesticide-containing PE yarn;
将含有所述药品纱线的聚乙烯 PE 纱线和涤纶纱线混纺, 生成 纺织面料。  A polyethylene PE yarn containing the drug yarn and a polyester yarn are blended to form a textile fabric.
进一步, 杀虫剂含在 PE纱线和涤纶纱线内, 生产过程包括: 将 PE 纱线和涤纶纱线放入杀虫剂中浸泡 1 ~ 2 小时, 温度在 100 ~ 200 °C之间, 生成药品纱线;  Further, the insecticide is contained in the PE yarn and the polyester yarn, and the production process includes: immersing the PE yarn and the polyester yarn in the insecticide for 1 to 2 hours, and the temperature is between 100 and 200 °C. Generating a drug yarn;
将所述药品纱线与不含杀虫剂的涤纶纱线混纺, 生成具有防虫 功能的纺织面料。  The pharmaceutical yarn is blended with a polyester yarn containing no insecticide to form a textile fabric having an insect-repellent function.
进一步, 杀虫剂含在涤纶纱线内, 聚乙烯 PE 纱线不含药, 生 产过程包括:  Further, the insecticide is contained in the polyester yarn, and the polyethylene PE yarn is free of medicine, and the production process includes:
将涤纶纱线放入杀虫剂中浸泡 1 ~ 2小时, 温度在 100 ~ 200 °C 之间, 生成药品纱线;  Put the polyester yarn into the insecticide for 1 ~ 2 hours, and the temperature is between 100 ~ 200 °C to produce the drug yarn;
将所述药品纱线和不含有杀虫剂的 PE 纱线混纺, 生成具有防 虫功能的纺织面料。 进一步: 通过在涤纶丝、 聚乙烯 PE 纱线或纺织面料外表层喷 撒、 涂覆杀虫制剂涂层, 或者将纺织面料直接浸泡在杀虫制剂中, 将所述杀虫剂附着到纺织面料上。 The pharmaceutical yarn and the PE yarn not containing the insecticide are blended to form a textile fabric having an insect-repellent function. Further: attaching the insecticide to the textile fabric by spraying or coating the outer layer of the polyester yarn, the polyethylene PE yarn or the textile fabric, coating the insecticide coating, or directly immersing the textile fabric in the insecticide preparation on.
技术效果包括:  Technical effects include:
1、 利用本发明技术方案生产的纺织面料具有手感柔软、 抗拉 能力强和耐用的特点, 并且纺织面料具有长效驱虫功能。 由于本发 明的纺织面料在编织之前采用加药处理, 再采用混纺工艺编织成成 品,该纺织物手感柔软, 实际应用中,能耐抗 410KPA以上的拉力, 耐洗 20次以上, 蚊虫死亡率仍达 100% , 使用期限 5年以上; 洗涤 20次后, 蚊虫的击倒率和死亡率也可以达到 85 %以上。  1. The textile fabric produced by the technical scheme of the invention has the characteristics of soft hand feeling, strong tensile strength and durability, and the textile fabric has long-term deworming function. Since the textile fabric of the present invention is medicated before weaving, and then weaved into a finished product by a blending process, the textile has a soft hand feeling, and in practical application, it can withstand a tensile force of more than 410 KPA, washable more than 20 times, and the mosquito mortality rate still reaches 100%, the service period is more than 5 years; after washing 20 times, the knockdown rate and mortality rate of mosquitoes can reach more than 85%.
2、 本发明的纺织面料用途广泛, 可以作为常规的纺织面料使 用。  2. The textile fabric of the present invention is widely used and can be used as a conventional textile fabric.
3、 本发明技术方案不同于一般防蚊虫手段, 使用起来更为方 便、 洁净环保, 同时对人体也无伤害, 使用安全。  3. The technical scheme of the present invention is different from the general anti-mosquito method, and is more convenient to use, clean and environmentally friendly, and has no harm to the human body and is safe to use.
4、 使用本发明技术方案生产的纺织面料, 可以有效击倒和驱 灭蚊虫, 而且产品对使用者和洗涤者安全, 可以广泛应用于人们的 生活中。 附图概述  4. The textile fabric produced by the technical scheme of the present invention can effectively knock down and drive out mosquitoes, and the product is safe for users and detergents, and can be widely used in people's lives. BRIEF abstract
图 1是本发明中含杀虫剂的纺织纱线的切面图。 本发明的较佳实施方式  BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 is a cross-sectional view showing a textile yarn containing an insecticide in the present invention. Preferred embodiment of the invention
为使本发明的上述目的、 特征和优点能够更加明显易懂, 下面 结合附图和具体实施方式对本发明作进一步详细的说明。  The above described objects, features and advantages of the present invention will become more apparent from the aspects of the appended claims.
本发明中, 具有长效驱蚊虫功能的纺织面料由含杀虫剂的 PE 纱线和涤纶纱线通过混纺工艺编织而成, 编织方法是经编交织混纺; 防虫功能是通过将杀虫剂加入到 P E 纱线或者涤纶纱线中实现的。 PE纱线中含有重量百分比为 1 % ~ 80%的杀虫剂 (驱蚊剂 ) , 驱蚊 剂选用 WHO ( World Health Organization , 世界卫生组织 ) 推荐使 用的杀虫剂, 包括: 顺式氯氰菊酯、 氟氯氰菊酯、 氯氰菊酯、 溴氰 菊酯、 醚菊酯、 三氟氯氰菊酯和氯醚酯等。 国内驱蚊剂选用的除虫 菊酯类药品有: 丙烯菊酯、 富右旋丙烯菊酯和甲醚菊酯等。 In the present invention, the textile fabric having the long-lasting insect repellent function is composed of PE containing insecticide. Yarn and polyester yarns are woven by a blending process, which is warp-knitted and blended; the insect-repellent function is achieved by adding pesticides to PE yarns or polyester yarns. The PE yarn contains 1% ~ 80% by weight of insecticide (mosquito repellent), and the insect repellent uses the insecticide recommended by the World Health Organization (World Health Organization), including: cypermethrin, Cyfluthrin, cypermethrin, deltamethrin, cypermethrin, cyhalothrin and chloroether ester. The pyrethroids selected for domestic mosquito repellents include: methrin, dextromethrin and methotrexate.
将杀虫剂加入到纺织面料中, 可以采用下列 3种方式:  Adding pesticides to textile fabrics can be done in the following three ways:
( 1 ) 杀虫剂含在药品纱线内, 涤纶纱线不含药;  (1) The insecticide is contained in the drug yarn, and the polyester yarn contains no drug;
( 2 ) 杀虫剂含在药品纱线和涤纶纱线内;  (2) Insecticides are contained in pharmaceutical yarns and polyester yarns;
( 3 ) 杀虫剂只含在涤纶纱线内。  (3) Insecticides are only contained in polyester yarns.
如图 1所示, 是本发明中含杀虫剂的纺织纱线的切面图。 从图 中可以看出, 纺织纱线包含有药品纱线 1 1 (可以是含有杀虫剂的 PE纱线或者涤纶纱线) 和不含有药品的涤纶纱线 12 , 药品纱线 11 和涤纶纱线 12互相混合在一起组成纺织纱线。  As shown in Fig. 1, it is a cutaway view of a textile yarn containing an insecticide in the present invention. As can be seen from the figure, the textile yarn comprises a pharmaceutical yarn 1 1 (which may be a PE yarn or a polyester yarn containing an insecticide) and a polyester yarn 12 containing no medicine, a pharmaceutical yarn 11 and a polyester yarn. The wires 12 are mixed with each other to form a textile yarn.
含杀虫剂的纺织面料的生产过程如下:  The production process of textile fabrics containing insecticides is as follows:
方式一:  method one:
1、 生成药品纱线。  1. Generate drug yarns.
把重量百分比 1 ~ 30%的色母,重量百分比 1 ~ 28%的防老化剂, 重量百分比 1 ~ 26%阻燃剂, 重量百分比 1 ~ 16%杀虫剂, 配成药母 粒, 然后将该药母粒、 HDPE颗粒和 LDPE颗粒混合并加热至 150 ~ 250摄氏度拉成丝, 生成药品纱线 11 ; 其中 HDPE 占总质量的比 例是 1 % ~ 90% , LDPE占总质量的比例是 1 ~ 30% , 药母粒占总质 量的比例是 1 % ~ 80%。 2、 将药品纱线 11 混入到不含有药品的 PE纱线中, 生成含杀 虫剂的 PE纱线; 1 to 30% by weight of color masterbatch, 1 to 28% by weight of anti-aging agent, 1% to 26% by weight of flame retardant, 1 to 16% by weight of pesticide, formulated into masterbatch, and then The masterbatch, HDPE particles and LDPE particles are mixed and heated to 150 ~ 250 ° C to form a drug yarn 11; wherein the ratio of HDPE to total mass is 1% ~ 90%, and the ratio of LDPE to total mass is 1 ~ 30%, the ratio of the masterbatch to the total mass is 1% ~ 80%. 2. Mixing the drug yarn 11 into the PE yarn containing no drug to form a PE yarn containing the pesticide;
3、 将含杀虫剂的 PE纱线和涤纶纱线 12混纺, 生成具有防虫 功能的纺织面料。  3. Blending PE yarn containing insecticide and polyester yarn 12 to produce a textile fabric with insect-proof function.
方式二: 杀虫剂含在 PE纱线和涤纶纱线内。  Method 2: The pesticide is contained in the PE yarn and the polyester yarn.
生产过程如下:  The production process is as follows:
1、 将 PE纱线和涤纶纱线放入杀虫剂中浸泡 1 ~ 2小时, 温度 在 100 ~ 200 °C之间, 生成药品纱线 1 1。  1. Pour the PE yarn and polyester yarn into the insecticide for 1 ~ 2 hours, and the temperature is between 100 ~ 200 °C to produce the pharmaceutical yarn 1 1 .
杀虫剂可以选取: 顺式氯氰菊酯、 氟氯氰菊酯、 氯氰菊酯、 溴 氰菊酯、 醚菊酯、 三氟氯氰菊酯、 氯醚酯、 丙烯菊酯、 富右旋丙烯 菊酯、甲醚菊酯等中的一种或者几种组合,添加比例为 1 ~ 30 g/kg。  Insecticides can be selected from: cypermethrin, cyfluthrin, cypermethrin, deltamethrin, etofenproxil, cyhalothrin, chloroether ester, methrin, dextromethrin, methamphate, etc. One or several combinations, the addition ratio is 1 ~ 30 g / kg.
杀虫剂也可以选取溴氰菊酯 1.8g/kg或者氯氰菊酯 5.5g/kg。 Insecticides may also be selected from deltamethrin 1.8 g/kg or cypermethrin 5.5 g/kg.
2、 将药品纱线 1 1 与不含杀虫剂的涤纶纱线 12 混纺, 生成具 有防虫功能的纺织面料。 2. Blend the pharmaceutical yarn 1 1 with the polyester yarn 12 without insecticide to produce a textile fabric with insect resistance.
方式三: 杀虫剂含在涤纶纱线内, PE纱线不含药。  Method 3: The insecticide is contained in the polyester yarn, and the PE yarn is free of medicine.
生产过程如下:  The production process is as follows:
1、将涤纶纱线放入杀虫剂中浸泡 1 ~ 2小时,温度在 100 ~ 200 °C 之间, 生成药品纱线 11。  1. Soak the polyester yarn into the insecticide for 1 ~ 2 hours, and the temperature is between 100 ~ 200 °C to produce the drug yarn.
杀虫剂可以选取: 顺式氯氰菊酯、 氟氯氰菊酯、 氯氰菊酯、 溴 氰菊酯、 醚菊酯、 三氟氯氰菊酯、 氯醚酯、 丙烯菊酯、 富右旋丙烯 菊酯、甲醚菊酯等中的一种或者几种组合,添加比例为 1 ~ 30 g/kg。  Insecticides can be selected from: cypermethrin, cyfluthrin, cypermethrin, deltamethrin, etofenproxil, cyhalothrin, chloroether ester, methrin, dextromethrin, methamphate, etc. One or several combinations, the addition ratio is 1 ~ 30 g / kg.
杀虫剂也可以选取溴氰菊酯 1.8g/kg或者氯氰菊酯 5.5g/kg。 Insecticides may also be selected from deltamethrin 1.8 g/kg or cypermethrin 5.5 g/kg.
2、 将药品纱线 11 和不含有杀虫剂的 PE纱线混纺, 生成具有 防虫功能的纺织面料。 方式四: 通过在涤纶丝、 PE 纱线或纺织面料外表层喷撒、 涂 覆杀虫制剂涂层, 或者将纺织面料直接浸泡在杀虫制剂中, 将杀虫 剂附着到纺织面料上。 杀虫剂的选取可以参考方式三。 2. Blend the drug yarn 11 with the PE yarn without insecticide to produce a textile fabric with insect-proof function. Method 4: The insecticide is attached to the textile fabric by spraying or coating the outer layer of the polyester yarn, the PE yarn or the textile fabric with the coating of the insecticidal preparation, or directly immersing the textile fabric in the insecticide preparation. For the selection of pesticides, refer to method three.
纺织面料耐洗测试:  Textile fabric washable test:
1、 取 25cm*25cm的纺织面料材料样品备用;  1. Take samples of 25cm*25cm textile fabric materials for use;
2、 按照世界卫生组织洗涤测试标准, 即在大烧杯中加入 0.5L 水和 l g肥皂,保持 pH值在 10 ~ 1 1 , 水温 30 °C , 至肥皂全部溶解; 2. According to the World Health Organization washing test standard, add 0.5L water and l g soap to the large beaker, keep the pH value at 10 ~ 1 1 , water temperature 30 °C, until the soap is completely dissolved;
3、 将 25cm*25cm大小的纺织面料样品放入含以上洗涤剂的烧 杯中, 并将烧杯放在摇床上, 以 155次 /min的速度洗涤的纺织面 料样品 l Omin; 之后, 将样品移出, 在净水中清洗两次, 清洗同样 在摇床上以 155次 /min的速度洗涤的纺织面料样品 l Omin; 3. Place a sample of 25cm*25cm textile fabric into a beaker containing the above detergent, place the beaker on a shaker, and wash the textile fabric sample at a speed of 155 times/min. lOmin; then, remove the sample. Washing twice in clean water, cleaning the textile fabric sample also washed on the shaker at a speed of 155 times / min l Omin;
4、 洗涤后,在 30 °C室温下晾干, 黑暗条件下保存至下次洗涤, 每次洗涤需间 1 ~ 3天。  4. After washing, dry at room temperature of 30 °C, and store in dark conditions until the next wash. Each wash takes 1-3 days.
以上过程反复进行至少 20次。  The above process is repeated at least 20 times.
防坟虫测试:  Anti-grave test:
实验室饲养的敏感品系白纹伊蚊 (雌性) 2 ~ 5 日龄成虫。  The sensitive species raised in the laboratory are Aedes albopictus (female) 2 to 5 day old adults.
测试结果: 具有防虫功能的纺织面料中的杀虫剂耐洗涤次数为 30~35次, 蚊虫死亡率达 100%以上。  Test results: The insecticides in the textile fabric with insect-proof function have a washing resistance of 30 to 35 times and a mosquito mortality rate of more than 100%.
该试验结果说明, 本发明的具有防虫功能的纺织面料具有耐洗、 耐用、 蚊虫击倒率高、 杀虫剂药效作用时间长等特点。  The test results show that the textile fabric with insect-proof function of the invention has the characteristics of washing resistance, durability, high mosquito knockdown rate and long duration of action of the insecticide.
上面已结合附图对本发明的具体实施例进行了示例性的描述, 显然本发明不限于此, 其它未作说明的细节也在本发明的保护范围 内。 工业实用性 The embodiments of the present invention have been described in detail with reference to the accompanying drawings, and the present invention is not limited thereto, and other details not illustrated are also within the scope of the present invention. Industrial applicability
利用本发明技术方案生产的纺织面料具有手感柔软、 抗拉能力 强和耐用的特点, 并且纺织面料具有长效驱虫功能。 使用本发明技 术方案生产的纺织面料可以有效击倒和驱灭蚊虫, 而且产品对使用 者和洗涤者安全, 可以广泛应用于人们的生活中。  The textile fabric produced by the technical scheme of the invention has the characteristics of soft hand feeling, strong tensile strength and durability, and the textile fabric has a long-lasting insect repellent function. The textile fabric produced by the technical solution of the present invention can effectively knock down and repel mosquitoes, and the product is safe for users and detergents, and can be widely used in people's lives.

Claims

权 利 要 求 书 Claim
1、 一种具有防虫功能的纺织面料, 其特征在于: 所述纺织面料含有 杀虫剂。 A textile fabric having an insect control function, characterized in that: the textile fabric contains an insecticide.
2、 如权利要求 1 所述的具有防虫功能的纺织面料, 其特征在于: 纺 织面料包含有药品纱线, 所述杀虫剂含在药品纱线内, 所述药品纱线中, 药 品占总质量的比例是 1% ~ 80% , 高密度聚乙烯 HDPE 占总质量的比例是 1% ~ 90%, 低密度 聚乙烯 LDPE占总质量的比例是 1 ~ 30%。 2. The textile fabric with pest control function according to claim 1, wherein: the textile fabric comprises a pharmaceutical yarn, and the insecticide is contained in a pharmaceutical yarn, wherein the pharmaceutical yarn accounts for The ratio of mass is 1% ~ 80%, the ratio of HDPE to total mass is 1% ~ 90%, and the ratio of low density polyethylene LDPE to total mass is 1 ~ 30%.
3、 如权利要求 2所述的具有防虫功能的纺织面料, 其特征在于: 所 述药品包括重量百分比 1 ~ 30%的色母、重量百分比 1-28%的防老化剂、重量 百分比 1 ~ 26%阻燃剂和重量百分比 1 ~ 16%杀虫剂。 3. The textile fabric with insectproof function according to claim 2, wherein: the medicine comprises a color masterbatch of 1 to 30% by weight, an anti-aging agent of 1-28% by weight, and a weight percentage of 1 to 26 % flame retardant and 1 to 16% by weight of pesticide.
4、 如权利要求 1 所述的具有防虫功能的纺织面料, 其特征在于: 所 述纺织面料通过在涤纶丝、 聚乙烯 PE纱线或纺织面料外表层喷撒、 涂覆或 者浸泡杀虫剂涂层将杀虫剂加入到纺织面料中; 药剂包括顺式氯氰菊酯、 氟 氯氰菊酯、 氯氰菊酯、 溴氰菊酯、 醚菊酯、 三氟氯氰菊酯、 氯醚酯、 丙烯菊 酯、 富右旋丙烯菊酯或者甲醚菊酯, 添加比例为 1 ~ 30 g/kg。 4. The textile fabric with pest control function according to claim 1, wherein: the textile fabric is sprayed, coated or immersed in an insecticide coating on the outer surface of a polyester yarn, a polyethylene PE yarn or a textile fabric. Adding insecticide to the fabric; the agent includes cypermethrin, cyfluthrin, cypermethrin, deltamethrin, cypermethrin, cyhalothrin, chloroether ester, methrin, dextromethrin or Methrin, in a ratio of 1 to 30 g/kg.
5、 如权利要求 1 所述的具有防虫功能的纺织面料, 其特征在于: 纺 织面料包含有药品纱线, 所述杀虫剂含在药品纱线内, 所述药品纱线是通过 对涤纶纱线放入温度 100 ~ 200°C杀虫剂浸泡 1 ~ 2小时生成, 药剂包括顺式 氯氰菊酯、 氟氯氰菊酯、 氯氰菊酯、 溴氰菊酯、 醚菊酯、 三氟氯氰菊酯、 氯 醚酯、 丙烯菊酯、 富右旋丙烯菊酯或者甲醚菊酯, 添加比例为 l ~ 30 g/kg。 5. The textile fabric with pest control function according to claim 1, wherein: the textile fabric comprises a pharmaceutical yarn, the insecticide is contained in a pharmaceutical yarn, and the pharmaceutical yarn is passed through a polyester yarn. The wire is placed in a temperature of 100 ~ 200 °C for 1 ~ 2 hours. The agent includes cypermethrin, cyfluthrin, cypermethrin, deltamethrin, cypermethrin, cyhalothrin, chloroether ester, and pyrethroid. , rich dextromethrin or methamphetamine, the addition ratio is l ~ 30 g / kg.
6、 一种具有防虫功能的纺织面料的生产方法, 包括: 将纺织面料进 6. A method for producing a textile fabric having an insect-proof function, comprising:
7、 如权利要求 6所述的具有防虫功能的纺织面料的生产方法, 其特 征在于, 所述纺织面料生产过程包括: 7. The method of producing a textile fabric having insect control function according to claim 6, wherein the textile fabric production process comprises:
生成药品纱线,将所述药品纱线混入到不含有药品的聚乙烯 P E 纱线中, 生成含杀虫剂的 PE纱线;  Generating a drug yarn, mixing the drug yarn into a polyethylene P E yarn containing no drug, and generating a pesticide-containing PE yarn;
将含有所述药品纱线的聚乙烯 PE 纱线和涤纶纱线混纺, 生成 纺织面料。  A polyethylene PE yarn containing the drug yarn and a polyester yarn are blended to form a textile fabric.
8、 如权利要求 6所述的具有防虫功能的纺织面料的生产方法, 其特 征在于, 杀虫剂含在 PE纱线和涤纶纱线内, 生产过程包括: A method of producing a textile fabric having insect control function according to claim 6, wherein the insecticide is contained in the PE yarn and the polyester yarn, and the production process comprises:
将 PE 纱线和涤纶纱线放入杀虫剂中浸泡 1 ~ 2 小时, 温度在 100 ~ 200 °C之间, 生成药品纱线;  Put the PE yarn and the polyester yarn into the insecticide for 1 ~ 2 hours, and the temperature is between 100 ~ 200 °C to produce the drug yarn;
将所述药品纱线与不含杀虫剂的涤纶纱线混纺, 生成具有防虫 功能的纺织面料。  The pharmaceutical yarn is blended with a polyester yarn containing no insecticide to form a textile fabric having an insect-repellent function.
9、 如权利要求 6所述的具有防虫功能的纺织面料的生产方法, 其特 征在于, 杀虫剂含在涤纶纱线内, 聚乙烯 PE 纱线不含药, 生产过程 包括: 9. The method for producing a textile fabric having insect control function according to claim 6, wherein the insecticide is contained in the polyester yarn, and the polyethylene PE yarn is free of medicine, and the production process comprises:
将涤纶纱线放入杀虫剂中浸泡 1 ~ 2小时, 温度在 100 ~ 200 °C 之间, 生成药品纱线;  Put the polyester yarn into the insecticide for 1 ~ 2 hours, and the temperature is between 100 ~ 200 °C to produce the drug yarn;
将所述药品纱线和不含有杀虫剂的 PE 纱线混纺, 生成具有防 虫功能的纺织面料。  The drug yarn and the PE yarn not containing the insecticide are blended to form a textile fabric having an insect-repellent function.
10、 如权利要求 6所述的具有防虫功能的纺织面料的生产方法, 其特 征在于: 通过在涤纶丝、 聚乙烯 PE纱线或纺织面料外表层喷撒、 涂 覆杀虫制剂涂层, 或者将纺织面料直接浸泡在杀虫制剂中, 将所述 杀虫剂附着到纺织面料上。 10. The method for producing a textile fabric having insect-repellent function according to claim 6, wherein: the coating of the insecticidal preparation is sprayed or coated on the outer surface of the polyester yarn, the polyethylene PE yarn or the textile fabric, or The textile fabric is directly immersed in the insecticidal preparation, and the insecticide is attached to the textile fabric.
PCT/CN2011/080132 2011-09-22 2011-09-23 Textile fabric having insect-proofing function and production method thereof WO2013040796A1 (en)

Applications Claiming Priority (4)

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CN2011102836885A CN102383258A (en) 2011-09-22 2011-09-22 Long-lasting insect repellent fabric and method for producing same
CN201110283688.5 2011-09-22
CN201110283701.7 2011-09-22
CN2011102837017A CN102444020A (en) 2011-09-22 2011-09-22 Fabrics having insect-proofing function and production method thereof

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1473988A (en) * 2003-07-01 2004-02-11 上海公泰纺织制品有限公司 Method for producing mothproof fabric
CN1664227A (en) * 2005-03-04 2005-09-07 天津永阔国际贸易有限公司 Fabric finishing liquor for expelling and killing mosquitoes, method of use and products thereof
CN102444020A (en) * 2011-09-22 2012-05-09 杨晓蓉 Fabrics having insect-proofing function and production method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1473988A (en) * 2003-07-01 2004-02-11 上海公泰纺织制品有限公司 Method for producing mothproof fabric
CN1664227A (en) * 2005-03-04 2005-09-07 天津永阔国际贸易有限公司 Fabric finishing liquor for expelling and killing mosquitoes, method of use and products thereof
CN102444020A (en) * 2011-09-22 2012-05-09 杨晓蓉 Fabrics having insect-proofing function and production method thereof

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