WO2013030262A1 - Insecticidal active mixtures comprising arylquinazolinone compounds - Google Patents
Insecticidal active mixtures comprising arylquinazolinone compounds Download PDFInfo
- Publication number
- WO2013030262A1 WO2013030262A1 PCT/EP2012/066839 EP2012066839W WO2013030262A1 WO 2013030262 A1 WO2013030262 A1 WO 2013030262A1 EP 2012066839 W EP2012066839 W EP 2012066839W WO 2013030262 A1 WO2013030262 A1 WO 2013030262A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- methyl
- compound
- active compound
- mixtures according
- pesticidal mixtures
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 282
- 150000001875 compounds Chemical class 0.000 title claims abstract description 249
- 230000000749 insecticidal effect Effects 0.000 title description 11
- HTSGKJQDMSTCGS-UHFFFAOYSA-N 1,4-bis(4-chlorophenyl)-2-(4-methylphenyl)sulfonylbutane-1,4-dione Chemical compound C1=CC(C)=CC=C1S(=O)(=O)C(C(=O)C=1C=CC(Cl)=CC=1)CC(=O)C1=CC=C(Cl)C=C1 HTSGKJQDMSTCGS-UHFFFAOYSA-N 0.000 claims abstract description 108
- 230000000361 pesticidal effect Effects 0.000 claims abstract description 66
- 241000238631 Hexapoda Species 0.000 claims abstract description 37
- 238000000034 method Methods 0.000 claims abstract description 33
- 239000003112 inhibitor Substances 0.000 claims abstract description 30
- 239000000463 material Substances 0.000 claims abstract description 30
- 241000244206 Nematoda Species 0.000 claims abstract description 21
- 230000002438 mitochondrial effect Effects 0.000 claims abstract description 11
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 10
- 239000000018 receptor agonist Substances 0.000 claims abstract description 9
- 229940044601 receptor agonist Drugs 0.000 claims abstract description 9
- 241000239223 Arachnida Species 0.000 claims abstract description 8
- 229920002101 Chitin Polymers 0.000 claims abstract description 5
- 230000001419 dependent effect Effects 0.000 claims abstract description 5
- 238000003786 synthesis reaction Methods 0.000 claims abstract description 5
- 108010052164 Sodium Channels Proteins 0.000 claims abstract description 4
- 102000018674 Sodium Channels Human genes 0.000 claims abstract description 4
- UPEZCKBFRMILAV-UHFFFAOYSA-N alpha-Ecdysone Natural products C1C(O)C(O)CC2(C)C(CCC3(C(C(C(O)CCC(C)(C)O)C)CCC33O)C)C3=CC(=O)C21 UPEZCKBFRMILAV-UHFFFAOYSA-N 0.000 claims abstract description 4
- 150000002632 lipids Chemical class 0.000 claims abstract description 4
- 230000010627 oxidative phosphorylation Effects 0.000 claims abstract description 4
- 239000003195 sodium channel blocking agent Substances 0.000 claims abstract description 4
- 229940127437 Chloride Channel Antagonists Drugs 0.000 claims abstract description 3
- 108050006807 Nicotinic acetylcholine receptors Proteins 0.000 claims abstract description 3
- 230000003281 allosteric effect Effects 0.000 claims abstract description 3
- 239000003467 chloride channel stimulating agent Substances 0.000 claims abstract description 3
- 229930014550 juvenile hormone Natural products 0.000 claims abstract description 3
- 239000002949 juvenile hormone Substances 0.000 claims abstract description 3
- 150000003633 juvenile hormone derivatives Chemical class 0.000 claims abstract description 3
- -1 C1-C4- haloalkenyl Chemical group 0.000 claims description 164
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 54
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 29
- 239000005665 Spiromesifen Substances 0.000 claims description 19
- 239000000460 chlorine Chemical group 0.000 claims description 19
- 229910052801 chlorine Inorganic materials 0.000 claims description 19
- 229910052731 fluorine Inorganic materials 0.000 claims description 19
- 239000011737 fluorine Chemical group 0.000 claims description 19
- 239000007787 solid Substances 0.000 claims description 19
- GOLXNESZZPUPJE-UHFFFAOYSA-N spiromesifen Chemical compound CC1=CC(C)=CC(C)=C1C(C(O1)=O)=C(OC(=O)CC(C)(C)C)C11CCCC1 GOLXNESZZPUPJE-UHFFFAOYSA-N 0.000 claims description 19
- 239000005892 Deltamethrin Substances 0.000 claims description 18
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- 239000005941 Thiamethoxam Substances 0.000 claims description 18
- ZVQOOHYFBIDMTQ-UHFFFAOYSA-N [methyl(oxido){1-[6-(trifluoromethyl)pyridin-3-yl]ethyl}-lambda(6)-sulfanylidene]cyanamide Chemical compound N#CN=S(C)(=O)C(C)C1=CC=C(C(F)(F)F)N=C1 ZVQOOHYFBIDMTQ-UHFFFAOYSA-N 0.000 claims description 18
- 229960002483 decamethrin Drugs 0.000 claims description 18
- OWZREIFADZCYQD-NSHGMRRFSA-N deltamethrin Chemical compound CC1(C)[C@@H](C=C(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 OWZREIFADZCYQD-NSHGMRRFSA-N 0.000 claims description 18
- 239000002689 soil Substances 0.000 claims description 18
- CLSVJBIHYWPGQY-GGYDESQDSA-N spirotetramat Chemical compound CCOC(=O)OC1=C(C=2C(=CC=C(C)C=2)C)C(=O)N[C@@]11CC[C@H](OC)CC1 CLSVJBIHYWPGQY-GGYDESQDSA-N 0.000 claims description 18
- NWWZPOKUUAIXIW-FLIBITNWSA-N thiamethoxam Chemical compound [O-][N+](=O)\N=C/1N(C)COCN\1CC1=CN=C(Cl)S1 NWWZPOKUUAIXIW-FLIBITNWSA-N 0.000 claims description 18
- ZOCSXAVNDGMNBV-UHFFFAOYSA-N 5-amino-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-[(trifluoromethyl)sulfinyl]-1H-pyrazole-3-carbonitrile Chemical compound NC1=C(S(=O)C(F)(F)F)C(C#N)=NN1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl ZOCSXAVNDGMNBV-UHFFFAOYSA-N 0.000 claims description 17
- IBSREHMXUMOFBB-JFUDTMANSA-N 5u8924t11h Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O3)C=C[C@H](C)[C@@H](C(C)C)O4)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 IBSREHMXUMOFBB-JFUDTMANSA-N 0.000 claims description 17
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- 239000005899 Fipronil Substances 0.000 claims description 17
- 239000005900 Flonicamid Substances 0.000 claims description 17
- 239000005906 Imidacloprid Substances 0.000 claims description 17
- 239000005925 Pymetrozine Substances 0.000 claims description 17
- 239000005663 Pyridaben Substances 0.000 claims description 17
- 239000005930 Spinosad Substances 0.000 claims description 17
- 239000005664 Spirodiclofen Substances 0.000 claims description 17
- 239000005658 Tebufenpyrad Substances 0.000 claims description 17
- 229950008167 abamectin Drugs 0.000 claims description 17
- OMFRMAHOUUJSGP-IRHGGOMRSA-N bifenthrin Chemical compound C1=CC=C(C=2C=CC=CC=2)C(C)=C1COC(=O)[C@@H]1[C@H](\C=C(/Cl)C(F)(F)F)C1(C)C OMFRMAHOUUJSGP-IRHGGOMRSA-N 0.000 claims description 17
- CWFOCCVIPCEQCK-UHFFFAOYSA-N chlorfenapyr Chemical compound BrC1=C(C(F)(F)F)N(COCC)C(C=2C=CC(Cl)=CC=2)=C1C#N CWFOCCVIPCEQCK-UHFFFAOYSA-N 0.000 claims description 17
- 229940013764 fipronil Drugs 0.000 claims description 17
- RLQJEEJISHYWON-UHFFFAOYSA-N flonicamid Chemical compound FC(F)(F)C1=CC=NC=C1C(=O)NCC#N RLQJEEJISHYWON-UHFFFAOYSA-N 0.000 claims description 17
- 229940056881 imidacloprid Drugs 0.000 claims description 17
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 claims description 17
- QHMTXANCGGJZRX-WUXMJOGZSA-N pymetrozine Chemical compound C1C(C)=NNC(=O)N1\N=C\C1=CC=CN=C1 QHMTXANCGGJZRX-WUXMJOGZSA-N 0.000 claims description 17
- DWFZBUWUXWZWKD-UHFFFAOYSA-N pyridaben Chemical compound C1=CC(C(C)(C)C)=CC=C1CSC1=C(Cl)C(=O)N(C(C)(C)C)N=C1 DWFZBUWUXWZWKD-UHFFFAOYSA-N 0.000 claims description 17
- 229940014213 spinosad Drugs 0.000 claims description 17
- DTDSAWVUFPGDMX-UHFFFAOYSA-N spirodiclofen Chemical compound CCC(C)(C)C(=O)OC1=C(C=2C(=CC(Cl)=CC=2)Cl)C(=O)OC11CCCCC1 DTDSAWVUFPGDMX-UHFFFAOYSA-N 0.000 claims description 17
- ZZYSLNWGKKDOML-UHFFFAOYSA-N tebufenpyrad Chemical compound CCC1=NN(C)C(C(=O)NCC=2C=CC(=CC=2)C(C)(C)C)=C1Cl ZZYSLNWGKKDOML-UHFFFAOYSA-N 0.000 claims description 17
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims description 17
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical group [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 16
- 239000005946 Cypermethrin Substances 0.000 claims description 16
- FNELVJVBIYMIMC-UHFFFAOYSA-N Ethiprole Chemical compound N1=C(C#N)C(S(=O)CC)=C(N)N1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl FNELVJVBIYMIMC-UHFFFAOYSA-N 0.000 claims description 16
- 239000005897 Etoxazole Substances 0.000 claims description 16
- 239000005914 Metaflumizone Substances 0.000 claims description 16
- MIFOMMKAVSCNKQ-HWIUFGAZSA-N Metaflumizone Chemical compound C1=CC(OC(F)(F)F)=CC=C1NC(=O)N\N=C(C=1C=C(C=CC=1)C(F)(F)F)\CC1=CC=C(C#N)C=C1 MIFOMMKAVSCNKQ-HWIUFGAZSA-N 0.000 claims description 16
- 239000005929 Spinetoram Substances 0.000 claims description 16
- GOENIMGKWNZVDA-OAMCMWGQSA-N Spinetoram Chemical compound CO[C@@H]1[C@H](OCC)[C@@H](OC)[C@H](C)O[C@H]1OC1C[C@H]2[C@@H]3C=C4C(=O)[C@H](C)[C@@H](O[C@@H]5O[C@H](C)[C@H](CC5)N(C)C)CCC[C@H](CC)OC(=O)CC4[C@@H]3CC[C@@H]2C1 GOENIMGKWNZVDA-OAMCMWGQSA-N 0.000 claims description 16
- 229960005424 cypermethrin Drugs 0.000 claims description 16
- IXSZQYVWNJNRAL-UHFFFAOYSA-N etoxazole Chemical compound CCOC1=CC(C(C)(C)C)=CC=C1C1N=C(C=2C(=CC=CC=2F)F)OC1 IXSZQYVWNJNRAL-UHFFFAOYSA-N 0.000 claims description 16
- MIOBBYRMXGNORL-UHFFFAOYSA-N pyrifluquinazon Chemical compound C1C2=CC(C(F)(C(F)(F)F)C(F)(F)F)=CC=C2N(C(=O)C)C(=O)N1NCC1=CC=CN=C1 MIOBBYRMXGNORL-UHFFFAOYSA-N 0.000 claims description 16
- HOKKPVIRMVDYPB-UVTDQMKNSA-N (Z)-thiacloprid Chemical compound C1=NC(Cl)=CC=C1CN1C(=N/C#N)/SCC1 HOKKPVIRMVDYPB-UVTDQMKNSA-N 0.000 claims description 15
- AWSZRJQNBMEZOI-UHFFFAOYSA-N 2-methoxyethyl 2-(4-tert-butylphenyl)-2-cyano-3-oxo-3-[2-(trifluoromethyl)phenyl]propanoate Chemical compound C=1C=C(C(C)(C)C)C=CC=1C(C#N)(C(=O)OCCOC)C(=O)C1=CC=CC=C1C(F)(F)F AWSZRJQNBMEZOI-UHFFFAOYSA-N 0.000 claims description 15
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- 239000005940 Thiacloprid Substances 0.000 claims description 15
- APJLTUBHYCOZJI-VZCXRCSSSA-N cyenopyrafen Chemical compound CC1=NN(C)C(\C(OC(=O)C(C)(C)C)=C(/C#N)C=2C=CC(=CC=2)C(C)(C)C)=C1C APJLTUBHYCOZJI-VZCXRCSSSA-N 0.000 claims description 15
- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 claims description 15
- YKBZOVFACRVRJN-UHFFFAOYSA-N dinotefuran Chemical compound [O-][N+](=O)\N=C(/NC)NCC1CCOC1 YKBZOVFACRVRJN-UHFFFAOYSA-N 0.000 claims description 15
- VBCVPMMZEGZULK-NRFANRHFSA-N indoxacarb Chemical compound C([C@@]1(OC2)C(=O)OC)C3=CC(Cl)=CC=C3C1=NN2C(=O)N(C(=O)OC)C1=CC=C(OC(F)(F)F)C=C1 VBCVPMMZEGZULK-NRFANRHFSA-N 0.000 claims description 15
- KAATUXNTWXVJKI-NSHGMRRFSA-N (1R)-cis-(alphaS)-cypermethrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-NSHGMRRFSA-N 0.000 claims description 14
- WCXDHFDTOYPNIE-RIYZIHGNSA-N (E)-acetamiprid Chemical compound N#C/N=C(\C)N(C)CC1=CC=C(Cl)N=C1 WCXDHFDTOYPNIE-RIYZIHGNSA-N 0.000 claims description 14
- 239000005875 Acetamiprid Substances 0.000 claims description 14
- 150000002148 esters Chemical class 0.000 claims description 13
- HBAQYPYDRFILMT-UHFFFAOYSA-N 8-[3-(1-cyclopropylpyrazol-4-yl)-1H-pyrazolo[4,3-d]pyrimidin-5-yl]-3-methyl-3,8-diazabicyclo[3.2.1]octan-2-one Chemical class C1(CC1)N1N=CC(=C1)C1=NNC2=C1N=C(N=C2)N1C2C(N(CC1CC2)C)=O HBAQYPYDRFILMT-UHFFFAOYSA-N 0.000 claims description 12
- 125000001153 fluoro group Chemical group F* 0.000 claims description 12
- 239000005877 Alpha-Cypermethrin Substances 0.000 claims description 11
- KVVDRQDTODKIJD-UHFFFAOYSA-N 2-cyclopropylacetic acid Chemical compound OC(=O)CC1CC1 KVVDRQDTODKIJD-UHFFFAOYSA-N 0.000 claims description 10
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- 238000009395 breeding Methods 0.000 claims description 10
- FMPFURNXXAKYNE-UHFFFAOYSA-N [2-ethyl-3,7-dimethyl-6-[4-(trifluoromethoxy)phenoxy]quinolin-4-yl] methyl carbonate Chemical compound C1=C2C(OC(=O)OC)=C(C)C(CC)=NC2=CC(C)=C1OC1=CC=C(OC(F)(F)F)C=C1 FMPFURNXXAKYNE-UHFFFAOYSA-N 0.000 claims description 9
- 230000009471 action Effects 0.000 claims description 9
- NYPJDWWKZLNGGM-UHFFFAOYSA-N fenvalerate Aalpha Natural products C=1C=C(Cl)C=CC=1C(C(C)C)C(=O)OC(C#N)C(C=1)=CC=CC=1OC1=CC=CC=C1 NYPJDWWKZLNGGM-UHFFFAOYSA-N 0.000 claims description 9
- QOIYTRGFOFZNKF-UHFFFAOYSA-N flupyradifurone Chemical compound C=1C(=O)OCC=1N(CC(F)F)CC1=CC=C(Cl)N=C1 QOIYTRGFOFZNKF-UHFFFAOYSA-N 0.000 claims description 9
- 125000000876 trifluoromethoxy group Chemical group FC(F)(F)O* 0.000 claims description 9
- ZXQYGBMAQZUVMI-RDDWSQKMSA-N (1S)-cis-(alphaR)-cyhalothrin Chemical compound CC1(C)[C@H](\C=C(/Cl)C(F)(F)F)[C@@H]1C(=O)O[C@@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-RDDWSQKMSA-N 0.000 claims description 8
- 125000006656 (C2-C4) alkenyl group Chemical group 0.000 claims description 8
- 230000001488 breeding effect Effects 0.000 claims description 8
- 229910052736 halogen Inorganic materials 0.000 claims description 8
- 150000002367 halogens Chemical group 0.000 claims description 8
- 239000005910 lambda-Cyhalothrin Substances 0.000 claims description 8
- 239000005901 Flubendiamide Substances 0.000 claims description 7
- ZGNITFSDLCMLGI-UHFFFAOYSA-N flubendiamide Chemical compound CC1=CC(C(F)(C(F)(F)F)C(F)(F)F)=CC=C1NC(=O)C1=CC=CC(I)=C1C(=O)NC(C)(C)CS(C)(=O)=O ZGNITFSDLCMLGI-UHFFFAOYSA-N 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- 239000001257 hydrogen Substances 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 7
- QZMQZUFFUNIGOE-LBPRGKRZSA-N 3-chloro-1-n-[4-(1,1,1,2,3,3,3-heptafluoropropan-2-yl)-2-methylphenyl]-2-n-[(2s)-1-methylsulfonylpropan-2-yl]benzene-1,2-dicarboxamide Chemical compound CS(=O)(=O)C[C@H](C)NC(=O)C1=C(Cl)C=CC=C1C(=O)NC1=CC=C(C(F)(C(F)(F)F)C(F)(F)F)C=C1C QZMQZUFFUNIGOE-LBPRGKRZSA-N 0.000 claims description 6
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- FIPWRIJSWJWJAI-UHFFFAOYSA-N Butyl carbitol 6-propylpiperonyl ether Chemical compound C1=C(CCC)C(COCCOCCOCCCC)=CC2=C1OCO2 FIPWRIJSWJWJAI-UHFFFAOYSA-N 0.000 claims description 5
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- YLFSVIMMRPNPFK-WEQBUNFVSA-N acrinathrin Chemical compound CC1(C)[C@@H](\C=C/C(=O)OC(C(F)(F)F)C(F)(F)F)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 YLFSVIMMRPNPFK-WEQBUNFVSA-N 0.000 claims description 5
- VHLKTXFWDRXILV-UHFFFAOYSA-N bifenazate Chemical compound C1=C(NNC(=O)OC(C)C)C(OC)=CC=C1C1=CC=CC=C1 VHLKTXFWDRXILV-UHFFFAOYSA-N 0.000 claims description 5
- 125000001028 difluoromethyl group Chemical group [H]C(F)(F)* 0.000 claims description 5
- NYPJDWWKZLNGGM-RPWUZVMVSA-N esfenvalerate Chemical compound C=1C([C@@H](C#N)OC(=O)[C@@H](C(C)C)C=2C=CC(Cl)=CC=2)=CC=CC=1OC1=CC=CC=C1 NYPJDWWKZLNGGM-RPWUZVMVSA-N 0.000 claims description 5
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- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 201000004792 malaria Diseases 0.000 description 1
- 238000004949 mass spectrometry Methods 0.000 description 1
- 125000004184 methoxymethyl group Chemical group [H]C([H])([H])OC([H])([H])* 0.000 description 1
- YLGXILFCIXHCMC-JHGZEJCSSA-N methyl cellulose Chemical compound COC1C(OC)C(OC)C(COC)O[C@H]1O[C@H]1C(OC)C(OC)C(OC)OC1COC YLGXILFCIXHCMC-JHGZEJCSSA-N 0.000 description 1
- 125000006216 methylsulfinyl group Chemical group [H]C([H])([H])S(*)=O 0.000 description 1
- 125000004170 methylsulfonyl group Chemical group [H]C([H])([H])S(*)(=O)=O 0.000 description 1
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- 125000006095 n-butyl sulfinyl group Chemical group 0.000 description 1
- 125000006126 n-butyl sulfonyl group Chemical group 0.000 description 1
- 125000006093 n-propyl sulfinyl group Chemical group 0.000 description 1
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- 239000004477 pesticide formulation type Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
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- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
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- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
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- 150000003141 primary amines Chemical class 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 108020001580 protein domains Proteins 0.000 description 1
- 235000015136 pumpkin Nutrition 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
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- 230000006798 recombination Effects 0.000 description 1
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- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
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- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
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- UJMBCXLDXJUMFB-GLCFPVLVSA-K tartrazine Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-GLCFPVLVSA-K 0.000 description 1
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- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 1
- CZDYPVPMEAXLPK-UHFFFAOYSA-N tetramethylsilane Chemical compound C[Si](C)(C)C CZDYPVPMEAXLPK-UHFFFAOYSA-N 0.000 description 1
- 235000010215 titanium dioxide Nutrition 0.000 description 1
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- 231100000759 toxicological effect Toxicity 0.000 description 1
- PJANXHGTPQOBST-VAWYXSNFSA-N trans-stilbene Chemical compound C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 description 1
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- 125000003866 trichloromethyl group Chemical group ClC(Cl)(Cl)* 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
- A01N43/12—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings condensed with a carbocyclic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/22—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom rings with more than six members
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/76—1,3-Oxazoles; Hydrogenated 1,3-oxazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
Definitions
- Insecticidal active mixtures comprising arylquinazolinone compounds
- the present invention relates to mixtures of active ingredients having synergistically enhanced action and to methods comprising applying said mixtures.
- the present invention relates to pesticidal mixtures comprising as active compounds
- R 1 is Ci-C4-alkyl, fluorinated Ci-C4-alkyl, C2-C4-alkenyl, fluorinated C2-C4- alkenyl, cyclopropyl or cyclopropylmethyl;
- R 2 is hydrogen, halogen, CN, Ci-C4-alkyl or Ci-C4-haloalkyl;
- R 3 is hydrogen, halogen, CN, Ci-C4-alkyl or Ci-C4-haloalkyl;
- R 4 is selected independently from the integer of k from the group consisting of halogen, CN, N0 2 , Ci-C 4 -alkyl, Ci-C 4 -haloalkyl, C 2 -C 4 -alkenyl, C1-C4- haloalkenyl, C2-C4-alkynyl, Ci-C4-haloalkynyl, Ci-C4-alkoxy-Ci-C4-alkyl, Ci- C4-alkoxy, Ci-C4-haloalkoxy, Ci-C4-alkylthio, Ci-C4-haloalkylthio, C1-C4- alkylsulfinyl, Ci-C4-haloalkylsulfinyl, Ci-C4-alkylsulfonyl and C1-C4- haloalkylsulfonyl;
- k 0, 1 , 2, 3 or 4;
- n 0, 1 or 2; or the tautomers, enantiomers, diastereomers or salts thereof, and
- aldicarb alanycarb, benfuracarb, carbaryl, carbofuran, carbosulfan, methiocarb, methomyl, oxamyl, pirimicarb, propoxur and thiodicarb; or
- fiproles consisting of ethiprole, fipronil, pyrafluprole and pyriprole
- sodium channel modulators from the class of pyrethroids consisting of acrinathrin, allethrin, bifenthrin, cyfluthrin, lambda-cyhalothrin, cyper- methrin, alpha-cypermethrin, beta-cypermethrin, zeta-cypermethrin, deltamethrin, esfenvalerate, etofenprox, fenpropathrin, fenvalerate, flucythrinate, tau-fluvalinate, permethrin, silafluofen and tralomethrin; nicotinic acteylcholine receptor agonists from the class of neonico- tinoids consisting of
- diafenthiuron, fenbutatin oxide and propargite uncouplers of oxidative phosphorylation such as chlorfenapyr
- nicotinic acetylcholine receptor channel blockers such as
- II-M.16 moulting disruptors such as cyromazine; II-M.17 Ecdyson receptor agonists such as
- Voltage-dependent sodium channel blockers such as
- Inhibitors of the lipid synthesis such as
- the present invention also provides methods for the control of insects, acarids or nematodes comprising contacting the insect, acarid or nematode or their food supply, habitat, breeding grounds or their locus with a pesticidally effective amount of mixtures of at least one active compound I with at least one active compound II.
- the present invention also relates to a method of protecting plants from attack or infestation by insects, acarids or nematodes comprising contacting the plant, or the soil or water in which the plant is growing, with a pesticidally effective amount of a mixture of at least one active compound I with at least one active compound II.
- the invention also provides a method for the protection of plant propagation material, preferably seeds, from soil insects and of the seedlings' roots and shoots from soil and foliar insects which comprises contacting the plant progagation material as e.g. the seeds before sowing and/or after pregermination with a pesticidally effective amount of a mixture of at least one active compound I with at least one active compound II.
- the invention also provides seeds comprising a mixture of at least one active compound I with at least one active compound II.
- the invention also relates to the use of a mixture of at least one active compound I with at least one active compound II for combating insects, arachnids or nematodes.
- halogen denotes in each case fluorine, bromine, chlorine or iodine, in particular fluorine, chlorine or bromine.
- Ci-C4-alkyl refers to saturated straight-chain or branched hydrocarbon radicals having 1 , 2, 3 or 4carbon atoms.
- Ci-C2-Alkyl is methyl or ethyl.
- Ci-C 4 -Alkyl is additionally also, for example, pro-pyl, isopropyl, butyl, 1 methylpropyl (sec-butyl), 2-methylpropyl (isobutyl) or 1 , 1 -dimethylethyl (tert-butyl).
- Ci-C 4 -haloalkyl refers to straight-chain or branched alkyl groups having 1 , 2, 3 or 4 carbon atoms (as mentioned above), where some or all of the hydrogen atoms in these groups may be replaced by halogen atoms as mentioned above: in particular Ci-C 4 -haloalkyl, such as chloromethyl, bromomethyl, dichloromethyl, trichloromethyl, fluoromethyl, difluoro-methyl, trifluoromethyl, chloro- fluoromethyl, dichlorofluoromethyl, chlorodifluoromethyl, 1 -chloroethyl, 1 -bromoethyl, 1 - fluoroethyl, 2-fluoroeth
- Ci-C 4 -fluoroalkyl or "fluorinated Ci-C 4 -alkyl” as used herein refers to straight-chain or branched alkyl groups having 1 to 4 carbon atoms (as mentioned above), where some or all of the hydrogen atoms in these groups may be replaced by fluorine atoms: examples include fluoromethyl, difluoromethyl, trifluoromethyl, 1 - fluoroethyl, 2-fluoroethyl, 2,2 difluoroethyl, 2,2,2-trifluoroethyl, pentafluoroethyl, 2,2,3,3- tetrafluoropropyl, 3,3-difluoropropyl, 2,3,3-trifluoropropyl, 2,2,3,3,3-pentafluoropropyl, 4,4-difluorobutyl, 4,4,4-trifluorobutyl, 3,4,4-trifluorobutyl, 3,4,4-tri
- C2-C4-alkenyl refers to monounsaturated straight-chain or branched hydrocarbon radicals having 2 to 4 carbon atoms and a double bond in any position, for example such as ethenyl, 1 -propenyl, 2-propenyl, 1 -methylethenyl, 1 butenyl, 2-butenyl, 3-butenyl, 1 - methyl-1 -propenyl, 2-methyl-1 -propenyl, 1 -methyl-2-propenyl, 2-methyl-2-propenyl and the like.
- C2-C4-haloalkenyl refers to unsaturated straight-chain or branched hydrocarbon radicals having 2 to 4 carbon atoms and a double bond in any position (as mentioned above), where some or all of the hydrogen atoms in these groups may be replaced by halogen atoms as mentioned above, in par-ticular fluorine, chlorine and bromine, for example 2-chlorovinyl, 2-chloroallyl (2-chloro-2-propen-1 -yl), 3-chloro-2-propen-1 -yl, 3,3-dichloro-2-propen-1 -yl, 2-fluorovinyl, 2,2-fluorovinyl, 3,3- difluoro-2-propen-1 -yl, 2,3,3-trifluoro-2-propen-1 -yl, 4,4-di
- C2-C4-fluoroalkenyl or “fluorinated C2-C4-alkenyl” as used herein refers to straight-chain or branched alkenyl groups having 2 to 4 carbon atoms (as mentioned above), where some or all of the hydrogen atoms in these groups may be replaced by fluorine atoms; examples include: 2-fluorovinyl, 2,2-fluorovinyl, 3,3-difluoro-2-propen-1 - yl, 2,3,3-trifluoro-2-propen-1 -yl, 4,4-difluoro-3-buten-1 -yl and 3,4,4-trifluoro-3-buten-1 - yi-
- C2-C4-alkynyl as used herein and the alkynyl moieties in alkynyloxy, al- kynylcarbonyl and the like refers to straight-chain or branched hydrocarbon groups having 2 to 4 carbon atoms and one
- Ci-C4-Alkoxy is methoxy or ethoxy.
- Ci-C4-Alkoxy is additionally also, for example, propoxy, isopropoxy, butoxy, 1 methylpropoxy (sec-butoxy), 2-methylpropoxy (isobutoxy) or 1 ,1 - dimethylethoxy (tert-butoxy).
- Ci-C4-alkylthio refers alkyl radicals as defined above having 1 to 4 carbon atoms which are bound to the remainder of the molecule via a sulphur atom; examples being methylthio, ethylthio, n-propylthio, isopropylthio, n-butylthio and tert.-butylthio.
- Ci-C4-alkylsulfonyl refers alkyl radicals as defined above having 1 to 4 carbon atoms which are bound to the remainder of the molecule via a S(0)2 group; examples being methylsulfonyl, ethylsulfonyl, n-propylsulfonyl, isopropyl- sulfonyl, n-butylsulfonyl and tert.-butylsulfonyl.
- Ci-C4-alkylsulfinyl refers alkyl radicals as defined above having 1 to 4 carbon atoms which are bound to the remainder of the molecule via a S(O) group; examples being methylsulfinyl, ethylsulfinyl, n-propylsulfinyl, isopropyl-sulfinyl, n-butylsulfinyl and tert.-butylsulfinyl.
- Ci-C4-haloalkoxy refers haloalkyl radicals as defined above having 1 to 4 carbon atoms which are bound to the remainder of the molecule via an oxygen atom groups having 1 to 4 carbon atoms (as mentioned above), where some or all of the hydrogen atoms in these groups may be replaced by fluorine atoms: examples include fluoromethoxy, difluoromethoxy, trifluoromethoxy, 1 -fluoroethoxy, 2- fluoroethoxy, 2,2 difluoroethoxy, 2,2,2-trifluoroethoxy, 2-chloro-2-fluoroethoxy, 2-chloro- 2,2-difluoroethoxy, pentafluoroethoxy, 2,2,3,3-tetrafluoropropoxy, 3,3-difluoropropoxy, 2,3,3-trifluoropropoxy, 2,2,3,3,3-pentafluoropropoxy, 4,4-difluorobutoxy
- Ci-C4-haloalkylthio refers haloalkyl radicals as defined above having 1 to 4 carbon atoms which are bound to the remainder of the molecule via a sulphur atom: examples include fluoromethylthio, difluoromethylthio, trifluoro- methylthio, 1 -fluoroethylthio, 2-fluoroethylthio, 2,2 difluoroethylthio, 2,2,2- trifluoroethylthio, 2-chloro-2-fluoroethylthio, 2-chloro-2,2-difluoroethylthio, pentafluoro- ethylthio, 2,2,3,3-tetrafluoropropylthio, 3,3-difluoropropylthio, 2,3,3-trifluoropropylthio, 2,2,3,3,3-pentafluoropropylthio, 4,4
- Ci-C4-haloalkylsulfonyl refers haloalkyl radicals as defined above having 1 to 4 carbon atoms which are bound to the remainder of the molecule via a S(0)2 group; examples include fluoromethylsulfonyl, difluoromethylsulfonyl, tri- fluoromethylsulfonyl, 1 -fluoroethylsulfonyl, 2-fluoroethylsulfonyl, 2,2 difluoroethyl- sulfonyl, 2,2,2-trifluoroethylsulfonyl, pentafluoroethylsulfonyl, 2,2,3,3- tetrafluoropropylsulfonyl, 3,3-difluoropropylsulfonyl, 2,3,3-trifluoropropylsulfonyl, 2,2,3,3,3-penta
- Ci-C4-haloalkylsulfinyl refers haloalkyl radicals as defined above having 1 to 4 carbon atoms which are bound to the remainder of the molecule via a S(O) group; examples include fluoromethylsulfinyl, difluoromethylsulfinyl, trifluo- romethylsulfinyl, 1 -fluoroethylsulfinyl, 2-fluoroethylsulfinyl, 2,2 difluoroethylsulfinyl, 2,2,2-trifluoroethylsulfinyl, pentafluoroethylsulfinyl, 2,2,3,3-tetrafluoropropylsulfinyl, 3,3- d ifl uoropropylsu Ifi nyl , 2,3,3-trifluoropropylsulfinyl, 2,2,
- Ci-C4-alkoxy-Ci-C4-alkyl refers to a linear or branched Ci- C4-alkyl radical as defined above, which is substituted by an Ci-C4-alkoxy radical, in particular to methoxymethyl, ethoxymethyl, n-propoxymethyl, n-butoxyethyl, 2- methoxyethyl, 2-ethoxyethyl, 2-(n-propoxy)ethyl, 2-(n-butoxy)ethyl, 2-methoxypropyl, 2- ethoxypropyl, 2-(n-propoxy) propyl, 2-(n-butoxy)propyl, 3-methoxypropyl, 3- ethoxypropyl, 3-(n-propoxy) propyl, 3-(n-butoxy)propyl, 4-methoxybutyl and 4- ethoxybutyl.
- the compounds I of formula (I) and their examples include their tautomers, racemic mixtures, individual pure enantiomers and diasteroemers and their optically active mixtures.
- Compounds II include their tautomers, racemic mixtures, individual pure enantiomers and diasteroemers and their optically active mixtures.
- the commercially available compounds II of the group M may be found in The Pesticide Manual, 15h Edition, British Crop Protection Council (2010) among other publica- tions.
- Cyanthraniliprole (Cyazypyr) is known from e.g. WO 2004/067528. Sulfoxaflor has been described in e.g. WO 2007/095229. Fluensulfone has been described in WO 2001/002378.
- the phthalamide compounds (R)-3-Chlor-N1 - ⁇ 2-methyl-4-[1 ,2,2,2- tetrafluor-1 -(trifluormethyl)ethyl]phenyl ⁇ -N2-(1 -methyl-2-methylsulfonylethyl) phthalamid and (S)-3-Chlor-N1 - ⁇ 2-methyl-4-[1 ,2,2,2- tetrafluor-1 -(trifluormethyl) ethyl]phenyl ⁇ -N2- (1 -methyl-2-methylsulfonylethyl)phthalamid are known from WO 2007/101540.
- the isoxazoline compound 4-[5-(3,5-Dichloro-phenyl)-5-trifluoromethyl-4,5-dihydro- isoxazol-3-yl]-2-methyl-N-[(2,2,2-trifluoro-ethylcarbamoyl)-methyl]-benzamide has been described in e.g. WO2005/085216, WO 2007/079162, WO 2007/026965, WO
- the pyripyropene derivative cyclopropane-acetic acid, 1 ,1 '- [(3S,4R,4aR,6S,6aS, 12R, 12aS, 12bS)-4-[[(2-cyclopropylacetyl)oxy]methyl]- 1 ,3,4,4a,5,6,6a,12,12a,12b-decahydro-12-hydroxy-4,6a,12b-trimethyl-1 1 -oxo-9-(3- pyridinyl)-2H,1 1 H-naphtho[2,1 -b]pyrano[3,4-e]pyran-3,6-diyl] ester has been described in WO2006/129714, WO 2008/66153 and WO 2008/108491 .
- the quinoline compound carbonic acid-2-ethyl-3,7-dimethyl-6-(4-trifluoromethoxy-phenoxy)-quinolin-4-yl ester methyl ester has
- R 2 is selected from chlorine, methyl, difluoromethyl, trifluoromethyl or cyano.
- R 2 is selected from chlorine, methyl, difluoromethyl, trifluoromethyl or cyano and R 3 is selected from hydrogen, fluorine, chlorine, methyl or trifluoromethyl.
- k is 1 , 2 or 3
- R 4 is selected independently from the integer of k from fluorine, chlorine, CN, NO2, methyl, trifluoromethyl, ,methoxy difluoromethoxy or trifluoromethoxy.
- R 4 is selected from fluorine, chlorine, methyl, trifluoromethyl, methoxy, difluoromethoxy and trifluoromethoxy,
- n 0 or 1.
- R 4 is selected from fluorine, chlorine, methyl, trifluoromethyl, methoxy, difluoromethoxy and trifluoromethoxy.
- the compounds I of formula l-A-2 carry a chiral sulfoxide group, so that they form two enantiomers with R- or S-configuration at the sulphur atom:
- n 0 or 1.
- the compound I of formula (l-B-2) carries a chiral sulfoxide group, so that it forms the following two enantiomers with R- or S-configuration at the sulphur atom:
- Examples of preferred arylquinazolinone compounds I of the present invention are of the following formula (l-C)
- R 4 is selected from fluorine, chlorine, methyl, trifluoromethyl, methoxy, difluo- romethoxy and trifluoromethoxy, and wherein n is 0 or 1 .
- R 4 is selected from fluorine, chlorine, methyl, trifluoromethyl, methoxy, difluo- romethoxy and trifluoromethoxy.
- R 4 is selected from fluorine, chlorine, methyl, trifluoromethyl, methoxy, difluo- romethoxy and trifluoromethoxy.
- the compounds of formula l-C-2 carry a chiral sulfoxide group, so that they form two enantiomers with R- or S-configuration at the sulphur atom:
- Examples of especially preferred arylquinazolinone compounds I of the present inven- tion are of formula (l-C) wherein R 4 and n are defined in one row of table C.1.1
- the compound II selected from group M-II.1.A as defined above is preferably carbofuran, benfuracarb or methomyl.
- the compound II selected from group M-II.2.B as defined above is preferably ethiprole or fipronil.
- the compound II selected from group M-II.3 defined above is preferably acrinathrin, bifenthrin, cyfluthrin, lambda-cyhalothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, zeta- cypermethrin, deltamethrin, esfenvalerate, etofenprox, fenpropathrin, flucythrinate, tau- fluvalinate, silafluofen or tralomethrin.
- the compound II is lambda-cyhalothrin, alpha-cypermethrin, bifenthrin or deltamethrin.
- the compound II selected from group M-II.4 as defined above is preferably acetamiprid, chlothianidin, dinotefuran, imidacloprid, nitenpyram, thiacloprid and thiamethoxam.
- the compound II is acetamiprid, clothianidine, dinotefuran, imidacloprid or thiamethoxam.
- the compound II selected from group M-II.5 as defined above is preferably spinosad or spinetoram. More preferably the compound II is spinosad.
- the compound II selected from group M-II.6 as defined above is preferably abamectin, emamectin ben- zoate, lepimectin or milbemectin.
- the compound II is abamectin.
- the compound II selected from group M-II.9 as defined above is preferably pymetrozine, flonicamid or pyrifluquinazone.
- the compound II selected from group II-M.10 as defined above is preferably etoxazole.
- the compound II selected from group II-M.12 as defined above is preferably chlorfenapyr.
- the compound II selected from group II-M.15 as defined above is preferably buprofezin.
- the compound II selected from group II-M.19.A as defined above is preferably pyridaben or
- the compound II selected from group M-II.20 as defined above is preferably indoxacarb or metaflumizo- ne.
- the compound II is metaflumizone.
- the compound II selected from group M-II.21 as defined above is preferably spirodiclofen, spiromesifen or spirotetramat.
- the compound II is spiromesifen or spirotetramat.
- the compound II selected from group M-II.22 as defined above is preferably flubendiamide, (R)-3-Chlor- N 1 - ⁇ 2-methyl-4-[1 ,2,2,2 - tetrafluor-1 -(trifluormethyl)ethyl]phenyl ⁇ -N2-(1 -methyl-2- methylsulfonylethyl)phthalamid and (S)-3-Chlor-N1 - ⁇ 2-methyl-4-[1 ,2,2,2 - tetrafluor-1 - (trifluormethyl)ethyl]phenyl ⁇ -N2-(1 -methyl-2-methylsulfonylethyl)phthalamid, chloran- thraniliprole or cyanthraniliprole.
- the compound II is flubendiamide, chloranthraniliprole or cyanthraniliprole.
- the compound II selected from group M-II.23 as defined above is preferably bifenazate, piperonyl butox- ide, pyridalyl, sulfoxaflor, the compound 4-[5-(3,5-Dichloro-phenyl)-5-trifluoromethyl- 4,5-dihydro-isoxazol-3-yl]-2-methyl-N-[(2,2,2-trifluoro-ethylcarbamoyl)-methyl]- benzamide, the compound cyclopropaneacetic acid, 1 ,1 '- [(3S,4R,4aR,6S,6aS, 12R, 12aS, 12bS)-4-[[(2-cyclopropylacetyl)oxy]methyl]-
- the compound II is cyclopropaneacetic acid, 1 ,1 '- [(3S,4R,4aR,6S,6aS, 12R, 12aS, 12bS)-4-[[(2-cyclopropylacetyl)oxy]methyl]- 1 ,3,4,4a,5,6,6a,12,12a,12b-decahydro-12-hydroxy-4,6a,12b-trimethyl-1 1 -oxo-9-(3- pyridinyl)-2H,1 1 H-naphtho[2,1 -b]pyrano[3,4-e]pyran-3,6-diyl] ester or 4- ⁇ [(6- Chloropyrid-3-yl)methyl](2,2-difluoroethyl)amino ⁇ furan-2(5H)-one or carbonic acid-2- ethyl-3,7-dimethyl-6-(4-trifluoromethoxy-phenoxy)-quinol
- pesticidal mixtures containing fipronil as compound II are Especially preferred.
- Especia y preferred are pesticida mixtures containing imidacloprid as compound II.
- Especia y preferred are pesticida mixtures containing thiamethoxam as compound II.
- Especia y preferred are pesticida mixtures containing pymetrozine as compound II.
- Especia y preferred are pesticida mixtures containing spirotetramat as compound II.
- Especia y preferred are pesticida mixtures containing chlorfenapyr as compound II.
- Especia y preferred are pesticida mixtures containing chlorantraniliprole as compound II.
- Especia y preferred are pesticida mixtures containing cyanthraniliprole as compound II.
- Especia y preferred are pesticida mixtures containing sulfoxaflor as compound II.
- pesticidal mixtures containing the compound 4- ⁇ [(6- chloropyrid-3-yl)methyl](2,2-difluoroethyl)amino ⁇ furan-2(5H)-one of formula CM.23-2:
- inventive mixtures according to the invention Especially preferred are inventive mixtures wherein the compound II of group M is fipronil and the compound I of formula I is a compound of Table C.I.1. Especially preferred are inventive mixtures wherein the compound II of group M is ethiprole and the compound I of formula I is a compound of Table C.I.1 .
- inventive mixtures wherein the compound II of group M is al- pha-cypermethrin and the compound I of formula I is a compound of Table C.I.1.
- inventive mixtures wherein the compound II of group M is lambda-cyhalothrin and the compound I of formula I is a compound of Table C.I .1. Especially preferred are inventive mixtures wherein the compound II of group M is bifenthrin and the compound I of formula I is a compound of Table C.I .1.
- inventive mixtures wherein the compound II of group M is del- tamethrin and the compound I of formula I is a compound of Table C.I.1 .
- inventive mixtures wherein the compound II of group M is clo- thianidin and the compound I of formula I is a compound of Table C.I.1 .
- inventive mixtures wherein the compound II of group M is di- notefuran and the compound I of formula I is a compound of Table C.I .1.
- inventive mixtures wherein the compound II of group M is im- idacloprid and the compound I of formula I is a compound of Table C.I.1 .
- inventive mixtures wherein the compound II of group M is thi- amethoxam and the compound I of formula I is a compound of Table C.I.1 .
- inventive mixtures wherein the compound II of group M is spi- nosad and the compound I of formula I is a compound of Table C.I.1 .
- inventive mixtures wherein the compound II of group M is spinetoram and the compound I of formula I is a compound of Table C.I .1.
- inventive mixtures wherein the compound II of group M is abamectin and the compound I of formula I is a compound of Table C.I.1 .
- inventive mixtures wherein the compound II of group M is pymetrozine and the compound I of formula I is a compound of Table C.I.1 .
- inventive mixtures wherein the compound II of group M is flonicamid and the compound I of formula I is a compound of Table C.I.1 .
- inventive mixtures wherein the compound II of group M is pyri- fluqunazone and the compound I of formula I is a compound of Table C.I .1.
- inventive mixtures wherein the compound II of group M is etoxazole and the compound I of formula I is a compound of Table C.I .1.
- inventive mixtures wherein the compound II of group M is chlorfenapyr and the compound I of formula I is a compound of Table C.I.1.
- inventive mixtures wherein the compound II of group M is pyridaben and the compound I of formula I is a compound of Table C.I.1 .
- inventive mixtures wherein the compound II of group M is tebufenpyrad and the compound I of formula I is a compound of Table C.I.1.
- inventive mixtures wherein the compound II of group M is cye- nopyrafen and the compound I of formula I is a compound of Table C.I.1 .
- inventive mixtures wherein the compound II of group M is cyflumetofen and the compound I of formula I is a compound of Table C.I.1 .
- inventive mixtures wherein the compound II of group M is in- doxacarb and the compound I of formula I is a compound of Table C.I.1.
- inventive mixtures wherein the compound II of group M is met- aflumizone and the compound I of formula I is a compound of Table C.I.1 .
- inventive mixtures wherein the compound II of group M is spi- rodiclofen and the compound I of formula I is a compound of Table C.I .1.
- inventive mixtures wherein the compound II of group M is spi- romesifen and the compound I of formula I is a compound of Table C.I.1 .
- inventive mixtures wherein the compound II of group M is spi- rotetramat and the compound I of formula I is a compound of Table C.I.1 .
- inventive mixtures wherein the compound II of group M is flubendiamide and the compound I of formula I is a compound of Table C.I.1. Especially preferred are inventive mixtures wherein the compound II of group M is chlorantraniliprole and the compound I of formula I is a compound of Table C.I.1.
- inventive mixtures wherein the compound II of group M is the cyanthraniliprole and the compound I of formula I is a compound of Table C.I .1.
- inventive mixtures wherein the compound II of group M is the sulfoxaflor and the compound I of formula I is a compound of Table C.I.1 .
- inventive mixtures wherein the compound II of group M is the cyclopropaneacetic acid, 1 ,1 '-[(3S,4R,4aR,6S,6aS,12R,12aS,12bS)-4-[[(2- cyclopropylacetyl)oxy]methyl]-1 ,3,4,4a,5,6,6a,12,12a,12b-decahydro-12-hydroxy- 4,6a, 12b-trimethyl-1 1 -oxo-9-(3-pyridinyl)-2H , 1 1 H-naphtho[2, 1 -b]pyrano[3,4-e]pyran- 3,6-diyl] ester of formula C.11-23.1 and the compound I of formula I is a compound of Table C.I.1 .
- inventive mixtures wherein the compound II of group M is the 4- ⁇ [(6-chloropyrid-3-yl)methyl](2,2-difluoroethyl)amino ⁇ furan-2(5H)-one of formula C.ll- 23.2 and the compound I of formula I is a compound of Table C.I.1.
- inventive mixtures wherein the compound II of group M is the carbonic acid-2-ethyl-3,7-dimethyl-6-(4-trifluoromethoxy-phenoxy)-quinolin-4-yl ester methyl ester of formula C.II-23.3 and the compound I of formula I is a compound of Table C.I.1 .
- table M represents perferred combinations of the active compounds I of formula I as defined in table C.1.1 and the active compounds II of group M in mixtures according to the invention:
- Insects from the order of the lepidopterans for example Agrotis ypsilon, Agrotis segetum, Alabama argillacea, Anticarsia gemmatalis, Argyresthia conjugella, Autographa gamma, Bupalus piniarius, Cacoecia murinana, Capua reticulana, Chei- matobia brumata, Choristoneura fumiferana, Choristoneura occidentalis, Cirphis unipuncta, Cydia pomonella, Dendrolimus pini, Diaphania nitidalis, Diatraea grandiosel- la, Earias insulana, Elasmopalpus lignosellus, Eupoecilia ambiguella, Evetria bouliana, Feltia subterranea, Galleria mellonella, Grapholitha funebrana, Grapholitha molesta,
- Dichromothrips corbetti Dichromothrips ssp , Frankliniella fusca, Frankliniella occidentalis, Frankliniella tritici, Scirtothrips citri, Thrips oryzae, Thrips palmi and Thrips tabaci, termites (Isoptera), e.g. Calotermes flavicollis, Leucotermes flavipes, Heterotermes aureus, Reticulitermes flavipes, Reticulitermes virginicus, Reticulitermes lucifugus, Termes natalensis, and Coptotermes formosanus, cockroaches (Blattaria - Blattodea), e.g.
- Blattella germanica Blattella asahinae, Peri- planeta americana, Periplaneta japonica, Periplaneta brunnea, Periplaneta fuligginosa, Periplaneta australasiae, and Blatta orientalis, true bugs (Hemiptera), e.g.
- Hoplocampa minuta Hoplocampa testudinea, Monomorium pha- raonis, Solenopsis geminata, Solen
- Vespula squamosa Paravespula vulgaris, Paraves- pula pennsylvanica, Paravespula germanica, Dolichovespula maculata, Vespa crabro, Polistes rubiginosa, Camponotus floridanus, and Linepithema humile, crickets, grasshoppers, locusts (Orthoptera), e.g.
- Arachnoidea such as arachnids (Acarina), e.g.
- Argasidae Ixodidae and Sarcoptidae, such as Amblyomma americanum, Amblyomma variegatum, Ambryomma maculatum, Argas persicus, Boophilus annulatus, Boophilus decoloratus, Boophilus microplus, Dermacentor silvarum, Dermacentor andersoni, Dermacentor variabilis, Hy- alomma truncatum, Ixodes ricinus, Ixodes rubicundus, Ixodes scapularis, Ixodes holo- cyclus, Ixodes pacificus, Ornithodorus moubata, Ornithodorus hermsi, Ornithodorus turicata, Ornithonyssus bacoti, Otobius megnini, Dermanyssus gallinae, Psoroptes ovis, Rhipicephalus sanguineus, Rhipicephal
- Tetranychidae spp. such as Tetranychus cinnabarinus, Tetranychus kanzawai,
- Earwigs (DermapteraJ, e.g. forficula auricularia, lice (Phthiraptera), e.g. Pediculus humanus capitis, Pediculus humanus corporis, Pthi- rus pubis, Haematopinus eurystemus, Haematopinus suis, Linognathus vituli, Bovicola bovis, Menopon gallinae, Menacanthus stramineus and Solenopotes capillatus.
- Plant parasitic nematodes such as root-knot nematodes, Meloidogyne arenaria, Me- loidogyne chitwoodi, Meloidogyne exigua, Meloidogyne hapla, Meloidogyne incognita, Meloidogyne javanica and other Meloidogyne species; cyst nematodes, Globodera rostochiensis, Globodera pallida, Globodera tabacum and other Globodera species, Heterodera avenae, Heterodera glycines, Heterodera schachtii, Heterodera trifolii, and other Heterodera species; seed gall nematodes, Anguina funesta, Anguina tritici and other Anguina species; stem and foliar nematodes, Aphelenchoides besseyi, Aphe- lenchoides fragariae, Aphelenchoides
- inventive mixtures are preferably useful for the control of nematodes of the order of Rhabditida, especially Rhabditidae such as Caenorhabditis ssp.
- the mixtures of the present invention are especially suitable for efficiently combating pests like insects from the order of the lepidopterans (Lepidoptera), beetles (Coleop- tera), flies and mosquitoes (Diptera), thrips (Thysanoptera), termites (Isoptera), bugs, aphids, leafhoppers, whiteflies, scale insects, cicadas (Hemiptera), ants, bees, wasps, sawflies (Hymenoptera), crickets, grasshoppers, locusts (Orthoptera), and also Arach- noidea, such as arachnids (Acarina).
- inventive mixtures are preferably useful for the control of Arachnoidae, especially for arachnids (Acarina) and more especially against mites (Tetranychus spp).
- the mixtures according to the present invention can be converted into the customary formulations, for example solutions, emulsions, suspensions, dusts, powders, pastes and granules.
- the use form depends on the particular intended purpose; in each case, it should ensure a fine and even distribution of the compounds according to the invention.
- the invention also relates to agrochemical compositions comprising an auxiliary and a mixture of at least one compound I of formula I and of at least one com- pound II according to the present invention.
- An agrochemical composition comprises a pesticidally effective amount of a pesticidal mixture.
- effective amount denotes an amount of the composition or of the mixture, which is sufficient for controlling harmful pests on cultivated plants or in the protection of materials and which does not result in a substantial damage to the treated plants. Such an amount can vary in a broad range and is dependent on various factors, such as the animal pests species to be con-trolled, the treated cultivated plant or material, the climatic conditions and the specific mixture used.
- compositions e.g. solutions, emulsions, suspensions, dusts, powders, pastes, gran-ules, pressings, capsules, and mixtures thereof.
- composition types are suspen-sions (e.g. SC, OD, FS), emulsifiable concentrates (e.g. EC), emulsions (e.g. EW, EO, ES, ME), capsules (e.g. CS, ZC), pastes, pastilles, wettable powders or dusts (e.g. WP, SP, WS, DP, DS), pressings (e.g.
- compositions types are defined in the " Catalogue of pes-ticide formulation types and international coding system" , Technical Monograph No. 2, 6th Ed. May 2008, CropLife International.
- compositions are prepared in a known manner, such as described by Mollet and Grube-mann, Formulation technology, Wiley VCH, Weinheim, 2001 ; or Knowles, New developments in crop protection product formulation, Agrow Reports DS243, T&F In- forma, London, 2005.
- auxiliaries are solvents, liquid carriers, solid carriers or fillers, surfactants, dis- persants, emulsifiers, wetters, adjuvants, solubilizers, penetration enhancers, protective colloids, adhe-sion agents, thickeners, humectants, repellents, attractants, feeding stimulants, compatibilizers, bactericides, anti-freezing agents, anti-foaming agents, colorants, tackifiers and binders.
- Suitable solvents and liquid carriers are water and organic solvents, such as mineral oil frac-tions of medium to high boiling point, e.g. kerosene, diesel oil; oils of vegetable or animal origin; aliphatic, cyclic and aromatic hydrocarbons, e. g. toluene, paraffin, tetra- hydronaphthalene, alky-lated naphthalenes; alcohols, e.g. ethanol, propanol, butanol, benzylalcohol, cyclo ⁇ hexanol; gly-cols; DMSO; ketones, e.g. cyclohexanone; esters, e.g.
- mineral oil frac-tions of medium to high boiling point e.g. kerosene, diesel oil
- oils of vegetable or animal origin oils of vegetable or animal origin
- aliphatic, cyclic and aromatic hydrocarbons e. g. toluene, paraffin, tetra-
- lactates carbonates, fatty acid esters, gamma-butyrolactone; fatty acids; phos- phonates; amines; amides, e.g. N-methylpyrrolidone, fatty acid dimethylamides; and mixtures thereof.
- Suitable solid carriers or fillers are mineral earths, e.g. silicates, silica gels, talc, kaolins, lime-stone, lime, chalk, clays, dolomite, diatomaceous earth, bentonite, calcium sulfate, magnesium sulfate, magnesium oxide; polysaccharides, e.g. cellulose, starch; fertilizers, e.g. ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas; products of vegetable origin, e.g. ce-real meal, tree bark meal, wood meal, nutshell meal, and mixtures thereof.
- Suitable surfactants are surface-active compounds, such as anionic, cationic, nonionic and am-photeric surfactants, block polymers, polyelectrolytes, and mixtures thereof. Such surfactants can be used as emusifier, dispersant, solubilizer, wetter, penetration enhancer, protective col-loid, or adjuvant. Examples of surfactants are listed in McCutcheon' s, Vol.1 : Emulsifiers & De-tergents, McCutcheon' s Directories, Glen Rock, USA, 2008 (International Ed. or North American Ed.).
- Suitable anionic surfactants are alkali, alkaline earth or ammonium salts of sulfonates, sulfates, phosphates, carboxylates, and mixtures thereof.
- sulfonates are alkylarylsulfonates, diphenylsulfonates, alpha-olefin sulfonates, lignine sulfonates, sulfonates of fatty acids and oils, sulfonates of ethoxylated alkylphenols, sulfonates of alkoxylated arylphenols, sulfonates of con-densed naphthalenes, sulfonates of do- decyl- and tridecylbenzenes, sulfonates of naphthalenes and alkyhnaphthalenes, sul- fosuccinates or sulfosuccinamates.
- Examples of sulfates are sulfates of fatty acids and oils, of ethoxylated alkylphenols, of alcohols, of ethoxylated alcohols, or of fatty acid esters.
- Examples of phosphates are phosphate esters.
- Examples of carboxylates are alkyl carboxylates, and carboxylated alcohol or alkylphenol ethoxylates.
- Suitable nonionic surfactants are alkoxylates, N-subsituted fatty acid amides, amine oxides, esters, sugar-based surfactants, polymeric surfactants, and mixtures thereof.
- alkoxylates are compounds such as alcohols, alkylphenols, amines, amides, arylphenols, fatty acids or fatty acid esters which have been alkoxylated with 1 to 50 equivalents.
- Ethylene oxide and/or propylene oxide may be employed for the alkoxylation, preferably ethylene oxide.
- Exam-pies of N-subsititued fatty acid amides are fatty acid glucamides or fatty acid alkanolamides.
- esters are fatty acid esters, glycerol esters or monoglycerides.
- sugar-based surfactants are sorbitans, ethoxylated sorbitans, sucrose and glucose esters or alkyl-polyglucosides.
- polymeric surfactants are home- or copolymers of vinylpyrrolidone, vinyl- alcohols, or vinylacetate.
- Suitable cationic surfactants are quaternary surfactants, for example quaternary ammonium compounds with one or two hydrophobic groups, or salts of long-chain primary amines.
- Suitable amphoteric surfactants are alkylbetains and imidazolines.
- Suitable block polymers are block polymers of the A-B or A-B-A type comprising blocks of poly- ethylene oxide and polypropylene oxide, or of the A-B-C type comprising alkanol, polyethylene oxide and polypropylene oxide.
- Suitable polyelectrolytes are polyacids or pol- ybases. Examples of polyacids are alkali salts of polyacrylic acid or polyacid comb polymers. Examples of polybases are polyvinylamines or poly-ethyleneamines.
- Suitable adjuvants are compounds, which have a neglectable or even no pesticidal activity themselves, and which improve the biological performance of the compound I on the target.
- examples are surfactants, mineral or vegetable oils, and other auxilaries. Further examples are listed by Knowles, Adjuvants and additives, Agrow Reports DS256, T&F Informa UK, 2006, chapter 5.
- Suitable thickeners are polysaccharides (e.g. xanthan gum, carboxymethylcellulose), anorganic clays (organically modified or unmodified), polycarboxylates, and silicates.
- Suitable bactericides are bronopol and isothiazolinone derivatives such as alkylisothia- zolinones and benzisothiazolinones.
- Suitable anti-freezing agents are ethylene glycol, propylene glycol, urea and glycerin.
- Suitable anti-foaming agents are silicones, long chain alcohols, and salts of fatty acids.
- Suitable colorants are pigments of low water solubility and water-soluble dyes.
- examples are inorganic colorants (e.g. iron oxide, titan oxide, iron hexacyanofer-rate) and organic colorants (e.g. alizarin-, azo- and phthalocyanine col- orants).
- Suitable tackifiers or binders are polyvinylpyrrolidone, polyvinylacetates, polyvinyl alcohols, polyacrylates, biological or synthetic waxes, and cellulose ethers.
- the agrochemical compositions generally comprise between 0.01 and 95%, preferably between 0.1 and 90%, and in particular between 0.5 and 75%, by weight of active substance.
- the active substances are employed in a purity of from 90% to 100%, preferably from 95% to 100% (ac-cording to NMR spectrum).
- Solutions for seed treatment (LS), Suspoemulsions (SE), flowable concentrates (FS), powders for dry treatment (DS), water-dispersible powders for slurry treatment (WS), water-soluble pow-ders (SS), emulsions (ES), emulsifiable concentrates (EC) and gels (GF) are usually employed for the purposes of treatment of plant propagation materials, particularly seeds.
- the composi-tions in question give, after two-to-tenfold dilution, ac- tive substance concentrations of from 0.01 to 60% by weight, preferably from 0.1 to
- Appli-cation can be carried out before or during sowing.
- Methods for applying compound I and corn-positions thereof, respectively, on to plant propagation material, especially seeds include dress-ing, coating, pelleting, dusting, soaking and in-furrow application methods of the propagation material.
- compound I or the compositions thereof, respectively are applied on to the plant propagation material by a method such that germination is not induced, e. g. by seed dressing, pelleting, coating and dusting.
- the amounts of active substances applied are, depending on the kind of effect desired, from 0.001 to 2 kg per ha, preferably from 0.005 to 2 kg per ha, more preferably from 0.05 to 0.9 kg per ha, and in particular from 0.1 to 0.75 kg per ha.
- amounts of active substance In treatment of plant propagation materials such as seeds, e. g. by dusting, coating or drenching seed, amounts of active substance of from 0.1 to 1000 g, preferably from 1 to 1000 g, more preferably from 1 to 100 g and most preferably from 5 to 100 g, per 100 kilogram of plant propagation material (preferably seeds) are generally required.
- the amount of active substance applied depends on the kind of application area and on the desired effect.
- Amounts customarily applied in the protection of materials are 0.001 g to 2 kg, preferably 0.005 g to 1 kg, of active substance per cubic meter of treated material.
- oils, wetters, adjuvants, fertilizer, or micronutrients, and further pesticides may be added to the active substances or the compositions cormprising them as premix or, if appropriate not until immedi-ately prior to use (tank mix).
- pesticides e.g. herbicides, insecticides, fungicides, growth regulators, safeners
- These agents can be ad- mixed with the compositions according to the invention in a weight ratio of 1 :100 to 100:1 , preferably 1 :10 to 10:1.
- the user applies the composition according to the invention usually from a predosage device, a knapsack sprayer, a spray tank, a spray plane, or an irrigation system.
- the agrochemi-cal composition is made up with water, buffer, and/or further auxilia- ries to the desired applica-tion concentration and the ready-to-use spray liquor or the agrochemical composition according to the invention is thus obtained.
- 20 to 2000 liters, preferably 50 to 400 liters, of the ready-to-use spray liquor are applied per hectare of agricultural useful area.
- individual components of the composition according to the in-vention such as parts of a kit or parts of a binary or ternary mixture may be mixed by the user himself in a spray tank and further auxiliaries may be added, if appropriate.
- either individual components of the composition according to the in-vention or partially premixed components e. g. components comprising com- pounds I of formula I and compounds II from group M, may be mixed by the user in a spray tank and further auxilia-ries and additives may be added, if appropriate.
- either individual components of the composition according to the in-vention or partially premixed components e. g. components comprising com- pounds I f formula I and compounds II from group M, can be applied jointly (e.g. after tank mix) or consecutively, meaning creating the mixture "in-situ”.
- the compounds I and the one or more compound(s) II can be applied simultaneously, that is jointly or separately, or in succession, that is immediately one after another and thereby creating the mixture "in-situ" on the desired location, as e.g. the plant, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
- mixtures of the invention are employed as such or in form of compositions by treating the insects or the plants, plant propagation materials, such as seeds, soil, surfaces, materials or rooms to be protected from insecticidal attack with a insecticidally effective amount of the active compounds.
- the application can be carried out both before and after the infection of the plants, plant propagation materials, such as seeds, soil, surfaces, materials or rooms by the insects.
- the compounds I and the one or more compound(s) II are usually applied in a weight ratio of from 500:1 to 1 :100, preferably from 20:1 to 1 :50, in particular from 5:1 to 1 :20.
- the application rates of the mixtures according to the invention are from 5 g/ha to 2000 g/ha, preferably from 50 to 1500 g/ha, in particular from 50 to 750 g/ha.
- the mixtures according to the invention are effective through both contact and inges- tion.
- the mixtures according to the present invention are employed via soil application.
- Soil application is especially favorable for use against ants, termites, crickets, or cockroaches.
- the mixtures according to the present invention are prepared into a bait preparation.
- the bait can be a liquid, a solid or a semisolid preparation (e.g. a gel).
- Another aspect of the present invention is when preparing the mixtures, it is preferred to employ the pure active compounds I and II, to which further active compounds, e.g. against harmful fungi or having herbicidal activity, or growth-regulating agents or fertilizers can be added.
- compositions of this invention may further contain other active ingredients than those listed above.
- active ingredients for example fungicides, herbicides, fertilizers such as ammonium nitrate, urea, potash, and superphosphate, phytotoxicants and plant growth regulators and safeners.
- additional ingredients may be used sequentially or in combination with the above-described compositions, if appropriate also added only immediately prior to use (tank mix).
- the plant(s) may be sprayed with a composition of this invention either before or after being treated with other active ingredients.
- the mixtures according to the invention can be applied to any and all developmental stages, such as egg, larva, pupa, and adult.
- the pests may be controlled by contacting the target pest, its food supply, habitat, breeding ground or its locus with a pesticidally effective amount of the inventive mixtures or of compositions comprising the mixtures.
- Locus means a plant, seed, soil, area, material or environment in which a pest is growing or may grow.
- pesticidally effective amount means the amount of the inventive mixtures or of compositions comprising the mixtures needed to achieve an observable effect on growth, including the effects of necrosis, death, retardation, prevention, and removal, destruction, or otherwise diminishing the occurrence and activity of the target organism.
- the pesticidally effective amount can vary for the various mixtures and/or compositions used in the invention.
- a pesticidally effective amount of the mixtures and/or compositions will also vary according to the prevailing conditions such as desired pesticidal effect and duration, weather, target species, locus, mode of application, and the like.
- inventive mixtures or compositions of these mixtures can also be employed for protecting plants from attack or infestation by insects, acarids or nematodes comprising contacting a plant, or soil or water in which the plant is growing.
- inventive mixtures are effective through both contact (via soil, glass, wall, bed net, carpet, plant parts or animal parts), and ingestion (bait, or plant part) and through trophallaxis and transfer.
- Preferred application methods are into water bodies, via soil, cracks and crevices, pas- tures, manure piles, sewers, into water, on floor, wall, or by perimeter spray application and bait.
- inventive mixtures are prepared into a bait preparation.
- the bait can be a liquid, a solid or a semisolid preparation (e.g. a gel).
- the bait employed in the composition is a product which is sufficiently attractive to incite insects such as ants, termites, wasps, flies, mosquitoes, crickets etc. or cockroaches to eat it.
- This attractant may be chosen from feeding stimulants or para and / or sex phero- mones readily known in the art.
- Methods to control infectious diseases transmitted by insects with the inventive mixtures and their respective compositions also comprise treating surfaces of huts and houses, air spraying and impregnation of curtains, tents, clothing items, bed nets, tsetse-fly trap or the like.
- Insecticidal compositions for application to fibers, fabric, knitgoods, non- wovens, netting material or foils and tarpaulins preferably comprise a composition including the inventive mixtures, optionally a repellent and at least one binder.
- the inventive mixtures and the compositions comprising them can be used for protecting wooden materials such as trees, board fences, sleepers, etc.
- the quantity of active ingredient(s) ranges from 0.0001 to 500 g per 100 m 2 , preferably from 0.001 to 20 g per 100 m 2 .
- Customary application rates in the protection of materials are, for example, from 0.01 g to 1000 g of active compound(s) per m 2 treated material, desirably from 0.1 g to 50 g per m 2 .
- Insecticidal compositions for use in the impregnation of materials typically contain from 0.001 to 95 weight %, preferably from 0.1 to 45 weight %, and more preferably from 1 to 25 weight % of at least one repellent and / or insecticide.
- the typical content of active ingredient(s) is from 0.0001 weight % to 15 weight %, desirably from 0.001 weight % to 5% weight % of active compound.
- the composition used may also comprise other additives such as a solvent of the active material, a flavoring agent, a preserving agent, a dye or a bitter agent. Its attractiveness may also be enhanced by a special color, shape or texture.
- the content of the mixture of the active ingredients is from 0.001 to 80 weights %, preferably from 0.01 to 50 weight % and most preferably from 0.01 to 15 weight %.
- the rate of application of the mixture of the active ingredients of this invention may be in the range of 0.1 g to 4000 g per hectare, desirably from 25 g to 600 g per hectare, more desirably from 50 g to 500 g per hectare.
- the term plant refers to an entire plant, a part of the plant or the plant propagation material.
- the mixtures of the present invention and the compositions comprising them are par- ticularly important in the control of a multitude of insects on various cultivated plants.
- Plants which can be treated with the inventive mixtures include all genetically modified plants or transgenic plants, e.g. crops which tolerate the action of herbicides or fungicides or insecticides owing to breeding, including genetic engineering methods, or plants which have modified characteristics in comparison with existing plants, which can be generated for example by traditional breeding methods and/or the generation of mutants, or by recombinant procedures.
- plant propagation material is to be understood to denote all the generative parts of the plant such as seeds and vegetative plant material such as cuttings and tubers (e. g. potatoes), which can be used for the multiplication of the plant. This includes seeds, roots, fruits, tubers, bulbs, rhizomes, shoots, sprouts and other parts of plants. Seedlings and young plants, which are to be transplanted after germination or after emergence from soil, may also be mentioned. These young plants may also be protected before transplantation by a total or partial treatment by immersion or pouring.
- cultivadas plants is to be understood as including plants which have been modified by breeding, mutagenesis or genetic engineering.
- Genetically modified plants are plants, which genetic material has been so modified by the use of recombinant DNA techniques that under natural circumstances cannot be obtained by cross breeding, mutations or natural recombination.
- one or more genes have been integrated into the genetic material of a genetically modified plant in order to improve certain properties of the plant.
- cultiva plants is to be understood also including plants that have been rendered tolerant to applications of specific classes of herbicides, such as hy- droxy-phenylpyruvate dioxygenase (HPPD) inhibitors; acetolactate synthase (ALS) inhibitors, such as sulfonyl ureas (see e. g. US 6,222,100, WO 01/82685, WO
- EPSPS enolpyruvylshikimate-3-phosphate synthase
- GS glutamine synthetase
- glufosinate see e. g. EP-A-0242236, EP-A-242246, or oxynil herbicides (see e. g. US 5,559,024) as a result of conventional methods of breeding or genetic engineering.
- cultivated plants have been rendered tolerant to herbicides by conventional methods of breeding (mutagenesis), for example Clearfield ® summer rape (Canola) being tolerant to imidazolinones, e. g. imazamox.
- mutagenesis for example Clearfield ® summer rape (Canola) being tolerant to imidazolinones, e. g. imazamox.
- Genetic engineering methods have been used to render cultivated plants, such as soybean, cotton, corn, beets and rape, tolerant to herbicides, such as glyphosate and glufosinate, some of which are commercially available under the trade names RoundupReady ® (glyphosate) and LibertyLink ® (glufosinate).
- cultiva plants is to be understood also including plants that are by the use of recombinant DNA techniques capable to synthesize one or more insecticidal proteins, especially those known from the bacterial genus Bacillus, particularly from Bacillus thuringiensis, such as a-endotoxins, e. g. CrylA(b), CrylA(c), CrylF, CrylF(a2), CryllA(b), CrylllA, CrylllB(bl ) or Cry9c; vegetative insecticidal proteins (VIP), e. g. VIP1 , VIP2, VIP3 or VIP3A; insecticidal proteins of bacteria colonizing nematodes, for example Photorhabdus spp.
- VIP vegetative insecticidal proteins
- toxins produced by animals such as scorpion toxins, arachnid toxins, wasp toxins, or other insect-specific neurotoxins
- toxins produced by fungi such Streptomycetes toxins, plant lectins, such as pea or barley lectins; agglutinins
- proteinase inhibitors such as trypsin inhibitors, serine protease inhibitors, patatin, cystatin or papain inhibitors
- ribosome-inactivating proteins (RIP) such as ricin, maize-RIP, abrin, luffin, saporin or bryodin
- steroid metabolism enzymes such as 3-hydroxysteroid oxidase, ecdysteroid-IDP-glycosyl-transferase, cholesterol oxidases, ecdysone inhibitors or HMG-CoA-reductase
- ion channel blockers such as blockers of sodium or calcium channels
- these insecticidal proteins or toxins are to be understood expressly also as pre-toxins, hybrid proteins, truncated or otherwise modified proteins.
- Hybrid proteins are characterized by a new combination of protein domains, (see, for example WO 02/015701 ).
- Further examples of such toxins or genetically-modified plants capable of synthesizing such toxins are dis-closed, for example, in EP-A 374 753, WO 93/007278, WO 95/34656, EP-A 427 529, EP-A 451 878, WO 03/018810 und WO 03/052073.
- the methods for producing such genetically modified plants are generally known to the person skilled in the art and are described, for example, in the publications mentioned above.
- insects which insecticidal proteins contained in the genetically modified plants impart to the plants producing these proteins tolerance to harmful pests from all taxonomic groups of insects, especially to beetles (Coeloptera), two-winged insects (Diptera), and butterflies (Lepidoptera).
- cultivars are to be understood also including plants that are by the use of recombinant DNA techniques capable to synthesize one or more proteins to in-crease the resistance or tolerance of those plants to bacterial, viral or fungal patho- gens.
- proteins are the so-called " pathogenesis-related proteins” (PR proteins, see, for example EP-A 0 392 225), plant disease resistance genes (for example potato cultivars, which express resistance genes acting against Phytophthora infestans derived from the mexican wild potato Solanum bulbocastanum) or T4- lyso-zym (e. g. potato cultivars capable of synthesizing these proteins with increased resistance against bacteria such as Erwinia amylvora).
- PR proteins pathogenesis-related proteins
- plant disease resistance genes for example potato cultivars, which express resistance genes acting against Phytophthora infestans derived from the mexican wild potato Solanum bulbocastanum
- T4- lyso-zym e.
- cultiva plants is to be understood also including plants that are by the use of recombinant DNA techniques capable to synthesize one or more proteins to increase the productivity (e. g. bio mass production, grain yield, starch content, oil content or protein content), tolerance to drought, salinity or other growth-limiting envi- ron-mental factors or tolerance to pests and fungal, bacterial or viral pathogens of those plants.
- cultiva plants is to be understood also including plants that contain by the use of recombinant DNA techniques a modified amount of substances of content or new substances of content, specifically to improve human or animal nutrition, for ex-ample oil crops that produce health-promoting long-chain omega-3 fatty acids or unsaturated omega-9 fatty acids (e. g. Nexera ® rape).
- cultiva plants is to be understood also including plants that contain by the use of recombinant DNA techniques a modified amount of substances of content or new substances of content, specifically to improve raw material production, for example potatoes that produce increased amounts of amylopectin (e. g. Amflora ® potato).
- Some of the inventive mixtures have systemic action and can therefore be used for the protection of the plant shoot against foliar pests as well as for the treatment of the seed and roots against soil pests.
- Seed treatment The mixtures according to the present invention are therfore suitable for the treatment of seeds in order to protect the seed from insect pest, in particular from soil-living insect pests and the resulting plant' s roots and shoots against soil pests and foliar insects.
- the protection of the resulting plant' s roots and shoots is preferred.
- More preferred is the protection of resulting plant' s shoots from piercing and sucking insects.
- the present invention therefore comprises a method for the protection of seeds from insects, in particular from soil insects and of the seedlings' roots and shoots from insects, in particular from soil and foliar insects, said method comprising contacting the seeds before sowing and/or after pregermination with mixtures according to the present invention.
- a method wherein the plant' s roots and shoots are protected, more preferably a method, wherein the plants shoots are protected form piercing and sucking insects, most preferably a method, wherein the plants shoots are protected from aphids.
- seed embraces seeds and plant propagules of all kinds including but not limited to true seeds, seed pieces, suckers, corms, bulbs, fruit, tubers, grains, cuttings, cut shoots and the like and means in a preferred embodiment true seeds.
- seed treatment comprises all suitable seed treatment techniques known in the art, such as seed dressing, seed coating, seed dusting, seed soaking and seed pelleting.
- the present invention also comprises seeds coated with or containing the active compound ⁇ ).
- coated with and/or containing generally signifies that the active ingredient(s) are for the most part on the surface of the propagation product at the time of application, although a greater or lesser part of the ingredient may penetrate into the propagation product, depending on the method of application. When the said propagation product are (re)planted, it may absorb the active ingredient.
- Suitable seeds are seeds of cereals, root crops, oil crops, vegetables, spices, ornamentals, for example seed of durum and other wheat, barley, oats, rye, maize (fodder maize and sugar maize / sweet and field corn), soybeans, oil crops, crucifers, cotton, sunflowers, bananas, rice, oilseed rape, turnip rape, sugarbeet, fodder beet, eggplants, potatoes, grass, lawn, turf, fodder grass, tomatoes, leeks, pumpkin/squash, cabbage, iceberg lettuce, pepper, cucumbers, melons, Brassica species, melons, beans, peas, garlic, onions, carrots, tuberous plants such as potatoes, sugar cane, tobacco, grapes, petunias, geranium/pelargoniums, pansies and impatiens.
- the mixtures according to the invention may also be used for the treatment seeds from plants, which tolerate the action of herbicides or fungicides or insecticides owing to breeding, including genetic engineering methods.
- the active mixtures can be employed in treatment of seeds from plants, which are resistant to herbicides from the group consisting of the sulfonylureas, imid- azolinones, glufosinate-ammonium or glyphosate-isopropylammonium and analogous active substances (see for example, EP-A-0242236, EP-A-242246) (WO 92/00377) (EP-A-0257993, U.S. Pat. No.
- the mixtures according to the present invention can be used also for the treatment of seeds from plants, which have modified characteristics in comparison with existing plants consist, which can be generated for example by traditional breeding methods and/or the generation of mutants, or by recombinant procedures).
- a number of cases have been described of recombinant modifications of crop plants for the purpose of modifying the starch synthesized in the plants (e.g. WO 92/1 1376, WO 92/14827, WO 91/19806) or of transgenic crop plants having a modified fatty acid composition (WO 91/13972).
- the seed treatment application of the mixtures is carried out by spraying or by dusting the seeds before sowing of the plants and before emergence of the plants.
- the corresponding formulations are applied by treating the seeds with an effective amount of the mixture according to the present invention.
- the application rates of the active compound(s) are generally from 0,1 g to 10 kg per 100 kg of seed, preferably from 1 g to 5 kg per 100 kg of seed, in particular from 1 g to 2,5 kg per 100 kg of seed. For specific crops such as lettuce the rate can be higher.
- compositions which are especially useful for seed treatment are e.g.:
- a Soluble concentrates (SL, LS)
- I Dustable powders (DP, DS) Conventional seed treatment formulations include for example flowable concentrates FS, solutions LS, powders for dry treatment DS, water dispersible powders for slurry treatment WS, water-soluble powders SS and emulsion ES and EC and gel formulation GF. These formulations can be applied to the seed diluted or undiluted. Application to the seeds is carried out before sowing, either directly on the seeds or after having pregerminated the latter
- a FS formulation is used for seed treatment.
- a FS formulation may comprise 1 -800 g/l of active ingredient(s), 1 -200 g/l Surfactant, 0 to 200 g/l antifreezing agent, 0 to 400 g/l of binder, 0 to 200 g/l of a pigment and up to 1 liter of a solvent, preferably water.
- Preferred FS formulations of compounds of formula I for seed treatment usually comprise from 0.1 to 80% by weight (1 to 800 g/l) of the active ingredient(s), from 0.1 to 20 % by weight (1 to 200 g/l) of at least one surfactant, e.g. 0.05 to 5 % by weight of a wetter and from 0.5 to 15 % by weight of a dispersing agent, up to 20 % by weight, e.g. from 5 to 20 % of an anti-freeze agent, from 0 to 15 % by weight, e.g. 1 to 15 % by weight of a pigment and/or a dye, from 0 to 40 % by weight, e.g.
- a binder (sticker /adhesion agent), optionally up to 5 % by weight, e.g. from 0.1 to 5 % by weight of a thickener, optionally from 0.1 to 2 % of an anti-foam agent, and optionally a preservative such as a biocide, antioxidant or the like, e.g. in an amount from 0.01 to 1 % by weight and a filler/vehicle up to 100 % by weight.
- a binder sticker /adhesion agent
- a preservative such as a biocide, antioxidant or the like
- Seed Treatment formulations may additionally also comprise binders and optionally colorants.
- Binders can be added to improve the adhesion of the active materials on the seeds after treatment.
- Suitable binders are block copolymers EO/PO surfactants but also pol- yvinylalcoholsl, polyvinylpyrrolidones, polyacrylates, polymethacrylates, polybutenes, polyisobutylenes, polystyrene, polyethyleneamines, polyethyleneamides, polyethylene- imines (Lupasol®, Polymin®), polyethers, polyurethans, polyvinylacetate, tylose and copolymers derived from these polymers.
- colorants can be included in the formulation.
- Suitable colorants or dyes for seed treatment formulations are Rhodamin B, C.I. Pigment Red 1 12, C.I. Solvent Red 1 , pigment blue 15:4, pigment blue 15:3, pigment blue 15:2, pigment blue 15:1 , pigment blue 80, pigment yellow 1 , pigment yellow 13, pigment red 1 12, pigment red 48:2, pigment red 48:1 , pigment red 57:1 , pigment red 53:1 , pigment orange 43, pigment orange 34, pigment orange 5, pigment green 36, pigment green 7, pigment white 6, pigment brown 25, basic violet 10, basic violet 49, acid red 51 , acid red 52, acid red 14, acid blue 9, acid yellow 23, basic red 10, basic red 108.
- the invention also relates to seed comprising mixtures according to the present invention.
- the amount of the compound I or the agriculturally useful salt thereof will in general vary from 0.1 g to 10 kg per 100 kg of seed, preferably from 1 g to 5 kg per 100 kg of seed, in particular from 1 g to 1000 g per 100 kg of seed.
- the compounds I of formula I can be accomplished according to standard methods of organic chemistry, e.g. by the methods or working examples described in WO
- Some of the preferred compound I examples are characterized in following table CE.1.1 and further by their physical data in the subsequent table CE.I.1 -D.1 .
- the compounds I were also characterized by LC-MS (High Performance Liquid Chromatography Mass Spectrometry HPLC/MS).
- the compounds I of formula I were preferably characterized by HPLC, which was carried out using an analytic RP-18 column (Chromolith Speed ROD from Merck KGaA, Germany) which was operated at 40°C.
- Acetonitrile with 0.1 % by volume of a trifluoroacetic acid/water mixture and 0.1 % by volume of trifluoroacetic acid served as mobile phase; flow rate: 1 .8 mL/min and injection volume: 2 ⁇ .
- table CE.1 hereinafter, and their respective physical date are provided in subsequent table CE-D.1 :
- CE.I.2. k 0 F CH 3 n-propyl 0
- CE.I.8. k 0 F CH 3 3,4,4-trifluoro-3-buten-1 -yl 0
- CE.I.9. k 0 F CH 3 3,4,4-trifluoro-3-buten-1 -yl 1
- CE.I.28. k 0 CH 3 CH 3 CF3-CH2- 0
- CE.I.29. k 0 CH 3 CH 3 CF3-CH2- 1
- CE.I.34. k 0 F CH 3 CF3-CH2- 0 Compound (R 4 ) k R 3 R2 R n
- table CE.1.1 * some compound examples of table CE.1.1 have also been described as preferred compounds I of the present invention in table C.I .1 ;
- test unit For evaluating control of vetch aphid (Megoura viciae) through contact or systemic means the test unit consisted of 24-well-microtiter plates containing broad bean leaf disks.
- the compounds or mixtures were formulated using a solution containing 75% water and 25% DMSO. Different concentrations of formulated compounds or mixtures were sprayed onto the leaf disks at 2.5 ⁇ , using a custom built micro atomizer, at two replications.
- the leaf disks were air-dried and 5 - 8 adult aphids placed on the leaf disks inside the microtiter plate wells. The aphids were then allowed to suck on the treated leaf disks and incubated at about 23 + 1 °C and about 50 + 5 % RH (relative humidity) for 5 days. Aphid mortality and fecundity was then visually assessed. For the mixture tested the results are listed in table B.1.
- Test compound is CE.I.34
- test unit For evaluating control of boll weevil (Anthonomus grandis) the test unit consisted of 24- well-microtiter plates containing an insect diet and 20-30 A. grandis eggs.
- the compounds or mixtures were formulated using a solution containing 75% water and 25% DMSO. Different concentrations of formulated compounds or mixtures were sprayed onto the insect diet at 20 ⁇ , using a custom built micro atomizer, at two replications. For experimental mixtures in these tests identical volumes of both mixing partners at the desired concentrations respectively, were mixed together.
- microtiter plates were incubated at about 23 + 1 °C and about 50 + 5 % RH for 5 days. Egg and larval mortality was then visually assessed. For the mixture tested the results are listed in table B.2.
- Test compounds are CE.I.34 and CE.I.35:
- Myzus persicae For evaluating control of green peach aphid (Myzus persicae) through systemic means the test unit consisted of 96-well-microtiter plates containing liquid artificial diet under an artificial membrane.
- the compounds or mixtures were formulated using a solution containing 75% water and 25% DMSO. Different concentrations of formulated compounds or mixtures were pipetted into the aphid diet, using a custom built pipetter, at two replications.
- Test compound is CE.I.34
- Test B.4 Control of Yellow fever mosquito (Aedes aegyptii) Test principle: Curative ultrasonic spraying of larvae in liquid diet For evaluating control of Aedes aegyptii , the assay was conducted in microtiter plates (MTP's), wherein each well was filled with 0.2ml of a Aedes aegypti suspension of 5 to 15 freshly hatched larvae in a liquid diet of 200 ppm yeast in water, prepared directly before spraying.
- MTP's microtiter plates
- the compounds were formulated at desired concentration using a solution containing 75% v/v water and 25% v/v DMSO. Different concentrations of formulated compounds were applied at 2.5 ⁇ , using a ultrasonic spraying, at two replications.
- the MTPs were sealed with the matching lids in a climatized test chamber at about 28°C + 1 °C and about 80 + 5 % RH (relative humidity)and at 3500 + 500 lux of fluorescent light.
- Test compound is CE.I.35
- Test principle Curative ultrasonic spraying of nematodes in liquid diet
- the test unit consisted of microtiter plates (MTP), wherein each well was filled with 0.18 ml of a C.EIegans suspension containing 60 to 100 individuals of C. elegans at mixed life stages in a liquid diet.
- the compounds were formulated at desired concentration using a solution containing 75% v/v water and 25% v/v DMSO. Different concentrations of formulated compounds were applied at 5 ⁇ by ultrasonic spraying onto the liquid diet, at two replications. After application, the treated microtiterplates were incubated in a climatized test chamber at temperature of about 18 +/- 1 °C and 70 +/- 5 % RH in the dark.
- Test compound is CE.I.34
- test unit For evaluating control of tobacco budworm (Heliothis virescens) the test unit consisted of 96-well-microtiter plates containing an insect diet and 15-25 H. virescens eggs.
- the compounds or mixtures were formulated using a solution containing 75% water and 25% DMSO. Different concentrations of formulated compounds or mixtures were sprayed onto the insect diet at 10 ⁇ , using a custom built micro atomizer, at two replications.
- Test compound is CE.1.31 Tobacco budworm ppm Average control %
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
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Abstract
Description
Claims
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
MX2014001706A MX2014001706A (en) | 2011-09-02 | 2012-08-30 | Insecticidal active mixtures comprising arylquinazolinone compounds. |
BR112014004037A BR112014004037A2 (en) | 2011-09-02 | 2012-08-30 | pesticide mixtures, plant protection method, insect control method, plant propagation material protection method, pesticide use and composition |
KR1020147008655A KR20140063757A (en) | 2011-09-02 | 2012-08-30 | Insecticidal active mixtures comprising arylquinazolinone compounds |
EP12762236.3A EP2750503A1 (en) | 2011-09-02 | 2012-08-30 | Insecticidal active mixtures comprising arylquinazolinone compounds |
AU2012300903A AU2012300903A1 (en) | 2011-09-02 | 2012-08-30 | Insecticidal active mixtures comprising arylquinazolinone compounds |
US14/241,983 US20140221201A1 (en) | 2011-09-02 | 2012-08-30 | Insecticidal active mixtures comprising arylquinazolinone compounds |
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CN201280042707.8A CN103763922A (en) | 2011-09-02 | 2012-08-30 | Insecticidal active mixtures comprising arylquinazolinone compounds |
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US11363815B2 (en) | 2018-06-05 | 2022-06-21 | Shenyang University Of Chemical Technology | Trifluoroethyl thioether (sulfoxide) substituted benzene compound and use thereof |
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CN111579673B (en) * | 2020-05-27 | 2022-07-15 | 中国科学院成都生物研究所 | Method for purifying and detecting fipronil and its metabolite in egg |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11363815B2 (en) | 2018-06-05 | 2022-06-21 | Shenyang University Of Chemical Technology | Trifluoroethyl thioether (sulfoxide) substituted benzene compound and use thereof |
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IN2014CN02367A (en) | 2015-06-19 |
JP2014529618A (en) | 2014-11-13 |
EP2750503A1 (en) | 2014-07-09 |
BR112014004037A2 (en) | 2017-06-20 |
AU2012300903A1 (en) | 2014-03-20 |
KR20140063757A (en) | 2014-05-27 |
CL2014000353A1 (en) | 2014-07-25 |
ZA201402359B (en) | 2017-11-29 |
US20140221201A1 (en) | 2014-08-07 |
CN103763922A (en) | 2014-04-30 |
AR088788A1 (en) | 2014-07-10 |
MX2014001706A (en) | 2014-03-21 |
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