Classifications

• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
  • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
  • A01N37/28—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group; Thio analogues thereof
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
  • A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
  • A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
  • A01N37/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system having at least one carboxylic group or a thio analogue, or a derivative thereof, and one oxygen or sulfur atom attached to the same aromatic ring system
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
  • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
  • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
  • A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
  • A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
  • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
  • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles

Definitions

• the present invention relates to a harmful arthropod control composition and a method for controlling harmful arthropods.
• An object of the present invention is to provide a harmful arthropod control composition having an excellent control effect on harmful arthropods.
• a harmful arthropod control composition comprising: an amide compound represented by the formula: at least one insect growth control compound selected from group (A); and at least one planthopper control compound selected from group (B). .
• a method for controlling harmful arthropods comprising a step of applying an effective amount of the composition for controlling harmful arthropods according to any one of [1] to [4] to a plant or a plant cultivation site.
• harmful arthropods can be controlled.
• the harmful arthropod control composition of the present invention is an amide compound represented by the following formula (1) (hereinafter referred to as the present amide compound) and at least one insect growth control selected from the following group (A).
• a compound hereinafter referred to as the present insect growth control compound
• at least one planthopper control compound selected from the following group (B) (hereinafter referred to as the present planthopper control compound).
• Group (A) A group consisting of methoxyphenozide, chromafenozide and tebufenozide.
• Group (B) A group consisting of clothianidin, nitenpyram, buprofezin and ethiprole.
• the present amide compound is a known compound and can be produced, for example, by the method described in International Publication No. 2003/010149.
• methoxyphenozide, chromafenozide, tebufenozide, clothianidin, nitenpyram, buprofezin and etiprole used in the present invention are all known compounds, for example, “The Pesticide Manual-15th edition (BCPC); ISBN 9788-19013; ⁇ 8 ”, pages 764, 211, 1074, 229, 817, 138, and 443. These compounds are obtained from commercially available preparations or can be obtained by producing them by known methods.
• the content ratio of the present amide compound, the present insect growth control compound and the present planthopper control compound is not particularly limited, but relative to 100 parts by weight of the present amide compound.
• the insect growth control compound is usually 0.2 to 50000 parts by weight, preferably 2 to 5000 parts by weight, more preferably 5 to 2000 parts by weight
• the present planthopper control compound is usually 0.2 to 50000 parts by weight. Parts by weight, preferably 2 to 5000 parts by weight, more preferably 5 to 2000 parts by weight.
• the weight ratio of the present amide compound to the present insect growth control compound (the present amide compound: the present insect growth control compound) in the harmful arthropod control composition of the present invention is usually 500: 1 to 1: 500, preferably 50: 1 to 1:50, more preferably 20: 1 to 1:20.
• the weight ratio of the present amide compound to the present planthopper control compound (the present amide compound: the present planthopper control compound) is usually 500: 1 to 1: 500, preferably 50: 1 to 1:50, more preferably 20: 1 to 1:20.
• the harmful arthropod control composition of the present invention may be a simple mixture of the present amide compound, the present insect growth control compound and the present planthopper control compound, but usually the present amide compound, the present insect growth control compound and This planthopper control compound and an inert carrier are mixed, and if necessary, surfactants and other formulation adjuvants are added, and oils, emulsions, flowables, wettable powders, granular wettable powders, powders In addition, those formulated into granules and the like are used. Moreover, the above-mentioned formulated harmful arthropod control composition can be used as a harmful arthropod control agent as it is or by adding other inactive ingredients.
• the total amount of the present amide compound, the present insect growth control compound and the present planthopper controlling compound in the harmful arthropod control composition of the present invention is usually 0.01 to 99% by weight, preferably 0.1 to 90% by weight. More preferably, it is in the range of 0.5 to 70% by weight.
• Examples of the inert carrier include a solid carrier and a liquid carrier.
• Examples of solid carriers include kaolin clay, attapulgite clay, bentonite, montmorillonite, acid clay, pyrophyllite, talc, diatomaceous earth, calcite, and other natural organic substances such as corn cob powder and walnut shell powder, urea, and the like.
• Examples of the liquid carrier include fine organic powders such as synthetic organic substances, salts such as calcium carbonate and ammonium sulfate, synthetic inorganic substances such as synthetic silicon hydroxide, and the like.
• Examples of liquid carriers include aromatic hydrocarbons such as xylene, alkylbenzene, and methylnaphthalene.
• Alcohols such as 2-propanol, ethylene glycol, propylene glycol and ethylene glycol monoethyl ether, ketones such as acetone, cyclohexanone and isophorone, vegetable oils such as soybean oil and cottonseed oil, petroleum aliphatic hydrocarbons and esters , Jimechi Sulfoxides, acetonitrile, and water.
• surfactants include anionic interfaces such as alkyl sulfate esters, alkylaryl sulfonates, dialkyl sulfosuccinates, polyoxyethylene alkylaryl ether phosphate esters, lignin sulfonates, naphthalene sulfonate formaldehyde polycondensates, and the like.
• Nonionic surfactants such as activators and polyoxyethylene alkyl aryl ethers, polyoxyethylene alkyl polyoxypropylene block copolymers, sorbitan fatty acid esters, and cationic surfactants such as alkyltrimethylammonium salts.
• formulation adjuvants examples include water-soluble polymers such as polyvinyl alcohol and polyvinyl pyrrolidone, gum arabic, alginic acid and salts thereof, polysaccharides such as carboxymethyl cellulose (CMC) and xanthan gum, inorganic substances such as aluminum magnesium silicate and alumina sol. , Preservatives, colorants, and stabilizers such as acidic isopropyl phosphate (PAP) and dibutylhydroxytoluene (BHT).
• water-soluble polymers such as polyvinyl alcohol and polyvinyl pyrrolidone
• gum arabic alginic acid and salts thereof
• polysaccharides such as carboxymethyl cellulose (CMC) and xanthan gum
• inorganic substances such as aluminum magnesium silicate and alumina sol.
• Preservatives, colorants, and stabilizers such as acidic isopropyl phosphate (PAP) and dibutylhydroxytoluene (BHT
• the harmful arthropod control composition of the present invention can be used to protect plants from harm by harmful arthropods that feed plants, suck and so on.
• Examples of the harmful arthropods having the control effect of the harmful arthropod control composition of the present invention include the following.
• Hemiptera small brown planthopper (Laodelphax striatellus), brown planthopper (Nilaparvata lugens), planthopper such Sejirounka (Sogatella furcifera), green rice leafhopper (Nephotettix cincticeps), Taiwan green rice leafhopper (Nephotettix virescens), Inazuma leafhopper (Recilia dorsalis), Chanomidorihime Leafhoppers such as leafhopper (Empoasca onukii), cotton aphid (Aphis gossypi), peach aphid (Myzus persicae), radish aphid (Brevicorine brassicae), snowy spruce (Aphasianis spruce) la), tulip beetle aphids (Macrosiphum euporbiae), potato beetle aphids (Aulacorthum solai), wheat beetle aphi
• Kibaga such as, Tiger Moth such as the United States White Arctiidae (Hyphantria cunea), clothes moth (Tinea translucens), Hirozukoga such as webbing clothes moth (Tineola bisselliella), Tuta absolute diluter (Tuta absolute diluter (Tuta absolute diluter (Tuta absolute diluter (Tuta absolute diluter (Tuta absolute diluter (Tuta absolute diluter (Tuta absolute diluter (Tuta absolute diluter (Tuta absolute diluter (Tuta absolute diluter (Tuta absolute diluter (Tuta absolute diluter (Tuta absolute diluter (Tuta absolute diluter (Tuta absolute diluter (Tuta absolute diluter (Tuta absolute diluter (Tuta absolute dil
• Thysanoptera western flower thrips (Frankliniella occidentalis), Minami thrips (Thrips peri), yellow tea thrips (Scirtothrips dorsalis), green onion thrips (Thrips tabaci), Hirazuhanaazamiuma (Frankliniella intonsa), tobacco thrips (Frankliniella fusca), rice thrips (Stenchaetotrips biformis), thrips such as Happhitrips acculeatus, etc .; Diptera: onion maggot (Hylemya antiqua), seedcorn maggot (Hylemya platura), rice leafminer (Agromyza oryzae), rice Hime leafminer (Hydrellia griseola), Inekimoguribae (Chlorops oryzae), leafminer such as beans leafminer (Liriomyza trifolii), melon fly (Dacus cucurbitae), Ceratotis capitat
• preferred examples include hemipod pests such as planthoppers and leafhoppers, and lepidopterous pests such as moths and moths.
• the harmful arthropod control composition of the present invention can also control plant diseases such as rice blight (Rhizotonia solani).
• the harmful arthropod control composition of the present invention can be used in agricultural fields such as fields, paddy fields, dry fields, lawns, orchards, or non-cultivated areas. Moreover, the harmful arthropod control composition of the present invention can be used for controlling pests in the farmland in farmlands where "plants" and the like are cultivated.
• Examples of plants to which the harmful arthropod control composition of the present invention can be used include the following.
• Agricultural crops corn, rice, wheat, barley, rye, oat, sorghum, cotton, soybean, peanut, buckwheat, sugar beet, rapeseed, sunflower, sugarcane, tobacco, etc.
• Vegetables Solanum vegetables (eggplants, tomatoes, peppers, peppers, potatoes, etc.), Cucurbitaceae vegetables (cucumbers, pumpkins, zucchini, watermelons, melons, etc.), Brassicaceae vegetables (radish, turnip, horseradish, kohlrabi, Chinese cabbage, cabbage) , Mustard, broccoli, cauliflower, rape, etc.), asteraceae vegetables (burdock, shungiku, artichoke, lettuce, etc.), liliaceae vegetables (eg, leek, onion, garlic, asparagus), celery family vegetables (carrot, parsley, celery, American Bow Fu etc.), Rubiaceae vegetables (spinach, chard, etc.), Lamiaceae vegetables (shiso, mint, basil etc.), strawberry, sweet potato, yam, taro etc.
• Fruit trees berries (apples, pears, Japanese pears, quince, quince, etc.), nuclear fruits (peaches, plums, nectarines, ume, sweet cherry, apricots, prunes, etc.), citrus (satsuma mandarin, orange, lemon, lime, grapefruit) ), Nuts (chestnut, walnut, hazel, almond, pistachio, cashew nut, macadamia nut, etc.), berries (blueberry, cranberry, blackberry, raspberry, etc.), grape, oyster, olive, loquat, banana, coffee, Date palm, coconut palm, oil palm etc.
• Trees other than fruit trees tea, mulberry, flowering trees (Satsuki, camellia, hydrangea, sasanqua, shikimi, sakura, yurinoki, crape myrtle, snapdragon, etc.), roadside trees (ash, birch, dogwood, eucalyptus, ginkgo, lilac, maple, oak) , Poplar, redwood, fu, sycamore, zelkova, blackfish, Japanese amberjack, moths, pine, pine, spruce, yew, elm, Japanese cypress, etc.), coral jug, dogwood, cedar, cypress, croton, masaki, kanamochi, etc.
• Lawn Shiba (Nasis, Pleurotus, etc.), Bermudagrass (Neurodonidae, etc.), Bentgrass (Oleoptera, Hykonukagusa, Odonoptera, etc.), Bluegrass (Nagahagusa, Oosuzunokatabira, etc.), Fescue (Oonishi nokegusa, Drosophila, etc.) , Grass, etc.), ryegrass (rat, wheat, etc.), anemonefish, blue whale, etc.
• corn, wheat, rice and the like can be mentioned as preferable examples. Of these, rice is particularly preferable.
• the “plant” may be a plant to which resistance is imparted by a genetic recombination technique or a breeding method by crossing.
• the harmful arthropod control composition of the present invention can control harmful arthropods by applying it to a plant or a plant cultivation site.
• plants include plant foliage, plant flowers, plant nuts, plant seeds, and the like.
• the method for controlling harmful arthropods according to the present invention includes a step of applying an effective amount of the composition for controlling harmful arthropods to a plant or a plant cultivation site.
• the method for controlling harmful arthropods of the present invention is performed by applying an effective amount of the composition for controlling harmful arthropods of the present invention to plants or plant cultivation areas.
• Examples include treatment of plant stems and leaves such as spraying, treatment of plant seeds, soil treatment, and treatment of plant cultivation areas such as water surface application.
• the effective amount of the harmful arthropod control composition of the present invention refers to the total amount of the present amide compound, the present insect growth control compound and the present planthopper control compound capable of exerting a control effect on harmful arthropods. Means dose.
• Plants that are cultivated by treatment on the foliage of plants such as ground spraying using a human sprayer, power sprayer, boom sprayer or cruckle sprayer, aerial spraying using air control or unmanned helicopters, etc.
• ground spraying using a human sprayer, power sprayer, boom sprayer or cruckle sprayer, aerial spraying using air control or unmanned helicopters, etc.
• the method of processing to the surface of this is mentioned.
• Examples of the treatment for plant seeds include immersion treatment, spraying treatment, smearing treatment, film coating treatment, and pellet coating treatment.
• Plant planting treatment includes planting hole treatment, plant root treatment, grooving treatment, rowing treatment, full surface treatment, side row treatment, seedling box treatment, nursery bed treatment, soil mixing, bed soil mixing, paste fertilizer mixing , Water surface treatment, water spraying and the like.
• the application amount is the type of plant, the type and degree of occurrence of harmful arthropods to be controlled, formulation form, application
• the total amount of the amide compound, the insect growth control compound, and the planthopper control compound is usually 0.5 to 3000 g per 1000 m 2 where the plant is cultivated, preferably 5 to 300 g.
• the harmful arthropod control composition of the present invention is an emulsion, a wettable powder, a flowable agent or the like, it is usually applied by diluting and spraying with water.
• the total concentration of the present amide compound, the present insect growth control compound and the present planthopper control compound is usually 0.00001 to 10% by weight, preferably 0.0001 to 5% by weight.
• the harmful arthropod composition of the present invention is a powder, granule or the like, it is usually applied as it is without dilution.
• Formulation Example 1 Add 20 parts of this amide compound, 5 parts of methoxyphenozide and 6.6 parts of clothianidin to a mixture of 4 parts of sodium lauryl sulfate, 2 parts of calcium lignin sulfonate, 20 parts of synthetic silicon hydroxide fine powder and the remainder of diatomaceous earth, and stir well. Mix to obtain 100 parts wettable powder.
• Formulation Example 5 Add 20 parts of this amide compound, 5 parts of Chromafenozide and 6.6 parts of clothianidin to a mixture of 4 parts of sodium lauryl sulfate, 2 parts of calcium lignin sulfonate, 20 parts of synthetic silicon hydroxide fine powder and the remainder of diatomaceous earth and stir well. Mix to obtain 100 parts wettable powder.
• Formulation Example 28 By finely pulverizing 100 parts of a mixture of 2 parts of the present amide compound, 10 parts of methoxyphenozide, 4 parts of clothianidin, 30 parts of white carbon containing 50 parts of polyoxyethylene alkyl ether sulfate ammonium salt and the remaining water by a wet grinding method. Obtain a flowable agent.
• white carbon containing 50 parts of polyoxyethylene alkyl ether sulfate ammonium salt means a 1: 1 weight ratio mixture of polyoxyethylene alkyl ether sulfate ammonium salt and white carbon.
• Formulation Example 32 By finely pulverizing 100 parts of a mixture of 2 parts of the present amide compound, 10 parts of chromafenozide, 4 parts of clothianidin, 30 parts of white carbon containing 50 parts of polyoxyethylene alkyl ether sulfate ammonium salt and the remainder of water by a wet grinding method, Obtain a flowable agent.
• Formulation Example 36 By finely pulverizing 100 parts of a mixture of 2 parts of the present amide compound, 16 parts of tebufenozide, 4 parts of clothianidin, 30 parts of white carbon containing 50 parts of polyoxyethylene alkyl ether sulfate ammonium salt and the remainder of water by a wet grinding method, Obtain a flowable agent.
• Test example 1 3 mg of the present amide compound is dissolved in 0.2 ml of acetone (manufactured by Wako Pure Chemical Industries, Ltd.) containing Sorgen TW-20 (Daiichi Kogyo Seiyaku Co., Ltd.) and then spreader (trade name: Dyne ( (Registered trademark), manufactured by Sumika Takeda Horticulture) was diluted with water containing 0.02% by volume.
• a commercial preparation of buprofezin (trade name: Auplo Flowable, manufactured by Nippon Agricultural Chemicals) and etiprol (trade name: Kirup Flowable, manufactured by Hokuko Chemical Co., Ltd.) is spread to a predetermined concentration (trade name: Dyne (registered trademark)), Diluted with water containing 0.02 vol%)
• a test drug solution was prepared by mixing a water diluted solution of the present amide compound, a water diluted solution of methoxyphenozide, chromafenozide or tebufenozide and a water diluted solution of buprofezin or ethiprol.

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• Life Sciences & Earth Sciences (AREA)
• Agronomy & Crop Science (AREA)
• Pest Control & Pesticides (AREA)
• Plant Pathology (AREA)
• Health & Medical Sciences (AREA)
• Engineering & Computer Science (AREA)
• Dentistry (AREA)
• General Health & Medical Sciences (AREA)
• Wood Science & Technology (AREA)
• Zoology (AREA)
• Environmental Sciences (AREA)
• Agricultural Chemicals And Associated Chemicals (AREA)

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• 2011
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• 2012
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  • 2012-08-24 KR KR1020147007172A patent/KR101947210B1/ko active IP Right Grant
  • 2012-08-24 WO PCT/JP2012/071459 patent/WO2013027829A1/ja active Application Filing
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