WO2013011312A1 - Porous carbon and methods of production thereof - Google Patents
Porous carbon and methods of production thereof Download PDFInfo
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- WO2013011312A1 WO2013011312A1 PCT/GB2012/051718 GB2012051718W WO2013011312A1 WO 2013011312 A1 WO2013011312 A1 WO 2013011312A1 GB 2012051718 W GB2012051718 W GB 2012051718W WO 2013011312 A1 WO2013011312 A1 WO 2013011312A1
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- carbon
- activated carbon
- porous carbon
- metal oxide
- impregnated
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Classifications
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/16—Use of materials for tobacco smoke filters of inorganic materials
- A24D3/163—Carbon
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/02—Manufacture of tobacco smoke filters
- A24D3/0275—Manufacture of tobacco smoke filters for filters with special features
- A24D3/0287—Manufacture of tobacco smoke filters for filters with special features for composite filters
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/062—Use of materials for tobacco smoke filters characterised by structural features
- A24D3/066—Use of materials for tobacco smoke filters characterised by structural features in the form of foam or having cellular structure
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/16—Use of materials for tobacco smoke filters of inorganic materials
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
- B01J20/28004—Sorbent size or size distribution, e.g. particle size
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28069—Pore volume, e.g. total pore volume, mesopore volume, micropore volume
- B01J20/28071—Pore volume, e.g. total pore volume, mesopore volume, micropore volume being less than 0.5 ml/g
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28069—Pore volume, e.g. total pore volume, mesopore volume, micropore volume
- B01J20/28073—Pore volume, e.g. total pore volume, mesopore volume, micropore volume being in the range 0.5-1.0 ml/g
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
- B01J20/3204—Inorganic carriers, supports or substrates
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
- B01J20/3234—Inorganic material layers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
- B01J20/3234—Inorganic material layers
- B01J20/3236—Inorganic material layers containing metal, other than zeolites, e.g. oxides, hydroxides, sulphides or salts
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/30—Active carbon
- C01B32/354—After-treatment
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
- B01J2220/42—Materials comprising a mixture of inorganic materials
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
- B01J2220/48—Sorbents characterised by the starting material used for their preparation
- B01J2220/4806—Sorbents characterised by the starting material used for their preparation the starting material being of inorganic character
Definitions
- Embodiments of the invention relate to porous carbon and methods of preparing porous carbon.
- the porous carbon is impregnated with a metal oxide and/or exhibits enhanced selectivity for hydrogen cyanide (HCN).
- HCN hydrogen cyanide
- the porous carbon of the invention may be particularly useful for smoke filtration in smoking articles, as it provides improved adsorption of the aforementioned smoke vapour phase constituent.
- Smoking article filters may include porous carbon materials to adsorb certain smoke constituents, typically by physisor tion.
- porous carbon materials can be made from the carbonized form of many different naturally occurring organic materials.
- synthetic carbons can be used, such as resins prepared by
- a method of preparing porous carbon comprising impregnating activated carbon with metal oxide.
- a porous carbon is provided which is obtained or obtainable by a method according to the first aspect of the invention.
- a porous carbon is provided comprising activated carbon impregnated with metal oxide.
- a filter element for a smoking article comprising a porovis carbon according to the second or third aspects of the invention.
- a smoking article comprising a porous carbon according to the second or third aspects of the invention.
- Figure 1 shows the nitrogen isotherm of the porous carbon of 100797 containing 1% ZnO by weight
- Figure 2 illustrates graphically the percentage reduction of hydrogen cyanide in smoke achieved with activated carbon impregnated with zinc oxide (1%, 3%, 5% and 10% zinc oxide) versus activated carbon without zinc oxide;
- Figure 3 illustrates the position of porous carbon granules according to
- the present invention relates to a method involving the application of metal salt to activated carbon so that the carbon becomes impregnated with metal oxide and, as a result, a porous carbon with enhanced adsorbent properties is produced.
- Porous carbons may be prodviced from materials including coconut shell, plant- based materials, wood powder, peat, bone, coal tar, resins and related polymers.
- Alternative sources of microporous carbon are synthetic carbons, such as those formed by a polymerisation reaction, such as resin-based synthetic carbons.
- Such carbons may, for example, be prepared by polycondensation of an aldehyde and a phenol.
- the physical properties of synthetic carbons may be controlled during manufacturing, allowing them to be tailored to provide desired filtration
- the performance and suitability of porous carbon material as an adsorbent in different environments is determined by various physical properties of the material, including the shape and size of the particles, the pore size, the surface area of the material, and so on. These various parameters may be controlled by manipulating the process and conditions by which the porous carbon is produced.
- the larger the surface area of a porous material the greater is the adsorption capacity of the material.
- the surface area of the material may be increased by increasing the number of pores and making the pores smaller, as the size of the pores approaches the size of the target molecule, it is less likely that the target molecules will enter the pores and adsorb to the material. This is particularly true if the material being filtered has a high flow rate relative to the activated carbon material, as is the case in a smoking article.
- pores in an adsorbent material that are less than 2nm in diameter are referred to as “micropores”
- pores having diameters of between 2nm and 50nm are referred to as “mesopores”
- pores having diameters exceeding 50nm may be referred to as “macropores”.
- Pores having diameters greater than 500nm do not usually contribute significantly to the adsorbency of porous materials.
- HCN hydrogen cyanide
- the present invention seeks to provide a method for preparing porous carbon having enhanced selective adsorption of HCN.
- the porous carbon is a carbonised form of an organic material, such as coconut shell.
- the porous carbon is a resin-based synthetic carbon, such as a carbon prepared by polycondensation of an aldehyde and a phenol to form a resin, which is then carbonised. Commercially available polycondensates may be used.
- the porous carbon is produced using sulfonated styrene-divinylbenzene copolymers, particularly sulfonated
- divinylbenzene-crosslinked polystyrenes preferably in grain form, more preferably in spherical form.
- the divinylbenzene content of the sulfonated styrene-divinylbenzene copolymers used as starting materials should particularly be in the range from 1 to 20% by weight, particularly 1 to 15% by weight, preferably 2 to 10% by weight, based on the styrene-divinylbenzene copolymers.
- the starting copolymers can in principle be selected from the gel type or else from the macroporous type.
- the sulfonation can be carried out in situ (in particular before and/ or during the carbonization), particularly using methods known per se to one sldlled in the art, preferably by means of sulfuric acid and/ or oleum and/ or S0 3 ; diis is familiar per se to one sldlled in the art.
- Starting materials which have proven particularly advantageous are the gel-form or macroporous types of the corresponding ion exchange resins or of the corresponding unsulfonated precursors of ion exchange resins which still have to be sulfonated.
- the carbonization is carried out under an inert atmosphere (for example nitrogen) or at most at a slightly oxidizing atmosphere.
- the inert atmosphere of the carbonization in particular if it is carried out at comparatively high temperatures (for example in the range from about 500 to 650°C) to be admixed with a minor amount of oxygen, in particular in die form of air (for example 1 to 5%) in order that an oxidation of the carbonized polymeric skeleton may be effected and the subsequent activation may thereby be facilitated.
- the carbonization is carried out at temperatures of 100 to 950°C, particularly 150 to 900°C, preferably 300 to 850°C.
- the total duration of the carbonization is approximately 30 minutes to approximately 10 hours, particularly approximately 1 hour to approximately 6 hours.
- the carbonized intermediate product is subjected to activation.
- Activation in an atmosphere comprising water vapour can be used to produce a microporous material.
- a second activated step in an atmosphere comprising C0 2 can be used to yield a material containing mesopores and macropores in addition to micropores,
- the general procedure is for the first activating step to be carried out at temperatures of 700 to 1300°C, particularly 800 to 1200°C, preferably 850 to 950°C, and/or for a duration of 5 to 24 hours, preferably 5 to 15 hours, particularly 6 to 12 hours.
- the duration of the first activation stage can be controlled as a function of the attainment of a predetermined iodine number; for example, the first activation stage can be carried out to attainment of an iodine number of at least 1000 mg/g, particularly at least 1250 mg/g.
- the atmosphere of the first activation stage comprises water vapour, particularly a mixture of water vapor/inert gas, preferably a mixture of water vapour/ itrogen, or consists thereof.
- the presence of activating gases other than water vapor particularly the presence of carbon oxides (C0 2 for example), oxygen and/ or ammonia, may be foreclosed in the context of the first activation stage.
- activating gases other than water vapor particularly the presence of carbon oxides (C0 2 for example), oxygen and/ or ammonia
- C0 2 carbon oxides
- oxygen and/ or ammonia may be foreclosed in the context of the first activation stage.
- Good results are obtained when the throughput or to be more precise the amount of water vapour used is 25 to 350 1/h, particularly 50 to 300 1/h, reckoned as water (i.e., liquid water at 25°C and under atmospheric pressure).
- the amount used or the mass-based throughput of water vapour should advantageously be 0.01 to 50 l/(h'kg), particularly 0.02 to 25 l/(h-kg), preferably 0.02 to 5 l/(h'kg), reckoned as P T/GB2012/051718
- the general procedure for the second activating step is for the second activating step to be carried out at temperatures of 700 to 1300°C, particularly 800 to 1200°C, preferably 850 to 950°C, and/ or for a duration of 1 to 10 hours, particularly 3 to 8 hours.
- the atmosphere of the second activation stage comprises C0 2 , particularly pure C0 2 or a mixture of
- C0 2 /inert gas particularly a mixture of C0 2 /nitrogen, or consists thereof, and pure carbon dioxide is particularly preferred.
- the presence of activating gases other than C0 2 in particular the presence of water vapour, may be foreclosed in the context of the second activation stage. Good results are obtained when the throughput or the amount used of C0 2 is 10 to 250m 3 /h, particularly 20 to 200m 3 /h (based on pure
- the amount used or the mass-based throughput of C0 2 should advantageously be 0.001 to 100m 3 / (h'kg), particularly 0.01 to 50m 3 / (h-kg), preferably 0.05 to 10 m 3 / (h'kg), reckoned as pure gaseous C0 2 under activating conditions, particularly at the respective pressure and the respective temperature, which are selected for the activation, and based on starting material to be activated with C0 2 .
- the process can be carried out such that the first and second activation stages merge into each other (for example by changing the activating atmosphere within the same apparatus).
- Material produced according to the method of some embodiments of the invention will have particles that are small enough to provide a large surface area for smoke filtration.
- the particles of activated carbon material are large enough that the smoke drawn through the filter is not restricted.
- the particles are large enough that they will not become entrained in the smoke and drawn through the filter to be inhaled by the smoker.
- the fragment si3 ⁇ 4e may be configured such that the surface area to volume ratio of the fragments will not reduce the filtration efficiency.
- the spherical, activated carbon used in some embodiments may have a particle size in the range of from ⁇ to 1500 ⁇ .
- the activated carbon used in embodiments of the invention may, for instance, have a particle size which lies within a range, the upper and lower limits of which are defined by any two of the following values that differ from each other, namely 100, 200, 300, 400, 500, 600, 700, 800, 900, 1000, 1100, 1200, 1300, 1400, 1500 ⁇ .
- the mean particle size is between 200jxm and ⁇ , and more preferably between 250 ⁇ and 600 ⁇ .
- the surface areas of activated carbon materials are estimated by measuring the variation of the volume of nitrogen adsorbed by the material in relation to the partial pressure of nitrogen at a constant temperature. Analysis of the results by mathematical models originated by Brunauer, Emmett and Teller results in a value known as the BET surface area.
- the BET surface area of the activated carbon materials used in some embodiments of the present invention is ideally at least 800m 2 /g, preferably at least 900m 2 /g, and desirably at least 1000, 1100, 1150, 1200, 1250, 1300, or 1350m 2 /g.
- Typical values for BET surface area of carbon materials produced by the method of the invention are up to about 1000, 1050, 1100, 1150, 1200, 1250, 1300, 1400, 1500, 1600, 1700, 1800, or 1900m 2 /g.
- Porous carbon materials with BET surface areas of between lOOOmYg and 1800m 2 /g are preferred, and material with surface areas of between 1200m 2 /g and 1600m 2 /g are most preferred.
- the impregnation according to the present invention can work even for activated carbon with a low surface area, for instance down to 450m 2 / .
- the relative volumes of micropores, mesopores and macropores in an activated carbon material can be estimated using well-known nitrogen adsorption and mercury porosimetry techniques.
- Mercury porosimetry can be used to estimate the volume of mesopores and macropores.
- Nitrogen adsorption can be used to estimate the volumes of micropores and mesopores, using the so-called BJH mathematical model.
- the method of the invention can use an activated carbon material having any pore structure that is generally suitable for smoke filtration, i.e. it may include micropores, mesopores or macropores, or any combination thereof.
- an activated carbon material having any pore structure that is generally suitable for smoke filtration, i.e. it may include micropores, mesopores or macropores, or any combination thereof.
- at least 20% but desirably no more than 65% of the pore volume (as estimated by nitrogen adsorption) is in mesopores.
- Typical minimum values for the volume of mesopores as a percentage of the combined micropore and mesopore volumes of the carbon materials of the invention are 25%, 35%, or 45%.
- Typical maximum values for such volumes are 55%, 60%, or 65%.
- the mesopore volume of the carbon materials of the invention is in the range of between 25% and 55% of the combined mesopore and micropore volume.
- the activated carbon used in some embodiments typically has at least 35% of its total pore volume formed by mesopores.
- the micopore : (mesopore + macropore) volume ratio of activated carbon having micropores, mesopores and macropores may be such that the carbon has at least 30% of its pore volume in micopores, for instance from 30% to 90%, o more particularly from 50% to 90%, from 70% to 90% or approximately 80%.
- the porous carbon materials used in some embodiments may have a pore volume (as estimated by nitrogen adsorption), for instance micropore volume, of at least 0.4cm 3 /g, and desirably at least 0.5, 0.6, 0.7, 0.8, or 0.9cm 3 /g.
- a pore volume as estimated by nitrogen adsorption
- Carbon materials with pore volumes of at least 0.5cm 3 /g are particularly useful as an adsorbent for tobacco smoke.
- Carbon materials with pore volumes significantly higher than the preferred values may be low in density, and are therefore less easy to handle in cigarette production equipment, Such carbon materials are less favourable for use in cigarettes or smoke filters for that reason.
- the pore structure and density of activated carbon material are closely related. Generally, the greater the pore volume of the material, the lower is the density.
- Activated carbon materials used in the invention preferably have bulk densities greater than 0.25g/cm 3 , and preferably greater than 0.3g/cm 3 .
- the activated carbon material may have a bulk density of up to 0.7g/ cm 3 , 0.6g/ cm 3 , or 0.5g/ cm 3 .
- An aqueous solution of a metal salt may be used in the present invention. This solution can be applied to the carbon by dip impregnation, spraying, or soaking (incipient wetness). After application, the sample is dried, for example at a temperature between 70 to 90°C for 2 to 24 hours.
- the sample is thermally treated in an oven under a nitrogen atmosphere to thermally decompose the metal salt.
- the nitrogen volume stream may be between 250 to 7501/hour, preferably between 400 to 6001/hour, most preferably about 5001/hour.
- the temperature program may start at 5, 10, 15, 20 25, 30, 35, 40, 45, 50°C and with 1, 2, 3, 5, 6, 8, 10, 12, 14, 16K/ minute, with the temperature being increased up to 550°C, preferably up to 450°C and more preferably up to 350°C.
- the temperature is kept at the aforementioned temperature for one to six, preferably two to four, or even more preferably three hours before the material may be cooled down and ready to use.
- the porous carbon is not washed after application of the metal salt to remove excess salt.
- the resulting carbon is impregnated with at least 0.25% but desirably no more than 20% metal oxide by weight of carbon.
- the activated carbon used in embodiments of the invention may, for instance, be impregnated with upper and lower Umits of metal oxide defined by any two of the following values that differ from each other, namely 0.25, 0.3, 0.4, 0.5, 0.6, 0.7, 0.8, 0.9, 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20%.
- Typical values are between 0.25% or 5%, preferably from 0.5% to 5% metal oxide by weight of carbon is impregnated.
- Impregnating more metal oxide can result in a lowering of the surface area.
- the pores may, for instance, be over filled with oxide leaving less space for smoke, which could cause a reduction in the adsorption of other vapour phase constituents.
- the metal oxide is able to bind to the HCN (ZnO + 2HCN ⁇ Zn(CN) 2 + H 2 0) thereby filtering it out of smoke, particularly mainstream smoke that is inhaled during smoking.
- This advantageously does not result in the production of cyanogen (CN) 2 , or does not result in the production of a substantial amount of cyanogen (CN) 2 .
- any production of cyanogen may be below levels detectable by known techniques.
- the activated carbon of high meso- and macro- porosity used is characterized by a spherical shape and size between 0.25 and 0.6 mm; at least 35% of the total pore volume being formed by pores having a diameter of more than 20A; and a BET surface area of at least 1250m /g.
- the activated carbon is obtained by a process comprising two-stage activation using steam and subsequent carbon dioxide activation and is referred to as product no. 100797 from Blucher GmbH. See International publication number WO2008/110233, where this process is described in further detail.
- the activated carbon used in the embodiments of the present invention has excellent abrasion and bursting resistance, so that it is useful in a multiplicity of different applications.
- Figure 1 shows the nitrogen isotherm of 100797 impregnated with 1% ZnO 60mg of carbon was inserted into a cavity filter of a reference cigarette. As a control and to allow percentage reductions in smoke components to be determined, a cigarette with empty filter cavity of similar dimensions was used.
- Cigarettes were conditioned at 22°C and 60% Relative Humidity for a period of three weeks prior to smoking under standard ISO smoking conditions (one 35ml volume puff of 2s durations taken every one minute).
- Smoke constituents including HCN were measured and results are shown in Table 2 using base carbon and carbon impregnated at levels of 1, 3, 5 and 10% ZnO. Cyanogen was not detected in the smoke.
- Table 2
- the raw data presented in Table 2 when converted to percentages shows that the zinc oxide impregnated activated carbon prepared above with 1% zinc oxide impregnation, reduced the percentage of HCN in smoke by 71%, whereas the carbons with no zinc oxide impregnation only reduced the HCN by 47%.
- the carbons with 3%, 5% and 10% zinc oxide impregnation resulted in a 76, 76 and 78% reduction in HCN, respectively.
- a smoking article 1 is schematically illustrated comprising a filter section 2 having a substantially cylindrical plug of material 3 wrapped in a plug wrap 4 around its circumferential surface.
- the end faces of the plug of filter material 3 are left unwrapped.
- the filter material 3 can comprise cellulose acetate material, for instance in the form of fibres.
- the porous carbon granules 5 as described herein, for instance impregnated with metal oxide, according to the embodiments of the invention, can be dispersed within the filter material 3, resulting in a filter arrangement generally referred to a "Dalmatian" filter.
- the filter section 2 may comprise a plurality of axially aligned sections, with each section comprising one or more of cellulose acetate, activated carbon, for instance granules 5 as described herein, and/ or other additives such as flavourant.
- the filter section 2 may, alternatively, comprise porous carbon granules as described herein, according to embodiments of the invention, arranged in a filter cavity, for instance formed between two cellulose acetate filter elements.
- a rod of smokable material 6 wrapped around its circumferential surface by a cigarette paper 7 is also provided.
- the filter section 2 is joined to the smokable material 6 using a tipping paper 8 to form the smoking article 1.
- the filter material 3 and/ of smokable mateiial fod 6 can be ventilated, for instance using ventilation holes (not shown) provided in the tipping paper 8, plug wrap 4 and/or cigarette paper 7.
- Example indicates that applying zinc oxide to activated carbon according to a method of the invention provides porous carbon having enhanced adsorption of smoke vapour constituents, such as HCN, for instance when compared to porous carbon which has not been impregnated with zinc oxide.
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- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Carbon And Carbon Compounds (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
Abstract
Description
Claims
Priority Applications (11)
Application Number | Priority Date | Filing Date | Title |
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CN201280035614.2A CN103687806A (en) | 2011-07-21 | 2012-07-18 | Porous carbon and methods of production thereof |
US14/233,950 US9642394B2 (en) | 2011-07-21 | 2012-07-18 | Porous carbon and methods of production thereof |
CA2838913A CA2838913C (en) | 2011-07-21 | 2012-07-18 | Porous carbon and methods of production thereof |
KR1020147004620A KR101898078B1 (en) | 2011-07-21 | 2012-07-18 | Porous carbon and methods of production thereof |
UAA201401619A UA113414C2 (en) | 2011-07-21 | 2012-07-18 | APPLICATION OF ACTIVATED CARBON DISTRIBUTED BY ZINC OXIDE FOR THE SELECTIVE ADSORPTION OF HYANIUM CYANIDE |
EP12741059.5A EP2734469A1 (en) | 2011-07-21 | 2012-07-18 | Porous carbon and methods of production thereof |
AU2012285504A AU2012285504B2 (en) | 2011-07-21 | 2012-07-18 | Porous carbon and methods of production thereof |
JP2014520726A JP2014523849A (en) | 2011-07-21 | 2012-07-18 | Porous carbon and method for producing the same |
BR112013033174A BR112013033174A2 (en) | 2011-07-21 | 2012-07-18 | method for improving selectivity of porous carbon to hydrocyanic acid, porous carbon, filter element and smoke article |
RU2014106345/05A RU2602116C2 (en) | 2011-07-21 | 2012-07-18 | Porous coal and methods for production thereof |
ZA2014/00064A ZA201400064B (en) | 2011-07-21 | 2014-01-06 | Porous carbon and methods of production thereof |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1112539.0 | 2011-07-21 | ||
GBGB1112539.0A GB201112539D0 (en) | 2011-07-21 | 2011-07-21 | Porous carbon and methods of production thereof |
GBGB1113839.3A GB201113839D0 (en) | 2011-07-21 | 2011-08-11 | Porous carbon and methods of production thereof |
GB1113839.3 | 2011-08-11 |
Publications (1)
Publication Number | Publication Date |
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WO2013011312A1 true WO2013011312A1 (en) | 2013-01-24 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/GB2012/051718 WO2013011312A1 (en) | 2011-07-21 | 2012-07-18 | Porous carbon and methods of production thereof |
Country Status (15)
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---|---|
US (1) | US9642394B2 (en) |
EP (1) | EP2734469A1 (en) |
JP (2) | JP2014523849A (en) |
KR (1) | KR101898078B1 (en) |
CN (2) | CN107758663A (en) |
AR (1) | AR088027A1 (en) |
AU (1) | AU2012285504B2 (en) |
BR (1) | BR112013033174A2 (en) |
CA (1) | CA2838913C (en) |
GB (2) | GB201112539D0 (en) |
RU (1) | RU2602116C2 (en) |
TW (1) | TW201323330A (en) |
UA (1) | UA113414C2 (en) |
WO (1) | WO2013011312A1 (en) |
ZA (1) | ZA201400064B (en) |
Cited By (4)
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CN103393219A (en) * | 2013-08-14 | 2013-11-20 | 中国烟草总公司郑州烟草研究院 | Modified natural plant filter tip additive material capable of selectively reducing burst size of hydrogen cyanide in main stream smoke of cigarettes and preparation method of modified natural plant filter tip additive material |
WO2015075452A1 (en) * | 2013-11-22 | 2015-05-28 | British American Tobacco (Investments) Limited | Adsorbent materials |
US9352297B2 (en) | 2013-11-27 | 2016-05-31 | King Fahd University Of Petroleum And Minerals | Methods for preparing composites of activated carbon/zinc oxide and activated carbon/zinc oxide/nickel oxide for desulfurization of fuels |
JP2017503477A (en) * | 2013-12-20 | 2017-02-02 | フィリップ・モーリス・プロダクツ・ソシエテ・アノニム | Smoking articles with filters containing capsules |
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3251365A (en) * | 1963-03-04 | 1966-05-17 | Ii Charles H Keith | Tobacco smoke filter |
US3355317A (en) * | 1966-03-18 | 1967-11-28 | Liggett & Myers Tobacco Co | Process of impregnating adsorbent materials with metal oxides |
US3460543A (en) * | 1966-03-21 | 1969-08-12 | Liggett & Myers Inc | Cigarette filter |
US6344071B1 (en) * | 2000-05-22 | 2002-02-05 | 3M Innovative Properties Company | Broad spectrum filter system for filtering contaminants from air or other gases |
WO2008110233A1 (en) | 2007-03-14 | 2008-09-18 | BLüCHER GMBH | High-performance adsorbents based on activated carbon having high meso- and macroporosity |
WO2010059607A1 (en) * | 2008-11-20 | 2010-05-27 | R.J. Reynolds Tobacco Company | Carbonaceous material having modified pore structure |
Family Cites Families (61)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB437039A (en) | 1934-04-26 | 1935-10-23 | Abraham Wix | Improvements in or relating to the manufacture of cigarettes |
US2963441A (en) * | 1944-11-23 | 1960-12-06 | Frank E Dolian | Sorbents and process for their preparation |
BE686826A (en) | 1965-09-20 | 1967-02-15 | ||
GB1200219A (en) | 1966-12-13 | 1970-07-29 | Mitsubishi Rayon Co | Cigarette filters |
CH506958A (en) | 1967-03-01 | 1971-05-15 | Ceskoslovenska Akademie Ved | Tobacco smoke filter contg silica gel and - active carbon |
US3621851A (en) | 1969-11-26 | 1971-11-23 | Kata Mfg & Filtering Co | Filter for smoker's article |
US3618619A (en) | 1970-03-03 | 1971-11-09 | Eastman Kodak Co | Tobacco smoke filters |
GB1284673A (en) | 1970-04-20 | 1972-08-09 | British American Tobacco Co | Improvements relating to tobacco-smoke filters |
GB1342931A (en) | 1970-10-07 | 1974-01-10 | British American Tobacco Co | Smoking articles |
GB1331096A (en) | 1970-10-07 | 1973-09-19 | British American Tobacco Co | Tobacco-smoke filters |
US3802441A (en) | 1972-01-26 | 1974-04-09 | Brown & Williamson Tobacco | Tobacco smoke filter additive |
US3889691A (en) | 1973-12-21 | 1975-06-17 | Calgon Corp | Tobacco smoke filter |
US4091822A (en) | 1975-04-25 | 1978-05-30 | Loews Theatres, Inc. | Article for the selective removal of hydrogen cyanide from tobacco smoke |
US4221226A (en) | 1979-02-15 | 1980-09-09 | Eastman Kodak Company | Hot melt adhesive for bonding filter tow, and filter elements bonded thereby |
GB8605860D0 (en) * | 1986-03-10 | 1986-04-16 | Secr Defence | Impregnated activated carbon |
EP0250806A3 (en) | 1986-06-30 | 1988-06-01 | Hercules Incorporated | Method and device for removing nitric oxide from cigarette smoke |
US5105836A (en) | 1989-09-29 | 1992-04-21 | R. J. Reynolds Tobacco Company | Cigarette and smokable filler material therefor |
ATE141468T1 (en) | 1990-10-04 | 1996-09-15 | Eastman Chem Co | COMPOSITION FOR IMPROVED DELIVERY OF TOBACCO MODIFICANTS |
WO1993010896A1 (en) | 1991-11-27 | 1993-06-10 | Calgon Carbon Corporation | Chromium-free impregnated activated universal respirator carbon for adsorption of toxic gases and/or vapors |
US5344626A (en) * | 1992-06-26 | 1994-09-06 | Minnesota Mining And Manufacturing Company | Dual impregnated activated carbon |
US5275859A (en) | 1992-12-21 | 1994-01-04 | Eastman Kodak Company | Tobacco smoke filter |
JPH0780299A (en) * | 1993-09-14 | 1995-03-28 | Kuraray Chem Corp | Metal oxide added activated carbon catalyst |
RU2138441C1 (en) * | 1998-03-02 | 1999-09-27 | ОАО "Электростальский химико-механический завод" | Method of preparing acidic gas absorbent |
US6789548B2 (en) | 2000-11-10 | 2004-09-14 | Vector Tobacco Ltd. | Method of making a smoking composition |
US7071249B2 (en) | 2001-10-05 | 2006-07-04 | William Ho | Biodegradable starch resin and method for making same |
RU2207903C2 (en) * | 2001-10-08 | 2003-07-10 | Закрытое акционерное общество "Сорбент - Центр Внедрение" | Respiratory apparatus protection means adsorbent |
EP1441603A2 (en) | 2001-11-09 | 2004-08-04 | Vector Tobacco Inc. | Method and composition for mentholation of charcoal filtered cigarettes |
JP2005512554A (en) | 2001-12-19 | 2005-05-12 | ベクター・タバコ・インコーポレーテッド | Method and composition for imparting a cooling effect to tobacco products |
WO2003053177A1 (en) | 2001-12-19 | 2003-07-03 | Vector Tobacco Inc. | Method and composition for mentholation of cigarettes |
MY135471A (en) | 2002-01-09 | 2008-04-30 | Philip Morris Prod | Cigarette filter with beaded carbon |
GB0209690D0 (en) | 2002-04-27 | 2002-06-05 | British American Tobacco Co | Improvements relating to smoking articles and smokable filler materials therefor |
JP2004091276A (en) * | 2002-09-02 | 2004-03-25 | Hitachi Plant Eng & Constr Co Ltd | Activated carbon for adsorption of arsenic and its manufacturing method |
US7243658B2 (en) | 2003-06-13 | 2007-07-17 | Philip Morris Usa Inc. | Nanoscale composite catalyst to reduce carbon monoxide in the mainstream smoke of a cigarette |
US9107452B2 (en) | 2003-06-13 | 2015-08-18 | Philip Morris Usa Inc. | Catalyst to reduce carbon monoxide in the mainstream smoke of a cigarette |
GB0324464D0 (en) * | 2003-10-20 | 2003-11-19 | Filtrona Int Ltd | Tobacco smoke filter |
US8439047B2 (en) | 2003-12-22 | 2013-05-14 | Philip Morris Usa Inc. | Composite mesoporous/microporous materials and their use in smoking articles for removing certain gas phase constituents from tobacco smoke |
EP1729603A1 (en) | 2004-04-02 | 2006-12-13 | Reemtsma Cigarettenfabriken GmbH | Tobacco smoke filter |
US20050247323A1 (en) | 2004-05-10 | 2005-11-10 | Brown & Williamson Tobacco Corporation | Selective filtration of cigarette smoke using chitosan derivatives |
GB0411988D0 (en) | 2004-05-28 | 2004-06-30 | British American Tobacco Co | Smoking articles and smoking materials |
US20060144410A1 (en) | 2004-12-30 | 2006-07-06 | Philip Morris Usa Inc. | Surface-modified activated carbon in smoking articles |
US8539957B2 (en) | 2005-01-14 | 2013-09-24 | Philip Morris Usa Inc. | Cigarettes and cigarette filters including activated carbon for removing nitric oxide |
US20070000505A1 (en) | 2005-02-24 | 2007-01-04 | Philip Morris Usa Inc. | Smoking article with tobacco beads |
US7622421B2 (en) | 2005-03-11 | 2009-11-24 | Philip Morris Usa Inc. | Catalysts for low temperature oxidation of carbon monoxide |
US7503960B2 (en) | 2005-03-15 | 2009-03-17 | Philip Morris Usa Inc. | Smoking articles and filters with carbon fiber composite molecular sieve sorbent |
GB0506278D0 (en) | 2005-03-29 | 2005-05-04 | British American Tobacco Co | Porous carbon materials and smoking articles and smoke filters therefor incorporating such materials |
GB0517551D0 (en) | 2005-08-27 | 2005-10-05 | Acetate Products Ltd | Process for making filter tow |
US8578943B2 (en) | 2005-12-20 | 2013-11-12 | Philip Morris Usa Inc. | Metal-containing nanowires prepared using mesoporous molecular sieves as templates, and their use in smoking articles for removing certain gas phase constituents from tobacco smoke |
PT2077731E (en) | 2006-01-17 | 2011-09-19 | Philip Morris Prod | Cigarette components having encapsulated catalyst particles and methods of making and use thereof |
US7569510B2 (en) | 2006-02-27 | 2009-08-04 | Philip Morris Usa Inc. | Catalysts to reduce carbon monoxide such as in the mainstream smoke of a cigarette |
ATE465650T1 (en) * | 2006-03-10 | 2010-05-15 | British American Tobacco Co | SMOKING ARTICLE FILTER |
CN100462139C (en) | 2006-06-08 | 2009-02-18 | 张洪图 | Method of preparing transition metal modified activated carbon for eliminating harmful substance |
US20100108083A1 (en) | 2007-04-17 | 2010-05-06 | Laurent Schwartz | Use of means for trapping co2 in a filter for preventing inflammation, cancer and cardiovascular diseases in a subject exposed to tobacco smoke |
US20080293565A1 (en) * | 2007-05-24 | 2008-11-27 | Calgon Carbon Corporation | Metal impregnated activated carbons and method of making same |
US8555896B2 (en) | 2007-12-19 | 2013-10-15 | Philip Morris Usa Inc. | Activated carbon from microcrystalline cellulose |
WO2009123023A1 (en) | 2008-04-01 | 2009-10-08 | 日本たばこ産業株式会社 | Cigarette filters |
EP2276359A2 (en) * | 2008-04-14 | 2011-01-26 | NanoScale Corporation | Method for neutralization, adsorption, and absorption of hazardous or otherwise undesired compounds in a tobacco product |
EP2130444A1 (en) | 2008-06-06 | 2009-12-09 | Xavier Wertz | Smokable material and smokable articles |
CA2735717A1 (en) | 2008-09-02 | 2010-03-11 | Allen R. Siedle | Ammonia-free gaseous air filter |
US20100122515A1 (en) * | 2008-11-18 | 2010-05-20 | Han-Wen Kuo | Poison-filter material and production method thereof |
US8511319B2 (en) | 2008-11-20 | 2013-08-20 | R. J. Reynolds Tobacco Company | Adsorbent material impregnated with metal oxide component |
CN101524186B (en) | 2009-04-09 | 2011-02-16 | 云南烟草科学研究院 | Filter additive for reducing content of hydrocyanic acid in smoke of cigarette and preparation method thereof |
-
2011
- 2011-07-21 GB GBGB1112539.0A patent/GB201112539D0/en not_active Ceased
- 2011-08-11 GB GBGB1113839.3A patent/GB201113839D0/en not_active Ceased
-
2012
- 2012-07-18 EP EP12741059.5A patent/EP2734469A1/en not_active Withdrawn
- 2012-07-18 CA CA2838913A patent/CA2838913C/en not_active Expired - Fee Related
- 2012-07-18 CN CN201710952452.3A patent/CN107758663A/en active Pending
- 2012-07-18 KR KR1020147004620A patent/KR101898078B1/en active IP Right Grant
- 2012-07-18 RU RU2014106345/05A patent/RU2602116C2/en active
- 2012-07-18 US US14/233,950 patent/US9642394B2/en not_active Expired - Fee Related
- 2012-07-18 CN CN201280035614.2A patent/CN103687806A/en active Pending
- 2012-07-18 BR BR112013033174A patent/BR112013033174A2/en not_active Application Discontinuation
- 2012-07-18 UA UAA201401619A patent/UA113414C2/en unknown
- 2012-07-18 JP JP2014520726A patent/JP2014523849A/en active Pending
- 2012-07-18 AU AU2012285504A patent/AU2012285504B2/en not_active Ceased
- 2012-07-18 WO PCT/GB2012/051718 patent/WO2013011312A1/en active Application Filing
- 2012-07-20 TW TW101126136A patent/TW201323330A/en unknown
- 2012-07-20 AR ARP120102635A patent/AR088027A1/en unknown
-
2014
- 2014-01-06 ZA ZA2014/00064A patent/ZA201400064B/en unknown
-
2016
- 2016-06-28 JP JP2016127375A patent/JP6212174B2/en not_active Expired - Fee Related
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3251365A (en) * | 1963-03-04 | 1966-05-17 | Ii Charles H Keith | Tobacco smoke filter |
US3355317A (en) * | 1966-03-18 | 1967-11-28 | Liggett & Myers Tobacco Co | Process of impregnating adsorbent materials with metal oxides |
US3460543A (en) * | 1966-03-21 | 1969-08-12 | Liggett & Myers Inc | Cigarette filter |
US6344071B1 (en) * | 2000-05-22 | 2002-02-05 | 3M Innovative Properties Company | Broad spectrum filter system for filtering contaminants from air or other gases |
WO2008110233A1 (en) | 2007-03-14 | 2008-09-18 | BLüCHER GMBH | High-performance adsorbents based on activated carbon having high meso- and macroporosity |
WO2010059607A1 (en) * | 2008-11-20 | 2010-05-27 | R.J. Reynolds Tobacco Company | Carbonaceous material having modified pore structure |
Non-Patent Citations (2)
Title |
---|
ADSOLPTIOLL, vol. 14, 2008, pages 335 - 341 |
BYRAPPA K ET AL: "Impregnation of ZnO onto activated carbon under hydrothermal conditions and its photocatalytic properties", JOURNAL OF MATERIALS SCIENCE, KLUWER ACADEMIC PUBLISHERS, BO, vol. 41, no. 5, 1 March 2006 (2006-03-01), pages 1355 - 1362, XP019211638, ISSN: 1573-4803, DOI: 10.1007/S10853-006-7341-X * |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103393219A (en) * | 2013-08-14 | 2013-11-20 | 中国烟草总公司郑州烟草研究院 | Modified natural plant filter tip additive material capable of selectively reducing burst size of hydrogen cyanide in main stream smoke of cigarettes and preparation method of modified natural plant filter tip additive material |
CN103393219B (en) * | 2013-08-14 | 2014-09-24 | 中国烟草总公司郑州烟草研究院 | Modified natural plant filter tip additive material capable of selectively reducing burst size of hydrogen cyanide in main stream smoke of cigarettes and preparation method of modified natural plant filter tip additive material |
WO2015075452A1 (en) * | 2013-11-22 | 2015-05-28 | British American Tobacco (Investments) Limited | Adsorbent materials |
US9352297B2 (en) | 2013-11-27 | 2016-05-31 | King Fahd University Of Petroleum And Minerals | Methods for preparing composites of activated carbon/zinc oxide and activated carbon/zinc oxide/nickel oxide for desulfurization of fuels |
JP2017503477A (en) * | 2013-12-20 | 2017-02-02 | フィリップ・モーリス・プロダクツ・ソシエテ・アノニム | Smoking articles with filters containing capsules |
JP2020000261A (en) * | 2013-12-20 | 2020-01-09 | フィリップ・モーリス・プロダクツ・ソシエテ・アノニム | Smoking article having filter including a capsule |
US11178907B2 (en) | 2013-12-20 | 2021-11-23 | Philip Morris Products S.A. | Smoking article having a filter including a capsule |
JP7254674B2 (en) | 2013-12-20 | 2023-04-10 | フィリップ・モーリス・プロダクツ・ソシエテ・アノニム | Smoking articles with filters containing capsules |
Also Published As
Publication number | Publication date |
---|---|
TW201323330A (en) | 2013-06-16 |
US9642394B2 (en) | 2017-05-09 |
CA2838913C (en) | 2018-01-30 |
KR20140054113A (en) | 2014-05-08 |
RU2014106345A (en) | 2015-08-27 |
JP2017019711A (en) | 2017-01-26 |
AU2012285504A1 (en) | 2014-01-16 |
JP2014523849A (en) | 2014-09-18 |
UA113414C2 (en) | 2017-01-25 |
GB201113839D0 (en) | 2011-09-28 |
ZA201400064B (en) | 2017-05-31 |
KR101898078B1 (en) | 2018-09-12 |
BR112013033174A2 (en) | 2017-03-01 |
AR088027A1 (en) | 2014-05-07 |
GB201112539D0 (en) | 2011-08-31 |
AU2012285504B2 (en) | 2015-01-15 |
RU2602116C2 (en) | 2016-11-10 |
CA2838913A1 (en) | 2013-12-04 |
US20140216487A1 (en) | 2014-08-07 |
EP2734469A1 (en) | 2014-05-28 |
JP6212174B2 (en) | 2017-10-11 |
CN107758663A (en) | 2018-03-06 |
CN103687806A (en) | 2014-03-26 |
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