WO2013006374A3 - Methods for preparing integral catalysts while maintaining zeolite acidity and catalysts made thereby - Google Patents

Methods for preparing integral catalysts while maintaining zeolite acidity and catalysts made thereby Download PDF

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Publication number
WO2013006374A3
WO2013006374A3 PCT/US2012/044638 US2012044638W WO2013006374A3 WO 2013006374 A3 WO2013006374 A3 WO 2013006374A3 US 2012044638 W US2012044638 W US 2012044638W WO 2013006374 A3 WO2013006374 A3 WO 2013006374A3
Authority
WO
WIPO (PCT)
Prior art keywords
zeolite
transition metal
catalyst
catalysts
methods
Prior art date
Application number
PCT/US2012/044638
Other languages
French (fr)
Other versions
WO2013006374A2 (en
Inventor
Howard S. Lacheen
Robert J. Saxton
Original Assignee
Chevron U.S.A. Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US13/327,233 external-priority patent/US20130157841A1/en
Application filed by Chevron U.S.A. Inc. filed Critical Chevron U.S.A. Inc.
Priority to BR112013027179A priority Critical patent/BR112013027179A2/en
Priority to CA2835886A priority patent/CA2835886A1/en
Priority to EP12807988.6A priority patent/EP2726205A4/en
Priority to AU2012279306A priority patent/AU2012279306A1/en
Priority to CN201280027156.8A priority patent/CN103582527A/en
Priority to JP2014519023A priority patent/JP2014520664A/en
Publication of WO2013006374A2 publication Critical patent/WO2013006374A2/en
Publication of WO2013006374A3 publication Critical patent/WO2013006374A3/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/061—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing metallic elements added to the zeolite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • B01J29/068—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • B01J29/072—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/076—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/46—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/334—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing molecular sieve catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/40—Special temperature treatment, i.e. other than just for template removal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Methods for preparing catalysts including a transition metal component and a zeolite component are disclosed. In some embodiments, the transition metal is deposited in a precursor solution onto a zeolite extrudate to form an intermediate integral catalyst wherein prior to the deposition, the zeolite has been subjected to an initial ion exchange with protecting cations which exchange with the protons of the zeolite. The intermediate integral catalyst is heated to decompose the transition metal, and the catalyst is subsequently subjected to a secondary ion exchange with an ionic ammonium complex which exchanges with the protecting cations. The resulting ammonium treated catalyst is heated to a temperature sufficient to decompose the ammonium complex to form ammonia and H+ ions. The transition metal in the resulting catalyst is in the form of reduced crystallites located outside the zeolite channels. No appreciable ion exchange of the transition metal occurs within the zeolite channels.
PCT/US2012/044638 2011-07-01 2012-06-28 Methods for preparing integral catalysts while maintaining zeolite acidity and catalysts made thereby WO2013006374A2 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
BR112013027179A BR112013027179A2 (en) 2011-07-01 2012-06-28 methods for preparing integral catalysts while maintaining zeolite acidity and catalysts made by them
CA2835886A CA2835886A1 (en) 2011-07-01 2012-06-28 Methods for preparing integral catalysts while maintaining zeolite acidity and catalysts made thereby
EP12807988.6A EP2726205A4 (en) 2011-07-01 2012-06-28 Methods for preparing integral catalysts while maintaining zeolite acidity and catalysts made thereby
AU2012279306A AU2012279306A1 (en) 2011-07-01 2012-06-28 Methods for preparing integral catalysts while maintaining zeolite acidity and catalysts made thereby
CN201280027156.8A CN103582527A (en) 2011-07-01 2012-06-28 Methods for preparing integral catalysts while maintaining zeolite acidity and catalysts made thereby
JP2014519023A JP2014520664A (en) 2011-07-01 2012-06-28 Method for producing a monolithic catalyst while maintaining the acidity of the zeolite and the catalyst produced thereby

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US201161503990P 2011-07-01 2011-07-01
US61/503,990 2011-07-01
US13/327,233 2011-12-15
US13/327,233 US20130157841A1 (en) 2011-12-15 2011-12-15 Methods for preparing integral catalysts while maintaining zeolite acidity and catalysts made thereby

Publications (2)

Publication Number Publication Date
WO2013006374A2 WO2013006374A2 (en) 2013-01-10
WO2013006374A3 true WO2013006374A3 (en) 2013-04-04

Family

ID=47437635

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2012/044638 WO2013006374A2 (en) 2011-07-01 2012-06-28 Methods for preparing integral catalysts while maintaining zeolite acidity and catalysts made thereby

Country Status (7)

Country Link
EP (1) EP2726205A4 (en)
JP (1) JP2014520664A (en)
CN (1) CN103582527A (en)
AU (1) AU2012279306A1 (en)
BR (1) BR112013027179A2 (en)
CA (1) CA2835886A1 (en)
WO (1) WO2013006374A2 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2995377A1 (en) 2014-09-09 2016-03-16 ETH Zurich Catalytic materials based on functionalized ZSM-5
CN111646483A (en) * 2020-06-12 2020-09-11 浙江浙能技术研究院有限公司 Ru-SSZ-13 molecular sieve and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4515681A (en) * 1982-09-08 1985-05-07 Exxon Research & Engineering Co. Catalytic dewaxing using collapsed large pore zeolites
US20100160464A1 (en) * 2008-12-24 2010-06-24 Chevron U.S.A. Inc. Zeolite Supported Cobalt Hybrid Fischer-Tropsch Catalyst
US7943674B1 (en) * 2009-11-20 2011-05-17 Chevron U.S.A. Inc. Zeolite supported cobalt hybrid fischer-tropsch catalyst

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4255349A (en) * 1978-12-18 1981-03-10 Mobil Oil Corporation Conversion of synthesis gas with iron-containing catalyst
US4665042A (en) * 1985-05-14 1987-05-12 The Standard Oil Company Catalysts for the conversion of syn gas
US6852214B1 (en) * 1998-08-31 2005-02-08 Mobil Oil Corporation Gasoline sulfur reduction in fluid catalytic cracking
US20060088469A1 (en) * 2002-11-25 2006-04-27 Yara International Asa Method for preparation and activation of multimetallic zeolite catalysts, a catalyst composition and application for n2o abatement

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4515681A (en) * 1982-09-08 1985-05-07 Exxon Research & Engineering Co. Catalytic dewaxing using collapsed large pore zeolites
US20100160464A1 (en) * 2008-12-24 2010-06-24 Chevron U.S.A. Inc. Zeolite Supported Cobalt Hybrid Fischer-Tropsch Catalyst
US7943674B1 (en) * 2009-11-20 2011-05-17 Chevron U.S.A. Inc. Zeolite supported cobalt hybrid fischer-tropsch catalyst

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP2726205A4 *

Also Published As

Publication number Publication date
AU2012279306A1 (en) 2013-11-07
CN103582527A (en) 2014-02-12
WO2013006374A2 (en) 2013-01-10
EP2726205A4 (en) 2015-08-19
JP2014520664A (en) 2014-08-25
BR112013027179A2 (en) 2017-01-17
EP2726205A2 (en) 2014-05-07
CA2835886A1 (en) 2013-01-10

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