WO2013003225A3 - Vegetable-oil derived plasticizer - Google Patents

Vegetable-oil derived plasticizer Download PDF

Info

Publication number
WO2013003225A3
WO2013003225A3 PCT/US2012/043740 US2012043740W WO2013003225A3 WO 2013003225 A3 WO2013003225 A3 WO 2013003225A3 US 2012043740 W US2012043740 W US 2012043740W WO 2013003225 A3 WO2013003225 A3 WO 2013003225A3
Authority
WO
WIPO (PCT)
Prior art keywords
vegetable
oil derived
derived plasticizer
oil
plasticizer
Prior art date
Application number
PCT/US2012/043740
Other languages
French (fr)
Other versions
WO2013003225A2 (en
Inventor
Abhijit Ghosh-Dastidar
Robert F. Eaton
Antoni Adamczyk
Bruce M. Bell
Robert M. Campbell
Original Assignee
Dow Global Technologies Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Llc filed Critical Dow Global Technologies Llc
Publication of WO2013003225A2 publication Critical patent/WO2013003225A2/en
Publication of WO2013003225A3 publication Critical patent/WO2013003225A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/003—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fatty acids with alcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/02—Polycondensates containing more than one epoxy group per molecule
    • C08G59/027—Polycondensates containing more than one epoxy group per molecule obtained by epoxidation of unsaturated precursor, e.g. polymer or monomer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/14—Polycondensates modified by chemical after-treatment
    • C08G59/1433—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
    • C08G59/1438—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds containing oxygen
    • C08G59/1455—Monocarboxylic acids, anhydrides, halides, or low-molecular-weight esters thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0016—Plasticisers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/15—Heterocyclic compounds having oxygen in the ring
    • C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
    • C08K5/1515—Three-membered rings
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/101—Esters; Ether-esters of monocarboxylic acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Emergency Medicine (AREA)
  • Fats And Perfumes (AREA)
  • Epoxy Compounds (AREA)

Abstract

Green plasticizers are made by a process comprising the steps, in any order, of epoxidizing and transesterifying a natural oil, e.g., corn, sunflower, etc., having (1) an iodine number (IV) of 60 or more, and (2) a linolenic acid content of 5 weight percent (wt%) or less based on the weight of the oil.
PCT/US2012/043740 2011-06-29 2012-06-22 Vegetable-oil derived plasticizer WO2013003225A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201161502579P 2011-06-29 2011-06-29
US61/502,579 2011-06-29

Publications (2)

Publication Number Publication Date
WO2013003225A2 WO2013003225A2 (en) 2013-01-03
WO2013003225A3 true WO2013003225A3 (en) 2013-03-14

Family

ID=46513835

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2012/043740 WO2013003225A2 (en) 2011-06-29 2012-06-22 Vegetable-oil derived plasticizer

Country Status (2)

Country Link
TW (1) TW201305100A (en)
WO (1) WO2013003225A2 (en)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8557139B2 (en) 2008-02-15 2013-10-15 Dow Global Technologies Llc Replacement plasticizer system for phthalate-plasticized formulations
WO2011041388A1 (en) 2009-09-30 2011-04-07 Dow Global Technologies Inc. Acetylated glyceride of 12-hydroxystearic acid and blends with epoxidized fatty acid esters
US8552098B2 (en) 2009-09-30 2013-10-08 Dow Global Technologies Llc Purified acetylated derivatives of castor oil and compositions including same
CN102648237B (en) 2009-09-30 2015-04-22 陶氏环球技术有限责任公司 Acetylated derivatives of castor oil and their blends with epoxidized fatty acid esters
EP2470597B1 (en) 2009-09-30 2013-09-04 Dow Global Technologies LLC Heat stabilized polymeric composition with epoxidized fatty acid ester plasticizer
BR112012028732B1 (en) 2010-05-10 2020-04-07 Dow Global Technologies Llc composition and wire or cable
TW201209168A (en) 2010-07-28 2012-03-01 Dow Global Technologies Llc Plasticizers made from oil extracted from microorganisms and polar polymeric compositions comprising the same
SG10201508216WA (en) 2011-10-14 2015-11-27 Galata Chemicals Llc Plasticizers derived from renewable feedstock
WO2013119402A1 (en) * 2012-02-08 2013-08-15 Dow Global Technologies Llc Plasticizer compositions and methods for making plasticizer compositions
KR102088075B1 (en) 2012-06-22 2020-03-11 다우 글로벌 테크놀로지스 엘엘씨 Acetylated polyol hydroxystearate plasticizers and plasticized polymeric compositions
EP2864406B1 (en) 2012-06-26 2017-03-08 Dow Global Technologies LLC Plasticizers and plasticized polymeric compositions
MX370205B (en) 2012-10-18 2019-12-05 Dow Global Technologies Llc Epoxidized fatty acid alkyl ester plasticizers and methods for making epoxidized fatty acid alkyl ester plasticizers.
KR102017370B1 (en) 2012-11-12 2019-09-02 다우 글로벌 테크놀로지스 엘엘씨 Epoxidized fatty acid alkyl ester plasticizers and methods for making epoxidized fatty acid alkyl ester plasticizers
US9593091B2 (en) 2012-11-12 2017-03-14 Dow Global Technologies Llc Methods for making epoxidized fatty acid alkyl esters
DE102013203973A1 (en) 2013-03-08 2014-09-11 Evonik Industries Ag Isononyl ester based on fatty acid mixtures of vegetable oils
DE102013203972A1 (en) * 2013-03-08 2014-09-11 Evonik Industries Ag Isononyl esters based on fatty acids or fatty acid mixtures of tall oil or linseed oil
EP2990470A1 (en) 2014-08-26 2016-03-02 Evonik Degussa GmbH Mixed epoxidised fatty acid esters
KR101789035B1 (en) 2015-02-10 2017-11-15 이맥바이오 주식회사 Pvc resin composition containing vegetable oil based flow improvers and manufacturing method of the same
BE1025186B1 (en) 2017-09-27 2018-11-26 Proviron Holding N.V. Plasticizer composition
CN110041195A (en) * 2019-01-22 2019-07-23 中国林业科学研究院林产化学工业研究所 A kind of fatty acid poleysters PVC plasticizer and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1300526A (en) * 1970-05-02 1972-12-20 Henkel & Cie Gmbh Process for the preparation of hydroxy-fatty acid esters
US4612192A (en) * 1983-07-22 1986-09-16 Henkel Kommanditgesellschaft Auf Aktien Oil components for cosmetics and pharmaceuticals
EP2070977A2 (en) * 2007-12-10 2009-06-17 Nexoleum Bioderivados Ltda. Epoxidised vegetable oils as PVC plasticizers
WO2011030076A1 (en) * 2009-09-11 2011-03-17 Centre National De La Recherche Scientifique (C.N.R.S) Novel method for preparing polyols and products obtained
WO2011041388A1 (en) * 2009-09-30 2011-04-07 Dow Global Technologies Inc. Acetylated glyceride of 12-hydroxystearic acid and blends with epoxidized fatty acid esters

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3347926A (en) 1964-04-15 1967-10-17 Atlas Chem Ind Ammonolysis process for producing aliphatic amines
US4014933A (en) 1969-10-23 1977-03-29 Basf Aktiengesellschaft Production of amines from alcohols
US3654370A (en) 1970-08-28 1972-04-04 Jefferson Chem Co Inc Process for preparing polyoxyalkylene polyamines

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1300526A (en) * 1970-05-02 1972-12-20 Henkel & Cie Gmbh Process for the preparation of hydroxy-fatty acid esters
US4612192A (en) * 1983-07-22 1986-09-16 Henkel Kommanditgesellschaft Auf Aktien Oil components for cosmetics and pharmaceuticals
EP2070977A2 (en) * 2007-12-10 2009-06-17 Nexoleum Bioderivados Ltda. Epoxidised vegetable oils as PVC plasticizers
WO2011030076A1 (en) * 2009-09-11 2011-03-17 Centre National De La Recherche Scientifique (C.N.R.S) Novel method for preparing polyols and products obtained
WO2011041388A1 (en) * 2009-09-30 2011-04-07 Dow Global Technologies Inc. Acetylated glyceride of 12-hydroxystearic acid and blends with epoxidized fatty acid esters

Also Published As

Publication number Publication date
WO2013003225A2 (en) 2013-01-03
TW201305100A (en) 2013-02-01

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