WO2012144959A1 - Colloidal silver production process and generator - Google Patents

Colloidal silver production process and generator Download PDF

Info

Publication number
WO2012144959A1
WO2012144959A1 PCT/SK2012/000003 SK2012000003W WO2012144959A1 WO 2012144959 A1 WO2012144959 A1 WO 2012144959A1 SK 2012000003 W SK2012000003 W SK 2012000003W WO 2012144959 A1 WO2012144959 A1 WO 2012144959A1
Authority
WO
WIPO (PCT)
Prior art keywords
signal
electrodes
accordance
colloidal silver
generator
Prior art date
Application number
PCT/SK2012/000003
Other languages
French (fr)
Other versions
WO2012144959A4 (en
Inventor
Ladislav SCHOBER
Original Assignee
Schober Ladislav
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Schober Ladislav filed Critical Schober Ladislav
Priority to DE112012001784.6T priority Critical patent/DE112012001784B4/en
Publication of WO2012144959A1 publication Critical patent/WO2012144959A1/en
Publication of WO2012144959A4 publication Critical patent/WO2012144959A4/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J13/00Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
    • B01J13/0004Preparation of sols
    • B01J13/0043Preparation of sols containing elemental metal

Definitions

  • the technique of the Colloidal Silver production is designed mainly for preparation nutritional supplements, disinfectants, antibacterial agents, antiviral agents, antifungal agents mainly in the form of drinks and it includes the design of the Colloidal Silver Generator.
  • Colloidal Silver is produced by electrolysis of distilled water using two electrodes one of which must be made of silver.
  • the quality of Colloidal Silver depends on the purity of the silver electrode (among other factors), therefore silver electrodes of purity 99.99% are being used.
  • a constant current source is used in the electrolysis and the voltage changes with decreasing resistance of the silver particle filled distilled water. Since the size of the silver particles depends on the amount of current between the electrodes and the the current does not change, the silver particles produced are all of similar size. That is a disadvantage of this method as the most health beneficial particle mix is in a defined range of small to medium size silver particles.
  • Another method of making Colloidal Silver uses A.C. voltage with zero D.C. offset with minimal voltage set at 0 Volts.
  • a known examlpe of a Colloidal Silver device consists of a plastic cover of a distilled water vessel through which two electrodes
  • the technical principle of the invention supports the production of a defined range of silver particles and it is the basis of the Colloidal Silver Generator.
  • the A.C. voltage has a constant frequency and amplitude or it has a constant frequency and changing amplitude.
  • the amplitude changes in accordance with a low frequency signal.
  • the bulk of the Colloidal Silver manufacturing equipment is built into a case to which two demountable electrodes are connected.
  • the case is connected to a power source via an adapter.
  • Inside the case is an electronic assembly, which produces and modulates an electric signal between the main electrode and the secondary electrode.
  • the electronic assembly contains a filter connected via a high frequency generator and an amplifier to the electrodes.
  • the modulator on the electronic assembly is placed between the amplifier and the electrodes and it is also connected to a low frequency generator, which is connected to a filter.
  • Figure I shows the setup for the making of Colloidal Silver
  • FIG. 2 shows the basic Block Diagram of the electronic setup
  • Figure 3 shows the Block Diagram of the Electronic Assembly with the Amplitude
  • FIG. 4 shows the make-up of Amplitude Modulation signals Detailed Description of the Invention
  • the Carrier is the Carrier
  • the carrier is a high frequency signal with a square, sine or triangle waveform and has a constant voltage of 12 Volts.
  • the carrier amplitude takes the shape of the low frequency modulating signal waveform while keeping its high frequency. Both the carrier and the modulating signal have the same peak voltage.
  • the shape of the modulating signal can be a sine or a triangular waveform.
  • Figure 4 is an example of Amplitude Modulation.
  • the carrier is a square wave of frequency 100 Hz and the modulating signal is a triangular wave of frequency 5 Hz.
  • the resultant amplitude modulated signal is a triangular waveform of frequency 5 Hz, which is made up of square wave of frequency 100 Kz..
  • One period of the triangular wave is made up of twenty periods of square wave.
  • the advantage of using a signal with amplitude modulation lies in the fact that even at larger average currents, small particles are still being produced as one period of the signal contains a mixture of high and low voltages, which are proportional to currents by Ohm's Law.
  • the D.C. offset saves time as the signal does not drop down to zero Volts. The ripping of silver particles into the water is very low or non existant between zero and two Volts and if the signal does not go below 2 Volts, silver particles are being produced all the time.

Abstract

The principle of the Colloidal Silver production is a high frequency A.C. signal with a D.C. offset such that the minimal value of voltage lies above 0 Volts and the signal is amplitude modulated. The Colloidal Silver Generator (1) has inside its case (2) an Electronic Assembly (11) to amplitude modulate the signal between the electrodes (21,22).

Description

Colloidal Silver Production Procedure and Generator Field of the Application
The technique of the Colloidal Silver production is designed mainly for preparation nutritional supplements, disinfectants, antibacterial agents, antiviral agents, antifungal agents mainly in the form of drinks and it includes the design of the Colloidal Silver Generator.
Background to the Invention
Colloidal Silver is produced by electrolysis of distilled water using two electrodes one of which must be made of silver. The quality of Colloidal Silver depends on the purity of the silver electrode (among other factors), therefore silver electrodes of purity 99.99% are being used.
There are two traditional ways of making Colloidal Silver.
In the first case, constant voltage source is used during the electrolysis process while the D.C. current is rising with falling resistance of the distilled water due to the increasingly higher concentration of silver particles in the distilled water. Larger currents ripp out larger particles form the silver elctrode, which is a disadvantage of this method because the most beneficial size of the silver particles lies in a defined range of small to medium size. The health beneficial broad spectrum range lies in a mixture of small to medium size particles.
In the second case, a constant current source is used in the electrolysis and the voltage changes with decreasing resistance of the silver particle filled distilled water. Since the size of the silver particles depends on the amount of current between the electrodes and the the current does not change, the silver particles produced are all of similar size. That is a disadvantage of this method as the most health beneficial particle mix is in a defined range of small to medium size silver particles.
Another method of making Colloidal Silver uses A.C. voltage with zero D.C. offset with minimal voltage set at 0 Volts.
A known examlpe of a Colloidal Silver device, utility model DE 202004000770 UI, consists of a plastic cover of a distilled water vessel through which two electrodes
secured by fasteners protrude into the vessel and are connected by bipolar plug to a power source. The disadvantage of this device is that it uses only one of the already described methods for Colloidal Silver production, either the constant voltage method or the constant current method. Another known Colloidal Silver device, patent number AT 414533B, uses retractable electrode holders which can be retracted into the device case during inactivity periods. There is no description of any electrical signal associated with this device. .
Brief Summary
The technical principle of the invention supports the production of a defined range of silver particles and it is the basis of the Colloidal Silver Generator.
The shortcomings of the previous methods of Colloidal Silver production have been largely removed from the way the Colloidal Silver is made - electrolysis of distilled water by two electrodes at least one of which is made from silver of high purity with a modulated high frequency A.C. voltage and a D.C. offset such that the minimum value of the signal lies above 0 Volts.
The A.C. voltage has a constant frequency and amplitude or it has a constant frequency and changing amplitude. The amplitude changes in accordance with a low frequency signal.
The bulk of the Colloidal Silver manufacturing equipment is built into a case to which two demountable electrodes are connected. The case is connected to a power source via an adapter. Inside the case is an electronic assembly, which produces and modulates an electric signal between the main electrode and the secondary electrode. The electronic assembly contains a filter connected via a high frequency generator and an amplifier to the electrodes. The modulator on the electronic assembly is placed between the amplifier and the electrodes and it is also connected to a low frequency generator, which is connected to a filter.
There is an LED power on indicator on the case.
Brief Description of the Drawings
The Figures demonstrate the design.
Figure I shows the setup for the making of Colloidal Silver
Figure 2 shows the basic Block Diagram of the electronic setup
Figure 3 shows the Block Diagram of the Electronic Assembly with the Amplitude
Modulation circuit
Figure 4 shows the make-up of Amplitude Modulation signals Detailed Description of the Invention
Example 1
The Carrier
The carrier is a high frequency signal with a square, sine or triangle waveform and has a constant voltage of 12 Volts.
Example 2
The Amplitude Modulated Signal
The carrier amplitude takes the shape of the low frequency modulating signal waveform while keeping its high frequency. Both the carrier and the modulating signal have the same peak voltage. The shape of the modulating signal can be a sine or a triangular waveform.
Figure 4 is an example of Amplitude Modulation. The carrier is a square wave of frequency 100 Hz and the modulating signal is a triangular wave of frequency 5 Hz. The resultant amplitude modulated signal is a triangular waveform of frequency 5 Hz, which is made up of square wave of frequency 100 Kz.. One period of the triangular wave is made up of twenty periods of square wave.
Example 3
During the manufacturing of Colloidal Silver particles of silver start to get ripped out of the electrode into the distilled water at around 2 Volts and therefore it is inefficient to have the signal between the electrodes start at 0 Volts. It is more efficient to have the signal start at 2 Volts by providing a further D.C offset. This D.C. offset refers also to Example 1 and 2.
The advantage of using a signal with amplitude modulation lies in the fact that even at larger average currents, small particles are still being produced as one period of the signal contains a mixture of high and low voltages, which are proportional to currents by Ohm's Law. The D.C. offset saves time as the signal does not drop down to zero Volts. The ripping of silver particles into the water is very low or non existant between zero and two Volts and if the signal does not go below 2 Volts, silver particles are being produced all the time.

Claims

C L A I M S
1. Colloidal Silver Production Procedure using electrolysis of distilled water by two electrodes at least one of which is made of high purity silver characterized by a high frequency A.C. signal with a D.C. offset between the electrodes such that the minimum voltage of the signal is above 0 Volts and the signal is modulated.
2. Production procedure in accordance with Claim I, characterized by an A.C. signal with constant frequency and amplitude.
3. Production procedure in accordance with Claim I, characterized by an A.C. signal with constant frequency and changing voltage amplitude.
4. Production procedure in accordance with Claim 1 and 3, charakterized by a signal amplitude changing with a low frequency signal.
5. Colloidal Silver production equipment in accordance with Claim 1 to 4 built into a case (2) to which two demountable electrodes are connected a which is connected to a power adapter, characterized by the presence of an electronic assembly (II) inside the case, which modulates the signal between the main (21) and the secondary electrode (22) and which is minimally composed of a filter (I I I) connected via high f equency generator (112) and an amplifier (113) to the electrodes (21,22).
6. Equipment in accordance with Claim 5, characterized by a modulator (115) placed between the amplifier (113) and the electrodes (21,22) on the electronic assembly (I I) to which is connected a low frequency generator (114) and the generator is connected to a filter (I I I).
7. Equipment in accordance with Claim 5 or 6, characterized by and LED power on indication aperture (13) on the case (2).
PCT/SK2012/000003 2011-04-20 2012-04-11 Colloidal silver production process and generator WO2012144959A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE112012001784.6T DE112012001784B4 (en) 2011-04-20 2012-04-11 Process and apparatus for the production of colloidal silver

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
SKPP50019-2011 2011-04-20
SK50019-2011A SK500192011A3 (en) 2011-04-20 2011-04-20 Method for production of colloidal silver and a device for performing the method

Publications (2)

Publication Number Publication Date
WO2012144959A1 true WO2012144959A1 (en) 2012-10-26
WO2012144959A4 WO2012144959A4 (en) 2013-02-21

Family

ID=46052854

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/SK2012/000003 WO2012144959A1 (en) 2011-04-20 2012-04-11 Colloidal silver production process and generator

Country Status (4)

Country Link
CZ (1) CZ2013806A3 (en)
DE (1) DE112012001784B4 (en)
SK (1) SK500192011A3 (en)
WO (1) WO2012144959A1 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20220056296A1 (en) 2018-12-20 2022-02-24 Eckart Gmbh Conductive ink jet printing ink composition
WO2021175698A1 (en) 2020-03-06 2021-09-10 Fabio And Markus Colloid Engineering Gmbh Control apparatus and method for controlling electrodes of at least one electrolysis device for the electrochemical production of nanoparticles
CN113333735A (en) * 2021-05-07 2021-09-03 东南大学 Method for purifying silver nanoparticles by circularly inducing morphology transformation through alternating electric field
WO2022248925A1 (en) * 2021-05-24 2022-12-01 Durgesh Kumar Nanda An apparatus for colloidal silver generation and a method to prepare the same

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6214299B1 (en) * 1999-06-01 2001-04-10 Robert J. Holladay Apparatus and method for producing antimicrobial silver solution
WO2005019096A1 (en) * 2003-08-23 2005-03-03 Chul-Sang Jeong Nanocomposite solution with complex function and method for preparation thereof
KR20070078426A (en) * 2004-10-12 2007-08-01 전창호 Inorganic composition with antibacterial and photocatalytic function
NL1037038C2 (en) * 2009-06-13 2010-12-23 Cooperatieve Vereniging Easy Measure U A METHOD AND DEVICE FOR TREATING TREES.

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE202004000770U1 (en) * 2004-01-20 2004-04-08 Hagans, Friedrich Device for the production of a colloidal precious metal solution, especially containing silver, comprises electrodes for holding plug-in terminals, a two pole connector, a battery charging unit, charging stations, and a battery
DE202009001866U1 (en) * 2009-02-14 2010-07-08 Miriana Ltd Apparatus for the electrolytic production of colloidal silver or gold water

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6214299B1 (en) * 1999-06-01 2001-04-10 Robert J. Holladay Apparatus and method for producing antimicrobial silver solution
WO2005019096A1 (en) * 2003-08-23 2005-03-03 Chul-Sang Jeong Nanocomposite solution with complex function and method for preparation thereof
KR20070078426A (en) * 2004-10-12 2007-08-01 전창호 Inorganic composition with antibacterial and photocatalytic function
NL1037038C2 (en) * 2009-06-13 2010-12-23 Cooperatieve Vereniging Easy Measure U A METHOD AND DEVICE FOR TREATING TREES.

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Week 200830, Derwent World Patents Index; AN 2008-E42274, XP002681724 *
DATABASE WPI Week 201149, Derwent World Patents Index; AN 2011-G88752, XP002681725 *
HU M Z ET AL: "A novel thermal electrochemical synthesis method for production of stable colloids of ''naked'' metal (Ag) nanocrystals", MATERIALS SCIENCE AND ENGINEERING C, ELSEVIER SCIENCE S.A, CH, vol. 29, no. 3, 30 April 2009 (2009-04-30), pages 726 - 736, XP026019032, ISSN: 0928-4931, [retrieved on 20090125], DOI: 10.1016/J.MSEC.2009.01.018 *
SI M Z ET AL: "Surface-enhanced Raman scattering (SERS) spectra of Methyl Orange in Ag colloids prepared by electrolysis method", APPLIED SURFACE SCIENCE, ELSEVIER, AMSTERDAM, NL, vol. 255, no. 11, 15 March 2009 (2009-03-15), pages 6007 - 6010, XP025999956, ISSN: 0169-4332, [retrieved on 20090129], DOI: 10.1016/J.APSUSC.2009.01.055 *

Also Published As

Publication number Publication date
CZ2013806A3 (en) 2014-02-12
DE112012001784T5 (en) 2014-01-16
DE112012001784B4 (en) 2018-01-25
SK500192011A3 (en) 2012-11-05
WO2012144959A4 (en) 2013-02-21

Similar Documents

Publication Publication Date Title
WO2012144959A1 (en) Colloidal silver production process and generator
KR20170129684A (en) Energy extraction system and methods
CN206851921U (en) A kind of frequency conversion electric field food preservation unit
CN100561847C (en) High-frequency pure sine wave inverter
CN109881229A (en) A kind of flexible carbon nano tube/metal composite film preparation method in the application of electromagnetic shielding field
CN202041615U (en) Electric testing device
CN201937944U (en) Arc plasma load arc-striking power supply device
CN202818133U (en) Circuit of dual-supply apparatus
CN109865197A (en) A kind of wearable intelligent low-frequency electronic pulse therapeutic equipment
CN201878032U (en) Vehicle inverter capable of carrying out wireless output of MP3 music
CN207891228U (en) Sludge cell wall breakage system based on high voltage pulse shaped wire
CN205544972U (en) DC high -voltage generator
CN210494894U (en) Endocrine local electrotherapy stimulation device
CN204117456U (en) Human body sensing conduction acousto-optic device
CN201868579U (en) Grounding wire clip used for testing
CN205532862U (en) Diesel generator with GPS location
CN207384602U (en) A kind of double-sided self-adhesive formula point electrode piece
CN209513986U (en) A kind of operation circuit circuit test tooling
CN205827601U (en) A kind of fire monitoring detector with mouse driving function
SK6168Y1 (en) Device for production of colloidal silver
CN202837373U (en) Detection device for microcurrent signals outputted by frequency converter
CN201343572Y (en) High-frequency electrolytic circuit for electrolyzing water
CN207220071U (en) A kind of pesticide residue measurement degraded instrument
CN201191811Y (en) High-frequency pure sine wave inverter
CN207381095U (en) A kind of touch type electronic voice map

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 12720303

Country of ref document: EP

Kind code of ref document: A1

WWE Wipo information: entry into national phase

Ref document number: PV2013-806

Country of ref document: CZ

WWE Wipo information: entry into national phase

Ref document number: 112012001784

Country of ref document: DE

Ref document number: 1120120017846

Country of ref document: DE

122 Ep: pct application non-entry in european phase

Ref document number: 12720303

Country of ref document: EP

Kind code of ref document: A1