WO2012138049A4 - Non-aqueous fluid marker containing n-benzyl-n-ethylaniline and method for preparing the same - Google Patents
Non-aqueous fluid marker containing n-benzyl-n-ethylaniline and method for preparing the same Download PDFInfo
- Publication number
- WO2012138049A4 WO2012138049A4 PCT/KR2012/000990 KR2012000990W WO2012138049A4 WO 2012138049 A4 WO2012138049 A4 WO 2012138049A4 KR 2012000990 W KR2012000990 W KR 2012000990W WO 2012138049 A4 WO2012138049 A4 WO 2012138049A4
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- group
- aqueous fluid
- marker
- acid
- benzyl
- Prior art date
Links
- 239000003550 marker Substances 0.000 title claims abstract description 48
- 239000012530 fluid Substances 0.000 title claims abstract description 42
- 238000000034 method Methods 0.000 title claims abstract description 21
- XNDVYXSTYJNTBL-UHFFFAOYSA-N n-benzyl-n-ethylaniline Chemical compound C=1C=CC=CC=1N(C[CH2])CC1=CC=CC=C1 XNDVYXSTYJNTBL-UHFFFAOYSA-N 0.000 title 1
- HSZCJVZRHXPCIA-UHFFFAOYSA-N n-benzyl-n-ethylaniline Chemical compound C=1C=CC=CC=1N(CC)CC1=CC=CC=C1 HSZCJVZRHXPCIA-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000002253 acid Substances 0.000 claims abstract description 20
- -1 n-dodecyl group Chemical group 0.000 claims description 32
- 150000001448 anilines Chemical class 0.000 claims description 12
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical group CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 claims description 8
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 claims description 8
- 125000004642 (C1-C12) alkoxy group Chemical group 0.000 claims description 7
- 125000006539 C12 alkyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 7
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 7
- 125000005843 halogen group Chemical group 0.000 claims description 7
- 239000008096 xylene Substances 0.000 claims description 7
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 6
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 6
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 6
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 3
- 239000000314 lubricant Substances 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 239000003225 biodiesel Substances 0.000 claims description 2
- 239000003350 kerosene Substances 0.000 claims description 2
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 2
- 239000000987 azo dye Substances 0.000 abstract description 7
- 238000006243 chemical reaction Methods 0.000 abstract description 6
- 238000003860 storage Methods 0.000 abstract description 4
- 238000009826 distribution Methods 0.000 abstract description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 35
- 239000000047 product Substances 0.000 description 35
- 239000000243 solution Substances 0.000 description 28
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 20
- 239000000986 disperse dye Substances 0.000 description 20
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 18
- 238000010521 absorption reaction Methods 0.000 description 14
- 229960000583 acetic acid Drugs 0.000 description 12
- 235000019260 propionic acid Nutrition 0.000 description 9
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 8
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- 125000000217 alkyl group Chemical group 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 150000008049 diazo compounds Chemical class 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000000975 dye Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 239000011259 mixed solution Substances 0.000 description 4
- 239000003209 petroleum derivative Substances 0.000 description 4
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 3
- 125000003545 alkoxy group Chemical group 0.000 description 3
- 238000006193 diazotization reaction Methods 0.000 description 3
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 3
- 150000007522 mineralic acids Chemical class 0.000 description 3
- 150000007524 organic acids Chemical class 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- 0 *c1ccc(*CNc2ccc(*)cc2)cc1 Chemical compound *c1ccc(*CNc2ccc(*)cc2)cc1 0.000 description 2
- LDMOEFOXLIZJOW-UHFFFAOYSA-N 1-dodecanesulfonic acid Chemical compound CCCCCCCCCCCCS(O)(=O)=O LDMOEFOXLIZJOW-UHFFFAOYSA-N 0.000 description 2
- 238000005160 1H NMR spectroscopy Methods 0.000 description 2
- FKPXGNGUVSHWQQ-UHFFFAOYSA-N 5-methyl-1,2-oxazol-3-amine Chemical compound CC1=CC(N)=NO1 FKPXGNGUVSHWQQ-UHFFFAOYSA-N 0.000 description 2
- KZHGPDSVHSDCMX-UHFFFAOYSA-N 6-methoxy-1,3-benzothiazol-2-amine Chemical compound COC1=CC=C2N=C(N)SC2=C1 KZHGPDSVHSDCMX-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- IOVCWXUNBOPUCH-UHFFFAOYSA-N Nitrous acid Chemical compound ON=O IOVCWXUNBOPUCH-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-MICDWDOJSA-N Trichloro(2H)methane Chemical compound [2H]C(Cl)(Cl)Cl HEDRZPFGACZZDS-MICDWDOJSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000005457 ice water Substances 0.000 description 2
- 239000000976 ink Substances 0.000 description 2
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000012265 solid product Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- OGIQUQKNJJTLSZ-UHFFFAOYSA-N 4-butylaniline Chemical compound CCCCC1=CC=C(N)C=C1 OGIQUQKNJJTLSZ-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- CSCPPACGZOOCGX-WFGJKAKNSA-N acetone d6 Chemical compound [2H]C([2H])([2H])C(=O)C([2H])([2H])[2H] CSCPPACGZOOCGX-WFGJKAKNSA-N 0.000 description 1
- 125000005036 alkoxyphenyl group Chemical group 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 239000012362 glacial acetic acid Substances 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000001819 mass spectrum Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000006606 n-butoxy group Chemical group 0.000 description 1
- 125000003136 n-heptyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 125000003935 n-pentoxy group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])O* 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000000425 proton nuclear magnetic resonance spectrum Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 238000002371 ultraviolet--visible spectrum Methods 0.000 description 1
- 238000001392 ultraviolet--visible--near infrared spectroscopy Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B29/00—Monoazo dyes prepared by diazotising and coupling
- C09B29/0025—Monoazo dyes prepared by diazotising and coupling from diazotized amino heterocyclic compounds
- C09B29/0074—Monoazo dyes prepared by diazotising and coupling from diazotized amino heterocyclic compounds the heterocyclic ring containing nitrogen and sulfur as heteroatoms
- C09B29/0077—Monoazo dyes prepared by diazotising and coupling from diazotized amino heterocyclic compounds the heterocyclic ring containing nitrogen and sulfur as heteroatoms containing a five-membered heterocyclic ring with one nitrogen and one sulfur as heteroatoms
- C09B29/0085—Thiazoles or condensed thiazoles
- C09B29/0088—Benzothiazoles
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N31/00—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods
- G01N31/22—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods using chemical indicators
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C245/00—Compounds containing chains of at least two nitrogen atoms with at least one nitrogen-to-nitrogen multiple bond
- C07C245/02—Azo compounds, i.e. compounds having the free valencies of —N=N— groups attached to different atoms, e.g. diazohydroxides
- C07C245/06—Azo compounds, i.e. compounds having the free valencies of —N=N— groups attached to different atoms, e.g. diazohydroxides with nitrogen atoms of azo groups bound to carbon atoms of six-membered aromatic rings
- C07C245/08—Azo compounds, i.e. compounds having the free valencies of —N=N— groups attached to different atoms, e.g. diazohydroxides with nitrogen atoms of azo groups bound to carbon atoms of six-membered aromatic rings with the two nitrogen atoms of azo groups bound to carbon atoms of six-membered aromatic rings, e.g. azobenzene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B29/00—Monoazo dyes prepared by diazotising and coupling
- C09B29/0003—Monoazo dyes prepared by diazotising and coupling from diazotized anilines
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B29/00—Monoazo dyes prepared by diazotising and coupling
- C09B29/06—Monoazo dyes prepared by diazotising and coupling from coupling components containing amino as the only directing group
- C09B29/08—Amino benzenes
- C09B29/0805—Amino benzenes free of acid groups
- C09B29/0807—Amino benzenes free of acid groups characterised by the amino group
- C09B29/0809—Amino benzenes free of acid groups characterised by the amino group substituted amino group
- C09B29/081—Amino benzenes free of acid groups characterised by the amino group substituted amino group unsubstituted alkylamino, alkenylamino, alkynylamino, cycloalkylamino, aralkylamino or arylamino
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
- C09B67/0083—Solutions of dyes
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/75—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated
- G01N21/77—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated by observing the effect on a chemical indicator
- G01N21/78—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated by observing the effect on a chemical indicator producing a change of colour
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/26—Oils; Viscous liquids; Paints; Inks
Definitions
- the present invention relates to an azo dye represented by the following Formula 1, which can be used as a marker for a non-aqueous fluid product, and a method for preparing the same.
- Recently, extensive research aimed at developing a novel azo dye suitable for a variety of applications by adding functionality to the dyes has continued to progress.
- a heteroazo disperse dye using N -benzyl- N -ethylaniline as a coupler exhibits solvatochromism.
- a maximum absorption wavelength ( ⁇ max ) of a compound represented by the following Formula 2 was 503 nm in a chloroform, but it shifted to a longer wavelength of 614 nm in a glacial acetic acid by 111 nm.
- the methods for identifying the non-aqueous fluid products are as follows ; a method for exhibiting a color by adding a marker to a non-aqueous fluid product and then adding an acid or a base as a developing agent thereto, a quantitative measurement using a dye absorbing in a near infrared region, etc., are used.
- these methods have some problems in that the color may not be detected as the effect of the marker is lost over time, the developing agent used to develop a detectable color of markers may be difficult to handle as it is easily decomposed, and the good quantitative measurement may not perform as the components of the marker are slowly decomposed in water or organic solvent.
- U.S. Patent No. 6,514,917 discloses that a variety of azo dyes, which are easily handled and have high storage stability, can be used as markers to label petroleum products by reaction with an organic or inorganic acid.
- US Patent No. 6,514,917 discloses a method for quantifying a marker using an organic phosphoric or sulfonic acid as a developing agent miscible with petroleum products without extraction to an aqueous phase from the petroleum products.
- the materials to be useful as markers for non-aqueous fluid products must have high solubility in a target product, have excellent storage stability, be detected even in a small amount, be easily detected, and be used in various non-aqueous fluid products.
- it is very difficult to use the existing azo dyes as a marker in terms of solubility and coloration in some non-aqueous fluid products such as petroleum products, solvents, inks, lubricants, etc.
- an object of the present invention is to provide a novel yellow azo disperse dye for identifying a non-aqueous fluid product, and a method for preparing the same.
- the present invention provides a non-aqueous fluid marker containing N -benzyl- N -ethylaniline represented by the following Formula 1:
- R is a C 1 to C 12 alkyl group, a C 1 to C 12 alkoxy group, a C 1 to C 12 hydroxyalkyl group, a C 1 to C 12 hydroxyalkoxyalkyl group, a C 1 to C 12 alkylphenyl group, a C 1 to C 12 alkoxyphenyl group, a nitro group, a cyano group or a halogen atom.
- the present invention provides a method for preparing a non-aqueous fluid marker, comprising: diazotizing an aniline derivative represented by the following Formula 3; and reacting N -benzyl- N -ethylaniline represented by the following Formula 4 with the diazotized aniline derivative:
- R is a C 1 to C 12 alkyl group, a C 1 to C 12 alkoxy group, a C 1 to C 12 hydroxyalkyl group, a C 1 to C 12 hydroxyalkoxyalkyl group, a C 1 to C 12 alkylphenyl group, a C 1 to C 12 alkoxyphenyl group, a nitro group, a cyano group or a halogen atom.
- the present invention provides a method for identifying a non-aqueous fluid product, comprising: dissolving a non-aqueous fluid marker, which contains N -benzyl- N -ethylaniline represented by the above Formula 1, in a target product; and developing a color of the target product with an acid developer.
- FIG. 1 is a graph illustrating a change in UV-VIS absorption spectra before and after addition of an acid developer to a marker solution containing an azo disperse dye prepared in Example 1, in which a change in maximum absorption wavelength is shown.
- the present invention provides a non-aqueous fluid marker containing N -benzyl- N -ethylaniline represented by the following Formula 1:
- R is a C 1 to C 12 alkyl group, a C 1 to C 12 alkoxy group, a C 1 to C 12 hydroxyalkyl group, a C 1 to C 12 hydroxyalkoxyalkyl group, a C 1 to C 12 alkylphenyl group, a C 1 to C 12 alkoxyphenyl group, a nitro group, a cyano group or a halogen atom.
- alkyl group refers to a linear or branched aliphatic saturated hydrocarbon group having 1 to 12 carbon atoms. More particularly, the alkyl group may include a methyl group, an ethyl group, a n -propyl group, an i -propyl group, a n -butyl group, an i -butyl group, a t -butyl group, an n -pentyl group, an i -pentyl group, a n -hexyl group, an i -hexyl group, a n -heptyl group, an i -heptyl group, a n -octyl group, an i -octyl group, a n -nonyl group, an i -nonyl group, a n -dodecyl group, an i -dodecyl group,
- alkoxy group refers to a linear or branched aliphatic alkoxy group having 1 to 12 carbon atoms. More particularly, the alkyl group may include a methoxy group, an ethoxy group, a n -propyloxy group, an i -propyloxy group, an n -butoxy group, an i -butoxy group, a t -butoxy group, an n -pentoxy group, an i -pentoxy group, etc.
- hydroxyalkyl group refers to a OH-alkyl group in which a hydroxyl group is bound to the aforementioned alkyl group. More particularly, the hydroxyalkyl group may include a hydroxymethyl group, a hydroxyethyl group, a hydroxy- n -propyl group, a hydroxy- n -butyl group, a hydroxy- i -butyl group, a hydroxy- n -pentyl group, a hydroxy- i -pentyl group, a hydroxy- n -hexyl group, a hydroxy- i -hexyl group, etc.
- hydroxyalkoxyalkyl group refers to a hydroxyalkyl-O-alkyl group in which an alkoxy group is bound to the hydroxyalkyl group. More particularly, the hydroxyalkoxyalkyl group may include a hydroxyethoxymethyl group, a hydroxyethoxyethyl group, a hydroxymethoxypropyl group, a hydroxyethoxypropyl group, a hydroxyethoxybutyl group, a hydroxyethoxypentyl group, a hydroxyethoxyhexyl group, etc.
- alkylphenyl group may include a methylphenyl group, an ethylphenyl group, a n -propylphenyl group, an n -butylphenyl group, etc.
- alkoxyphenyl group may include a methoxyphenyl group, an ethoxyphenyl group, a n -propyloxyphenyl group, a n -butoxyphenyl group, etc.
- halogen atom is a fluorine atom, a chlorine atom, a bromine atom or an iodine atom.
- a particularly preferred the oil marker is a compound in which R in Formula 1 is a C 1 to C 12 alkyl group or a C 1 to C 12 alkoxy group.
- the present invention provides a method for preparing a non-aqueous fluid marker containing N -benzyl- N -ethylaniline represented by the Formula 1.
- the non-aqueous fluid marker may be prepared by diazotizing an aniline derivative represented by the following Formula 3 and reacting the diazotized aniline derivative with N -benzyl- N -ethylaniline represented by the following Formula 4.
- R has the same meaning as defined above.
- the diazotization is performed by dispersing an aniline derivative in water or acetic acid or in a mixed solution of acetic acid and propionic acid at 0-10 °C and adding concentrated hydrochloric acid and NaNO 2 or HO 3 SONO to react with each other.
- the mixed solution of the acetic acid and propionic acid may be mixed in a volume ratio of 5:1.
- the diazotized aniline derivative may be reacted with the N -benzyl- N -ethylaniline represented by the above Formula 4 to give a yellow azo disperse dye represented by the above Formula 1.
- the N -benzyl- N -ethylaniline may be dissolved in acetic acid or in a mixed solution of acetic acid and propionic acid in a separate container and maintained at 0-10 °C, and the prepared solution may then be added to the diazotized solution to carry out a coupling reaction at 0-10 °C.
- the acetic acid and propionic acid may be mixed in a volume ratio of 5:1.
- the present invention provides a method for identifying a target product using a non-aqueous fluid marker containing N -benzyl- N -ethylaniline represented by the above Formula 1.
- the non-aqueous fluid marker containing the N -benzyl- N -ethylaniline represented by the above Formula 1 according to the present invention shows a purple color by reacting with acid developer when the non-aqueous fluid marker is dissolved in a target product. That is, when the marker according to the present invention reacts with the acid developer in the non-aqueous fluid product, a maximum absorption wavelength of the non-aqueous fluid product shifts from 410 nm to a longer wavelength of 560 nm. Therefore, the color of the non-aqueous fluid product is changed from its own color (i.e., yellow) to purple. Accordingly, it is possible to distinguish the non-aqueous fluid product including the marker according to the present invention from marker-free products.
- the non-aqueous fluid manufacturer dissolves the marker according to the present invention in the non-aqueous fluid product, it is possible to easily distinguish the product from other companies’ products using the acid developer. Therefore, it is possible to control the quality of the product in the distribution process.
- the type of non-aqueous fluids to be distinguished is not particularly limited, and the non-aqueous fluid may include gasoline, diesel, kerosene, biodiesel, bioethanol, xylene, ink, non-aqueous lubricant, solvent, and mixtures thereof.
- the acid developer may include an organic acid such as dodecyl sulfonic acid, and an inorganic acid such as sulfuric acid or phosphoric acid.
- the dodecyl sulfonic acid may be used as the acid developer.
- N -benzyl- N -ethylaniline as a coupler was dissolved in 20 ml of an acid mixture (where the volume ratio of acetic acid to propionic acid was 5:1) and maintained at 5-10 °C. Then, the prepared solution was slowly added to the diazotized solution and stirred at 5-10 °C for 3.5 hours. 25 g of sodium acetate (NaOAc) was added to the reaction solution and stirred at room temperature for 30 minutes. The reaction mixture was poured into 250 g of ice-water, stirred for 1 hour to produce a solid product, and filtered.
- NaOAc sodium acetate
- the isolated product was dispersed in 100 ml of isopropyl alcohol, stirred at room temperature for 30 minutes, filtered, and then dried, thereby obtaining a marker according to the present invention as a yellow solid azo disperse dye represented by the following Formula 5.
- non-aqueous fluid markers containing N -benzyl- N -ethylaniline according to the present invention were prepared in the same manner as in Example 1, except that aniline derivatives as listed in the following Table 1 were used.
- Example 1 4-C 4 H 9 5.36 76.3
- Example 2 4-tert-C 4 H 9 5.36 78.2
- Example 3 4-C 12 H 25 9.40 41.4
- Example 4 4-CH 3 3.85 69.9
- Example 5 4-OCH 3 4.43 17.3
- N -benzyl- N -ethylaniline as a coupler was dissolved in 10 ml of an acid mixture (where the volume ratio of acetic acid to propionic acid was 5:1) and maintained at 5-10 °C. Then, the prepared solution was slowly added to the diazotized solution and stirred at 0-5 °C for 2 hours. 2.5 g of NaOAc was added to the reaction mixture and stirred at room temperature for 30 minutes. The reaction mixture was poured into 50 g of ice-water, stirred for 1 hour to produce a solid product, and filtered.
- Example 1 371 A; 0.92(3H, t), 1.25(3H, t), 1.36(2H, sextet), 1.62(2H, qt), 2.66(2H, t), 3.64(2H, q), 4.70(2H, s), 6.84(2H, d), 7.23-7.35(7H, m), 7.73(2H, d), 7.78(2H, d)
- Example 2 371 C; 1.26(3H, t), 1.33(9H, s), 3.56(2H, q), 4.61(2H, s), 6.75(2H, d), 7.20-7.34(5H, m), 7.45(2H, d), 7.74(2H, d), 7.81(2H, d)
- Example 3 483 C 0.86(3H, t), 1.24-1.28(20H, m), 1.57-1.64(4H,
- Example 1 402 A 1.30(3H, t), 3.72(2H, q), 3.89(3H, s), 4.81 (2H, s), 6.94(2H, d), 7.09(1H, dd), 7.26-7.37(5H, m), 7.50(1H, d), 7.83-7.90(3H, m)
- Example 2 320 A 1.27(3H, t), 2.44(3H, s), 3.68(2H, q), 4.76 (2H, s), 6.36(1H, s), 6.87(2H, d), 7.24-7.36(5H, m), 7.80(2H, d) * Solvent for 1 H NMR ; CDCl 3 (C), Acetone- d 6 (A)
- Test Example 1 Test for acid reactivity of yellow azo disperse dyes
- UV-VIS molar absorption coefficients ( ⁇ ) and maximum absorption wavelengths ( ⁇ max ) of the samples prepared in (1) were measured. Then, 10 ⁇ l of the acid developer solution prepared in (2) was added to each sample and stirred for 1 minute. Then, the UV-VIS molar absorption coefficient ( ⁇ ) and maximum absorption wavelength ( ⁇ max ) of each sample were measured to observe a change in color.
- the UV-VIS molar absorption coefficient and maximum absorption wavelength were measured using a UV-VIS-NIR spectrophotometer (UV-3101 PC, SHIMADZU). The measurement results are listed in the following Table 3 and shown in FIG. 1.
- the alkyl group-substituted yellow azo disperse dyes prepared in Examples 1 -4 showed a distinct purple color and a maximum absorption wavelength was shifted to a longer wavelength by 150 nm or more when the dodecylbenzene sulfonic acid solution was added to the marker solution.
- the methoxy group-substituted yellow azo disperse dye prepared in Example 5 had a higher absorbance at 476 nm than at 565 nm as shown in the above Table 3, when the dodecylbenzene sulfonic acid solution was added to the marker solution. The color change of the marker solution could be observed, however the appearance of color was not distinctive.
- alkyl group-substituted yellow azo disperse dyes prepared in Examples 1-4 which exhibits their distinct colors by addition of dodecylbenzene sulfonic acid solution as the acid developer, can be more effectively used as an acid-reactive marker.
- the marker containing N -benzyl- N -ethylaniline according to the present invention exhibits high solubility in non-aqueous fluid products, has excellent storage stability, can be detected even in a small amount, and can develop a distinct color by reaction with an organic acid such as dodecylbenzene sulfonic acid and an inorganic acid such as sulfuric acid or phosphoric acid in the non-aqueous fluid product. Therefore, when the marker is added to a product, the product can be easily distinguished from other companies’ products containing no marker or illegally distributed products such as adulterated gasoline, which makes it possible to easily control the quality of the product in the distribution process.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Immunology (AREA)
- General Physics & Mathematics (AREA)
- Pathology (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Plasma & Fusion (AREA)
- Food Science & Technology (AREA)
- Medicinal Chemistry (AREA)
- Biophysics (AREA)
- Molecular Biology (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
Abstract
The present invention provides an azo dye which can be used as a marker for a non-aqueous fluid product containing N-benzyl-N-ethylaniline, and a method for preparing the same. The marker containing N-benzyl-N-ethylaniline according to the present invention exhibits high solubility in non-aqueous fluid products, has excellent storage stability, can be detected even in a small amount, and can exhibit a distinct color by reaction with an acid developer in the non-aqueous fluid product. Therefore, when the marker is added to a non-aqueous fluid product, the product can be easily distinguished from other companies' products containing no marker, which makes it possible to easily control the quality of the non-aqueous fluid product in the distribution process.
Description
The present invention relates to an azo dye represented by the following Formula 1, which can be used as a marker for a non-aqueous fluid product, and a method for preparing the same.
Formula 1
A dye containing an azo group (-N=N-) as a chromophore is called an azo dye, and the azo dyes account for 50 % or more of the currently used dyes. Recently, extensive research aimed at developing a novel azo dye suitable for a variety of applications by adding functionality to the dyes has continued to progress.
According to a recent report (M. R. Yazdanbakhsh. et. al., J. Mol. Liquid. 151: 107-112 (2010)), a heteroazo disperse dye using N-benzyl-N-ethylaniline as a coupler exhibits solvatochromism. For example, a maximum absorption wavelength (λmax) of a compound represented by the following Formula 2 was 503 nm in a chloroform, but it shifted to a longer wavelength of 614 nm in a glacial acetic acid by 111 nm.
At present, the methods for identifying the non-aqueous fluid products are as follows ; a method for exhibiting a color by adding a marker to a non-aqueous fluid product and then adding an acid or a base as a developing agent thereto, a quantitative measurement using a dye absorbing in a near infrared region, etc., are used. However, these methods have some problems in that the color may not be detected as the effect of the marker is lost over time, the developing agent used to develop a detectable color of markers may be difficult to handle as it is easily decomposed, and the good quantitative measurement may not perform as the components of the marker are slowly decomposed in water or organic solvent.
U.S. Patent No. 6,514,917, U.S. Patent No. 5,737,871, U.S. Patent No. 5,490,872, WO 1995-017483, and WO 1999-067346 disclose that a variety of azo dyes, which are easily handled and have high storage stability, can be used as markers to label petroleum products by reaction with an organic or inorganic acid. In particular, US Patent No. 6,514,917 discloses a method for quantifying a marker using an organic phosphoric or sulfonic acid as a developing agent miscible with petroleum products without extraction to an aqueous phase from the petroleum products.
The materials to be useful as markers for non-aqueous fluid products must have high solubility in a target product, have excellent storage stability, be detected even in a small amount, be easily detected, and be used in various non-aqueous fluid products. However, it is very difficult to use the existing azo dyes as a marker in terms of solubility and coloration in some non-aqueous fluid products such as petroleum products, solvents, inks, lubricants, etc.
As a result of continuous studies to develop a compound which can exhibit a distinct color in a non-aqueous fluid product and facilitate quantitative measurement without extraction to an aqueous phase, the present inventors completed this invention by synthesizing several types of yellow azo disperse dyes containing N-benzyl-N-ethylaniline and these dyes could be effectively used as markers for non-aqueous fluid products.
Accordingly, an object of the present invention is to provide a novel yellow azo disperse dye for identifying a non-aqueous fluid product, and a method for preparing the same.
In one aspect, the present invention provides a non-aqueous fluid marker containing N-benzyl-N-ethylaniline represented by the following Formula 1:
Formula 1
wherein R is a C1 to C12 alkyl group, a C1 to C12 alkoxy group, a C1 to C12 hydroxyalkyl group, a C1 to C12 hydroxyalkoxyalkyl group, a C1 to C12 alkylphenyl group, a C1 to C12 alkoxyphenyl group, a nitro group, a cyano group or a halogen atom.
In another aspect, the present invention provides a method for preparing a non-aqueous fluid marker, comprising: diazotizing an aniline derivative represented by the following Formula 3; and reacting N-benzyl-N-ethylaniline represented by the following Formula 4 with the diazotized aniline derivative:
wherein R is a C1 to C12 alkyl group, a C1 to C12 alkoxy group, a C1 to C12 hydroxyalkyl group, a C1 to C12 hydroxyalkoxyalkyl group, a C1 to C12 alkylphenyl group, a C1 to C12 alkoxyphenyl group, a nitro group, a cyano group or a halogen atom.
In still another aspect, the present invention provides a method for identifying a non-aqueous fluid product, comprising: dissolving a non-aqueous fluid marker, which contains N-benzyl-N-ethylaniline represented by the above Formula 1, in a target product; and developing a color of the target product with an acid developer.
The above and other features of the present invention will now be described in detail with reference to certain exemplary embodiments thereof illustrated the accompanying drawings which are given hereinbelow by way of illustration only, and thus are not limitative of the present invention, and wherein:
FIG. 1 is a graph illustrating a change in UV-VIS absorption spectra before and after addition of an acid developer to a marker solution containing an azo disperse dye prepared in Example 1, in which a change in maximum absorption wavelength is shown.
Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings.
The present invention provides a non-aqueous fluid marker containing N-benzyl-N-ethylaniline represented by the following Formula 1:
Formula 1
wherein R is a C1 to C12 alkyl group, a C1 to C12 alkoxy group, a C1 to C12 hydroxyalkyl group, a C1 to C12 hydroxyalkoxyalkyl group, a C1 to C12 alkylphenyl group, a C1 to C12 alkoxyphenyl group, a nitro group, a cyano group or a halogen atom.
The above-described substituents will be described in detail below.
The term “alkyl group” refers to a linear or branched aliphatic saturated hydrocarbon group having 1 to 12 carbon atoms. More particularly, the alkyl group may include a methyl group, an ethyl group, a n-propyl group, an i-propyl group, a n-butyl group, an i-butyl group, a t-butyl group, an n-pentyl group, an i-pentyl group, a n-hexyl group, an i-hexyl group, a n-heptyl group, an i-heptyl group, a n-octyl group, an i-octyl group, a n-nonyl group, an i-nonyl group, a n-dodecyl group, an i-dodecyl group, etc.
The term “alkoxy group” refers to a linear or branched aliphatic alkoxy group having 1 to 12 carbon atoms. More particularly, the alkyl group may include a methoxy group, an ethoxy group, a n-propyloxy group, an i-propyloxy group, an n-butoxy group, an i-butoxy group, a t-butoxy group, an n-pentoxy group, an i-pentoxy group, etc.
The term “hydroxyalkyl group” refers to a OH-alkyl group in which a hydroxyl group is bound to the aforementioned alkyl group. More particularly, the hydroxyalkyl group may include a hydroxymethyl group, a hydroxyethyl group, a hydroxy-n-propyl group, a hydroxy-n-butyl group, a hydroxy-i-butyl group, a hydroxy-n-pentyl group, a hydroxy-i-pentyl group, a hydroxy-n-hexyl group, a hydroxy-i-hexyl group, etc.
The term “hydroxyalkoxyalkyl group” refers to a hydroxyalkyl-O-alkyl group in which an alkoxy group is bound to the hydroxyalkyl group. More particularly, the hydroxyalkoxyalkyl group may include a hydroxyethoxymethyl group, a hydroxyethoxyethyl group, a hydroxymethoxypropyl group, a hydroxyethoxypropyl group, a hydroxyethoxybutyl group, a hydroxyethoxypentyl group, a hydroxyethoxyhexyl group, etc.
The term “alkylphenyl group” may include a methylphenyl group, an ethylphenyl group, a n-propylphenyl group, an n-butylphenyl group, etc.
The term “alkoxyphenyl group” may include a methoxyphenyl group, an ethoxyphenyl group, a n-propyloxyphenyl group, a n-butoxyphenyl group, etc.
The term “halogen atom” is a fluorine atom, a chlorine atom, a bromine atom or an iodine atom.
According to the present invention, a particularly preferred the oil marker is a compound in which R in Formula 1 is a C1 to C12 alkyl group or a C1 to C12 alkoxy group.
Moreover, the present invention provides a method for preparing a non-aqueous fluid marker containing N-benzyl-N-ethylaniline represented by the Formula 1. The non-aqueous fluid marker may be prepared by diazotizing an aniline derivative represented by the following Formula 3 and reacting the diazotized aniline derivative with N-benzyl-N-ethylaniline represented by the following Formula 4.
In the above Formulas 1 and 3, R has the same meaning as defined above.
In more detail, in the step of diazotizing an aniline derivative represented by the above Formula 3, the diazotization is performed by dispersing an aniline derivative in water or acetic acid or in a mixed solution of acetic acid and propionic acid at 0-10 °C and adding concentrated hydrochloric acid and NaNO2 or HO3SONO to react with each other. Preferably, in the mixed solution of the acetic acid and propionic acid may be mixed in a volume ratio of 5:1.
Then, the diazotized aniline derivative may be reacted with the N-benzyl-N-ethylaniline represented by the above Formula 4 to give a yellow azo disperse dye represented by the above Formula 1. The N-benzyl-N-ethylaniline may be dissolved in acetic acid or in a mixed solution of acetic acid and propionic acid in a separate container and maintained at 0-10 °C, and the prepared solution may then be added to the diazotized solution to carry out a coupling reaction at 0-10 °C. Preferably, in the mixed solution of acetic acid and propionic acid, the acetic acid and propionic acid may be mixed in a volume ratio of 5:1.
Furthermore, the present invention provides a method for identifying a target product using a non-aqueous fluid marker containing N-benzyl-N-ethylaniline represented by the above Formula 1.
The non-aqueous fluid marker containing the N-benzyl-N-ethylaniline represented by the above Formula 1 according to the present invention shows a purple color by reacting with acid developer when the non-aqueous fluid marker is dissolved in a target product. That is, when the marker according to the present invention reacts with the acid developer in the non-aqueous fluid product, a maximum absorption wavelength of the non-aqueous fluid product shifts from 410 nm to a longer wavelength of 560 nm. Therefore, the color of the non-aqueous fluid product is changed from its own color (i.e., yellow) to purple. Accordingly, it is possible to distinguish the non-aqueous fluid product including the marker according to the present invention from marker-free products. That is, when the non-aqueous fluid manufacturer dissolves the marker according to the present invention in the non-aqueous fluid product, it is possible to easily distinguish the product from other companies’ products using the acid developer. Therefore, it is possible to control the quality of the product in the distribution process. The type of non-aqueous fluids to be distinguished is not particularly limited, and the non-aqueous fluid may include gasoline, diesel, kerosene, biodiesel, bioethanol, xylene, ink, non-aqueous lubricant, solvent, and mixtures thereof. Moreover, the acid developer may include an organic acid such as dodecyl sulfonic acid, and an inorganic acid such as sulfuric acid or phosphoric acid. Preferably, the dodecyl sulfonic acid may be used as the acid developer.
Next, the present invention will be described in detail with reference to Examples, but the present invention is not limited by the following Examples.
EXAMPLES
Example 1
5.37 g (0.036 mol) of 4-butylaniline as a diazo compound was added to 70 ml ; of an acid mixture (where the volume ratio of acetic acid to propionic acid was 5: 1) and stirred at room temperature for about 20 minutes. Then, 7.7 ml (0.089 mol) of 35% hydrochloric acid was added to the resulting reactant and then maintained at 5-10 °C. Thereafter, 13 ml (0.039 mol) of 3N NaNO2 was slowly added thereto so that the reaction temperature would not rise and stirred at 5-10 °C for 1.5 hours, thereby completing diazotization. Finally, a small amount of sulfamic acid was added to remove excess nitrous acid.
Meanwhile, 7.6 g (0.036 mol) of N-benzyl-N-ethylaniline as a coupler was dissolved in 20 ml of an acid mixture (where the volume ratio of acetic acid to propionic acid was 5:1) and maintained at 5-10 °C. Then, the prepared solution was slowly added to the diazotized solution and stirred at 5-10 °C for 3.5 hours. 25 g of sodium acetate (NaOAc) was added to the reaction solution and stirred at room temperature for 30 minutes. The reaction mixture was poured into 250 g of ice-water, stirred for 1 hour to produce a solid product, and filtered. In order to purify the product, the isolated product was dispersed in 100 ml of isopropyl alcohol, stirred at room temperature for 30 minutes, filtered, and then dried, thereby obtaining a marker according to the present invention as a yellow solid azo disperse dye represented by the following Formula 5.
Formula 5
Examples 2-5
As yellow solid azo disperse dyes, non-aqueous fluid markers containing N-benzyl-N-ethylaniline according to the present invention were prepared in the same manner as in Example 1, except that aniline derivatives as listed in the following Table 1 were used.
The aniline derivatives represented by the above Formula 3 prepared in Examples 1-5, the amounts of aniline derivatives used, and their synthesis yields are listed in the following Table 1.
R | Amount of diazo compound used (g) | Yield (%) | |
Example 1 | 4-C4H9 | 5.36 | 76.3 |
Example 2 | 4-tert-C4H9 | 5.36 | 78.2 |
Example 3 | 4-C12H25 | 9.40 | 41.4 |
Example 4 | 4-CH3 | 3.85 | 69.9 |
Example 5 | 4-OCH3 | 4.43 | 17.3 |
Comparative Example 1
0.9 g (0.005 mol) of 2-amino-6-methoxybenzothiazole as a diazo compound was added to 10 ml of an acid mixture (where the volume ratio of acetic acid to propionic acid was 5:1) and stirred at room temperature for about 20 minutes. Then, the resulting reactant was maintained at 5-10 °C. Thereafter, 1.05 ml (0.0053 mol) of 40% HO3SONO was slowly added thereto so that the reaction temperature would not rise, and the resulting reactant was stirred at 5-10 °C for 1.5 hours, thereby completing diazotization. Finally, a small amount of sulfamic acid was added to remove excess nitrous acid.
Meanwhile, 1.05 g (0.005 mol) of N-benzyl-N-ethylaniline as a coupler was dissolved in 10 ml of an acid mixture (where the volume ratio of acetic acid to propionic acid was 5:1) and maintained at 5-10 °C. Then, the prepared solution was slowly added to the diazotized solution and stirred at 0-5 °C for 2 hours. 2.5 g of NaOAc was added to the reaction mixture and stirred at room temperature for 30 minutes. The reaction mixture was poured into 50 g of ice-water, stirred for 1 hour to produce a solid product, and filtered. In order to purify the product, the isolated product was dispersed 20 ml of isopropyl alcohol, stirred at room temperature for 30 minutes, filtered, and then dried, thereby obtaining 1.78 g of a red solid azo disperse dye represented by the following Formula 2 (yield = 88.6 %).
Comparative Example 2
The compound of Formula 6 was prepared according to the method described in Comparative Example 1 using 0.49 g (0.005 mol) of 3-amino-5-methylisoxazole as diazo compound, thereby obtaining 1.20 g of a yellow solid azo disperse dye (yield = 75 %) represented by the following Formula 6.
Formula 6
The mass spectra (m/e) and 1H NMR spectra data for confirming the respective structures of the azo disperse dyes containing N-benzyl-N-ethylaniline prepared in Examples 1-5 and Comparative Examples 1 and 2 are listed in the following Table 2.
m/e | 1H NMR* (δ ppm ) | |
Example 1 | 371 | A; 0.92(3H, t), 1.25(3H, t), 1.36(2H, sextet), 1.62(2H, qt), 2.66(2H, t), 3.64(2H, q), 4.70(2H, s), 6.84(2H, d), 7.23-7.35(7H, m), 7.73(2H, d), 7.78(2H, d) |
Example 2 | 371 | C; 1.26(3H, t), 1.33(9H, s), 3.56(2H, q), 4.61(2H, s), 6.75(2H, d), 7.20-7.34(5H, m), 7.45(2H, d), 7.74(2H, d), 7.81(2H, d) |
Example 3 | 483 | C; 0.86(3H, t), 1.24-1.28(20H, m), 1.57-1.64(4H, m), 2.63(2H, t), 3.56(2H, q), 4.62(2H, s), 6.75(2H, d), 7.20-7.34(7H, m), 7.73(2H, d), 7.81(2H, d) |
Example 4 | 329 | C; 1.25(3H, t), 2.38(3H, s), 3.55(2H, q), 4.61(2H, s), 6.75(2H, d), 7.20-7.31(7H, m), 7.72(2H, d), 7.80(2H, d) |
Example 5 | 345 | A; 1.25(3H, t), 3.63(2H, q), 3.86(3H, s), 4.70 (2H, s), 6.83(2H, d), 7.03(2H, d), 7.21-7.35(7H, m), 7.74(2H, d), 7.78(2H, d) |
Comp. Example 1 |
402 | A; 1.30(3H, t), 3.72(2H, q), 3.89(3H, s), 4.81 (2H, s), 6.94(2H, d), 7.09(1H, dd), 7.26-7.37(5H, m), 7.50(1H, d), 7.83-7.90(3H, m) |
Comp. Example 2 |
320 | A; 1.27(3H, t), 2.44(3H, s), 3.68(2H, q), 4.76 (2H, s), 6.36(1H, s), 6.87(2H, d), 7.24-7.36(5H, m), 7.80(2H, d) |
* Solvent for 1H NMR ; CDCl3(C), Acetone-d6 (A) |
Test Example 1: Test for acid reactivity of yellow azo disperse dyes
(1) Preparation of marker solution
A proper amount of each of the azo disperse dyes prepared in Examples 1-5 and Comparative Examples 1 and 2 was taken and diluted with xylene in a 25 ml volumetric flask, and 1 ml of the azo disperse dye solution was taken and diluted with xylene in a 10 ml volumetric flask to prepare a marker solution. Concentrations of the marker solutions are listed in the following Table 3.
(2) Preparation of acid developer solution
3 g of xylene was added to 7 g of dodecylbenzene sulfonic acid to prepare a coloring agent solution.
(3) Measurement of UV-VIS molar absorption coefficients and maximum absorption wavelength
The UV-VIS molar absorption coefficients (ε) and maximum absorption wavelengths (λmax) of the samples prepared in (1) were measured. Then, 10 μl of the acid developer solution prepared in (2) was added to each sample and stirred for 1 minute. Then, the UV-VIS molar absorption coefficient (ε) and maximum absorption wavelength (λmax) of each sample were measured to observe a change in color. The UV-VIS molar absorption coefficient and maximum absorption wavelength were measured using a UV-VIS-NIR spectrophotometer (UV-3101 PC, SHIMADZU). The measurement results are listed in the following Table 3 and shown in FIG. 1.
Concentration (mg /L) |
Before addition of developing agent |
After addition of developing agent |
Wavelength shift (nm) |
|||
λmax * | εmax/ Lmol-1cm-1 |
λmax * | εmax/ Lmol-1cm-1 |
|||
Example 1 | 17.12 | 410 | 3.261 x 104 | 562 | 4.537 x 104 | 152 |
542 | 4.507 x 104 | |||||
Example 2 | 14.84 | 409 | 3.235 x 104 | 563 | 4.633 x 104 | 154 |
542 | 4.590 x 104 | |||||
Example 3 | 16.64 | 410 | 3.086 x 104 | 562 | 4.488 x 104 | 152 |
542 | 4.464 x 104 | |||||
Example 4 | 15.00 | 409 | 3.216 x 103 | 562 | 4.464 x 104 | 153 |
539 | 4.424 x 104 | |||||
Example 5 | 16.04 | 409 | 2.850 x 104 | 565 | 1.693 x 104 | 67 |
476 | 2.089 x 104 | |||||
Comp. Example 1 | 15.40 | 489 | 4.252 x 104 | 512 | 3.310 x 104 | 23 |
Comp. Example 2 | 17.28 | 408 | 3.152 x 104 | 451 | 2.052 x 104 | 43 |
* Solvent for UV measurement: Xylene |
The alkyl group-substituted yellow azo disperse dyes prepared in Examples 1 -4 showed a distinct purple color and a maximum absorption wavelength was shifted to a longer wavelength by 150 nm or more when the dodecylbenzene sulfonic acid solution was added to the marker solution.
The methoxy group-substituted yellow azo disperse dye prepared in Example 5 had a higher absorbance at 476 nm than at 565 nm as shown in the above Table 3, when the dodecylbenzene sulfonic acid solution was added to the marker solution. The color change of the marker solution could be observed, however the appearance of color was not distinctive.
In Comparative Example 1 using 2-amino-6-methoxybenzothiazole as the diazo compound, when the dodecylbenzene sulfonic acid solution was added to the marker solution, a maximum absorption wavelength of the azo disperse dye was shifted to a longer wavelength by 23 nm, and thus the color change of the marker solution was insignificant. Moreover, the compound of Formula 2 prepared in Comparative Example 1 was not suitable for use as a marker since the compound itself exhibited a red visible color in the xylene.
In Comparative Example 2 using 3-amino-5-methylisoxazole as the diazo compound, when the dodecylbenzene sulfonic acid solution was added to the marker solution, a maximum absorption wavelength of the azo disperse dye was shifted to a longer wavelength by 43 nm, and thus the color change of the marker solution was insignificant. The azo disperse dye was not suitable for use as a marker since the azo disperse dye exhibited a dark yellow visible color even when the acid developer was added to the marker solution.
Therefore, it is considered that the alkyl group-substituted yellow azo disperse dyes prepared in Examples 1-4, which exhibits their distinct colors by addition of dodecylbenzene sulfonic acid solution as the acid developer, can be more effectively used as an acid-reactive marker.
As described above, the marker containing N-benzyl-N-ethylaniline according to the present invention exhibits high solubility in non-aqueous fluid products, has excellent storage stability, can be detected even in a small amount, and can develop a distinct color by reaction with an organic acid such as dodecylbenzene sulfonic acid and an inorganic acid such as sulfuric acid or phosphoric acid in the non-aqueous fluid product. Therefore, when the marker is added to a product, the product can be easily distinguished from other companies’ products containing no marker or illegally distributed products such as adulterated gasoline, which makes it possible to easily control the quality of the product in the distribution process.
The invention has been described in detail with reference to preferred embodiments thereof. However, it will be appreciated by those skilled in the art that changes may be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Claims (6)
- A non-aqueous fluid marker comprising N-benzyl-N-ethylaniline represented by the following Formula 1:
Formula 1
wherein R is a C1 to C12 alkyl group, a C1 to C12 alkoxy group, a C1 to C12 hydroxyalkyl group, a C1 to C12 hydroxyalkoxyalkyl group, a C1 to C12 alkylphenyl group, a C1 to C12 alkoxyphenyl group, a nitro group, a cyano group or a halogen atom. - The non-aqueous fluid marker according to claim 1, wherein R is a methyl group, a n-butyl group, a t-butyl group, an n-dodecyl group or a methoxy group.
- A method for preparing a non-aqueous fluid marker, comprising:
diazotizing an aniline derivative represented by the following Formula 3; and
reacting N-benzyl-N-ethylaniline represented by the following Formula 4 with the diazotized aniline derivative:
wherein R is a C1 to C12 alkyl group, a C1 to C12 alkoxy group, a C1 to C12 hydroxyalkyl group, a C1 to C12 hydroxyalkoxyalkyl group, a C1 to C12 alkylphenyl group, a C1 to C12 alkoxyphenyl group, a nitro group, a cyano group or a halogen atom.
- A method for identifying a non-aqueous fluid product, comprising:
dissolving a non-aqueous fluid marker, which contains N-benzyl-N-ethylaniline represented by the following Formula 1, in a target product; and developing a detectable color of the target product with an acid developer:
Formula 1
wherein R is a C1 to C12 alkyl group, a C1 to C12 alkoxy group, a C1 to C12 hydroxyalkyl group, a C1 to C12 hydroxyalkoxyalkyl group, a C1 to C12 alkylphenyl group, a C1 to C12 alkoxyphenyl group, a nitro group, a cyano group or a halogen atom.
- The method according to claim 4, wherein the target product is at least one selected from the group consisting of gasoline, diesel, kerosene, biodiesel, bioethanol, xylene, ink, and non-aqueous lubricant.
- The method according to claim 4, wherein the acid developer is dodecylbenzene sulfonic acid, sulfuric acid or phosphoric acid.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020110032329A KR101300673B1 (en) | 2011-04-07 | 2011-04-07 | Nonaqueous fluid marker having N-benzyl-N-ethylaniline and Preparing method thereof |
KR10-2011-0032329 | 2011-04-07 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2012138049A1 WO2012138049A1 (en) | 2012-10-11 |
WO2012138049A4 true WO2012138049A4 (en) | 2012-12-13 |
Family
ID=46969406
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/KR2012/000990 WO2012138049A1 (en) | 2011-04-07 | 2012-02-10 | Non-aqueous fluid marker containing n-benzyl-n-ethylaniline and method for preparing the same |
Country Status (2)
Country | Link |
---|---|
KR (1) | KR101300673B1 (en) |
WO (1) | WO2012138049A1 (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103242249A (en) * | 2013-05-30 | 2013-08-14 | 杨文龙 | Compound capable of identifying dodecylbenzene sulfonic acid ions as well as preparation method and application thereof |
CN105859576A (en) * | 2016-05-05 | 2016-08-17 | 成都中恒华铁科技有限公司 | Method for synthesizing phenylbutazone drug intermediate azobenzene |
CN107421899A (en) * | 2017-06-28 | 2017-12-01 | 重庆市宇驰检测技术有限公司 | Determine the detection method of water quality aniline, formaldehyde simultaneously based on ultraviolet-visible absorption spectroscopy |
CN112051224B (en) * | 2020-08-12 | 2021-08-06 | 昆明理工大学 | Method for detecting blending ratio of biodiesel blending fuel based on ultraviolet-visible spectrophotometry |
KR20220118077A (en) | 2021-02-18 | 2022-08-25 | 한국화학연구원 | Azo based compound for detecting hazardous acids and detection method using the same |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB0108318D0 (en) * | 2001-04-03 | 2001-05-23 | Clariant Int Ltd | Organic compounds |
US6514917B1 (en) * | 2001-08-28 | 2003-02-04 | United Color Manufacturing, Inc. | Molecular tags for organic solvent systems |
US6764541B1 (en) * | 2003-04-24 | 2004-07-20 | Xerox Corporation | Colorant compositions |
BRPI0514197A (en) * | 2004-08-11 | 2008-06-03 | Ciba Sc Holding Ag | method of printing a time-temperature indicator based on azo coupling reactions on a substrate |
EP1820537A1 (en) * | 2006-02-18 | 2007-08-22 | Wella Aktiengesellschaft | Agents for coloring keratin fibers |
CN101981167B (en) * | 2008-03-25 | 2014-08-13 | 卢布里佐尔公司 | Marker dyes for petroleum products |
-
2011
- 2011-04-07 KR KR1020110032329A patent/KR101300673B1/en active IP Right Review Request
-
2012
- 2012-02-10 WO PCT/KR2012/000990 patent/WO2012138049A1/en active Application Filing
Also Published As
Publication number | Publication date |
---|---|
WO2012138049A1 (en) | 2012-10-11 |
KR20120114663A (en) | 2012-10-17 |
KR101300673B1 (en) | 2013-08-28 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
WO2012138049A1 (en) | Non-aqueous fluid marker containing n-benzyl-n-ethylaniline and method for preparing the same | |
Geng et al. | 2-Amino-4-chloro-5-formylthiophene-3-carbonitrile derived azo dyes | |
JP2009280691A (en) | Azo compound and salt of the same | |
CN105038316A (en) | Heterocyclic-ring disperse azo dye and preparation method thereof | |
JP2009013290A (en) | Azo compound or its salt | |
Geng et al. | From heterocyclic hydrazone to hydrazone-azomethine dyes: Solvent and pH induced hydrazone and azo-keto transformation for a family of pyrazolone-based heterocyclic dyes | |
Zhao et al. | Construction of benzothiazole/pyridone based bi-heterocyclic dyes and their NiII and CuII complexes | |
CN101245195B (en) | Novel heterocycle azo cationic dye and manufacture method thereof | |
CN111896536A (en) | Benzothiazole azo acid-base indicator and synthesis method thereof | |
KR101521141B1 (en) | Azo compound or its salt | |
Li et al. | Crystallographic study of two monoazo disperse dyes with a D–π–A system | |
KR20220118077A (en) | Azo based compound for detecting hazardous acids and detection method using the same | |
EP0553858B1 (en) | Monoazo compound and dense solution thereof | |
Yen | Synthesis and solvatochromism of heterocyclic bichromophoric dyes derived from 2‐aminothiazole | |
Lee et al. | Synthesis of quenchers to control the fluorescence of Rhodamine B and improve the contrast ratio of blue filters for LCDs | |
Seferoĝlu et al. | Hetarylazoindoles 1. Synthesis, characterization, and spectroscopic properties of new hetarylazoindole dyes | |
CN109988118B (en) | Heterocyclic azo compound and synthesis method and application thereof | |
CN105820596A (en) | Tetrahydroquinoline dye, ink and electrowetting display | |
US2075743A (en) | Mordant azodyestuffs and their production | |
Shan et al. | A new highly sensitive and colorimetric pH indicator derived from 2-amino-5-nitrothiazole and H-acid | |
CN101337942A (en) | Azo compound or salts thereof | |
RU2273652C1 (en) | Dyes based on 3,5-dinitroaniline and 2-amino-4,6-dinitrotoluene | |
CN115073934A (en) | Benzisothiazole heterocyclic azo dye and preparation method thereof | |
KR20090004762A (en) | Azo compound or its salt | |
JP3005877B2 (en) | Concentrated solution of monoazo compound |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 12767892 Country of ref document: EP Kind code of ref document: A1 |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
122 | Ep: pct application non-entry in european phase |
Ref document number: 12767892 Country of ref document: EP Kind code of ref document: A1 |