WO2012124977A2

WO2012124977A2 - Joining material for polyethylene pipe, and joining method using same

Info

Publication number: WO2012124977A2
Application number: PCT/KR2012/001834
Authority: WO
Inventors: 박우일; 천만식
Original assignee: Park Woo Il; Cheon Man Sik
Priority date: 2011-03-15
Filing date: 2012-03-14
Publication date: 2012-09-20
Also published as: WO2012124977A3

Abstract

The present invention relates to a joining material for a polyethylene pipe, to a method for joining a polyethylene pipe using the joining material, and to a joining material for a polyethylene pipe, a connection pipe and a heating sheet, used in said method. More particularly, the present invention relates to a joining material for a polyethylene pipe to be used in joining a polyethylene pipe, wherein the inside of the joining material is packed with joining particles including carbon nanotubes and polyethylene. The polyethylene pipe to be joined is fitted to a connection pipe, and the joining material filled with joining particles is inserted between the polyethylene pipe and the connection pipe, and a heating sheet wraps around and melts the joining member, and thus, the polyethylene pipe is connected. The joining material for a polyethylene pipe according to the present invention contains carbon nanotubes, which have superior thermal conductivity, in a heat transfer layer formed on the outer surface of the joining material and the joining particles, and therefore the joining material of the present invention may quickly transfer heat from a heat source to the polyethylene. As a result, polyethylene may be quickly melted to enable the polyethylene pipe to be connected in a short time period.

Description

Polyethylene pipe joint and joining method using the same

The present invention relates to a polyethylene pipe bonding material, a polyethylene pipe bonding method using the bonding material, a polyethylene pipe bonding material, a connecting pipe and a heat generating sheet used in the bonding method. Specifically, the present invention is to insert the polyethylene pipe to be bonded to the connecting pipe, the pipe bonding material filled with the bonding particles including carbon nanotubes and polyethylene therebetween the polyethylene pipe, wrapped around the heating sheet and the pipe bonding material It relates to a polyethylene pipe bonding material or the like used to join polyethylene pipes by melting them.

Polyethylene pipes for water and sewage and gas do not have corrosion, corrosion, and no capstone, and thus have excellent physical properties as pipes. Furthermore, it is odorless, has excellent physical and chemical properties such as acid resistance and alkali resistance, and has a life span of more than 50 years.

On the other hand, the quality of the pipe depends on the connection area. Polyethylene does not bond with other polymers and does not dissolve in solvents, so connection of polyethylene pipes is possible only by melt bonding.

Such fusion splicing methods include butt fusion, socket fusion, saddle fusion, and the like. Butt fusion is a method of melting the end of a pipe with a heating plate when connecting, and then removing the heating plate and bonding the pipes to each other, but when removing the heating plate, the temperature distribution in the melt at the end of the pipe changes rapidly, resulting in poor adhesion. In many cases, the construction conditions were difficult, such as fusion conditions were changed depending on the surrounding environment. In addition, the sockets or birds are expensive in themselves, and there is a problem in that they are not easy to apply because of limitations in shape or size. In order to solve this problem, there have been attempts to change the copper wire inside the socket to carbon fiber, but it has been difficult to be widely accepted in terms of economics.

The present invention has been made to solve the above problems, the outer surface is coated with a carbon nanotube and a thermoplastic resin mixture, the inside is a polyethylene including a sealed polyethylene pouch filled with bonded particles including carbon nanotubes and polyethylene It is an object to provide a pipe joint.

In another aspect, the present invention is to insert the polyethylene pipe to be bonded to a separate connecting pipe at intervals, and then the pipe bonding material is sandwiched in the gap, and to melt and cool the pipe bonding material with a separate heating sheet to join the polyethylene pipe Another object is to provide a method for joining polyethylene pipes.

Another object of the present invention is to provide a polyethylene pipe bonding material used in the polyethylene pipe bonding method.

Another object of the present invention is to provide a connecting pipe used in the polyethylene pipe joining method.

Another object of the present invention is to provide a heat generating sheet used in the polyethylene pipe joining method.

In order to achieve the object as described above, the polyethylene pipe joint member of the present invention,

Hermetically sealed pouches made of polyethylene film;

A heat transfer layer coating an outer surface of the sealed pouch and including carbon nanotubes and a thermoplastic resin; And

Filling the inside of the sealed pouch, the bonding particles containing carbon nanotubes and polyethylene

Characterized in that it comprises a.

In addition, the thermoplastic resin included in the heat transfer layer of the pipe bonding material may be selected from the group consisting of vinyl resins, acrylic resins, polyamides, polyesters, polyethers and mixtures thereof.

In addition, the heat transfer layer thickness of the pipe bonding material may be 0.1 to 5 ㎛.

In addition, the weight ratio of the carbon nanotubes and the thermoplastic resin in the heat transfer layer of the pipe bonding material may be carbon nanotubes: thermoplastic resin = 0.1 to 60: 40 to 99.9% by weight.

In addition, the weight ratio of the carbon nanotubes and polyethylene in the bonding particles of the pipe joint material may be carbon nanotubes: polyethylene = 0.1 to 30: 70 to 99.9% by weight.

On the other hand, the polyethylene pipe joining method of the present invention

(A) Fit each pair of polyethylene pipes to be joined to both ends of the connecting pipe, wherein the outer surface of the connecting pipe is in close contact with the inner surface of the polyethylene pipe to be joined, and the spacing between the polyethylene pipes is 20 to 100 of the thickness of the polyethylene pipe. % Phosphorus step;

(B) inserting the polyethylene pipe joint into the gap between the polyethylene pipes;

(C) wrapping the pipe joint and the adjacent polyethylene pipe outer surface with a protective film;

(D) wrapping the protective film with a heating sheet coated with a heating layer including a thermosetting resin and carbon nanotubes on one surface of the polyimide film, wherein the heating layer is wrapped in contact with the protective film;

(E) supplying electricity to the heat generating layer of the heat generating sheet to generate heat, thereby melting the pipe joint and the adjacent polyethylene pipe to fill a gap between the polyethylene pipes;

(F) discontinuing the supply of electricity to the heating sheet and cooling the molten pipe joint and the adjacent polyethylene pipe; And

(G) removing the heating sheet and the protective film

Characterized in that it comprises a.

In addition, after step (B) and before step (G), a step of adjusting the gap between the polyethylene pipes is adjusted so that the outer diameter of the polyethylene pipe bonding material cooled after melting is 95 to 120% of the outer diameter of the polyethylene pipe. It can be included as.

In addition, after step (D) and before step (E), the method may further include covering the heating sheet with a cover.

In addition, the carbon nanotubes included in the heat transfer layer of the pipe joining material, the carbon nanotubes included in the joining particles of the pipe joining material and the carbon nanotubes included in the heat generating layer of the heating sheet are independently of each other, single-walled carbon nanotubes. , Double-walled carbon nanotubes, multi-walled carbon nanotubes and mixtures thereof.

In addition, the temperature of the pipe bonding material melted in the step (D) may be 130 to 270 ℃.

On the other hand, the polyethylene pipe joining material of the present invention is characterized in that it is used in the polyethylene pipe joining method.

In addition, the inner diameter of the connecting pipe may increase toward both ends.

In addition, the connecting pipe may be made of polyethylene.

In addition, the length of the connecting pipe may be 10 to 200 mm.

In addition, the thickness of the connecting pipe may be 1 to 5 mm.

In addition, the protective film may be made of polyimide.

In addition, the thermosetting resin constituting the heat generating layer of the heat generating sheet may be selected from the group consisting of polyurethane, phenol resin, amino resin, epoxy resin and mixtures thereof.

In addition, the weight ratio between the carbon nanotubes and the thermosetting resin in the heat generating layer of the heat generating sheet may be 15 to 45 parts by weight of the thermosetting resin per 100 parts by weight of the carbon nanotubes.

In addition, the heat generating layer of the heat generating sheet may further include an antioxidant.

In addition, the antioxidant may be hydroquinone.

In addition, the weight ratio between the carbon nanotubes and the antioxidant in the heat generating layer of the heat generating sheet may be 1 to 2 parts by weight of antioxidant per 100 parts by weight of carbon nanotubes.

In addition, the heat generating layer of the heat generating sheet may further include a dispersant.

In addition, the dispersant may be lecithin.

In addition, the weight ratio between the carbon nanotubes and the dispersant in the heat generating layer of the heat generating sheet may be 1 to 2 parts by weight of the dispersant per 100 parts by weight of carbon nanotubes.

In addition, the exothermic layer of the exothermic sheet is carbon in a solvent selected from the group consisting of ketone, toluene, butyl cellosolve, N-methyl-2-pyrrolidone (NMP) and mixtures thereof. Nanotubes and thermosetting resins may be added and mixed and then coated and dried.

In addition, the heat generating layer of the heat generating sheet,

A pair of conductive parts spaced apart from two opposite sides of the heating sheet and formed in parallel to the two sides; And

A heating unit disposed between the pair of conductive units and connecting the conductive units to each other

It may be made of.

In addition, the heating unit may be provided with 1 to 100 on the heating sheet.

In addition, a portion of the conductive portion may extend to be connected to a portion of the opposite conductive portion.

In addition, the thickness of the heat generating layer of the conductive portion may be 1 to 100 ㎛.

In addition, the thickness of the heat generating layer of the heat generating portion may be 1 to 50 ㎛.

In addition, the width of the first conductive portion may be 1 to 200 mm.

On the other hand, the connection pipe of the present invention is characterized in that it is used in the polyethylene pipe joining method.

On the other hand, the heat generating sheet of the present invention is characterized in that it is used in the polyethylene pipe joining method.

The polyethylene pipe bonding material of the present invention can quickly transfer heat from a heat source to polyethylene by containing carbon nanotubes having excellent thermal conductivity in the heat transfer layer and the bonding particles on the outer surface. As a result, it is possible to melt the polyethylene quickly and connect the polyethylene pipe to be joined in a short time. This can shorten the time required for joining the socket compared to the melting of the pipe itself, etc., it is also possible to enjoy the effect of reducing the cost and working time. In addition, the polyethylene pipe joining method of the present invention using the polyethylene pipe joining material not only the end of the pipe but the outer diameter of the connection portion is wrapped with a heating sheet to supply heat, and after the completion of fusion does not remove the heating sheet until the end of cooling. By doing so, it is possible to fundamentally eliminate the imperfection of the fusion due to the removal of the heat source during the bonding, which has been a problem of the conventional butt fusion method. This complete fusion and separate connection pipe improves pressure resistance and impact resistance, and prolongs the airtightness of the joints, greatly reducing the maintenance and repair costs of the pipes. In addition, there is no need to provide expensive sockets or birds separately, such as socket fusion or saddle fusion, and there is no need to provide sockets or birds of various sizes and shapes in the field, thereby improving economics and workability.

1 is a cross-sectional perspective view of a polyethylene pipe joining material used in the polyethylene pipe joining method of the present invention.

2 is a cross-sectional view illustrating a state in which a polyethylene pipe to be joined to a connection pipe is inserted and a polyethylene pipe bonding material is inserted therebetween.

3 is a cross-sectional view illustrating a state in which a polyethylene film bonding material is wrapped around a protective film, a heating sheet, and a cover.

4 is a cross-sectional view of FIG. 3 viewed from a pipe length direction without a cover.

5 is a cross-sectional view showing an embodiment of a connecting pipe used in the polyethylene pipe joining method of the present invention.

Figure 6 is a cross-sectional view showing another embodiment of the connecting pipe used in the polyethylene pipe joining method of the present invention.

Figure 7 is a plan view showing an embodiment of a heat generating sheet used in the polyethylene pipe joining method of the present invention.

8 is a plan view showing another embodiment of a heat generating sheet used in the polyethylene pipe joining method of the present invention.

9 is a plan view showing another embodiment of a heat generating sheet used in the polyethylene pipe joining method of the present invention.

10 is a plan view showing another embodiment of a heat generating sheet used in the polyethylene pipe joining method of the present invention.

Hereinafter, preferred embodiments of the present invention will be described in detail. In addition, many specific details such as specific components are described in the following description, which is provided to help a more general understanding of the present invention, and the present invention may be practiced without these specific details. It is self-evident to those who have knowledge of the world. In describing the present invention, when it is determined that a detailed description of a related known function or configuration may unnecessarily obscure the subject matter of the present invention, the detailed description thereof will be omitted.

As used herein, the term 'thickness' refers to half of the difference between the outer diameter and the inner diameter in the case of pipes.

In order to achieve the object as described above, the polyethylene pipe bonding material 100 of the present invention is inserted between the polyethylene pipes 400 to be bonded, and then melted and cooled by a separate heat source to bond the polyethylene pipes 400. It is characterized by connecting.

As shown in FIG. 1, the pipe bonding member 100 includes a sealed pouch 120 made of polyethylene film, a heat transfer layer 110 coated on an outer surface thereof, and a bonding particle 130 filling the inside of the pouch 120. ). The heat transfer layer 110 includes carbon nanotubes and a thermoplastic resin, and the bonding particles 130 include carbon nanotubes and polyethylene.

While the conventional butt fusion method heats the end surface of the pipe to melt the pipe itself and then fusions it, the polyethylene pipe joining method of the present invention inserts a separate polyethylene between the pipes and is a heat transfer promoting material mixed with the polyethylene. It is characterized in that the polyethylene is rapidly melted through the nanotubes to bond between the pipes. The polyethylene melted by heating is gentle in temperature change of the melt by keeping in contact with the heat source until the joining of the pipe is completed and the molten polyethylene is cooled. Therefore, it is possible to fundamentally block the imperfection of the joint due to a sudden temperature change as in conventional butt fusion.

In order to achieve the function of the polyethylene pipe bonding material 100, the heat supplied from the external heat source is transferred to the entire surface of the pouch 120 through the heat transfer layer 110, and the heat is evenly transmitted back to the inner bonding particles 130. Can be. Furthermore, the bonding particles 130 also contain carbon nanotubes therein, so that the heat transferred from the heat transfer layer 110 can be quickly transferred to the adjacent polyethylene. The heat transferred in this way melts the polyethylene of the bonding particles 130 and the polyethylene of the pouch 120 to fill the gap between the polyethylene pipes 400 in an airtight manner. It is the joining method of the present invention that the melt is cooled to completely join the pipes.

The temperature of the molten pipe joining material 100 is 130 to 270 ℃, if less than 130 ℃, near or below the melting point of polyethylene does not melt the polyethylene, if it exceeds 270 ℃ polyethylene decomposition or denaturation occurs The durability of the connection site cannot be guaranteed.

Here, the carbon nanotubes are mixed with the thermoplastic resin and coated on the heat transfer layer 110 of the pipe joint 100, but there is no limitation on the thermoplastic resin mixed with the carbon nanotubes. It is preferably selected from the group consisting of resins, polyamides, polyesters, polyethers and mixtures thereof.

In addition, the weight ratio of the carbon nanotubes and the thermoplastic resin in the heat transfer layer 110 of the pipe joint 100 may be carbon nanotubes: thermoplastic resin = 0.1 to 60: 40 to 99.9% by weight. If the carbon nanotube is less than 0.1% by weight, it is difficult to quickly transfer heat from the heat generating sheet 200 to be described later to the bonding particles 130, on the contrary, when the carbon nanotube exceeds 60% by weight, it is excessive compared to the thermoplastic resin serving as a binder. Containing carbon nanotubes from the heat transfer layer 110.

And, the thickness of the heat transfer layer 110 of the pipe bonding material 100 is preferably 0.1 to 5 ㎛, if less than 0.1 ㎛ to quickly transfer the heat from the heat generating sheet 200 to be described later to the bonding particles (130). In contrast, if the thickness exceeds 5 μm, the flexibility of the pipe joint 100 is reduced, making it difficult to sandwich the polyethylene pipe 400, and even if it is sandwiched, the heat transfer layer 110 is more likely to be broken.

On the other hand, the bonding particles 130 of the pipe joint 100 is also preferably a carbon nanotube and the weight ratio of the carbon nanotube: polyethylene = 0.1 to 30: 70 to 99.9% by weight, the carbon nanotube 0.1% by weight If less than, it is difficult to quickly transfer heat from the heat transfer layer 110 to the adjacent polyethylene, on the contrary, if it exceeds 30% by weight, the content of the non-polyethylene material is excessively high at the connection portion of the polyethylene pipe 400. There is a possibility that the durability is reduced.

The polyethylene pipe joining method of the present invention first begins by inserting each of the pair of polyethylene pipes 400 to be joined at both ends of the connecting pipe 300 as shown in FIGS. 2 and 3. The presence of such a connecting pipe 300 forms a major feature of the present invention. In the case of conventional butt fusion, a separate connecting pipe 300 is applied due to a process of applying and removing a heating plate corresponding to a cross section of the polyethylene pipe 400 to be joined. It was difficult to intervene. However, since the present invention wraps and melts the outside of the pipe, it is possible to interpose the connection pipe 300 therein, and due to the mechanical strength of the connection pipe 300 itself, the durability and impact resistance of the pipe connection area is dramatically increased. will be. Further, the connection pipe 300 used in the present invention is characterized in that it is used in the polyethylene pipe joining method of the present invention.

At this time, the outer surface of the connection pipe 300 is in close contact with the inner surface of the polyethylene pipe 400 to be bonded, as shown in FIGS. 2 and 3, the polyethylene pipe 400 to be bonded is not opposed to each other but the polyethylene pipe 400 20 to 100% of the thickness is inserted apart from each other, the pipe joining material 100 to be described later is inserted in this interval. If the gap is less than 20% of the thickness of the polyethylene pipe 400 to be bonded, the amount of the pipe bonding material 100 to be inserted is small, so that it is difficult to realize complete bonding. The amount is unnecessarily increased and economic efficiency is lowered.

Here, the inner diameter of the connecting pipe 300 may be constant with respect to the longitudinal direction of the connecting pipe 300, as shown in Figures 2 and 3, but more increases toward both ends as shown in Figure 5 or 6 desirable. According to the polyethylene pipe joining method of the present invention, the inner diameter of the pipe is reduced due to the presence of the connection pipe 300 at the connection portion of the pipe, the fluid flowing inside the pipe is obstructed flow due to the thickness of the connection pipe 300 This results in an increase in the operating cost by increasing the pressure required to transfer the fluid. In order to solve this problem, the inner diameter of the connecting pipe 300 gradually increases toward both ends, so that the fluid flows smoothly and the generation of unnecessary vortices can be suppressed. The inner diameter increasing method may have a straight cross section as shown in FIG. 5, or a curved cross section as shown in FIG. 6.

And, the material of the connecting pipe 300 is not limited as long as it is a synthetic resin that can be used as a pipe, but more preferably made of the same polyethylene as the pipe to be bonded.

The length of the connection pipe 300 can be changed and used according to the site situation to be applied, and particularly preferably 10 to 200 mm. If the length of the connecting pipe 300 is less than 10 mm there is a possibility that the length of contact with both polyethylene pipe 400 is short and can be separated, on the contrary, if the length of the connecting pipe 300 exceeds 200 mm, the section of narrowing the inner diameter is unnecessarily increased. .

Similarly, the thickness of the connection pipe 300 can be used in accordance with the field conditions to be applied, it is particularly preferred that the 1 to 5 mm. If the thickness of the connecting pipe 300 is less than 1 mm, there is a possibility that the mechanical strength of the connecting pipe 300 itself may be excessively reduced, and the shape of the pipe may be lost due to excessive melting with the pipe joint 100 during construction. On the contrary, if the diameter exceeds 5 mm, the inner diameter becomes too narrow, which increases the operating pressure.

When the polyethylene pipe bonding material 100 is sandwiched between the pipes, the outer surface of the pipe bonding material 100 and the adjacent polyethylene pipe 400 is surrounded by the protective film 500 as shown in FIG. 3. The protective film 500 is introduced to prevent the phenomenon that the molten pipe bonding material 100 becomes difficult to remove the heating sheet 200 by contaminating the heating sheet 200 to be described later. Since the heating sheet 200 is heated to a temperature much higher than the melting point of polyethylene, it should be a material having a very high melting point that does not cause decomposition or denaturation even at such a temperature. Meade is preferred.

After the protective film 500 is wrapped in this way, the protective film 500 is wrapped with the heating sheet 200 as shown in FIGS. 3 and 4.

The heat generating sheet 200 is coated with a heat generating layer 210 including a thermosetting resin and carbon nanotubes on one surface of the polyimide film 220, so that the heat generating layer 210 is in contact with the protective film 500. do. The heating sheet 200 used in the present invention is characterized in that it is used in the polyethylene pipe bonding method as described above.

Applying the polyimide film 220 as the substrate of the heat generating sheet 200 is the same as the reason for using the polyimide film as the protective film 500, the thermosetting resin constituting the heat generating layer 210 is a stable resin even at high temperatures Although it may be used without limitation, it is more preferably selected from the group consisting of polyurethane, phenol resin, amino resin, epoxy resin and mixtures thereof.

The weight ratio between the carbon nanotubes and the thermosetting resin in the heat generating layer 210 of the heat generating sheet 200 is preferably 15 to 45 parts by weight of the thermosetting resin per 100 parts by weight of the carbon nanotubes, the binder is less than 15 parts by weight of the thermosetting resin There is a problem that there is a possibility that the carbon nanotubes are lost from the heat generating layer 210 due to too little thermosetting resin to play a role and the temperature rises easily, making it difficult to control the temperature. On the contrary, when the content of the thermosetting resin exceeds 45 parts by weight, it takes a long time to heat and it is difficult to raise the temperature to the desired temperature.

In addition, the heat generating layer 210 of the heat generating sheet 200 may further include an antioxidant to prevent deterioration of the function of the heat generating layer 210 due to oxidation, but there is no particular limitation on the antioxidant used. , Hydroquinone is particularly preferred. Furthermore, the weight ratio between the carbon nanotubes and the antioxidant in the heating layer 210 of the heat generating sheet 200 is preferably 1 to 2 parts by weight of antioxidant per 100 parts by weight of carbon nanotubes, but less than 1 part by weight of the antioxidant effect When it is difficult to harvest enough, on the contrary, if it exceeds 2 parts by weight, the increase in the antioxidant effect due to the increase of the amount of the antioxidant is insignificant, which is unnecessary both economically and in terms of durability.

In addition, the heating layer 210 of the heating sheet 200 may further include a dispersant to facilitate the dispersion of the carbon nanotubes, there is no particular limitation on the dispersant used, lecithin (lecithin) is particularly desirable. Further, the weight ratio between the carbon nanotubes and the dispersant in the heat generating layer 210 of the heat generating sheet 200 is preferably 1 to 2 parts by weight of antioxidant per 100 parts by weight of carbon nanotubes, if less than 1 part by weight is sufficient to the dispersion effect On the contrary, if the amount is more than 2 parts by weight, the increase of the dispersing effect due to the increase of the amount of the dispersant is insignificant, which is unnecessary both economically and in terms of durability.

Mixing of the thermosetting resin and the carbon nanotubes, and the antioxidants and dispersants for forming the exothermic layer 210 is achieved by dissolving and mixing the components in a suitable solvent, and then applied and dried on the polyimide film 220 The coating layer is formed. The solvent used is not particularly limited as long as it is a substance capable of mixing the above components, but ketone, toluene, butyl cellosolve, N-methyl-2-pyrrolidone (N-Methyl-2-Pyrrolidone, NMP) and It is preferable to select from the group which consists of the mixture.

Meanwhile, the heating layer 210 of the heating sheet 200 may be coated on the polyimide film 220 in a form spaced apart from two opposite sides of the polyimide film 220 as shown in FIG. 7. However, it may be divided into a conductive portion 212 that is responsible for the flow of current and a heating portion 214 that is responsible for heat generation.

Specifically, as shown in FIG. 8, the heat generating layer 210 is provided with a pair of conductive parts 212 spaced apart from two sides facing each other of the heat generating sheet 200 and formed side by side on the two sides; And a heating unit 214 disposed between the pair of conductive units 212 and connecting the conductive units 212 to each other.

Although the thickness of the conductive part 212 of the heating layer 210 may be the same as the heating part 214 as shown in FIG. 7, the thickness of the conductive part 212 is higher than that of the heating part 214 to lower the resistance and increase the conductivity to increase the electrical conduction efficiency. It is preferable that the thickness is 1-100 micrometers. If the thickness of the conductive portion 212 is less than 1 μm, the conduction efficiency is lowered and peeling or breaking of the heat generating layer 210 is likely to occur.

The thickness of the heat generating layer 210 of the heat generating part 214 is preferably formed to increase the heat generation amount, the thickness is preferably 1 to 50 ㎛. When the thickness of the heat generating part 214 is less than 1 μm, the conduction efficiency is too low, the efficiency is low, and the peeling or breaking of the heat generating layer 210 is likely to occur.

In addition, the width of the conductive portion 212 may be selected according to the size of the polyethylene pipe 400 to be bonded, preferably 1 to 200 mm.

Meanwhile, when the size of the heat generating sheet 200 increases, the conductive part 212 extends a part of the conductive part 212 as shown in FIG. 10 to increase the conduction efficiency of the conductive part 212. May be connected to a portion of the If the polyethylene pipe 400 to be bonded is large, the heating sheet 200 should also be large. If the conductive parts 212 are separated from each other, electrical conduction through the heat generating part 214 having high resistance may not be smooth. In this case, when the conductive parts 212 are connected to each other by the conductive parts 212 like a ladder, as shown in FIG. 10, electrical conduction can be stably performed.

In addition, when the polyethylene pipe 400 to be bonded to the heat generating part 214 is small, the heat generating sheet 200 also becomes small, and as a result, a relatively large current flows in a small area, and thus the temperature may increase rapidly. In this case, for proper temperature control, as shown in FIG. 9, it is preferable to form an empty space in the middle of the heat generating layer 210 so as to appropriately control the temperature rise. 214 may be provided with 1 to 100.

After the protective film 500 is wrapped with the heating sheet 200, the power supply 250 is connected to the heating layer 210 of the heating sheet 200, specifically, the conductive part 212 as shown in FIG. It supplies heat. The supplied electricity heats the heat generating layer 210, and the heat generated therein is rapidly bonded to the bonded particles 130 by the carbon nanotubes included in the heat transfer layer 110 and the bonded particles 130 of the polyethylene pipe bonding material 100. And to the polyethylene of the pouch 120 and further to the adjacent polyethylene pipe 400 to melt the polyethylene and their melt to fill the gap between the polyethylene pipe 400 to be bonded.

After the polyethylene melt is completely filled with the gap between the polyethylene pipes 400 to be joined, the electricity supply to the heating sheet 200 is stopped, and the molten pipe bonding material 100 and the adjacent polyethylene pipes 400 are cooled. After the removal, the bonding of the polyethylene pipe 400 is completed by removing the heating sheet 200 and the protective film 500.

In addition, the polyethylene pipe joining method of the present invention, after inserting the pipe joining material 100 in the interval between the polyethylene pipe 400, one or several times between the appropriate time point before the cooling is completed, the cooled after the melting It is preferred to have a step of adjusting the spacing between the polyethylene pipes 400 such that the outer diameter of the pipe joint 100 is 95 to 120% of the outer diameter of the polyethylene pipe 400. Through this, the joint of the pipe can be secured to a reliable level. If the outer diameter of the cooled pipe joint 100 after melting is less than 95% of the outer diameter of the polyethylene pipe 400, the durability of the connection is not preferable, Excessive use in excess of 120% is inefficient because it unnecessarily increases the amount of pipe joint 100 to be melted.

Furthermore, the polyethylene pipe bonding method of the present invention after wrapping the protective film 500 with the heat generating sheet 200, in order to prevent unnecessary heat loss of the heat generating sheet 200, as shown in FIG. More preferably).

On the other hand, the carbon nanotubes included in the heat transfer layer 110 of the pipe bonding material 100, the carbon nanotubes included in the bonding particles 130 of the pipe bonding material 100 and the heat generating layer (200) Carbon nanotubes included in 210 are not limited as long as they can promote heat transfer, and may be independently selected from the group consisting of single-walled carbon nanotubes, double-walled carbon nanotubes, multi-walled carbon nanotubes, and mixtures thereof. have.

EMBODIMENT OF THE INVENTION Hereinafter, the Example of this invention is described.

실시예Example

Example: Bonding of Polyethylene Pipes

A pair of polyethylene pipes having an outer diameter of 60 mm, an inner diameter of 40 mm, and a length of 1 m was inserted at both ends of the connecting pipe having an outer diameter of 40 mm, an inner diameter of 30 mm, and a length of 60 mm with a distance of 7 mm. Polyvinyl chloride resin: multi-walled carbon nanotubes = 90: 10 wt% heat transfer layer, polyethylene: single-walled and double-walled carbon nanotube mixture = 90: containing a sealed polyethylene pouch filled with 10 wt% of the bonded particles Pipe joints were sandwiched in the gaps between the polyethylene pipes. Here, the heat-sealing sheet is formed of a 100 mm wide polyimide protective film to surround the pipe joint and the adjacent polyethylene pipe, and the conductive sheet and the heat generating portion are formed on the polyimide film having a width of 80 mm thereon. Wrapped to contact the protective film. The pipe joint and the adjacent polyethylene pipe were melted by covering the heating sheet with a separate cover and then supplying 220 V of electricity to raise the temperature to 200 ° C. and heating for 10 minutes. The electricity supply was stopped, the molten pipe joint and the adjacent polyethylene pipe were condensed, and then the cover, the heating sheet and the protective film were removed to complete the joining of the polyethylene pipe. In order to evaluate the degree of bonding of the junction, the test was carried out for 10 minutes at a water pressure of 5 kg _f / cm ² it was confirmed that no leakage occurs.

In the above description of the preferred embodiment of the present invention, the present invention is not limited to the specific embodiments described above, those skilled in the art various modifications without departing from the gist of the present invention Of course it is possible. Therefore, the scope of the present invention should not be construed as being limited to the above embodiments, but should be defined by the claims below and equivalents thereof.

[Description of the code]

100: pipe bonding material 110: heat transfer layer

120: sealed pouch 130: bonded particles

200: heating sheet 210: heating layer

212: conductive portion 214: heat generating portion

220: polyimide film 250: power

300: connection pipe 400: polyethylene pipe

500: protective film 600: cover

Claims

Hermetically sealed pouches made of polyethylene film;

A heat transfer layer coating an outer surface of the sealed pouch and including carbon nanotubes and a thermoplastic resin; And

Filling the inside of the sealed pouch, the bonding particles containing carbon nanotubes and polyethylene

Pipe joint material comprising a.
The method according to claim 1,

The thermoplastic resin included in the heat transfer layer of the pipe joint is selected from the group consisting of vinyl resin, acrylic resin, polyamide, polyester, polyether and mixtures thereof.
The method according to claim 1,

Polyethylene pipe bonding material, characterized in that the heat transfer layer thickness of the pipe bonding material is 0.1 to 5 ㎛.
The method according to claim 1,

The weight ratio of the carbon nanotubes and the thermoplastic resin in the heat transfer layer of the pipe bonding material is carbon nanotubes: thermoplastic resin = 0.1 to 60: 40 to 99.9% by weight, polyethylene pipe bonding material.
The method according to claim 1,

The weight ratio of carbon nanotubes to polyethylene in the bonding particles of the pipe bonding material is carbon nanotubes: polyethylene = 0.1 to 30: polyethylene pipe bonding material, characterized in that 70 to 99.9% by weight.
(A) Fit each pair of polyethylene pipes to be joined to both ends of the connecting pipe, wherein the outer surface of the connecting pipe is in close contact with the inner surface of the polyethylene pipe to be joined, and the spacing between the polyethylene pipes is 20 to 100 of the thickness of the polyethylene pipe. % Phosphorus step;

(B) inserting the polyethylene pipe joint of any one of claims 1 to 5 into a gap between the polyethylene pipes;

(C) wrapping the pipe joint and the adjacent polyethylene pipe outer surface with a protective film;

(D) wrapping the protective film with a heating sheet coated with a heating layer including a thermosetting resin and carbon nanotubes on one surface of the polyimide film, wherein the heating layer is wrapped in contact with the protective film;

(E) supplying electricity to the heat generating layer of the heat generating sheet to generate heat, thereby melting the pipe joint and the adjacent polyethylene pipe to fill a gap between the polyethylene pipes;

(F) discontinuing the supply of electricity to the heating sheet and cooling the molten pipe joint and the adjacent polyethylene pipe; And

(G) removing the heating sheet and the protective film

Polyethylene pipe bonding method comprising a.
The method according to claim 6,

After step (B) and before step (G), further comprising adjusting the gap between the polyethylene pipes such that the outer diameter of the cooled and melted polyethylene pipe joint is 95 to 120% of the outside diameter of the polyethylene pipe. Polyethylene pipe bonding method characterized in that.
The method according to claim 6,

After the step (D) and before the step (E), the polyethylene pipe bonding method further comprising the step of covering the heating sheet with a cover.
The method according to claim 6,

Carbon nanotubes included in the heat transfer layer of the pipe bonding material, carbon nanotubes included in the bonding particles of the pipe bonding material and carbon nanotubes included in the heating layer of the heating sheet are independently of each other, single-walled carbon nanotubes, double wall A polyethylene pipe joining method, characterized in that selected from the group consisting of carbon nanotubes, multi-walled carbon nanotubes and mixtures thereof.
The method according to claim 6,

Polyethylene pipe joining method, characterized in that the temperature of the pipe bonding material melted in the step (D) is 130 to 270 ℃.
The method according to claim 6,

The inner diameter of the connecting pipe is polyethylene pipe joining method characterized in that it increases toward both ends.
The method according to claim 6,

The heating layer of the heating sheet,

A pair of conductive parts spaced apart from two opposite sides of the heating sheet and formed in parallel to the two sides; And

A heating unit disposed between the pair of conductive units and connecting the conductive units to each other

Polyethylene pipe joining method comprising a.
The polyethylene pipe bonding material used for the polyethylene pipe joining method of any one of Claims 6-12.
The connection pipe used for the polyethylene pipe joining method of any one of Claims 6-12.
The heat generating sheet used for the polyethylene pipe joining method of any one of Claims 6-12.