WO2012122026A2

WO2012122026A2 - In situ catalytic upgrading

Info

Publication number: WO2012122026A2
Application number: PCT/US2012/027520
Authority: WO
Inventors: Wayne Reid DREHER; Joe D. Allison; Wendell P. Menard; Thomas J. Wheeler
Original assignee: Conocophillips Company
Priority date: 2011-03-09
Filing date: 2012-03-02
Publication date: 2012-09-13
Also published as: US20120227966A1; CA2829066A1; WO2012122026A3; CA2829066C

Abstract

A system and method for in situ upgrading of crude oil is provided. The system includes at least one injection well, at least two first production wells, and at least one second production well. The at least one injection well has a vertical portion and a plurality of non-vertical portions connected to the vertical portion. The at least two first production wells are preferably equi-spaced and each has a horizontal portion with a first axial direction, wherein each said horizontal portion of the first production wells is horizontally spaced apart. The at least one second production well has a horizontal portion with a second axial direction. The catalytic reactor is placed at the horizontal portion of the at least one second production well such that oil coming through the second production well will first go through the catalytic reactor for hydroprocessing.

Description

IN SITU CATALYTIC UPGRADING

CROSS-REFERENCE TO RELATED APPLICATIONS

[0001] This application is a PCT International application which claims the benefit of and priority to U.S. Provisional Application Ser. No. 61/450,872 filed March 9, 2011 and U.S. Application Serial No. 13/410,891 filed March 2, 2012, entitled "In Situ Catalytic Upgrading," both of which are hereby incorporated by reference.

FEDERALLY SPONSORED RESEARCH STATEMENT

[0001] Not applicable.

FIELD OF THE INVENTION

[0002] The invention relates to in situ hydrocarbon upgrading system and method, and more particularly to an in situ oil upgrading for upgrading the crude oil before production.

BACKGROUND OF THE INVENTION

[0003] Heavy oils such as bitumen and oil sands can be very difficult to access due to their high viscosity. In situ upgrading is an enhanced recovery technique that aims to upgrade heavy crude oil and bitumen while still within the subsurface of the earth, making the hydrocarbons easier to produce and transport. Attempts have been made to address this challenge by using in situ combustion approaches, solvent extraction, radio frequency (including microwave radiation) heating, and thermal resistive heating. Although each of these attempts has shown some technical merit, no method currently exists which addresses all of the requirements of a commercially viable process.

[0004] In situ upgrading has also been attempted by using a solvent process known as "Vapex." In this approach, a solvent mobilizes the oil by decreasing its viscosity through a dissolution effect. During this process, asphaltenes, heteroatoms, and heavy metals may precipitate, resulting in upgraded oil. Solvent to oil ratios are high, however, and make this process economically unfeasible. In addition, as larger molecules precipitate, flocculation may occur which may lead to the clogging of the producing well.

[0005] A similar approach has been to simply use a catalyst bed around the producer well in a modified toe to heel air injection (THAI) process. This approach is limited to the amount of upgrading that may occur and does not utilize hydrogen.

[0006] Although the prior art methods have achieved success, they could be further improved with novel combinations of techniques and/or novel well configurations, to further increase production and/or decreases production costs. Thus, what is needed in the art are improved, cost effective methods of in situ upgrading of hydrocarbon deposits.

SUMMARY OF THE INVENTION

[0007] The use of the word "a" or "an" when used in conjunction with the term

"comprising" in the claims or the specification means one or more than one, unless the context dictates otherwise.

[0008] The term "about" means the stated value plus or minus the margin of error of measurement or plus or minus 10% if no method of measurement is indicated.

[0009] The use of the term "or" in the claims is used to mean "and/or" unless explicitly indicated to refer to alternatives only or if the alternatives are mutually exclusive.

[0010] The terms "comprise", "have", "include" and "contain" (and their variants) are open-ended linking verbs and allow the addition of other elements when used in a claim.

[0011] The following abbreviations are used herein:

[0012] As used herein a "Fishbone" configuration is defined as a well having an initially vertical portion and a plurality of non-vertical, deviated portions connected to the vertical portion and extending in the oil reservoir. The non-vertical portions of a Fishbone well can further progress through the reservoir at angles different from the original angle.

[0013] As used herein, "in situ upgrading" refers to a system and/or process that upgrades crude oil, i.e. hydro-cracks the heavy oil, prior to production. In other words, the process occurs inside the ground or hydrocarbon reservoir.

[0014] The objective of the present invention is to upgrade mobilized oil within a reservoir prior to production of the oil to the surface. Generally speaking the invention requires pushing fluid through a reservoir, the lighter components of which then escape laterally through production wells. The heavier components sink to a lower horizontal production well, where it optionally filters through porous catalysts contained in the wellbore, thus being upgraded before production. The unique placement of the injector and producer wells optimizes production in this method.

[0015] In preferred embodiments, the present invention utilizes an injection well having a Fishbone configuration that facilitates the moving of a combustion front in the reservoir. In addition, by using two production wells having equi-spaced (parallel if only two) horizontal portions and another production well having a lower, but perpendicular horizontal portion, the mobilized oil can be more easily drained and produced through the lower production well, while gases escape through the higher production wells. In situ upgrading of the crude oil is realized by adding the catalytic reactor to the lower but perpendicular horizontal portion of the production well, so that the oil taken in the production well will first undergo hydro-processing in the catalytic reactor to further increase the mobility and quality of the oil. If desired, this lower portion can also be equipped with heaters to reduce oil viscosity and/or drive the catalytic reactions.

[0016] According to one aspect of the present invention, there is provided a system for in situ upgrading crude oil within an oil reservoir prior to production. The system includes at least one injection well, at least two first production wells, and at least one second production well. The at least one injection well has a vertical portion and a plurality of non- vertical portions connected to the vertical portion. The two first production wells are parallel to each other (but are roughly equi-spaced if more than two), and each has a horizontal portion with a first axial direction, wherein each said horizontal portion of the first production wells is horizontally spaced apart.

[0017] The at least one second production well has a horizontal portion with a second axial direction. The catalytic reactor is placed at the horizontal portion of the at least one second production well such that oil coming through the second production well will first go through the catalytic reactor for hydro-processing. Preferably, the horizontal portion of the at least one second production well is vertically lower than the horizontal portion of the at least two first production wells to ensure better oil drainage and production. Preferably, the first axial direction of the first production wells is substantially perpendicular to the second axial direction of the second production well (or equi-spaced if more than two).

[0018] Of course, additional production wells can be used and the placement varied accordingly. Furthermore, when we refer to placement, the placement need not be exact, but can vary according to convenience, depending on surface structures or subsurface impediments. Thus, the placement of parallel or perpendicular wells, etc. is only a rough description.

[0019] In one embodiment, the catalytic reactor comprises a catalyst bed, a fluid inlet for introducing the fluid required for upgrading, and a plurality of slots for taking in the crude oil. In another embodiment, the catalytic reactor comprises a catalyst bed, a gas inlet, a plurality of slots for taking in the crude oil, and heaters for heating the reactor and/or the oil so as to facilitate the required temperatures necessary to upgrade the oil. In some embodiments, the heaters can be thermal resistive heaters, but other heating methods can also be used.

[0020] In one embodiment, the catalytic bed comprises hydro-processing catalysts. Examples of the hydro-processing catalysts include, but not limited to, metal sulfides, metal carbides, refractory type metal compounds or the combination thereof. The metal sulfides may include MoS₂, WS₂, CoMoS, NiMoS, or combinations thereof. The metal carbides can include Mo₂C, WC, or combinations thereof. In another embodiment, the refractory type metal compound includes phosphosides, nitrides or borides of transition metals. In yet another embodiment, the refractory type metal compound includes hydrogenation catalysts such as Co₂P, Ni₂P, MoP, WP, NiMoP or Mo₂N, Co₄N, Fe₃N, W₂N or MoB, WB, Ni₂B, Co₂B, or the combination thereof, with optional support such as A1₂0₃, Ti0₂, MgO, Si0₂ and the combination thereof.

[0021] The injection well, especially the non-vertical portions, may progress within the oil reservoir to any place depending on the need and technological limitations, except that preferably it does not extend deeper than 5 meters above the bottom of the pay.

[0022] According to another aspect of the present invention, there is provided a method for in situ upgrading crude oil within an oil reservoir prior to production. The method comprises the following steps: providing an injection well within the oil reservoir, the injection well having a vertical portion and a plurality of non-vertical portions connected to the vertical portion; providing at least two first production wells each having a horizontal portion with a first axial direction, wherein each said horizontal portion of the first production wells being horizontally spaced apart; providing at least one second production well having a horizontal portion with a second axial direction, wherein the horizontal portion of the at least one second production well being vertically lower than the horizontal portion of the at least two first production wells, the first axial direction being substantially perpendicular to the second axial direction, and a catalytic reactor being attached to the horizontal portion of the second production well; performing cyclic steam stimulation to heat the oil deposit with the oil reservoir; injecting a combustion agent into the injection well; and producing crude oil from the at least one second production well.

[0023] In a preferred embodiment, the method further comprises the step of introducing hydrogen through the gas inlet to the catalytic reactor.

[0024] In another embodiment, the combustion agent is selected from oxygen, oxygen-enriched air, or the combination thereof, although plain air and oxygen-depleted air are also applicable when the exotherm is large. In addition, chemical oxidants such as H₂0₂ or 0₃, or other organic and inorganic peroxides may also be used. BRIEF DESCRIPTION OF THE DRAWINGS

[0025] FIG. 1 is a schematic view showing the Fishbone configuration of the injection well of the present invention.

[0026] FIG. 2 is a gas saturation contour for the slice of the reservoir where the

Producers 1 and 3 of Fig. 1 are situated.

[0027] FIG. 3 is a gas saturation contour for the slice of the reservoir where the

Producer 2 of Fig. 1 is situated.

[0028] FIG. 4 is a schematic view showing the Fishbone configuration of the injection well of the present invention, where the lower well bore is equipped with a reactor for catalytic upgrading of hydrocarbons.

[0029] FIG. 5 is a cross-sectional view of one embodiment of the reactor/producer 2 shown in Fig. 4.

[0030] FIG. 6 is a cross-sectional view of an alternative embodiment of the reactor/producer 2 shown in Fig. 4.

DESCRIPTION OF EMBODIMENTS OF THE INVENTION

[0031] The present invention utilizes a novel well-configuration to facilitate the application of in situ combustion in a bitumen and/or heavy oil reservoir and offers a novel approach for upgrading the bitumen and/or heavy oil prior to surface production. The well configuration of interest is a fishbone well configuration as shown in Fig. 1.

[0032] At the beginning, wells are drilled in a fishbone pattern. A single vertical well from the surface can facilitate this drilling. Multiple wells at angles varying from 30 to 120 degree from vertical will be drilled into the reservoir from the single vertical well. Additionally, these vertically deviated wells may progress through the reservoir at angles that differ from the original angle. This will facilitate the best placement of the well within the reservoir. These wells will be placed anywhere within the reservoir with the exception that the lowest well should be at least five (5) meters above the bottom of the pay. In addition, this process requires the use of three producer wells that will be completed through the use of horizontal drilling technologies. These horizontal wells can be placed near or at the base of the reservoir pay zone, where at least one or more producers are arranged perpendicular (or roughly equi-spaced depending on how many are used) to one or more producer wells situated vertically beneath the other well pairs. In Fig. 1, this process is facilitated by two producer wells above a single, perpendicular producer well.

[0033] Once the wells have been placed within the reservoir, they will be used in a primary or preliminary recovery method known as cyclic steam stimulation (CSS) or similar technique. This process will facilitate the heating of the reservoir and preliminary recovery of oil. Once the pay between the wells has been heated (> 80°C), the CSS processes can be shut in. The main objective for the CSS process is to condition the reservoir by lowering the viscosity to a level that allows for fluid communication prior to the initiation of an in situ combustion process. CSS is a technology known to a skilled artisan in the field, and will not be elaborated here.

[0034] Once CSS operations are completed, the Fishbone well setup will now be used as injector wells for the introduction of combustion agent, for example oxygen or oxygen enriched air, into the formation. The major driver for the recovery of oil through the combustion process will be gravity drainage. In the present specification, "gravity drainage" refers to a recovery mechanism in which the oil is pushed or displaced into the production well by the force of gravity.

[0035] For example, as the combustion agent propagates from the Fishbone injector wells into the formation, oil and combustion gas products will drain to the base of the reservoir. The unique aspect of this well pair arrangement for the in situ combustion process is that it facilitates the ability to produce oil and gas products from separate wells. This phenomenon aides in the overall process by removing gas products from the reservoir, which allows the oil to flow more freely to the bottom of the reservoir where it can be produced by Producer 2 well in Fig. 1. [0036] Simulation results are shown in Fig. 2 to illustrate this effect. Fig. 2 is a gas saturation contour for the slice of the reservoir where Producers 1 and 3 are situated, and gravity segregation of products is shown. As shown in the figure, there is a high accumulation of gas present in this region. In other words, gas can be produced from a dedicated gas producer that allows oil to more freely flow to the base of the reservoir for production. Gas production profiles can further illustrate this effect by illustrating the majority of the gas being produced by Producers 1 and 3.

[0037] Fig. 3 is a gas saturation profile for the bottom of the reservoir where

Producer 2 is situated. As shown, it is clear that a segregation has occurred in the reservoir where higher saturations of gas exist and are being produced in the region above the area where Producer 2 is located. Conversely to this, a similar plot for oil saturation would show that the majority of the oil is draining to the bottom of the reservoir and being produced by Producer 2. For this process, oil is expected and can be shown to be produced by Producers 1 and 3, but this production was early in the cycle of the process and largely due to oil being present around the producer wells prior to initiating the process. Once this oil was produced, the main recovery mechanism was gravity drainage to the bottom of the reservoir.

[0038] An extension of the above mentioned process is that the fluid separation and gravity drainage mechanisms consistent with this approach offer a unique opportunity to upgrade bitumen and heavy oil subsurface.

[0039] Fig. 4 illustrates a modification to the Fishbone process that enables in situ upgrading. As shown, Producer 2 now utilizes an upgrading reactor. Ultimately, heated mobile oil will drain through the slotted liner and into the producer/reactor, which is packed with a catalyst bed. Specific catalysts that facilitate upgrading for the process will ideally be less susceptible to poisoning by sulfur species, water oxidation, nitrogen or heavy metal poisoning or other forms of potential transition metal catalyst poisoning.

[0040] Some examples of possible hydro-processing catalysts that may be applicable are metal sulfides (MoS₂, WS₂, CoMoS, NiMoS, etc.), metal carbides (MoC, WC, etc.) or other refractory type metal compounds such as metal phosphides, borides, etc. The refractory type metal compound includes phosphosides, nitrides or borides of transition metals. In one embodiment, the refractory type metal compound includes hydrogenation catalysts such as Co₂P, Ni₂P, MoP, WP, NiMoP or Mo₂N, Co₄N, Fe₃N, W₂N or MoB, WB, Ni₂B, Co₂B, or the combination thereof, with optional support such as A1₂0₃, Ti0₂, MgO, Si0₂ and the combination thereof. It is not anticipated that reduced metal catalysts will remain active for a long period of time in this application.

[0041] Typical hydro-processing reactions will consist of impurity removal processes, such as the removal of sulfur, nitrogen and metals. This can improve the ultimate quality of the crude. Hydrogen assisted removal of oxygen can lower the acid number of the crude. Reduction of aromatics will produce "lighter" hydrocarbons thus lowering the API gravity of the crudes. Potential hydrocracking/isomerization reactions can provide lower carbon number branched hydrocarbons and will improve a lower viscosity crude. It is expected that some combination of all the above reactions will be realized thus giving an improved quality and less viscous crude oil.

[0042] Fig. 5 is a cross-sectional view of the reactor/producer well. As shown, hydrogen can be injected into the reactor/producer well by using straight or even coiled tubing. Hydro-processing reactions of the type expected (desulfurization, olefin and aromatic saturation, hydrocracking) can occur between hydrogen pressures of 50 psi to several thousand psi H₂. It is anticipated to provide H₂ at as high of partial pressure as feasible. This can be from between 50 and 1200 psi H₂ and preferably between 600 to 800 psi H₂. Ultimate hydrogen pressure in practice will be determined via experimental testing.

[0043] The space velocity of the hydrocarbon in the catalyst/hydrogen zone should be between 0.05 to 1.0 hr^-1 or more preferably between 0.2 and 0.5 hr ¹. The unique aspect of this approach is that the hydrogen will be sufficiently separated from the high temperatures of the combustion front due to the fact that the main recovery mechanism is gravity separation. The producer tubing is placed vertically near the bottom of the reactor/producer, which promotes increased contact with the catalyst and hydrogen prior to production.

[0044] In a separate embodiment of this invention, thermal resistive heaters may be incorporated within the reactor/producer wells to facilitate the required temperatures necessary to upgrade the oil prior to production. An example of this is shown in Fig. 6. Other heating mechanisms can also be used.

[0045] An advantage of this invention is that it allows for oils to contact catalyst and hydrogen at required upgrading temperatures prior to being produced. As the oil is upgraded, the viscosity will be further reduced which will lead to an increase in the overall recovery of the oil and limit or eliminate surface processing. Also, the present invention allows for the successful, both technically and economically, implementation of in situ combustion.

[0046] The foregoing description of the present invention is exemplary only, and other variation of the present invention can be readily contemplated by a person having ordinary skill in the art based on the teaching of the specification without deviating from the spirit of the present invention. The foregoing description is intended to be illustrative only, and not unduly limit the scope of the appended claims.

[0047] What is claimed is:

Claims

1. A system for in situ upgrading crude oil within an oil reservoir prior to production, comprising: at least one injection well having a vertical portion and a plurality of non-vertical portions connected to the vertical portion;

at least two first production wells parallel to each other and each having a horizontal portion with a first axial direction, wherein each said horizontal portion of the first production wells being horizontally spaced apart;

at least one second production well having a horizontal portion with a second axial direction; and

a catalytic reactor placed at the horizontal portion of the at least one second production well;

wherein the horizontal portion of the at least one second production well is vertically lower than the horizontal portion of the at least two first production wells; the first axial direction is substantially perpendicular to the second axial direction or are substantially equi-spaced if more than two.

2. The system of claim 1, wherein the catalytic reactor comprises a catalyst bed, a gas inlet and a plurality of slots for taking in crude oil.

3. The system of claim 1, wherein the catalytic bed comprises hydro-processing catalysts.

4. The system of claim 2, wherein the hydro-processing catalysts are selected from the group consisting of metal sulfides, metal carbides, refractory type metal compounds, and combination thereof.

5. The system of claim 3, wherein the metal sulfides are selected from the group consisting of MoS₂, WS₂, C0M0S, NiMoS, and combination thereof.

6. The system of claim 3, wherein the metal carbides are selected from the group consisting of MoC, WC, and combinations thereof.

7. The system of claim 3, wherein the refractory type metal compounds are selected from the group consisting of phosphosides, nitrides and borides of transition metals.

8. The system of claim 6, wherein the refractory type metal compounds are selected from the group consisting of Co₂P, Ni₂P, MoP, WP, NiMoP, Mo₂N, Co₄N, Fe₃N, W₂N, MoB, WB, Ni₂B, Co₂B, and combinations thereof.

9. The system of claim 1, wherein the injection well extends within the oil reservoir until at least 5 meters above the bottom of the reservoir.

10. The system of claim 1, wherein the catalytic reactor further comprises at least one heater for heating the catalyst bed.

11. A method of in-situ upgrading crude oil within an oil reservoir prior to production, comprising: providing an injection well within the oil reservoir, the injection well having a vertical portion and a plurality of non-vertical portions connected to the vertical portion; providing at least two first production wells each having a horizontal portion with a first axial direction, wherein each said horizontal portion of the first production wells being horizontally spaced apart;

providing at least one second production well having a horizontal portion with a second axial direction, wherein a catalytic reactor being placed at the horizontal portion of the second production well, the horizontal portion of the at least one second production well being vertically lower than the horizontal portion of the at least two first production wells, and the first axial direction being substantially perpendicular to the second axial direction or are substantially equi- spaced if more than two;

performing steam stimulation to heat the oil deposit with the oil reservoir;

injecting a combustion agent into the injection well; and

producing crude oil from the at least one second production well.

12. The method of claim 10, wherein the catalytic reactor comprises a catalyst bed, a gas inlet, and a plurality of slots for taking in the crude oil.

13. The method of claim 11, wherein the catalytic bed comprises hydro-processing catalysts.

14. The method of claim 12, wherein the hydro-processing catalysts include metal sulfides, metal carbides, refractory type metal compounds, or combinations thereof.

15. The method of claim 13, wherein the metal sulfides are selected from the group consisting of MoS₂, Ws₂, CoMoS, NiMoS, and combinations thereof.

16. The method of claim 13, wherein the metal carbides are selected from the group consisting of MoC, WC, and combinations thereof.

17. The method of claim 13, wherein the refractory type metal compounds include phosphosides, nitrides or borides of transition metals.

18. The method of claim 16, wherein the refractory type metal compounds are selected from the group consisting of Co₂P, Ni₂P, MoP, WP, NiMoP, Mo₂N, Co₄N, Fe₃N, W₂N, MoB, WB, Ni₂B, Co₂B, and combinations thereof.

19. The method of claim 11, wherein the catalytic reactor further comprises at least one heater for heating the reactor.

20. The method of claim 10, further comprising the following step: introducing hydrogen through the gas inlet to the catalytic reactor.

21. The system of claim 10, wherein the combustion agent is selected from oxygen, oxygen- enriched air, and the combination thereof.