WO2012115014A1 - Pneumatic transport facility for chlorine bypass dust, and cement kiln exhaust gas treatment system equipped with the facility - Google Patents

Pneumatic transport facility for chlorine bypass dust, and cement kiln exhaust gas treatment system equipped with the facility Download PDF

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Publication number
WO2012115014A1
WO2012115014A1 PCT/JP2012/053866 JP2012053866W WO2012115014A1 WO 2012115014 A1 WO2012115014 A1 WO 2012115014A1 JP 2012053866 W JP2012053866 W JP 2012053866W WO 2012115014 A1 WO2012115014 A1 WO 2012115014A1
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Prior art keywords
dust
tank
air
exhaust gas
pressurized tank
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PCT/JP2012/053866
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French (fr)
Japanese (ja)
Inventor
朝明 西岡
靖雄 柳原
和之 伊藤
俊一 長崎
一平 中島
渡辺 晴夫
小林 稔
Original Assignee
電気化学工業株式会社
デンカエンジニアリング株式会社
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Application filed by 電気化学工業株式会社, デンカエンジニアリング株式会社 filed Critical 電気化学工業株式会社
Priority to CN201280004081.1A priority Critical patent/CN103261114B/en
Publication of WO2012115014A1 publication Critical patent/WO2012115014A1/en

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B7/00Rotary-drum furnaces, i.e. horizontal or slightly inclined
    • F27B7/20Details, accessories, or equipment peculiar to rotary-drum furnaces
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D17/00Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
    • F27D17/008Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases cleaning gases

Definitions

  • the present invention relates to an air transportation facility for chlorine bypass dust.
  • the present invention also relates to a cement kiln exhaust gas treatment system equipped with the chlorine bypass dust pneumatic transportation facility according to the present invention.
  • the exhaust gas from the cement kiln equipment contains volatile components such as alkali chlorides and alkali sulfates. These volatile components are gradually concentrated while circulating between the preheater and the kiln in the cement kiln facility, and are taken into the clinker to adversely affect the quality of the cement and adhere to the inner wall of the preheater as a coating.
  • a part of the exhaust gas is extracted from the volatile component concentration region near the bottom of the cement kiln kiln (Japanese Patent Laid-Open Nos. 9-175847 and 11- No. 35355, JP 2001-335348 A, Japanese Patent No. 4435273, etc.).
  • the volatile component in the extracted exhaust gas solidified by cooling is called chlorine bypass dust.
  • Chlorine bypass dust can be processed with a finishing mill together with cement clinker, etc., but there is a certain distance from the cement kiln to the finishing mill, and it is necessary to transport the chlorine bypass dust to there.
  • a conventional method for transporting chlorine bypass dust there is a method in which chlorine bypass dust is extracted from a storage tank near a cement kiln and transported to a storage tank near a finishing mill by a truck (Japanese Patent Laid-Open No. 2000-354838).
  • Japanese Patent Laid-Open No. 2000-354838 Japanese Patent Laid-Open No. 2000-354838
  • the present invention has been made in view of the above circumstances, and eliminates the need for truck transportation to the finish mill of chlorine bypass dust, while reducing piping blockage in the process of transporting chlorine bypass dust by a method different from slurrying. It is an object of the present invention to provide a chlorine bypass dust transport facility that can be used. Moreover, this invention makes it a subject to provide the processing system of the cement kiln exhaust gas provided with the transport equipment of the said chlorine bypass dust.
  • the present inventor has intensively studied to solve the above problems, and found that it is effective to pneumatically transport dehumidified dry air having a predetermined dew point without discharging chlorine bypass dust out of the system. Based on this, the following invention was created.
  • a first dust collecting tank having a cement kiln exhaust gas inlet and outlet, a dust collector for collecting dust from the cement kiln exhaust gas, and a collected dust outlet;
  • a pressurized tank having a dust inlet from the first dust collection tank, an air inlet, and a dust air outlet, and for pneumatically transporting the dust by compressed air; provided that the first dust The dust outlet in the collection tank is above the dust inlet in the pressurized tank, and both are communicated by a first pipe.
  • An air supply source for supplying dry compressed air having an atmospheric dew point of ⁇ 35 ° C.
  • the exhaust gas flowing into the cement kiln exhaust gas of the first dust collection tank has an atmospheric dew point of 10 to 40 ° C. and a temperature of 50 to 150 ° C. Previously dehumidified and cooled.
  • the air supply source includes an adsorption air dryer or a heatless air dryer.
  • the gas temperature in the pressurized tank is 0 to 40 ° C.
  • the pneumatic transportation equipment is still another embodiment, Pressure switch to monitor the pressure in the pressurized tank, A level switch for monitoring the amount of dust in the pressurized tank; and When the level switch detects that the amount of dust in the pressurized tank has reached a predetermined level, the supply of dust from the first dust collection tank to the pressurized tank is stopped, and the pressurized tank is dried.
  • the pressure switch detects that the pressure has been increased by air and increased to a predetermined pressure, it starts air transportation of dust to the second dust collection tank, and then the pressure switch indicates that the pressure has decreased to the predetermined pressure.
  • the apparatus further includes a control mechanism that stops pneumatic transportation of dust and restarts supply of dust from the first dust collection tank to the pressurized tank.
  • the supply of dust from the first dust collection tank to the pressurized tank is stopped, and then the pressurization from the first dust collection tank is performed.
  • the time until the supply of dust to the tank is restarted is within 10 minutes.
  • dust is passing through the first pipe from the dust outlet in the first dust collecting tank to the dust inlet in the pressurized tank.
  • the dry air flows in the first pipe from the pressurized tank toward the first dust collecting tank at a flow rate that does not flow backward.
  • the pressure in the pressurized tank during pneumatic transportation of dust is 0.1 to 0.5 MPaG.
  • the dust in the pressurized tank flows into the pressurized tank during pneumatic transportation of the dust from the pressurized tank to the second dust collecting tank. Being fluidized by dry air.
  • two or more pressurized tanks are installed in parallel, and at least one of the remaining pressurized tanks during pneumatic transportation is at least one of the pressurized tanks. Dust is put into one pressurized tank from the first dust collection tank.
  • a primary storage tank is installed in series before the pressurized tank, and the first dust collection is performed during the pneumatic transportation of the latter pressurized tank. Dust is thrown from the tank into the primary storage tank.
  • a cement kiln exhaust gas treatment system comprising the pneumatic transportation equipment and the extraction facility for cement kiln exhaust gas according to the present invention described above,
  • the extraction facility for cement kiln exhaust gas includes an extraction pipe for extracting a part of the cement kiln exhaust gas, a blower for supplying air for dehumidification and cooling into the extraction pipe, and a collector connected to the outlet of the extraction pipe.
  • a dust cyclone an air cooler connected to the outlet of the cyclone, a blower for supplying air for dehumidification and cooling into the air cooler, and an induction fan
  • the outlet of the first dust collection tank is connected to the induction fan
  • the second dust collection tank has an outlet for the collected dust, which is in communication with a mill or cement clinker tank for cement production; This is a cement kiln exhaust gas treatment system.
  • the air outlet of the second dust collection tank is connected to the induction fan.
  • the gas flow rate at the outlet of the extraction pipe is set to 10 m / s or more.
  • the chlorine bypass dust is deliquescent during storage or transportation, so that dust adheres to and clogs the container and piping. This makes it possible to pneumatically transport chlorine bypass dust that is practical.
  • FIG. 1 is a cement kiln exhaust gas treatment system according to an embodiment of the present invention.
  • the pneumatic transportation equipment of chlorine bypass dust concerning the present invention, it is a mimetic diagram showing an example at the time of installing a pressurized tank in parallel. It is a schematic diagram which shows an example at the time of installing a primary storage tank in the front
  • the chlorine bypass dust pneumatic transportation facility is, in one embodiment, A first dust collection tank 100 having a cement kiln exhaust gas inlet 101 and outlet 102, a dust collector 103 for collecting dust from the cement kiln exhaust gas, and a collected dust outlet 104; A pressurized tank 200 having a dust inlet 201 from the first dust collection tank 100, an air inlet 202, and a dust air transport outlet 203 for pneumatically transporting the dust by compressed air; The dust outlet 104 in the first dust collection tank 100 is above the dust inlet 201 in the pressurized tank 200, and both are communicated by the first pipe 105.
  • Deliquession is a phenomenon in which when a solid is exposed to the atmosphere, it absorbs water vapor in the atmosphere and dissolves it to create an aqueous solution.
  • the chlorine bypass dust generated by cooling the exhaust gas extracted in the cement manufacturing process generally has potassium chloride (hereinafter referred to as KCl) as a main component.
  • KCl potassium chloride
  • Table 1 shows the storage time dependence of the moisture content of chlorine bypass dust and Portland cement under conditions of room temperature and humidity of 100%. It can be understood how high the deliquescence of chlorine bypass dust is. it can.
  • the cement kiln exhaust gas flows into the first dust collection tank 100 through the inlet 101.
  • the inflowing cement kiln exhaust gas contains chlorine bypass dust, which is collected by the dust collector 103.
  • a dust collector For example, a bag filter, a cyclone, and an electric dust collector are suitable.
  • the exhaust gas after the chlorine bypass dust is collected is discharged from the outlet 102.
  • Cement kiln exhaust gas is generally a high-temperature and high-humidity gas having a temperature of about 900 to 1100 ° C. and an atmospheric dew point of 55 ° C. or higher, typically about 60 to 70 ° C.
  • the dust collector 103 exceeds the durability limit and malfunctions.
  • the chlorine bypass dust to which moisture adheres is deliquescent and is likely to be clogged.
  • the equipment cost jumps and is not realistic.
  • the cement kiln exhaust gas flowing into the inlet 101 is preferably dehumidified in advance so that the atmospheric dew point is 10 to 40 ° C., and more preferably dehumidified to 20 to 30 ° C. . Further, the cement kiln exhaust gas flowing into the inlet 101 is preferably cooled in advance so that the temperature becomes 50 to 150 ° C., and more preferably precooled so that the temperature becomes 60 to 100 ° C. . Further, the relative humidity is preferably less than 100%, more preferably 50% or less, and even more preferably 20% or less.
  • outside air can be utilized as cooling air, and it is practical also from the viewpoint of durability of the dust collector 103 and suppression of deliquescence in the first dust collection tank 100 and the first pipe 105.
  • Lowering the exhaust gas temperature after cooling improves the durability of the bag filter, and it is possible to use an inexpensive product with a low heat-resistant temperature for the bag filter.
  • the temperature is kept by any known means such as covering the periphery of the first dust collection tank 100 with a heat insulating material or installing a heater around it. Or you may heat.
  • the exhaust gas discharged from the cement kiln exhaust gas outlet 102 can be directed to the induction fan 108 through the exhaust pipe 106, for example. After exiting the induction fan 108, it can be exhausted from the chimney after passing through a dryer, a stabilizer, an electric dust collector or the like as necessary.
  • the induction fan 108 it is convenient and economical to use a kiln IDF that attracts most of the exhaust gas from the cement kiln.
  • the kiln IDF is also used in the embodiment according to FIG.
  • a bag filter exhaust fan 107 is preferably installed upstream of the induction fan 108 to collect dust that could not be collected by the dust collector 103, and is also installed in the present embodiment of FIG.
  • the dust collected in the first dust collection tank 100 goes from the outlet 104 to the lower pressurized tank 200 through the first pipe 105.
  • the outlet 104 is preferably provided at the bottom of the first dust collection tank 100 so that the dust collected in the first dust collection tank 100 can be extracted by gravity.
  • the one dust collection tank 100 is preferably formed in a tapered shape or a cone shape that is recessed toward the bottom from the viewpoint of facilitating extraction of dust.
  • the dust outlet 104 in the first dust collection tank 100 above the dust inlet 201 in the pressurized tank 200, the dust discharged from the outlet 104 passes through the first pipe 105 by gravity. Thus, it can fall naturally into the pressurized tank 200.
  • the first pipe 105 communicating the dust inlet 201 and the dust outlet 104 preferably extends in the vertical direction, but may be slightly inclined as long as the dust is smoothly transported.
  • dust is passing through the first pipe 105 from the dust outlet 104 in the first dust collection tank 100 to the dust inlet 201 in the pressurized tank 200.
  • the dry air described later may flow through the first pipe 105 from the pressurized tank 200 toward the first dust collecting tank 100 at a flow rate that does not cause the dust to flow backward.
  • the first pipe 105 may be kept warm or heated.
  • the first pipe 105 can be provided with a valve for controlling the flow of dust.
  • a dust input valve 501 can be provided at or near the dust outlet 104
  • a dust input valve 502 can be provided at or near the dust inlet 201.
  • the pressurized tank 200 stores the dust from the first dust collection tank 100. When a predetermined amount of dust accumulates, it is sealed and pressurized to the pressure necessary for pneumatic transport of the dust, and then the transport valve 504 installed at the dust air transport outlet 203 is opened to collect the dust in the second dust collection. Air transport to tank 400. During transportation, compressed air is introduced from the air inlet 202 into the second dust collection tank 400 through the second pipe 204.
  • This compressed air is supplied from the air supply source 300 to the pressurized tank 200 through the air pipe 303.
  • the air supply source 300 is generally provided with an air compressor 301 using outside air, but is not limited thereto.
  • An air supply valve 503 for controlling the supply of compressed air can be installed in the air pipe 303 between the air supply source 300 and the pressurized tank 200. From the viewpoint of preventing dust deliquescence, air should have as low a dew point as possible. Specifically, it is desirable to use dry air having an atmospheric dew point of ⁇ 35 ° C. or lower.
  • the atmospheric pressure dew point of the compressed air is more preferably ⁇ 40 ° C. or less, still more preferably ⁇ 50 ° C. or less, most preferably ⁇ 60 ° C. or less.
  • the temperature can be 80 ° C to -35 ° C.
  • Such dry air can be obtained by using an air supply source 300 having an air dryer 302 such as an adsorption air dryer or a heatless air dryer.
  • the pressure inside the pressurized tank 200 is adjusted to be 0.1 to 0.5 MPaG.
  • the dust in the pressurized tank 200 is in a fluid state due to the dry air flowing into the pressurized tank 200. Thereby, it is possible to suppress the dust in the pressurized tank 200 from adhering to the inner wall of the pressurized tank 200, and it is possible to reduce the dust remaining in the pressurized tank 200 after pneumatic transportation.
  • an air inlet 202 can be provided at the bottom of the pressurized tank 200. The dust stored in the pressurized tank 200 is fluidized by the compressed air introduced into the pressurized tank 200.
  • Dust is introduced into the second dust collection tank 400 from the inlet 401 by pneumatic transportation.
  • the second dust collection tank 400 has a dust collector 402 for collecting dust and an air outlet 403.
  • a dust collector 402 for collecting dust
  • the air after the dust is collected is discharged from the outlet 403.
  • the air discharged from the outlet 403 may be released to the atmosphere as it is, or may be discharged by providing a dedicated exhaust system.
  • an exhaust pipe 404 may be connected to the outlet 403, and this may be joined to the exhaust pipe 106 of the first dust collection tank 100. This is economical because the exhaust system is integrated.
  • chlorine bypass dust can be stored for a long time while suppressing deliquescence. For example, it can be stored for one week or longer, and preferably can be stored for one month or longer. After the storage period, the dust can be smoothly discharged from the second dust collection tank 400.
  • the discharged dust can be put into a nearby cement manufacturing mill (finishing mill) or a cement clinker tank through a valve such as a rotary valve.
  • the pneumatic transport facility for chlorine bypass dust can include a pressure switch 601 for monitoring the pressure in the pressurized tank 200 and a level switch 602 for monitoring the amount of dust in the pressurized tank 200.
  • a control mechanism for controlling pneumatic transport can be provided.
  • the control mechanism can operate the pneumatic transportation facility in the following procedure.
  • the tank 200 is pressurized with dry air, and when it is detected by the pressure switch 601 that the pressure has risen to a predetermined pressure, the air transportation of dust to the second dust collecting tank 400 is started, and then the pressure is lowered to the predetermined pressure. When this is detected by the pressure switch 601, the pneumatic transportation of dust is stopped, and the supply of dust from the first dust collection tank 100 to the pressurized tank 200 is resumed.
  • FIG. 1 A more detailed operation procedure of the pneumatic transportation facility in the embodiment according to FIG. 1 will be described.
  • the input valve 501, the input valve 502, the air supply valve 503, and the transport valve 504 are closed, first, the input valve 502 and the input valve 501 are opened in order, so that the inside of the first dust collection tank 100. Is started to enter the pressurized tank 200.
  • the level switch 602 detects that the amount of dust in the pressurized tank 200 has reached a predetermined amount
  • the charging source valve 501 and the charging valve 502 are closed in order, so that the addition from the first dust collection tank 100 is performed.
  • the supply of dust to the pressure tank 200 is stopped.
  • the air supply valve 503 is opened, and the inside of the pressurized tank 200 is pressurized with dry air.
  • the transport valve 504 When the pressure switch 601 detects that the pressure has risen to a predetermined pressure, the transport valve 504 is opened and the pneumatic transport of dust to the second dust collection tank 400 is started.
  • the pressure in the pressurized tank 200 decreases rapidly when there is no dust to be transported. Therefore, when the pressure switch 601 detects that the pressure has dropped to a predetermined pressure, the air supply valve and the transport valve are closed in order to stop the air transport of dust. Thereafter, when the input valve 502 and the input source valve 501 are sequentially opened, the input of the dust in the first dust collection tank 100 into the pressurized tank 200 is started again, and the above-described operation is repeated.
  • the dust is accumulated in one dust collecting tank 100.
  • the humidity in the first dust collection tank 100 is relatively high, from the viewpoint of suppressing dust deliquescence, the dust should stay in the first dust collection tank 100 for a long time. Is not preferred. Therefore, after the supply of dust from the first dust collection tank 100 to the pressurized tank 200 is stopped, the supply of dust from the first dust collection tank 100 to the pressurized tank 200 is restarted.
  • the shorter time is desirable, for example, preferably within 10 minutes, and more preferably within 5 minutes. However, if this time is too short, the frequency of opening and closing of the valve increases, which adversely affects the life of the valve. Therefore, it is preferably 1 minute or longer, and typically 2 to 4 minutes.
  • two pressurized tanks 200 are installed in parallel, and dust can be put into the other pressurized tank while one pressurized tank is pneumatically transported.
  • two or more pressurized tanks 200 may be installed in parallel. In that case, while a certain pressurized tank is pneumatically transported, dust is thrown into the remaining pressurized tank from the first dust collection tank.
  • a primary storage tank 205 is installed in series in the front stage of the pressurized tank, and dust is thrown into the primary storage tank 205 in the previous stage while the subsequent pressurized tank 200 is transported by air. When transportation is completed, dust can be put into the pressurized tank from the primary storage tank. By doing in this way, dust can be continuously discharged from the first dust collection tank 100. Dry air similar to that sent to the pressurized tank 200 can be sent to the primary storage tank 205 to keep the inside dry.
  • cement kiln exhaust gas treatment system The above-described chlorine bypass dust pneumatic transportation facility according to the present invention can be combined with a cement kiln exhaust gas extraction facility to constitute a cement kiln exhaust gas treatment system. As a result, a series of steps from recovering chlorine bypass dust from the exhaust gas extracted from the cement kiln and treating it with the finishing mill can be continuously performed by the piping system.
  • the cement kiln exhaust gas treatment system according to the present invention eliminates the need for truck transportation to the finishing mill of chlorine bypass dust, reduces pipe blockage in the transportation process of chlorine bypass dust, and corrodes the water spray nozzle in the finishing mill. In addition, it is possible to reduce the clogging and blockage, and it is possible to pneumatically transport chlorine bypass dust that is practical.
  • a cement kiln exhaust gas treatment system includes, in one embodiment, the above-described chlorine bypass dust pneumatic transportation facility and cement kiln exhaust gas extraction facility according to the present invention, and cement kiln exhaust gas.
  • the extraction equipment is connected to an extraction pipe 702 for extracting a part of the cement kiln exhaust gas, a blower 703 for supplying air for dehumidification and cooling into the extraction pipe 702, and an outlet of the extraction pipe 702.
  • the inlet 101 of the first dust collection tank 100 is in communication with the air cooler 705 and the exhaust pipe 710, and The outlet 102 of the waste collection tank 100 is connected to the induction fan 108 by the exhaust pipe 106, and the second dust collection tank 400 has an outlet 405 of the collected dust, which is used for cement production.
  • a mill or cement clinker tank To a mill or cement clinker tank.
  • the extraction pipe 702 extracts a part of the exhaust gas containing volatile components discharged from the rotary kiln.
  • the exhaust gas is a hot and humid gas as described above.
  • the bleed pipe 702 is generally provided in the middle of a rising duct or a calcining furnace that extends right above the kiln kiln 701. In FIG. 1, air is extracted from the rising duct.
  • a blower 703 is connected to the extraction pipe 702 by a duct, from which air for dehumidification and cooling is pushed into the extraction pipe 702 so as to flow in the direction of the cyclone 704. The introduced air cools and dehumidifies the exhaust gas while mixing with the extracted exhaust gas.
  • the gas flow rate at the outlet of the extraction pipe 702 is preferably 10 m / s or more, for example, 10 to 30 m / s. It can be.
  • the mixed gas of the exhaust gas and the cooling air that has exited the extraction pipe 702 is introduced into the dust collecting cyclone 704 through the exhaust pipe 709, and coarse particles are separated. Thereafter, the mixed gas is mixed with the cooling air pushed by the blower 706 in the air cooler 705 and further cooled. Thereafter, the mixed gas is introduced into the first dust collection tank 100 through the exhaust pipe 710, and the chlorine bypass dust is recovered in the first dust collection tank 100 from the exhaust gas.
  • the amount of air for dehumidification and cooling supplied from the blower 703 and the blower 706 is adjusted so that the temperature and humidity of the cement kiln exhaust gas flowing into the first dust collection tank 100 are within the above-described ranges. That's fine.
  • the operation of the pneumatic transport facility for chlorine bypass dust after the chlorine bypass dust is introduced into the first dust collection tank 100 is as described above.
  • Example 1 The cement kiln exhaust gas treatment system in the embodiment of FIG. 1 was operated for one week under the following operating conditions.
  • the dew points of the cement kiln exhaust gas at the inlet of the extraction pipe 702 and the cement kiln exhaust gas flowing into the inlet 101 were calculated based on JIS Z 8808-1995 by measuring the moisture content in the exhaust gas using a moisture absorption pipe.
  • the dew point of air for cooling and dehumidification and the dew point of air for transportation were measured by a capacitance type temperature and humidity sensor.
  • Example 2 The cement kiln exhaust gas treatment system in the embodiment shown in FIG. 1 was operated for one week in the same manner as in Example 1 except that the operating conditions were changed as follows.
  • ⁇ Operating conditions> (1) Air for cooling and dehumidification: -Outside air (temperature: 2-16 ° C, atmospheric dew point: -5-11 ° C) -Air volume sent from the blower to the extraction pipe 702: 100 [m 3 N / min] -Air flow rate sent from the blower to the cooler 705: 100 [m 3 N / min] (2) Gas flow velocity at the outlet of the extraction pipe 702: 6 m / s (3) Cement kiln exhaust gas flowing into the inlet 101: -Gas temperature: 230-270 ° C -Atmospheric pressure dew point: 43-52 ° C (4) Gas temperature in the pressurized tank 200: 65 to 98 ° C
  • Example 1 The cement kiln exhaust gas treatment system was operated for one week under the same conditions as in Example 1 except that the compressed air was not dried with an air dryer.
  • the atmospheric pressure dew point of the transportation air was ⁇ 5 to 5 ° C.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Treating Waste Gases (AREA)
  • Filtering Of Dispersed Particles In Gases (AREA)

Abstract

Provided is a transport facility for chlorine bypass dust, in which the occurrence of a blockage in a pipe can be reduced during the transport of the chlorine bypass dust. A pneumatic transport facility for dust collected from a cement kiln exhaust gas, comprising: a first dust collection tank which is equipped with an inlet port and a discharge port for a cement kiln exhaust gas, a dust collector for collecting dust from the cement kiln exhaust gas, and a discharge port for the collected dust; a pressurized tank which is equipped with an inlet port for the dust from the first dust collection tank, an inlet port for air and an discharge port for pneumatic transport of the dust and which enables the pneumatic transport of the dust by means of compressed air; an air supply source which supplies dried and compressed air having an atmospheric dew point of -35˚C or lower to the pressurized tank; and a second dust collection tank which is equipped with an inlet port for dust that is pneumatically transported from the pressurized tank through a second pipe, a dust collector for collecting dust, and a discharge port for air.

Description

塩素バイパスダストの空気輸送設備及び当該設備を備えたセメントキルン排ガスの処理システムChlorine bypass dust pneumatic transportation equipment and cement kiln exhaust gas treatment system equipped with the equipment
 本発明は、塩素バイパスダストの空気輸送設備に関する。また、本発明は本発明に係る塩素バイパスダストの空気輸送設備を備えたセメントキルン排ガスの処理システムに関する。 The present invention relates to an air transportation facility for chlorine bypass dust. The present invention also relates to a cement kiln exhaust gas treatment system equipped with the chlorine bypass dust pneumatic transportation facility according to the present invention.
 セメントキルン設備の排ガス中にはアルカリ塩化物やアルカリ硫酸塩などの揮発性成分が含まれている。これらの揮発性成分はセメントキルン設備内でプレヒーターとキルンの間を循環しながら次第に濃縮され、クリンカ中に取り込まれてセメントの品質に悪影響を及ぼすほか、プレヒーター等の内部壁面にコーティングとして付着して、プレヒーター等の内部壁面を閉塞させる原因になる為、セメントキルン窯尻付近の揮発性成分濃縮領域から排ガスを一部抽気している(特開平9-175847号公報、特開平11-35355号公報、特開2001-335348号公報、特許4435273号公報など)。この抽気された排ガス中の揮発性成分が冷却によって固化したものは塩素バイパスダストと呼ばれている。 The exhaust gas from the cement kiln equipment contains volatile components such as alkali chlorides and alkali sulfates. These volatile components are gradually concentrated while circulating between the preheater and the kiln in the cement kiln facility, and are taken into the clinker to adversely affect the quality of the cement and adhere to the inner wall of the preheater as a coating. In order to block the inner wall surface of the preheater or the like, a part of the exhaust gas is extracted from the volatile component concentration region near the bottom of the cement kiln kiln (Japanese Patent Laid-Open Nos. 9-175847 and 11- No. 35355, JP 2001-335348 A, Japanese Patent No. 4435273, etc.). The volatile component in the extracted exhaust gas solidified by cooling is called chlorine bypass dust.
 塩素バイパスダストは、セメントクリンカ等と共に仕上ミルで処理することができるが、セメントキルンから仕上ミルまでは一定の距離があり、塩素バイパスダストをそこまで輸送する必要がある。従来の塩素バイパスダストの輸送方法としては、セメントキルン付近で貯蔵タンクから塩素バイパスダストを抜き出し、トラックで仕上ミル付近の貯蔵タンク迄輸送する方法がある(特開2000-354838号公報)。しかしながら、塩素バイパスダストは潮解性があるので、これら貯蔵タンクの壁面温度が低下すると潮解により配管の閉塞を起こし、塩素バイパスダストが貯蔵タンクから抜き出し難くなるという問題があった。また、特許第3318714号公報には、塩素バイパスダストをセメントキルン系外に排出した後、空気輸送でセメント仕上げミルへ輸送する可能性について記載されているが、塩素バイパスダストは潮解性が高いため、空気輸送中に配管が閉塞することは目に見えており、これまで成功例はない。 Chlorine bypass dust can be processed with a finishing mill together with cement clinker, etc., but there is a certain distance from the cement kiln to the finishing mill, and it is necessary to transport the chlorine bypass dust to there. As a conventional method for transporting chlorine bypass dust, there is a method in which chlorine bypass dust is extracted from a storage tank near a cement kiln and transported to a storage tank near a finishing mill by a truck (Japanese Patent Laid-Open No. 2000-354838). However, since chlorine bypass dust is deliquescent, there is a problem that when the wall surface temperature of these storage tanks is lowered, piping is clogged due to deliquescence, making it difficult to extract chlorine bypass dust from the storage tank. Japanese Patent No. 3318714 describes the possibility of transporting the chlorine bypass dust out of the cement kiln system and then transporting it to the cement finishing mill by pneumatic transport. However, chlorine bypass dust is highly deliquescent. The pipes are clogged during pneumatic transportation, and there has been no success so far.
 これらの閉塞を防止するため、塩素バイパスダストに水を加えてスラリーとし、このスラリーをクリンカ、石膏及び混合材の少なくとも一つと共にセメント製造用のミルで混合する方法が提案されている(特開2000-354838号公報)。当該文献によれば、バイパスガス中のダストの粗粉分離工程を有する装置と組み合わせて適用することにより、スラリー生成量をセメント生産量に対して最大でも1%とすることが可能となることや、この量はクリンカ粉砕時に行うミル内散水量と同等以下であり、セメントの品質には影響を与えないことが記載されている。 In order to prevent these blockages, a method has been proposed in which water is added to chlorine bypass dust to form a slurry, and this slurry is mixed in a cement manufacturing mill together with at least one of clinker, gypsum, and a mixed material (Japanese Patent Application Laid-Open (JP-A)). 2000-354838). According to the literature, by applying in combination with an apparatus having a coarse powder separation step of dust in the bypass gas, it is possible to make the slurry generation amount at most 1% with respect to the cement production amount. It is described that this amount is equal to or less than the amount of water sprayed in the mill at the time of clinker grinding and does not affect the quality of cement.
特開平9-175847号公報Japanese Patent Laid-Open No. 9-175847 特開平11-35355号公報JP-A-11-35355 特開2001-335348号公報JP 2001-335348 A 特許第4435273号公報Japanese Patent No. 4435273 特開2000-354838号公報JP 2000-354838 A 特許第3318714号公報Japanese Patent No. 3318714
 しかしながら、特開2000-354838号公報に記載された塩素バイパスダストをスラリー化する方法だと、ミル内の散水ノズルの腐食や閉塞を起しやすいと考えられる。その結果、ノズルからの散水量制御が困難となり、散水量の変動によるミル出口温度の変動を起しやすく、セメントの品質の変動にも影響を与える懸念が残る。 However, the method of slurrying chlorine bypass dust described in Japanese Patent Application Laid-Open No. 2000-354838 is likely to cause corrosion and blockage of the watering nozzle in the mill. As a result, it becomes difficult to control the amount of water sprayed from the nozzle, and the mill outlet temperature is likely to fluctuate due to fluctuations in the water sprinkling amount.
 本発明は上記事情に鑑みてなされたものであり、塩素バイパスダストの仕上ミルまでのトラック輸送を不要化しつつ、スラリー化とは別の方法で、塩素バイパスダストの輸送過程での配管閉塞を低減することのできる塩素バイパスダストの輸送設備を提供することを課題とする。また、本発明は当該塩素バイパスダストの輸送設備を備えたセメントキルン排ガスの処理システムを提供することを課題とする。 The present invention has been made in view of the above circumstances, and eliminates the need for truck transportation to the finish mill of chlorine bypass dust, while reducing piping blockage in the process of transporting chlorine bypass dust by a method different from slurrying. It is an object of the present invention to provide a chlorine bypass dust transport facility that can be used. Moreover, this invention makes it a subject to provide the processing system of the cement kiln exhaust gas provided with the transport equipment of the said chlorine bypass dust.
 本発明者は上記課題を解決するために鋭意検討したところ、塩素バイパスダストを系外に排出することなく、所定の露点をもつ除湿乾燥空気によって空気輸送することが有効であることを見出し、これに基づいて以下の発明を創作した。 The present inventor has intensively studied to solve the above problems, and found that it is effective to pneumatically transport dehumidified dry air having a predetermined dew point without discharging chlorine bypass dust out of the system. Based on this, the following invention was created.
 本発明は一側面において、
 セメントキルン排ガスの入口及び出口、セメントキルン排ガスからダストを捕集するための集塵機、並びに捕集されたダストの出口を有する第一のダスト捕集タンクと、
 第一のダスト捕集タンクからのダストの入口、空気の入口、及びダストの空気輸送用出口を有し、当該ダストを圧縮空気により空気輸送するための加圧タンクと、ただし、第一のダスト捕集タンクにおけるダストの出口は加圧タンクにおけるダストの入口の上方にあり、両者は第一の配管によって連通されている、
 大気圧露点が-35℃以下の乾燥した圧縮空気を加圧タンクに供給する空気供給源と、
 加圧タンクから第二の配管を通って空気輸送されるダストの入口、ダストを捕集するための集塵機、並びに空気の出口を有する第二のダスト捕集タンクと、
を備えたセメントキルン排ガスから捕集されたダストの空気輸送設備である。
In one aspect of the present invention,
A first dust collecting tank having a cement kiln exhaust gas inlet and outlet, a dust collector for collecting dust from the cement kiln exhaust gas, and a collected dust outlet;
A pressurized tank having a dust inlet from the first dust collection tank, an air inlet, and a dust air outlet, and for pneumatically transporting the dust by compressed air; provided that the first dust The dust outlet in the collection tank is above the dust inlet in the pressurized tank, and both are communicated by a first pipe.
An air supply source for supplying dry compressed air having an atmospheric dew point of −35 ° C. or lower to the pressurized tank;
A dust inlet that is pneumatically transported from the pressurized tank through the second pipe, a dust collector for collecting the dust, and a second dust collection tank having an air outlet;
Is a pneumatic transportation facility for dust collected from cement kiln exhaust gas.
 本発明に係る空気輸送設備は一実施形態において、第一のダスト捕集タンクのセメントキルン排ガスの入口に流入する排ガスは、大気圧露点が10~40℃、温度が50~150℃となるように予め除湿及び冷却されている。 In one embodiment of the pneumatic transportation equipment according to the present invention, the exhaust gas flowing into the cement kiln exhaust gas of the first dust collection tank has an atmospheric dew point of 10 to 40 ° C. and a temperature of 50 to 150 ° C. Previously dehumidified and cooled.
 本発明に係る空気輸送設備は別の一実施形態において、空気供給源は吸着式エアドライヤ又はヒートレス式エアドライヤを有する。 In another embodiment of the pneumatic transportation facility according to the present invention, the air supply source includes an adsorption air dryer or a heatless air dryer.
 本発明に係る空気輸送設備は更に別の一実施形態において、加圧タンク内のガス温度が0~40℃である。 In still another embodiment of the pneumatic transportation facility according to the present invention, the gas temperature in the pressurized tank is 0 to 40 ° C.
 本発明に係る空気輸送設備は更に別の一実施形態において、
 加圧タンク内の圧力を監視する圧力スイッチ、
 加圧タンク内のダスト量を監視するレベルスイッチ、及び、
 加圧タンク内のダスト量が所定量に到達したことがレベルスイッチにより検知されると、第一のダスト捕集タンクからの加圧タンクへのダストの供給を停止し、加圧タンクを前記乾燥空気によって加圧し、所定の圧力に上昇したことが圧力スイッチにより検知されると第二のダスト捕集タンクへのダストの空気輸送を開始し、その後、所定の圧力に下降したことが圧力スイッチにより検知されるとダストの空気輸送を停止して、第一のダスト捕集タンクからの加圧タンクへのダストの供給を再開する制御機構を
更に備える。
The pneumatic transportation equipment according to the present invention is still another embodiment,
Pressure switch to monitor the pressure in the pressurized tank,
A level switch for monitoring the amount of dust in the pressurized tank; and
When the level switch detects that the amount of dust in the pressurized tank has reached a predetermined level, the supply of dust from the first dust collection tank to the pressurized tank is stopped, and the pressurized tank is dried. When the pressure switch detects that the pressure has been increased by air and increased to a predetermined pressure, it starts air transportation of dust to the second dust collection tank, and then the pressure switch indicates that the pressure has decreased to the predetermined pressure. When detected, the apparatus further includes a control mechanism that stops pneumatic transportation of dust and restarts supply of dust from the first dust collection tank to the pressurized tank.
 本発明に係る空気輸送設備は更に別の一実施形態において、第一のダスト捕集タンクからの加圧タンクへのダストの供給を停止してから、第一のダスト捕集タンクからの加圧タンクへのダストの供給を再開するまでの時間が10分以内である。 In still another embodiment of the pneumatic transportation facility according to the present invention, the supply of dust from the first dust collection tank to the pressurized tank is stopped, and then the pressurization from the first dust collection tank is performed. The time until the supply of dust to the tank is restarted is within 10 minutes.
 本発明に係る空気輸送設備は更に別の一実施形態において、ダストが第一のダスト捕集タンクにおけるダストの出口から加圧タンクにおけるダストの入口へと第一の配管を通過中に、ダストが逆流しない程度の流量で加圧タンクから第一のダスト捕集タンクに向けて前記乾燥空気が第一の配管内を流れる。 In still another embodiment of the pneumatic transportation facility according to the present invention, dust is passing through the first pipe from the dust outlet in the first dust collecting tank to the dust inlet in the pressurized tank. The dry air flows in the first pipe from the pressurized tank toward the first dust collecting tank at a flow rate that does not flow backward.
 本発明に係る空気輸送設備は更に別の一実施形態において、ダストを空気輸送中の加圧タンク内の圧力が0.1~0.5MPaGである。 In still another embodiment of the pneumatic transportation facility according to the present invention, the pressure in the pressurized tank during pneumatic transportation of dust is 0.1 to 0.5 MPaG.
 本発明に係る空気輸送設備は更に別の一実施形態において、加圧タンクから第二のダスト捕集タンクへのダストの空気輸送中は、加圧タンク中のダストが加圧タンクに流入する前記乾燥空気によって流動状態にある。 In still another embodiment of the pneumatic transportation facility according to the present invention, the dust in the pressurized tank flows into the pressurized tank during pneumatic transportation of the dust from the pressurized tank to the second dust collecting tank. Being fluidized by dry air.
 本発明に係る空気輸送設備は更に別の一実施形態において、加圧タンクが並列に2台以上設置されており、少なくとも一つの加圧タンクが空気輸送中には残りの加圧タンクの内少なくとも一つの加圧タンクに第一のダスト捕集タンクからダストが投入される。 In still another embodiment of the pneumatic transportation facility according to the present invention, two or more pressurized tanks are installed in parallel, and at least one of the remaining pressurized tanks during pneumatic transportation is at least one of the pressurized tanks. Dust is put into one pressurized tank from the first dust collection tank.
 本発明に係る空気輸送設備は更に別の一実施形態において、加圧タンクの前段に一次貯留タンクが直列に設置されており、後段の加圧タンクが空気輸送中には第一のダスト捕集タンクから一次貯留タンクにダストが投入される。 In still another embodiment of the pneumatic transportation facility according to the present invention, a primary storage tank is installed in series before the pressurized tank, and the first dust collection is performed during the pneumatic transportation of the latter pressurized tank. Dust is thrown from the tank into the primary storage tank.
 本発明は別の一側面において、
 上記に記載の本発明に係る空気輸送設備及びセメントキルン排ガスの抽気設備を備えたセメントキルン排ガスの処理システムであって、
 セメントキルン排ガスの抽気設備は、セメントキルン排ガスの一部を抽気するための抽気管と、抽気管内に除湿及び冷却のための空気を供給するための送風機と、抽気管の出口に連結された集塵用サイクロンと、サイクロンの出口に連結された空気冷却器と、空気冷却器内に除湿及び冷却のための空気を供給するための送風機と、誘引通風機とを備え、
 第一のダスト捕集タンクの出口は誘引通風機に連結されており、
 第二のダスト捕集タンクは捕集されたダストの出口を有し、当該出口はセメント製造用のミル又はセメントクリンカータンクに連通されている、
セメントキルン排ガスの処理システムである。
In another aspect of the present invention,
A cement kiln exhaust gas treatment system comprising the pneumatic transportation equipment and the extraction facility for cement kiln exhaust gas according to the present invention described above,
The extraction facility for cement kiln exhaust gas includes an extraction pipe for extracting a part of the cement kiln exhaust gas, a blower for supplying air for dehumidification and cooling into the extraction pipe, and a collector connected to the outlet of the extraction pipe. A dust cyclone, an air cooler connected to the outlet of the cyclone, a blower for supplying air for dehumidification and cooling into the air cooler, and an induction fan,
The outlet of the first dust collection tank is connected to the induction fan,
The second dust collection tank has an outlet for the collected dust, which is in communication with a mill or cement clinker tank for cement production;
This is a cement kiln exhaust gas treatment system.
 本発明に係るセメントキルン排ガスの処理システムは一実施形態において、第二のダスト捕集タンクにおける空気の出口は前記誘引通風機に連結されている。 In one embodiment of the cement kiln exhaust gas treatment system according to the present invention, the air outlet of the second dust collection tank is connected to the induction fan.
 本発明に係るセメントキルン排ガスの処理システムは別の一実施形態において、抽気管出口におけるガス流速を10m/s以上とする。 In another embodiment of the cement kiln exhaust gas treatment system according to the present invention, the gas flow rate at the outlet of the extraction pipe is set to 10 m / s or more.
 本発明に係る空気輸送設備及びセメントキルン排ガスの処理システムによれば、塩素バイパスダストが保管時や輸送時に潮解することによって、容器及び配管へのダストの付着やそれによる閉塞が発生してしまうのを軽減することができ、実用性のある塩素バイパスダストの空気輸送が可能となる。 According to the pneumatic transportation equipment and the cement kiln exhaust gas treatment system according to the present invention, the chlorine bypass dust is deliquescent during storage or transportation, so that dust adheres to and clogs the container and piping. This makes it possible to pneumatically transport chlorine bypass dust that is practical.
本発明の一実施形態に係るセメントキルン排ガスの処理システムである。1 is a cement kiln exhaust gas treatment system according to an embodiment of the present invention. 本発明に係る塩素バイパスダストの空気輸送設備において、加圧タンクを並列に設置した場合の一例を示す模式図である。In the pneumatic transportation equipment of chlorine bypass dust concerning the present invention, it is a mimetic diagram showing an example at the time of installing a pressurized tank in parallel. 本発明に係る塩素バイパスダストの空気輸送設備において、加圧タンクの前段に一次貯留タンクを設置した場合の一例を示す模式図である。It is a schematic diagram which shows an example at the time of installing a primary storage tank in the front | former stage of a pressurized tank in the pneumatic transport equipment of the chlorine bypass dust which concerns on this invention.
<1.空気輸送設備>
 図1を参照すると、本発明に係る塩素バイパスダストの空気輸送設備は、一実施形態において、
 セメントキルン排ガスの入口101及び出口102、セメントキルン排ガスからダストを捕集するための集塵機103、並びに捕集されたダストの出口104を有する第一のダスト捕集タンク100と、
 第一のダスト捕集タンク100からのダストの入口201、空気の入口202、及びダストの空気輸送用出口203を有し、当該ダストを圧縮空気により空気輸送するための加圧タンク200と、ただし、第一のダスト捕集タンク100におけるダストの出口104は加圧タンク200におけるダストの入口201の上方にあり、両者は第一の配管105によって連通されている、
 大気圧露点が-35℃以下の乾燥した圧縮空気を加圧タンク200に供給する空気供給源300と、
 加圧タンク200から第二の配管204を通って空気輸送されるダストの入口401、ダストを捕集するための集塵機402、並びに空気の出口403を有する第二のダスト捕集タンク400と、
を備えている。
<1. Air transportation equipment>
Referring to FIG. 1, the chlorine bypass dust pneumatic transportation facility according to the present invention is, in one embodiment,
A first dust collection tank 100 having a cement kiln exhaust gas inlet 101 and outlet 102, a dust collector 103 for collecting dust from the cement kiln exhaust gas, and a collected dust outlet 104;
A pressurized tank 200 having a dust inlet 201 from the first dust collection tank 100, an air inlet 202, and a dust air transport outlet 203 for pneumatically transporting the dust by compressed air; The dust outlet 104 in the first dust collection tank 100 is above the dust inlet 201 in the pressurized tank 200, and both are communicated by the first pipe 105.
An air supply source 300 for supplying dry compressed air having an atmospheric pressure dew point of −35 ° C. or lower to the pressurized tank 200;
A dust inlet 401 that is pneumatically transported from the pressurized tank 200 through the second pipe 204, a dust collector 402 for collecting dust, and a second dust collection tank 400 having an air outlet 403;
It has.
 潮解とは、ある固体が大気中に曝されているとき、大気中の水蒸気を吸収してそれに溶解し水溶液をつくる現象である。セメント製造プロセスで抽気される排ガスを冷却することで生成する塩素バイパスダストは、主成分を塩化カリウム(以下、KCl)とするのが一般的である。純粋なKClは潮解性がないとされている報告があるが、塩素バイパスダストは塩化カリウム以外にもCaOやSiO2など他の成分が含まれているせいか、非常に高い潮解性を示す。表1は、常温、湿度100%の条件下における塩素バイパスダストとポルトランドセメントの含水率の保存時間依存性を示したものであるが、塩素バイパスダストの潮解性が如何に高いか理解することができる。 Deliquession is a phenomenon in which when a solid is exposed to the atmosphere, it absorbs water vapor in the atmosphere and dissolves it to create an aqueous solution. The chlorine bypass dust generated by cooling the exhaust gas extracted in the cement manufacturing process generally has potassium chloride (hereinafter referred to as KCl) as a main component. Although there is a report that pure KCl does not have deliquescence, the chlorine bypass dust shows very high deliquescence because it contains other components such as CaO and SiO 2 in addition to potassium chloride. Table 1 shows the storage time dependence of the moisture content of chlorine bypass dust and Portland cement under conditions of room temperature and humidity of 100%. It can be understood how high the deliquescence of chlorine bypass dust is. it can.
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001
 第一のダスト捕集タンク100には、セメントキルン排ガスが入口101を介して流入してくる。流入してくるセメントキルン排ガス中には塩素バイパスダストが含まれており、これは集塵機103によって捕集される。集塵機の種類としては特に制限はないが、例えばバグフィルター、サイクロン、及び電気式集塵機が好適である。塩素バイパスダストが捕集された後の排ガスは出口102から排出される。 The cement kiln exhaust gas flows into the first dust collection tank 100 through the inlet 101. The inflowing cement kiln exhaust gas contains chlorine bypass dust, which is collected by the dust collector 103. Although there is no restriction | limiting in particular as a kind of dust collector, For example, a bag filter, a cyclone, and an electric dust collector are suitable. The exhaust gas after the chlorine bypass dust is collected is discharged from the outlet 102.
 セメントキルン排ガスは一般に温度が900~1100℃程度、大気圧露点が55℃以上、典型的には60~70℃程度の高温多湿ガスである。このような高温多湿の状態でセメントキルン排ガスが第一のダスト捕集タンク100に流入すると、集塵機103の耐久限度を超えて機能不全となってしまうし、第一のダスト捕集タンク100内や第一の配管105内で水分の付着した塩素バイパスダストが潮解して閉塞を生じやすくなったりする。一方で、除湿を強力に実施するために除湿空気によってセメントキルン排ガスを冷却しようとすると設備コストが跳ね上がり、現実的ではない。 Cement kiln exhaust gas is generally a high-temperature and high-humidity gas having a temperature of about 900 to 1100 ° C. and an atmospheric dew point of 55 ° C. or higher, typically about 60 to 70 ° C. When the cement kiln exhaust gas flows into the first dust collection tank 100 in such a high temperature and high humidity state, the dust collector 103 exceeds the durability limit and malfunctions. In the first pipe 105, the chlorine bypass dust to which moisture adheres is deliquescent and is likely to be clogged. On the other hand, if the cement kiln exhaust gas is cooled by dehumidified air in order to perform dehumidification strongly, the equipment cost jumps and is not realistic.
 そこで、入口101に流入するセメントキルン排ガスは、大気圧露点が10~40℃となるように予め除湿されていることが好ましく、大気圧露点が20~30℃に除湿されていることがより好ましい。また、入口101に流入するセメントキルン排ガスは、温度が50~150℃となるように予め冷却されていることが好ましく、温度が60~100℃となるように予め冷却されていることがより好ましい。また、相対湿度としては100%未満であることが好ましく、50%以下であることがより好ましく、20%以下であることが更により好ましい。この範囲であれば冷却空気として外気を利用でき、集塵機103の耐久性、第一のダスト捕集タンク100内や第一の配管105内での潮解抑制の観点でも実用的である。冷却後の排ガス温度を低くすることで、バグフィルターの耐久性が向上し、バグフィルターに耐熱温度の低い安価品を用いる事も可能となる。所望の温度を維持してダストの潮解を防止するために、第一のダスト捕集タンク100の周囲を保温材で覆ったり、周囲にヒーターを設置したりするなどの任意の公知の手段で保温や加温をしてもよい。 Therefore, the cement kiln exhaust gas flowing into the inlet 101 is preferably dehumidified in advance so that the atmospheric dew point is 10 to 40 ° C., and more preferably dehumidified to 20 to 30 ° C. . Further, the cement kiln exhaust gas flowing into the inlet 101 is preferably cooled in advance so that the temperature becomes 50 to 150 ° C., and more preferably precooled so that the temperature becomes 60 to 100 ° C. . Further, the relative humidity is preferably less than 100%, more preferably 50% or less, and even more preferably 20% or less. If it is this range, outside air can be utilized as cooling air, and it is practical also from the viewpoint of durability of the dust collector 103 and suppression of deliquescence in the first dust collection tank 100 and the first pipe 105. Lowering the exhaust gas temperature after cooling improves the durability of the bag filter, and it is possible to use an inexpensive product with a low heat-resistant temperature for the bag filter. In order to maintain the desired temperature and prevent deliquescent of the dust, the temperature is kept by any known means such as covering the periphery of the first dust collection tank 100 with a heat insulating material or installing a heater around it. Or you may heat.
 セメントキルン排ガスの出口102から排出された排ガスは、例えば排気管106を通って誘引通風機108に向かうことができる。誘引通風機108を出た後は、ドライヤ、スタビライザー、電気集塵機などを必要に応じて経た後、煙突から排気することができる。誘引通風機108としては、セメントキルンの排ガスの大部分を誘引するキルンIDFを使用するのが便宜であり、経済的である。図1に係る実施形態においてもキルンIDFを使用している。誘引通風機108の上流には集塵機103で捕集しきれなかったダスト回収のためバッグフィルター排気ファン107を設置することが好ましく、図1の本実施形態においても設置されている。 The exhaust gas discharged from the cement kiln exhaust gas outlet 102 can be directed to the induction fan 108 through the exhaust pipe 106, for example. After exiting the induction fan 108, it can be exhausted from the chimney after passing through a dryer, a stabilizer, an electric dust collector or the like as necessary. As the induction fan 108, it is convenient and economical to use a kiln IDF that attracts most of the exhaust gas from the cement kiln. The kiln IDF is also used in the embodiment according to FIG. A bag filter exhaust fan 107 is preferably installed upstream of the induction fan 108 to collect dust that could not be collected by the dust collector 103, and is also installed in the present embodiment of FIG.
 一方、第一のダスト捕集タンク100内に捕集されたダストは、出口104から第一の配管105を通って下方の加圧タンク200へと向かう。図1に示すように、出口104は第一のダスト捕集タンク100内に回収されたダストが重力で抜き出せるように第一のダスト捕集タンク100の底部に設けるのが好ましく、また、第一のダスト捕集タンク100はダストを抜き取りやすくする観点から底部に向かってすぼむテーパー状又はコーン状に形成されているのが好ましい。また、第一のダスト捕集タンク100におけるダストの出口104を加圧タンク200におけるダストの入口201の上方に配置することで、出口104から排出されたダストが重力によって第一の配管105を通って加圧タンク200内へ自然に落下できるようになっている。ダストの入口201とダストの出口104を連通する第一の配管105は垂直方向に延びているのが好ましいが、ダストがスムーズに輸送される限り多少傾斜していても構わない。 On the other hand, the dust collected in the first dust collection tank 100 goes from the outlet 104 to the lower pressurized tank 200 through the first pipe 105. As shown in FIG. 1, the outlet 104 is preferably provided at the bottom of the first dust collection tank 100 so that the dust collected in the first dust collection tank 100 can be extracted by gravity. The one dust collection tank 100 is preferably formed in a tapered shape or a cone shape that is recessed toward the bottom from the viewpoint of facilitating extraction of dust. Further, by arranging the dust outlet 104 in the first dust collection tank 100 above the dust inlet 201 in the pressurized tank 200, the dust discharged from the outlet 104 passes through the first pipe 105 by gravity. Thus, it can fall naturally into the pressurized tank 200. The first pipe 105 communicating the dust inlet 201 and the dust outlet 104 preferably extends in the vertical direction, but may be slightly inclined as long as the dust is smoothly transported.
 図1に係る実施形態においては採用していないが、ダストが第一のダスト捕集タンク100におけるダストの出口104から加圧タンク200におけるダストの入口201へと第一の配管105を通過中に、ダストが逆流しない程度の流量で加圧タンク200から第一のダスト捕集タンク100に向けて後述する乾燥空気が第一の配管105内を流れるようにしてもよい。これによって、第一の配管105でのダストの潮解を抑制することができる。ダストの潮解を防止の観点から、第一の配管105を保温や加温をしてもよい。第一の配管105にはダストの流れを制御するためのバルブを設置することができる。例えば、ダストの出口104又はその近傍にダストの投入元弁501を設けることができ、ダストの入口201又はその近傍にダストの投入弁502を設けることができる。 Although not employed in the embodiment according to FIG. 1, dust is passing through the first pipe 105 from the dust outlet 104 in the first dust collection tank 100 to the dust inlet 201 in the pressurized tank 200. The dry air described later may flow through the first pipe 105 from the pressurized tank 200 toward the first dust collecting tank 100 at a flow rate that does not cause the dust to flow backward. As a result, the deliquescence of dust in the first pipe 105 can be suppressed. From the viewpoint of preventing dust deliquescence, the first pipe 105 may be kept warm or heated. The first pipe 105 can be provided with a valve for controlling the flow of dust. For example, a dust input valve 501 can be provided at or near the dust outlet 104, and a dust input valve 502 can be provided at or near the dust inlet 201.
 加圧タンク200は第一のダスト捕集タンク100からのダストを収容する。所定量のダストが貯まると、密閉してダストの空気輸送に必要な圧力まで加圧した後、ダストの空気輸送用出口203に設置された輸送弁504を開けてダストを第二のダスト捕集タンク400まで空気輸送する。輸送時には圧縮空気が空気の入口202から第二の配管204を通って第二のダスト捕集タンク400内に導入される。 The pressurized tank 200 stores the dust from the first dust collection tank 100. When a predetermined amount of dust accumulates, it is sealed and pressurized to the pressure necessary for pneumatic transport of the dust, and then the transport valve 504 installed at the dust air transport outlet 203 is opened to collect the dust in the second dust collection. Air transport to tank 400. During transportation, compressed air is introduced from the air inlet 202 into the second dust collection tank 400 through the second pipe 204.
 この圧縮空気は空気供給源300から空気配管303を通って加圧タンク200に供給される。空気供給源300は外気を利用した空気圧縮機301を備えるのが一般的であるが、これに限られない。空気供給源300と加圧タンク200の間の空気配管303には圧縮空気の供給を制御するための空気供給弁503を設置することができる。ダストの潮解防止の観点から極力露点の低い空気とすべきであり、具体的には大気圧露点が-35℃以下の乾燥空気を使用するのが望ましい。これにより、加圧タンク200内のガス温度が特に加熱したりしない常温(例えば0~40℃、典型的には10~30℃)であっても、実用可能な程度にダストの潮解を抑制することができる。圧縮空気の大気圧露点は-40℃以下であることがより好ましく、-50℃以下であることが更により好ましく、-60℃以下であることが最も好ましく、例示的には大気圧露点を-80℃~-35℃とすることができる。このような乾燥空気は、例えば吸着式エアドライヤ又はヒートレス式エアドライヤなどのエアドライヤ302を備えた空気供給源300を使用することで入手可能である。 This compressed air is supplied from the air supply source 300 to the pressurized tank 200 through the air pipe 303. The air supply source 300 is generally provided with an air compressor 301 using outside air, but is not limited thereto. An air supply valve 503 for controlling the supply of compressed air can be installed in the air pipe 303 between the air supply source 300 and the pressurized tank 200. From the viewpoint of preventing dust deliquescence, air should have as low a dew point as possible. Specifically, it is desirable to use dry air having an atmospheric dew point of −35 ° C. or lower. As a result, even if the gas temperature in the pressurized tank 200 is not particularly heated (for example, 0 to 40 ° C., typically 10 to 30 ° C.), liquefaction of dust is suppressed to a practical level. be able to. The atmospheric pressure dew point of the compressed air is more preferably −40 ° C. or less, still more preferably −50 ° C. or less, most preferably −60 ° C. or less. The temperature can be 80 ° C to -35 ° C. Such dry air can be obtained by using an air supply source 300 having an air dryer 302 such as an adsorption air dryer or a heatless air dryer.
 圧縮空気の圧力条件としては、輸送圧力が低すぎるとダストが目的地まで輸送できなくなる一方で、輸送圧力が高すぎると相対湿度が上昇してダストの潮解が起きやすくなるので、ダストを空気輸送中の加圧タンク200内の圧力が0.1~0.5MPaGとなるように調節されるのが好ましい。 As for the compressed air pressure condition, if the transport pressure is too low, the dust cannot be transported to the destination, but if the transport pressure is too high, the relative humidity increases and the liquefaction of the dust easily occurs. It is preferable that the pressure inside the pressurized tank 200 is adjusted to be 0.1 to 0.5 MPaG.
 加圧タンク200から第二のダスト捕集タンク400へのダストの空気輸送中は、加圧タンク200中のダストが加圧タンク200に流入する前記乾燥空気によって流動状態にあることが好ましい。これによって、加圧タンク200中のダストが加圧タンク200の内壁に固着するのを抑制することができ、空気輸送後に加圧タンク200内に残留するダストを減らすこともできる。このためには、例えば、図1に示すように、加圧タンク200の底部に空気の入口202を設けることができる。加圧タンク200内に導入される圧縮空気によって加圧タンク200内に収容されているダストが流動化する。 During the pneumatic transportation of dust from the pressurized tank 200 to the second dust collection tank 400, it is preferable that the dust in the pressurized tank 200 is in a fluid state due to the dry air flowing into the pressurized tank 200. Thereby, it is possible to suppress the dust in the pressurized tank 200 from adhering to the inner wall of the pressurized tank 200, and it is possible to reduce the dust remaining in the pressurized tank 200 after pneumatic transportation. For this purpose, for example, as shown in FIG. 1, an air inlet 202 can be provided at the bottom of the pressurized tank 200. The dust stored in the pressurized tank 200 is fluidized by the compressed air introduced into the pressurized tank 200.
 加圧タンク200の周囲を保温材で覆ったり、周囲にヒーターを設置したりするなどの任意の公知の手段で保温や加温をすることもできる。また、図1に係る実施形態では採用していないが、空気供給源300がヒーターを備えることで、比較的高温の圧縮空気を供給することも出来る。これにより、加圧タンク200や第二の配管204内におけるガスの相対湿度を下げることができるので、ダストの潮解防止に役立つ。 It is also possible to keep warm or warm by any known means such as covering the periphery of the pressurized tank 200 with a heat insulating material or installing a heater around it. Although not employed in the embodiment according to FIG. 1, relatively high-temperature compressed air can be supplied by providing the air supply source 300 with a heater. As a result, the relative humidity of the gas in the pressurized tank 200 and the second pipe 204 can be lowered, which is useful for preventing dust deliquescence.
 第二のダスト捕集タンク400には入口401から空気輸送によってダストが導入される。第二のダスト捕集タンク400はダストを捕集するための集塵機402及び空気の出口403を有する。集塵機の種類としては特に制限はないが、例えばバグフィルターが好適である。ダストが捕集された後の空気は出口403から排出される。出口403から排出された空気はそのまま大気に放出してもよく、専用の排気系統を別途設けて排出してもよい。また、図1に示すように、出口403に排気管404を連結して、これを第一のダスト捕集タンク100の排気管106に合流させてもよい。これにより、排気系統が集約されるので経済的である。 Dust is introduced into the second dust collection tank 400 from the inlet 401 by pneumatic transportation. The second dust collection tank 400 has a dust collector 402 for collecting dust and an air outlet 403. Although there is no restriction | limiting in particular as a kind of dust collector, For example, a bag filter is suitable. The air after the dust is collected is discharged from the outlet 403. The air discharged from the outlet 403 may be released to the atmosphere as it is, or may be discharged by providing a dedicated exhaust system. Further, as shown in FIG. 1, an exhaust pipe 404 may be connected to the outlet 403, and this may be joined to the exhaust pipe 106 of the first dust collection tank 100. This is economical because the exhaust system is integrated.
 第二のダスト捕集タンク400内は前述した乾燥空気が送り込まれているため、第二のダスト捕集タンク400内には水分の持ち込みがほとんどない。そのため、潮解を抑制しながら塩素バイパスダストを長期間保存することが可能となる。例えば、1週間以上の保存が可能であり、好ましくは1ヶ月以上保存することも可能である。保存期間終了後は、第二のダスト捕集タンク400からダストをスムーズに排出することができる。排出されたダストはロータリーバルブなどの弁を介して、近傍のセメント製造用のミル(仕上ミル)又はセメントクリンカータンクに投入することができる。 Since the above-described dry air is fed into the second dust collection tank 400, there is almost no moisture brought into the second dust collection tank 400. Therefore, chlorine bypass dust can be stored for a long time while suppressing deliquescence. For example, it can be stored for one week or longer, and preferably can be stored for one month or longer. After the storage period, the dust can be smoothly discharged from the second dust collection tank 400. The discharged dust can be put into a nearby cement manufacturing mill (finishing mill) or a cement clinker tank through a valve such as a rotary valve.
 本発明に係る塩素バイパスダストの空気輸送設備は、加圧タンク200内の圧力を監視する圧力スイッチ601、及び加圧タンク200内のダスト量を監視するレベルスイッチ602を有することができ、これに基づいて空気輸送を制御する制御機構を備えることができる。例えば、制御機構は以下のような手順で空気輸送設備を稼働させることができる。加圧タンク200内のダスト量が所定量に到達したことがレベルスイッチ602により検知されると、第一のダスト捕集タンク100からの加圧タンク200へのダストの供給を停止し、加圧タンク200を乾燥空気によって加圧し、所定の圧力に上昇したことが圧力スイッチ601により検知されると第二のダスト捕集タンク400へのダストの空気輸送を開始し、その後、所定の圧力に下降したことが圧力スイッチ601により検知されるとダストの空気輸送を停止して、第一のダスト捕集タンク100からの加圧タンク200へのダストの供給を再開する。 The pneumatic transport facility for chlorine bypass dust according to the present invention can include a pressure switch 601 for monitoring the pressure in the pressurized tank 200 and a level switch 602 for monitoring the amount of dust in the pressurized tank 200. A control mechanism for controlling pneumatic transport can be provided. For example, the control mechanism can operate the pneumatic transportation facility in the following procedure. When the level switch 602 detects that the amount of dust in the pressurized tank 200 has reached a predetermined amount, the supply of dust from the first dust collection tank 100 to the pressurized tank 200 is stopped, and the pressure is increased. The tank 200 is pressurized with dry air, and when it is detected by the pressure switch 601 that the pressure has risen to a predetermined pressure, the air transportation of dust to the second dust collecting tank 400 is started, and then the pressure is lowered to the predetermined pressure. When this is detected by the pressure switch 601, the pneumatic transportation of dust is stopped, and the supply of dust from the first dust collection tank 100 to the pressurized tank 200 is resumed.
 図1に係る実施形態におけるより詳細な空気輸送設備の稼働手順について説明する。投入元弁501、投入弁502、空気供給弁503及び輸送弁504が閉じた状態から開始すると、まず、投入弁502及び投入元弁501が順に開くことで、第一のダスト捕集タンク100内のダストの加圧タンク200内への投入が開始される。加圧タンク200内のダスト量が所定量に到達したことがレベルスイッチ602により検知されると、投入元弁501及び投入弁502が順に閉じることで、第一のダスト捕集タンク100からの加圧タンク200へのダストの供給が停止される。次いで、空気供給弁503が開き、加圧タンク200内が乾燥空気によって加圧される。所定の圧力に上昇したことが圧力スイッチ601により検知されると、輸送弁504が開き、第二のダスト捕集タンク400へのダストの空気輸送が開始される。加圧タンク200内の圧力は、輸送すべきダストがなくなると急激に減少する。そのため、所定の圧力に下降したことが圧力スイッチ601により検知されると空気供給弁及び輸送弁を順に閉じることでダストの空気輸送を停止する。その後、投入弁502及び投入元弁501が順に開くことで、再び、第一のダスト捕集タンク100内のダストの加圧タンク200内への投入が開始され、先述した動作が繰り返し行われる。 A more detailed operation procedure of the pneumatic transportation facility in the embodiment according to FIG. 1 will be described. When the input valve 501, the input valve 502, the air supply valve 503, and the transport valve 504 are closed, first, the input valve 502 and the input valve 501 are opened in order, so that the inside of the first dust collection tank 100. Is started to enter the pressurized tank 200. When the level switch 602 detects that the amount of dust in the pressurized tank 200 has reached a predetermined amount, the charging source valve 501 and the charging valve 502 are closed in order, so that the addition from the first dust collection tank 100 is performed. The supply of dust to the pressure tank 200 is stopped. Next, the air supply valve 503 is opened, and the inside of the pressurized tank 200 is pressurized with dry air. When the pressure switch 601 detects that the pressure has risen to a predetermined pressure, the transport valve 504 is opened and the pneumatic transport of dust to the second dust collection tank 400 is started. The pressure in the pressurized tank 200 decreases rapidly when there is no dust to be transported. Therefore, when the pressure switch 601 detects that the pressure has dropped to a predetermined pressure, the air supply valve and the transport valve are closed in order to stop the air transport of dust. Thereafter, when the input valve 502 and the input source valve 501 are sequentially opened, the input of the dust in the first dust collection tank 100 into the pressurized tank 200 is started again, and the above-described operation is repeated.
 加圧タンク200から第二のダスト捕集タンク400へダストを空気輸送している間は、第一のダスト捕集タンク100から加圧タンク200へのダストの供給が停止しているため、第一のダスト捕集タンク100にはダストが蓄積されていくことになる。しかしながら、第一のダスト捕集タンク100内は比較的に湿度が高い状態あるため、ダストの潮解抑制の観点からは、長時間ダストを第一のダスト捕集タンク100内に滞留させておくことは好ましいことではない。そこで、第一のダスト捕集タンク100からの加圧タンク200へのダストの供給を停止してから、第一のダスト捕集タンク100からの加圧タンク200へのダストの供給を再開するまでの時間は短い方が望ましく、例えば10分以内とするのが好ましく、5分以内とするのがより好ましい。ただし、この時間をあまりに短くするとバルブの開閉頻度が多くなり、バルブの寿命に悪影響を与えることから、1分以上とするのが好ましく、典型的には2~4分とすることができる。 While dust is pneumatically transported from the pressurized tank 200 to the second dust collection tank 400, the supply of dust from the first dust collection tank 100 to the pressurized tank 200 is stopped. The dust is accumulated in one dust collecting tank 100. However, since the humidity in the first dust collection tank 100 is relatively high, from the viewpoint of suppressing dust deliquescence, the dust should stay in the first dust collection tank 100 for a long time. Is not preferred. Therefore, after the supply of dust from the first dust collection tank 100 to the pressurized tank 200 is stopped, the supply of dust from the first dust collection tank 100 to the pressurized tank 200 is restarted. The shorter time is desirable, for example, preferably within 10 minutes, and more preferably within 5 minutes. However, if this time is too short, the frequency of opening and closing of the valve increases, which adversely affects the life of the valve. Therefore, it is preferably 1 minute or longer, and typically 2 to 4 minutes.
 別法として、図2に示すように、加圧タンク200を並列に2台設置し、一方の加圧タンクが空気輸送中には他方の加圧タンクにダストを投入することができる。必要に応じて加圧タンク200は2台以上並列に設置してもよい。その場合、ある加圧タンクが空気輸送中には残りの加圧タンクに第一のダスト捕集タンクからダストが投入される。或いは、図3に示すように、加圧タンクの前段に一次貯留タンク205を直列に設置し、後段の加圧タンク200が空気輸送中には前段の一次貯留タンク205にダストを投入し、空気輸送が終了すると、一次貯留タンクから加圧タンクにダストが投入されるようにすることができる。このようにすることで、第一のダスト捕集タンク100からダストを連続的に排出することができるようになる。一次貯留タンク205に加圧タンク200に送るのと同様の乾燥空気を送り、内部を乾燥状態に保持することもできる。 As another method, as shown in FIG. 2, two pressurized tanks 200 are installed in parallel, and dust can be put into the other pressurized tank while one pressurized tank is pneumatically transported. If necessary, two or more pressurized tanks 200 may be installed in parallel. In that case, while a certain pressurized tank is pneumatically transported, dust is thrown into the remaining pressurized tank from the first dust collection tank. Alternatively, as shown in FIG. 3, a primary storage tank 205 is installed in series in the front stage of the pressurized tank, and dust is thrown into the primary storage tank 205 in the previous stage while the subsequent pressurized tank 200 is transported by air. When transportation is completed, dust can be put into the pressurized tank from the primary storage tank. By doing in this way, dust can be continuously discharged from the first dust collection tank 100. Dry air similar to that sent to the pressurized tank 200 can be sent to the primary storage tank 205 to keep the inside dry.
<2.セメントキルン排ガスの処理システム>
 上記で説明した本発明に係る塩素バイパスダストの空気輸送設備はセメントキルン排ガスの抽気設備と組み合わせてセメントキルン排ガスの処理システムを構成することができる。これによって、セメントキルンから抽気された排ガスから塩素バイパスダストを回収し、これを仕上ミルで処理するまでの一連の工程を配管システムによって連続的に行うことができるようになる。本発明に係るセメントキルン排ガスの処理システムによれば、塩素バイパスダストの仕上ミルまでのトラック輸送が不要となり、塩素バイパスダストの輸送過程での配管閉塞の低減、及び仕上ミル内の散水ノズルの腐食や閉塞を低減することができ、実用性のある塩素バイパスダストの空気輸送が可能となる。
<2. Cement kiln exhaust gas treatment system>
The above-described chlorine bypass dust pneumatic transportation facility according to the present invention can be combined with a cement kiln exhaust gas extraction facility to constitute a cement kiln exhaust gas treatment system. As a result, a series of steps from recovering chlorine bypass dust from the exhaust gas extracted from the cement kiln and treating it with the finishing mill can be continuously performed by the piping system. The cement kiln exhaust gas treatment system according to the present invention eliminates the need for truck transportation to the finishing mill of chlorine bypass dust, reduces pipe blockage in the transportation process of chlorine bypass dust, and corrodes the water spray nozzle in the finishing mill. In addition, it is possible to reduce the clogging and blockage, and it is possible to pneumatically transport chlorine bypass dust that is practical.
 図1を参照すると、本発明に係るセメントキルン排ガスの処理システムは一実施形態において、前述した本発明に係る塩素バイパスダストの空気輸送設備及びセメントキルン排ガスの抽気設備を備えており、セメントキルン排ガスの抽気設備は、セメントキルン排ガスの一部を抽気するための抽気管702と、抽気管702内に除湿及び冷却のための空気を供給するための送風機703と、抽気管702の出口に連結された集塵用サイクロン704と、サイクロン704の出口に連結された空気冷却器705と、空気冷却器705内に除湿及び冷却のための空気を供給するための送風機706と、誘引通風機108とを備え、第一のダスト捕集タンク100の入口101は空気冷却器705と排気管710によって連通しており、第一のダスト捕集タンク100の出口102は誘引通風機108に排気管106によって連通されており、第二のダスト捕集タンク400は捕集されたダストの出口405を有し、当該出口はセメント製造用のミル又はセメントクリンカータンクに連通されている。 Referring to FIG. 1, a cement kiln exhaust gas treatment system according to the present invention includes, in one embodiment, the above-described chlorine bypass dust pneumatic transportation facility and cement kiln exhaust gas extraction facility according to the present invention, and cement kiln exhaust gas. The extraction equipment is connected to an extraction pipe 702 for extracting a part of the cement kiln exhaust gas, a blower 703 for supplying air for dehumidification and cooling into the extraction pipe 702, and an outlet of the extraction pipe 702. A dust collecting cyclone 704, an air cooler 705 connected to the outlet of the cyclone 704, a blower 706 for supplying air for dehumidification and cooling into the air cooler 705, and an induction fan 108. The inlet 101 of the first dust collection tank 100 is in communication with the air cooler 705 and the exhaust pipe 710, and The outlet 102 of the waste collection tank 100 is connected to the induction fan 108 by the exhaust pipe 106, and the second dust collection tank 400 has an outlet 405 of the collected dust, which is used for cement production. To a mill or cement clinker tank.
 抽気管702は、ロータリーキルンから排出された揮発性成分を含有する排ガスの一部を抽気する。排ガスは先述したような高温多湿ガスである。抽気管702は、キルン窯尻701の他、キルン窯尻701から直上に延びたライジングダクトや仮焼炉の途中に設けられるのが一般的である。図1ではライジングダクトから抽気している。抽気管702には送風機703がダクトによって連結されており、そこから除湿及び冷却のための空気がサイクロン704の方向に流れるように抽気管702に押し込まれる。導入された空気は抽気された排ガスと混合しながら排ガスを冷却及び除湿する。先述したように、ここで使用する空気は外気で十分であるが、冷却速度確保の理由により、抽気管702の出口におけるガス流速を10m/s以上とすることが好ましく、例えば10~30m/sとすることができる。 The extraction pipe 702 extracts a part of the exhaust gas containing volatile components discharged from the rotary kiln. The exhaust gas is a hot and humid gas as described above. In addition to the kiln kiln 701, the bleed pipe 702 is generally provided in the middle of a rising duct or a calcining furnace that extends right above the kiln kiln 701. In FIG. 1, air is extracted from the rising duct. A blower 703 is connected to the extraction pipe 702 by a duct, from which air for dehumidification and cooling is pushed into the extraction pipe 702 so as to flow in the direction of the cyclone 704. The introduced air cools and dehumidifies the exhaust gas while mixing with the extracted exhaust gas. As described above, outside air is sufficient as the air used here, but for the reason of securing the cooling rate, the gas flow rate at the outlet of the extraction pipe 702 is preferably 10 m / s or more, for example, 10 to 30 m / s. It can be.
 抽気管702を出た排ガスと冷却空気の混合ガスは、排気管709を通って集塵用サイクロン704に導入され、粗粒が分離される。その後、混合ガスは、空気冷却器705内で、送風機706により押し込まれる冷却空気と混合されて更に冷却される。その後、混合ガスは排気管710を通って第一のダスト捕集タンク100に導入され、排ガス中から塩素バイパスダストが第一のダスト捕集タンク100内に回収される。送風機703及び送風機706から供給される除湿及び冷却のための空気の量は、第一のダスト捕集タンク100内に流入するセメントキルン排ガスの温度及び湿度が先述した範囲内になるように調節すればよい。第一のダスト捕集タンク100内に塩素バイパスダストが導入された後の塩素バイパスダストの空気輸送設備の動作に関しては先述したとおりである。 The mixed gas of the exhaust gas and the cooling air that has exited the extraction pipe 702 is introduced into the dust collecting cyclone 704 through the exhaust pipe 709, and coarse particles are separated. Thereafter, the mixed gas is mixed with the cooling air pushed by the blower 706 in the air cooler 705 and further cooled. Thereafter, the mixed gas is introduced into the first dust collection tank 100 through the exhaust pipe 710, and the chlorine bypass dust is recovered in the first dust collection tank 100 from the exhaust gas. The amount of air for dehumidification and cooling supplied from the blower 703 and the blower 706 is adjusted so that the temperature and humidity of the cement kiln exhaust gas flowing into the first dust collection tank 100 are within the above-described ranges. That's fine. The operation of the pneumatic transport facility for chlorine bypass dust after the chlorine bypass dust is introduced into the first dust collection tank 100 is as described above.
 以下、実施例を用いて本発明を説明するが、本発明はこれらの実施例に限定されるものではない。 Hereinafter, the present invention will be described using examples, but the present invention is not limited to these examples.
(実施例1)
 図1の実施形態におけるセメントキルン排ガスの処理システムを以下の稼働条件にて1週間運転した。
Example 1
The cement kiln exhaust gas treatment system in the embodiment of FIG. 1 was operated for one week under the following operating conditions.
<稼働条件>
(1)抽気管702入口のセメントキルン排ガス:
  -温度:900~1100℃、
  -大気圧露点:60~69℃
  -風量:150[m3N/min]
(2)冷却及び除湿用の空気:
  -外気(温度:2~16℃、大気圧露点:-5~11℃)
  -抽気管702へ送風機より送り込まれる空気風量:250[m3N/min]
  -冷却器705へ送風機より送り込まれる空気風量:320[m3N/min]
(3)抽気管702出口におけるガス流速:15m/s
(4)入口101に流入するセメントキルン排ガス:
  -ガス温度:58~82℃
  -大気圧露点:30~39℃
(5)第一のダスト捕集タンク100の集塵機103:バグフィルター
(6)第一のダスト捕集タンク100の保温の有無:有り(保温材+電気ヒーター)
(7)第一の配管105の保温の有無:有り(保温材)
(8)加圧タンク200内のガス温度:12~38℃
(9)空気輸送中の加圧タンク内の圧力:0.15MPaG
(10)輸送用空気供給源:
  空気圧縮機
  吸着式エアドライヤ(CKD社製SHD3045)
(11)輸送用空気の大気圧露点:-40~-56℃
(12)加圧タンク200の保温の有無:有り(保温材)
(13)第二のダスト捕集タンク400の集塵機402:バグフィルター
(14)第一のダスト捕集タンク100からの加圧タンク200へのダストの供給を停止してから、第一のダスト捕集タンク100からの加圧タンク200へのダストの供給を再開するまでの時間:約2分
(15)圧力スイッチ高(PIS H)設定値:0.15MPaG
(16)圧力スイッチ低(PIS L)設定値:0.06MPaG
(17)レベルスイッチ高(LS H)設定値:0.1m3
(18)空気輸送の距離:150m
<Operating conditions>
(1) Cement kiln exhaust gas at the inlet of the extraction pipe 702:
-Temperature: 900-1100 ° C
-Atmospheric pressure dew point: 60-69 ° C
-Air volume: 150 [m 3 N / min]
(2) Air for cooling and dehumidification:
-Outside air (temperature: 2-16 ° C, atmospheric dew point: -5-11 ° C)
-Air volume sent from the blower to the extraction pipe 702: 250 [m 3 N / min]
-Air flow rate sent from the blower to the cooler 705: 320 [m 3 N / min]
(3) Gas flow velocity at the outlet of the extraction pipe 702: 15 m / s
(4) Cement kiln exhaust gas flowing into the inlet 101:
-Gas temperature: 58-82 ° C
-Atmospheric pressure dew point: 30-39 ° C
(5) Dust collector 103 of the first dust collection tank 100: Bag filter (6) Presence / absence of heat insulation of the first dust collection tank 100: Existence (heat insulation material + electric heater)
(7) Presence / absence of heat insulation of the first pipe 105: Existence (heat insulation material)
(8) Gas temperature in the pressurized tank 200: 12 to 38 ° C
(9) Pressure in the pressurized tank during pneumatic transportation: 0.15 MPaG
(10) Transportation air supply source:
Air compressor Adsorption air dryer (SHD3045 made by CKD)
(11) Atmospheric pressure dew point of transport air: -40 to -56 ° C
(12) Presence / absence of heat retention of the pressurized tank 200: Existence (heat insulation material)
(13) Dust collector 402 of second dust collection tank 400: bag filter (14) After the supply of dust from the first dust collection tank 100 to the pressurized tank 200 is stopped, the first dust collection Time until dust supply from the collection tank 100 to the pressurized tank 200 is restarted: about 2 minutes (15) Pressure switch height (PISH) setting value: 0.15 MPaG
(16) Pressure switch low (PIS L) set value: 0.06 MPaG
(17) Level switch height (LS H) set value: 0.1 m 3
(18) Pneumatic transport distance: 150m
 抽気管702入口のセメントキルン排ガス、及び入口101に流入するセメントキルン排ガスの露点はJIS Z8808-1995に基づき、排ガス中の水分量を吸湿管を用いて測定して算出した。
 冷却及び除湿用の空気の露点及び輸送用空気の露点は静電容量式温湿度センサーにより測定した。
The dew points of the cement kiln exhaust gas at the inlet of the extraction pipe 702 and the cement kiln exhaust gas flowing into the inlet 101 were calculated based on JIS Z 8808-1995 by measuring the moisture content in the exhaust gas using a moisture absorption pipe.
The dew point of air for cooling and dehumidification and the dew point of air for transportation were measured by a capacitance type temperature and humidity sensor.
 なお、抽気管702内の排ガスの一部をサンプリングし、冷却することで得られた塩素バイパスダストの化学分析を行ったところ、表2に記載のような結果であった。 In addition, when the chemical analysis of the chlorine bypass dust obtained by sampling a part of the exhaust gas in the extraction pipe 702 and cooling it, the results shown in Table 2 were obtained.
Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000002
 上記稼働条件でセメントキルン排ガスの処理システムを運転した結果、第一の配管105、加圧タンク200及び第二の配管204の何れにもダストの付着はほとんど見られなかった。 As a result of operating the cement kiln exhaust gas treatment system under the above operating conditions, almost no dust was observed on any of the first pipe 105, the pressurized tank 200, and the second pipe 204.
(実施例2)
 稼働条件を以下のように変更した他は実施例1と同様に図1に実施形態におけるセメントキルン排ガスの処理システムを1週間運転した。
<稼働条件>
(1)冷却及び除湿用の空気:
  -外気(温度:2~16℃、大気圧露点:-5~11℃)
  -抽気管702へ送風機より送り込まれる空気風量:100[m3N/min]
  -冷却器705へ送風機より送り込まれる空気風量:100[m3N/min]
(2)抽気管702出口におけるガス流速:6m/s
(3)入口101に流入するセメントキルン排ガス:
  -ガス温度:230~270℃
  -大気圧露点:43~52℃
(4)加圧タンク200内のガス温度:65~98℃
(Example 2)
The cement kiln exhaust gas treatment system in the embodiment shown in FIG. 1 was operated for one week in the same manner as in Example 1 except that the operating conditions were changed as follows.
<Operating conditions>
(1) Air for cooling and dehumidification:
-Outside air (temperature: 2-16 ° C, atmospheric dew point: -5-11 ° C)
-Air volume sent from the blower to the extraction pipe 702: 100 [m 3 N / min]
-Air flow rate sent from the blower to the cooler 705: 100 [m 3 N / min]
(2) Gas flow velocity at the outlet of the extraction pipe 702: 6 m / s
(3) Cement kiln exhaust gas flowing into the inlet 101:
-Gas temperature: 230-270 ° C
-Atmospheric pressure dew point: 43-52 ° C
(4) Gas temperature in the pressurized tank 200: 65 to 98 ° C
 上記稼働条件でセメントキルン排ガスの処理システムを運転した結果、第一の配管105、加圧タンク200及び第二の配管204の何れにもダストの付着はほとんど見られなかった。しかしながら、第一のダスト捕集タンクに流入するセメントキルン排ガスの温度が高すぎるため、バグフィルターの寿命に影響を与えると考えられる。具体的には、高温によるバグフィルターの濾布の樹脂の劣化寿命に影響を与え、半年の連続運転が不可能となるだろう。 As a result of operating the cement kiln exhaust gas treatment system under the above operating conditions, almost no dust was observed on any of the first pipe 105, the pressurized tank 200, and the second pipe 204. However, since the temperature of the cement kiln exhaust gas flowing into the first dust collection tank is too high, it is considered that the life of the bag filter is affected. Specifically, it will affect the deterioration life of the resin of the bag filter filter cloth due to high temperature, and continuous operation for six months will be impossible.
(比較例1)
 圧縮空気をエアドライヤで乾燥させなかった他は、実施例1と同様の条件でセメントキルン排ガスの処理システムを1週間稼働させた。輸送用空気の大気圧露点は-5~5℃であった。その結果、第一の配管105、加圧タンク200及び第二の配管204の何れにおいても実施例1よりも多量のダストの付着、成長し、管内閉塞を起し、試験の途中で連続運転が不可能となった。
(Comparative Example 1)
The cement kiln exhaust gas treatment system was operated for one week under the same conditions as in Example 1 except that the compressed air was not dried with an air dryer. The atmospheric pressure dew point of the transportation air was −5 to 5 ° C. As a result, in all of the first pipe 105, the pressurized tank 200, and the second pipe 204, a larger amount of dust adheres and grows than in the first embodiment, which causes clogging in the pipe, and continuous operation is performed during the test. It became impossible.
100 第一のダスト捕集タンク
101 セメントキルン排ガスの入口
102 セメントキルン排ガスの出口
103 集塵機
104 ダストの出口
105 第一の配管
106 排気管 
107 バッグフィルター排気ファン
108 誘引通風機
200 加圧タンク
201 第一のダスト捕集タンクからのダストの入口
202 空気の入口
203 ダストの空気輸送用出口
204 第二の配管
205 一次貯留タンク
300 空気供給源
301 空気圧縮機
302 エアドライヤ
303 空気配管
400 第二のダスト捕集タンク
401 空気輸送されるダストの入口
402 集塵機
403 空気の出口
404 排気管
405 ダストの出口
501 投入元弁
502 投入弁
503 空気供給弁
504 輸送弁
601 圧力スイッチ 
602 レベルスイッチ
701 キルン窯尻
702 抽気管
703 送風機
704 集塵用サイクロン
705 空気冷却器
706 送風機
709 排気管
710 排気管
DESCRIPTION OF SYMBOLS 100 First dust collection tank 101 Cement kiln exhaust gas inlet 102 Cement kiln exhaust gas outlet 103 Dust collector 104 Dust outlet 105 First pipe 106 Exhaust pipe
107 Bag filter exhaust fan 108 Induction fan 200 Pressurized tank 201 Dust inlet 202 from the first dust collection tank 202 Air inlet 203 Dust air transport outlet 204 Second piping 205 Primary storage tank 300 Air supply source 301 Air Compressor 302 Air Dryer 303 Air Pipe 400 Second Dust Collection Tank 401 Air Dust Inlet 402 Dust Collector 403 Air Outlet 404 Exhaust Pipe 405 Dust Outlet 501 Input Source Valve 502 Input Valve 503 Air Supply Valve 504 Transport valve 601 Pressure switch
602 Level switch 701 Kiln kiln bottom 702 Extraction pipe 703 Blower 704 Dust collection cyclone 705 Air cooler 706 Blower 709 Exhaust pipe 710 Exhaust pipe

Claims (14)

  1.  セメントキルン排ガスの入口及び出口、セメントキルン排ガスからダストを捕集するための集塵機、並びに捕集されたダストの出口を有する第一のダスト捕集タンクと、
     第一のダスト捕集タンクからのダストの入口、空気の入口、及びダストの空気輸送用出口を有し、当該ダストを圧縮空気により空気輸送するための加圧タンクと、ただし、第一のダスト捕集タンクにおけるダストの出口は加圧タンクにおけるダストの入口の上方にあり、両者は第一の配管によって連通されている、
     大気圧露点が-35℃以下の乾燥した圧縮空気を加圧タンクに供給する空気供給源と、
     加圧タンクから第二の配管を通って空気輸送されるダストの入口、ダストを捕集するための集塵機、並びに空気の出口を有する第二のダスト捕集タンクと、
    を備えたセメントキルン排ガスから捕集されたダストの空気輸送設備。
    A first dust collecting tank having a cement kiln exhaust gas inlet and outlet, a dust collector for collecting dust from the cement kiln exhaust gas, and a collected dust outlet;
    A pressurized tank having a dust inlet from the first dust collection tank, an air inlet, and a dust air outlet, and for pneumatically transporting the dust by compressed air; provided that the first dust The dust outlet in the collection tank is above the dust inlet in the pressurized tank, and both are communicated by a first pipe.
    An air supply source for supplying dry compressed air having an atmospheric dew point of −35 ° C. or lower to the pressurized tank;
    A dust inlet that is pneumatically transported from the pressurized tank through the second pipe, a dust collector for collecting the dust, and a second dust collection tank having an air outlet;
    Air transport equipment for dust collected from exhaust gas from a cement kiln.
  2.  第一のダスト捕集タンクのセメントキルン排ガスの入口に流入する排ガスは、大気圧露点が10~40℃、温度が50~150℃となるように予め除湿及び冷却されている請求項1に記載の空気輸送設備。 The exhaust gas flowing into the cement kiln exhaust gas inlet of the first dust collection tank is dehumidified and cooled in advance so that the atmospheric dew point is 10 to 40 ° C and the temperature is 50 to 150 ° C. Air transport equipment.
  3.  空気供給源は吸着式エアドライヤ又はヒートレス式エアドライヤを有する請求項1又は2に記載の空気輸送設備。 The air transportation equipment according to claim 1 or 2, wherein the air supply source has an adsorption air dryer or a heatless air dryer.
  4.  加圧タンク内のガス温度が0~40℃である請求項1~3の何れか一項に記載の空気輸送設備。 The pneumatic transportation equipment according to any one of claims 1 to 3, wherein the gas temperature in the pressurized tank is 0 to 40 ° C.
  5.  加圧タンク内の圧力を監視する圧力スイッチ、
     加圧タンク内のダスト量を監視するレベルスイッチ、及び、
     加圧タンク内のダスト量が所定量に到達したことがレベルスイッチにより検知されると、第一のダスト捕集タンクからの加圧タンクへのダストの供給を停止し、加圧タンクを前記乾燥空気によって加圧し、所定の圧力に上昇したことが圧力スイッチにより検知されると第二のダスト捕集タンクへのダストの空気輸送を開始し、その後、所定の圧力に下降したことが圧力スイッチにより検知されるとダストの空気輸送を停止して、第一のダスト捕集タンクからの加圧タンクへのダストの供給を再開する制御機構を
    更に備えた請求項1~4の何れか一項に記載の空気輸送設備。
    Pressure switch to monitor the pressure in the pressurized tank,
    A level switch for monitoring the amount of dust in the pressurized tank; and
    When the level switch detects that the amount of dust in the pressurized tank has reached a predetermined level, the supply of dust from the first dust collection tank to the pressurized tank is stopped, and the pressurized tank is dried. When the pressure switch detects that the pressure has been increased by air and increased to a predetermined pressure, it starts air transportation of dust to the second dust collection tank, and then the pressure switch indicates that the pressure has decreased to the predetermined pressure. 5. A control mechanism according to claim 1, further comprising a control mechanism that stops pneumatic transportation of dust when detected and restarts supply of dust from the first dust collection tank to the pressurized tank. Pneumatic transport equipment as described.
  6.  第一のダスト捕集タンクからの加圧タンクへのダストの供給を停止してから、第一のダスト捕集タンクからの加圧タンクへのダストの供給を再開するまでの時間が10分以内である請求項5に記載の空気輸送設備。 Within 10 minutes from when the supply of dust from the first dust collection tank to the pressurized tank is stopped until the supply of dust from the first dust collection tank to the pressurized tank is resumed The pneumatic transportation equipment according to claim 5.
  7.  ダストが第一のダスト捕集タンクにおけるダストの出口から加圧タンクにおけるダストの入口へと第一の配管を通過中に、ダストが逆流しない程度の流量で加圧タンクから第一のダスト捕集タンクに向けて前記乾燥空気が第一の配管内を流れる請求項1~6の何れか一項に記載の空気輸送設備。 While dust passes through the first pipe from the dust outlet in the first dust collection tank to the dust inlet in the pressurized tank, the first dust collection from the pressurized tank at a flow rate that does not cause the dust to flow back. The pneumatic transportation equipment according to any one of claims 1 to 6, wherein the dry air flows in the first pipe toward the tank.
  8.  ダストを空気輸送中の加圧タンク内の圧力が0.1~0.5MPaGである請求項1~7の何れか一項に記載の空気輸送設備。 The pneumatic transportation equipment according to any one of claims 1 to 7, wherein the pressure in the pressurized tank during the pneumatic transportation of dust is 0.1 to 0.5 MPaG.
  9.  加圧タンクから第二のダスト捕集タンクへのダストの空気輸送中は、加圧タンク中のダストが加圧タンクに流入する前記乾燥空気によって流動状態にある請求項1~8の何れか一項に記載の空気輸送設備。 The dust in the pressurized tank is in a fluidized state by the dry air flowing into the pressurized tank during the pneumatic transportation of the dust from the pressurized tank to the second dust collecting tank. Pneumatic transportation equipment according to item.
  10.  加圧タンクが並列に2台以上設置されており、少なくとも一つの加圧タンクが空気輸送中には残りの加圧タンクの内少なくとも一つの加圧タンクに第一のダスト捕集タンクからダストが投入される請求項1~4の何れか一項に記載の空気輸送設備。 Two or more pressurized tanks are installed in parallel, and when at least one pressurized tank is pneumatically transported, at least one of the remaining pressurized tanks receives dust from the first dust collection tank. The pneumatic transportation equipment according to any one of claims 1 to 4, which is input.
  11.  加圧タンクの前段に一次貯留タンクが直列に設置されており、後段の加圧タンクが空気輸送中には第一のダスト捕集タンクから一次貯留タンクにダストが投入される請求項1~4の何れか一項に記載の空気輸送設備。 The primary storage tank is installed in series in front of the pressurized tank, and dust is thrown into the primary storage tank from the first dust collection tank while the latter pressurized tank is pneumatically transported. The pneumatic transport facility according to any one of the above.
  12.  請求項1~11の何れか一項に記載の空気輸送設備及びセメントキルン排ガスの抽気設備を備えたセメントキルン排ガスの処理システムであって、
     セメントキルン排ガスの抽気設備は、セメントキルン排ガスの一部を抽気するための抽気管と、抽気管内に除湿及び冷却のための空気を供給するための送風機と、抽気管の出口に連結された集塵用サイクロンと、サイクロンの出口に連結された空気冷却器と、空気冷却器内に除湿及び冷却のための空気を供給するための送風機と、誘引通風機とを備え、
     第一のダスト捕集タンクの出口は誘引通風機に連結されており、
     第二のダスト捕集タンクは捕集されたダストの出口を有し、当該出口はセメント製造用のミル又はセメントクリンカータンクに連通されている、
    セメントキルン排ガスの処理システム。
    A cement kiln exhaust gas treatment system comprising the pneumatic transportation facility according to any one of claims 1 to 11 and a cement kiln exhaust gas extraction facility,
    The extraction facility for cement kiln exhaust gas includes an extraction pipe for extracting a part of the cement kiln exhaust gas, a blower for supplying air for dehumidification and cooling into the extraction pipe, and a collector connected to the outlet of the extraction pipe. A dust cyclone, an air cooler connected to the outlet of the cyclone, a blower for supplying air for dehumidification and cooling into the air cooler, and an induction fan,
    The outlet of the first dust collection tank is connected to the induction fan,
    The second dust collection tank has an outlet for the collected dust, which is in communication with a mill or cement clinker tank for cement production;
    Cement kiln exhaust gas treatment system.
  13.  第二のダスト捕集タンクにおける空気の出口は前記誘引通風機に連結されている請求項12に記載のセメントキルン排ガスの処理システム。 The cement kiln exhaust gas treatment system according to claim 12, wherein an air outlet of the second dust collection tank is connected to the induction fan.
  14.  抽気管出口におけるガス流速を10m/s以上とする請求項12又は13に記載のセメントキルン排ガスの処理システム。 The cement kiln exhaust gas treatment system according to claim 12 or 13, wherein the gas flow rate at the outlet of the extraction pipe is 10 m / s or more.
PCT/JP2012/053866 2011-02-22 2012-02-17 Pneumatic transport facility for chlorine bypass dust, and cement kiln exhaust gas treatment system equipped with the facility WO2012115014A1 (en)

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JP2011036232A JP4746158B1 (en) 2011-02-22 2011-02-22 Chlorine bypass dust pneumatic transportation equipment and cement kiln exhaust gas treatment system equipped with the equipment

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CN116929081A (en) * 2023-09-18 2023-10-24 赣州有色冶金机械有限公司 Dust collection and discharging device and rotary reduction furnace with same

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JP2019164056A (en) * 2018-03-20 2019-09-26 東京電力ホールディングス株式会社 Fresh air leakage amount measurement method and fresh air leakage amount measuring device

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JP3318714B2 (en) * 1995-12-11 2002-08-26 太平洋セメント株式会社 Kiln exhaust gas treatment method and apparatus by chlorine bypass

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Publication number Priority date Publication date Assignee Title
CN116929081A (en) * 2023-09-18 2023-10-24 赣州有色冶金机械有限公司 Dust collection and discharging device and rotary reduction furnace with same
CN116929081B (en) * 2023-09-18 2023-12-01 赣州有色冶金机械有限公司 Dust collection and discharging device and rotary reduction furnace with same

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