WO2012108850A1 - Method of forming antimicrobial layer and products obtained with this method - Google Patents

Method of forming antimicrobial layer and products obtained with this method Download PDF

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Publication number
WO2012108850A1
WO2012108850A1 PCT/TR2012/000020 TR2012000020W WO2012108850A1 WO 2012108850 A1 WO2012108850 A1 WO 2012108850A1 TR 2012000020 W TR2012000020 W TR 2012000020W WO 2012108850 A1 WO2012108850 A1 WO 2012108850A1
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WO
WIPO (PCT)
Prior art keywords
products
porcelain
ceramic
glass
antimicrobial
Prior art date
Application number
PCT/TR2012/000020
Other languages
French (fr)
Inventor
Murat Erdem KURTOGLU
Original Assignee
Gurallar Yapi Malzemeleri Ve Kimya Sanayii Anonim Sirketi
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Publication date
Application filed by Gurallar Yapi Malzemeleri Ve Kimya Sanayii Anonim Sirketi filed Critical Gurallar Yapi Malzemeleri Ve Kimya Sanayii Anonim Sirketi
Publication of WO2012108850A1 publication Critical patent/WO2012108850A1/en

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/34—Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
    • C03C17/007—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2204/00—Glasses, glazes or enamels with special properties
    • C03C2204/02—Antibacterial glass, glaze or enamel
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/40—Coatings comprising at least one inhomogeneous layer
    • C03C2217/43—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
    • C03C2217/46—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase
    • C03C2217/47—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase consisting of a specific material
    • C03C2217/475—Inorganic materials
    • C03C2217/477—Titanium oxide
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/40—Coatings comprising at least one inhomogeneous layer
    • C03C2217/43—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
    • C03C2217/46—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase
    • C03C2217/47—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase consisting of a specific material
    • C03C2217/475—Inorganic materials
    • C03C2217/479—Metals
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00—Methods for coating glass
    • C03C2218/10—Deposition methods
    • C03C2218/11—Deposition methods from solutions or suspensions
    • C03C2218/112—Deposition methods from solutions or suspensions by spraying

Definitions

  • the invention relates to coating of glass, ceramic, metal (stainless steel, aluminium, brass etc.) and so on with substances comprising silver, copper, zinc, or titanium with antimicrobial activity during or after production.
  • cup, dishes etc. glass household goods used on tabletop or food storage container or bottle jar etc. can or packaging materials of beverage or drug etc. products or glazed porcelain ceramic dishes etc. tabletop goods or sink, closet etc. health equipments, and effective solutions are brought to the above given limitations.
  • the present invention relates to coating the surfaces of glass, ceramic, porcelain, and so on tabletop equipments and packaging materials made of glass, porcelain, and ceramic and tiling etc. products used as floor and wall tiling and closet, sink etc. health equipments by antimicrobial material via spray pirolysis method.
  • the antimicrobial solution material that would be used in the spray pirolysis method has to be prepared.
  • Non-leachable antimicrobial Ti0 2 part in 0 percent to 50 percent ratio iii) One or more of Zr0 2 or AI2O3 as alkali resistant material in 0.1 percent to 40 percent ratio; iv) Acid resistant part and S1O2 in 2 percent to 94.5 percent ratio; and v) Stabilizer, acetonitrile, pyridine etc. and preferably acetonitrile comprising amine group to be bonded to silver with the purpose of eliminating the undesired colours formed due to presence of silver, is applied in solution form on hot glass, ceramic, porcelain etc. products via spraying, direct applying, or immersion etc. any other method.
  • antimicrobial material has to comprise at least one leachable (Ag, Cu, or Zn) and/or optionally a non-leachable photo-active antimicrobial Ti0 2 .
  • the products to gain antimicrobial characteristics are repeatedly washed with detergents, they have to be basic or acidic resistant. It has to comprise Si0 2 in order to gain acidic resistance; and Zr0 2 or AI 2 O 3 , preferably Zr0 2 for basic resistance.
  • an organic substance comprising amine group that can be bonded to silver, preferably acetonitrile, has to be present.
  • composition For hot medium applications as functional agents, above said composition has to be prepared by being melted within; preferably methyl chloride and toluene having low combustible characteristics but high spontaneous combustion characteristics or water etc. organic solvents that do not have any combustion characteristics. Use of any solvent is suitable in cold applications. Said compound or solvents gain functionality by forming a metal oxide/metal layer on glass or porcelain etc. products and via melting of organic parts during contact in hot application and by means of an additional firing process in cold application. Said composition having antimicrobial characteristics is
  • the required temperature of the product has to be between 100 C° to 650 C°, but preferably between 125 C° to 550 C°.
  • product temperature has to be between 20 C° to 250 C°.
  • Said temperatures are applied in press-and-blow, press, blow-and-blow and IS (glass packaging machine) etc. machines before or after the packaging process.
  • IS glass packaging machine
  • Said molten composition comprising antimicrobial material can be applied via various methods.
  • the main one of these methods is spraying method.
  • Spraying method has the feature of easier and more effective application on the inner sides of glass products, such as the inner side of cups or storage containers or jars, bottle etc. products to be used as packaging materials.
  • Other methods comprise direct application, spraying, and immersion on dishes etc. products via certain tools.
  • methods listed here are only for exemplary purposes and are not restrictive.
  • antimicrobial characteristics can be given to ceramic, porcelain household goods or health equipments via application of molten composition having antimicrobial characteristics by means of spraying or another method at the above said temperatures after being taken out of the furnace and thus leaving metal oxide/metal layer on the surface.
  • This method is not only limited to glass, ceramic, porcelain etc. household goods and health equipments, and it can be applied on metal (stainless, brass etc.) using the same method.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Plant Pathology (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Composite Materials (AREA)
  • Agronomy & Crop Science (AREA)
  • Dispersion Chemistry (AREA)
  • Pest Control & Pesticides (AREA)
  • General Chemical & Material Sciences (AREA)
  • Toxicology (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Surface Treatment Of Glass (AREA)
  • Paints Or Removers (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention relates to coating the surfaces of glass, ceramic, porcelain, and so on tabletop equipments and packaging materials made of glass, porcelain, and ceramic and tiling etc. products used as floor and wall tiling and closet, sink etc. health equipments by antimicrobial material via spray pirolysis method.

Description

METHOD OF FORMING ANTIMICROBIAL LAYER AND PRODUCTS OBTAINED
WITH THIS METHOD
DESCRIPTION
THE RELATED ART The invention relates to coating of glass, ceramic, metal (stainless steel, aluminium, brass etc.) and so on with substances comprising silver, copper, zinc, or titanium with antimicrobial activity during or after production.
BACKGROUND OF THE INVENTION
In our day, wherein consumption has reached massive scale as a result of socialization of humanity, especially commercialization of human and animal food with increasing intensity has brought along microbic pollution. Various studies have been made within the last 20 years in order to prevent proliferation of diseases caused by microbes. Therefore, various materials are provided with characteristics that do not permit living of microbes via various tools and methods. Most significant ones among these comprise providing antimicrobial characteristics by making use of silver, zinc, titanium etc. metals.
Providing antimicrobial characteristics to the material being produced by means of adding the said active antimicrobial substances in certain ratios brings about significant problems. In order to provide adequate antimicrobial effect by addition of antimicrobial material obtained by a valuable metal such as silver, it has to be added in the ratio of 0.1 percent to 8 percent of the product weight. The most significant disadvantage of such an application is addition of antibacterial silver or similar antibacterial material in the rate of 0.1 percent to 8 percent of the total product weight. On the other hand, as a result of adding antimicrobial material, undesired characteristics may occur in some products due to the own characteristics of the products. For instance, in ceramic, porcelain etc. products, antimicrobial material added into glazing leads to colour change in glazing. In addition, it is known that antimicrobial material found in glazing degenerates in porcelain fired in high temperatures. In glass products, which are both used as household goods a\
limitations are found in antibacterial product usage due to the intrinsic characteristics of glass. These limitations can be listed as follows: first of all, both cup, dishes etc. household goods and bottle, jar etc. goods used as storage containers or packaging materials are relatively cheaper products than other ones. Therefore, addition of high cost antimicrobial material into the product constitution with 0.1 to 8 percent by weight ratio would cause significant increase in product cost. One of the solutions developed for overcoming this problem is disclosed in USA patent document no 6,797,278 B2 as coating antimicrobial material on the product via sol-gel method at low temperature. However, again a significant increase of cost is observed. With this method, an additional process is required in the production procedure of glass household goods or glass packaging materials. And this will naturally be a separate cost component.
Another limitation which couldn't be solved in antimicrobial coating methods is repeated washing of cup, dishes etc. glass household goods with basic detergents at high temperatures. Coatings that do not integrate with the glass surface lose their antimicrobial characteristics as a result of the chemical impact of the detergent and being exposed to high temperatures.
With the present invention, cheap, effective, and permanent antimicrobial coating is provided on cup, dishes etc. glass household goods used on tabletop or food storage container or bottle jar etc. can or packaging materials of beverage or drug etc. products or glazed porcelain ceramic dishes etc. tabletop goods or sink, closet etc. health equipments, and effective solutions are brought to the above given limitations.
DESCRIPTION OF THE INVENTION The present invention relates to coating the surfaces of glass, ceramic, porcelain, and so on tabletop equipments and packaging materials made of glass, porcelain, and ceramic and tiling etc. products used as floor and wall tiling and closet, sink etc. health equipments by antimicrobial material via spray pirolysis method.
First of all, the antimicrobial solution material that would be used in the spray pirolysis method has to be prepared. For this, the antimicrobial material prepared by using; i) One or more of leachable antimicrobial silver (Ag), c«
metals in 0.1 percent to 8 percent ratio; ii) Non-leachable antimicrobial Ti02 part in 0 percent to 50 percent ratio; iii) One or more of Zr02 or AI2O3 as alkali resistant material in 0.1 percent to 40 percent ratio; iv) Acid resistant part and S1O2 in 2 percent to 94.5 percent ratio; and v) Stabilizer, acetonitrile, pyridine etc. and preferably acetonitrile comprising amine group to be bonded to silver with the purpose of eliminating the undesired colours formed due to presence of silver, is applied in solution form on hot glass, ceramic, porcelain etc. products via spraying, direct applying, or immersion etc. any other method.
Above said antimicrobial material has to comprise at least one leachable (Ag, Cu, or Zn) and/or optionally a non-leachable photo-active antimicrobial Ti02.
On the other hand, as mentioned above, since the products to gain antimicrobial characteristics are repeatedly washed with detergents, they have to be basic or acidic resistant. It has to comprise Si02 in order to gain acidic resistance; and Zr02 or AI2O3, preferably Zr02 for basic resistance.
Again, in order to prevent formation of nano-silver that gives colour to the solution and coating to be used, an organic substance comprising amine group that can be bonded to silver, preferably acetonitrile, has to be present.
For hot medium applications as functional agents, above said composition has to be prepared by being melted within; preferably methyl chloride and toluene having low combustible characteristics but high spontaneous combustion characteristics or water etc. organic solvents that do not have any combustion characteristics. Use of any solvent is suitable in cold applications. Said compound or solvents gain functionality by forming a metal oxide/metal layer on glass or porcelain etc. products and via melting of organic parts during contact in hot application and by means of an additional firing process in cold application. Said composition having antimicrobial characteristics is
production of glass or porcelain etc. household goods and packaging material. Application is made on hot or cold product via spraying or a similar method. After application on hot product, organic substances found within the composition melt with the impact of heat. In this way, a metal oxide or metal layer having antimicrobial characteristics is coated on the product. An additional firing process (between 200 C° and 600 C°) is required in the cold product.
For application of the said composition, the required temperature of the product has to be between 100 C° to 650 C°, but preferably between 125 C° to 550 C°. In cold medium coatings, product temperature has to be between 20 C° to 250 C°.
Said temperatures are applied in press-and-blow, press, blow-and-blow and IS (glass packaging machine) etc. machines before or after the packaging process.
Said molten composition comprising antimicrobial material can be applied via various methods. The main one of these methods is spraying method. Spraying method has the feature of easier and more effective application on the inner sides of glass products, such as the inner side of cups or storage containers or jars, bottle etc. products to be used as packaging materials. Other methods comprise direct application, spraying, and immersion on dishes etc. products via certain tools. However, methods listed here are only for exemplary purposes and are not restrictive.
In the same way, antimicrobial characteristics can be given to ceramic, porcelain household goods or health equipments via application of molten composition having antimicrobial characteristics by means of spraying or another method at the above said temperatures after being taken out of the furnace and thus leaving metal oxide/metal layer on the surface.
This method is not only limited to glass, ceramic, porcelain etc. household goods and health equipments, and it can be applied on metal (stainless, brass etc.) using the same method.

Claims

1. The invention is the method of formation of an antimicrobial metal dioxide/metal layer said on the product and the product obtained with this method comprising one or more of silver (Ag), copper (Cu), or zinc (Zn) or optionally photo-active titanium dioxide (ΤΊΟ2) to provide antimicrobial activity, silisium dioxide (S1O2) to provide acidic resistance, Zr02 or Al203 or preferably Zr02 to provide basic resistance, and an organic compound comprising amine group, preferably acetonitrile, to prevent formation of silver-related undesired colours; and in hot medium applications, comprises dissolution of organic substances via preparing composition of the said ingredients together with methyl chloride and toluene etc. organic solvents and application on hot glass or porcelain or ceramic products between 100 C° to 650 C° temperature interval by means of spraying or another method; and in cold medium applications via wider variety of organic solvents, it is the method and the products obtained with this method comprising spraying of the same composition on glass, porcelain, and ceramic products between room temperature and 250 C° temperature and then firing between 250 C° and 600 C° and the products obtained with this method.
2. Composition prepared according to claim 1 , and it is characterized in that; it is applied on glass household goods, tabletop products, glass bottle, jar etc. packaging materials and has antimicrobial characteristics.
3. Composition prepared according to claim 1 , and it is characterized in that; it is applied on porcelain, ceramic etc. tabletop goods and it has antibacterial characteristics.
4. Composition prepared according to claim 1 , and it is characterized in that; porcelain ceramic medical equipments and it has antibacterial characteristics.
5. Composition prepared according to claim 1 , and it is characterized in that; it is applied on porcelain ceramic floor and wall covering products and has antibacterial characteristics.
6. Composition prepared according to claim 1 , and it is characterized in that; it is applied on metal (stainless steel, aluminium, brass etc.) products and it has antibacterial characteristics.
PCT/TR2012/000020 2011-02-09 2012-01-31 Method of forming antimicrobial layer and products obtained with this method WO2012108850A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
TR2011/01244A TR201101244A2 (en) 2011-02-09 2011-02-09 Antimicrobial Layer Forming Method and Products Obtained by This Method
TR2011/01244 2011-02-09

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103422080A (en) * 2013-08-20 2013-12-04 蒋春华 Preparation method of antimicrobial mould-proof stainless steel coating containing silver, zinc and cerium
CN108976475A (en) * 2018-07-18 2018-12-11 安徽江淮汽车集团股份有限公司 A kind of antibacterial agent and preparation method thereof
US10524598B2 (en) 2016-05-03 2020-01-07 Benny Green Easily cleanable drinking assembly
CN112694346A (en) * 2020-12-25 2021-04-23 同曦集团有限公司 Photocatalyst antibacterial mildew-proof porous ceramic and preparation method and application thereof
US12006338B2 (en) 2019-10-18 2024-06-11 Topikos Scientific, Inc. Antimicrobial organosilanes

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5180585A (en) * 1991-08-09 1993-01-19 E. I. Du Pont De Nemours And Company Antimicrobial compositions, process for preparing the same and use
US5503840A (en) * 1991-08-09 1996-04-02 E. I. Du Pont De Nemours And Company Antimicrobial compositions, process for preparing the same and use
WO1998041585A1 (en) * 1997-03-20 1998-09-24 Alliedsignal Inc. Alumina-based hydrophilic antimicrobial coating
US20030118624A1 (en) * 2001-12-21 2003-06-26 Delwin Jackson Antimicrobial sol-gel films comprising specific metal-containing antimicrobial agents

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5180585A (en) * 1991-08-09 1993-01-19 E. I. Du Pont De Nemours And Company Antimicrobial compositions, process for preparing the same and use
US5503840A (en) * 1991-08-09 1996-04-02 E. I. Du Pont De Nemours And Company Antimicrobial compositions, process for preparing the same and use
WO1998041585A1 (en) * 1997-03-20 1998-09-24 Alliedsignal Inc. Alumina-based hydrophilic antimicrobial coating
US20030118624A1 (en) * 2001-12-21 2003-06-26 Delwin Jackson Antimicrobial sol-gel films comprising specific metal-containing antimicrobial agents
US6797278B2 (en) 2001-12-21 2004-09-28 Milliken & Company Antimicrobial sol-gel films comprising specific metal-containing antimicrobial agents

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
ANDREW M P MCDONNELL ET AL: "Hydrophilic and Antimicrobial Zeolite Coatings for Graivty-Independent Water Separation", ADVANCED FUNCTIONAL MATERIALS, WILEY - V C H VERLAG GMBH & CO. KGAA, DE, vol. 15, no. 2, 1 February 2005 (2005-02-01), pages 336 - 340, XP002405731, ISSN: 1616-301X, DOI: 10.1002/ADFM.200400183 *
MIOLA M ET AL: "Surface silver-doping of biocompatible glasses to induce antibacterial properties. Part II: plasma sprayed glass-coatings", JOURNAL OF MATERIALS SCIENCE: MATERIALS IN MEDICINE, KLUWER ACADEMIC PUBLISHERS, BO, vol. 20, no. 3, 1 March 2009 (2009-03-01), pages 741 - 749, XP002571365, ISSN: 1573-4838, [retrieved on 20081106], DOI: 10.1007/S10856-008-3618-8 *

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103422080A (en) * 2013-08-20 2013-12-04 蒋春华 Preparation method of antimicrobial mould-proof stainless steel coating containing silver, zinc and cerium
CN103422080B (en) * 2013-08-20 2015-05-06 臣贤工贸（上海）有限公司 Preparation method of antimicrobial mould-proof stainless steel coating containing silver, zinc and cerium
US10524598B2 (en) 2016-05-03 2020-01-07 Benny Green Easily cleanable drinking assembly
CN108976475A (en) * 2018-07-18 2018-12-11 安徽江淮汽车集团股份有限公司 A kind of antibacterial agent and preparation method thereof
US12006338B2 (en) 2019-10-18 2024-06-11 Topikos Scientific, Inc. Antimicrobial organosilanes
US12024533B2 (en) 2019-10-18 2024-07-02 Topikos Scientific, Inc. Antimicrobial organosilanes
CN112694346A (en) * 2020-12-25 2021-04-23 同曦集团有限公司 Photocatalyst antibacterial mildew-proof porous ceramic and preparation method and application thereof

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