WO2012096585A3 - Method for production of dichloropropanols from glycerol - Google Patents

Method for production of dichloropropanols from glycerol Download PDF

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Publication number
WO2012096585A3
WO2012096585A3 PCT/PL2012/000001 PL2012000001W WO2012096585A3 WO 2012096585 A3 WO2012096585 A3 WO 2012096585A3 PL 2012000001 W PL2012000001 W PL 2012000001W WO 2012096585 A3 WO2012096585 A3 WO 2012096585A3
Authority
WO
WIPO (PCT)
Prior art keywords
dichloropropanols
stream
hydrochlorination
stage
directed
Prior art date
Application number
PCT/PL2012/000001
Other languages
French (fr)
Other versions
WO2012096585A2 (en
Inventor
Marian SPADŁO
Piotr SEMRAU
Marcin GOŹDZIKIEWICZ
Lech RUCZYŃSKI
Andrzej BRZEZICKI
Damian KIEŁKIEWICZ
Lech IWAŃSKI
Tadeusz KRAŚNIK
Sylwester KRZYŻANOWSKI
Grzegorz KIEŁKOWSKI
Marek KOZIEL
Tadeusz KOZIEL
Robert SZCZEPANIAK
Eryk REMIEZOWICZ
Ryszard SARNOWSKI
Original Assignee
Zakłady Chemiczne Zachem Spółka Akcyjna
Instytut Ciężkiej Syntezy Organicznej "BLACHOWNIA"
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zakłady Chemiczne Zachem Spółka Akcyjna, Instytut Ciężkiej Syntezy Organicznej "BLACHOWNIA" filed Critical Zakłady Chemiczne Zachem Spółka Akcyjna
Publication of WO2012096585A2 publication Critical patent/WO2012096585A2/en
Publication of WO2012096585A3 publication Critical patent/WO2012096585A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/62—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by introduction of halogen; by substitution of halogen atoms by other halogen atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Method for production of dichloropropanols from glycerol using continuous method, in the presence of acetic acid as a catalyst, with the catalyst concentration in the reacting mass varying in the range of 0.0005 to 0.007 mol/L, and the process of hydrochlorina¬ tion is carried out in the temperature range from 80 to 160°C, consists in the fact that hydrochlorination of glycerol is carried out in two stages, while in the first stage, glycer¬ ol is subjected to wet hydrochlorination using hydrochloric acid contained in the stream of acidic dichloropropanols, then the post-reaction mass from the first stage of hydro¬ chlorination is directed to a reactive column, in which completing the reaction of resi¬ dues of dissolved hydrogen chloride is carried out, as well as separation of the post- reaction mixture to stream of diluted dichloropropanols and decoction stream, which is directed to the second stage of dry hydrochlorination under pressure with gaseous hy¬ drogen chloride; after the second stage of hydrochlorination, the post-reaction mixture is directed to a distillation column, in which dewatering is carried out, while the distillate from the distillation column is directed to the first stage of glycerol hydrochlorination as a stream of acidic dichloropropanols, and the decoction being a stream of concentrated dichloropropanols is subjected to rectification.
PCT/PL2012/000001 2011-01-10 2012-01-04 Method for production of dichloropropanols from glycerol WO2012096585A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
PLP.393606 2011-01-10
PL393606A PL215730B1 (en) 2011-01-10 2011-01-10 Process for the preparation of dichloropropanols from glycerine

Publications (2)

Publication Number Publication Date
WO2012096585A2 WO2012096585A2 (en) 2012-07-19
WO2012096585A3 true WO2012096585A3 (en) 2012-11-08

Family

ID=45768275

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/PL2012/000001 WO2012096585A2 (en) 2011-01-10 2012-01-04 Method for production of dichloropropanols from glycerol

Country Status (2)

Country Link
PL (1) PL215730B1 (en)
WO (1) WO2012096585A2 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI585072B (en) * 2016-05-31 2017-06-01 國立清華大學 Apparatus for manufacturing dichlorohydrin and manufacturing method thereof
CN112573997A (en) * 2020-12-03 2021-03-30 浙江镇洋发展股份有限公司 Process for separating hydrogen chloride from crude dichloropropanol and separation equipment thereof
CN113731332A (en) * 2021-09-09 2021-12-03 黄山五环科技有限公司 Hydrogen chloride supply equipment for producing epoxy resin by glycerol method and supply method thereof

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0374342A (en) * 1989-08-10 1991-03-28 Daiso Co Ltd Continuous production of 2,3-dichloro-1-propanol and device therefor
WO2005054167A1 (en) * 2003-11-20 2005-06-16 Solvay (Société Anonyme) Process for producing dichloropropanol from glycerol, the glycerol coming eventually from the conversion of animal fats in the manufacture of biodiesel
FR2868419A1 (en) * 2004-04-05 2005-10-07 Solvay Sa Sa Belge Producing chlorinated organic compounds e.g. dichloropropanol involves using glycerol obtained from renewable raw materials, as a starting product
WO2006106154A1 (en) * 2005-05-20 2006-10-12 Solvay (Société Anonyme) Continuous method for making chlorhydrines
WO2009002585A1 (en) * 2007-04-12 2008-12-31 Dow Global Technologies Inc. Process and apparatus for producing chlorohydrin
TW200925143A (en) * 2007-12-04 2009-06-16 Chang Chun Plastics Co Ltd Process and apparatus for continuous preparing dichloropropanol
WO2009104961A2 (en) * 2008-02-21 2009-08-27 Bouwe De Jong Process for the preparation of a dichloropropanol product
WO2010076914A1 (en) * 2008-12-31 2010-07-08 Samsung Fine Chemicals Co., Ltd. Method of preparing dichloropropanol using glycerol with improved selectivity for dichloropropanol
PL210903B1 (en) * 2007-08-17 2012-03-30 Zakłady Chemiczne Zachem Społka Akcyjna The manner of obtaining monochloropropandiols and dichloropropanols

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL198551A1 (en) 1977-05-31 1978-04-10 Wyzsza Szkola Morska SYSTEM OF SINGLE-PHASE REGULATED THYRISTOR POWER SUPPLY WITH HIGH FREQUENCY
CZ20032346A3 (en) 2003-09-01 2005-04-13 Spolek Pro Chemickou A Hutní Výrobu,A.S. Process for preparing dichloropropanols from glycerin
CN102516205B (en) 2004-07-21 2016-05-04 兰科知识产权有限责任公司 Multihydroxylated-aliphatic hydrocarbon or its ester are to the conversion of chloropharin
WO2008074733A1 (en) 2006-12-19 2008-06-26 Akzo Nobel N.V. Process for the catalytic halogenation of a hydroxylated organic compound
PL211897B1 (en) 2007-10-05 2012-07-31 Inst Ciężkiej Syntezy Organicznej Blachownia The manner of production of the mixture of 1,3- and 2,3-dichloropropanol
ES2387000T3 (en) 2007-11-19 2012-09-11 Conser S.P.A. Conversion of glycerin to dichlorohydrins and epichlorohydrin
KR100881344B1 (en) 2007-12-12 2009-02-02 삼성정밀화학 주식회사 Method of preparing dichloropropanol from glycerol using heteropolyacid catalysts
RU2358964C1 (en) 2007-12-27 2009-06-20 Общество с ограниченной ответственностью "Синтез-2" Method of producing dichloropropanols
DE102008007622A1 (en) 2008-02-04 2009-08-06 Biopetrol Industries Ag Process for the preparation of epichlorohydrin from glycerol

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0374342A (en) * 1989-08-10 1991-03-28 Daiso Co Ltd Continuous production of 2,3-dichloro-1-propanol and device therefor
WO2005054167A1 (en) * 2003-11-20 2005-06-16 Solvay (Société Anonyme) Process for producing dichloropropanol from glycerol, the glycerol coming eventually from the conversion of animal fats in the manufacture of biodiesel
FR2868419A1 (en) * 2004-04-05 2005-10-07 Solvay Sa Sa Belge Producing chlorinated organic compounds e.g. dichloropropanol involves using glycerol obtained from renewable raw materials, as a starting product
WO2006106154A1 (en) * 2005-05-20 2006-10-12 Solvay (Société Anonyme) Continuous method for making chlorhydrines
WO2009002585A1 (en) * 2007-04-12 2008-12-31 Dow Global Technologies Inc. Process and apparatus for producing chlorohydrin
PL210903B1 (en) * 2007-08-17 2012-03-30 Zakłady Chemiczne Zachem Społka Akcyjna The manner of obtaining monochloropropandiols and dichloropropanols
TW200925143A (en) * 2007-12-04 2009-06-16 Chang Chun Plastics Co Ltd Process and apparatus for continuous preparing dichloropropanol
WO2009104961A2 (en) * 2008-02-21 2009-08-27 Bouwe De Jong Process for the preparation of a dichloropropanol product
WO2010076914A1 (en) * 2008-12-31 2010-07-08 Samsung Fine Chemicals Co., Ltd. Method of preparing dichloropropanol using glycerol with improved selectivity for dichloropropanol

Also Published As

Publication number Publication date
WO2012096585A2 (en) 2012-07-19
PL393606A1 (en) 2012-07-16
PL215730B1 (en) 2014-01-31

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