WO2012082684A3 - Integrated desulfurization and denitrification process including mild hydrotreating of aromatic-lean fraction - Google Patents

Integrated desulfurization and denitrification process including mild hydrotreating of aromatic-lean fraction Download PDF

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Publication number
WO2012082684A3
WO2012082684A3 PCT/US2011/064542 US2011064542W WO2012082684A3 WO 2012082684 A3 WO2012082684 A3 WO 2012082684A3 US 2011064542 W US2011064542 W US 2011064542W WO 2012082684 A3 WO2012082684 A3 WO 2012082684A3
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WIPO (PCT)
Prior art keywords
organosulfur
aromatic
organonitrogen compounds
compounds
organonitrogen
Prior art date
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PCT/US2011/064542
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French (fr)
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WO2012082684A2 (en
Inventor
Omer Refa Koseoglu
Abdennour Bourane
Farhan M. Al-Shahrani
Emad Al-Shafi
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Saudi Arabian Oil Company
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Publication date
Application filed by Saudi Arabian Oil Company filed Critical Saudi Arabian Oil Company
Priority to JP2013544670A priority Critical patent/JP5960719B2/en
Priority to CN201180067053.XA priority patent/CN103703107B/en
Priority to EP11849228.9A priority patent/EP2652091B1/en
Publication of WO2012082684A2 publication Critical patent/WO2012082684A2/en
Publication of WO2012082684A3 publication Critical patent/WO2012082684A3/en

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G21/00—Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/22—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing with hydrogen dissolved or suspended in the oil
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0053—Details of the reactor
    • B01J19/006—Baffles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
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    • B01J19/18—Stationary reactors having moving elements inside
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G21/00—Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents
    • C10G21/06—Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents characterised by the solvent used
    • C10G21/12—Organic compounds only
    • C10G21/16—Oxygen-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G21/00—Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents
    • C10G21/06—Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents characterised by the solvent used
    • C10G21/12—Organic compounds only
    • C10G21/20—Nitrogen-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G21/00—Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents
    • C10G21/06—Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents characterised by the solvent used
    • C10G21/12—Organic compounds only
    • C10G21/27—Organic compounds not provided for in a single one of groups C10G21/14 - C10G21/26
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • C10G27/12—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen with oxygen-generating compounds, e.g. per-compounds, chromic acid, chromates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • C10G27/14—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen with ozone-containing gases
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
    • C10G67/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
    • C10G67/04—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only including solvent extraction as the refining step in the absence of hydrogen
    • C10G67/0409—Extraction of unsaturated hydrocarbons
    • C10G67/0418—The hydrotreatment being a hydrorefining
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
    • C10G67/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
    • C10G67/12—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only including oxidation as the refining step in the absence of hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
    • C10G67/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
    • C10G67/14—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only including at least two different refining steps in the absence of hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00761—Details of the reactor
    • B01J2219/00763—Baffles
    • B01J2219/00765—Baffles attached to the reactor wall
    • B01J2219/00768—Baffles attached to the reactor wall vertical
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00761—Details of the reactor
    • B01J2219/00763—Baffles
    • B01J2219/00765—Baffles attached to the reactor wall
    • B01J2219/00777—Baffles attached to the reactor wall horizontal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1096—Aromatics or polyaromatics
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/44—Solvents

Abstract

Deep desulfurization of hydrocarbon feeds containing undesired organosulfur and organonitrogen compounds to produce a hydrocarbon product having low levels of sulfur-containing and nitrogen-containing compounds, is achieved by first subjecting the entire feed to an extraction zone to separate an aromatic-rich fraction containing a substantial amount of the refractory organosulfur and organonitrogen compounds and an aromatic-lean fraction containing a substantial amount of the labile organosulfur and organonitrogen compounds. The aromatic-lean fraction is contacted with a hydrotreating catalyst in a hydrotreating reaction zone operating under mild conditions to convert the labile organosulfur and organonitrogen compounds. The aromatic-rich fraction is oxidized to convert the refractory organosulfur and organonitrogen compounds to oxidized organosulfur and organonitrogen compounds. These oxidized organosulfur and organonitrogen compounds are subsequently removed, producing a stream containing reduced levels of organosulfur and organonitrogen compounds.
PCT/US2011/064542 2010-12-15 2011-12-13 Integrated desulfurization and denitrification process including mild hydrotreating of aromatic-lean fraction and oxidation of aromatic-rich fraction WO2012082684A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP2013544670A JP5960719B2 (en) 2010-12-15 2011-12-13 Desulfurization and denitrification integrated process including mild hydrotreatment of aromatic dilute fraction and oxidation of aromatic rich fraction
CN201180067053.XA CN103703107B (en) 2010-12-15 2011-12-13 The integrated desulphurization and denitrification method of dilute fragrant hydrocarbon-fraction is handled including mild hydrogenation
EP11849228.9A EP2652091B1 (en) 2010-12-15 2011-12-13 Integrated desulfurization and denitrification process including mild hydrotreating of aromatic-lean fraction and oxidation of aromatic-rich fraction

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12/968,431 US8741128B2 (en) 2010-12-15 2010-12-15 Integrated desulfurization and denitrification process including mild hydrotreating of aromatic-lean fraction and oxidation of aromatic-rich fraction
US12/968,431 2010-12-15

Publications (2)

Publication Number Publication Date
WO2012082684A2 WO2012082684A2 (en) 2012-06-21
WO2012082684A3 true WO2012082684A3 (en) 2014-01-03

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PCT/US2011/064542 WO2012082684A2 (en) 2010-12-15 2011-12-13 Integrated desulfurization and denitrification process including mild hydrotreating of aromatic-lean fraction and oxidation of aromatic-rich fraction

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US (2) US8741128B2 (en)
EP (1) EP2652091B1 (en)
JP (1) JP5960719B2 (en)
CN (1) CN103703107B (en)
WO (1) WO2012082684A2 (en)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101642695B1 (en) 2007-05-03 2016-07-27 오테라, 인코포레이티드 Product containing monomer and polymers of titanyls and methods for making same
US9206359B2 (en) 2008-03-26 2015-12-08 Auterra, Inc. Methods for upgrading of contaminated hydrocarbon streams
US8298404B2 (en) 2010-09-22 2012-10-30 Auterra, Inc. Reaction system and products therefrom
US8764973B2 (en) 2008-03-26 2014-07-01 Auterra, Inc. Methods for upgrading of contaminated hydrocarbon streams
US8894843B2 (en) 2008-03-26 2014-11-25 Auterra, Inc. Methods for upgrading of contaminated hydrocarbon streams
US9061273B2 (en) 2008-03-26 2015-06-23 Auterra, Inc. Sulfoxidation catalysts and methods and systems of using same
US9828557B2 (en) 2010-09-22 2017-11-28 Auterra, Inc. Reaction system, methods and products therefrom
US9200375B2 (en) 2011-05-19 2015-12-01 Calera Corporation Systems and methods for preparation and separation of products
US9005433B2 (en) * 2011-07-27 2015-04-14 Saudi Arabian Oil Company Integrated process for in-situ organic peroxide production and oxidative heteroatom conversion
US8574427B2 (en) * 2011-12-15 2013-11-05 Uop Llc Process for removing refractory nitrogen compounds from vacuum gas oil
TWI633206B (en) * 2013-07-31 2018-08-21 卡利拉股份有限公司 Electrochemical hydroxide systems and methods using metal oxidation
US9957621B2 (en) 2014-09-15 2018-05-01 Calera Corporation Electrochemical systems and methods using metal halide to form products
US10246647B2 (en) 2015-03-26 2019-04-02 Auterra, Inc. Adsorbents and methods of use
USD768844S1 (en) * 2015-05-18 2016-10-11 Saudi Arabian Oil Company Catalyst basket
US10266954B2 (en) 2015-10-28 2019-04-23 Calera Corporation Electrochemical, halogenation, and oxyhalogenation systems and methods
US10450516B2 (en) 2016-03-08 2019-10-22 Auterra, Inc. Catalytic caustic desulfonylation
CN106336889A (en) * 2016-10-13 2017-01-18 宁夏宝塔石化科技实业发展有限公司 Crude oil desulfurizer and preparation method and desulfurization process
US10683461B2 (en) * 2016-10-18 2020-06-16 Mawetal Llc Polished turbine fuel
US10619254B2 (en) 2016-10-28 2020-04-14 Calera Corporation Electrochemical, chlorination, and oxychlorination systems and methods to form propylene oxide or ethylene oxide
WO2018170130A1 (en) * 2017-03-14 2018-09-20 Alternative Petroleum Technologies, Inc. System and method for liquid hydrocarbon desulfurization
EP3645671A4 (en) 2017-06-26 2021-03-31 Alternative Petroleum Technologies, Inc. System and method for liquid hydrocarbon desulfurization
WO2019060345A1 (en) 2017-09-19 2019-03-28 Calera Corporation Systems and methods using lanthanide halide
US10590054B2 (en) 2018-05-30 2020-03-17 Calera Corporation Methods and systems to form propylene chlorohydrin from dichloropropane using Lewis acid
US10703998B2 (en) * 2018-10-22 2020-07-07 Saudi Arabian Oil Company Catalytic demetallization and gas phase oxidative desulfurization of residual oil
US11292970B2 (en) * 2019-11-05 2022-04-05 Saudi Arabian Oil Company Hydrocracking process and system including separation of heavy poly nuclear aromatics from recycle by oxidation
CN115260003A (en) * 2022-07-22 2022-11-01 煤炭科学技术研究院有限公司 Coal pyrolysis/gasification crude phenol impurity removal method and impurity removal system

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020035306A1 (en) * 2000-08-01 2002-03-21 Walter Gore Method of desulfurization and dearomatization of petroleum liquids by oxidation and solvent extraction
US20070102323A1 (en) * 2004-11-23 2007-05-10 Chinese Petroleum Corporation Oxidative desulfurization and denitrogenation of petroleum oils

Family Cites Families (45)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2749284A (en) 1950-11-15 1956-06-05 British Petroleum Co Treatment of sulphur-containing mineral oils with kerosene peroxides
NL283421A (en) * 1961-09-21
BE625074A (en) 1961-11-24
US3238119A (en) * 1962-12-19 1966-03-01 Exxon Research Engineering Co Nitrogen removal from hydrocracking feeds
US3551328A (en) * 1968-11-26 1970-12-29 Texaco Inc Desulfurization of a heavy hydrocarbon fraction
US4006076A (en) * 1973-04-27 1977-02-01 Chevron Research Company Process for the production of low-sulfur-content hydrocarbon mixtures
US4062762A (en) * 1976-09-14 1977-12-13 Howard Kent A Process for desulfurizing and blending naphtha
US4125458A (en) * 1977-10-31 1978-11-14 Exxon Research & Engineering Co. Simultaneous deasphalting-extraction process
US4359596A (en) 1981-08-03 1982-11-16 Exxon Research And Engineering Co. Liquid salt extraction of aromatics from process feed streams
US4592832A (en) 1984-09-06 1986-06-03 Exxon Research And Engineering Co. Process for increasing Bright Stock raffinate oil production
US4636299A (en) 1984-12-24 1987-01-13 Standard Oil Company (Indiana) Process for the manufacture of lubricating oils
US4909927A (en) 1985-12-31 1990-03-20 Exxon Research And Engineering Company Extraction of hydrocarbon oils using a combination polar extraction solvent-aliphatic-aromatic or polar extraction solvent-polar substituted naphthenes extraction solvent mixture
FR2635112B1 (en) 1988-08-02 1990-09-28 Inst Francais Du Petrole PROCESS FOR FRACTIONATION AND EXTRACTION OF HYDROCARBONS FOR OBTAINING AN ESSENCE WITH IMPROVED OCTANE INDEX AND AN IMPROVED SMOKE POINT KEROSENE
US5110445A (en) 1990-06-28 1992-05-05 Mobil Oil Corporation Lubricant production process
US5232854A (en) 1991-03-15 1993-08-03 Energy Biosystems Corporation Multistage system for deep desulfurization of fossil fuels
US5409599A (en) 1992-11-09 1995-04-25 Mobil Oil Corporation Production of low sulfur distillate fuel
US5880325A (en) 1993-09-07 1999-03-09 Exxon Research And Engineering Company Aromatics extraction from hydrocarbon oil using tetramethylene sulfoxide
US5753102A (en) 1994-11-11 1998-05-19 Izumi Funakoshi Process for recovering organic sulfur compounds from fuel oil
US5910440A (en) 1996-04-12 1999-06-08 Exxon Research And Engineering Company Method for the removal of organic sulfur from carbonaceous materials
JP3795574B2 (en) * 1996-04-12 2006-07-12 新日本石油株式会社 Low sulfur gas oil
US5824207A (en) 1996-04-30 1998-10-20 Novetek Octane Enhancement, Ltd. Method and apparatus for oxidizing an organic liquid
US6087544A (en) 1998-05-07 2000-07-11 Exxon Research And Engineering Co. Process for the production of high lubricity low sulfur distillate fuels
US6277271B1 (en) 1998-07-15 2001-08-21 Uop Llc Process for the desulfurization of a hydrocarbonaceoous oil
US6171478B1 (en) 1998-07-15 2001-01-09 Uop Llc Process for the desulfurization of a hydrocarbonaceous oil
JP3871449B2 (en) * 1998-10-05 2007-01-24 新日本石油株式会社 Hydrodesulfurization method of light oil
US6090270A (en) 1999-01-22 2000-07-18 Catalytic Distillation Technologies Integrated pyrolysis gasoline treatment process
FR2793256B1 (en) * 1999-05-05 2001-07-27 Total Raffinage Distrib PROCESS FOR OBTAINING LOW SULFUR OIL PRODUCTS BY DESULPHURIZING EXTRACTS
US6676829B1 (en) 1999-12-08 2004-01-13 Mobil Oil Corporation Process for removing sulfur from a hydrocarbon feed
US6402940B1 (en) 2000-09-01 2002-06-11 Unipure Corporation Process for removing low amounts of organic sulfur from hydrocarbon fuels
US6866772B2 (en) 2001-01-09 2005-03-15 Indian Oil Corporation Limited Extraction of aromatics from hydrocarbon oil using furfural-co-solvent extraction process
US6497813B2 (en) 2001-01-19 2002-12-24 Process Dynamics, Inc. Solvent extraction refining of petroleum products
US6827845B2 (en) 2001-02-08 2004-12-07 Bp Corporation North America Inc. Preparation of components for refinery blending of transportation fuels
US6623627B1 (en) 2001-07-09 2003-09-23 Uop Llc Production of low sulfur gasoline
US20030094400A1 (en) 2001-08-10 2003-05-22 Levy Robert Edward Hydrodesulfurization of oxidized sulfur compounds in liquid hydrocarbons
US7374666B2 (en) 2001-12-13 2008-05-20 Lehigh University Oxidative desulfurization of sulfur-containing hydrocarbons
US7318845B2 (en) 2002-07-10 2008-01-15 Applied Research Associates, Inc. Compact distillates fuel processor with effective sulfur removal process
EP1403358A1 (en) * 2002-09-27 2004-03-31 ENI S.p.A. Process and catalysts for deep desulphurization of fuels
FR2847260B1 (en) 2002-11-14 2006-07-14 Inst Francais Du Petrole DESULFURATION PROCESS COMPRISING A SELECTIVE HYDROGENATION STEP OF THE DIOLEFINS AND A STEP FOR EXTRACTING THE SULFUR COMPOUNDS
US7252756B2 (en) 2002-12-18 2007-08-07 Bp Corporation North America Inc. Preparation of components for refinery blending of transportation fuels
US7175755B2 (en) * 2003-05-06 2007-02-13 Petroleo Brasileiro S.A.-Petrobras Process for the extractive oxidation of contaminants from raw hydrocarbon streams
WO2005056728A2 (en) 2003-12-05 2005-06-23 Exxonmobil Research And Engineering Company Two-stage hydrotreating process for diesel fuel
KR20070091297A (en) 2004-12-29 2007-09-10 비피 코포레이션 노쓰 아메리카 인코포레이티드 Oxidative desulfurization process
FR2889539B1 (en) 2005-08-08 2011-05-13 Inst Francais Du Petrole PROCESS FOR THE DESULFURATION OF SPECIES COMPRISING ADSORPTION DESULFURATION OF LIGHT FRACTION AND HYDRODESULFURATION OF HEAVY FRACTION
US7744749B2 (en) 2005-09-08 2010-06-29 Saudi Arabian Oil Company Diesel oil desulfurization by oxidation and extraction
US8343336B2 (en) * 2007-10-30 2013-01-01 Saudi Arabian Oil Company Desulfurization of whole crude oil by solvent extraction and hydrotreating

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020035306A1 (en) * 2000-08-01 2002-03-21 Walter Gore Method of desulfurization and dearomatization of petroleum liquids by oxidation and solvent extraction
US20070102323A1 (en) * 2004-11-23 2007-05-10 Chinese Petroleum Corporation Oxidative desulfurization and denitrogenation of petroleum oils

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