WO2012082229A8 - Composition comprising cyclohexylbenzene and 1 - phenyl - 1 -methylcyclopentane and use thereof in oxidation processes - Google Patents

Composition comprising cyclohexylbenzene and 1 - phenyl - 1 -methylcyclopentane and use thereof in oxidation processes Download PDF

Info

Publication number
WO2012082229A8
WO2012082229A8 PCT/US2011/057330 US2011057330W WO2012082229A8 WO 2012082229 A8 WO2012082229 A8 WO 2012082229A8 US 2011057330 W US2011057330 W US 2011057330W WO 2012082229 A8 WO2012082229 A8 WO 2012082229A8
Authority
WO
WIPO (PCT)
Prior art keywords
methylcyclopentane
phenyl
composition
cyclohexylbenzene
oxidation processes
Prior art date
Application number
PCT/US2011/057330
Other languages
French (fr)
Other versions
WO2012082229A1 (en
Inventor
Jihad M. Dakka
Edmund J. Mozeleski
Charles M. Smith
Bryan A. Patel
Original Assignee
Exxonmobil Chemical Patents Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Chemical Patents Inc. filed Critical Exxonmobil Chemical Patents Inc.
Publication of WO2012082229A1 publication Critical patent/WO2012082229A1/en
Publication of WO2012082229A8 publication Critical patent/WO2012082229A8/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/74—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition with simultaneous hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C407/00—Preparation of peroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • C07C2529/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65 containing iron group metals, noble metals or copper
    • C07C2529/74—Noble metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • C07C2529/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65 containing iron group metals, noble metals or copper
    • C07C2529/76—Iron group metals or copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
    • C07C2601/08—Systems containing only non-condensed rings with a five-membered ring the ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Disclosed herein is an oxidation having: (i) greater than 0.2 wt% by weight of 1- phenyl- 1-methylcyclopentane; and (ii) greater than 50 wt% by weight of a second alkylaromatic compound. The composition may be oxidized to convert a portion of the 1- phenyl- 1-methylcyclopentane and/or the second alkylaromatic compound to an alkylaromatic oxygenate.
PCT/US2011/057330 2010-12-17 2011-10-21 Composition comprising cyclohexylbenzene and 1 - phenyl - 1 -methylcyclopentane and use thereof in oxidation processes WO2012082229A1 (en)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US201061424229P 2010-12-17 2010-12-17
US201061424236P 2010-12-17 2010-12-17
US61/424,236 2010-12-17
US61/424,229 2010-12-17
EP11151462 2011-01-19
EP11151462.6 2011-01-19

Publications (2)

Publication Number Publication Date
WO2012082229A1 WO2012082229A1 (en) 2012-06-21
WO2012082229A8 true WO2012082229A8 (en) 2012-10-04

Family

ID=43977987

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2011/057330 WO2012082229A1 (en) 2010-12-17 2011-10-21 Composition comprising cyclohexylbenzene and 1 - phenyl - 1 -methylcyclopentane and use thereof in oxidation processes

Country Status (1)

Country Link
WO (1) WO2012082229A1 (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20150119091A (en) * 2013-03-14 2015-10-23 엑손모빌 케미칼 패턴츠 인코포레이티드 Methyl-substituted biphenyl compounds, their production and their use in the manufacture of plasticizers
CN105829272A (en) * 2013-12-20 2016-08-03 埃克森美孚化学专利公司 Phenol composition
US10259759B2 (en) 2013-12-20 2019-04-16 Exxonmobil Chemical Patents Inc. Cyclohexylbenzene composition
EP3083538A2 (en) * 2013-12-20 2016-10-26 ExxonMobil Chemical Patents Inc. Process for making phenol and/or cyclohexanone
WO2015094952A1 (en) * 2013-12-20 2015-06-25 Exxonmobil Chemical Patents Inc. Process for making cyclohexylbenzene and/or phenol and/or cyclohexanone
US9708230B2 (en) * 2015-03-25 2017-07-18 Exxonmobil Chemical Patents Inc. Production of biphenyl compounds
TWI600640B (en) * 2015-03-31 2017-10-01 艾克頌美孚化學專利股份有限公司 Transalkylated cyclohexylbenzyl and biphenyl compounds
CN107438590A (en) 2015-03-31 2017-12-05 埃克森美孚化学专利公司 The cyclohexyl benzyl and biphenol compound of transfering alkylation

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3117135A1 (en) 1981-04-30 1982-11-18 Bayer Ag, 5090 Leverkusen CRYSTALLINE ALUMOSILICATE, METHOD FOR THE PRODUCTION THEREOF AND THE USE THEREOF FOR CATALYTICALLY CONVERTING METHANOL AND / OR DIMETHYL ETHER IN HYDROCARBONS
US4826667A (en) 1986-01-29 1989-05-02 Chevron Research Company Zeolite SSZ-25
US4954325A (en) 1986-07-29 1990-09-04 Mobil Oil Corp. Composition of synthetic porous crystalline material, its synthesis and use
IT1205681B (en) 1987-05-26 1989-03-31 Eniricerche Spa SYNTHETIC POROUS CRYSTALLINE MATERIAL CONTAINING SILICON AND BORON OXIDES
US5250277A (en) 1991-01-11 1993-10-05 Mobil Oil Corp. Crystalline oxide material
US5236575A (en) 1991-06-19 1993-08-17 Mobil Oil Corp. Synthetic porous crystalline mcm-49, its synthesis and use
US5362697A (en) 1993-04-26 1994-11-08 Mobil Oil Corp. Synthetic layered MCM-56, its synthesis and use
ES2124154B1 (en) 1995-11-08 1999-12-01 Univ Politecnica De Valencia C PREPARATION METHOD AND CATALYTIC PROPERTIES OF A MICROPOROUS SOLID WITH HIGH EXTERNAL SURFACE.
ES2105982B1 (en) 1995-11-23 1998-07-01 Consejo Superior Investigacion ZEOLITE ITQ-1
TW382146B (en) 1998-06-19 2000-02-11 United Microeletronics Corp Semiconductor step-down voltage device having low power consumption
US6037513A (en) 1998-07-09 2000-03-14 Mobil Oil Corporation Hydroalkylation of aromatic hydrocarbons
DE10015874A1 (en) 2000-03-30 2001-10-11 Creavis Tech & Innovation Gmbh Process for the preparation of aromatic alcohols, especially phenol
US6756030B1 (en) 2003-03-21 2004-06-29 Uop Llc Crystalline aluminosilicate zeolitic composition: UZM-8
US7326815B2 (en) 2005-12-27 2008-02-05 Exxonmobil Chemical Patents Inc. Selective oxidation of alkylbenzenes
US7874423B2 (en) 2007-08-22 2011-01-25 Aw Chang Corporation Device and method for displaying neckties
CN101687784B (en) 2007-08-22 2014-11-12 埃克森美孚化学专利公司 Oxidation of hydrocarbons
WO2009038900A1 (en) 2007-09-21 2009-03-26 Exxonmobil Chemical Patents Inc. Process for producing cyclohexylbenzene
US8178728B2 (en) 2008-04-14 2012-05-15 Exxonmobil Chemical Patents Inc. Process for producing cyclohexylbenzene
CN102015588B (en) 2008-04-25 2013-09-25 埃克森美孚化学专利公司 Process for producing phenol and/or cyclohexanone
US7579511B1 (en) 2008-10-10 2009-08-25 Exxonmobil Research And Engineering Company Process for making cyclohexylbenzene
CN105732304A (en) 2009-02-26 2016-07-06 埃克森美孚化学专利公司 Process for producing phenol
MY158196A (en) 2009-05-26 2016-09-15 Exxonmobil Chemical Patents Inc Transalkylation of polycyclohexylbenzenes

Also Published As

Publication number Publication date
WO2012082229A1 (en) 2012-06-21

Similar Documents

Publication Publication Date Title
WO2012082229A8 (en) Composition comprising cyclohexylbenzene and 1 - phenyl - 1 -methylcyclopentane and use thereof in oxidation processes
WO2013178668A3 (en) Surfactant solutions containing n-methyl-n-oleylglucamines and n-methyl-n-c12-c14-acylglucamines
WO2014206554A3 (en) Use of special n-methyl-n-acylglucamines in skin-cleaning agents and hand dishwashing agents
CA2891921C (en) Peroxide-stable oral care compositions
WO2011084553A3 (en) Compositions and uses of cis-1,1,1,4,4,4-hexafluoro-2-butene
MX2009011938A (en) Antimicrobial compositions, products, and methods of use.
WO2011053940A3 (en) Templated nanoconjugates
WO2011139702A3 (en) Modified nucleosides and oligomeric compounds prepared therefrom
WO2012068357A3 (en) Cosmetic compositions and methods for inhibiting or reducing trypsin activity based on cyclohexane- 1, 2, 3, 4, 5, 6 -hexol and a n-acyl amino acid compound
MX350446B (en) Environmentally preferred antimicrobial compositions.
WO2012170784A3 (en) Personal care compositions
MX368745B (en) Self-adhesive lavatory treatment compositions.
WO2011141110A3 (en) Photo-stabilizing agents
MY153516A (en) Sunscreen formula vanishing cream
WO2013020960A3 (en) Novel composition
WO2011052989A3 (en) Etching solution composition
WO2012051727A3 (en) Oxidative stable micellar compositions
WO2011006875A3 (en) Mineral fibres and their use
JP2011181765A5 (en)
WO2013101932A3 (en) Triclosan-free antibacterial soap
WO2013025990A3 (en) Lead-free solder compositions
MX355784B (en) Heat transfer fluid additive composition.
WO2013072674A3 (en) Depilatory compositions
WO2010148180A3 (en) Cosmetic compositions and methods for enhanced uv protection
EP3138850B8 (en) Compositions containing deoxycholic acid and 10% deionized water in ethanol, directed to the purification of deoxycholic acid

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 11778759

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase in:

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 11778759

Country of ref document: EP

Kind code of ref document: A1