WO2012082110A1 - Hydrocarbon refrigerant and detergent composition - Google Patents
Hydrocarbon refrigerant and detergent composition Download PDFInfo
- Publication number
- WO2012082110A1 WO2012082110A1 PCT/US2010/060277 US2010060277W WO2012082110A1 WO 2012082110 A1 WO2012082110 A1 WO 2012082110A1 US 2010060277 W US2010060277 W US 2010060277W WO 2012082110 A1 WO2012082110 A1 WO 2012082110A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- hydrocarbon
- composition
- refrigerant
- detergent
- detergent composition
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
- C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
- C09K5/042—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising compounds containing carbon and hydrogen only
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/50—Solvents
- C11D7/5004—Organic solvents
- C11D7/5027—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/24—Hydrocarbons
Definitions
- This present invention relates to hydrocarbon compositions.
- the present invention relates to hydrocarbon compositions used as refrigerants for air conditioners, refrigerators or the like, and further which may be used as a detergent for cleaning precision components, such as semiconductor chips, motherboards or the like.
- Chlorofluorocarbons such as dichlorodifluoromethane
- CFCs have been used due to their relatively safe incombustibility, high stability, and low toxicity. However, CFCs are known to aid in the depletion of the Earth' s ozone layer, thus exerting a dangerous influence upon the global environment. Due to this reason, the production and use of CFCs have been gradually reduced, and few CFCs are in use today.
- HFCs Hydrofluorocarbons
- 1,1,1,2- tetrafluoroethane and 1,1,1-trifloroethane are presently being utilized as replacements for CFCs.
- HFCs also cause degradation of the ozone layer, though to a lesser extent. Further, HFCs act as greenhouse gases, contributing to global warming.
- Hydrocarbon mixtures are presently being explored as replacements for CFCs and HFCs, due to their relatively benign effect on the environment.
- Conventional hydrocarbon compositions are generally used in combination with CFCs, HFCs or the like and, therefore, still provide some level of environmental hazard.
- One prior hydrocarbon refrigerant composition consists solely of a mixture of propane and butane.
- such a composition tends to decompose into its individual components (i.e., propane and butane) when leaking outside a cooling system or other apparatus.
- propane and butane the refrigerant left in the cooling system may also break down, requiring full replacement of the refrigerant, and possibly damaging the cooling apparatus.
- such a refrigerant has a low ignition temperature, on the order of 400° C.
- the usage of such a composition presents a safety hazard to those around the cooling apparatus.
- the hydrocarbon refrigerant and detergent composition is a hydrocarbon-based composition which may be used as a refrigerant for air conditioners, refrigerators or the like, and further which may be used as a detergent for cleaning precision components, such as semiconductor chips, motherboards or the like.
- the hydrocarbon composition includes about 5.0% ethane, about 60.0% propane, about 5.0% isobutene and about 30.0% butane by volume.
- the present invention relates to hydrocarbon compositions, which may be used as a refrigerant or a detergent.
- the hydrocarbon composition includes ethane, propane, isobutene and butane in combination.
- the hydrocarbon composition may be used as a refrigerant having a relatively high ignition temperature with minimal environmental impact.
- the hydrocarbon composition may further be used as a detergent, cleaner or the like for high precision and delicate electronic components, such as semiconductor chips, motherboards and the like.
- the hydrocarbon composition preferably includes about 5.0% ethane, 60.0% propane, 5.0% isobutene and 30.0% butane by volume. It should be understood that this preferred composition may include variations in the volume concentrations of each component by as much as 20%.
- the hydrocarbon composition having approximately 5.0% ethane, 60.0% propane, 5.0% isobutene and 30.0% butane by volume may be used as a replacement for a
- 1,1,1,2-tetrafluoroethane also called 1,1,1,2-tetrafluoroethane
- tetrafluoroethane is a common haloalkane refrigerant with thermodynamic properties similar to R-12 (dichlorodifluoromethane), but without its ozone depletion potential. It has the formula CH 2 FCF 3 , and a boiling point of -26.3°C (-15.34°F).
- the present hydrocarbon composition may replace R-134a in a refrigerator system, with the present hydrocarbon composition being as effective as R-134a, but in smaller quantities. For example, one fluid ounce of the present hydrocarbon refrigerant would produce the same result as using four fluid ounces of R-134a. Thus, by replacing R-134a with the present hydrocarbon composition, a refrigerator using the present hydrocarbon composition would require less energy to run as efficiently (since the compressor of the refrigeration unit would perform less work on the decreased volume).
- chlorodifluoromethane or difluoromonochloromethane is a
- hydrochlorofluorocarbon once commonly used as a propellant and in air
- This gas is commonly known as HCFC-22 or R-22. Its usage in these applications is being phased out due to ozone depletion potential and status as a potent greenhouse gas.
- the present hydrocarbon composition may be used as a replacement for R- 22, since it has no ozone depletion potential and no known greenhouse effects. Further, only 35 to 40%, by volume, of the present hydrocarbon composition is needed to replace R-22. As noted above, this requires the refrigerator or air conditioner (or similar apparatus) to use less energy for the same result.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Combustion & Propulsion (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Detergent Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/US2010/060277 WO2012082110A1 (en) | 2010-12-14 | 2010-12-14 | Hydrocarbon refrigerant and detergent composition |
CN2010800023249A CN102656246A (en) | 2010-12-14 | 2010-12-14 | Hydrocarbon refrigerant and detergent composition |
JP2012548943A JP2013508537A (en) | 2010-12-14 | 2010-12-14 | Hydrocarbon refrigerant and detergent composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/US2010/060277 WO2012082110A1 (en) | 2010-12-14 | 2010-12-14 | Hydrocarbon refrigerant and detergent composition |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2012082110A1 true WO2012082110A1 (en) | 2012-06-21 |
Family
ID=46244999
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2010/060277 WO2012082110A1 (en) | 2010-12-14 | 2010-12-14 | Hydrocarbon refrigerant and detergent composition |
Country Status (3)
Country | Link |
---|---|
JP (1) | JP2013508537A (en) |
CN (1) | CN102656246A (en) |
WO (1) | WO2012082110A1 (en) |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20050086950A1 (en) * | 2003-10-28 | 2005-04-28 | Ajay Khatri | Closed cycle refrigeration system and mixed component refrigerant |
US20060120891A1 (en) * | 2002-12-20 | 2006-06-08 | Won-Hyun Jung | Reciprocating compressor for compressing refrigerant |
US20090127497A1 (en) * | 2007-11-16 | 2009-05-21 | Spatz Mark W | Hydrofluorocarbon/trifluoroiodomethane/ hydrocarbons refrigerant compositions |
KR20100108385A (en) * | 2007-12-26 | 2010-10-06 | 요시노부 신카와 | Hydrocarbon mixture refrigerant, freezing/refrigerating or air-conditioning system, freezing/refrigerating or air-conditioning method, and process for producing freezing/refrigerating or air-conditioning system |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3452915B1 (en) * | 2002-07-03 | 2003-10-06 | エー・エス・トラスト アンド ホールディングズ インク | Hydrocarbon composition used as refrigerant and cleaning agent |
-
2010
- 2010-12-14 JP JP2012548943A patent/JP2013508537A/en active Pending
- 2010-12-14 CN CN2010800023249A patent/CN102656246A/en active Pending
- 2010-12-14 WO PCT/US2010/060277 patent/WO2012082110A1/en active Application Filing
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20060120891A1 (en) * | 2002-12-20 | 2006-06-08 | Won-Hyun Jung | Reciprocating compressor for compressing refrigerant |
US20050086950A1 (en) * | 2003-10-28 | 2005-04-28 | Ajay Khatri | Closed cycle refrigeration system and mixed component refrigerant |
US20090127497A1 (en) * | 2007-11-16 | 2009-05-21 | Spatz Mark W | Hydrofluorocarbon/trifluoroiodomethane/ hydrocarbons refrigerant compositions |
KR20100108385A (en) * | 2007-12-26 | 2010-10-06 | 요시노부 신카와 | Hydrocarbon mixture refrigerant, freezing/refrigerating or air-conditioning system, freezing/refrigerating or air-conditioning method, and process for producing freezing/refrigerating or air-conditioning system |
Also Published As
Publication number | Publication date |
---|---|
CN102656246A (en) | 2012-09-05 |
JP2013508537A (en) | 2013-03-07 |
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