WO2012070157A1 - Shrinking pack cosmetic - Google Patents

Shrinking pack cosmetic Download PDF

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Publication number
WO2012070157A1
WO2012070157A1 PCT/JP2010/071425 JP2010071425W WO2012070157A1 WO 2012070157 A1 WO2012070157 A1 WO 2012070157A1 JP 2010071425 W JP2010071425 W JP 2010071425W WO 2012070157 A1 WO2012070157 A1 WO 2012070157A1
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WO
WIPO (PCT)
Prior art keywords
pack
albumin
water
shrinkable
cosmetic
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PCT/JP2010/071425
Other languages
French (fr)
Japanese (ja)
Inventor
泰良 北野
昭夫 南出
佐佳 菅谷
Original Assignee
株式会社シーヴァ
株式会社ヘルスガイド
株式会社カラーズ
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Publication date
Application filed by 株式会社シーヴァ, 株式会社ヘルスガイド, 株式会社カラーズ filed Critical 株式会社シーヴァ
Priority to JP2012545591A priority Critical patent/JP5829620B2/en
Priority to KR1020137014241A priority patent/KR20130086622A/en
Priority to PCT/JP2010/071425 priority patent/WO2012070157A1/en
Publication of WO2012070157A1 publication Critical patent/WO2012070157A1/en

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Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0212Face masks
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37Esters of carboxylic acids
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/64Proteins; Peptides; Derivatives or degradation products thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin

Definitions

  • the present invention relates to a pack cosmetic having contractility.
  • Cosmetic packs also called mask packs, are used by covering the surface of the skin in a film form, and there are types such as a sheet type, a cream type, and a peel-off type. Packs are known to effectively permeate cosmetic ingredients into the skin, and to remove pore dirt and old keratin by blending clay, etc. . If such a pack has physical effects such as shrinkage, it will be possible to penetrate the active ingredient into the skin while tightening tight skin and open pores. It can be expected to produce a beauty effect with immediate effect, which is a big selling point. However, such shrinkable face packs are not currently recognized and cannot be found in the prior art.
  • JP-A-3-190810 discloses (A) 1 to 20% by weight of a water-swellable clay mineral selected from bentonite, montmorillonite, saponite and hectorite, (B) poly (meth) acrylic acid ester, poly Contains 0.1 to 20% by weight of a synthetic resin emulsion resin selected from vinyl acetate, polyvinyl chloride, polyethylene vinyl and polyisobutylene, and (A) and (B) (as resin) Clay-like pack cosmetics having a blending ratio in the range of 10: 1 to 1: 6 are disclosed.
  • the invention of the same number is used by mixing two components (A) and (B), and is described as having a tension at the time of use, and it is also described that the effect of removing sebum is excellent. Yes. However, there is no description that it is a pack that exhibits contractility, and the component that should provide contractility is not described in the present invention. Moreover, the method of mixing the two agents is to cause a chemical reaction by mixing the two agents, and cannot be used unless the two components are mixed immediately before packing. Otherwise, problems such as immediate solidification will occur, and it goes without saying that it takes time to mix the two agents.
  • the present invention has been made paying attention to the above points, and the problem is that the pack has the property that it shrinks simultaneously with application to the skin and drying, and the labor of mixing the two agents is reduced. It is intended to provide a shrinkable pack cosmetic that can be used as it is without being required. In addition, another object of the present invention is to provide a one-pack type shrinkable pack cosmetic that has stability that does not harden or deteriorate even when left in a container for a long period of time. That is.
  • the present invention provides a pack cosmetic that adheres to the skin and contracts, and is 30 to 90% water, 3 to 65% albumin, and 2 to 7% emulsion base material by mass ratio. , 0.05 to 0.3% of a preservative and 0.5 to 3% of a solvent.
  • a pack cosmetic that adheres to the skin and contracts, and is 30 to 90% water, 3 to 65% albumin, and 2 to 7% emulsion base material by mass ratio. , 0.05 to 0.3% of a preservative and 0.5 to 3% of a solvent.
  • Each of the above components can be added to the emulsifier and stirred under the required temperature conditions and cooled to obtain the shrinkable pack cosmetic of the present invention.
  • No special manufacturing method is required, and it can be manufactured by a known technique for manufacturing cosmetics.
  • the pack manufactured with the above component ratio makes the skin feel a significant contraction force mainly by the action of albumin.
  • the present invention also provides 30 to 90% water, 3 to 65% albumin, 2 to 7% emulsion base material, 0.05 to 0.3% preservative and 0.5 to 3 by mass ratio. % Of solvent as an essential component, and further containing 0.1 to 5% clay, 0.0005 to 0.05% APPS, and 0.05 to 1% hyaluronic acid with the total amount as 100%. It is characterized by this.
  • the pack material manufactured with the said component ratio exhibits the remarkable effect which adsorb
  • Albumin has a property of shrinking with the progress of drying, and constitutes a main component in the pack of the present invention.
  • the albumin By controlling solidification accompanying drying, the albumin can be left in a state filled for about 3 years. It shall be stable and will not harden or deteriorate.
  • the amount of components required is 3 to 65% because the shrinkage force is too short when the mass ratio is less than 3%, and the shrinkage force becomes excessive when the mass ratio exceeds 65%.
  • Purified water is used as the water, and the amount is determined in inverse proportion to the amount of albumin. That is, the amount of water is small when the amount of albumin is large, and the amount of water is large when the amount of albumin is small.
  • the lower limit of the component amount is 30%, which is too hard to use as a pack, and the upper limit is 90%, which is too soft.
  • the albumin is known as a main component of the protein constituting the egg white, and the egg albumin constituting the egg white can also be used in the present invention.
  • a pack agent with albumin as the main component By properly preparing a pack agent with albumin as the main component and applying it to the skin, drying and solidification starts with the passage of time, along with the progress of skin shrinkage, dirt entering the pores, Sebum etc. will be excluded.
  • the shrinkage force as a pack agent is required for drying and solidification of albumin, and the long-term stability required for cosmetics is adjusted by so-called additives.
  • the emulsion base is used to make the pack of the present invention into a cream form, and when the above-mentioned pack of the present invention mainly composed of albumin is applied to the skin, it is easy to spread.
  • Either an oil-in-water type (o / w) or a water-in-oil type (w / o) can be used.
  • the amount of components necessary for the present invention is suitably 2 to 7%. If it is less than 2%, the spreadability is insufficient, and if it exceeds 7%, the spreadability is excessive.
  • As the above-mentioned emulsion base material there is a commercially available product that can be suitably used for albumin.
  • Sepigel 305 SEPIGEL 305; polyacrylamide, hydrogenated polyisobutene, laureth-7 and water as main components
  • Simalgel NS (SIMULGEL NS; hydroxyethyl acrylate / acryloyldimethyltaurine Na) copolymer, squalane. , Polysorbate 60 and water as main components
  • Sepinov EMT SEPINOV EMT10; (based on hydroxyethyl acrylate / acryloyldimethyltaurine Na) copolymer).
  • a preservative is necessary, and in the present invention, one or more of methylparaben, ethylparaben, propylparaben, butylparaben, and phenoxyethanol can be freely selected. it can.
  • the component amount of the preservative is required to be at least 0.05%, and when it exceeds 0.3%, it tends to precipitate, so 0.05 to 0.3% is preferable.
  • a solvent or a humectant is added to the preservative.
  • the solvent or humectant can be freely selected from one or more of butylene glycol, propylene glycol and pentanediol.
  • the amount of the solvent or humectant component depends on the amount of the preservative, but is generally 0.5 to 3%.
  • the shrinkable pack material of the present invention can take a form to which clay, APPS, hyaluronic acid and the like are added in order to further enhance the cosmetic effect.
  • Clay is said to have a function of adsorbing skin dirt mainly composed of protein, and among them, Okinawa fine particle clay called kukua is suitable.
  • the amount of the clay component necessary for obtaining the effect is 0.1 to 5%.
  • APPS is one of vitamin C derivatives (ascorbic acid-2-phosphate-6 palmitic acid), which is known as a highly osmotic vitamin and is said to have a pore tightening effect.
  • the component amount is suitably 0.0005 to 0.05%.
  • Hyaluronic acid is said to have a moisturizing effect, and an appropriate component amount is 0.05 to 1%.
  • an appropriate component amount is 0.05 to 1%.
  • an example of a known technique in the production of cosmetics that can be applied in producing the shrinkable pack material of the present invention is as follows. In other words, the required amount of water is added to the vacuum emulsifier and heated, and the above-mentioned emulsion base material, preservative and solvent components are added in necessary amounts, if necessary, and constantly stirred and mixed. While repeating the above, albumin is added in small portions several times and stirred sufficiently so that albumin does not harden.
  • the system is cooled to an appropriate temperature, and further necessary operations such as deaeration and cooling are performed while stirring is continued.
  • the obtained bulk is packaged, packed and shipped after filling the container, but it can also be stored frozen in the bulk and thawed after the fact and shipped.
  • a one-pack type shrinkable pack cosmetic that does not require the trouble of mixing two agents with albumin as a main ingredient can be realized and removed from a package or a container.
  • the pack exhibits the remarkable effect of adsorbing and removing dirt that has entered the pores due to the action of clay.
  • a shrinkable pack cosmetic can be provided.
  • the shrinkable pack material was manufactured.
  • the shrinkable pack material of Example 1 obtained was a one-pack type pack cosmetic, so that it could be applied to the skin as it was, and it was excellent in spreadability and took some time to dry. The contractile force could be felt on the skin, and good moisture retention was exhibited.
  • Optimum albumin content with 49.8% water, 45% albumin, 3% emulsion base, 2% preservative and 0.2% solvent as the main components and blend ratio
  • a shrinkable pack material As in Example 1, purified water as water, egg albumin as albumin, Sepigel 305 (SEPIGEL 305; mainly composed of polyacrylamide, hydrogenated polyisobutene, laureth-7 and water) as an emulsion base, antiseptic. Methyl paraben was used as the agent and butylene glycol was used as the solvent.
  • Purified water is added to the vacuum emulsifier, heated to 40 ° C., methyl paraben added to butylene glycol and heated and dissolved, and then poured into purified water.
  • Sepigel 305 stirring and mixing are performed. Is added in small portions in several batches, and the charging and stirring are repeated until it is familiar. Furthermore, it cools to 30 degreeC, continuing stirring and mixing. Thereafter, stirring with a paddle and stirring with a homomixer were carried out until there was no lumps (see above), and finally only paddle stirring was performed, followed by deaeration and cooling to produce a shrinkable pack material.
  • the resulting shrinkable pack material of Example 2 has moderate spreading properties, is not sticky, and dries in about 10 minutes, which is the same as the standard pack material. As the drying progresses, the shrinkage force is applied to the skin. It can be felt and is easy to use as a one-pack type cosmetic pack, and it makes the skin feel a strong contraction force.
  • the upper limit of the albumin content is 34.8% water, 60% albumin, 3% emulsion base, 2% preservative and 0.2% solvent as the main components and blending ratio. It is an example of a near shrinkable pack fee.
  • purified water as water, egg albumin as albumin, Sepigel 305 as the emulsion base (SEPIGE 305; polyacrylamide, hydrogenated polyisobutene, laureth-7 and water as main components), antiseptic. Methyl paraben was used as the agent and butylene glycol was used as the solvent.
  • Purified water is added to the vacuum emulsifier, heated to 40 ° C., butened with methylparaben added to butylene glycol and dissolved in heated water, and sepigel 305 is added, followed by stirring and mixing.
  • it is added in small portions in several batches, and charging and stirring are repeated until the whole is familiar. Furthermore, it cools to 30 degreeC, continuing stirring and mixing. Thereafter, stirring with a paddle and stirring with a homomixer were carried out until there was no lumps (see above), and finally only paddle stirring was performed, followed by deaeration and cooling to produce a shrinkable pack material.
  • the obtained shrinkable pack material of Example 3 is a one-pack type pack cosmetic, and although a slight decrease in spreadability was observed, it showed strong adhesion and was shorter in time than the standard pack material. Dried and felt a strong contraction force on the skin.
  • the clay used was a fine clay from Okinawa called Kucha. 60% of the fine particle clay had a particle size of about 5 ⁇ m, and the amount of the component was 3% in terms of the mass ratio, with the total amount of the shrinkable pack material of Example 2 being 100%. The lower of the ranges.
  • the component amount of APPS was similarly 0.01%, and the component amount of hyaluronic acid was also 0.01%. These clay, APPS, and hyaluronic acid were added after the Sepigel 305 was added.
  • the shrinkable pack material of the present invention was produced in the same manner as in Example 2.
  • the obtained shrinkable pack material of Example 4 is also a one-pack type pack cosmetic, showing properties almost similar to those of Example 2, having an appropriate spreadability, non-sticky, and dry.
  • the time did not change, and the skin felt a strong contraction force.
  • Example 4 it is an example of a form in which clay, APPS, and hyaluronic acid are added in order to further enhance the cosmetic effect with the shrinkable pack material having the main component and blending ratio of Example 2 as essential components.
  • the clay used was also a fine particle clay having a particle size of about 5 ⁇ m in 60%, and the amount of the component was 5% by mass with the total amount of the shrinkable pack material of Example 2 being 100%. Both the amount and the component amount of hyaluronic acid are 0.01%.
  • the shrinkable pack material of the present invention was produced by the same method as in Example 2 except that these clay, APPS, and hyaluronic acid were added after the Sepigel 305 was added.
  • the obtained shrinkable pack material of Example 5 is also a one-pack type pack cosmetic, showing properties almost similar to those of Example 2, having an appropriate spreadability, not sticky, and dry.
  • the time did not change, and the skin felt a strong contraction force. Therefore, due to the protein adsorbing effect of fine particle clay and APPS, pore stains disappeared to an inconspicuous level, and a moist feeling of skin considered to be due to moisture retention could be obtained.
  • the present invention is a one-pack type shrinkable pack cosmetic, it does not seem to harden immediately without taking a method of causing a chemical reaction by the mixing of two agents to shrink. No troubles occur. Therefore, the shrinkable pack can be used as it is without taking a complicated preparation, taking it out from the package or the container.
  • the shrinkable pack material of the present invention is a so-called cream-type pack material, and in the standard specification, drying starts in a few minutes and finishes drying in a few dozen minutes. Can get the feeling that the whole face is tightened. Further, since the shrinkable pack material of the present invention is water-soluble, it can be easily washed away with lukewarm water after finishing the pack, and combined with the one-pack type, is extremely simple to use. .

Abstract

Provided is a one-agent shrinking pack cosmetic that shrinks as the pack is applied on the skin and dried, does not require the work of mixing two agents but can be used as such out of the packaging or container, and has a stability such that it does not harden or deteriorate even when left for long periods filled in a container. In mass ratios, the shrinking pack cosmetic is obtained from 30-90% of water, 3-65% of albumin, 2-7% of an emulsion base, 0.05-0.3% of a preservative and 0.5-3% of a solvent.

Description

収縮性パック化粧料Shrinkable pack cosmetic
 本発明は、収縮性を有するパック化粧料に関するものである。 The present invention relates to a pack cosmetic having contractility.
 マスク・パックなどともいわれる化粧用のパックは、皮膚表面を膜状に覆って使用するものであり、シートタイプ、クリームタイプ及びピール・オフタイプなどの種類がある。パックは、美容成分を効果的に肌に浸透させたり、クレイなどを配合することで毛穴汚れや古い角質等を取り去ったりする効果を有し、全体として著しい美容効果を奏することで知られている。このようなパックに、収縮性等の物理的効果が備われば、たるんだ肌や、開いた毛穴を引き締めながら有効成分を肌に浸透させることが可能となり、そのような特性を有しないパックよりも高く、即効性のある美容効果が期待でき、大きなセールスポイントとなる。しかし、そのような収縮性を有するフェイスパックは、現在のところ認知されておらず、先行技術にも見出すことができない。
 これに対して特開平3−190810号は、(A)ベントナイト、モンモリロナイト、サポナイト及びヘクトライトから選ばれる水膨潤性粘土鉱物1~20重量%、(B)ポリ(メタ)アクリル酸エステル系、ポリ酢酸ビニル系、ポリ塩化ビニル系、ポリエチレンビニル系及びポリイソブチレン系から選ばれる合成樹脂エマルジョン樹脂分として0.1~20重量%を含有し、(A)と(B)の(樹脂分として)の配合比を10:1~1:6の範囲としたクレイ状パック化粧料を開示している。同号の発明は二つの成分(A)と(B)を混合して使用するもので、使用時の緊張感があると記載されており、それによる皮脂除去効果が優れているとも記載されている。しかし、収縮性を発揮するパックであるとの記載はなく、また、収縮性をもたらすべき成分も、同発明には記載されていない。
 しかも、2剤を混合するという方法は、2剤の混合によって化学反応を起こさせるためであり、パックをする直前に2成分を混合するのでなければ使用することができないのである。そうしなければ、直ぐに固まってしまうなどの不具合を生じるものであるからであり、2剤を混合する作業に手間のかかることは言うまでもない。これに対して、2成分系の組成物を1剤化することも不可能ではないが、化粧品に期待される使用期間の目安として、3年程度の長期間放置しても固まったり変質したりすることのない、安定性を備えたパック剤を製造することは簡単ではない。
Cosmetic packs, also called mask packs, are used by covering the surface of the skin in a film form, and there are types such as a sheet type, a cream type, and a peel-off type. Packs are known to effectively permeate cosmetic ingredients into the skin, and to remove pore dirt and old keratin by blending clay, etc. . If such a pack has physical effects such as shrinkage, it will be possible to penetrate the active ingredient into the skin while tightening tight skin and open pores. It can be expected to produce a beauty effect with immediate effect, which is a big selling point. However, such shrinkable face packs are not currently recognized and cannot be found in the prior art.
On the other hand, JP-A-3-190810 discloses (A) 1 to 20% by weight of a water-swellable clay mineral selected from bentonite, montmorillonite, saponite and hectorite, (B) poly (meth) acrylic acid ester, poly Contains 0.1 to 20% by weight of a synthetic resin emulsion resin selected from vinyl acetate, polyvinyl chloride, polyethylene vinyl and polyisobutylene, and (A) and (B) (as resin) Clay-like pack cosmetics having a blending ratio in the range of 10: 1 to 1: 6 are disclosed. The invention of the same number is used by mixing two components (A) and (B), and is described as having a tension at the time of use, and it is also described that the effect of removing sebum is excellent. Yes. However, there is no description that it is a pack that exhibits contractility, and the component that should provide contractility is not described in the present invention.
Moreover, the method of mixing the two agents is to cause a chemical reaction by mixing the two agents, and cannot be used unless the two components are mixed immediately before packing. Otherwise, problems such as immediate solidification will occur, and it goes without saying that it takes time to mix the two agents. On the other hand, it is not impossible to make a two-component composition into a single agent, but as a guideline for the expected period of use for cosmetics, it can be hardened or deteriorated after being left for a long period of about 3 years. It is not easy to produce a stable pack that does not.
 本発明は前記の点に着目してなされたものであって、その課題は、パックが肌への塗布、乾燥と同時に収縮するという特性を有しており、かつ、2剤を混合する手間を必要とせず、包装又は容器から取り出してそのまま使用できる収縮性パック化粧料を提供することである。また、本発明の他の課題は、容器に充填した状態で長期間放置しても、固まったり変質したりすることのない安定性を備えた、1剤型の収縮性パック化粧料を提供することである。 The present invention has been made paying attention to the above points, and the problem is that the pack has the property that it shrinks simultaneously with application to the skin and drying, and the labor of mixing the two agents is reduced. It is intended to provide a shrinkable pack cosmetic that can be used as it is without being required. In addition, another object of the present invention is to provide a one-pack type shrinkable pack cosmetic that has stability that does not harden or deteriorate even when left in a container for a long period of time. That is.
 前記の課題を解決するため、本発明は、皮膚に付着して収縮するパック化粧料として、質量比で30~90%の水、3~65%のアルブミン、2~7%の乳剤性基材、0.05~0.3%の防腐剤及び0.5~3%の溶剤から成るものとするという手段を講じたものである。なお、上記各成分は、これらを乳化ガマに投入するとともに、所要の温度条件のもとに撹拌し、冷却して、本発明の収縮性パック化粧料を得ることができるものであるが、その製造方法に格別のものは必要なく、化粧料の製造上公知の技術により製造可能なものとする。上記成分比をもって製造したパック料は、主としてアルブミンの作用により、顕著な収縮力を肌に感じさせる。
 本発明は、また、質量比で30~90%の水、3~65%のアルブミン、2~7%の乳剤性基材、0.05~0.3%の防腐剤及び0.5~3%の溶剤を必須成分として含み、さらに、その全量を100%として、0.1~5%のクレイ、0.0005~0.05%のAPPS、0.05~1%のヒアルロン酸を含有することを特徴とするものである。上記成分比をもって製造したパック料は、クレイの作用により毛穴に入り込んだ汚れを吸着し、除去する顕著な効果を発揮する。
 アルブミンは、乾燥の進行とともに収縮する性質を持ち、本発明のパックにおける主要成分を構成するもので、乾燥に伴う固化を制御することによって、容器に充填した状態で3年程度は放置しても、固まったり変質したりすることのない、安定性を備えるものとする。このために必要な成分量としては、質量比で3%未満では収縮力が不足し過ぎ、65%を超えると収縮力が過剰となるので3~65%とする。水には精製水を使用するが、その量はアルブミン量に逆比例的に決められる。即ち、アルブミン量が大の場合に水分量は小とし、アルブミン量が小の場合に水分量は大とする。成分量の下限は、パックとして硬くなり過ぎて使用し難くなる限界が30%であり、上限は、逆に柔らかくなり過ぎる限界が90%である。
 上記アルブミンは、卵白を構成しているタンパク質の主成分として知られており、本発明においても卵白を構成する卵アルブミンを使用することができる。アルブミンを主成分として、適正にパック剤を調製し、これを皮膚に塗布することで、時間の経過とともに乾燥と固化が始まり、それに伴って皮膚の収縮が進行し、毛穴に入り込んでいる汚れ、皮脂等が排除されるようになる。本発明は、パック剤としての収縮力をアルブミンの乾燥と固化に求めるものであり、化粧品に求められる長期間の安定性を、いわゆる添加剤によって調節するものである。
 乳剤性基材は、本発明のパック剤をクリーム状にするものであり、上記アルブミンを主成分とする本発明のパック剤を皮膚に塗布したときに、塗り延ばし易くするものである。水中油型(o/w)、油中水型(w/o)の何れの型も取り得る。本発明のために必要な成分量としては、2~7%が適切であって、2%未満では塗り延ばし性が不足し、7%を超えると塗り延ばし性が過剰となる。
 上記乳剤性基材には、アルブミンに好適に使用することができる、市販品があるのでそれを利用する。その例としては、セピゲル305(SEPIGEL305;ポリアクリルアミド、水添ポリイソブテン、ラウレス−7及び水を主成分とする。)、シマルゲルNS((SIMULGEL NS;アクリル酸ヒドロキシエチル/アクリロイルジメチルタウリンNa)コポリマー、スクワラン、ポリソルベート60及び水を主成分とする。)、セピノヴ EMT(SEPINOV EMT10;(アクリル酸ヒドロキシエチル/アクリロイルジメチルタウリンNa)コポリマーを主成分とする。)を挙げることができる。これらは、何れも、(株)成和化成の商品として知られている。
 パック剤に品質安定性を付与するために、防腐剤が必要であり、本発明ではメチルパラベン、エチルパラベン、プロピルパラベン、ブチルパラベン、フェノキシエタノールの内の1又は2以上のものから自由に選択することができる。防腐剤の成分量としては少なくとも0.05%は必要であり、また、0.3%を超えると析出する傾向があるので、0.05~0.3%が良い。
 上記防腐剤には、溶剤又は保湿剤が加えられる。上記の溶剤又は保湿剤にはブチレングリコール、プロピレングリコール、ペンタンジオールの内の1又は2以上のものから自由に選択することができる。溶剤又は保湿剤の成分量としては上記防腐剤の量に依存する側面があるが、おおむね0.5~3%が適切である。
 本発明の収縮性パック料は、さらに美容効果を高めるために、クレイ、APPS、ヒアルロン酸などを添加した形態を取ることができる。クレイは、タンパク質を主成分とする皮膚の汚れを吸着する機能を有するとされており、中でもクチャと呼ばれる沖縄産の微粒子クレイが好適である。その効果を得るために必要なクレイの成分量としては、0.1~5%が必要である。APPSはビタミンC誘導体(アスコルビン酸−2リン酸−6パルミチン酸)の一つであり、高浸透型ビタミンとして知られ、毛穴の引き締め効果があるとされる。成分量としては0.0005~0.05%が適当である。ヒアルロン酸は保湿効果があるとされており、成分量としては0.05~1%が適当である。一々列挙することはしないが、これら以外にも、商品の性質に応じる成分を添加することができる。
 ここで、本発明の収縮性パック料を製造するに当たり、適用することができる化粧料の製造上公知の技術の一例を挙げれば、以下の様なものである。即ち、真空乳化ガマに所要量の水を投入して加温し、上述の乳剤性基材、防腐剤及び溶剤から成る成分を夫々所要量、必要により加熱して投入し、常時、撹拌、混合を繰り返しながら、アルブミンを少量ずつ数回に分けて投入し、アルブミンが固まらないように十分に撹拌を行う。次いで、適温に冷却し、さらに、撹拌を継続しつつ、脱気、冷却等の必要な作業を行う。得られたバルクは、容器充填の上、包装、梱包され出荷することになるが、バルクのまま冷凍保存し、事後に解凍の上、出荷することも可能である。
 本発明は以上のように構成されかつ作用するものであるから、アルブミンを主剤として2剤を混合する手間を必要としない1剤型の収縮性パック化粧料が実現でき、包装又は容器から取りしてそのまま使用されるとともに、パックが肌への塗布、乾燥と同時に収縮するという特性を有しており、かつ、クレイの作用により毛穴に入り込んでいる汚れを吸着して除去する顕著な効果を発揮する収縮性パック化粧料を提供することができる。また、本発明によれば、容器に充填した状態で長期間放置しても固まったり変質したりすることのない安定性を備えた1剤型の収縮性パック化粧料を提供することができるという効果を奏する。
In order to solve the above-mentioned problems, the present invention provides a pack cosmetic that adheres to the skin and contracts, and is 30 to 90% water, 3 to 65% albumin, and 2 to 7% emulsion base material by mass ratio. , 0.05 to 0.3% of a preservative and 0.5 to 3% of a solvent. Each of the above components can be added to the emulsifier and stirred under the required temperature conditions and cooled to obtain the shrinkable pack cosmetic of the present invention. No special manufacturing method is required, and it can be manufactured by a known technique for manufacturing cosmetics. The pack manufactured with the above component ratio makes the skin feel a significant contraction force mainly by the action of albumin.
The present invention also provides 30 to 90% water, 3 to 65% albumin, 2 to 7% emulsion base material, 0.05 to 0.3% preservative and 0.5 to 3 by mass ratio. % Of solvent as an essential component, and further containing 0.1 to 5% clay, 0.0005 to 0.05% APPS, and 0.05 to 1% hyaluronic acid with the total amount as 100%. It is characterized by this. The pack material manufactured with the said component ratio exhibits the remarkable effect which adsorb | sucks and removes the dirt which entered the pore by the effect | action of clay.
Albumin has a property of shrinking with the progress of drying, and constitutes a main component in the pack of the present invention. By controlling solidification accompanying drying, the albumin can be left in a state filled for about 3 years. It shall be stable and will not harden or deteriorate. For this purpose, the amount of components required is 3 to 65% because the shrinkage force is too short when the mass ratio is less than 3%, and the shrinkage force becomes excessive when the mass ratio exceeds 65%. Purified water is used as the water, and the amount is determined in inverse proportion to the amount of albumin. That is, the amount of water is small when the amount of albumin is large, and the amount of water is large when the amount of albumin is small. The lower limit of the component amount is 30%, which is too hard to use as a pack, and the upper limit is 90%, which is too soft.
The albumin is known as a main component of the protein constituting the egg white, and the egg albumin constituting the egg white can also be used in the present invention. By properly preparing a pack agent with albumin as the main component and applying it to the skin, drying and solidification starts with the passage of time, along with the progress of skin shrinkage, dirt entering the pores, Sebum etc. will be excluded. In the present invention, the shrinkage force as a pack agent is required for drying and solidification of albumin, and the long-term stability required for cosmetics is adjusted by so-called additives.
The emulsion base is used to make the pack of the present invention into a cream form, and when the above-mentioned pack of the present invention mainly composed of albumin is applied to the skin, it is easy to spread. Either an oil-in-water type (o / w) or a water-in-oil type (w / o) can be used. The amount of components necessary for the present invention is suitably 2 to 7%. If it is less than 2%, the spreadability is insufficient, and if it exceeds 7%, the spreadability is excessive.
As the above-mentioned emulsion base material, there is a commercially available product that can be suitably used for albumin. Examples include Sepigel 305 (SEPIGEL 305; polyacrylamide, hydrogenated polyisobutene, laureth-7 and water as main components), Simalgel NS ((SIMULGEL NS; hydroxyethyl acrylate / acryloyldimethyltaurine Na) copolymer, squalane. , Polysorbate 60 and water as main components), and Sepinov EMT (SEPINOV EMT10; (based on hydroxyethyl acrylate / acryloyldimethyltaurine Na) copolymer). These are all known as products of Seiwa Kasei Co., Ltd.
In order to impart quality stability to the pack agent, a preservative is necessary, and in the present invention, one or more of methylparaben, ethylparaben, propylparaben, butylparaben, and phenoxyethanol can be freely selected. it can. The component amount of the preservative is required to be at least 0.05%, and when it exceeds 0.3%, it tends to precipitate, so 0.05 to 0.3% is preferable.
A solvent or a humectant is added to the preservative. The solvent or humectant can be freely selected from one or more of butylene glycol, propylene glycol and pentanediol. The amount of the solvent or humectant component depends on the amount of the preservative, but is generally 0.5 to 3%.
The shrinkable pack material of the present invention can take a form to which clay, APPS, hyaluronic acid and the like are added in order to further enhance the cosmetic effect. Clay is said to have a function of adsorbing skin dirt mainly composed of protein, and among them, Okinawa fine particle clay called kukua is suitable. The amount of the clay component necessary for obtaining the effect is 0.1 to 5%. APPS is one of vitamin C derivatives (ascorbic acid-2-phosphate-6 palmitic acid), which is known as a highly osmotic vitamin and is said to have a pore tightening effect. The component amount is suitably 0.0005 to 0.05%. Hyaluronic acid is said to have a moisturizing effect, and an appropriate component amount is 0.05 to 1%. Although not enumerated one by one, in addition to these, components depending on the properties of the product can be added.
Here, an example of a known technique in the production of cosmetics that can be applied in producing the shrinkable pack material of the present invention is as follows. In other words, the required amount of water is added to the vacuum emulsifier and heated, and the above-mentioned emulsion base material, preservative and solvent components are added in necessary amounts, if necessary, and constantly stirred and mixed. While repeating the above, albumin is added in small portions several times and stirred sufficiently so that albumin does not harden. Next, the system is cooled to an appropriate temperature, and further necessary operations such as deaeration and cooling are performed while stirring is continued. The obtained bulk is packaged, packed and shipped after filling the container, but it can also be stored frozen in the bulk and thawed after the fact and shipped.
Since the present invention is constructed and functions as described above, a one-pack type shrinkable pack cosmetic that does not require the trouble of mixing two agents with albumin as a main ingredient can be realized and removed from a package or a container. In addition to being applied to the skin and shrinking at the same time as drying, the pack exhibits the remarkable effect of adsorbing and removing dirt that has entered the pores due to the action of clay. A shrinkable pack cosmetic can be provided. In addition, according to the present invention, it is possible to provide a one-pack type shrinkable pack cosmetic with stability that does not harden or deteriorate even when left in a container for a long period of time. There is an effect.
 以下、実施例によって本発明をより詳細に説明する。 Hereinafter, the present invention will be described in more detail with reference to examples.
 質量比で89.8%の水、5%のアルブミン、3%の乳剤性基材、2%の防腐剤及び0.2%の溶剤を主成分、配合比とする、アルブミン含有量の下限に近い収縮性パック料の例である。水として精製水、アルブミンとして卵アルブミン、乳剤性基材として前記のセピゲル305(SEPIGEL305;ポリアクリルアミド、水添ポリイソブテン、ラウレス−7及び水を主成分とする。)、防腐剤としてメチルパラベン、溶剤としてブチレングリコールを使用した。
 真空乳化ガマに精製水を全量投入し、加温して40℃とし、ブチレングリコールにメチルパラベンを加え加熱溶解したものを精製水中に投入し、セピゲル305を投入した後、撹拌、混合を行い、アルブミンを全量投入し、全体になじむようにする。さらに、撹拌、混合を継続しながら30℃まで冷却する。この後、パドルによる撹拌、ホモミクサーによる撹拌をダマ(パウダーで供給するアルブミンが完全に分散されるまでの不均一な小塊)がなくなってなじむまで行い、最後にパドル撹拌のみにし、脱気、冷却し、収縮性パック料を製造した。得られた実施例1の収縮性パック料は、1剤型のパック化粧料であるのでそのまま肌に塗ることができるとともに、塗り延ばし性に優れており、乾くまでにやや時間を要したが、収縮力を皮膚に感じ取ることができ、また、良好な保湿性を示すものであった。
89.8% water by weight, 5% albumin, 3% emulsion base, 2% preservative and 0.2% solvent as main components and blending ratio, lower limit of albumin content It is an example of a near shrinkable pack fee. Purified water as water, egg albumin as albumin, Sepigel 305 (SEPIGEL 305; mainly composed of polyacrylamide, hydrogenated polyisobutene, laureth-7 and water) as emulsion base material, methylparaben as preservative, butylene as solvent Glycol was used.
Purified water is added to the vacuum emulsifier, heated to 40 ° C., methyl paraben added to butylene glycol and heated and dissolved, and then poured into purified water. After adding Sepigel 305, stirring and mixing are performed. Add the entire amount so that it fits the whole. Furthermore, it cools to 30 degreeC, continuing stirring and mixing. After this, stirring with a paddle and stirring with a homomixer are carried out until there is no lumps (uneven small lumps until albumin supplied in powder is completely dispersed), and only paddle stirring is performed, and then deaeration and cooling are performed. The shrinkable pack material was manufactured. The shrinkable pack material of Example 1 obtained was a one-pack type pack cosmetic, so that it could be applied to the skin as it was, and it was excellent in spreadability and took some time to dry. The contractile force could be felt on the skin, and good moisture retention was exhibited.
 質量比で49.8%の水、45%のアルブミン、3%の乳剤性基材、2%の防腐剤及び0.2%の溶剤を主成分、配合比とする、アルブミン含有量を最適とした収縮性パック料の例である。実施例1と同様に、水として精製水、アルブミンとして卵アルブミン、乳剤性基材として前記のセピゲル305(SEPIGEL305;ポリアクリルアミド、水添ポリイソブテン、ラウレス−7及び水を主成分とする。)、防腐剤としてメチルパラベン、溶剤としてブチレングリコールを使用した。
 真空乳化ガマに精製水を全量投入し、加温して40℃とし、ブチレングリコールにメチルパラベンを加え加熱溶解したものを精製水中に投入し、セピゲル305を投入した後、撹拌、混合を行い、アルブミンを少量ずつ数回に分けて投入するとともに、投入、撹拌を繰り返し、全体になじませる。さらに、撹拌、混合を継続しながら30℃まで冷却する。この後、パドルによる撹拌、ホモミクサーによる撹拌をダマ(前記参照)がなくなってなじむまで行い、最後にパドル撹拌のみにし、脱気、冷却し、収縮性パック料を製造した。得られた実施例2の収縮性パック料は、適度の塗り延ばし性を有し、べたつかず、標準的なパック料と変わらない十数分ほどで乾燥し、乾燥の進行とともに収縮力を皮膚に感じ取ることができ、1剤型のパック化粧料として使い易く、かつ、力強い収縮力を肌に感じさせるものであった。
Optimum albumin content, with 49.8% water, 45% albumin, 3% emulsion base, 2% preservative and 0.2% solvent as the main components and blend ratio It is an example of a shrinkable pack material. As in Example 1, purified water as water, egg albumin as albumin, Sepigel 305 (SEPIGEL 305; mainly composed of polyacrylamide, hydrogenated polyisobutene, laureth-7 and water) as an emulsion base, antiseptic. Methyl paraben was used as the agent and butylene glycol was used as the solvent.
Purified water is added to the vacuum emulsifier, heated to 40 ° C., methyl paraben added to butylene glycol and heated and dissolved, and then poured into purified water. After adding Sepigel 305, stirring and mixing are performed. Is added in small portions in several batches, and the charging and stirring are repeated until it is familiar. Furthermore, it cools to 30 degreeC, continuing stirring and mixing. Thereafter, stirring with a paddle and stirring with a homomixer were carried out until there was no lumps (see above), and finally only paddle stirring was performed, followed by deaeration and cooling to produce a shrinkable pack material. The resulting shrinkable pack material of Example 2 has moderate spreading properties, is not sticky, and dries in about 10 minutes, which is the same as the standard pack material. As the drying progresses, the shrinkage force is applied to the skin. It can be felt and is easy to use as a one-pack type cosmetic pack, and it makes the skin feel a strong contraction force.
 質量比で34.8%の水、60%のアルブミン、3%の乳剤性基材、2%の防腐剤及び0.2%の溶剤を主成分、配合比とする、アルブミン含有量の上限に近い収縮性パック料の例である。実施例1と同様に、水として精製水、アルブミンとして卵アルブミン、乳剤性基材として前記のセピゲル305(SEPIGEL305;ポリアクリルアミド、水添ポリイソブテン、ラウレス−7及び水を主成分とする。)、防腐剤としてメチルパラベン、溶剤としてブチレングリコールを使用した。
 真空乳化ガマに精製水を全量投入し、加温して40℃とし、ブチレングリコールにメチルパラベンを加え加熱溶解したものを精製水中に投入し、セピゲル305を投入した後、撹拌、混合を行い、アルブミンが固まらないように少量ずつ多数回に分けて投入するとともに、投入、撹拌を繰り返し、全体になじませる。さらに、撹拌、混合を継続しながら30℃まで冷却する。この後、パドルによる撹拌、ホモミクサーによる撹拌を、ダマ(前記参照)がなくなってなじむまで行い、最後にパドル撹拌のみにし、脱気、冷却し、収縮性パック料を製造した。得られた実施例3の収縮性パック料は、1剤型のパック化粧料であり、やや塗り延ばし性の低下は見られたが、強い付着力を示し、標準的なパック料よりも短い時間で乾燥し、強力な収縮力を皮膚に感じるものであった。
The upper limit of the albumin content is 34.8% water, 60% albumin, 3% emulsion base, 2% preservative and 0.2% solvent as the main components and blending ratio. It is an example of a near shrinkable pack fee. As in Example 1, purified water as water, egg albumin as albumin, Sepigel 305 as the emulsion base (SEPIGE 305; polyacrylamide, hydrogenated polyisobutene, laureth-7 and water as main components), antiseptic. Methyl paraben was used as the agent and butylene glycol was used as the solvent.
Purified water is added to the vacuum emulsifier, heated to 40 ° C., butened with methylparaben added to butylene glycol and dissolved in heated water, and sepigel 305 is added, followed by stirring and mixing. In order to prevent the powder from solidifying, it is added in small portions in several batches, and charging and stirring are repeated until the whole is familiar. Furthermore, it cools to 30 degreeC, continuing stirring and mixing. Thereafter, stirring with a paddle and stirring with a homomixer were carried out until there was no lumps (see above), and finally only paddle stirring was performed, followed by deaeration and cooling to produce a shrinkable pack material. The obtained shrinkable pack material of Example 3 is a one-pack type pack cosmetic, and although a slight decrease in spreadability was observed, it showed strong adhesion and was shorter in time than the standard pack material. Dried and felt a strong contraction force on the skin.
 上記実施例2の主成分、配合比を有する、収縮性パック料を必須成分としてさらに美容効果を高めるために、クレイ、APPS、ヒアルロン酸を添加した形態の例である。クレイにはクチャと呼ばれる沖縄産の微粒子クレイを使用した。微粒子クレイはその60%が約5μmの粒径のものを用い、その成分量は、実施例2の収縮性パック料の全量を100%として、質量比で3%としたが、これは投入量の範囲の中でも低い方である。APPSの成分量は同様に0.01%とし、ヒアルロン酸の成分量も同様に0.01%とした。これらのクレイ、APPS、ヒアルロン酸はセピゲル305の投入後に投入した。その他は実施例2と同じ方法によって本発明の収縮性パック料を製造した。
 得られた実施例4の収縮性パック料も、1剤型のパック化粧料であり、実施例2のものとほぼ同様の性質を示して、適度の塗り延ばし性を有し、べたつかず、乾燥時間も変わらず、力強い収縮力を皮膚に感じさせるものであった。しかも、微粒子クレイ及びAPPSによるタンパク質吸着効果により、毛穴汚れがほぼ目立たない程度にまで消失し、保湿性によると考えられる皮膚の潤い感を得ることができた。
This is an example of a form in which clay, APPS, and hyaluronic acid are added in order to further enhance the cosmetic effect using the shrinkable pack material having the main component and blending ratio of Example 2 as an essential component. The clay used was a fine clay from Okinawa called Kucha. 60% of the fine particle clay had a particle size of about 5 μm, and the amount of the component was 3% in terms of the mass ratio, with the total amount of the shrinkable pack material of Example 2 being 100%. The lower of the ranges. The component amount of APPS was similarly 0.01%, and the component amount of hyaluronic acid was also 0.01%. These clay, APPS, and hyaluronic acid were added after the Sepigel 305 was added. Otherwise, the shrinkable pack material of the present invention was produced in the same manner as in Example 2.
The obtained shrinkable pack material of Example 4 is also a one-pack type pack cosmetic, showing properties almost similar to those of Example 2, having an appropriate spreadability, non-sticky, and dry. The time did not change, and the skin felt a strong contraction force. In addition, due to the protein adsorption effect of fine particle clay and APPS, pore dirt was eliminated to an almost inconspicuous level, and it was possible to obtain a moist feeling of skin considered to be due to moisture retention.
 実施例4と同様に、実施例2の主成分、配合比を有する、収縮性パック料を必須成分としてさらに美容効果を高めるために、クレイ、APPS、ヒアルロン酸を添加した形態の例である。使用したクレイも60%が約5μmの粒径の微粒子クレイであるが、その成分量は、実施例2の収縮性パック料の全量を100%として、質量比で5%であり、APPSの成分量、ヒアルロン酸の成分量は、ともに0.01%である。これらのクレイ、APPS、ヒアルロン酸を、セピゲル305の投入後に投入した他は、実施例2と同じ方法によって本発明の収縮性パック料を製造した。
 得られた実施例5の収縮性パック料も、1剤型のパック化粧料であり、実施例2のものとほぼ同様の性質を示して、適度の塗り延ばし性を有し、べたつかず、乾燥時間も変わらず、力強い収縮力を皮膚に感じさせるものであった。従って、微粒子クレイ及びAPPSによるタンパク質吸着効果により、毛穴汚れがほぼ目立たない程度にまで消失し、保湿性によると考えられる皮膚の潤い感を得ることができた。
 このように、本発明のものは1剤型の収縮性パック化粧料であるにも拘らず、2剤の混合によって化学反応を起こさせて収縮する方法を取らなくても、直ぐに固まってしまうような不具合を生じることがない。従って、包装又は容器から取りしてそのまま、手間のかかる下準備なしに、収縮性パックを使用することができるようになる。しかも、本発明によれば、容器に充填した状態で、化粧品に期待される使用期間の目安である3年程度の長期間放置しても、固まったり変質したりすることのない、安定性を備えたパック剤であるから、極めて手軽にこの種のパックを可能にするものである。
 本発明の収縮性パック料は、いわゆるクリームタイプのパック料であり、標準的な仕様では数分で乾燥が始まり十数分で乾燥終了となるが、その間に皮膚の収縮を生じ、最終的には顔全体が引き締まったような感覚を得ることができる。また、本発明の収縮性パック料は水溶性であるから、パックを終えた後はぬるま湯で容易に洗い流すことができ、1剤型であることと相俟って、使用法が著しく簡単である。
In the same manner as in Example 4, it is an example of a form in which clay, APPS, and hyaluronic acid are added in order to further enhance the cosmetic effect with the shrinkable pack material having the main component and blending ratio of Example 2 as essential components. The clay used was also a fine particle clay having a particle size of about 5 μm in 60%, and the amount of the component was 5% by mass with the total amount of the shrinkable pack material of Example 2 being 100%. Both the amount and the component amount of hyaluronic acid are 0.01%. The shrinkable pack material of the present invention was produced by the same method as in Example 2 except that these clay, APPS, and hyaluronic acid were added after the Sepigel 305 was added.
The obtained shrinkable pack material of Example 5 is also a one-pack type pack cosmetic, showing properties almost similar to those of Example 2, having an appropriate spreadability, not sticky, and dry. The time did not change, and the skin felt a strong contraction force. Therefore, due to the protein adsorbing effect of fine particle clay and APPS, pore stains disappeared to an inconspicuous level, and a moist feeling of skin considered to be due to moisture retention could be obtained.
Thus, even though the present invention is a one-pack type shrinkable pack cosmetic, it does not seem to harden immediately without taking a method of causing a chemical reaction by the mixing of two agents to shrink. No troubles occur. Therefore, the shrinkable pack can be used as it is without taking a complicated preparation, taking it out from the package or the container. In addition, according to the present invention, even when left in a container for a long period of about 3 years, which is a standard for the expected period of use, it does not harden or deteriorate. Since the pack agent is provided, this type of pack can be made very easily.
The shrinkable pack material of the present invention is a so-called cream-type pack material, and in the standard specification, drying starts in a few minutes and finishes drying in a few dozen minutes. Can get the feeling that the whole face is tightened. Further, since the shrinkable pack material of the present invention is water-soluble, it can be easily washed away with lukewarm water after finishing the pack, and combined with the one-pack type, is extremely simple to use. .

Claims (2)

  1. 収縮性を有するパック化粧料であって、
    質量比で30~90%の水、3~65%のアルブミン、2~7%の乳剤性基材、0.05~0.3%の防腐剤及び0.5~3%の溶剤から成ることを特徴とする収縮性パック化粧料。
    Pack cosmetics having shrinkage,
    Consist of 30 to 90% water, 3 to 65% albumin, 2 to 7% emulsion base material, 0.05 to 0.3% preservative and 0.5 to 3% solvent by weight. A shrinkable pack cosmetic.
  2. 質量比で30~90%の水、3~65%のアルブミン、2~7%の乳剤性基材、0.05~0.3%の防腐剤及び0.5~3%の溶剤を必須成分として含み、その全量を100%として、さらに、0.1~5%のクレイ、0.0005~0.05%のAPPS、0.05~1%のヒアルロン酸を含有する
    請求項1記載の収縮性パック化粧料。
    30 to 90% water by weight, 3 to 65% albumin, 2 to 7% emulsion base, 0.05 to 0.3% preservative and 0.5 to 3% solvent as essential components The shrinkage according to claim 1, further comprising 0.1 to 5% clay, 0.0005 to 0.05% APPS and 0.05 to 1% hyaluronic acid, the total amount of which is 100%. Sex pack cosmetics.
PCT/JP2010/071425 2010-11-24 2010-11-24 Shrinking pack cosmetic WO2012070157A1 (en)

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KR1020137014241A KR20130086622A (en) 2010-11-24 2010-11-24 Shrinking pack cosmetic
PCT/JP2010/071425 WO2012070157A1 (en) 2010-11-24 2010-11-24 Shrinking pack cosmetic

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JP2017500292A (en) * 2013-11-22 2017-01-05 ロレアル Sheet clay products for beauty use

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JPS6322008A (en) * 1986-05-09 1988-01-29 エクソバ−,インコ−ポレイテイド Wrinkle-removing cosmetic composition
JP2002029924A (en) * 2000-07-14 2002-01-29 Etsuo Ito Dermatological agent using fine particles of okinawa siltstone as principal ingredient and method of preparing the same
JP2005187466A (en) * 2003-12-04 2005-07-14 Showa Denko Kk Skin care preparation for external use containing salt of higher fatty acid ester of ascorbic acid-2-phosphoric acid ester, method for stabilizing the salt of ester, and stabilizing agent
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JPS61118310A (en) * 1984-11-06 1986-06-05 エクソバー,インコーポレイテツド Wrinkle removing cosmetic composition
JPS6322008A (en) * 1986-05-09 1988-01-29 エクソバ−,インコ−ポレイテイド Wrinkle-removing cosmetic composition
JP2002029924A (en) * 2000-07-14 2002-01-29 Etsuo Ito Dermatological agent using fine particles of okinawa siltstone as principal ingredient and method of preparing the same
JP2005187466A (en) * 2003-12-04 2005-07-14 Showa Denko Kk Skin care preparation for external use containing salt of higher fatty acid ester of ascorbic acid-2-phosphoric acid ester, method for stabilizing the salt of ester, and stabilizing agent
JP2009286735A (en) * 2008-05-29 2009-12-10 Shiseido Co Ltd Skin care preparation

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017500292A (en) * 2013-11-22 2017-01-05 ロレアル Sheet clay products for beauty use

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