WO2012059412A1 - Composition de mousse colorante à base d'un mélange d'alcanolamines comprenant de la monoéthanolamine - Google Patents

Composition de mousse colorante à base d'un mélange d'alcanolamines comprenant de la monoéthanolamine Download PDF

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Publication number
WO2012059412A1
WO2012059412A1 PCT/EP2011/068933 EP2011068933W WO2012059412A1 WO 2012059412 A1 WO2012059412 A1 WO 2012059412A1 EP 2011068933 W EP2011068933 W EP 2011068933W WO 2012059412 A1 WO2012059412 A1 WO 2012059412A1
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composition
weight
monoethanolamine
alkyl
composition according
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PCT/EP2011/068933
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English (en)
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Caroline Goget
Richard Sabourin
Delphine Allard
Jean-Marc Ascione
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L'oreal
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Publication of WO2012059412A1 publication Critical patent/WO2012059412A1/fr

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/046—Aerosols; Foams
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/10—Preparations for permanently dyeing the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
    • A61K2800/88—Two- or multipart kits

Definitions

  • the present invention pertains to a method for colouring hair, in mousse form, employing a composition comprising oxidation dye precursors, and also to a composition in mousse from.
  • the methods of colouring human keratinic fibres, such as the hair include permanent or oxidation dyeing. More particularly, this dyeing method uses one or more oxidation dyes, usually one or more oxidation bases optionally combined with one or more couplers.
  • oxidation bases are chosen from ortho- or para-phenylenediamines, ortho- or para-aminophenols and heterocyclic compounds. These oxidation bases are colourless or weakly coloured compounds, which, when combined with oxidizing products, can give access to coloured species.
  • the shades obtained with these oxidation bases are often varied by combining them with one or more couplers, these couplers being chosen especially from aromatic mefa-diamines, mefa-aminophenols, mefa-diphenols and certain heterocyclic compounds, such as indole compounds.
  • Permanent dyeing processes therefore involve employing, together with the dyeing composition, an aqueous composition comprising at least one oxidizing agent such as hydrogen peroxide, under alkaline pH conditions in the great majority of cases.
  • the alkaline agent conventionally used is aqueous ammonia, or other alkaline agents, such as alkanolamines.
  • the colouring compositions may take various forms, such as lotions, gels, emulsions, creams or mousses.
  • Colouring mousses are pleasant to use, but are often subject to poor persistence. It is possible, for example, to observe rapid disappearance of the mousse following application, or inconsistent application along the fibres.
  • composition for colouring human keratinic fibres such as the hair, in mousse form, comprising:
  • the invention also relates to a method for colouring human keratinic fibres, employing this composition.
  • the invention likewise provides a multi-compartment device comprising in one of the compartments a composition containing one or more surfactants, one or more oxidation dye precursors, monoethanolamine, and one or more alkanolamines other than monoethanolamine, and, in a second compartment, a composition containing one or more oxidizing agents and a distributor of mousse based on the composition of the invention obtained by mixing the two preceding compositions.
  • the invention further provides a device for colouring keratinic fibres, capable of forming a mousse as described above, comprising the composition of the invention in liquid form and a mousse distributor for delivering the composition in the form of a mousse.
  • the composition of the invention takes the form of a mousse which is particularly pleasant to apply. It has a light and airy texture, so making such mousses particularly pleasant to use.
  • the qualities of the mousse are sufficiently persistent to allow the colouring product to be applied uniformly and without running.
  • the composition of the invention makes it possible to conserve dyeing properties such as the strength of the colour, the resistance to external agents (shampoos, perspiration, light) and selectivity that are particularly effective.
  • the human keratinic fibres treated by the method according to the invention are preferably the hair.
  • the composition comprises monoethanolamine.
  • Monoethanolamine may be present in very variable amounts. According to one particular embodiment, the monoethanolamine is present in an amount varying from 0.01 % to 30% by weight, preferably from 0.1 % to 20% by weight, more preferably from 1 % to 10% by weight relative to the weight of the composition according to the invention.
  • composition of the invention comprises at least one alkanolamine other than monoethanolamine.
  • alkanolamine means an organic amine comprising a primary, secondary or tertiary amine function, and one or more linear or branched C C 8 alkyl groups bearing one or more hydroxyl radicals.
  • Alkanolamines such as mono-, di- or tri- alkanolamines comprising from one to three identical or different C C 4 hydroxyalkyl radicals are in particular suitable for performing the invention.
  • Compounds of this type include diethanolamine, triethanolamine, monoisopropanolamine, diisopropanolamine, N-dimethylaminoethanolamine, 2-amino-2-methyl-1-propanol, triisopropanolamine, 2-amino-2-methyl-1 ,3-propane- diol, 3-amino-1 ,2-propanediol, 3-dimethylamino-1 ,2-propanediol and trishydroxy- methylaminomethane.
  • the alkanolamine other than monoethanolamine is preferably 2-amino-2-methyl-1-propanol.
  • composition according to the invention generally comprises an amount of alkanolamine(s) other than monoethanolamine varying from 0.01 % to 30% by weight, preferably from 0.1 % to 20% by weight, more preferably from 0.5% to 10% by weight relative to the weight of the said composition.
  • the weight ratio of monoethanolamine to alkanolamines other than monoethanolamine varies preferably from 0.05 to 20, more preferably from 0.5 to 10, more preferably still from 1 to 5.
  • composition of the invention may comprise other alkaline agents, such as ethoxylated and/or propoxylated ethylenediamines, amino acids and the compounds of formula (I) below:
  • W is a C C 6 alkylene residue optionally substituted with a hydroxyl group or a C C 6 alkyl radical
  • Rx, Ry, Rz and Rt which may be identical or different, represent a hydrogen atom or a C C 6 alkyl, C C 6 hydroxyalkyl or C C 6 aminoalkyl radical.
  • Examples of such amines that may be mentioned include 1 ,3-diaminopropane, 1 ,3-diamino-2-propanol, spermine and spermidine.
  • amino acids that may be used in the present invention, mention may be made especially of aspartic acid, glutamic acid, alanine, arginine, ornithine, citrulline, asparagine, carnitine, cysteine, glutamine, glycine, histidine, lysine, isoleucine, leucine, methionine, N-phenylalanine, proline, serine, taurine, threonine, tryptophan, tyrosine and valine.
  • the composition of the invention contains a small amount of aqueous ammonia, and preferably does not contain aqueous ammonia.
  • the composition according to the invention further comprises at least one oxidizing agent.
  • the oxidizing agents are selected for example from hydrogen peroxide, urea peroxide, alkali metal bromates or ferricyanides, peroxygenated salts such as, for example, persulphates, perborates, peracids and precursors thereof, and the percarbonates of alkali metals or alkaline earth metals.
  • the oxidizing agent is hydrogen peroxide.
  • the amount of oxidizing agent(s) represents more particularly from 0.1 % to 20% by weight, preferably from 0.5% to 10% by weight, relative to the weight of the composition.
  • composition according to the invention comprises at least one oxidation dye precursor.
  • Oxidation dye precursors which can be used include oxidation bases and couplers.
  • the oxidation bases are selected from para-phenylenediamines, bisphenylalkylenediamines, para-aminophenols, ortho-aminophenols, heterocyclic bases and their addition salts.
  • the para-phenylenediamines include, for example, para-phenylenediamine, para-tolylenediamine, 2-chloro-para-phenylenediamine, 2,3-dimethyl-para-phenylene- diamine, 2,6-dimethyl-para-phenylenediamine, 2,6-diethyl-para-phenylenediamine, 2,5-dimethyl-para-phenylenediamine, N,N-dimethyl-para-phenylenediamine, ⁇ , ⁇ -diethyl-para-phenylenediamine, N,N-dipropyl-para-phenylenediamine, 4-amino-N,N-diethyl-3-methylaniline, N,N-bis ⁇ -hydroxyethyl)-para-phenylene- diamine, 4-N,N-bis ⁇ -hydroxyethyl)amino-2-methylaniline, 4-N,N-bis ⁇ -hydroxy- ethyl)amino-2-ch
  • para-phenylenediamine para-tolylenediamine, 2-isopropyl-para-phenylenediamine, 2 ⁇ -hydroxyethyl-para- phenylenediamine, 2 ⁇ -hydroxyethyloxy-para-phenylenediamine, 2,6-dimethyl-para- phenylenediamine, 2,6-diethyl-para-phenylenediamine, 2,3-dimethyl-para- phenylenediamine, N,N-bis -hydroxyethyl)-para-phenylenediamine, 2-chloro-para- phenylenediamine and 2- ⁇ -acetylaminoethyloxy-para-phenylenediamine, and the addition salts thereof with an acid, are particularly preferred.
  • bis(phenyl)alkylenediamines that may be mentioned, for example, are N,N'-bis( ⁇ -hydroxyethyl)-N,N'-bis(4'-aminophenyl)-1 ,3-diaminopropanol, N,N'-bis- ( ⁇ -hydroxyethyl)-N,N'-bis(4'-aminophenyl)ethylenediamine, N,N'-bis(4- aminophenyl)tetramethylenediamine, N,N'-bis -hydroxyethyl)-N,N'-bis(4- aminophenyl)tetramethylenediamine, N,N'-bis(4- methylaminophenyl)tetramethylenediamine, N,N'-bis(ethyl)-N,N'-bis(4'-amino-3'- methylphenyl)ethylenediamine, 1 ,8-bis(2,5-diaminophenoxy)
  • para-aminophenols that may be mentioned, for example, are para- aminophenol, 4-amino-3-methylphenol, 4-amino-3-fluorophenol, 4-amino-3- chlorophenol, 4-amino-3-hydroxymethylphenol, 4-amino-2-methylphenol, 4-amino-2- hydroxymethylphenol, 4-amino-2-methoxymethylphenol, 4-amino-2- aminomethylphenol, 4-amino-2-( ⁇ -hydroxyethylaminomethyl)phenol and 4-amino-2- fluorophenol, and the addition salts thereof with an acid.
  • ortho-aminophenols that may be mentioned, for example, are 2- aminophenol, 2-amino-5-methylphenol, 2-amino-6-methylphenol and 5-acetamido-2- aminophenol, and the addition salts thereof.
  • heterocyclic bases that may be mentioned, for example, are pyridine derivatives, pyrimidine derivatives and pyrazole derivatives.
  • the pyridine derivatives include the compounds described, for example, in patents GB 1 026 978 and GB 1 153 196, such as 2,5-diaminopyridine, 2-(4-methoxy- phenyl)amino-3-aminopyridine, 3,4-diaminopyridine and their addition salts.
  • pyridine oxidation bases that are useful in the present invention are the 3-aminopyrazolo[1 ,5-a]pyridine oxidation bases or addition salts thereof described, for example, in patent application FR 2 801 308.
  • Examples include pyrazolo[1 ,5-a]pyridin-3-ylamine; 2-acetylaminopyrazolo-[1 ,5-a]pyridin-3-ylamine; 2-morpholin-4-ylpyrazolo[1 ,5-a]pyridin-3-ylamine; 3-aminopyrazolo[1 ,5-a]pyridine-2- carboxylic acid; 2-methoxypyrazolo[1 ,5-a]pyridin-3-ylamine; (3-amino- pyrazolo[1 ,5-a]pyridin-7-yl)methanol; 2-(3-aminopyrazolo[1 ,5-a]pyridin-5-yl)ethanol; 2-(3-
  • pyrimidine derivatives that may be mentioned are the compounds described, for example, in the patents DE 2359399; JP 88-169571 ; JP 05-63124; EP 0770375 or patent application WO 96/15765, such as 2,4,5,6-tetraaminopyrimidine,
  • pyrazole derivatives that may be mentioned are the compounds described in the patents DE 3843892, DE 4133957 and patent applications WO 94/08969, WO 94/08970, FR-A-2 733 749 and DE 195 43 988, such as 4,5-diamino- 1-methylpyrazole, 4,5-diamino-1- ⁇ -hydroxyethyl)pyrazole, 3,4-diaminopyrazole, 4,5- diamino-1-(4'-chlorobenzyl)pyrazole, 4,5-diamino-1 ,3-dimethylpyrazole, 4,5-diamino- 3-methyl-1-phenylpyrazole, 4,5-diamino-1-methyl-3-phenylpyrazole, 4-amino-1 ,3- dimethyl-5-hydrazinopyrazole, 1-benzyl-4,5-diamino-3-methylpyrazole, 4,5-diamino-3-methylpyrazo
  • a 4,5-diaminopyrazole will preferably be used, and even more preferentially 4,5- diamino-1- ⁇ -hydroxyethyl)pyrazole and/or a salt thereof.
  • Pyrazole derivatives that may also be mentioned include diamino-N,N-dihydro- pyrazolopyrazolones and especially those described in patent application FR-A-2 886 136, such as the following compounds and the addition salts thereof: 2,3-diamino-6,7- dihydro-1 H,5H-pyrazolo[1 ,2-a]pyrazol-1-one, 2-amino-3-ethylamino-6,7-dihydro- 1 H,5H-pyrazolo[1 ,2-a]pyrazol-1-one, 2-amino-3-isopropylamino-6,7-dihydro-1 H,5H- pyrazolo[1 ,2-a]pyra-zol-1-one, 2-amino-3-(pyrrolidin-1-yl)-6,7-dihydro-1 H,5H- pyrazolo[1 ,2-a]pyrazol-1-one, 4,5-diamino-1
  • the couplers which can be used in the composition of the invention include in particular meta-phenylenediamines, meta-aminophenols, meta-diphenols, naphthalenic couplers, heterocyclic couplers and their addition salts.
  • Examples include 1 ,3-dihydroxybenzene, 1 ,3-dihydroxy-2-methylbenzene, 4-chloro-1 ,3-dihydroxybenzene, 2,4-diamino-1-(B-hydroxyethyloxy)benzene, 2-amino- 4-(B-hydroxyethylamino)-1-methoxybenzene, 1 ,3-diaminobenzene, 1 ,3-bis(2,4- diaminophenoxy)propane, 3-ureidoaniline, 3-ureido-1-dimethylaminobenzene, sesamol, 1 ⁇ -hydroxyethylamino-3,4-methylenedioxybenzene, a-naphthol, 2-methyl- 1-naphthol, 6-hydroxyindole, 4-hydroxyindole, 4-hydroxy-N-methylindole, 2-amino-3- hydroxypyridine, 6-hydroxybenzomorpholine, 3,5-diamino-2
  • the addition salts of the oxidation bases and couplers are especially chosen from the addition salts with an acid such as the hydrochlorides, hydrobromides, sulfates, citrates, succinates, tartrates, lactates, tosylates, benzenesulfonates, phosphates and acetates.
  • an acid such as the hydrochlorides, hydrobromides, sulfates, citrates, succinates, tartrates, lactates, tosylates, benzenesulfonates, phosphates and acetates.
  • the oxidation base or bases are generally present each in an amount of between 0.0001 % to 10% by weight relative to the total weight of the composition, and preferably from 0.005% to 5% by weight relative to the total weight of the composition.
  • the coupler or couplers each represent in general from 0.0001 % to 10% by weight relative to the total weight of the emulsion, and preferably from 0.005% to 5% by weight relative to the total weight of the composition.
  • the composition of the invention contains an amount of aqueous ammonia of less than 1.5%, preferably less than 0.5%. More preferably the composition of the invention contains no aqueous ammonia.
  • the composition according to the invention may contain cationic or nonionic, natural or synthetic direct dyes.
  • particularly suitable direct dyes include the nitro dyes of the benzene series; direct azo dyes; azomethine dyes; methine dyes; azocarbocyanines such as tetraazacarbocyanines (tetraazapentamethines); direct quinone dyes and more particularly anthraquinone, naphthoquinone or benzoquinone dyes; direct azine dyes; xanthene dyes; triarylmethane dyes; indoamine dyes; indigoid dyes; phthalocyanines; porphyrins and natural direct dyes, alone or in mixtures.
  • direct dyes from among: azo; methine; carbonyl; azine; nitro (hetero)aryl; tri(hetero)arylmethane; porphyrin; phthalocyanine and natural direct dyes, alone or as mixtures.
  • the direct dye or dyes represent more particularly from 0.0001 % to 10% by weight of the total weight of the composition, and preferably from 0.005% to 5% by weight.
  • the composition according to the invention comprises one or more surfactants.
  • the surfactant or surfactants may be anionic and/or amphoteric surfactants.
  • the surfactants useful in the composition of the invention are surfactants known per se in the field of the colouring of keratinic fibres.
  • amphoteric or zwitterionic surfactant or surfactants which can be used in the present invention may be, in particular, optionally quaternized derivatives of secondary or tertiary aliphatic amines in which the aliphatic group is a linear or branched chain containing from 8 to 22 carbon atoms, the said amine derivatives containing at least one anionic group such as, for example, a carboxylate, sulphonate, sulphate, phosphate or phosphonate group.
  • alkyl (C 8 -C 2 o) betaines Particular mention may be made of alkyl (C 8 -C 2 o) betaines, sulphobetaines, alkyl (C 8 -C 2 o) amidoalkyl (C C 6 ) betaines or alkyl (C 8 -C 2 o) amidoalkyl (C C 6 ) sulphobetaines, preferably alkyl (C 8 -C 2 o) amidoalkyl (C C 6 ) betaines.
  • alkyl (C 8 -C 2 o) betaines alkyl (C 8 -C 2 o) betaines.
  • Ra represents a Ci 0 -C 30 alkyl or alkenyl group derived from an acid
  • Ra-COOH preferably present in hydrolysed coconut oil, a heptyl, nonyl or undecyl group,
  • Rb represents a beta-hydroxyethyl group
  • Rc represents a carboxymethyl group
  • X' represents the group -CH 2 -COOH, CH 2 -COOZ', -CH 2 CH 2 -COOH, -CH 2 CH 2 -COOZ', or a hydrogen atom
  • Y' represents -COOH, -COOZ', or the group -CH 2 -CHOH-S0 3 H or -CH 2 -CHOH-S0 3 Z',
  • Z' represents an ion derived from an alkali metal or alkaline-earth metal, such as sodium, an ammonium ion or an ion derived from an organic amine,
  • Ra' represents a Ci 0 -C 30 alkyl or alkenyl group of an acid Ra'-COOH which is preferably present in coconut oil or in hydrolysed linseed oil, an alkyl group, more particularly a C17 alkyl group in its iso form, or an unsaturated Ci 7 group.
  • cocoamphodiacetate sold by the company Rhodia under the trade name Miranol ® C2M Concentrate.
  • amphoteric or zwitterionic surfactants it is preferred to use betaines comprising at least one saturated or unsaturated C8-C30 fatty chain, and more particularly the compounds of formula (A) :
  • A1 and A2 denoting, independently of one another, a linear or branched C Ci 0 alkylene radical optionally substituted by a hydroxyl radical,
  • R1 denoting a linear or branched C6-C30 alkyl or alkenyl radical
  • R2 and R3 denoting, independently of one another, a linear or branched C C 4 alkyl radical
  • R2 and R3 denote a methyl radical.
  • amphoteric betaine surfactant or surfactants used in the cosmetic composition according to the present invention may in particular be alkyl(C8-20)betaines, alkyl(C8-20)sulphobetaines, (C8-20 alkyl)amido(C2-8 alkyl)betaines or (C8-20 alkyl)amido(C6-8 alkyl)sulphobetaines.
  • amphoteric surfactants it is preferred to use (C8-20 alkyl)betaines, (C8-20 alkyl)amido(C2-8 alkyl)betaines and mixtures thereof.
  • amphoteric surfactants of betaine type ii) are selected from cocobetaine and cocamidopropylbetaine.
  • anionic surfactant is a surfactant containing only anionic groups as ionic or ionizable groups. These anionic groups are selected preferably from the groups C0 2 H, C0 2 " , S0 3 H, S0 3 " , OSO3H, OSO3 " , H2PO3 ,HP0 3 " , P0 3 2” , H2PO2, HP0 2 , HP0 2 “ , P0 2 “ , POH and PO " .
  • anionic surfactants that may be used in the composition according to the invention, mention may be made of alkyl sulphates, alkyl ether sulphates, alkylamido ether sulphates, alkylaryl polyether sulphates, monoglyceride sulphates, alkyl sulphonates, alkylamide sulphonates, alkylaryl sulphonates, alpha- olefin sulphonates, paraffin sulphonates, alkyl sulphosuccinates, alkyl ether sulphosuccinates, alkylamide sulphosuccinates, alkyl sulphoacetates, acyl sarcosinates, acyl glutamates, alkyl sulphosuccinamates, acyl isethionates and N- acyltaurates, salts of alkyl monoesters of polyglycoside-polycarboxylic acids, acyl
  • These compounds may be oxyethylenated and then preferably comprise from 1 to 50 ethylene oxide units.
  • the salts of C6-24 alkyl monoesters and polyglycoside-polycarboxylic acids may be selected from C6-24 alkyl polyglycoside-citrates, C6-24 alkyl polyglycoside- tartrates and C6-24 alkyl polyglycoside-sulphosuccinates.
  • anionic surfactant(s) (ii) when they are in salt form, they may be chosen from alkali metal salts such as the sodium or potassium salt and preferably the sodium salt, the ammonium salts, the amine salts and in particular amino alcohol salts or the alkaline-earth metal salts such as the magnesium salt.
  • salts of amino alcohols include in particular the salts of mono-, di- and triethanolamine, the salts of mono-, di- or triisopropanolamine, the salts of 2- amino-2-methyl-1-propanol, 2-amino-2-methyl-1 ,3-propanediol and tris(hydroxy- methyl)aminomethane.
  • Alkali metal or alkaline-earth metal salts and in particular the sodium or magnesium salts are preferably used.
  • anionic surfactants it is preferred according to the invention to use the alkyl sulphate salts and alkyl ether sulphate salts and mixtures thereof.
  • the nonionic surfactants when present, are more particularly selected from mono- or polyoxyalkylenated and mono- or polyglycerolated nonionic surfactants.
  • the oxyalkylene units are more particularly oxyethylene or oxypropylene units or a combination thereof, preferably oxyethylene units.
  • oxyalkylenated nonionic surfactants examples include:
  • esters of saturated or unsaturated, linear or branched, C 8 -C 30 acids and of polyethylene glycols • esters of saturated or unsaturated, linear or branched, C 8 -C 30 acids and of polyethylene glycols,
  • the surfactants having between 1 and 100, preferably between 2 and 50 and more preferably between 2 and 30 mol ethylene oxide and/or propylene oxide.
  • the oxyalkylenated nonionic surfactants are selected from oxyethylenated C 8 -C 30 alcohols containing from 1 to 100 mol of ethylene oxide; and polyoxyethylenated esters of linear or branched, saturated or unsaturated C 8 -C 30 acids and sorbitol, containing from 1 to 100 mol ethylene oxide.
  • mono- or polyglycerolated nonionic surfactants it is preferred to use mono- or polyglycerolated C 8 -C 40 alcohols.
  • the monoglycerolated or polyglycerolated C 8 -C 40 alcohols correspond to the following formula:
  • R represents a linear or branched C 8 -C 40 and preferably C 8 -C 30 alkyl or alkenyl radical
  • m represents a number ranging from 1 to 30 and preferably from 1 to 10.
  • lauryl alcohol containing 4 mol of glycerol (I NCI name: Polyglyceryl-4 Lauryl Ether), lauryl alcohol containing 1.5 mol of glycerol, oleyl alcohol containing 4 mol of glycerol (INCI name: Polyglyceryl-4 Oleyl Ether), oleyl alcohol containing 2 mol of glycerol (INCI name: Polyglyceryl-2 Oleyl Ether), cetearyl alcohol containing 2 mol of glycerol, cetearyl alcohol containing 6 mol of glycerol, oleocetyl alcohol containing 6 mol of glycerol, and octadecanol containing 6 mol of glycerol.
  • the alcohol may represent a mixture of alcohols in the same way that the value of m represents a statistical value, which means that, in a commercial product, several species of polyglycerolated fatty alcohols may coexist in the form of a mixture.
  • the monoglycerolated or polyglycerolated alcohols it is more particularly preferred to use the C 8 /Ci 0 alcohol containing 1 mol of glycerol, the C1 0 /C12 alcohol containing 1 mol of glycerol and the C12 alcohol containing 1.5 mol of glycerol.
  • Nonionic surfactants also include non-oxyethylenated esters of fatty acids and sorbitan, esters of fatty acids and sucrose, optionally oxyalkylenated alkylpolyglycosides, alkylglucoside esters, derivatives of N-alkylglucamine and of N-acylmethylglucamine, aldobionamides, and amine oxides.
  • the surfactant or surfactants are preferably selected from amphoteric, nonionic and anionic surfactants. More preferably, the surfactant or surfactants are selected from amphoteric and anionic surfactants. Even more preferably, the surfactant or surfactants are selected from amphoteric surfactants.
  • the composition of the invention comprises one or more amphoteric surfactants, one or more nonionic surfactants and one or more anionic surfactants.
  • the nonionic surfactant is preferably selected from saturated or unsaturated oxyethylenated fatty alcohols and saturated or unsaturated oxyethylenated plant oils.
  • the anionic surfactant is selected from alkyl sulphates or alkyl ether sulphates.
  • the total amount of surfactants in the composition of the invention is generally between 0.1 % and 30% by weight, preferably from 1 % to 20%, more preferably from 1 % to 10%, by weight relative to the weight of the composition.
  • compositions may also comprise various adjuvants which are typically used in compositions for colouring or lightening hair, such as anionic, cationic or nonionic polymers or mixtures thereof; antioxidants; penetrants; sequestrants; fragrances; dispersants; film-formers; ceramides; preservatives; opacifiers; and cationic surfactants.
  • adjuvants which are typically used in compositions for colouring or lightening hair, such as anionic, cationic or nonionic polymers or mixtures thereof; antioxidants; penetrants; sequestrants; fragrances; dispersants; film-formers; ceramides; preservatives; opacifiers; and cationic surfactants.
  • the above adjuvants are generally present in an amount, for each of them, of between 0.01 % and 20% by weight relative to the weight of the composition.
  • composition according to the invention preferably comprises one or more cationic polymers.
  • the composition according to the invention may comprise water and/or one or more organic solvents.
  • Organic solvents include for example monoalcohols or diols, which are linear or branched, preferably saturated, and contain 2 to 10 carbon atoms, such as ethyl alcohol, isopropyl alcohol, hexylene glycol (2-methyl-2,4-pentanediol), neopentyl glycol and 3-methyl-1 ,5-pentanediol, butylene glycol, dipropylene glycol and propylene glycol; aromatic alcohols such as benzyl alcohol and phenylethyl alcohol; polyols having more than two hydroxyl functions, such as glycerol; polyol ethers such as, for example, the monomethyl, monoethyl and monobutyl ethers of ethylene glycol, propylene glycol or its ethers such as, for example, the monomethyl ether of propylene glycol; and also the alkyl
  • the organic solvents when they are present, generally represent between 1 % and 40% by weight relative to the total weight of the dye composition, and preferably between 5% and 30% by weight relative to the total weight of the dye composition.
  • the composition is preferably aqueous. In this case it preferably comprises from 30% to 95% of water by weight, more preferably from 40% to 90% of water by weight, even more preferably from 50% to 85% of water by weight relative to the total weight of the composition.
  • the pH of the composition according to the invention is generally between 3 and 12, preferably between 5 and 11 , more preferably between 7 and 1 1 , end points included.
  • the pH may be adjusted to the desired value by means of acidifying or alkalifying agents which are commonly used in dyeing keratinic fibres, and in particular the alkanolamines of the invention.
  • composition according to the invention is in the form of a mousse.
  • composition in mousse form according to the invention is formed from a mixture of air or an inert gas with the composition described above.
  • the composition according to the invention is in the form of a temporary mousse produced just before use.
  • the composition may be packaged in a mousse distributor.
  • the compositions in question may be aerosol products, distributed from a pressurized container by means of a propellant gas, thus forming a mousse at the time of their distribution, or compositions which are distributed from a container by means of a mechanical pump connected to a distribution head, where the passage of the composition into the distribution head transforming it into a mousse no later than at the outlet orifice of such a head.
  • the distributor may be an aerosol containing, in addition to the base composition, divided generally into two parts, one with the oxidizing agent or agents and the other with the dye precursor or precursors, a propellant gas. In a configuration of this kind, the two parts are generally stored each separately in a container under pressure. Accordingly, the propellant gases selected in each of the containers may be adapted to the component contained.
  • the propellant gas which can be used may be selected from carbon dioxide, nitrogen, nitrogen oxide, dimethyl ether, volatile hydrocarbons such as butane, isobutane, propane and pentane, and mixtures thereof.
  • the distribution head is such that the system sprayed in mousse form is the composition according to the invention, in other words the mixture of the composition with the oxidizing agent or agents and the composition with the oxidation dye precursor or precursors.
  • the composition may be located within a pump canister mousse distributor.
  • These distributors comprise a distribution head for delivering the composition, a pump and a descender tube for transferring the composition from the container to the head for delivering the product.
  • the mousse is formed by forcing the composition through a material comprising a porous substance, such as a sintered material, a metal or plastic filtering grid, or similar structures.
  • the oxidizing agent or agents are packaged in a first container equipped with a stopper, and the oxidation dye precursor or precursors are packaged in a second container, distinct from the first, and likewise closed by a closing member.
  • the closing member may be a pump distribution mechanism.
  • the composition according to the invention is then formed by mixing, before use, a composition with the oxidizing agent or agents and a composition with the oxidation dye precursor or precursors.
  • one of the first and second containers defines an internal volume sufficient to accommodate the whole of the two compositions.
  • the mixture of the compositions can be homogenized by closing this container and shaking it.
  • the container is advantageously closed directly with the distribution head.
  • This distribution head comprises a mechanical pump held in a band intended to be mounted, by snap- fastening or screwing, onto the neck of the container holding the mixture.
  • the pump comprises a pump body connected to a descender tube for allowing the whole of the mixture to be distributed.
  • the pump also comprises a pushbutton for actuating the pump body such that, on each actuation, one dose of composition is drawn into the descender tube and ejected in the form of a mousse at the distribution orifice of the head.
  • the containers are preferably made from a thermoplastic material, and are obtained by extrusion blow moulding or injection blow moulding processes.
  • the container intended for packaging the composition with the oxidation dye precursor or precursors is made from a material having a non-zero proportion of EVOH.
  • the pump is, for example, the standard "F2 - L9" model sold by Rexam.
  • the invention provides a non-aerosol device comprising the composition of the invention.
  • the colouring method according to the invention involves applying the composition according to the invention to wet or dry human keratinic fibres for a time sufficient for development of the desired coloration.
  • the composition applied to the keratinic fibres is in mousse from.
  • the colouring method is generally employed at ambient temperature (between 15 to 25°C) and at temperatures which may be up to 60°C to 80°C.
  • the keratinic fibres are rinsed with water and optionally undergo washing with a shampoo, followed by rinsing with water.
  • compositions below are prepared (the amounts are expressed in g% of active substances)
  • Oxidation dye precursors base(s) and coupler(s)) qs shade
  • composition above is obtained by mixing weight for weight, before use, two compositions, A and B, as follows:
  • Composition A % by weight
  • Oxidation dye precursors base(s) and coupler(s)) qs shade
  • Composition B % by weight
  • the mixture is introduced in an amount of 65 g (26 g of composition A + 39 g of composition B) into a pump canister (Rexam L9) equipped with a descender tube.
  • the device by pumping, allows a mousse to be obtained which is sufficiently compact to be applied to natural or permanent-waved grey hair containing 90% white hairs, without undergoing instantaneous disintegration. The comfort on application is very good.
  • the locks of hair are rinsed, washed with a standard shampoo, rinsed again and then dried to give the desired coloration. This coloration is strong and of low selectivity.

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  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

La présente invention concerne une composition de coloration de fibres kératiniques humaines telles que les cheveux, sous forme de mousse, comprenant : (a) au moins un agent tensio-actif amphotère et/ou anionique ; (b) de la monoéthanolamine ; (c) au moins une alcanolamine autre que la monoéthanolamine ; (d) au moins un agent oxydant ; (e) au moins un précurseur de colorant d'oxydation. L'invention concerne également un procédé de traitement de fibres kératiniques humaines employant cette composition sous forme de mousse, et des dispositifs aérosols ou non-aérosols pour générer cette mousse.
PCT/EP2011/068933 2010-11-02 2011-10-28 Composition de mousse colorante à base d'un mélange d'alcanolamines comprenant de la monoéthanolamine WO2012059412A1 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
FR1059005A FR2966724B1 (fr) 2010-11-02 2010-11-02 Composition de coloration mousse a base d'un melange d'alcanolamine dont la monoethanolamine
FR1059005 2010-11-02
US41297810P 2010-11-12 2010-11-12
US61/412,978 2010-11-12

Publications (1)

Publication Number Publication Date
WO2012059412A1 true WO2012059412A1 (fr) 2012-05-10

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FR (1) FR2966724B1 (fr)
WO (1) WO2012059412A1 (fr)

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JPS63169571A (ja) 1987-01-06 1988-07-13 Nec Corp ト−ン検出装置
DE3843892A1 (de) 1988-12-24 1990-06-28 Wella Ag Oxidationshaarfaerbemittel mit einem gehalt an diaminopyrazolderivaten und neue diaminopyrazolderivate
JPH0563124A (ja) 1991-09-03 1993-03-12 Mitsubishi Electric Corp 混成集積回路装置
DE4133957A1 (de) 1991-10-14 1993-04-15 Wella Ag Haarfaerbemittel mit einem gehalt an aminopyrazolderivaten sowie neue pyrazolderivate
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WO1994008969A1 (fr) 1992-10-16 1994-04-28 Wella Aktiengesellschaft Procede de production de derives de 4,5-diaminopyrazole, leur utilisation pour la teinture des cheveux, et nouveaux derives de pyrazole
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EP0770375A1 (fr) 1995-10-21 1997-05-02 GOLDWELL GmbH Composition pour la teinture des cheveux
DE19543988A1 (de) 1995-11-25 1997-05-28 Wella Ag Oxidationshaarfärbemittel mit einem Gehalt an 3,4,5-Triaminopyrazolderivaten sowie neue 3,4,5-Triaminopyrazolderivate
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GB1153196A (en) 1965-07-07 1969-05-29 Schwarzkopf Verwaltung G M B H Method of Dyeing Hair
US3709437A (en) 1968-09-23 1973-01-09 Hershel Earl Wright Method and device for producing foam
GB1271331A (en) * 1969-05-21 1972-04-19 Gillette Co Hair dye package
DE2359399A1 (de) 1973-11-29 1975-06-12 Henkel & Cie Gmbh Haarfaerbemittel
US3937364A (en) 1975-04-03 1976-02-10 Hershel Earl Wright Foam dispensing device
US4022351A (en) 1975-04-03 1977-05-10 Hershel Earl Wright Foam dispenser
US4184615A (en) 1975-04-03 1980-01-22 Wright Hershel E Foam dispensing device
US4147306A (en) 1977-09-28 1979-04-03 Bennett Robert S Foam producing apparatus
US4598862A (en) 1983-05-31 1986-07-08 The Dow Chemical Company Foam generating device and process
US4615467A (en) 1985-07-24 1986-10-07 Calmar, Inc. Liquid foam dispenser
JPS63169571A (ja) 1987-01-06 1988-07-13 Nec Corp ト−ン検出装置
DE3843892A1 (de) 1988-12-24 1990-06-28 Wella Ag Oxidationshaarfaerbemittel mit einem gehalt an diaminopyrazolderivaten und neue diaminopyrazolderivate
JPH0563124A (ja) 1991-09-03 1993-03-12 Mitsubishi Electric Corp 混成集積回路装置
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WO1994008970A1 (fr) 1992-10-16 1994-04-28 Wella Aktiengesellschaft Colorants d'oxydation pour cheveux, renfermant des derives du 4,5-diaminopyrazole, nouveaux derives du 4,5-diaminopyrazole et leur procede de fabrication
WO1994008969A1 (fr) 1992-10-16 1994-04-28 Wella Aktiengesellschaft Procede de production de derives de 4,5-diaminopyrazole, leur utilisation pour la teinture des cheveux, et nouveaux derives de pyrazole
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FR2733749A1 (fr) 1995-05-05 1996-11-08 Oreal Compositions pour la teinture des fibres keratiniques contenant des diamino pyrazoles, procede de teinture, nouveaux diamino pyrazoles et leur procede de preparation
DE19527121A1 (de) * 1995-07-25 1997-01-30 Henkel Kgaa Oxidationsfärbemittel
EP0770375A1 (fr) 1995-10-21 1997-05-02 GOLDWELL GmbH Composition pour la teinture des cheveux
DE19543988A1 (de) 1995-11-25 1997-05-28 Wella Ag Oxidationshaarfärbemittel mit einem Gehalt an 3,4,5-Triaminopyrazolderivaten sowie neue 3,4,5-Triaminopyrazolderivate
FR2801308A1 (fr) 1999-11-19 2001-05-25 Oreal COMPOSITIONS DE TEINTURE DE FIBRES KERATINIQUES CONTENANT DE DES 3-AMINO PYRAZOLO-[1,(-a]-PYRIDINES, PROCEDE DE TEINTURE, NOUVELLES 3-AMINO PYRAZOLO-[1,5-a]-PYRIDINES
US20040103488A1 (en) * 2002-11-27 2004-06-03 Takahiro Yamashita Hair dye composition
FR2886136A1 (fr) 2005-05-31 2006-12-01 Oreal Composition pour la teinture des fibres keratiniques comprenant au moins un derive de diamino-n,n-dihydro- pyrazolone et un colorant d'oxydation cationique

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FR2966724A1 (fr) 2012-05-04

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