WO2012040088A3 - A novel class of olefin metathesis catalysts, methods of preparation, and processes for the use thereof - Google Patents
A novel class of olefin metathesis catalysts, methods of preparation, and processes for the use thereof Download PDFInfo
- Publication number
- WO2012040088A3 WO2012040088A3 PCT/US2011/052109 US2011052109W WO2012040088A3 WO 2012040088 A3 WO2012040088 A3 WO 2012040088A3 US 2011052109 W US2011052109 W US 2011052109W WO 2012040088 A3 WO2012040088 A3 WO 2012040088A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- group
- processes
- preparation
- methods
- olefin metathesis
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 2
- 238000000034 method Methods 0.000 title 2
- 238000005865 alkene metathesis reaction Methods 0.000 title 1
- 239000003446 ligand Substances 0.000 abstract 3
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 150000004703 alkoxides Chemical class 0.000 abstract 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 abstract 1
- 150000008052 alkyl sulfonates Chemical class 0.000 abstract 1
- 125000000129 anionic group Chemical group 0.000 abstract 1
- -1 aryloxides Chemical class 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 150000002431 hydrogen Chemical class 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 238000005649 metathesis reaction Methods 0.000 abstract 1
- 230000007935 neutral effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/002—Osmium compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/46—Ruthenium, rhodium, osmium or iridium
- B01J23/462—Ruthenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/46—Ruthenium, rhodium, osmium or iridium
- B01J23/466—Osmium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/121—Metal hydrides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2286—Alkynes, e.g. acetylides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
- C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
- C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0046—Ruthenium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
- C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
- C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
- C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
- B01J2231/54—Metathesis reactions, e.g. olefin metathesis
- B01J2231/543—Metathesis reactions, e.g. olefin metathesis alkene metathesis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/821—Ruthenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/825—Osmium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- C07C2531/22—Organic complexes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
- C07C2601/10—Systems containing only non-condensed rings with a five-membered ring the ring being unsaturated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
- C08G2261/33—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain
- C08G2261/332—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms
- C08G2261/3324—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms derived from norbornene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
- C08G2261/33—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain
- C08G2261/332—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms
- C08G2261/3325—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms derived from other polycyclic systems
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/40—Polymerisation processes
- C08G2261/41—Organometallic coupling reactions
- C08G2261/418—Ring opening metathesis polymerisation [ROMP]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Catalysts (AREA)
Abstract
This invention relates to a metathesis catalyst comprising (i) a Group 8 metal hydride- dihydrogen complex represented by the formula (I); wherein M is a Group 8 metal; X is an anionic ligand; and L1and L2 are neutral donor ligands; and (ii) a ligand exchange agent represented by the formula J-Y, wherein J is selected from the group consisting of hydrogen, a C1 to C30 hydrocarbyl, and a C1 to C30 substituted hydrocarbyl; and Y is selected from the group consisting of halides, alkoxides, aryloxides, and alkyl sulfonates.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP11827288.9A EP2618930A4 (en) | 2010-09-24 | 2011-09-19 | A novel class of olefin metathesis catalysts, methods of preparation, and processes for the use thereof |
CN201180041259.5A CN103079699B (en) | 2010-09-24 | 2011-09-19 | A novel class of olefin metathesis catalysts, methods of preparation, and processes for the use thereof |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/890,315 US8227371B2 (en) | 2010-09-24 | 2010-09-24 | Class of olefin metathesis catalysts, methods of preparation, and processes for the use thereof |
US12/890,315 | 2010-09-24 | ||
EP10194264.7 | 2010-12-09 | ||
EP10194264 | 2010-12-09 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2012040088A2 WO2012040088A2 (en) | 2012-03-29 |
WO2012040088A3 true WO2012040088A3 (en) | 2012-06-14 |
Family
ID=45874302
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2011/052109 WO2012040088A2 (en) | 2010-09-24 | 2011-09-19 | A novel class of olefin metathesis catalysts, methods of preparation, and processes for the use thereof |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP2618930A4 (en) |
CN (1) | CN103079699B (en) |
WO (1) | WO2012040088A2 (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103732636B (en) * | 2011-08-12 | 2016-05-18 | 埃克森美孚化学专利公司 | The polymer of preparing by open loop/cross metathesis |
AU2014302626B2 (en) * | 2013-06-24 | 2017-09-28 | Materia, Inc. | Thermal insulation |
CN110170077B (en) * | 2019-03-26 | 2021-09-28 | 南京理工大学 | Polyion type biological lubricant and preparation method thereof |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5726334A (en) * | 1995-01-31 | 1998-03-10 | E. I. Du Pont De Nemours And Company | Process for the preparation of ruthenium hydrogenation catalysts and products thereof |
US5917071A (en) * | 1996-11-15 | 1999-06-29 | California Institute Of Technology | Synthesis of ruthenium or osmium metathesis catalysts |
US6500975B1 (en) * | 1998-05-08 | 2002-12-31 | Basf Aktiengesellschaft | Cationic ruthenium complexes, their production and their use |
US20030100782A1 (en) * | 2001-04-02 | 2003-05-29 | Grubbs Robert H. | One-pot synthesis of group 8 transition metal carbene complexes useful as olefin metathesis catalysts |
-
2011
- 2011-09-19 WO PCT/US2011/052109 patent/WO2012040088A2/en active Application Filing
- 2011-09-19 EP EP11827288.9A patent/EP2618930A4/en not_active Withdrawn
- 2011-09-19 CN CN201180041259.5A patent/CN103079699B/en not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5726334A (en) * | 1995-01-31 | 1998-03-10 | E. I. Du Pont De Nemours And Company | Process for the preparation of ruthenium hydrogenation catalysts and products thereof |
US5917071A (en) * | 1996-11-15 | 1999-06-29 | California Institute Of Technology | Synthesis of ruthenium or osmium metathesis catalysts |
US6500975B1 (en) * | 1998-05-08 | 2002-12-31 | Basf Aktiengesellschaft | Cationic ruthenium complexes, their production and their use |
US20030100782A1 (en) * | 2001-04-02 | 2003-05-29 | Grubbs Robert H. | One-pot synthesis of group 8 transition metal carbene complexes useful as olefin metathesis catalysts |
Non-Patent Citations (1)
Title |
---|
See also references of EP2618930A4 * |
Also Published As
Publication number | Publication date |
---|---|
EP2618930A4 (en) | 2014-04-02 |
CN103079699B (en) | 2015-07-08 |
CN103079699A (en) | 2013-05-01 |
WO2012040088A2 (en) | 2012-03-29 |
EP2618930A2 (en) | 2013-07-31 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
WO2012097379A3 (en) | Z-selective olefin metathesis catalysts and their synthetic procedure | |
MX350592B (en) | Process for selectively polymerizing ethylene and catalyst therefor. | |
JP2012082435A5 (en) | ||
MX357204B (en) | Phosphinyl amidine compounds, metal complexes, catalyst systems, and their use to oligomerize or polymerize olefins. | |
WO2010022228A3 (en) | Metal-ligand complexes and catalysts | |
MY152879A (en) | Transition metal complex compounds, olefin oligomerization catalysts including the compounds, and processes for producing olefin oligomers using the catalysts | |
CN104169003A (en) | Catalyst systems for preparing 1-hexene and/or 1-octene from ethylene | |
CA2954836C (en) | Catalyst composition and process for oligomerization of ethylene to produce 1-hexene and/or 1-octene | |
MX2008011107A (en) | Fluorinated transition metal catalysts and formation thereof. | |
WO2011057780A3 (en) | Process for preparing ruthenium(0)-olefin complexes | |
WO2011069134A3 (en) | Supported olefin metathesis catalysts | |
WO2010146176A3 (en) | Process for hydrogenation of halogenoalkenes without dehalogenation | |
Dyakonov | Dzhemilev reactions in organic and organometallic synthesis | |
TW200942327A (en) | Catalyst composition and process for oligomerization of ethylene | |
WO2011154841A3 (en) | Catalyst for olefin polymerization | |
WO2011012687A3 (en) | Phosphine borane compounds comprising imidazol groups and method for producing phosphine borane compounds comprising imidazol groups | |
Singh et al. | Direct C H bond Arylation in Water Promoted by (O, O)-and (O, N)-Chelate Ruthenium (II) Catalysts. | |
WO2012040088A3 (en) | A novel class of olefin metathesis catalysts, methods of preparation, and processes for the use thereof | |
WO2011010891A3 (en) | Novel post metallocene-type transition metal compound | |
WO2011119778A3 (en) | Method for in-situ formation of metathesis catalysts | |
CN106795185B (en) | Ligand compound, organo-chromium compound, the oligomeric antigravity system for alkene and the method using the antigravity system lower polyolefins | |
WO2008148202A8 (en) | Method for the preparation of aminophosphine ligands and their use in metal catalysts | |
WO2011085350A8 (en) | Ziegler-natta catalyst systems and polymers formed therefrom | |
WO2012166259A3 (en) | A novel class of olefin metathesis catalysts, methods of preparation, and processes for the use thereof | |
WO2011156921A3 (en) | Catalyst ligands, catalytic ligand complexes and polymerization processes using same |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
WWE | Wipo information: entry into national phase |
Ref document number: 201180041259.5 Country of ref document: CN |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 11827288 Country of ref document: EP Kind code of ref document: A2 |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
REEP | Request for entry into the european phase |
Ref document number: 2011827288 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2011827288 Country of ref document: EP |