WO2012035004A3 - Hydrocracking catalyst composition - Google Patents

Hydrocracking catalyst composition Download PDF

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Publication number
WO2012035004A3
WO2012035004A3 PCT/EP2011/065837 EP2011065837W WO2012035004A3 WO 2012035004 A3 WO2012035004 A3 WO 2012035004A3 EP 2011065837 W EP2011065837 W EP 2011065837W WO 2012035004 A3 WO2012035004 A3 WO 2012035004A3
Authority
WO
WIPO (PCT)
Prior art keywords
catalyst composition
hydrocracking catalyst
catalyst
hydrocracking
help
Prior art date
Application number
PCT/EP2011/065837
Other languages
French (fr)
Other versions
WO2012035004A2 (en
Inventor
Wiebe Sjoerd Kijlstra
Marcello Stefano Rigutto
Arend Jan Van Welsenes
Original Assignee
Shell Internationale Research Maatschappij B.V.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij B.V. filed Critical Shell Internationale Research Maatschappij B.V.
Publication of WO2012035004A2 publication Critical patent/WO2012035004A2/en
Publication of WO2012035004A3 publication Critical patent/WO2012035004A3/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/16—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J29/166—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
    • B01J29/14—Iron group metals or copper
    • B01J29/146—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0239—Quaternary ammonium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0254—Nitrogen containing compounds on mineral substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C10G47/16—Crystalline alumino-silicate carriers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C10G47/16—Crystalline alumino-silicate carriers
    • C10G47/20—Crystalline alumino-silicate carriers the catalyst containing other metals or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Hydrocracking catalyst composition which comprises a faujasite containing refractory oxide support, one or more catalytically active metals and a polyalkylene polyamine, process for preparing such catalyst and process for hydrocracking with the help of such catalyst.
PCT/EP2011/065837 2010-09-17 2011-09-13 Hydrocracking catalyst composition WO2012035004A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP10177361.2 2010-09-17
EP10177361 2010-09-17

Publications (2)

Publication Number Publication Date
WO2012035004A2 WO2012035004A2 (en) 2012-03-22
WO2012035004A3 true WO2012035004A3 (en) 2012-11-15

Family

ID=44584204

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2011/065837 WO2012035004A2 (en) 2010-09-17 2011-09-13 Hydrocracking catalyst composition

Country Status (1)

Country Link
WO (1) WO2012035004A2 (en)

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3200082A (en) * 1958-09-24 1965-08-10 Union Carbide Corp Metal loading of molecular sieves
EP0181035A2 (en) * 1984-11-05 1986-05-14 Shell Internationale Researchmaatschappij B.V. Preparation of high activity silica-supported hydrotreating catalysts and catalysts thus prepared
US4632747A (en) * 1984-12-28 1986-12-30 Exxon Research And Engineering Company Hydrotreating process employing catalysts comprising a supported, mixed metal sulfide iron promoted Mo and W
WO1995031280A1 (en) * 1994-05-13 1995-11-23 Cytec Technology Corp. High activity catalysts
WO2002004117A1 (en) * 2000-07-12 2002-01-17 Akzo Nobel N.V. Process for preparing an additive-based mixed metal catalyst
JP2002239385A (en) * 2001-02-15 2002-08-27 Cosmo Oil Co Ltd Method for producing hydrotreatment catalyst for hydrocarbon oil and method for hydrotreating hydrocarbon oil
WO2005070542A1 (en) * 2004-01-20 2005-08-04 Shell Internationale Research Maatschappij B.V. A method of restoring catalytic activity of a spent hydrotreating catalyst, the resulting restored catalyst, and a method of hydroprocessing
FR2910351A1 (en) * 2006-12-22 2008-06-27 Total France Sa Hydrotreating catalyst comprising Group VIII and VIB metals on a refractory oxide support comprises an organic compound comprising two thiol groups separated by a ketone- or ether-functional hydrocarbon group
WO2010039772A2 (en) * 2008-10-03 2010-04-08 Chevron U.S.A. Inc. Hydrocracking catalyst and process using a magnesium aluminosilicate clay

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8722839D0 (en) 1987-09-29 1987-11-04 Shell Int Research Hydrocracking of hydrocarbon feedstock
GB8722840D0 (en) 1987-09-29 1987-11-04 Shell Int Research Converting hydrocarbonaceous feedstock
GB8925980D0 (en) 1989-11-16 1990-01-04 Shell Int Research Process for converting hydrocarbon oils
US5435987A (en) 1993-07-22 1995-07-25 Pq Corporation Process for preparing ammonium zeolites of low alkali metal content
US5925235A (en) 1997-12-22 1999-07-20 Chevron U.S.A. Inc. Middle distillate selective hydrocracking process
US7611689B2 (en) 2004-09-24 2009-11-03 Shell Oil Company Faujasite zeolite, its preparation and use in hydrocracking

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3200082A (en) * 1958-09-24 1965-08-10 Union Carbide Corp Metal loading of molecular sieves
EP0181035A2 (en) * 1984-11-05 1986-05-14 Shell Internationale Researchmaatschappij B.V. Preparation of high activity silica-supported hydrotreating catalysts and catalysts thus prepared
US4632747A (en) * 1984-12-28 1986-12-30 Exxon Research And Engineering Company Hydrotreating process employing catalysts comprising a supported, mixed metal sulfide iron promoted Mo and W
WO1995031280A1 (en) * 1994-05-13 1995-11-23 Cytec Technology Corp. High activity catalysts
WO2002004117A1 (en) * 2000-07-12 2002-01-17 Akzo Nobel N.V. Process for preparing an additive-based mixed metal catalyst
JP2002239385A (en) * 2001-02-15 2002-08-27 Cosmo Oil Co Ltd Method for producing hydrotreatment catalyst for hydrocarbon oil and method for hydrotreating hydrocarbon oil
WO2005070542A1 (en) * 2004-01-20 2005-08-04 Shell Internationale Research Maatschappij B.V. A method of restoring catalytic activity of a spent hydrotreating catalyst, the resulting restored catalyst, and a method of hydroprocessing
FR2910351A1 (en) * 2006-12-22 2008-06-27 Total France Sa Hydrotreating catalyst comprising Group VIII and VIB metals on a refractory oxide support comprises an organic compound comprising two thiol groups separated by a ketone- or ether-functional hydrocarbon group
WO2010039772A2 (en) * 2008-10-03 2010-04-08 Chevron U.S.A. Inc. Hydrocracking catalyst and process using a magnesium aluminosilicate clay

Also Published As

Publication number Publication date
WO2012035004A2 (en) 2012-03-22

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