WO2012020321A3 - Washable carpet products with coating layers formed from vinyl ester/ethylene copolymer dispersions - Google Patents

Washable carpet products with coating layers formed from vinyl ester/ethylene copolymer dispersions Download PDF

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Publication number
WO2012020321A3
WO2012020321A3 PCT/IB2011/002652 IB2011002652W WO2012020321A3 WO 2012020321 A3 WO2012020321 A3 WO 2012020321A3 IB 2011002652 W IB2011002652 W IB 2011002652W WO 2012020321 A3 WO2012020321 A3 WO 2012020321A3
Authority
WO
WIPO (PCT)
Prior art keywords
carpet products
ethylene
vinyl acetate
copolymer
ethylene copolymer
Prior art date
Application number
PCT/IB2011/002652
Other languages
French (fr)
Other versions
WO2012020321A2 (en
Inventor
Harmin Muller
Paul Stuart Wormald
Paolo Bavaj
Original Assignee
Celanese Emulsions Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Celanese Emulsions Gmbh filed Critical Celanese Emulsions Gmbh
Priority to EP11804780.2A priority Critical patent/EP2603633A2/en
Priority to CN201180039275.0A priority patent/CN103119215B/en
Priority to US13/811,962 priority patent/US20130177733A1/en
Priority to BR112013003394A priority patent/BR112013003394A2/en
Publication of WO2012020321A2 publication Critical patent/WO2012020321A2/en
Publication of WO2012020321A3 publication Critical patent/WO2012020321A3/en

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • D06N7/0063—Floor covering on textile basis comprising a fibrous top layer being coated at the back with at least one polymer layer, e.g. carpets, rugs, synthetic turf
    • D06N7/0071—Floor covering on textile basis comprising a fibrous top layer being coated at the back with at least one polymer layer, e.g. carpets, rugs, synthetic turf characterised by their backing, e.g. pre-coat, back coating, secondary backing, cushion backing
    • D06N7/0073—Floor covering on textile basis comprising a fibrous top layer being coated at the back with at least one polymer layer, e.g. carpets, rugs, synthetic turf characterised by their backing, e.g. pre-coat, back coating, secondary backing, cushion backing the back coating or pre-coat being applied as an aqueous dispersion or latex
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/042—Acrylic polymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0006—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using woven fabrics
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0009—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using knitted fabrics
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0011—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using non-woven fabrics
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/004—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using flocked webs or pile fabrics upon which a resin is applied; Teasing, raising web before resin application
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2203/00—Macromolecular materials of the coating layers
    • D06N2203/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N2203/042—Polyolefin (co)polymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/10—Properties of the materials having mechanical properties
    • D06N2209/106—Roughness, anti-slip, abrasiveness
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/23907—Pile or nap type surface or component
    • Y10T428/23979—Particular backing structure or composition
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/23907—Pile or nap type surface or component
    • Y10T428/23986—With coating, impregnation, or bond

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Laminated Bodies (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)

Abstract

Disclosed are carpet products comprising at least one flexible substrate and at least one coating layer associated with the at least one flexible substrate. The coating layer is formed from an aqueous composition comprising: A) an emulsifier-stabilized vinyl acetate/ethylene (VAE) emulsion copolymer dispersion wherein the VAE copolymer therein comprises co- monomers which include at least vinyl acetate copolymerized with ethylene and optionally also with other additional functional and/or non-functional co-monomers; and B) at least one particulate filler material selected from particulate inorganic compounds and particulate plastic material. The vinyl acetate/ethylene copolymer in the copolymer dispersion has a particle size, dw, ranging from about 50 to about 500 nm as determined by Laser Aerosol Spectroscopy. Such carpet products maintain their integrity and appearance after multiple machine washing operations. Some of these carpet products which have backing coated with certain of the coating compositions used herein also exhibit desirable non-slip properties.
PCT/IB2011/002652 2010-08-12 2011-08-12 Washable carpet products with coating layers formed from vinyl ester/ethylene copolymer dispersions WO2012020321A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP11804780.2A EP2603633A2 (en) 2010-08-12 2011-08-12 Washable carpet products with coating layers formed from vinyl ester/ethylene copolymer dispersions
CN201180039275.0A CN103119215B (en) 2010-08-12 2011-08-12 There is the carpet product washed of the coating layer formed by vinyl acetate/ethylene copolymer dispersion
US13/811,962 US20130177733A1 (en) 2010-08-12 2011-08-12 Washable Carpet Products With Coating Layers Formed From Vinyl Ester/Ethylene Copolymer Dispersions
BR112013003394A BR112013003394A2 (en) 2010-08-12 2011-08-12 washable carpet products with coating layers formed from vinyl ester / ethylene copolymer dispersions

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US37309110P 2010-08-12 2010-08-12
US61/373,091 2010-08-12
US201161481445P 2011-05-02 2011-05-02
US61/481,445 2011-05-02

Publications (2)

Publication Number Publication Date
WO2012020321A2 WO2012020321A2 (en) 2012-02-16
WO2012020321A3 true WO2012020321A3 (en) 2012-04-26

Family

ID=45444650

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB2011/002652 WO2012020321A2 (en) 2010-08-12 2011-08-12 Washable carpet products with coating layers formed from vinyl ester/ethylene copolymer dispersions

Country Status (5)

Country Link
US (1) US20130177733A1 (en)
EP (1) EP2603633A2 (en)
CN (1) CN103119215B (en)
BR (1) BR112013003394A2 (en)
WO (1) WO2012020321A2 (en)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10301772B2 (en) * 2010-05-03 2019-05-28 Celanese International Corporation Carpets with surfactant-stabilized emulsion polymer carpet binders for improved processability
EP2603632B1 (en) 2010-08-12 2020-12-23 Celanese Sales Germany GmbH Flame retardant carpet products with coating and/or adhesive layers formed from vinyl acetate/ethlene copolymer dispersions
CN104302829B (en) * 2011-12-20 2016-10-26 塞拉尼斯销售德国有限公司 The carpet coating compositions of the improved stability formed by vinyl acetate/ethylene/copolymer dispersion
WO2013123210A1 (en) * 2012-02-15 2013-08-22 Celanese International Corporation Carpet products and processes for making same using latex coating compositions
CN102627726B (en) * 2012-04-20 2014-12-03 北京化工大学 Preparation method for formaldehyde catcher and application of formaldehyde catcher to urea resin
US9382341B2 (en) 2012-09-27 2016-07-05 Wacker Chemical Corporation Carpet coating composition
EP2929082A1 (en) * 2012-12-07 2015-10-14 Celanese Emulsions GmbH Carpet products and methods for making same
WO2014165388A1 (en) * 2013-04-02 2014-10-09 Celanese International Corporation Carpet products and processes for making same using latex coating compositions
US20150017376A1 (en) * 2013-07-11 2015-01-15 Milliken & Company Washable Carpet Tile
CN105658868B (en) 2013-10-24 2017-11-17 瓦克化学公司 Carpet product and the method for manufacturing carpet product
DE102014214472A1 (en) 2014-07-24 2016-01-28 Wacker Chemie Ag Aqueous, polyvinyl alcohol-stabilized vinyl acetate-ethylene copolymer dispersion with high filler compatibility for carpet coating compositions
DE102014225773A1 (en) 2014-12-12 2016-06-16 Wacker Chemie Ag Polymers for carpet coating compositions
DE102015206954A1 (en) 2015-04-17 2016-10-20 Wacker Chemie Ag Carpet coating compositions
US20170081544A1 (en) * 2015-09-18 2017-03-23 Celanese International Corporation Carpet coating compositions
US20180250910A1 (en) * 2017-03-06 2018-09-06 Celanese International Corporation Carpet tiles and methods of their manufacture
BR102017010905A2 (en) * 2017-05-24 2018-12-18 Marcio Bretas Fontes De Resende self-adhesive textile coating for decoration on walls, floors, facades and others
KR102228541B1 (en) 2017-09-22 2021-03-15 코오롱인더스트리 주식회사 Non-woven for carpet backing with improved pull-out strength and manufacturing method thereof
WO2022055511A1 (en) 2020-09-14 2022-03-17 Celanese International Corporation Emulsifier stabilized formulated copolymer dispersions and uses thereof in nozzle application for dots and lines
CN114920881A (en) * 2022-05-25 2022-08-19 合肥工业大学 HDPE/PEW-g- (MAH-co-HEMA) micro powder for powder coating and preparation method thereof
CN116063611B (en) * 2022-12-29 2024-05-14 广东银洋环保新材料有限公司 Washable denim coating emulsion and preparation method thereof

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1408894A (en) * 1971-11-02 1975-10-08 Air Prod & Chem Method of forming a laminated fabric
US4735986A (en) * 1985-08-02 1988-04-05 Air Products And Chemicals, Inc. Vinyl acetate/ethylene copolymer emulsions useful as carpet adhesives
EP0263267A2 (en) * 1986-09-08 1988-04-13 National Starch and Chemical Corporation Textile coatings based on ethylene vinyl acetate-maleate copolymers
EP0432391A2 (en) * 1989-12-15 1991-06-19 National Starch and Chemical Investment Holding Corporation Emulsion binder for carpet and carpet tiles
EP0864685A2 (en) * 1997-03-10 1998-09-16 National Starch and Chemical Investment Holding Corporation Carpet coating compositions
EP1008689A2 (en) * 1998-12-09 2000-06-14 National Starch and Chemical Investment Holding Corporation Carpet back coating composition having increased wet strength
US20050287336A1 (en) * 2004-06-24 2005-12-29 Lunsford David J Carpet coating compositions
WO2008054614A1 (en) * 2006-10-31 2008-05-08 Dow Global Technologies Inc. Carpet backing composition
EP2088162A1 (en) * 2008-02-09 2009-08-12 Celanese Emulsions GmbH Method for manufacturing polymer dispersions, dispersions created thereby and their application
WO2010089142A1 (en) * 2009-02-09 2010-08-12 Celanese Emulsions Gmbh Vinyl acetate-ethylene-copolymer dispersions and textile web material treated therewith
WO2011139267A1 (en) * 2010-05-03 2011-11-10 Celanese International Corporation Carpets with surfactant-stabilized emulsion polymer carpet binders for improved processability

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DE102006037317A1 (en) * 2006-08-08 2008-02-14 Celanese Emulsions Gmbh Vinyl ester copolymer dispersions, process for their preparation and use
CN101868572B (en) * 2007-11-23 2013-03-27 皇家飞利浦电子股份有限公司 Tufted textile
CN104302829B (en) * 2011-12-20 2016-10-26 塞拉尼斯销售德国有限公司 The carpet coating compositions of the improved stability formed by vinyl acetate/ethylene/copolymer dispersion

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1408894A (en) * 1971-11-02 1975-10-08 Air Prod & Chem Method of forming a laminated fabric
US4735986A (en) * 1985-08-02 1988-04-05 Air Products And Chemicals, Inc. Vinyl acetate/ethylene copolymer emulsions useful as carpet adhesives
EP0263267A2 (en) * 1986-09-08 1988-04-13 National Starch and Chemical Corporation Textile coatings based on ethylene vinyl acetate-maleate copolymers
EP0432391A2 (en) * 1989-12-15 1991-06-19 National Starch and Chemical Investment Holding Corporation Emulsion binder for carpet and carpet tiles
EP0864685A2 (en) * 1997-03-10 1998-09-16 National Starch and Chemical Investment Holding Corporation Carpet coating compositions
EP1008689A2 (en) * 1998-12-09 2000-06-14 National Starch and Chemical Investment Holding Corporation Carpet back coating composition having increased wet strength
US20050287336A1 (en) * 2004-06-24 2005-12-29 Lunsford David J Carpet coating compositions
WO2008054614A1 (en) * 2006-10-31 2008-05-08 Dow Global Technologies Inc. Carpet backing composition
EP2088162A1 (en) * 2008-02-09 2009-08-12 Celanese Emulsions GmbH Method for manufacturing polymer dispersions, dispersions created thereby and their application
WO2010089142A1 (en) * 2009-02-09 2010-08-12 Celanese Emulsions Gmbh Vinyl acetate-ethylene-copolymer dispersions and textile web material treated therewith
WO2011139267A1 (en) * 2010-05-03 2011-11-10 Celanese International Corporation Carpets with surfactant-stabilized emulsion polymer carpet binders for improved processability
WO2011140065A2 (en) * 2010-05-03 2011-11-10 Celanese International Corporation Carpets with surfactant-stabilized emulsion polymer carpet binders for improved processability

Also Published As

Publication number Publication date
CN103119215B (en) 2015-09-23
EP2603633A2 (en) 2013-06-19
CN103119215A (en) 2013-05-22
BR112013003394A2 (en) 2019-09-24
WO2012020321A2 (en) 2012-02-16
US20130177733A1 (en) 2013-07-11

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