WO2011163348A2 - Traitements de carburant d'aviation dans bioraffinerie forestière intégrée - Google Patents

Traitements de carburant d'aviation dans bioraffinerie forestière intégrée Download PDF

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Publication number
WO2011163348A2
WO2011163348A2 PCT/US2011/041431 US2011041431W WO2011163348A2 WO 2011163348 A2 WO2011163348 A2 WO 2011163348A2 US 2011041431 W US2011041431 W US 2011041431W WO 2011163348 A2 WO2011163348 A2 WO 2011163348A2
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WO
WIPO (PCT)
Prior art keywords
wood
jet fuel
processes
process platform
organic acids
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Application number
PCT/US2011/041431
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English (en)
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WO2011163348A3 (fr
Inventor
Hemant P. Pendse
G. Peter Van Walsum
M. Clayton Wheeler
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University Of Maine System Board Of Trustees
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Publication of WO2011163348A2 publication Critical patent/WO2011163348A2/fr
Publication of WO2011163348A3 publication Critical patent/WO2011163348A3/fr

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08H—DERIVATIVES OF NATURAL MACROMOLECULAR COMPOUNDS
    • C08H8/00—Macromolecular compounds derived from lignocellulosic materials
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/002—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal in combination with oil conversion- or refining processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/006—Combinations of processes provided in groups C10G1/02 - C10G1/08
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/02—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by distillation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/40—Thermal non-catalytic treatment
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/50—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids in the presence of hydrogen, hydrogen donors or hydrogen generating compounds
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P39/00—Processes involving microorganisms of different genera in the same process, simultaneously
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/40—Preparation of oxygen-containing organic compounds containing a carboxyl group including Peroxycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/40—Preparation of oxygen-containing organic compounds containing a carboxyl group including Peroxycarboxylic acids
    • C12P7/54—Acetic acid
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/40—Preparation of oxygen-containing organic compounds containing a carboxyl group including Peroxycarboxylic acids
    • C12P7/56—Lactic acid
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C10G2300/1014—Biomass of vegetal origin
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/08—Jet fuel
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P2203/00—Fermentation products obtained from optionally pretreated or hydrolyzed cellulosic or lignocellulosic material as the carbon source
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Definitions

  • Jet fuel is currently derived from petroleum resources. Increasing worldwide use of air travel and leveling production of petroleum are likely to result in high prices for jet fuel into the foreseeable future. Unlike other uses for liquid fuels, such as home heating or ground transportation, there are no renewable alternatives available for fueling jet-powered air transportation. For reasons of increased sustainability and national security, it would be desirable to produce jet fuel from renewable resources.
  • This invention relates to an integrated suite of processes to make jet fuel from wood.
  • the processes are located within a wood products processing facility.
  • Fig. 5 is a graph showing accumulation of C3-C7 carboxylic acids in four wood extract fermentation conditions.
  • Fig. 6 is a graph showing accumulation of lactic acid in four wood extract fermentation conditions.
  • Fig. 7 is a graph showing accumulation of lactic acid in four wood extract fermentation conditions.
  • Fig. 8 shows sequencing batch fermentation at 50 gallon scale. After initial batch growth, fermented extract was removed and replaced with fresh extract at a rate of 20% volume once per week. On day 94 the extract was increased to 50% volume once per week.
  • Any suitable woody or other lignocellulosic feedstock can be used in the process.
  • specific feedstocks of interest include (1) forest residue available as low quality whole tree chips often used for direct combustion in wood-fired boilers and (2) raw wood extracts rich in hemicelluloses that otherwise would have been burned as a part of spent black liquor in recovery boilers at pulp mills. These two feedstocks are potentially available at existing wood processing facilities. Pulp mill facilities can include both producing facilities and repurposed facilities that are no longer producing pulp.
  • TDO Thermal deoxygenation
  • Hydroprocessing involves hydrogenation and hydroisomerization aimed at producing an appropriate mix of high carbon number alkanes and branched or cyclo alkanes.
  • the invention provides an integrated suite of processes to make jet fuel and associated hydrocarbon products from wood.
  • the processes are located within a wood products processing facility such as a pulp mill.
  • Brownstock which had been produced from wood chips in which much of the hemicellulose had been removed by hot water extraction.
  • extract was generated from mixed hardwood either in the Department of Chemical and Biological Engineering at the University of Maine or was kindly supplied by Old Town Fuel and Fiber, of Old Town ME.
  • the extracts were used raw, without conditioning.
  • the extracts used for this study were prepared by carrying out relatively mild condition extractions on hardwoods using either hot water or water mixed with green liquor.
  • Hot water extracts were obtained by cooking aspen wood strands in water.
  • the small scale green liquor extract was a blended 1.44% green liquor hemicellulose extract from mixed hard wood chips.
  • the total sugar content in the green liquor extract was measured to be around 10.25g/L and the acetic acid content was around 11.8g/L.
  • the total sugar content in the hot water extract was measured to be around 27g/L and the acetic acid was about 9.6g/L.
  • the large scale green liquor extracts were generated under similar but not identical conditions.
  • Inocula for this experiment were obtained from various sources, including secondary clarifier sludge from the waste water treatment facility at a kraft pulp mill, saline sediments from The Great Salt Lake in Utah and salt water sediment collected from tidal flats near Rockland or Friendship, ME. To minimize the exposure to oxygen, these were collected in tightly sealed containers with the solids content having microbes covered with sea water.
  • Methanogen Inhibitor
  • the small scale experiments were carried out in duplicate or triplicate batch mode to determine reproducibility of results.
  • the batch fermentations were performed in 250 ml serum bottles (Wheaton science products # 223950).
  • the bottles were filled with approximately 100ml of the wood extract in each bottle, which left sufficient head space for accumulation of produced gasses.
  • These bottles were placed in a shaking incubator (Sartorius Certomat BS-1) with continuous shaking at about 200 rpm and constant temperature maintenance. Two different temperatures are investigated for the process: one at 37°C and the other at 55°C.
  • the floor scale fermentations took place in a single 50 gallon fermentor.
  • One experiment was carried out in sequencing batch mode, in which 20 to 50% of the volume of the fermentor was exchanged once per week with fresh wood extract. This sequencing batch fermentation converted the extract sugar oligomers to organic acids without need of added enzymes or extract conditioning.
  • Bench scale scale fermentations were completed at four conditions: hot water extract at 37 and 55°C and green liquor extract at 37 and 55°C. A summary of results is presented in table SUB5.1.
  • Floor scale fermentations were carried out at 37 C with calcium carbonate and lime as buffers. In general, higher temperature fermentation favors production of acetic acid whereas mesophilic temperature fermentation produces a broader spectrum of longer chain aliphatic acids.
  • Table SUB5.1 Hot water and green liquor extract fermentations at thermophilic and mesophilic temperatures using ammonium bicarbonate as buffering agent.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Zoology (AREA)
  • Biochemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Biotechnology (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • General Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Microbiology (AREA)
  • Materials Engineering (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Abstract

Cette invention concerne une suite intégrée de traitements qui permettent de fabriquer du carburant d'aviation à partir du bois. Dans des modes de réalisation préférés, les traitements sont effectués dans une usine de traitement de produits du bois. L'invention concerne également une plateforme de traitement centrale qui utilise une désoxygénation thermique (TDO) d'acides organiques mélangés afin de produire un mélange majoritairement d'hydrocarbures. L'invention concerne en outre des produits provenant du traitement qui sont hydrotraités afin de faire varier le rendement et la composition du produit d'hydrocarbures qui comprend du carburant d'aviation et d'autres fractions d'hydrocarbures associées. Les produits peuvent être mélangés avec des tri-décanes ou tri-acylglycérides afin d'améliorer la qualité du carburant.
PCT/US2011/041431 2010-06-22 2011-06-22 Traitements de carburant d'aviation dans bioraffinerie forestière intégrée WO2011163348A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US35728010P 2010-06-22 2010-06-22
US61/357,280 2010-06-22

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WO2011163348A2 true WO2011163348A2 (fr) 2011-12-29
WO2011163348A3 WO2011163348A3 (fr) 2012-04-12

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2735610A1 (fr) 2012-11-26 2014-05-28 Neste Oil Oyj Cellules bactériennes oléagineuses et procédés pour produire des lipides
US9073841B2 (en) 2012-11-05 2015-07-07 Segetis, Inc. Process to prepare levulinic acid
US10618864B2 (en) 2011-11-23 2020-04-14 Gfbiochemicals Ip Assets B.V. Process to prepare levulinic acid

Citations (9)

* Cited by examiner, † Cited by third party
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WO2007068797A2 (fr) * 2005-12-12 2007-06-21 Neste Oil Oyj Procede de production d'un compose d'hydrocarbure ramifie
US20090031615A1 (en) * 2007-08-01 2009-02-05 General Electric Company Integrated method for producing a fuel component from biomass and system therefor
US20090056201A1 (en) * 2007-08-27 2009-03-05 Endicott Biofuels Ii, Llc Production of Ester-based Fuels Such As Biodiesel From Renewable Starting Materials
WO2009059936A2 (fr) * 2007-11-09 2009-05-14 Upm-Kymmene Oyj Procédé intégré de fabrication de carburant diesel à partir de matière biologique et produits, utilisations et appareillage se rapportant audit procédé
US20090124839A1 (en) * 2006-06-06 2009-05-14 Dumesic James A Production of liquid alkanes in the jet fuel range (c8-c15) from biomass-derived carbohydrates
US20090229172A1 (en) * 2008-03-17 2009-09-17 Brady John P Production of Transportation Fuel from Renewable Feedstocks
US20090253947A1 (en) * 2008-04-06 2009-10-08 Brandvold Timothy A Production of Blended Fuel from Renewable Feedstocks
US20100140136A1 (en) * 2008-12-08 2010-06-10 Chevron U.S.A. Inc., Selective, integrated processing of bio-derived ester species to yield low molecular weight hydrocarbons and hydrogen for the production of biofuels
US20100146843A1 (en) * 2008-12-17 2010-06-17 Bp Corporation North America Inc. Process, Plant And Biofuel For Integrated Biofuel Production

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007068797A2 (fr) * 2005-12-12 2007-06-21 Neste Oil Oyj Procede de production d'un compose d'hydrocarbure ramifie
US20090124839A1 (en) * 2006-06-06 2009-05-14 Dumesic James A Production of liquid alkanes in the jet fuel range (c8-c15) from biomass-derived carbohydrates
US20090031615A1 (en) * 2007-08-01 2009-02-05 General Electric Company Integrated method for producing a fuel component from biomass and system therefor
US20090056201A1 (en) * 2007-08-27 2009-03-05 Endicott Biofuels Ii, Llc Production of Ester-based Fuels Such As Biodiesel From Renewable Starting Materials
WO2009059936A2 (fr) * 2007-11-09 2009-05-14 Upm-Kymmene Oyj Procédé intégré de fabrication de carburant diesel à partir de matière biologique et produits, utilisations et appareillage se rapportant audit procédé
US20090229172A1 (en) * 2008-03-17 2009-09-17 Brady John P Production of Transportation Fuel from Renewable Feedstocks
US20090253947A1 (en) * 2008-04-06 2009-10-08 Brandvold Timothy A Production of Blended Fuel from Renewable Feedstocks
US20100140136A1 (en) * 2008-12-08 2010-06-10 Chevron U.S.A. Inc., Selective, integrated processing of bio-derived ester species to yield low molecular weight hydrocarbons and hydrogen for the production of biofuels
US20100146843A1 (en) * 2008-12-17 2010-06-17 Bp Corporation North America Inc. Process, Plant And Biofuel For Integrated Biofuel Production

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10618864B2 (en) 2011-11-23 2020-04-14 Gfbiochemicals Ip Assets B.V. Process to prepare levulinic acid
US9073841B2 (en) 2012-11-05 2015-07-07 Segetis, Inc. Process to prepare levulinic acid
EP2735610A1 (fr) 2012-11-26 2014-05-28 Neste Oil Oyj Cellules bactériennes oléagineuses et procédés pour produire des lipides
WO2014080070A1 (fr) 2012-11-26 2014-05-30 Neste Oil Oyj Cellules bactériennes oléagineuses et procédés de production de lipides

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