WO2011148067A8 - Method for the conversion of synthesis gas into vapor, and apparatus for carrying out said method - Google Patents

Method for the conversion of synthesis gas into vapor, and apparatus for carrying out said method Download PDF

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Publication number
WO2011148067A8
WO2011148067A8 PCT/FR2011/000363 FR2011000363W WO2011148067A8 WO 2011148067 A8 WO2011148067 A8 WO 2011148067A8 FR 2011000363 W FR2011000363 W FR 2011000363W WO 2011148067 A8 WO2011148067 A8 WO 2011148067A8
Authority
WO
WIPO (PCT)
Prior art keywords
vapor
conversion
carrying
synthesis gas
water
Prior art date
Application number
PCT/FR2011/000363
Other languages
French (fr)
Other versions
WO2011148067A1 (en
Inventor
Christophe Boyer
Béatrice Fischer
Karine Surla
Fabrice Giroudiere
Jean Calvez
Sylvain Rethore
Original Assignee
IFP Energies Nouvelles
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles filed Critical IFP Energies Nouvelles
Publication of WO2011148067A1 publication Critical patent/WO2011148067A1/en
Publication of WO2011148067A8 publication Critical patent/WO2011148067A8/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/12Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C01B3/16Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24Stationary reactors without moving elements inside
    • B01J19/248Reactors comprising multiple separated flow channels
    • B01J19/249Plate-type reactors
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B01J8/067Heating or cooling the reactor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796Details of the reactor or of the particulate material
    • B01J2208/00823Mixing elements
    • B01J2208/00831Stationary elements
    • B01J2208/00849Stationary elements outside the bed, e.g. baffles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24Stationary reactors without moving elements inside
    • B01J2219/2401Reactors comprising multiple separate flow channels
    • B01J2219/245Plate-type reactors
    • B01J2219/2461Heat exchange aspects
    • B01J2219/2462Heat exchange aspects the reactants being in indirect heat exchange with a non reacting heat exchange medium
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0283Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C01B2203/0288Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step containing two CO-shift steps
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0872Methods of cooling
    • C01B2203/0888Methods of cooling by evaporation of a fluid
    • C01B2203/0894Generation of steam
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1047Group VIII metal catalysts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1047Group VIII metal catalysts
    • C01B2203/1052Nickel or cobalt catalysts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1047Group VIII metal catalysts
    • C01B2203/1064Platinum group metal catalysts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1076Copper or zinc-based catalysts

Abstract

The invention relates to a water gas shift reactor comprising, in a single enclosure, a catalytic water gas shift reaction zone, a water tank, and a heat exchanger between the catalytic zone and the water.
PCT/FR2011/000363 2010-05-25 2011-06-23 Method for the conversion of synthesis gas into vapor, and apparatus for carrying out said method WO2011148067A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR10/02181 2010-05-25
FR1002181A FR2960451B1 (en) 2010-05-25 2010-05-25 STEAM CONVERSION METHOD FOR SYNTHESIS GAS AND APPARATUS FOR CARRYING OUT SAID METHOD

Publications (2)

Publication Number Publication Date
WO2011148067A1 WO2011148067A1 (en) 2011-12-01
WO2011148067A8 true WO2011148067A8 (en) 2012-10-11

Family

ID=43402225

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2011/000363 WO2011148067A1 (en) 2010-05-25 2011-06-23 Method for the conversion of synthesis gas into vapor, and apparatus for carrying out said method

Country Status (2)

Country Link
FR (1) FR2960451B1 (en)
WO (1) WO2011148067A1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3060553B1 (en) * 2016-12-15 2021-02-19 Air Liquide EXCHANGER-REACTOR INCLUDING CONNECTORS WITH SUPPORTS
FR3064348B1 (en) * 2017-03-24 2019-04-05 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude HEAT EXCHANGER COMPRISING CONNECTORS WITH SUPPORTS

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3825501A (en) * 1969-11-26 1974-07-23 Texaco Inc Exothermic reaction process
GB8521649D0 (en) * 1985-08-30 1985-10-02 Ici Plc Hydrogen production
US6306354B1 (en) * 1996-05-17 2001-10-23 International Fuel Cells, Llc Shift converter
DE19851109B4 (en) * 1998-11-06 2008-01-10 Heisel, Michael, Dr. Reactor for carrying out catalytic reactions with strong heat of reaction
DE10040209A1 (en) * 2000-08-17 2002-02-28 Linde Ag Reactor for carrying out a strongly heat-toned catalytic reaction
WO2002053491A2 (en) * 2000-12-28 2002-07-11 Ballard Power Systems Inc. Shell and tube reactor
US20040226217A1 (en) 2003-05-16 2004-11-18 University Of Chicago Fuel processor for producing hydrogen from hydrocarbon fuels
CN101616865B (en) 2006-11-30 2012-11-07 国际壳牌研究有限公司 Systems and processes for producing hydrogen and carbon dioxide
WO2009052764A1 (en) * 2007-10-19 2009-04-30 Ren Lou A composite reaction apparatus and the chemical production method using the same
US8528343B2 (en) * 2008-01-07 2013-09-10 General Electric Company Method and apparatus to facilitate substitute natural gas production

Also Published As

Publication number Publication date
FR2960451B1 (en) 2017-07-28
FR2960451A1 (en) 2011-12-02
WO2011148067A1 (en) 2011-12-01

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