WO2011140351A2 - Compositions anhydres contenant un épaississant acrylique - Google Patents

Compositions anhydres contenant un épaississant acrylique Download PDF

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Publication number
WO2011140351A2
WO2011140351A2 PCT/US2011/035373 US2011035373W WO2011140351A2 WO 2011140351 A2 WO2011140351 A2 WO 2011140351A2 US 2011035373 W US2011035373 W US 2011035373W WO 2011140351 A2 WO2011140351 A2 WO 2011140351A2
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WIPO (PCT)
Prior art keywords
composition
oil
present
acrylic thickener
compositions
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PCT/US2011/035373
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English (en)
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WO2011140351A3 (fr
Inventor
Chunhua Li
Hy Si Bui
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L'oreal S.A.
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Publication of WO2011140351A2 publication Critical patent/WO2011140351A2/fr
Publication of WO2011140351A3 publication Critical patent/WO2011140351A3/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/31—Hydrocarbons
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/342—Alcohols having more than seven atoms in an unbroken chain
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A61K8/8182—Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/927—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of insects, e.g. shellac
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/30—Characterized by the absence of a particular group of ingredients
    • A61K2800/31—Anhydrous

Definitions

  • the present invention relates to anhydrous compositions comprising at least one acrylic thickener.
  • anhydrous compositions containing an acrylic thickener have surprisingly good volumizing and removal properties.
  • compositions including pigmented cosmetics such as foundations, concealers, lipsticks, and mascaras, and other cosmetic and sunscreen compositions, have been formulated in an attempt to posses good feel and texture upon application.
  • pigmented cosmetics such as foundations, concealers, lipsticks, and mascaras
  • other cosmetic and sunscreen compositions have been formulated in an attempt to posses good feel and texture upon application.
  • many of these compositions can be difficult to apply and do not possess a soft texture or smooth feel upon application.
  • such compositions oftentimes have a tendency to feel tacky, yielding poor application and spreadability characteristics.
  • Silicone elastomers have been added to cosmetic compositions to improve the feel of the compositions.
  • the use of silicone elastomers can be problematic, given their expense and that they l can be difficult to formulate owing to their chemical make up -- for example, compositions including silicone elastomers can be unstable, particularly if uncomplimentary compounds are added to an elastomer-containing composition.
  • one aspect of the present invention is a care and/or makeup and/or treatment composition for keratinous material which has good cosmetic properties such as, for example, good feel and/or texture properties upon application, good volumizing properties and/or good removability.
  • the present invention relates to anhydrous compositions comprising at least one acrylic thickener.
  • the present invention also relates to colored anhydrous compositions comprising at least one coloring agent and at least one acrylic thickener.
  • colored compositions can be, for example, cosmetic compositions such as lip compositions (for example, lipstick or liquid lip colors), mascaras, eyeshadows or foundations.
  • the present invention also relates to methods of treating, caring for and/or making up keratinous material (for example, skin, eyes, eyelashes or lips) by applying compositions of the present invention comprising at least one acrylic thickener to the keratinous material in an amount sufficient to treat, care for and/or make up the keratinous material.
  • these methods further comprise exposing the applied
  • composition to water in an amount sufficient to swell the acrylic thickener.
  • the present invention also relates to methods of enhancing the appearance of keratinous material (for example, skin, eyes, eyelashes, or lips) by applying compositions of the present invention comprising at least one acrylic thickener to the keratinous material in an amount sufficient to enhance the appearance of the keratinous material.
  • these methods further comprise exposing the applied
  • composition to water in an amount sufficient to swell the acrylic thickener.
  • the present invention also relates to methods of volumizing eyelashes comprising applying a mascara composition of the present invention comprising at least one acrylic thickener to eyelashes and exposing the applied mascara to water in an amount sufficient to swell the acrylic thickener in an amount sufficient to volumize the eyelashes.
  • the present invention further relates to anhydrous compositions having improved cosmetic properties such as, for example, increased volumizing and removal properties.
  • the present invention further relates to kits containing an anhdrous composition of the present invention comprising at least one acrylic thickener, and a topcoat composition comprising water.
  • anhydrous composition of the present invention is a mascara.
  • Fig. 1 is a graphic demonstration of the results from example 1 in which the diameter of lashes was monitored as a function of time, and the swelling-deswelling-reswelling behavior was monitored as a function of time.
  • the expression “at least one” means one or more and thus includes individual components as well as mixtures/combinations.
  • Film former or "film forming agent” as used herein means a polymer or resin that leaves a film on the substrate to which it is applied, for example, after a solvent accompanying the film former has evaporated, absorbed into and/or dissipated on the substrate.
  • Transfer resistance refers to the quality exhibited by compositions that are not readily removed by contact with another material, such as, for example, a glass, an item of clothing or the skin, for example, when eating or drinking. Transfer resistance may be evaluated by any method known in the art for evaluating such. For example, transfer resistance of a composition may be evaluated by a "kiss” test. The "kiss" test may involve application of the composition to human keratin material such as hair, skin or lips followed by rubbing a material, for example, a sheet of paper, against the hair, skin or lips after expiration of a certain amount of time following application, such as 2 minutes after application. Similarly, transfer resistance of a composition may be
  • compositions evaluated by the amount of product transferred from a wearer to any other substrate, such as transfer from the hair, skin or lips of an individual to a collar when putting on clothing after the expiration of a certain amount of time following application of the composition to the hair, skin or lips.
  • the amount of composition transferred to the substrate may then be evaluated and compared.
  • a composition may be transfer resistant if a majority of the product is left on the wearer's hair, skin or lips. Further, the amount transferred may be compared with that transferred by other compositions, such as commercially available
  • compositions In a preferred embodiment of the present invention, little or no composition is transferred to the substrate from the hair, skin or lips.
  • Long wear compositions refers to compositions where color remains the same or substantially the same as at the time of application, as viewed by the naked eye, after an extended period of time.
  • Long wear properties may be evaluated by any method known in the art for evaluating such properties. For example, long wear may be evaluated by a test involving the application of a composition to human hair, skin or lips and evaluating the color of the composition after an extended period of time. For example, the color of a composition may be evaluated immediately following application to hair, skin or lips and these characteristics may then be re-evaluated and compared after a certain amount of time. Further, these characteristics may be evaluated with respect to other compositions, such as commercially available compositions.
  • Substituted means comprising at least one substituent.
  • substituents include atoms, such as oxygen atoms and nitrogen atoms, as well as functional groups, such as hydroxyl groups, ether groups, alkoxy groups, acyloxyalky groups, oxyalkylene groups, polyoxyalkylene groups, carboxylic acid groups, amine groups, acylamino groups, amide groups, halogen containing groups, ester groups, thiol groups, sulphonate groups, thiosulphate groups, siloxane groups, and polysiloxane groups.
  • the substituent(s) may be further substituted.
  • Volatile as used herein, means having a flash point of less than about 100°C.
  • Non-volatile as used herein, means having a flash point of greater than about 100°C.
  • compositions contain less than 1 % water.
  • compositions of the present invention comprising the at least one acrylic thickener contain no water.
  • compositions may be in any form, either liquid or non-liquid (semi-solid, soft solid, solid, etc.).
  • they may be a paste, a solid, a gel, or a cream.
  • They may be an emulsion, such as an oil-in-water or water-in-oil emulsion, a multiple emulsion, such as an oil-in-water-in-oil emulsion or a water-in-oil-in-water emulsion, or a solid, rigid or supple gel.
  • the compositions of the invention may, for example, comprise an external or continuous fatty phase.
  • the compositions can also be a molded composition or cast as a stick or a dish.
  • hardness of the composition may also be considered.
  • the hardness of a composition may, for example, be expressed in gramforce (gf).
  • the composition of the present invention may, for example, have a hardness ranging from 20 gf to 2000 gf, such as from 20 gf to 900 gf, and further such as from 20 gf to 600 gf .
  • a first test for hardness is according to a method of penetrating a probe into the composition and in particular using a texture analyzer (for example TA-XT2i from Rheo) equipped with an ebonite cylinder of height 25 mm and diameter 8 mm.
  • the hardness measurement is carried out at 20°C at the center of 5 samples of the composition.
  • the cylinder is introduced into each sample of composition at a pre-speed of 2 mm/s and then at a speed of 0.5 mm/s and finally at a post-speed of 2 mm/s, the total displacement being 1 mm.
  • the recorded hardness value is that of the maximum peak observed.
  • the measurement error is ⁇ 50gf.
  • the second test for hardness is the "cheese wire” method, which involves cutting an 8.1 mm or preferably 12.7 mm in diameter stick composition and measuring its hardness at 20°C using a DFGHS 2 tensile testing machine from Indelco-Chatillon Co. at a speed of 100 mm/minute.
  • the hardness value from this method is expressed in grams as the shear force required to cut a stick under the above conditions.
  • the hardness of compositions according to the present invention which may be in stick form may, for example, range from 30 gf to 300 gf, such as from 30 gf to 250 gf, for a sample of 8.1 mm in diameter stick, and further such as from 30 gf to 200 gf, and also further such as from 30 gf to 120 gf for a sample of 12.7 mm in diameter stick.
  • the hardness of the composition of the present invention may be such that the compositions are self-supporting and can easily disintegrate to form a satisfactory deposit on keratin materials.
  • this hardness may impart good impact strength to the inventive
  • compositions which may be molded or cast, for example, in stick or dish form.
  • composition may be evaluated using at least one of the tests for hardness outlined above based on the application envisaged and the hardness desired. If one obtains an acceptable hardness value, in view of the intended application, from at least one of these hardness tests, the composition falls within preferred embodiments of the invention.
  • stability is tested by placing the composition in a controlled environment chamber for 8 weeks at 25°C.
  • the physical condition of the sample is inspected as it is placed in the chamber.
  • the sample is then inspected again at 24 hours, 3 days, 1 week, 2 weeks, 4 weeks and 8 weeks.
  • the sample is examined fo abnormalities in the composition such as phase separation if the composition is in the form of an emulsion, bending or leaning if the composition is in stick form, melting, or syneresis (or sweating).
  • the stability is further tested by repeating the 8-week test at 25°C, 37°C, 45°C and under freeze-thaw conditions.
  • a composition is considered to lack stability if in any of these tests an abnormality that impedes functioning of the composition is observed. The skilled artisan will readily recognize an abnormality that impedes functioning of a composition based on the intended application.
  • compositions and methods of the present invention can comprise, consist of, or consist essentially of the essential elements and limitations of the invention described herein, as well as any additional or optional ingredients, components, or limitations described herein or otherwise useful in personal care.
  • compositions comprising at least one acrylic thickener are provided.
  • Acrylic thickener refers to polymers based upon one or more (meth)acrylic acid (and corresponding (meth)acrylate) monomers or similar monomers.
  • the acrylic thickener is an anionic acrylic polymer comprising at least one monomer performing a weak acid function such as, for example, acrylic acid, methacrylic acid, itaconic acid, crotonic acid, maleic acid and/or fumaric acid.
  • a weak acid function such as, for example, acrylic acid, methacrylic acid, itaconic acid, crotonic acid, maleic acid and/or fumaric acid.
  • the acrylic thickener is an anionic acrylic polymer further comprising at least one monomer performing a strong acid function such as, for example, monomers having a function of the sulfonic acid type or phosphonic acid type, such as 2- acrylamido-2-methylpropane sulfonic acid (AMPS).
  • a strong acid function such as, for example, monomers having a function of the sulfonic acid type or phosphonic acid type, such as 2- acrylamido-2-methylpropane sulfonic acid (AMPS).
  • the anionic acrylic polymer may be crosslinked (or branched). Suitable examples of
  • acceptable crosslinking agents include, but are not limited to, methylene bisacrylamide (MBA), ethylene glycol diacrylate, polyethylene glycol dimethacrylate, diacrylamide, cyanomethacrylate, vinyloxyethacrylate or methacrylate, formaldehyde, glyoxal, and compositions of the glycidylether type such as ethyleneglycol diglycidylether, or epoxydes.
  • MVA methylene bisacrylamide
  • ethylene glycol diacrylate polyethylene glycol dimethacrylate
  • diacrylamide diacrylamide
  • cyanomethacrylate vinyloxyethacrylate or methacrylate
  • formaldehyde glyoxal
  • compositions of the glycidylether type such as ethyleneglycol diglycidylether, or epoxydes.
  • Particularly preferred acrylic thickeners are disclosed in U.S. patent application publication nos. 2004/0028637 and 2008/0196174, the entire contents of both of which are incorporated herein by reference.
  • Particularly preferred acrylic thickeners are sodium acrylate/sodium acryloyldimethyl taurate.
  • a particularly preferred acrylic thickener is that sold under the INCI name Sodium Acrylate/Sodium Acryloyldimethyl Taurate Copolymer & Hydrogenated Polydecene & Sorbitan Laurate & Trideceth-6 which is marketed by Arch Personal Care Products, South Plainfield, NJ, USA under the tradename ViscUp®EZ.
  • the acrylic thickener(s) represent from about 0.1 % to about 20 % of the total weight of the composition, more preferably from about 1 % to about 10% of the total weight of the composition, and most preferably from about 2.5% to about 7.5%, including all ranges and subranges therebetween.
  • compositions comprising at least one fatty substance are provided.
  • Suitable fatty substances include oil(s) and/or wax(es).
  • Oil means any non-aqueous medium which is liquid at ambient temperature (25°C) and atmospheric pressure (760 mm Hg).
  • a "wax” for the purposes of the present disclosure is a lipophilic fatty compound that is solid at ambient temperature (25°C) and changes from the solid to the liquid state reversibly, having a melting temperature of more than 30°C and, for example, more than 45°C, which can be as high as 150°C, a hardness of more than 0.5 MPa at ambient temperature, and an anisotropic crystalline organization in the solid state.
  • Suitable oils include volatile and/or non-volatile oils.
  • oils can be any acceptable oil including but not limited to silicone oils and/or hydrocarbon oils.
  • the composition of the present invention preferably comprise one or more volatile silicone oils.
  • volatile silicone oils include linear or cyclic silicone oils having a viscosity at room temperature less than or equal to 6cSt and having from 2 to 7 silicon atoms, these silicones being optionally substituted with alkyl or alkoxy groups of 1 to 10 carbon atoms.
  • Specific oils that may be used in the invention include octamethyltetrasiloxane,
  • volatile oils which may be used include KF 96A of 6 cSt viscosity, a commercial product from Shin Etsu having a flash point of 94°C.
  • the volatile silicone oils have a flash point of at least 40°C.
  • Non-limiting examples of volatile silicone oils are listed in Table 1 below.
  • a volatile linear silicone oil may be employed in the present invention.
  • Suitable volatile linear silicone oils include those described in U.S. patent no. 6,338,839 and WO03/042221 , the contents of which are incorporated herein by reference.
  • the volatile linear silicone oil is decamethyltetrasiloxane.
  • the decamethyltetrasiloxane is further combined with another solvent that is more volatile than decamethyltetrasiloxane.
  • the composition of the present invention preferably comprises one or more non-silicone volatile oils and may be selected from volatile hydrocarbon oils, volatile esters and volatile ethers.
  • volatile non-silicone oils include, but are not limited to, volatile hydrocarbon oils having from 8 to 16 carbon atoms and their mixtures and in particular branched Cs to Ci 6 alkanes such as C 8 to C-I 6 isoalkanes (also known as isoparaffins), isododecane, isodecane, and for example, the oils sold under the trade names of Isopar or Permethyl.
  • the volatile non-silicone oils have a flash point of at least 40°C.
  • Non-limiting examples of volatile non-silicone volatile oils are given in Table 2 below.
  • the volatility of the solvents/oils can be determined using the evaporation speed as set forth in U.S. patent no. 6,338,839, the contents of which are incorporated by reference herein.
  • the composition comprises at least one non-volatile oil.
  • non-volatile oils that may be used in the present invention include, but are not limited to, polar oils such as:
  • hydrocarbon-based plant oils with a high triglyceride content consisting of fatty acid esters of glycerol, the fatty acids of which may have varied chain lengths, these chains possibly being linear or branched, and saturated or unsaturated; these oils are especially wheat germ oil, corn oil, sunflower oil, karite butter, castor oil, sweet almond oil, macadamia oil, apricot oil, soybean oil, rapeseed oil, cottonseed oil, alfalfa oil, poppy oil, pumpkin oil, sesame seed oil, marrow oil, avocado oil, hazelnut oil, grape seed oil, blackcurrant seed oil, evening primrose oil, millet oil, barley oil, quinoa oil, olive oil, rye oil, safflower oil, candlenut oil, passion flower oil or musk rose oil; or caprylic/capric acid triglycerides, for instance those sold by the company Stearineries Dubois or those sold under the names Miglyol
  • R 5 represents a linear or branched higher fatty acid residue containing from 1 to 40 carbon atoms, including from 7 to 19 carbon atoms
  • R 6 represents a branched hydrocarbon-based chain containing from 1 to 40 carbon atoms, including from 3 to 20 carbon atoms, with R 6 + R7 > 10, such as, for example, Purcellin oil (cetostearyl octanoate), isononyl isononanoate, C12 to C15 alkyl benzoate, isopropyl myristate, 2-ethylhexyl palmitate, and octanoates, decanoates or ricinoleates of alcohols or of polyalcohols;
  • Purcellin oil cetostearyl octanoate
  • isononyl isononanoate C12 to C15 alkyl benzoate
  • isopropyl myristate isopropyl myristate, 2-ethylhexyl palmitate
  • hydroxylated esters for instance isostearyl lactate or diisostearyl malate; and pentaerythritol esters;
  • C 8 to C 2 6 fatty alcohols for instance oleyl alcohol, cetyl alcohol, stearyl alcohol, and cetearly alcohol;
  • non-volatile oils examples include, but are not limited to, non-polar oils such as branched and unbranched hydrocarbons and hydrocarbon waxes including polyolefins, in particular Vaseline (petrolatum), paraffin oil, squalane, squalene, hydrogenated polyisobutene, hydrogenated polydecene, polybutene, mineral oil, pentahydrosqualene, and mixtures thereof.
  • non-polar oils such as branched and unbranched hydrocarbons and hydrocarbon waxes including polyolefins, in particular Vaseline (petrolatum), paraffin oil, squalane, squalene, hydrogenated polyisobutene, hydrogenated polydecene, polybutene, mineral oil, pentahydrosqualene, and mixtures thereof.
  • the at least oil is a high viscosity oil which is a silicone oil and/or a hydrocarbon oil.
  • “High viscosity” means an oil having a viscosity greater than 250 cSt at 25°C.
  • Suitable examples of such silicone oils include, but are not limited to, non-volatile silicone fluids such as, for example, polyalkyl (aryl) siloxanes.
  • Suitable polyalkyl siloxanes include, but are not limited to, polydimethyl siloxanes, which have the CTFA designation dimethicone, polydiethyl siloxane, phenyl trimethicone, trimethyl pentaphenyl trisiloxane, phenyldimethicone, phenyltrimethylsiloxydiphenylsiloxane,
  • suitable high viscosity silicone oils include, but are not limited to, 15 M 30 from PCR (500 cSt) or Belsil PDM 1000 (1 000 cSt) from
  • Wacker and Dow Corning 200 (350 cSt) (the values in parenthesis represent viscosities at 25°C).
  • hydrocarbon oils include, but are not limited to, fluids having a molecular mass of more than 500 g/mol, for example more than 600 g/mol, and for example more than 650 g/mol.
  • hydrocarbon a compound comprising principally atoms of carbon and hydrogen and optionally one or more functional groups chosen from hydroxyl, ester, ether and carboxyl functions.
  • compounds are, according to one aspect, devoid of --S1--O-- groups.
  • Suitable ester oils can also be described according to formula R-
  • Ri represents a linear or branched higher fatty acid residue containing from 1 to 40 carbon atoms, including from 7 to 19 carbon atoms
  • R 2 represents a branched hydrocarbon-based chain
  • esters for instance isostearyl lactate or diisostearyl malate; and pentaerythritol esters.
  • a particularly preferred ester is diisostearyl malate.
  • the at least one oil is present in the compositions of the present invention in an amount ranging from about 0.1 to about 30% by weight, more preferably from about 0.5% to about 15% by weight, and most preferably from about 1 % to about 5% by weight, based on the total weight of the composition, including all ranges and subranges within these ranges.
  • the compositions of the present invention comprise at least one wax.
  • suitable examples of waxes that can be used in accordance with the present disclosure include those generally used in the cosmetics field: they include those of natural origin, such as beeswax, carnauba wax, candelilla wax, ouricoury wax, Japan wax, cork fibre wax or sugar cane wax, rice wax, montan wax, paraffin wax, lignite wax or microcrystalline wax, ceresin or ozokerite, and hydrogenated oils such as hydrogenated castor oil or jojoba oil; synthetic waxes such as the polyethylene waxes obtained from the polymerization or copolymerization of ethylene, and Fischer-Tropsch waxes, or else esters of fatty acids, such as octacosanyl stearate, glycerides which are concrete at 30°C, for example at 45°C, silicone waxes, such as alkyl- or alkoxydimethicones having an al
  • Heterene under the name HEST 2T-4S, and mixtures thereof.
  • the wax or waxes may be present in an amount ranging from 0.1 to 50% by weight relative to the total weight of the composition, for example from 1 to 30%, and for example from 3 to 25%, including all ranges and subranges therebetween.
  • the acrylic thickener and the fatty substance(s) are present in the compositions of the present invention in a weight ratio of 1 :2 to 1 :20, preferably 1 :3 to 1 :15, and preferably 1 :4 to 1 :12, including all ranges and subranges therebetween.
  • compositions further comprising at least one coloring agent are provided.
  • such colored compositions can be cosmetic
  • compositions such as, for example, lip compositions (for example, lipstick or liquid lip colors), mascaras, nail polish or foundations.
  • the at least one coloring agent is preferably chosen from pigments, dyes, such as liposoluble dyes, nacreous pigments, and pearling agents.
  • Representative liposoluble dyes which may be used according to the present invention include Sudan Red, DC Red 17, DC Green 6, ⁇ -carotene, soybean oil, Sudan Brown, DC Yellow 1 1 , DC Violet 2, DC Orange 5, annatto, and quinoline yellow.
  • the liposoluble dyes when present, generally have a concentration ranging up to 20% by weight of the total weight of the composition, such as from 0.0001 % to 6%, including all ranges and subranges therebetween..
  • the nacreous pigments which may be used according to the present invention may be chosen from white nacreous pigments such as mica coated with titanium or with bismuth oxychloride, colored nacreous pigments such as titanium mica with iron oxides, titanium mica with ferric blue or chromium oxide, titanium mica with an organic pigment chosen from those mentioned above, and nacreous pigments based on bismuth oxychloride.
  • white nacreous pigments such as mica coated with titanium or with bismuth oxychloride
  • colored nacreous pigments such as titanium mica with iron oxides, titanium mica with ferric blue or chromium oxide, titanium mica with an organic pigment chosen from those mentioned above, and nacreous pigments based on bismuth oxychloride.
  • composition in a concentration ranging up to 50% by weight of the total weight of the composition, such as from 0.1 % to 20%, preferably from 0.1 % to 15%, including all ranges and subranges therebetween.
  • the pigments which may be used according to the present invention, may be chosen from white, colored, inorganic, organic, polymeric, nonpolymeric, coated and uncoated pigments.
  • Representative examples of mineral pigments include titanium dioxide, optionally surface- treated, zirconium oxide, zinc oxide, cerium oxide, iron oxides, chromium oxides, manganese violet, ultramarine blue, chromium hydrate, and ferric blue.
  • Representative examples of organic pigments include carbon black, pigments of D & C type, and lakes based on cochineal carmine, barium, strontium, calcium, and aluminum. [0070] If present, the pigments may be present in the
  • the composition in a concentration ranging up to 50 % by weight of the total weight of the composition, such as from 0.5% to 40%, and further such as from 2% to 30%, including all ranges and subranges therebetween.
  • the pigments, including nacreous pigments may, for example, represent up to 50% by weight of the composition.
  • composition of the invention can also comprise any additive usually used in the field under consideration.
  • dispersants such as poly(12-hydroxystearic acid), antioxidants, film forming agents, essential oils, sunscreens, preserving agents, fragrances, fillers, neutralizing agents, cosmetic and dermatological active agents such as, for example, emollients, moisturizers, vitamins, essential fatty acids,
  • surfactants silicone elastomers, pasty compounds, viscosity increasing agents such as waxes or liposoluble/lipodispersible polymers, and mixtures thereof can be added.
  • a non-exhaustive listing of such ingredients can be found in U.S. patent application publication no. 2004/0170586, the entire contents of which is hereby incorporated by reference.
  • Further examples of suitable additional components can be found in the other references which have been incorporated by reference in this application. Still further examples of such additional ingredients may be found in the International Cosmetic Ingredient Dictionary and Handbook (9 th ed. 2002).
  • additives may be present in the composition in a proportion from 0% to 99% (such as from 0.01 % to 90%) relative to the total weight of the composition and further such as from 0.1 % to 50% (if present), including all ranges and subranges therebetween.
  • composition of the invention should be cosmetically or dermatologically acceptable, i.e., it should contain a nontoxic physiologically acceptable medium and should be able to be applied to the eyelashes of human beings.
  • compositions of the present invention contain less than 10% wax, preferably less than 5% wax, preferably less than 3% wax, preferably less than 2% wax, and preferably less than 1 % wax.
  • compositions of the present invention are provided.
  • "making up" the keratin material includes applying at least one coloring agent to the keratin material in an amount sufficient to provide color to the keratin material.
  • compositions of the present invention to the keratinous material in an amount sufficient to enhance the appearance of the keratinous material are provided.
  • the compositions of the present invention comprising at least one acrylic thickener are applied topically to the desired area of the keratin material in an amount sufficient to treat, care for and/or make up the keratinous material, to cover or hide defects associated with keratinous material, skin imperfections or discolorations, or to enhance the appearance of keratinous material.
  • the compositions may be applied to the desired area as needed, preferably once or twice daily, more preferably once daily and then preferably allowed to dry before subjecting to contact such as with clothing or other objects (for example, a glass or a topcoat).
  • the composition is allowed to dry for about 1 minute or less, more preferably for about 45 seconds or less.
  • the composition is preferably applied to the desired area that is dry or has been dried prior to application, or to which a basecoat has been previously applied.
  • these methods further comprise exposing the applied anhydrous composition to water in an amount sufficient to swell the acrylic thickener.
  • such exposure to water occurs after the applied composition has dried.
  • the applied composition is exposed to a composition consisting of or consisting essentially of water (for example, water is sprayed or applied on the eyelashes after the anhydrous composition comprising the acrylic thickener has been applied).
  • the applied composition may also be exposed to a composition comprising water such as, for example, a topcoat composition comprising water which is applied on eyelashes after the composition comprising the acrylic thickener has been applied.
  • Such a topcoat composition can be in any form such as, for example, a liquid composition comprising water or a gelled composition comprising water.
  • the amount of water to which the applied composition is exposed is sufficient to cause the acrylic thickener to swell but insufficient to facilitate removal of the applied composition.
  • the amount of water applied to cause a swelling but not removal effect is preferably between 1 and 4 grams of water, preferably between 1 and 3 grams of water.
  • the anhydrous composition of the present invention and the water-containing composition are present in a kit.
  • methods of volumizing eyelashes comprise applying an anhydrous mascara composition of the present invention comprising at least one acrylic thickener to eyelashes and exposing the applied mascara to water in an amount sufficient to swell the acrylic thickener in an amount sufficient to volumize the eyelashes.
  • the water can be contained in a composition consisting of, consisting essentially of or comprising water.
  • compositions having improved cosmetic properties such as, for example, increased volumizing and removal properties are provided.
  • compositions comprise at least one acrylic thickener.
  • the improved volumizing and removal properties result from the presence of the acrylic thickener. Exposure to controlled amounts of water causes the acrylic thickener to swell, thereby providing a volumizing effect on keratinous material such as hair or eyelashes as discussed above. Exposure to greater amounts of water causes the acrylic thickener to breakdown and the applied composition to breakdown, resulting in easier removal of the applied composition as discussed below.
  • the compositions of the present invention can be removed using water or a composition comprising water.
  • the amount of water to which the applied composition is exposed is sufficient to cause the acrylic thickener to breakdown to facilitate removal of the applied composition.
  • the amount of water applied to facilitate removal is preferably between 5 and 20 grams of water, preferably between 6 and 15 grams of water, and preferably between 7 and 10 grams of water.
  • a Steareth-2 2.30 %
  • phase A materials were added and heated until 90°C (solids melted and became uniform)

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  • Insects & Arthropods (AREA)
  • Emergency Medicine (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne une composition anhydre, en particulier une composition cosmétique, qui comprend au moins un épaississant acrylique, ainsi que des procédés d'utilisation desdites compositions.
PCT/US2011/035373 2010-05-05 2011-05-05 Compositions anhydres contenant un épaississant acrylique WO2011140351A2 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US33166310P 2010-05-05 2010-05-05
US33163710P 2010-05-05 2010-05-05
US61/331,663 2010-05-05
US61/331,637 2010-05-05

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WO2011140351A2 true WO2011140351A2 (fr) 2011-11-10
WO2011140351A3 WO2011140351A3 (fr) 2012-04-05

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030118619A1 (en) * 2001-09-12 2003-06-26 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Thickened cosmetic compositions
US20060088486A1 (en) * 2002-12-27 2006-04-27 Mcnamara William E Topical use of post-application expanding cosmetic composition
US20090047309A1 (en) * 2007-08-13 2009-02-19 Maes Daniel H Cosmetic methods and compositions for repairing human skin
US20090068132A1 (en) * 2007-09-08 2009-03-12 Daniela Bratescu Resveratrol Ferulate Compounds, Compositions Containing The Compounds, And Methods Of Using The Same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030118619A1 (en) * 2001-09-12 2003-06-26 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Thickened cosmetic compositions
US20060088486A1 (en) * 2002-12-27 2006-04-27 Mcnamara William E Topical use of post-application expanding cosmetic composition
US20090047309A1 (en) * 2007-08-13 2009-02-19 Maes Daniel H Cosmetic methods and compositions for repairing human skin
US20090068132A1 (en) * 2007-09-08 2009-03-12 Daniela Bratescu Resveratrol Ferulate Compounds, Compositions Containing The Compounds, And Methods Of Using The Same

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