Classifications

• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
  • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
  • B65D83/00—Containers or packages with special means for dispensing contents
  • B65D83/14—Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
  • B65D83/44—Valves specially adapted therefor; Regulating devices
  • B65D83/46—Tilt valves

Definitions

• the present invention concerns a valve for dispensing fluid from a pressurized container, more particularly for moisture sensitive fluids such as one or two component polyurethane foam compositions.
• the containers are usually made of metal, topped with a metal cup wherein a valve is provided.
• the valve is the most sensitive element of the container in terms of moisture ingress and is by far the most important part regarding ease of handling of the container and ease of dispensing of the fluid without wasting the valuable fluid contained in the container.
• the grommet essentially comprises a tubular member having an outwardly extending skirt at one end thereof, the surface of the skirt facing away from the tubular member defining the valve seat.
• the tubular member hereby fulfills a spring function, whereas the skirt has a primary sealing function.
• a remaining challenge for the existing valves is that moisture can penetrate through the valve to the valve seat such that for example polyurethane compositions start curing against the valve seat, preventing good closing of the valve and rendering the content of the container unusable.
• WO 2009/004097 discloses a valve resolving the problem of moisture ingress, wherein the grommet is a dual plastic grommet that is manufactured in two materials.
• the skirt is manufactured in a material having a hardness that is greater hardness of the tubular member.
• WO 2005/102867 discloses another valve resolving the problem of moisture ingress, by altering the design of the grommet.
• WO 2005/102867 describes a so called flat grommet, wherein the skirt of the grommet is designed as a flat flange with a reduced thickness of less than 4 mm. This altered grommet design limits the surface through which moisture can penetrate into the container and hence improves shelf life of the container.
• said flat grommet has the inconvenience that the skirt is compressed by the stem at elevated pressure levels in the container at which for example polyurethane foam compositions are stored. Due to that compression of the skirt, the stem protrudes further through the cup and increases the risk of accidental opening of the valve by contact therewith, for example at the time of mounting a dispensing gun on the container.
• the present invention meets this demand by providing a new grommet that ensures extended shelf life of the fluid in the concerned container and that is easy in manufacture and valve assembly and allows easy handling of the concerned container.
• the present invention concerns a valve comprising a grommet and a stem, the grommet comprising a tubular member having an outwardly extending radial skirt at one end, said grommet being manufactured in a single material, characterized in that said material has a hardness ranging between 80 Shore A - 90 Shore A and in that the valve has a gas loss of less than 5 grams per year, preferably less than 3 grams per year, more preferably less than 2,5 grams per year, most preferably less than 1 ,5 grams per year.
• the hardness of the grommet material preferably ranges between 85 Shore A and 90 Shore A and even more preferably between 87 Shore A and 90 Shore A.
• the material preferably has a pressure deformation at room temperature of 25% or less, preferably 20% or less, and more preferably 15% or less according to DIN ISO 815.
• the grommet is preferably manufactured in a thermoplastic polyurethane (TPU) and more preferably in an aromatic TPU.
• TPU thermoplastic polyurethane
• the grommet has a sealing function in view of a stem and a spring function acting on said stem in a closing direction of the valve, such that the valve can lack a spring.
• the present invention further relates to the use of the above described valve in pressurized containers for storing moisture sensitive liquids such as one or two component polyurethane compositions.
• Figure 1 represents a side view of a valve according to the present invention
• Figure 2 represents a cross section according to line A-A in figure 1 ;
• Figure 3 represents another embodiment of a valve according to the present invention.
• Figure 4 represents a cross section according to line B-B in figure 3;
• Figure 5 represents yet another embodiment of a valve according to the present invention.
• Figure 6 represents a cross section according to line C-C in figure 5;
• Figure 7 represents yet another embodiment of a valve according to the present invention.
• Figure 8 represents a cross section according to line D-D in figure 7. Description of a preferred Embodiment
• Figure 1 represents a cup 1 bearing a gun valve 2 the cup being designed for fixing on a container for closing it.
• Figure 2 represents a cross section visualizing the gun valve 2 that comprises a grommet 3 and a stem 4.
• the grommet 3 is fixed in a sealing relation in an orifice 5 in the cup 1 of the container and grommet essentially comprises a tubular member 6 having an outwardly extending skirt 7 at one end thereof. The other end 8 of the tubular element 6 is preferably free.
• annular groove 9 is provided in the outer surface of the tubular member 6, adjacent to the skirt 7, that is designed to snap fit with edges 10 of an orifice in the cup 1 to fix the grommet 3 in a sealing relation in the cup 1 , such that the skirt 7 is located inside the container when assembled, whereas the tubular member 6 extends through the orifice out of the container.
• the grommet is manufactured in a single material having a hardness ranging between 80 Shore A - 90 Shore A and preferably between 85 Shore A and 90 Shore A, most preferably between 87 Shore A and 90 Shore A.
• the grommet material further preferably has a pressure deformation at room temperature of 20% or more preferably 15% or less according to DIN ISO 815.
• the grommet is preferably manufactured in a thermoplastic polyurethane (TPU), more preferably an aromatic TPU.
• TPU thermoplastic polyurethane
• a suitable TPU with a hardness 85 Shore A is described in for example US 2008/207846 A1 .
• the stem 4 is preferably manufactured in a dimensionally stable material such as polypropylene or polyethylene either or not comprising glass fibers and comprises a hollow shaft 1 1 extending perpendicularly from a base plate 12 and a radially extending shoulder 13 provided on the shaft 1 1 at a defined distance from the base plate 12. The distance between the facing surfaces of the base plate 12 and the shoulder 13 being slightly smaller than the distance between a surface 14 of the grommet's skirt 7 facing away from the tubular element 6 and the free end 8 of the tubular member of the grommet 3.
• a series of openings 15 is provided through which, in an open position of the valve, a fluid to be dispensed can flow from the container through the shaft of the stem 4.
• the grommet 3 is snap fitted in the cup 1 of the container such that the skirt 7 abuts the inner surface of the cup 1 .
• the stem 4 is mounted in the grommet 3 such that the base plate is located in the container and abuts the surface of the skirt facing away from the grommet's tubular member 6, this surface of the skirt 7 defining the valve seat.
• the shaft 1 1 of the stem extends through the tubular member 6 out of the container, whereby the shoulder 13 faces the free end of the tubular member 6, thereby preventing that the stem 4 can be pressed through the grommet into the container and at least slightly compressing the tubular member in the longitudinal direction, such that the tubular member exerts a force on the stem in a closing direction of the valve.
• the gun valve In use, the gun valve is forced into a closed position by, on the one hand a spring functionality of the grommet and in particular of the tubular member 6 acting on the shoulder 13 of the shaft 1 1 , and on the other hand, by the pressure inside the container, acting on the base of the stem and forcing it in close abutment with the grommet's skirt 7.
• valve At release of the pressure applied on the stem, the valve is forced closed by the spring function of the tubular member regaining its uncompressed state and by the pressure inside the container that is higher than ambient pressure.
• the valve according to the present invention preferably lacks a separate spring acting on the stem in a valve closing direction.
• valve has a gas loss of less than 5 grams per year, preferably less than 3 grams per year, even more preferably of less than 2,5 grams per year and most preferably less than 1 ,5 grams per year.
• the gas loss in grams/year is measured by providing the valve on a container in a sealing relation and filling the container with a gas mixture of 4 volume parts of LPG (LPG being defined by a mixture of 46,5% propane; 33,5% butane and 20% isobutane) and 1 volume part of dimethylether upto a pressure of 6 bar at 23°C.
• LPG being defined by a mixture of 46,5% propane; 33,5% butane and 20% isobutane
• the container is than stored at 23°C in a position wherein the valve is situated at the top of the container.
• the amount of gas escaping from the closed container with the valve kept closed is measured weekly for upto 8 weeks, by measuring the loss of weight of the closed container and the results are extrapolated to a period of a year, resulting in a value of X grams per year of gas lost.
• Figures 3 and 4 represent a gun valve 20 wherein the design of the skirt 27 of the grommet 23 is slightly different in that the thickness thereof is larger.
• the design corresponds to the design of the valve as described in WO 2004/002986.
• the functionality of this gun valve is essentially similar to what is described above.
• Figures 5 and 6 represent a tilting valve 30 with a design similar to the valve represented in claims 1 and 2, with the only difference that the shaft 31 1 of the stem 34 is provided with a screw thread at it's free end.
• Figures 7 and 8 represents a tilting valve 40 with the grommet design corresponding to that in figures 3 and 4.
• the valve according to the present invention is particularly suitable for use in pressurized containers storing moisture sensitive liquids, such as for example one or two component polyurethane (foam) compositions.
• moisture sensitive liquids such as for example one or two component polyurethane (foam) compositions.

Landscapes

• Chemical & Material Sciences (AREA)
• Dispersion Chemistry (AREA)
• Engineering & Computer Science (AREA)
• Mechanical Engineering (AREA)
• Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
• Closures For Containers (AREA)

Applications Claiming Priority (2)

Publications (1)

Family

ID=42646257

Family Applications (1)

Country Status (2)

Cited By (1)

Citations (7)

• 2010
  • 2010-04-07 EP EP10159274A patent/EP2374731A1/de not_active Withdrawn
• 2011
  • 2011-03-31 WO PCT/EP2011/055020 patent/WO2011124520A1/en active Application Filing

Patent Citations (7)

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