WO2011123508A4 - Methods for producing pyrolysis products - Google Patents

Methods for producing pyrolysis products Download PDF

Info

Publication number
WO2011123508A4
WO2011123508A4 PCT/US2011/030470 US2011030470W WO2011123508A4 WO 2011123508 A4 WO2011123508 A4 WO 2011123508A4 US 2011030470 W US2011030470 W US 2011030470W WO 2011123508 A4 WO2011123508 A4 WO 2011123508A4
Authority
WO
WIPO (PCT)
Prior art keywords
previous
group
oxide catalyst
metal oxide
basic metal
Prior art date
Application number
PCT/US2011/030470
Other languages
French (fr)
Other versions
WO2011123508A2 (en
WO2011123508A3 (en
Inventor
Doron Levin
Original Assignee
Exxonmobil Research And Engineering Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Research And Engineering Company filed Critical Exxonmobil Research And Engineering Company
Priority to CA2795044A priority Critical patent/CA2795044A1/en
Priority to EP11713934A priority patent/EP2553051A2/en
Priority to AU2011235233A priority patent/AU2011235233A1/en
Priority to CN2011800174883A priority patent/CN102822318A/en
Priority to SG2012070371A priority patent/SG184206A1/en
Priority to JP2013502791A priority patent/JP2013523960A/en
Publication of WO2011123508A2 publication Critical patent/WO2011123508A2/en
Publication of WO2011123508A3 publication Critical patent/WO2011123508A3/en
Publication of WO2011123508A4 publication Critical patent/WO2011123508A4/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/02—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B57/00—Other carbonising or coking processes; Features of destructive distillation processes in general
    • C10B57/12—Applying additives during coking
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y02P20/145—Feedstock the feedstock being materials of biological origin
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Coke Industry (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

The present invention provides pyrolysis products that have greater stability than pyrolysis products obtained from conventional pyrolysis production processes. The invention involves pyrolyzing a hydrocarbon feedstock in the presence of a basic metal oxide catalyst to produce a pyrolysis product. The pyrolysis product of the present invention can advantageously be particularly high in alcohol content.

Claims

AMENDED CLAIMS received by the International Bureau on 26 July 2012 (26.07.2012)
1. A method of producing a pyrolysis product, comprising pyrolyzing a hydrocarbon feedstock in the presence of a basic metal oxide catalyst to produce a pyrolysis product, wherein the basic metal oxide catalyst has an uptake of carbon dioxide at 100°C of at least 0.03 mg/m2 of the basic metal oxide catalyst.
2. The method of claim 1 , wherein the metal oxide catalyst is comprised of at least one metal from Group 2, Group 3 including Lanthanides and Actinides, and Group 4 of the Periodic Table of Elements.
3. The method of any one of the previous claims, wherein the pyrolysis product contains at least one alcohol.
4. The method of any one of the previous claims, wherein the feedstock comprises biomass material.
5. The method of any one of the previous claims, wherein the basic metal oxide catalyst comprises at least one Group 2 metal.
6. The method of any one of the previous claims, wherein the Group 2 metal comprises magnesium.
7. The method of any one of the previous claims, wherein the basic metal oxide catalyst comprises hydrotalcite.
8. The method of any one of the previous claims, wherein the basic metal oxide catalyst comprises at least one Group 3 metal, including Lanthanides and Actinides.
9. The method of any one of the previous claims, wherein the Group 3 metal comprises at least one of yttrium, cerium, and praseodymium.
10. The method of any one of the previous claims, wherein the basic metal oxide catalyst comprises at least one Group 4 metal.
1 1. The method of any one of the previous claims, wherein the Group 4 metal comprises zirconium.
PCT/US2011/030470 2010-03-31 2011-03-30 Methods for producing pyrolysis products WO2011123508A2 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
CA2795044A CA2795044A1 (en) 2010-03-31 2011-03-30 Methods for producing pyrolysis products
EP11713934A EP2553051A2 (en) 2010-03-31 2011-03-30 Methods for producing pyrolysis products
AU2011235233A AU2011235233A1 (en) 2010-03-31 2011-03-30 Methods for producing pyrolysis products
CN2011800174883A CN102822318A (en) 2010-03-31 2011-03-30 Methods for producing pyrolysis products
SG2012070371A SG184206A1 (en) 2010-03-31 2011-03-30 Methods for producing pyrolysis products
JP2013502791A JP2013523960A (en) 2010-03-31 2011-03-30 Method for producing pyrolysis product

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US34145210P 2010-03-31 2010-03-31
US61/341,452 2010-03-31

Publications (3)

Publication Number Publication Date
WO2011123508A2 WO2011123508A2 (en) 2011-10-06
WO2011123508A3 WO2011123508A3 (en) 2012-07-19
WO2011123508A4 true WO2011123508A4 (en) 2012-09-13

Family

ID=42261383

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2011/030470 WO2011123508A2 (en) 2010-03-31 2011-03-30 Methods for producing pyrolysis products

Country Status (7)

Country Link
EP (1) EP2553051A2 (en)
JP (1) JP2013523960A (en)
CN (1) CN102822318A (en)
AU (1) AU2011235233A1 (en)
CA (1) CA2795044A1 (en)
SG (1) SG184206A1 (en)
WO (1) WO2011123508A2 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112015002752A2 (en) * 2012-08-08 2017-07-04 Albemarle Europe Sprl selective catalytic deoxygenation method of biomass, catalyst composition for it, its preparation method and method for converting solid state biomass material into one or more fluid hydrocarbon products
CN104549098B (en) * 2013-10-22 2016-05-18 中国石油化工股份有限公司 A kind of preparation method of bio oil
KR20200020518A (en) * 2018-08-17 2020-02-26 서울시립대학교 산학협력단 Recycle device for wood or lignin and method for producing phenol from wood or lignin using the same
CN114774146B (en) * 2022-04-20 2024-03-29 北京科技大学 Preparation method of high-density biomass hydrogen-rich micro powder for blast furnace injection

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3539306A (en) 1966-07-25 1970-11-10 Kyowa Chem Ind Co Ltd Process for the preparation of hydrotalcite
US4904457A (en) 1974-03-30 1990-02-27 Aluminum Company Of America Synthetic hydrotalcite
US4656156A (en) 1986-01-21 1987-04-07 Aluminum Company Of America Adsorbent and substrate products and method of producing same
US4774212A (en) 1987-12-22 1988-09-27 Amoco Corporation Pillared hydrotalcites
US4883533A (en) 1988-07-05 1989-11-28 J. M. Huber Corporation Modified synthetic hydrotalcite
US5364828A (en) 1992-10-21 1994-11-15 Minerals Technologies Spheroidal aggregate of platy synthetic hydrotalcite
US7513989B1 (en) 1997-07-15 2009-04-07 Exxonmobil Research And Engineering Company Hydrocracking process using bulk group VIII/Group VIB catalysts
US7288182B1 (en) 1997-07-15 2007-10-30 Exxonmobil Research And Engineering Company Hydroprocessing using bulk Group VIII/Group VIB catalysts
US7435335B1 (en) 1998-12-08 2008-10-14 Exxonmobil Research And Engineering Company Production of low sulfur distillates
WO2001079391A1 (en) 2000-04-18 2001-10-25 Exxonmobil Research And Engineering Company Selective hydroprocessing and mercaptan removal
US6995111B2 (en) 2002-02-28 2006-02-07 Exxonmobil Chemical Patents Inc. Molecular sieve compositions, catalysts thereof, their making and use in conversion processes
US7208442B2 (en) 2002-02-28 2007-04-24 Exxonmobil Chemical Patents Inc. Molecular sieve compositions, catalyst thereof, their making and use in conversion processes
US6844291B2 (en) 2002-02-28 2005-01-18 Exxonmobil Chemical Patents Inc. Molecular sieve compositions, catalyst thereof, their making and use in conversion processes
US7220352B2 (en) 2002-04-02 2007-05-22 Exxonmobil Research And Engineering Company Selective hydrodesulfurization of naphtha streams
US7288181B2 (en) 2003-08-01 2007-10-30 Exxonmobil Research And Engineering Company Producing low sulfur naphtha products through improved olefin isomerization
US6951830B2 (en) 2003-08-05 2005-10-04 Exxonmobil Chemical Patents Inc. Molecular sieve catalyst compositions, their production and use in conversion processes
US7199278B2 (en) 2004-07-30 2007-04-03 Exxonmobil Chemical Patents Inc. Conversion of oxygenates to olefins
EP1852490A1 (en) * 2006-05-05 2007-11-07 BIOeCON International Holding N.V. Pretreatment of particulate carbon-based energy carrier material
WO2009018531A1 (en) 2007-08-01 2009-02-05 Virginia Tech Intellectual Properties, Inc. Fractional catalytic pyrolysis of biomass
US20090151253A1 (en) 2007-12-17 2009-06-18 Range Fuels, Inc. Methods and apparatus for producing syngas and alcohols
EP2105486A1 (en) * 2008-03-25 2009-09-30 KiOR Inc. Low total acid number bio-crude
US7976797B2 (en) * 2008-04-08 2011-07-12 Exxonmobil Chemical Patents Inc. Advanced materials for regenerative pyrolysis reactors, methods, and reactors using the same

Also Published As

Publication number Publication date
WO2011123508A2 (en) 2011-10-06
SG184206A1 (en) 2012-10-30
JP2013523960A (en) 2013-06-17
AU2011235233A1 (en) 2012-10-18
CA2795044A1 (en) 2011-10-06
CN102822318A (en) 2012-12-12
EP2553051A2 (en) 2013-02-06
WO2011123508A3 (en) 2012-07-19

Similar Documents

Publication Publication Date Title
Du et al. Tunable copper-catalyzed chemoselective hydrogenolysis of biomass-derived γ-valerolactone into 1, 4-pentanediol or 2-methyltetrahydrofuran
WO2009118363A3 (en) Low total acid number bio-crude
EP3016909B1 (en) Method for processing magnesium chloride solutions
WO2011123508A4 (en) Methods for producing pyrolysis products
ECSP11011404A (en) METHOD FOR SOLID CARBON PRODUCTION THROUGH CARBON OXIDE REDUCTION
MY179719A (en) Process for beta-lactone production
MY190134A (en) Pyrolysis oil and method and system for the production thereof
WO2013115659A3 (en) Recombinant microorganisms and methods of use thereof
NZ596872A (en) Improved method for synthesizing pirfenidone
WO2013169806A3 (en) Biogenic activated carbon and methods of making and using same
WO2012061005A3 (en) Hydrocarbons from pyrolysis oil
MX2012013920A (en) Finishing reactor for purifying ethanol.
MY148576A (en) Process for preparing epsilon-caprolactone
WO2017004441A3 (en) Methods for coproduction of terephthalic acid and styrene from ethylene oxide
GB2513756A (en) Anaerobic process
WO2011031023A3 (en) Method for producing cyclicised compounds from organic acids having from 4 to 6 carbon atoms
WO2014143840A3 (en) Process for separating product gas using carbonylation processes
WO2012121838A3 (en) Single solvent gas expanded hydroformylation process
MX345086B (en) A nitrided mixed oxide catalyst system and a process for the production of ethylenically unsaturated carboxylic acids or esters.
MX2015007907A (en) Biofuels production from bio-derived carboxylic-acid esters.
WO2013052971A3 (en) Process for producing ethanol using hydrogenation catalysts prepared from polyoxometalate precursors
AU2015359691A8 (en) Fischer-Tropsch process using reductively-activated cobalt catalyst
WO2013019328A3 (en) Processes for converting lignocellulosics to reduced acid pyrolysis oil
WO2010082772A3 (en) Process for preparing high purity butanol
MY169859A (en) Process for making esters

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 201180017488.3

Country of ref document: CN

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 11713934

Country of ref document: EP

Kind code of ref document: A2

ENP Entry into the national phase

Ref document number: 2795044

Country of ref document: CA

WWE Wipo information: entry into national phase

Ref document number: 2013502791

Country of ref document: JP

NENP Non-entry into the national phase

Ref country code: DE

ENP Entry into the national phase

Ref document number: 2011235233

Country of ref document: AU

Date of ref document: 20110330

Kind code of ref document: A

WWE Wipo information: entry into national phase

Ref document number: 2011713934

Country of ref document: EP