WO2011118359A1 - Hermetic battery - Google Patents

Hermetic battery Download PDF

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Publication number
WO2011118359A1
WO2011118359A1 PCT/JP2011/054947 JP2011054947W WO2011118359A1 WO 2011118359 A1 WO2011118359 A1 WO 2011118359A1 JP 2011054947 W JP2011054947 W JP 2011054947W WO 2011118359 A1 WO2011118359 A1 WO 2011118359A1
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WO
WIPO (PCT)
Prior art keywords
cleavage
vent
plate
battery
thin
Prior art date
Application number
PCT/JP2011/054947
Other languages
French (fr)
Japanese (ja)
Inventor
渡辺 修
森本 充
Original Assignee
日立マクセルエナジー株式会社
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Filing date
Publication date
Application filed by 日立マクセルエナジー株式会社 filed Critical 日立マクセルエナジー株式会社
Publication of WO2011118359A1 publication Critical patent/WO2011118359A1/en

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/30Arrangements for facilitating escape of gases
    • H01M50/342Non-re-sealable arrangements
    • H01M50/3425Non-re-sealable arrangements in the form of rupturable membranes or weakened parts, e.g. pierced with the aid of a sharp member
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/572Means for preventing undesired use or discharge
    • H01M50/574Devices or arrangements for the interruption of current
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2200/00Safety devices for primary or secondary batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2200/00Safety devices for primary or secondary batteries
    • H01M2200/20Pressure-sensitive devices
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings, jackets or wrappings of a single cell or a single battery
    • H01M50/147Lids or covers
    • H01M50/166Lids or covers characterised by the methods of assembling casings with lids
    • H01M50/167Lids or covers characterised by the methods of assembling casings with lids by crimping
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings, jackets or wrappings of a single cell or a single battery
    • H01M50/147Lids or covers
    • H01M50/166Lids or covers characterised by the methods of assembling casings with lids
    • H01M50/171Lids or covers characterised by the methods of assembling casings with lids using adhesives or sealing agents
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Definitions

  • the present invention relates to a sealed battery having a current interruption function.
  • a sealed battery including a bottomed cylindrical outer can and two metal members that are arranged so as to cover the opening of the outer can and are partially joined to each other.
  • Such a sealed battery is generally configured so that when a gas is generated inside due to overcharge or the like, the current is cut off inside the battery by separating the two metal members by the pressure of the gas. ing.
  • a metal thin plate is welded to a safety valve made of a metal plate material and gas is generated inside the battery, the metal thin plate is The welded portion with the safety valve is configured to peel off.
  • the metal parts may break at other locations (for example, a part of the metal thin plate) instead of the welded portions thereof. Therefore, also in this case, there is a possibility that the pressure value in the battery that interrupts the current inside the battery may vary.
  • An object of the present invention is to obtain a configuration capable of reducing variations in pressure values inside a battery in which a current is interrupted in a sealed battery having a current interrupting function.
  • a sealed battery according to an embodiment of the present invention is disposed so as to cover a bottomed cylindrical outer can in which an electrode body is housed and an opening side of the outer can, and responds to a pressure increase in the outer can.
  • a cleavage plate that deforms and cleaves, and is disposed on the inside of the outer can of the cleavage plate so as to overlap with the cleavage plate in the thickness direction, and is electrically connected to the electrode body and one of the cleavage plates.
  • a shielding plate that is also joined to the portion, and the shielding plate is provided with a thin-walled portion having a connecting portion to be joined to the cleavage plate, and the thin-walled portion includes the cleavage portion of the connecting portion.
  • a groove portion that lowers the shear strength of the thin-walled portion is formed so as to surround the connecting portion as compared with the joint portion with the plate (first configuration).
  • the thin portion is formed with a plurality of through-hole portions penetrating the thin-wall portion in the thickness direction, and the groove portion connects the plurality of through-hole portions to each other. It is preferable to be provided in the part (second configuration).
  • the blocking plate is easily broken at the groove. That is, since the shear strength around the groove is further reduced by the through hole formed in the thin portion, the blocking plate is more reliably broken at the groove.
  • the cleavage plate is formed with a bulging portion that bulges toward the thin portion of the blocking plate and contacts the connecting portion of the thin portion. It is preferable to be provided inside the bulging portion as viewed from the stacking direction of the cleavage plate and the blocking plate (third configuration).
  • the cleavage plate can be reliably brought into contact with the connecting portion of the blocking plate, and the cleavage plate and the blocking plate can be more reliably joined at the connecting portion. Then, by providing the groove portion on the inner side of the bulging portion when viewed from the stacking direction of the cleavage plate and the blocking plate, the thin portion is pressed by the bulging portion when the cleavage plate and the blocking plate are brought into contact with each other. Even if it is deformed, it can be prevented from breaking at the groove. Further, by providing the groove portion on the inner side of the bulging portion as described above, the groove portion can be broken with a smaller force than when the groove portion is provided on the outer side of the bulging portion.
  • the length of the blocking plate attached to the cleavage plate side can be shortened. Thereby, according to the pressure rise inside the sealed battery, the breaker plate is more reliably broken at the groove, and after the breakage, a part of the breaker plate attached to the cleavage plate side and the remaining breaker plate Can be prevented from continuing to flow in the battery due to contact.
  • connection portion is formed thinner than the other portions of the thin portion (fourth configuration).
  • the connecting portion is formed thinner than the other portions so as to have an appropriate thickness that provides high bonding strength, the blocking plate can be more reliably bonded to the cleavage plate at the connecting portion.
  • the thin portion and the groove portion of the blocking plate are formed by coining (fifth configuration).
  • the shielding board which has a thin part and a groove part can be formed at low cost.
  • the shielding plate formed by coining work hardening occurs, and therefore, when stress concentrates on the work hardened portion, it tends to break.
  • the shielding plate is broken at the groove portion, so that variation in pressure inside the battery where the cleavage plate and the shielding plate are separated can be suppressed.
  • the groove portion having a lower shear strength than the joining portion between the cleavage plate and the shielding plate is formed in the thin portion of the shielding plate joined to a part of the cleavage plate. Since it is provided so as to surround the connecting portion, it is possible to reduce variations in the pressure value inside the battery where the cleavage plate and the blocking plate are separated.
  • FIG. 1 is a perspective view showing a schematic configuration of a sealed battery sealing body according to an embodiment of the present invention.
  • 2 is a cross-sectional view taken along line II-II in FIG.
  • FIG. 3 is a bottom view of the blocking vent.
  • 4 is a cross-sectional view taken along line IV-IV in FIG.
  • FIG. 5 is an enlarged view showing a thin portion of the blocking vent.
  • FIG. 6 is an enlarged cross-sectional view showing an enlarged welded portion between the blocking vent and the cleavage vent.
  • FIG. 1 is a diagram showing a schematic configuration of a sealed battery 1 according to an embodiment of the present invention.
  • a sealing body 20 is attached to the opening side of a bottomed cylindrical battery can 10 (exterior can).
  • the sealed battery 1 is disposed between the battery can 10, the sealing body 20, the opening end portion 11 a of the battery can 10, and the outer peripheral side of the sealing body 20.
  • a gasket 30 and an electrode body 40 housed in a space formed by the battery can 10 and the sealing body 20 are provided.
  • a nonaqueous electrolytic solution (not shown) is also enclosed.
  • the battery can 10 is made of a metal material such as a steel plate or stainless steel whose surface is nickel-plated, and is formed into a bottomed cylindrical shape by press molding. That is, the battery can 10 is formed by integrally forming a circular bottom portion (not shown) and a cylindrical peripheral wall portion 11. A negative electrode tab (not shown) extending from the electrode body 40 is connected to the bottom of the battery can 10. That is, in the present embodiment, the battery can 10 functions as a negative electrode terminal of the sealed battery 1. Note that the battery can 10 may be used as the positive electrode terminal.
  • the open end portion 11 a of the peripheral wall portion 11 of the battery can 10 is caulked to the sealing body 20 via the gasket 30. That is, in the state where the sealing body 20 and the gasket 30 are disposed inside the battery can 10, the open end 11 a of the battery can 10 is bent toward the inside of the battery can. Thereby, the sealing body 20 is fixed to the opening side of the battery can 10.
  • the sealing body 20 includes a terminal plate 21 as a positive electrode terminal, a cleavage vent 22 (a cleavage plate) that is deformed and cleaved in response to a rise in pressure inside the battery, and a cutoff vent 25 (functioning as a current cutoff mechanism together with the cleavage vent 22).
  • a shielding plate In the sealing body 20 in this embodiment, a resistance plate 23 whose resistance changes according to temperature is disposed between the terminal plate 21 and the cleavage vent 22.
  • the terminal plate 21 functions as a positive electrode terminal. However, when the battery can 10 functions as a positive electrode terminal, the terminal plate 21 functions as a negative electrode terminal.
  • the terminal plate 21 is made of a material in which the surface of a rolled steel plate is nickel-plated, and is formed in a substantially hat shape having an annular flange 21a on the outer peripheral side. That is, a convex portion 21 b that bulges into a bottomed cylindrical shape toward the outside of the battery can 10 is formed at the center portion of the terminal plate 21.
  • a plurality of gas discharge holes 21c are provided on the outer peripheral side of the convex portion 21b. In the present embodiment, as shown in FIG. 1, the gas discharge holes 21c are provided at a total of four locations at intervals of approximately 90 degrees in the circumferential direction on the outer peripheral side of the convex portion 21b.
  • the cleavage vent 22 is a member made of aluminum and is formed in a substantially hat shape like the terminal plate 21. That is, the cleavage vent 22 includes a cleavage portion 22a that swells into a bottomed cylindrical shape, and a flange portion 22b that is positioned on the outer peripheral side of the cleavage portion 22a.
  • the cleavage vent 22 is disposed in the battery can 10 in a reverse hat shape with respect to the terminal plate 21 so that the cleavage portion 22a bulges toward the inner side of the battery can 10.
  • a bulging portion 22c that bulges in the bulging direction of the cleavage portion 22a is formed at the center portion.
  • a groove portion 22d having a substantially V-shaped cross section is provided in an annular shape on the inner bottom surface of the cleavage portion 22a so as to surround the central bulge portion 22c.
  • four groove portions 22e having a substantially V-shaped cross section are provided on the bottom surface inside the cleavage portion 22a so as to extend in a cross shape from the annular groove portion 22d in plan view (not shown).
  • the cleavage vent 22 is broken at the groove portions 22d and 22e.
  • a predetermined pressure for example, the internal pressure is 2.5 MPa
  • the resistance plate 23 is formed by, for example, sandwiching a conductive polymer sheet between two metal electrode foils, and is configured such that the resistance increases as the temperature inside the battery rises.
  • the resistance plate 23 is formed in an annular shape so as to be sandwiched between the flange portion 21 a of the terminal plate 21 and the flange portion 22 b of the cleavage vent 22. Thereby, when the temperature in the sealed battery 1 becomes equal to or higher than a predetermined value, the resistance plate 23 suppresses a current from flowing between the cleavage vent 22 and the terminal plate 21. On the other hand, when the temperature decreases, the resistance plate 23 decreases in resistance value and returns to the original conductive state.
  • the opening portions of the peripheral wall portion 11 of the battery can 10 are sandwiched between the flange portions 21 a and 22 b and the resistance plate 23.
  • the part 11a is caulked. Accordingly, the resistance plate 23 can be fixed to the opening side of the battery can 10 while being held between the terminal plate 21 and the cleavage vent 22.
  • the blocking vent 25 is a member made of aluminum and is formed in a bottomed cylindrical shape so as to cover the cleavage portion 22a of the cleavage vent 22. That is, the blocking vent 25 includes a circular bottom surface portion 25a and a peripheral wall portion 25b formed on the outer peripheral side of the bottom surface portion 25a. The opening end side of the peripheral wall portion 25b is held by the cylindrical cleaving portion 22a of the cleaving vent 22 by an annular holding member 24 made of an insulating material.
  • the holding member 24 is a member made of polybutylene terephthalate (PBT) or polypropylene (PP). Therefore, the holding member 24 can insulate the cleavage vent 22 and the blocking vent 25 except for the welded portion 50 described later.
  • PBT polybutylene terephthalate
  • PP polypropylene
  • a plurality (six in this embodiment) of through holes 25 c are formed at equal intervals in the circumferential direction on the bottom surface portion 25 a of the blocking vent 25.
  • These through holes 25c are gas vent holes through which gas generated by overcharging or the like in the battery can 10 passes. By providing these through holes 25 c, gas passes through the blocking vent 25 and pressure is applied to the cleavage portion 22 a of the cleavage vent 22.
  • a part of the bottom surface portion 25 a of the blocking vent 25 is welded (joined) to the cleavage portion 22 a of the cleavage vent 22.
  • a positive electrode tab 45 extending from the electrode body 40 is connected to the blocking vent 25 (see FIG. 2). That is, the electrode body 40, the blocking vent 25, and the cleavage vent 22 are electrically connected.
  • the interruption vent 25 functions as a current interruption mechanism together with the cleavage vent 22.
  • the gasket 30 is a substantially cylindrical member made of polybutylene terephthalate (PBT) or polypropylene (PP).
  • the gasket 30 is provided with a step portion 31 at the center portion in the cylinder axis direction so that the diameter of the end portion on one side is larger than the diameter of the end portion on the other side. That is, the gasket 30 has a large-diameter portion 33, a small-diameter portion 32, and a step portion 31 positioned therebetween.
  • the large diameter portion 33 has an inner diameter larger than the outer diameter of the sealing body 20 so that the sealing body 20 can be accommodated.
  • the sealing body 20 is accommodated in the large diameter portion 33 of the gasket 30 so as to support the sealing body 20 by the step portion 31, and the opening end 10 a of the peripheral wall portion 10 of the battery can 10 is sealed together with the opening side of the large diameter portion 33.
  • the gasket 30 is sandwiched between the battery can 10 and the sealing body 20 as shown in FIG.
  • the electrode body 40 is wound in a spiral shape in a state where a sheet-like positive electrode and a negative electrode are laminated in the thickness direction via a separator, although not particularly illustrated.
  • the positive electrode has a positive electrode active material
  • the negative electrode has a negative electrode active material, and is configured to be chargeable / dischargeable.
  • Detailed configurations of the positive electrode, the negative electrode, and the separator are the same as those in the related art, and thus detailed description thereof is omitted.
  • the positive electrode of the electrode body 40 is electrically connected to the blocking vent 25 via the positive electrode tab 45 on the opening end side of the battery can 10.
  • the negative electrode of the electrode body 40 is electrically connected to the battery can 10 by a negative electrode tab (not shown) on the bottom side of the battery can 10.
  • Examples of the positive electrode active material used for the positive electrode include lithium cobalt oxide such as LiCoO 2 , lithium manganese oxide such as LiMn 2 O 4 , lithium nickel oxide such as LiNiO 2 , manganese dioxide, vanadium pentoxide, and chromium oxide.
  • Metal oxides such as materials, and metal sulfides such as titanium disulfide and molybdenum disulfide are used.
  • the negative electrode active material used for the negative electrode may be any material that can dope and dedope lithium ions.
  • a negative electrode active material graphite, pyrolytic carbons, cokes, glassy carbons, organic polymer compound fired bodies, mesocarbon microbeads, carbon fibers, activated carbon and other carbon materials, Si, Sn, In, etc. It is preferable to use an alloy of Si, Sn, In or the like that can be charged and discharged at a low voltage close to Li.
  • FIGS. 3 is a bottom view of the blocking vent 25
  • FIG. 4 is a sectional view taken along line IV-IV in FIG. 3
  • FIG. 5 is an enlarged view of a central portion of the bottom portion 25a of the blocking vent 25, and
  • FIG. It is an expanded sectional view of the welding part 50 with the cleavage vent 22.
  • FIG. 3 is a bottom view of the blocking vent 25
  • FIG. 4 is a sectional view taken along line IV-IV in FIG. 3
  • FIG. 5 is an enlarged view of a central portion of the bottom portion 25a of the blocking vent 25
  • FIG. It is an expanded sectional view of the welding part 50 with the cleavage vent 22.
  • FIG. 3 is a bottom view of the blocking vent 25
  • FIG. 4 is a sectional view taken along line IV-IV in FIG. 3
  • FIG. 5 is an enlarged view of a central portion of the bottom portion 25a of the blocking vent 25
  • FIG. It is an expanded sectional view of the welding part 50 with the
  • a thin portion 26 is provided at the center of the bottom surface (outer surface) of the bottom surface portion 25a.
  • the thin portion 26 is formed by thinning the central portion of the bottom surface of the bottom surface portion 25a in a step shape.
  • the thin portion 26 is formed in a circular shape in plan view.
  • a connection portion 27 formed to be thinner is provided at the central portion of the thin portion 26.
  • the connecting portion 27 is formed in a circular shape in plan view, and is joined to the bulging portion 22c of the cleavage portion 22a of the cleavage vent 22 by YAG laser welding or the like, as shown in FIG. Thereby, the welding part 50 (joining part) is formed in the connection part 27 and the bulging part 22c.
  • each through-hole portion 26 a is an elongated hole formed in an arc shape with the connection portion 27 as the center, and is provided at the same position in the radial direction of the blocking vent 25 with respect to the connection portion 27.
  • a plurality of groove portions 26b are formed in the thin portion 26 so as to surround the connection portion 27 and connect the plurality of through-hole portions 26a.
  • each groove 26b is formed in a substantially V-shaped cross section so that the width of the groove bottom is smaller than the groove width on the opening side.
  • each groove part 26b is formed so that it may mutually connect in the radial direction inner side part of the interruption
  • the shear strength of the groove bottom portion of the groove portion 26b is set to the welded portion 50 between the bulging portion 22c of the cleavage vent 22 and the connection portion 27. It can be made smaller than the shear strength. Therefore, when gas is generated in the sealed battery 1 due to overcharge or the like and the cleavage vent 22 is deformed to the terminal plate 21 side, the connection portion 27 welded to the cleavage vent 22 is connected to the terminal plate 21 side together with the cleavage vent 22. When it is pulled, the blocking vent 25 is broken at the groove 26b.
  • the pressure inside the sealed battery 1 is not affected by the joining conditions such as welding.
  • a certain value for example, 1.4 MPa
  • the blocking vent 25 having the above-described configuration is formed by coining. Therefore, the blocking vent 25 can be formed at a lower cost than the configuration using the metal foil.
  • the blocking vent 25 is formed by coining, work hardening occurs at the outer peripheral edge portion of the thin portion 26, and breakage tends to occur due to stress concentration. If it does so, dispersion
  • the groove part 26b as described above, the blocking vent 25 can be broken at the groove part 26b. Therefore, even when the blocking vent 25 is formed by coining, the cleavage vent 22 and the blocking vent 25 can be separated by the groove portion 26b when the internal pressure of the battery reaches a certain value.
  • each groove portion 26 b is in plan view (in the state where the bulging portion 22 c of the cleavage vent 22 is pressed against the thin portion 26 of the interruption vent 25). , As viewed from the stacking direction), and is formed inside the bulging portion 22c.
  • the groove 26b is close to the connecting portion 27. Therefore, when the groove 26b breaks, the portion of the blocking vent 25 that adheres to the cleavage vent 22 side is removed. Can be small. As a result, it is possible to prevent a part of the blocking vent 25 attached to the cleavage vent 22 side from contacting the remaining part of the blocking vent 25 and causing a current to continue flowing in the sealed battery 1.
  • the blocking vent 25 can be broken at the groove portion 26b with a smaller force than when the groove portion is provided outside the bulging portion 22c in plan view. . That is, when the groove portion 26b is far from the connection portion 27, the distance of the groove portion 26b is increased correspondingly, and the shear strength of the groove bottom portion is also increased. However, by providing the groove portion 26b closer to the connection portion 27, it is small. Even with pressure, the blocking vent 25 can be more reliably broken by the groove 26b.
  • the cleavage vent 22 breaks at the groove portions 22d and 22e. Thereby, the cleavage vent 22 is cleaved, and the gas and the electrolyte in the battery can 10 are ejected from the hole formed in the cleavage vent 22 to the outside.
  • the groove portion 26 b is provided on the inner side of the bulging portion 22 c of the cleavage vent 22, so that the bulging portion 22 c is a thin-walled portion 26 of the blocking vent 25. It is possible to prevent the groove 26b from being broken when pressed against. In addition, with this configuration, when the groove 26b breaks, the length of a part of the blocking vent 25 attached to the cleavage vent 22 side can be relatively shortened. It is possible to prevent a short circuit due to contact between the portion and the remaining portion of the blocking vent 25. Furthermore, since the groove part 26b is formed at a position relatively close to the coupling part 27, the blocking vent 25 can be broken at the groove part 26b with a relatively small force.
  • the groove 26b is provided so as to connect a plurality of through holes 26a provided in the thin portion 26 of the blocking vent 25. Therefore, the shear strength of the groove bottom portion of the groove portion 26 b can be reduced as compared with the welded portion 50 between the blocking vent 25 and the cleavage vent 22. Therefore, the blocking vent 25 can be more reliably broken at the groove 26b.
  • three through holes 26 a are formed in the thin portion 26 of the blocking vent 25.
  • the number of the through holes 26a may be two or less or four or more as long as the blocking vent 25 is broken at the groove 26b when the cleavage vent 22 is deformed. May not be provided.
  • the through-hole portion is not provided, for example, by making the cross-sectional shape of the groove portion 26b easier to break, or by providing the groove portion 26b closer to the connecting portion 27, the groove portion 26b can be more easily broken. There is a need.
  • the cross-sectional shape of the groove 26b provided in the thin portion 26 of the blocking vent 25 is substantially V-shaped.
  • other cross-sectional shapes may be used as long as the cross-sectional shape is broken at the groove 26b.
  • the groove portion 26b is provided on the bottom surface outside the blocking vent 25 (the inner surface of the battery can 10).
  • the groove 26b may be provided on the bottom surface inside the blocking vent 25 (the surface on the side of the cleavage vent 22).
  • the connecting portion 27 of the blocking vent 25 and the bulging portion 22c of the cleavage vent 22 are joined by welding.
  • any method other than welding may be used as long as the members can be joined together.
  • the resistance plate 23 is provided between the cleavage vent 22 and the terminal plate 21.
  • the cleavage vent 22 and the terminal plate 21 may be brought into direct contact without providing the resistance plate 23.
  • the sealed battery according to the present invention can be used for a sealed battery having a current interruption function.

Abstract

In a hermetic battery with a current cutoff function, a structure is obtained that can reduce the variation in pressure values inside the battery in which current is cut off. The hermetic battery (1) comprises: a battery can (10) having a cylindrical shape with a bottom and housing an electrode body (40); a cleavage vent (22) disposed so as to cover the opening side of the battery can (10) and deformed and cleaved by the increase of pressure inside the battery can (10); and a cutoff vent (25) disposed on the battery-can inner side of the cleavage vent (22), electrically connected to the electrode body (40), and also joined with a part of the cleavage vent (22). The cutoff vent (25) is provided with a thin-walled portion (26) having a connection portion (27) joined with the cleavage vent (22). The thin-walled portion (26) has a trench portion (26b) formed so as to surround the connection portion (27), the trench portion (26b) reducing the shear strength of the thin-walled portion (26) compared with that of a welding portion (50).

Description

密閉型電池Sealed battery
 本発明は、電流遮断機能を備えた密閉型電池に関する。 The present invention relates to a sealed battery having a current interruption function.
 従来より、有底筒状の外装缶と、該外装缶の開口を覆うように配置され且つ互いに部分的に接合された2つの金属部材と、を備えた密閉型電池が知られている。このような密閉型電池では、一般的に、過充電等によって内部にガスが発生した場合、そのガスの圧力によって2つの金属部材が分離することにより、電池内部で電流を遮断するように構成されている。具体的には、例えば特開平5-343043号公報に開示される密閉型電池では、金属板材からなる安全弁に金属薄板を溶接し、電池内部でガスが発生すると、電池内部の圧力によって金属薄板と安全弁との溶接部分が剥離するように構成されている。 Conventionally, a sealed battery including a bottomed cylindrical outer can and two metal members that are arranged so as to cover the opening of the outer can and are partially joined to each other is known. Such a sealed battery is generally configured so that when a gas is generated inside due to overcharge or the like, the current is cut off inside the battery by separating the two metal members by the pressure of the gas. ing. Specifically, for example, in a sealed battery disclosed in JP-A-5-343043, when a metal thin plate is welded to a safety valve made of a metal plate material and gas is generated inside the battery, the metal thin plate is The welded portion with the safety valve is configured to peel off.
 ところで、上述の特開平5-343043号公報に開示されている構成の場合、2つの金属部材(安全弁、金属薄板)の溶接の条件等によって、溶接部分が剥離する力が変わる。そのため、電池内部で電流を遮断する電池内の圧力値にばらつきが生じる可能性がある。 By the way, in the case of the configuration disclosed in the above-mentioned JP-A-5-343043, the force at which the welded part is peeled changes depending on the welding conditions of the two metal members (safety valve, metal thin plate). Therefore, there is a possibility that the pressure value in the battery that interrupts the current inside the battery may vary.
 また、2つの金属部材の強度によっては、それらの溶接部分ではなく、それ以外の箇所(例えば金属薄板の一部)で破断する可能性がある。したがって、この場合にも、電池内部で電流を遮断する電池内の圧力値にばらつきが生じる可能性がある。 Also, depending on the strength of the two metal members, there is a possibility that the metal parts may break at other locations (for example, a part of the metal thin plate) instead of the welded portions thereof. Therefore, also in this case, there is a possibility that the pressure value in the battery that interrupts the current inside the battery may vary.
 本発明の目的は、電流遮断機能を備えた密閉型電池において、電流が遮断される電池内部の圧力値のばらつきを低減可能な構成を得ることにある。 An object of the present invention is to obtain a configuration capable of reducing variations in pressure values inside a battery in which a current is interrupted in a sealed battery having a current interrupting function.
 本発明の一実施形態にかかる密閉型電池は、電極体が収納される有底筒状の外装缶と、該外装缶の開口側を覆うように配置され、該外装缶内の圧力上昇に応じて変形し開裂する開裂板と、該開裂板の外装缶内方側に該開裂板と厚み方向に重ね合わされるように配置され、前記電極体に電気的に接続されるとともに該開裂板の一部にも接合される遮断板と、を備え、該遮断板には、前記開裂板と接合される接続部を有する薄肉部が設けられていて、前記薄肉部には、前記接続部の該開裂板との接合部分よりも前記薄肉部のせん断強度を低下させる溝部が、前記接続部を囲むように形成されている(第1の構成)。 A sealed battery according to an embodiment of the present invention is disposed so as to cover a bottomed cylindrical outer can in which an electrode body is housed and an opening side of the outer can, and responds to a pressure increase in the outer can. A cleavage plate that deforms and cleaves, and is disposed on the inside of the outer can of the cleavage plate so as to overlap with the cleavage plate in the thickness direction, and is electrically connected to the electrode body and one of the cleavage plates. A shielding plate that is also joined to the portion, and the shielding plate is provided with a thin-walled portion having a connecting portion to be joined to the cleavage plate, and the thin-walled portion includes the cleavage portion of the connecting portion. A groove portion that lowers the shear strength of the thin-walled portion is formed so as to surround the connecting portion as compared with the joint portion with the plate (first configuration).
 この構成により、過充電等によって密閉型電池の内部でガスが発生した場合でも、開裂板と遮断板との接合部分で分離するのではなく、該遮断板の薄肉部に形成された溝部で破断する。すなわち、遮断板の溝部周辺のせん断強度が開裂板と遮断板との接合部分よりも低いため、該接続部の接合条件に関係なく、前記溝部で破断する。よって、密閉型電池の内圧が一定の値に達した際に、開裂板と遮断板とを分離して、密閉型電池内で電流を遮断することができる。 With this configuration, even when gas is generated inside the sealed battery due to overcharge or the like, it is not separated at the joint between the cleavage plate and the shielding plate, but is broken at the groove formed in the thin portion of the shielding plate. To do. That is, since the shear strength around the groove portion of the shield plate is lower than the joint portion between the cleavage plate and the shield plate, the groove portion is ruptured regardless of the joining condition of the connection portion. Therefore, when the internal pressure of the sealed battery reaches a certain value, the current can be cut off in the sealed battery by separating the cleavage plate and the blocking plate.
 前記第1の構成において、前記薄肉部には、該薄肉部を厚み方向に貫通する複数の貫通穴部が形成されていて、前記溝部は、前記複数の貫通穴部同士を繋ぐように前記薄肉部に設けられているのが好ましい(第2の構成)。 In the first configuration, the thin portion is formed with a plurality of through-hole portions penetrating the thin-wall portion in the thickness direction, and the groove portion connects the plurality of through-hole portions to each other. It is preferable to be provided in the part (second configuration).
 これにより、密閉型電池内の圧力が高くなって開裂板が変形した場合に、遮断板は溝部で破断しやすくなる。すなわち、薄肉部に形成された貫通穴部によって、溝部周辺のせん断強度がさらに低下するため、遮断板は該溝部でより確実に破断する。 Therefore, when the pressure in the sealed battery is increased and the cleavage plate is deformed, the blocking plate is easily broken at the groove. That is, since the shear strength around the groove is further reduced by the through hole formed in the thin portion, the blocking plate is more reliably broken at the groove.
 前記第1または第2の構成において、前記開裂板には、前記遮断板の薄肉部側に膨出して該薄肉部の接続部に当接する膨出部が形成されていて、前記溝部は、前記開裂板及び遮断板の積層方向から見て前記膨出部よりも内側に設けられているのが好ましい(第3の構成)。 In the first or second configuration, the cleavage plate is formed with a bulging portion that bulges toward the thin portion of the blocking plate and contacts the connecting portion of the thin portion. It is preferable to be provided inside the bulging portion as viewed from the stacking direction of the cleavage plate and the blocking plate (third configuration).
 こうすることで、開裂板を遮断板の接続部により確実に当接させて、該接続部で開裂板と遮断板とをより確実に接合することができる。そして、前記溝部を、開裂板及び遮断板の積層方向から見て膨出部よりも内側に設けることにより、該開裂板と遮断板とを当接させる際に、膨出部によって薄肉部が押圧されて変形しても、前記溝部で破断するのを防止できる。また、上述のように膨出部よりも内側に溝部を設けることで、該溝部を膨出部の外側に設ける場合に比べて、より小さな力で溝部を破断することが可能になるとともに、該溝部で破断した後に、開裂板側に付着した状態の遮断板の長さを短くすることができる。これにより、密閉型電池の内部の圧力上昇に応じて、遮断板を溝部でより確実に破断するとともに、破断後に、開裂板側に付着した状態の遮断板の一部と、残りの遮断板とが接触して電池内で電流が流れ続けるのを防止できる。 By doing so, the cleavage plate can be reliably brought into contact with the connecting portion of the blocking plate, and the cleavage plate and the blocking plate can be more reliably joined at the connecting portion. Then, by providing the groove portion on the inner side of the bulging portion when viewed from the stacking direction of the cleavage plate and the blocking plate, the thin portion is pressed by the bulging portion when the cleavage plate and the blocking plate are brought into contact with each other. Even if it is deformed, it can be prevented from breaking at the groove. Further, by providing the groove portion on the inner side of the bulging portion as described above, the groove portion can be broken with a smaller force than when the groove portion is provided on the outer side of the bulging portion. After breaking at the groove, the length of the blocking plate attached to the cleavage plate side can be shortened. Thereby, according to the pressure rise inside the sealed battery, the breaker plate is more reliably broken at the groove, and after the breakage, a part of the breaker plate attached to the cleavage plate side and the remaining breaker plate Can be prevented from continuing to flow in the battery due to contact.
 前記第1から第3のいずれか一つの構成において、前記接続部は、前記薄肉部の他の部分に比べてさらに薄肉に形成されているのが好ましい(第4の構成)。これにより、薄肉部の接続部以外を、比較的、大きな厚みにすることが可能になるため、溝部以外の薄肉部で破断するのを防止できる。接続部は、高い接合強度が得られる適度な厚みになるように、他の部分に比べて薄肉に形成されているため、該接続部で遮断板を開裂板に対してより確実に接合できる。 In any one of the first to third configurations, it is preferable that the connection portion is formed thinner than the other portions of the thin portion (fourth configuration). Thereby, since it becomes possible to make comparatively big thickness except a connection part of a thin part, it can prevent that it fractures | ruptures in thin parts other than a groove part. Since the connecting portion is formed thinner than the other portions so as to have an appropriate thickness that provides high bonding strength, the blocking plate can be more reliably bonded to the cleavage plate at the connecting portion.
 前記第1から第4のいずれか一つの構成において、前記遮断板の薄肉部及び溝部は、コイニングによって形成されるのが好ましい(第5の構成)。これにより、薄肉部及び溝部を有する遮断板を低コストで形成することができる。コイニングによって形成された遮断板の場合、加工硬化が生じるため、その加工硬化部分に応力が集中すると、破断しやすくなる。これに対し、前記第1から第4のような構成を適用することで、遮断板は溝部で破断するため、開裂板と遮断板とが分離する電池内部の圧力のばらつきを抑えることができる。 In any one of the first to fourth configurations, it is preferable that the thin portion and the groove portion of the blocking plate are formed by coining (fifth configuration). Thereby, the shielding board which has a thin part and a groove part can be formed at low cost. In the case of the shielding plate formed by coining, work hardening occurs, and therefore, when stress concentrates on the work hardened portion, it tends to break. On the other hand, by applying the first to fourth configurations, the shielding plate is broken at the groove portion, so that variation in pressure inside the battery where the cleavage plate and the shielding plate are separated can be suppressed.
 本発明の一実施形態にかかる密閉型電池によれば、開裂板の一部に接合される遮断板の薄肉部に、該開裂板と遮断板との接合部分よりもせん断強度の低い溝部を、接続部を囲むように設けたため、開裂板と遮断板とが分離する電池内部の圧力値のばらつきを低減できる。 According to the sealed battery according to the embodiment of the present invention, the groove portion having a lower shear strength than the joining portion between the cleavage plate and the shielding plate is formed in the thin portion of the shielding plate joined to a part of the cleavage plate. Since it is provided so as to surround the connecting portion, it is possible to reduce variations in the pressure value inside the battery where the cleavage plate and the blocking plate are separated.
図1は、本発明の一実施形態にかかる密閉型電池の封口体の概略構成を示す斜視図である。FIG. 1 is a perspective view showing a schematic configuration of a sealed battery sealing body according to an embodiment of the present invention. 図2は、図1におけるII-II線断面図である。2 is a cross-sectional view taken along line II-II in FIG. 図3は、遮断ベントの底面図である。FIG. 3 is a bottom view of the blocking vent. 図4は、図3におけるIV-IV線断面図である。4 is a cross-sectional view taken along line IV-IV in FIG. 図5は、遮断ベントの薄肉部を拡大して示す図である。FIG. 5 is an enlarged view showing a thin portion of the blocking vent. 図6は、遮断ベントと開裂ベントとの溶接部分を拡大して示す拡大断面図である。FIG. 6 is an enlarged cross-sectional view showing an enlarged welded portion between the blocking vent and the cleavage vent.
 以下、図面を参照し、本発明の実施の形態を詳しく説明する。図中の同一または相当部分については同一の符号を付してその説明は繰り返さない。 Hereinafter, embodiments of the present invention will be described in detail with reference to the drawings. The same or corresponding parts in the drawings are denoted by the same reference numerals and description thereof will not be repeated.
 (全体構成)
 図1は、本発明の一実施形態である密閉型電池1の概略構成を示す図である。この密閉型電池1では、有底筒状の電池缶10(外装缶)の開口側に封口体20が取り付けられている。詳しくは、図2に断面で示すように、密閉型電池1は、電池缶10と、封口体20と、電池缶10の開口端部11aと封口体20の外周側との間に配置されるガスケット30と、電池缶10及び封口体20によって形成される空間内に収納される電極体40とを備えている。電池缶10と封口体20との間に形成される空間内には、電極体40以外に、非水電解液(図示省略)も封入されている。
(overall structure)
FIG. 1 is a diagram showing a schematic configuration of a sealed battery 1 according to an embodiment of the present invention. In the sealed battery 1, a sealing body 20 is attached to the opening side of a bottomed cylindrical battery can 10 (exterior can). Specifically, as shown in a cross-section in FIG. 2, the sealed battery 1 is disposed between the battery can 10, the sealing body 20, the opening end portion 11 a of the battery can 10, and the outer peripheral side of the sealing body 20. A gasket 30 and an electrode body 40 housed in a space formed by the battery can 10 and the sealing body 20 are provided. In the space formed between the battery can 10 and the sealing body 20, in addition to the electrode body 40, a nonaqueous electrolytic solution (not shown) is also enclosed.
 電池缶10は、表面にニッケルメッキが施された鋼板やステンレス鋼などの金属材料からなり、プレス成形によって有底円筒状に形成されている。すなわち、電池缶10は、円形状の底部(図示省略)と、円筒状の周壁部11とが一体形成されてなる。この電池缶10の底部には、電極体40から延びる負極タブ(図示省略)が接続されている。すなわち、本実施形態において、この電池缶10は、密閉型電池1の負極端子として機能している。なお、この限りではなく、電池缶10を正極端子として用いてもよい。 The battery can 10 is made of a metal material such as a steel plate or stainless steel whose surface is nickel-plated, and is formed into a bottomed cylindrical shape by press molding. That is, the battery can 10 is formed by integrally forming a circular bottom portion (not shown) and a cylindrical peripheral wall portion 11. A negative electrode tab (not shown) extending from the electrode body 40 is connected to the bottom of the battery can 10. That is, in the present embodiment, the battery can 10 functions as a negative electrode terminal of the sealed battery 1. Note that the battery can 10 may be used as the positive electrode terminal.
 電池缶10の周壁部11の開口端部11aは、ガスケット30を介して封口体20にかしめられている。すなわち、封口体20及びガスケット30を電池缶10の内方に配置した状態で、該電池缶10の開口端部11aは、電池缶内方に向かって折り曲げられている。これにより、電池缶10の開口側に、封口体20が固定される。 The open end portion 11 a of the peripheral wall portion 11 of the battery can 10 is caulked to the sealing body 20 via the gasket 30. That is, in the state where the sealing body 20 and the gasket 30 are disposed inside the battery can 10, the open end 11 a of the battery can 10 is bent toward the inside of the battery can. Thereby, the sealing body 20 is fixed to the opening side of the battery can 10.
 封口体20は、正極端子としての端子板21と、電池内部の圧力上昇に応じて変形し開裂する開裂ベント22(開裂板)と、該開裂ベント22とともに電流遮断機構として機能する遮断ベント25(遮断板)と、を備えている。この実施形態における封口体20では、端子板21と開裂ベント22との間に、温度に応じて抵抗が変化する抵抗板23が配置されている。なお、本実施形態では、端子板21は正極端子として機能しているが、電池缶10が正極端子として機能している場合には、端子板21は、負極端子として機能する。 The sealing body 20 includes a terminal plate 21 as a positive electrode terminal, a cleavage vent 22 (a cleavage plate) that is deformed and cleaved in response to a rise in pressure inside the battery, and a cutoff vent 25 (functioning as a current cutoff mechanism together with the cleavage vent 22). A shielding plate). In the sealing body 20 in this embodiment, a resistance plate 23 whose resistance changes according to temperature is disposed between the terminal plate 21 and the cleavage vent 22. In the present embodiment, the terminal plate 21 functions as a positive electrode terminal. However, when the battery can 10 functions as a positive electrode terminal, the terminal plate 21 functions as a negative electrode terminal.
 端子板21は、圧延鋼板の表面にニッケルメッキが施された材料からなり、外周側に円環状の鍔部21aを有する略ハット状に形成されている。すなわち、端子板21の中央部分には、電池缶10の外方に向かって有底円筒状に膨出する凸部21bが形成されている。この凸部21bの外周側には、複数のガス排出孔21cが設けられている。本実施形態では、ガス排出孔21cは、図1に示すように、凸部21bの外周側に、周方向に略90度の間隔で合計4箇所に設けられている。 The terminal plate 21 is made of a material in which the surface of a rolled steel plate is nickel-plated, and is formed in a substantially hat shape having an annular flange 21a on the outer peripheral side. That is, a convex portion 21 b that bulges into a bottomed cylindrical shape toward the outside of the battery can 10 is formed at the center portion of the terminal plate 21. A plurality of gas discharge holes 21c are provided on the outer peripheral side of the convex portion 21b. In the present embodiment, as shown in FIG. 1, the gas discharge holes 21c are provided at a total of four locations at intervals of approximately 90 degrees in the circumferential direction on the outer peripheral side of the convex portion 21b.
 図2に示すように、開裂ベント22は、アルミニウム製の部材であり、端子板21と同様、略ハット状に形成されている。すなわち、開裂ベント22は、有底円筒状に膨出する開裂部22aと、該開裂部22aの外周側に位置する鍔部22bと、を有している。開裂ベント22は、開裂部22aが電池缶10の内方側に向かって膨出するように、端子板21とは逆ハット状に電池缶10内に配置されている。 As shown in FIG. 2, the cleavage vent 22 is a member made of aluminum and is formed in a substantially hat shape like the terminal plate 21. That is, the cleavage vent 22 includes a cleavage portion 22a that swells into a bottomed cylindrical shape, and a flange portion 22b that is positioned on the outer peripheral side of the cleavage portion 22a. The cleavage vent 22 is disposed in the battery can 10 in a reverse hat shape with respect to the terminal plate 21 so that the cleavage portion 22a bulges toward the inner side of the battery can 10.
 開裂部22aには、中央部分に、該開裂部22aの膨出方向に向かって膨出する膨出部22cが形成されている。また、開裂部22aの内側の底面には、中央の膨出部22cを囲むように、断面略V字状の溝部22dが円環状に設けられている。さらに、開裂部22aの内側の底面には、円環状の溝部22dから平面視で十字状に延びるように断面略V字状の溝部22eが4つ設けられている(図示省略)。 In the cleavage portion 22a, a bulging portion 22c that bulges in the bulging direction of the cleavage portion 22a is formed at the center portion. Further, a groove portion 22d having a substantially V-shaped cross section is provided in an annular shape on the inner bottom surface of the cleavage portion 22a so as to surround the central bulge portion 22c. Further, four groove portions 22e having a substantially V-shaped cross section are provided on the bottom surface inside the cleavage portion 22a so as to extend in a cross shape from the annular groove portion 22d in plan view (not shown).
 このように、開裂ベント22の開裂部22aの底面に溝部22d,22eを設けることにより、密閉型電池1の内部の圧力が所定の圧力(例えば、内圧が2.5MPa)まで上昇した際に、該開裂ベント22が溝部22d,22eで破断する。このように、密閉型電池1の内部の圧力に応じて開裂ベント22が溝部22d,22eで破断するように構成することで、電池缶10が電池内部の圧力上昇によって破裂するのを防止できる。 Thus, by providing the groove portions 22d and 22e on the bottom surface of the cleavage portion 22a of the cleavage vent 22, when the internal pressure of the sealed battery 1 rises to a predetermined pressure (for example, the internal pressure is 2.5 MPa), The cleavage vent 22 is broken at the groove portions 22d and 22e. As described above, by configuring the cleavage vent 22 to break at the groove portions 22d and 22e according to the pressure inside the sealed battery 1, it is possible to prevent the battery can 10 from being ruptured due to an increase in pressure inside the battery.
 抵抗板23は、例えば2枚の金属電極箔によって導電性ポリマーのシートを挟み込んでなるもので、電池内部の温度が上昇すると抵抗が大きくなるように構成されている。抵抗板23は、端子板21の鍔部21aと開裂ベント22の鍔部22bとの間に挟み込まれるように円環状に形成されている。これにより、密閉型電池1内の温度が所定値以上になると、抵抗板23は開裂ベント22と端子板21との間で電流が流れるのを抑制する。一方、温度が低下すると、抵抗板23は、抵抗値が下がって元の導通状態に復帰する。 The resistance plate 23 is formed by, for example, sandwiching a conductive polymer sheet between two metal electrode foils, and is configured such that the resistance increases as the temperature inside the battery rises. The resistance plate 23 is formed in an annular shape so as to be sandwiched between the flange portion 21 a of the terminal plate 21 and the flange portion 22 b of the cleavage vent 22. Thereby, when the temperature in the sealed battery 1 becomes equal to or higher than a predetermined value, the resistance plate 23 suppresses a current from flowing between the cleavage vent 22 and the terminal plate 21. On the other hand, when the temperature decreases, the resistance plate 23 decreases in resistance value and returns to the original conductive state.
 端子板21の鍔部21aと開裂ベント22の鍔部22bとの間に抵抗板23を挟み込んだ状態で、鍔部21a,22b及び抵抗板23には、電池缶10の周壁部11の開口端部11aがかしめられている。これにより、抵抗板23を端子板21と開裂ベント22との間に保持した状態で、電池缶10の開口側に固定することができる。 With the resistance plate 23 sandwiched between the flange portion 21 a of the terminal plate 21 and the flange portion 22 b of the cleavage vent 22, the opening portions of the peripheral wall portion 11 of the battery can 10 are sandwiched between the flange portions 21 a and 22 b and the resistance plate 23. The part 11a is caulked. Accordingly, the resistance plate 23 can be fixed to the opening side of the battery can 10 while being held between the terminal plate 21 and the cleavage vent 22.
 遮断ベント25は、アルミニウム製の部材であり、開裂ベント22の開裂部22aを覆うように有底円筒状に形成されている。すなわち、遮断ベント25は、円形状の底面部25aと、該底面部25aの外周側に形成された周壁部25bとを備えている。周壁部25bの開口端側は、絶縁材料からなる円環状の保持部材24によって、開裂ベント22の円筒状の開裂部22aに保持されている。 The blocking vent 25 is a member made of aluminum and is formed in a bottomed cylindrical shape so as to cover the cleavage portion 22a of the cleavage vent 22. That is, the blocking vent 25 includes a circular bottom surface portion 25a and a peripheral wall portion 25b formed on the outer peripheral side of the bottom surface portion 25a. The opening end side of the peripheral wall portion 25b is held by the cylindrical cleaving portion 22a of the cleaving vent 22 by an annular holding member 24 made of an insulating material.
 保持部材24は、ポリブチレンテレフタレート(PBT)またはポリプロピレン(PP)製の部材である。よって、保持部材24は、開裂ベント22と遮断ベント25とを、後述する溶接部分50以外では絶縁することができる。 The holding member 24 is a member made of polybutylene terephthalate (PBT) or polypropylene (PP). Therefore, the holding member 24 can insulate the cleavage vent 22 and the blocking vent 25 except for the welded portion 50 described later.
 図3に示すように、遮断ベント25の底面部25aには、複数(本実施形態では6つ)の貫通孔25cが周方向に等間隔で形成されている。これらの貫通孔25cは、電池缶10内で過充電等によって発生したガスが通過するためのガス通気孔である。これらの貫通孔25cを設けることにより、遮断ベント25をガスが通過して、開裂ベント22の開裂部22aに圧力が付与される。 As shown in FIG. 3, a plurality (six in this embodiment) of through holes 25 c are formed at equal intervals in the circumferential direction on the bottom surface portion 25 a of the blocking vent 25. These through holes 25c are gas vent holes through which gas generated by overcharging or the like in the battery can 10 passes. By providing these through holes 25 c, gas passes through the blocking vent 25 and pressure is applied to the cleavage portion 22 a of the cleavage vent 22.
 また、詳しくは後述するように、遮断ベント25の底面部25aの一部は、開裂ベント22の開裂部22aに溶接(接合)されている。さらに、遮断ベント25には、電極体40から延びる正極タブ45が接続されている(図2参照)。すなわち、電極体40、遮断ベント25及び開裂ベント22は、電気的に接続されている。上述のように密閉型電池1の内部の圧力が高くなって開裂ベント22の開裂部22aが変形すると、該開裂部22aが遮断ベント25から分離して、密閉型電池1内の電流を遮断する。すなわち、本実施形態において、遮断ベント25は、開裂ベント22とともに、電流遮断機構として機能している。 Further, as will be described in detail later, a part of the bottom surface portion 25 a of the blocking vent 25 is welded (joined) to the cleavage portion 22 a of the cleavage vent 22. Further, a positive electrode tab 45 extending from the electrode body 40 is connected to the blocking vent 25 (see FIG. 2). That is, the electrode body 40, the blocking vent 25, and the cleavage vent 22 are electrically connected. As described above, when the internal pressure of the sealed battery 1 is increased and the cleavage portion 22a of the cleavage vent 22 is deformed, the cleavage portion 22a is separated from the cutoff vent 25, and the current in the sealed battery 1 is cut off. . That is, in this embodiment, the interruption vent 25 functions as a current interruption mechanism together with the cleavage vent 22.
 遮断ベント25の詳しい構成については後述する。 The detailed configuration of the blocking vent 25 will be described later.
 ガスケット30は、ポリブチレンテレフタレート(PBT)またはポリプロピレン(PP)などからなる概略円筒状の部材である。ガスケット30には、一方側の端部の径が他方側の端部の径に比べて大きくなるように、筒軸方向の中央部分に段部31が設けられている。すなわち、ガスケット30は、大径部33と、小径部32と、それらの間に位置する段部31と、を有している。大径部33は、封口体20を収納可能なように、該封口体20の外径よりも大きい内径を有する。ガスケット30の大径部33内に、段部31で封口体20を支持するように収納し、該大径部33の開口側とともに電池缶10の周壁部10の開口端部10aを封口体20にかしめることにより、図2に示すように、ガスケット30が電池缶10と封口体20との間に挟みこまれる。 The gasket 30 is a substantially cylindrical member made of polybutylene terephthalate (PBT) or polypropylene (PP). The gasket 30 is provided with a step portion 31 at the center portion in the cylinder axis direction so that the diameter of the end portion on one side is larger than the diameter of the end portion on the other side. That is, the gasket 30 has a large-diameter portion 33, a small-diameter portion 32, and a step portion 31 positioned therebetween. The large diameter portion 33 has an inner diameter larger than the outer diameter of the sealing body 20 so that the sealing body 20 can be accommodated. The sealing body 20 is accommodated in the large diameter portion 33 of the gasket 30 so as to support the sealing body 20 by the step portion 31, and the opening end 10 a of the peripheral wall portion 10 of the battery can 10 is sealed together with the opening side of the large diameter portion 33. By caulking, the gasket 30 is sandwiched between the battery can 10 and the sealing body 20 as shown in FIG.
 電極体40は、特に図示しないが、シート状の正極及び負極がセパレータを介して厚み方向に積層された状態で、渦巻状に捲回されたものである。電極体40は、正極が正極活物質を有する一方、負極が負極活物質を有し、充放電可能に構成されている。正極、負極及びセパレータの詳しい構成については、従来と同様なので、詳しい説明を省略する。なお、電極体40の正極は、電池缶10の開口端部側で、正極タブ45を介して遮断ベント25に電気的に接続されている。一方、電極体40の負極は、電池缶10の底部側で、図示しない負極タブによって該電池缶10に電気的に接続されている。 The electrode body 40 is wound in a spiral shape in a state where a sheet-like positive electrode and a negative electrode are laminated in the thickness direction via a separator, although not particularly illustrated. In the electrode body 40, the positive electrode has a positive electrode active material, while the negative electrode has a negative electrode active material, and is configured to be chargeable / dischargeable. Detailed configurations of the positive electrode, the negative electrode, and the separator are the same as those in the related art, and thus detailed description thereof is omitted. The positive electrode of the electrode body 40 is electrically connected to the blocking vent 25 via the positive electrode tab 45 on the opening end side of the battery can 10. On the other hand, the negative electrode of the electrode body 40 is electrically connected to the battery can 10 by a negative electrode tab (not shown) on the bottom side of the battery can 10.
 正極に用いられる正極活物質としては、例えば、LiCoOなどのリチウムコバルト酸化物、LiMnなどのリチウムマンガン酸化物、LiNiOなどのリチウムニッケル酸化物、二酸化マンガン、五酸化バナジウム、クロム酸化物などの金属酸化物や、二硫化チタン、二硫化モリブデンなどの金属硫化物などが用いられる。 Examples of the positive electrode active material used for the positive electrode include lithium cobalt oxide such as LiCoO 2 , lithium manganese oxide such as LiMn 2 O 4 , lithium nickel oxide such as LiNiO 2 , manganese dioxide, vanadium pentoxide, and chromium oxide. Metal oxides such as materials, and metal sulfides such as titanium disulfide and molybdenum disulfide are used.
 一方、負極に用いられる負極活物質としては、リチウムイオンをドープ及び脱ドープすることができるものであればどのような物質でもよい。例えば、負極活物質として、黒鉛、熱分解炭素類、コークス類、ガラス状炭素類、有機高分子化合物の焼成体、メソカーボンマイクロビーズ、炭素繊維、活性炭などの炭素材料、Si、Sn、Inなどの合金、または、Liに近い低電圧で充放電できるSi、Sn、Inなどの酸化物等を用いるのが好ましい。 On the other hand, the negative electrode active material used for the negative electrode may be any material that can dope and dedope lithium ions. For example, as a negative electrode active material, graphite, pyrolytic carbons, cokes, glassy carbons, organic polymer compound fired bodies, mesocarbon microbeads, carbon fibers, activated carbon and other carbon materials, Si, Sn, In, etc. It is preferable to use an alloy of Si, Sn, In or the like that can be charged and discharged at a low voltage close to Li.
 (遮断ベント)
 以下で、開裂ベント22とともに電流遮断機構として機能する遮断ベント25の構成を、図3から図6を用いて詳細に説明する。ここで、図3は遮断ベント25の底面図、図4は図3におけるIV-IV線断面図、図5は遮断ベント25の底面部25aの中央部分の拡大図、図6は遮断ベント25と開裂ベント22との溶接部分50の拡大断面図である。
(Blocking vent)
Below, the structure of the interruption | blocking vent 25 which functions as an electric current interruption | blocking mechanism with the cleavage vent 22 is demonstrated in detail using FIGS. 3 is a bottom view of the blocking vent 25, FIG. 4 is a sectional view taken along line IV-IV in FIG. 3, FIG. 5 is an enlarged view of a central portion of the bottom portion 25a of the blocking vent 25, and FIG. It is an expanded sectional view of the welding part 50 with the cleavage vent 22. FIG.
 図3から図6に示すように、底面部25aの底面(外方側の面)の中央部分には、薄肉部26が設けられている。この薄肉部26は、底面部25aの底面の中央部分を段状に薄くすることにより形成される。薄肉部26は、平面視で円形状に形成されている。また、薄肉部26の中央部分には、さらに薄肉に形成された接続部27が設けられている。この接続部27は、平面視で円形状に形成されていて、図6に示すように、開裂ベント22の開裂部22aの膨出部22cにYAGレーザー溶接等によって接合される。これにより、接続部27及び膨出部22cに、溶接部分50(接合部分)が形成される。 As shown in FIGS. 3 to 6, a thin portion 26 is provided at the center of the bottom surface (outer surface) of the bottom surface portion 25a. The thin portion 26 is formed by thinning the central portion of the bottom surface of the bottom surface portion 25a in a step shape. The thin portion 26 is formed in a circular shape in plan view. Further, a connection portion 27 formed to be thinner is provided at the central portion of the thin portion 26. The connecting portion 27 is formed in a circular shape in plan view, and is joined to the bulging portion 22c of the cleavage portion 22a of the cleavage vent 22 by YAG laser welding or the like, as shown in FIG. Thereby, the welding part 50 (joining part) is formed in the connection part 27 and the bulging part 22c.
 図3及び図5に示すように、薄肉部26には、接続部27を囲むように、複数(本実施形態では3つ)の貫通穴部26aが形成されている。各貫通穴部26aは、接続部27を中心とした円弧状に形成された長穴であり、該接続部27に対して、遮断ベント25の径方向の同じ位置に設けられている。さらに、薄肉部26には、接続部27を囲んで且つ複数の貫通穴部26aを繋ぐように、複数の溝部26bが形成されている。具体的には、各溝部26bは、溝底の幅が開口側の溝幅に比べて小さくなるように断面略V字状に形成されている。また、各溝部26bは、図5に拡大して示すように、貫通穴部26aにおける遮断ベント25の径方向内側部分に、互いに繋がるように形成されている。さらに、各溝部26bは、開口側の溝幅が、貫通穴部26aの開口の短手方向の長さよりも小さくなるように形成されている。 As shown in FIGS. 3 and 5, a plurality of (three in this embodiment) through-hole portions 26 a are formed in the thin portion 26 so as to surround the connection portion 27. Each through-hole portion 26 a is an elongated hole formed in an arc shape with the connection portion 27 as the center, and is provided at the same position in the radial direction of the blocking vent 25 with respect to the connection portion 27. Furthermore, a plurality of groove portions 26b are formed in the thin portion 26 so as to surround the connection portion 27 and connect the plurality of through-hole portions 26a. Specifically, each groove 26b is formed in a substantially V-shaped cross section so that the width of the groove bottom is smaller than the groove width on the opening side. Moreover, each groove part 26b is formed so that it may mutually connect in the radial direction inner side part of the interruption | blocking vent 25 in the through-hole part 26a, as expanded and shown in FIG. Furthermore, each groove part 26b is formed so that the groove width on the opening side is smaller than the length in the short direction of the opening of the through hole part 26a.
 このように、複数の貫通穴部26aを繋ぐように溝部26bを設けることで、該溝部26bの溝底部分のせん断強度を、開裂ベント22の膨出部22cと接続部27との溶接部分50のせん断強度よりも小さくすることができる。したがって、密閉型電池1内で過充電等によってガスが発生して開裂ベント22が端子板21側に変形した場合、開裂ベント22と溶接された接続部27が該開裂ベント22とともに端子板21側に引っ張られると、遮断ベント25は、溝部26bで破断する。すなわち、開裂ベント22と遮断ベント25との溶接部分50ではなく、該遮断ベント25の溝部26bで破断するため、溶接などの接合条件の影響を受けることなく、密閉型電池1の内部の圧力が一定値(例えば、1.4MPa)に達した際に開裂ベント22と遮断ベント25とを分離できる。 In this way, by providing the groove portion 26b so as to connect the plurality of through-hole portions 26a, the shear strength of the groove bottom portion of the groove portion 26b is set to the welded portion 50 between the bulging portion 22c of the cleavage vent 22 and the connection portion 27. It can be made smaller than the shear strength. Therefore, when gas is generated in the sealed battery 1 due to overcharge or the like and the cleavage vent 22 is deformed to the terminal plate 21 side, the connection portion 27 welded to the cleavage vent 22 is connected to the terminal plate 21 side together with the cleavage vent 22. When it is pulled, the blocking vent 25 is broken at the groove 26b. That is, since the fracture is caused not by the welded portion 50 between the cleavage vent 22 and the blocking vent 25 but by the groove portion 26b of the blocking vent 25, the pressure inside the sealed battery 1 is not affected by the joining conditions such as welding. When reaching a certain value (for example, 1.4 MPa), the cleavage vent 22 and the blocking vent 25 can be separated.
 また、上述のような構成を有する遮断ベント25は、コイニングによって形成される。したがって、金属箔を用いる構成に比べて低コストで遮断ベント25を形成することができる。ところが、コイニングによって遮断ベント25を形成すると、薄肉部26の外周縁部で加工硬化が生じ、応力集中によって破断しやすくなる。そうすると、遮断ベント25が破断する力にばらつきが生じてしまう。これに対し、上述のような溝部26bを設けることにより、遮断ベント25を該溝部26bで破断することができる。したがって、上述の構成により、遮断ベント25をコイニングによって形成した場合でも、電池内部の圧力が一定値に達した際に、溝部26bで開裂ベント22と遮断ベント25とを分離することができる。 Further, the blocking vent 25 having the above-described configuration is formed by coining. Therefore, the blocking vent 25 can be formed at a lower cost than the configuration using the metal foil. However, when the blocking vent 25 is formed by coining, work hardening occurs at the outer peripheral edge portion of the thin portion 26, and breakage tends to occur due to stress concentration. If it does so, dispersion | variation will arise in the force which the interruption | blocking vent 25 fractures | ruptures. On the other hand, by providing the groove part 26b as described above, the blocking vent 25 can be broken at the groove part 26b. Therefore, even when the blocking vent 25 is formed by coining, the cleavage vent 22 and the blocking vent 25 can be separated by the groove portion 26b when the internal pressure of the battery reaches a certain value.
 さらに、図6に示すように、各溝部26bは、遮断ベント25の薄肉部26に開裂ベント22の膨出部22cが押し当てられた状態で、平面視で(該遮断ベント25及び開裂ベント22の積層方向から見て)、膨出部22cの内側に形成されている。 Furthermore, as shown in FIG. 6, each groove portion 26 b is in plan view (in the state where the bulging portion 22 c of the cleavage vent 22 is pressed against the thin portion 26 of the interruption vent 25). , As viewed from the stacking direction), and is formed inside the bulging portion 22c.
 遮断ベント25の薄肉部26の接続部27と開裂ベント22の膨出部22cとをYAGレーザー溶接等によって接合するためには、該膨出部22cと接続部27との隙間をできるだけ小さくする必要がある。そのためには、膨出部22cを薄肉部26に押し付ける必要があるが、平面視で該膨出部22cよりも外側に溝部26bが形成されていると、該溝部26bに応力が集中して該溝部26bで破断する可能性がある。これに対し、上述のような位置に溝部26bを設けることにより、膨出部22cを薄肉部26に押し付けた場合に、溝部26bに大きな力が加わらないため、該溝部26bで破断するのを防止できる。 In order to join the connecting portion 27 of the thin portion 26 of the blocking vent 25 and the bulging portion 22c of the cleavage vent 22 by YAG laser welding or the like, it is necessary to make the gap between the bulging portion 22c and the connecting portion 27 as small as possible. There is. For this purpose, it is necessary to press the bulging portion 22c against the thin-walled portion 26. However, if the groove portion 26b is formed outside the bulging portion 22c in a plan view, stress concentrates on the groove portion 26b and the There is a possibility of breaking at the groove 26b. On the other hand, by providing the groove portion 26b at the position as described above, when the bulging portion 22c is pressed against the thin portion 26, a large force is not applied to the groove portion 26b, thereby preventing the groove portion 26b from breaking. it can.
 また、上述のような位置に溝部26bを設けることで、該溝部26bが接続部27に近くなるため、該溝部26bで破断した場合に、遮断ベント25のうち開裂ベント22側に付着する部分を小さくすることができる。これにより、開裂ベント22側に付着した遮断ベント25の一部が、該遮断ベント25の残りの部分に接触して密閉型電池1内で電流が流れ続けるのを防止できる。 Further, by providing the groove 26b at the position as described above, the groove 26b is close to the connecting portion 27. Therefore, when the groove 26b breaks, the portion of the blocking vent 25 that adheres to the cleavage vent 22 side is removed. Can be small. As a result, it is possible to prevent a part of the blocking vent 25 attached to the cleavage vent 22 side from contacting the remaining part of the blocking vent 25 and causing a current to continue flowing in the sealed battery 1.
 さらに、上述のような位置に溝部26bを設けることで、溝部を平面視で膨出部22cよりも外側に設けた場合に比べて、小さい力によって遮断ベント25を溝部26bで破断させることができる。すなわち、溝部26bが接続部27から遠くなると、その分、該溝部26bの距離が長くなって溝底部分のせん断強度も高くなるが、溝部26bを接続部27のより近くに設けることにより、小さい圧力でも溝部26bで遮断ベント25をより確実に破断させることができる。 Furthermore, by providing the groove portion 26b at the position as described above, the blocking vent 25 can be broken at the groove portion 26b with a smaller force than when the groove portion is provided outside the bulging portion 22c in plan view. . That is, when the groove portion 26b is far from the connection portion 27, the distance of the groove portion 26b is increased correspondingly, and the shear strength of the groove bottom portion is also increased. However, by providing the groove portion 26b closer to the connection portion 27, it is small. Even with pressure, the blocking vent 25 can be more reliably broken by the groove 26b.
 (開裂ベント及び遮断ベントの動作)
 次に、上述のような構成を有する開裂ベント22及び遮断ベント25の高圧条件下での動作について以下で説明する。
(Operation of cleavage vent and blocking vent)
Next, the operation of the cleavage vent 22 and the blocking vent 25 having the above-described configuration under high pressure conditions will be described below.
 密閉型電池1で過充電等の異常が発生して電池缶10内の圧力が上昇した場合、該圧力によって開裂ベント22が端子板21側へ変形する。そして、電池缶10内の圧力が1.4MPaになると、遮断ベント25が溝部26bで破断し、該遮断ベント25と開裂ベント22とが分離する。これにより、遮断ベント25と開裂ベント22との間に電流が流れなくなって、密閉型電池1内で電流が流れなくなる。 When an abnormality such as overcharge occurs in the sealed battery 1 and the pressure in the battery can 10 increases, the cleavage vent 22 is deformed to the terminal plate 21 side by the pressure. And if the pressure in the battery can 10 becomes 1.4 MPa, the interruption | blocking vent 25 will fracture | rupture in the groove part 26b, and this interruption | blocking vent 25 and the cleavage vent 22 will isolate | separate. As a result, no current flows between the blocking vent 25 and the cleavage vent 22, and no current flows in the sealed battery 1.
 さらに電池缶10内の圧力が上昇して該電池缶10内の圧力が2.5MPaになると、開裂ベント22が溝部22d,22eで破断する。これにより、開裂ベント22は開裂されて、電池缶10内のガスや電解液が開裂ベント22に形成された穴から外部へ噴出する。 Further, when the pressure in the battery can 10 rises and the pressure in the battery can 10 reaches 2.5 MPa, the cleavage vent 22 breaks at the groove portions 22d and 22e. Thereby, the cleavage vent 22 is cleaved, and the gas and the electrolyte in the battery can 10 are ejected from the hole formed in the cleavage vent 22 to the outside.
 このように開裂ベント22及び遮断ベント25が動作することで、密閉型電池1内の圧力上昇に応じて電流を遮断できるとともに、電池缶10が内圧によって破裂するのを防止できる。 As described above, by operating the cleavage vent 22 and the shutoff vent 25, it is possible to cut off the current according to the pressure increase in the sealed battery 1, and to prevent the battery can 10 from being ruptured by the internal pressure.
 (実施形態の効果)
 以上の構成により、遮断ベント25の薄肉部26に、開裂ベント22との溶接部分50よりもせん断強度を低下させる溝部26bを、接続部27を囲むように設けたため、該遮断ベント25を溝部26bで破断することができる。したがって、溶接部分50の溶接条件等に影響を受けることなく、電池缶10内の内圧が所定値に達した際に溝部26bで遮断ベント25と開裂ベント22とを分離することができる。すなわち、上述の構成により、遮断ベント25と開裂ベント22とが分離する電池缶10内の圧力値のばらつきを低減できる。
(Effect of embodiment)
With the above configuration, since the groove portion 26b for lowering the shear strength than the welded portion 50 with the cleavage vent 22 is provided in the thin wall portion 26 of the interruption vent 25 so as to surround the connection portion 27, the interruption vent 25 is provided in the groove portion 26b. Can be broken. Therefore, the interruption vent 25 and the cleavage vent 22 can be separated by the groove 26b when the internal pressure in the battery can 10 reaches a predetermined value without being affected by the welding conditions of the welded portion 50 and the like. That is, with the above-described configuration, it is possible to reduce variations in the pressure value in the battery can 10 where the blocking vent 25 and the cleavage vent 22 are separated.
 また、遮断ベント25及び開裂ベント22の積層方向から見て、溝部26bを、該開裂ベント22の膨出部22cよりも内側に設けることで、該膨出部22cを遮断ベント25の薄肉部26に押し当てた際に、溝部26bが破断するのを防止できる。しかも、この構成により、溝部26bで破断した場合に、開裂ベント22側に付着した遮断ベント25の一部の長さを比較的短くできるため、該開裂ベント22側に付着した遮断ベント25の一部と該遮断ベント25の残りの部分とが接触して短絡するのを防止できる。さらに、溝部26bが結合部27に比較的近い位置に形成されるため、遮断ベント25を比較的小さい力によって該溝部26bで破断できる。 Further, as seen from the stacking direction of the blocking vent 25 and the cleavage vent 22, the groove portion 26 b is provided on the inner side of the bulging portion 22 c of the cleavage vent 22, so that the bulging portion 22 c is a thin-walled portion 26 of the blocking vent 25. It is possible to prevent the groove 26b from being broken when pressed against. In addition, with this configuration, when the groove 26b breaks, the length of a part of the blocking vent 25 attached to the cleavage vent 22 side can be relatively shortened. It is possible to prevent a short circuit due to contact between the portion and the remaining portion of the blocking vent 25. Furthermore, since the groove part 26b is formed at a position relatively close to the coupling part 27, the blocking vent 25 can be broken at the groove part 26b with a relatively small force.
 さらに、溝部26bは、遮断ベント25の薄肉部26に設けられた複数の貫通穴部26aを繋ぐように設けられている。そのため、該溝部26bの溝底部分のせん断強度を遮断ベント25と開裂ベント22との溶接部分50に比べて小さくすることができる。よって、遮断ベント25を溝部26bでより確実に破断することができる。 Furthermore, the groove 26b is provided so as to connect a plurality of through holes 26a provided in the thin portion 26 of the blocking vent 25. Therefore, the shear strength of the groove bottom portion of the groove portion 26 b can be reduced as compared with the welded portion 50 between the blocking vent 25 and the cleavage vent 22. Therefore, the blocking vent 25 can be more reliably broken at the groove 26b.
 (その他の実施形態)
 以上、本発明の実施の形態を説明したが、上述した実施の形態は本発明を実施するための例示に過ぎない。よって、本発明は上述した実施の形態に限定されることなく、その趣旨を逸脱しない範囲内で上述した実施の形態を適宜変形して実施することが可能である。
(Other embodiments)
While the embodiments of the present invention have been described above, the above-described embodiments are merely examples for carrying out the present invention. Therefore, the present invention is not limited to the above-described embodiment, and can be implemented by appropriately modifying the above-described embodiment without departing from the spirit thereof.
 前記実施形態では、遮断ベント25の薄肉部26に貫通穴部26aを3つ形成している。しかしながら、開裂ベント22が変形した際に遮断ベント25が溝部26bで破断するような構成であれば、貫通穴部26aの数は2つ以下や4つ以上であってもよいし、貫通穴部を設けなくてもよい。貫通穴部を設けない場合には、例えば、溝部26bの断面形状をより破断しやすい形状にしたり、溝部26bを接続部27により近い位置に設けたりすることによって、溝部26bでより破断しやすくする必要がある。 In the above embodiment, three through holes 26 a are formed in the thin portion 26 of the blocking vent 25. However, the number of the through holes 26a may be two or less or four or more as long as the blocking vent 25 is broken at the groove 26b when the cleavage vent 22 is deformed. May not be provided. When the through-hole portion is not provided, for example, by making the cross-sectional shape of the groove portion 26b easier to break, or by providing the groove portion 26b closer to the connecting portion 27, the groove portion 26b can be more easily broken. There is a need.
 前記実施形態では、遮断ベント25の薄肉部26に設ける溝部26bの断面形状を略V字状にしている。しかしながら、溝部26bで破断するような断面形状であれば、それ以外の断面形状であってもよい。 In the above-described embodiment, the cross-sectional shape of the groove 26b provided in the thin portion 26 of the blocking vent 25 is substantially V-shaped. However, other cross-sectional shapes may be used as long as the cross-sectional shape is broken at the groove 26b.
 前記実施形態では、遮断ベント25の外側の底面(電池缶10の内方側の面)に溝部26bを設けている。しかしながら、遮断ベント25の内側の底面(開裂ベント22側の面)に溝部26bを設けてもよい。 In the above-described embodiment, the groove portion 26b is provided on the bottom surface outside the blocking vent 25 (the inner surface of the battery can 10). However, the groove 26b may be provided on the bottom surface inside the blocking vent 25 (the surface on the side of the cleavage vent 22).
 前記実施形態では、遮断ベント25の接続部27と開裂ベント22の膨出部22cとを溶接によって接合している。しかしながら、部材同士を接合できる方法であれば、溶接以外の方法で接合してもよい。 In the above embodiment, the connecting portion 27 of the blocking vent 25 and the bulging portion 22c of the cleavage vent 22 are joined by welding. However, any method other than welding may be used as long as the members can be joined together.
 前記実施形態では、開裂ベント22と端子板21との間に抵抗板23を設けている。しかしながら、抵抗板23を設けずに、開裂ベント22と端子板21とを直接接触させるようにしてもよい。 In the above embodiment, the resistance plate 23 is provided between the cleavage vent 22 and the terminal plate 21. However, the cleavage vent 22 and the terminal plate 21 may be brought into direct contact without providing the resistance plate 23.
 本発明による密閉型電池は、電流遮断機能を備えた密閉型電池に利用可能である。 The sealed battery according to the present invention can be used for a sealed battery having a current interruption function.

Claims (5)

  1.  電極体が収納される有底筒状の外装缶と、
     前記外装缶の開口側を覆うように配置され、該外装缶内の圧力上昇に応じて変形し開裂する開裂板と、
     前記開裂板の外装缶内方側に該開裂板と厚み方向に重ね合わされるように配置され、前記電極体に電気的に接続されるとともに該開裂板の一部にも接合される遮断板と、を備え、
     前記遮断板には、前記開裂板と接合される接続部を有する薄肉部が設けられていて、
     前記薄肉部には、前記接続部の該開裂板との接合部分よりも前記薄肉部のせん断強度を低下させる溝部が、前記接続部を囲むように形成されている、密閉型電池。
    A bottomed cylindrical outer can in which an electrode body is stored;
    A cleavage plate that is arranged so as to cover the opening side of the outer can, and is deformed and cleaved in response to a pressure increase in the outer can;
    A blocking plate that is arranged on the inner side of the outer can of the cleavage plate so as to overlap the cleavage plate in the thickness direction, and is electrically connected to the electrode body and also joined to a part of the cleavage plate; With
    The blocking plate is provided with a thin portion having a connection portion joined to the cleavage plate,
    A sealed battery, wherein the thin-walled portion is formed with a groove portion that lowers the shear strength of the thin-walled portion so as to surround the connecting portion, rather than a joint portion of the connecting portion with the cleavage plate.
  2.  請求項1に記載の密閉型電池において、
     前記薄肉部には、該薄肉部を厚み方向に貫通する複数の貫通穴部が形成されていて、
     前記溝部は、前記複数の貫通穴部同士を繋ぐように前記薄肉部に設けられている、密閉型電池。
    The sealed battery according to claim 1,
    In the thin wall portion, a plurality of through-hole portions penetrating the thin wall portion in the thickness direction are formed,
    The groove portion is a sealed battery provided in the thin portion so as to connect the plurality of through-hole portions.
  3.  請求項1または2に記載の密閉型電池において、
     前記開裂板には、前記遮断板の薄肉部側に膨出して該薄肉部の接続部に当接する膨出部が形成されていて、
     前記溝部は、前記開裂板及び遮断板の積層方向から見て前記膨出部よりも内側に設けられている、密閉型電池。
    The sealed battery according to claim 1 or 2,
    The cleavage plate is formed with a bulging portion that bulges toward the thin portion of the blocking plate and contacts the connecting portion of the thin portion,
    The said groove part is a sealed battery provided in the inner side rather than the said bulging part seeing from the lamination direction of the said cleavage plate and the interruption | blocking board.
  4.  請求項1から3のいずれか一つに記載の密閉型電池において、
     前記接続部は、前記薄肉部の他の部分に比べてさらに薄肉に形成されている、密閉型電池。
    The sealed battery according to any one of claims 1 to 3,
    The said connection part is a sealed battery formed further thinly compared with the other part of the said thin part.
  5.  請求項1から4のいずれか一つに記載の密閉型電池において、
     前記遮断板の薄肉部及び溝部は、コイニングによって形成される、密閉型電池。
    The sealed battery according to any one of claims 1 to 4,
    The thin-walled portion and the groove portion of the blocking plate are sealed batteries formed by coining.
PCT/JP2011/054947 2010-03-26 2011-03-03 Hermetic battery WO2011118359A1 (en)

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WO2023097584A1 (en) * 2021-12-01 2023-06-08 宁德时代新能源科技股份有限公司 Battery cell, battery, electrical apparatus and manufacturing method and apparatus for battery cell

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