WO2011111479A1 - Photomask, exposure device, and method for producing liquid crystal display panel - Google Patents
Photomask, exposure device, and method for producing liquid crystal display panel Download PDFInfo
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- WO2011111479A1 WO2011111479A1 PCT/JP2011/053117 JP2011053117W WO2011111479A1 WO 2011111479 A1 WO2011111479 A1 WO 2011111479A1 JP 2011053117 W JP2011053117 W JP 2011053117W WO 2011111479 A1 WO2011111479 A1 WO 2011111479A1
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- photomask
- exposure
- light
- liquid crystal
- substrate
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F1/00—Originals for photomechanical production of textured or patterned surfaces, e.g., masks, photo-masks, reticles; Mask blanks or pellicles therefor; Containers specially adapted therefor; Preparation thereof
- G03F1/52—Reflectors
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F1/00—Originals for photomechanical production of textured or patterned surfaces, e.g., masks, photo-masks, reticles; Mask blanks or pellicles therefor; Containers specially adapted therefor; Preparation thereof
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F1/00—Originals for photomechanical production of textured or patterned surfaces, e.g., masks, photo-masks, reticles; Mask blanks or pellicles therefor; Containers specially adapted therefor; Preparation thereof
- G03F1/50—Mask blanks not covered by G03F1/20 - G03F1/34; Preparation thereof
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/1303—Apparatus specially adapted to the manufacture of LCDs
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1337—Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers
- G02F1/13378—Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers by treatment of the surface, e.g. embossing, rubbing or light irradiation
- G02F1/133788—Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers by treatment of the surface, e.g. embossing, rubbing or light irradiation by light irradiation, e.g. linearly polarised light photo-polymerisation
Definitions
- the present invention relates to a photomask, an exposure apparatus, and a method for manufacturing a liquid crystal display panel. More particularly, the present invention relates to a photomask used for alignment division by an alignment film, an exposure apparatus, and a method for manufacturing a liquid crystal display panel.
- a photomask is used for exposing a photosensitive resin layer on a substrate, and is used for manufacturing various electronic members. In particular, it is widely used in alignment film exposure by a photo-alignment method for manufacturing a liquid crystal display panel.
- the alignment film exposure process is an important process for forming an alignment film that controls and regulates the alignment direction of the liquid crystal molecules, and this makes it possible to manufacture a liquid crystal display panel having an excellent viewing angle. For example, by applying light from a predetermined direction through a photomask, the alignment film is given an alignment regulating force for liquid crystal molecules, and in the next step, the alignment film is selectively irradiated from different directions. A method of performing alignment division of the alignment film is used.
- a liquid crystal display device in which at least one holding a liquid crystal has a pair of transparent substrates, and an alignment film for regulating the alignment direction of liquid crystal molecules is provided on each substrate.
- This is a method of manufacturing, and by applying ultraviolet rays through an optical mask, the alignment film is given an alignment regulating force of liquid crystal molecules, and the alignment film is selectively irradiated with ultraviolet rays from different directions, whereby the alignment film
- a method for manufacturing a liquid crystal display device including performing alignment division, wherein an optical mask having a light-shielding pattern surface provided with a metal-dielectric multilayer film is used, and the multilayer film transmits ultraviolet rays having a specific incident angle.
- a method of manufacturing a liquid crystal display device characterized by being optimized is disclosed (for example, see Patent Document 1).
- An object of this manufacturing method is to optimize the alignment division by narrowing the range of the overlapped exposure region when performing the alignment division, thereby enabling stable alignment of the alignment film.
- a scanning exposure method in which a plurality of small photomasks are connected to reduce the running cost of the photomask. Since the photomask is small, it is usually irradiated with light such as ultraviolet rays in several times. As the number of exposure steps increases, the number of exposure stages increases accordingly.
- FIG. 6 is a schematic plan view of a conventional photomask 111.
- a light shielding unit 113 and a transmission unit 115 are provided, and exposure can be performed, for example, for each half-pixel width by light transmitted through the transmission unit 115.
- an exposure process is further provided to irradiate the substrate main surface with ultraviolet rays from different directions.
- the exposure process is classified in each light irradiation direction, and exposure is performed using a plurality of small masks.
- the entire substrate on which the alignment film before exposure is formed in a plurality of times using a plurality of small masks when the alignment division processing is performed by performing light irradiation from two or more different directions, the entire substrate Since the exposure is performed at least two times and at least two different directions in order to divide the plurality of times into a plurality of times, at least four exposure stages are required.
- a transfer stage for preparing for pre-exposure is provided between the exposure stages, and the entire facility becomes huge.
- FIG. 7 conceptually shows the exposure process of such a conventional exposure apparatus.
- FIG. 7 shows that the alignment film exposure process for alignment division is composed of four stages and a transport stage connecting them. Specifically, it is composed of four stage portions 171a, 171b, 171c, and 171d, and the substrate 130 advances along the substrate flow 181.
- the direction of inclination with the ultraviolet ray 121 is different.
- the photo-alignment method different tilts can be imparted to the liquid crystal by irradiating light with different irradiation directions.
- the main surface of the photomask 111 is parallel to the main surface of the substrate 130 to be exposed, and the photomask 111 transmits the irradiation light from the exposure light source for each half-pixel width. Exposure.
- the conventional exposure apparatus has a large installation space, and each stage is provided with expensive consumables such as a plurality of photomasks and high-pressure mercury lamps, and in particular, a photomask that is different for each normal model is used. Therefore, it leads to an increase in equipment cost and running cost. That is, since a plurality of light sources (exposure light source and tracking light source) and a photomask are required for each exposure stage, the running cost of the entire apparatus is enormous. In the conventional exposure apparatus and liquid crystal display manufacturing method, there are significant problems in terms of efficiency of the production process and production space.
- the present invention has been made in view of the above-described present situation, and an object thereof is to provide a photomask, an exposure apparatus, and a method for manufacturing a liquid crystal display panel that can reduce running costs and equipment. To do.
- the present inventor conducted various studies on a photomask (exposure mask) used in the alignment film exposure process, an exposure apparatus using the photomask, and a method for manufacturing a liquid crystal display panel.
- the conventional photomask is divided into a transmission part and a light shielding part.
- the photomask is configured such that light incident on the photomask from the light source is irradiated to the alignment film on the substrate through the transmission part, while part of the incident light is shielded by the light shielding part. Pay attention.
- a light reflection film layer as a reflection part on the light shielding part of the photomask, it is possible to irradiate light in two directions by irradiating light from one light source.
- the process that had to be performed can be completed by one irradiation, and it was found that it can be omitted, and the inventors have conceived that the above problems can be solved brilliantly.
- the direction of installation of the photomask with respect to the substrate is different from that of the conventional substrate main surface, and is substantially perpendicular to the substrate main surface (normal direction of the substrate). While the light is transmitted and directly irradiated onto the substrate, the light reflected by the remaining reflecting portion is irradiated from the opposite direction to the former at a position shifted by approximately half a pixel from the transmitting portion.
- the purpose of alignment film exposure in alignment division is satisfied, and the present invention has been achieved.
- the present invention is a photomask used to expose an alignment film for each exposure region in the substrate surface, and the photomask transmits and reflects light incident on the main surface of the photomask.
- the photomask is characterized in that the transmitted light is irradiated toward one of the exposure regions and the reflected light is irradiated toward the other of the exposure regions.
- a part of the photomask is a transmission part and the other part is constituted by a reflection part.
- the photomask has a light-shielding part.
- a light-shielding portion is provided around the periphery and the edge of the photomask.
- the transmissive portion is preferably formed by being divided into a plurality of parts in one photomask, and usually has a form in which a plurality of slit-shaped transmissive portions are arranged at a constant direction and at a constant interval.
- the reflection part may be formed of a member that reflects light so that the alignment film can be oriented, and the light reflection layer is preferably formed of a metal film having a high light reflectance such as an aluminum film.
- a plurality of slit-shaped transmission parts are arranged in a predetermined direction (fixed direction) and at a predetermined interval (fixed interval), and between the plurality of transmission parts.
- a plurality of reflective portions having substantially the same shape as the transmissive portion are arranged in a predetermined direction (constant direction) and at a predetermined interval (constant interval), and the short axis side of the slit-shaped transmissive portion and the short axis side of the reflective portion are arranged side by side
- the both-ends of the photomask along the line form a light shielding part.
- the photomask of the present invention As long as the light incident on the main surface of the photomask is transmitted and reflected, it has the transmissive part and the reflective part as described above.
- a form in which a photomask is constituted by a member that transmits and reflects light at the same time, and transmission and reflection are performed in the same area in the photomask can be cited.
- light incident from one direction is normally decomposed in two directions by transmission and reflection and irradiated in two directions, and such a form is preferable. You may make it irradiate in more directions by changing the shape of a reflection part partially.
- the light is preferably incident from one direction, but may be incident from multiple directions.
- One preferred form of the photomask of the present invention is a form in which the main surface is arranged and used so as to be substantially perpendicular to the substrate surface subjected to exposure.
- the light irradiation direction can be decomposed in two directions so as to be substantially symmetric with respect to the normal line of the substrate main surface.
- the process of changing the direction of irradiation which is the cause of the enlargement of the exposure equipment in the alignment division, can be performed at one time, and a remarkable effect that cannot be realized with a conventional photomask can be obtained.
- the photomask main surface is arranged so as to be substantially perpendicular to the substrate surface to be exposed, the angle of light decomposed in two directions and irradiated to the substrate surface is the same.
- the main surface of the photomask is inclined with respect to the substrate surface. It does not prevent it.
- This invention is also an exposure apparatus provided with the light source which irradiates the light which exposes the photomask and alignment film of this invention.
- a preferred form of the above exposure apparatus is a form in which a scan exposure method is performed in which a plurality of small photomasks are joined together.
- an alignment film before exposure is formed in several steps to expose the entire substrate. Then, light such as ultraviolet rays is irradiated from a predetermined direction toward the substrate.
- the exposure apparatus of the present invention makes it possible to perform substantially two exposures in one exposure operation, and particularly in an alignment division exposure process in which an alignment film in one pixel is divided into a plurality of alignment directions. Therefore, the production process can be made more efficient and the production space can be reduced.
- the present invention further provides a method for producing a liquid crystal display panel comprising a pair of substrates, a liquid crystal layer provided between the substrates, and an alignment film provided on the surface of at least one liquid crystal layer of the substrate,
- the manufacturing method is a method for manufacturing a liquid crystal display panel including a step of exposing the alignment film using the exposure apparatus of the present invention.
- the present invention is also a method for producing a liquid crystal display panel comprising a pair of substrates, a liquid crystal layer provided between the substrates, and an alignment film provided on the surface of at least one liquid crystal layer of the substrate,
- the substrate surface is divided into two or more exposure regions, the alignment film in one of the exposure regions is exposed with light transmitted through the photomask, and the alignment film in the other of the exposure regions is exposed with light reflected from the photomask.
- the exposure area is, for example, one picture element divided into half picture elements, one half picture element having a constant orientation direction, and the other half picture element having a constant orientation direction different from the orientation direction.
- one half picture element is used as one exposure area
- the other half picture element is used as another exposure area.
- the orientation of the alignment film is different for each exposure region, which improves the viewing angle of the liquid crystal display panel.
- the exposure step irradiates light to the main surface of the photomask from an oblique direction with respect to the normal line of the main surface of the substrate to perform transmission and reflection.
- Other configurations of the above-described photomask, exposure apparatus, and liquid crystal display panel manufacturing method of the present invention may be set as appropriate, and are not particularly limited as long as the effects of the present invention are not impaired.
- the photomask, exposure apparatus, and liquid crystal display panel manufacturing method of the present invention not only reduce running costs and equipment, but also mask operation control because the number of scan exposures is halved in some cases. It will also help to reduce the risk of defects due to mistakes. Further, in the conventional exposure apparatus, since about half of the photomask area is shielded, a great deal of energy from the light source is wasted, but in the present invention, substantially all of the light from the light source is used. Efficient use of energy becomes possible. Note that the present invention only needs to exhibit an effect of either sufficiently reducing the running cost or reducing the equipment.
- the running cost can be sufficiently reduced and the equipment can be reduced.
- the production process of the liquid crystal display panel is made more efficient, and as a result, the reduction in the number of processes also contributes to higher quality.
- FIG. 2 is a schematic plan view of a photomask according to Embodiment 1.
- FIG. It is a cross-sectional schematic diagram which shows the usage pattern of the photomask which concerns on Embodiment 1.
- FIG. 1 is a schematic diagram showing an exposure apparatus according to Embodiment 1.
- FIG. 2 is a schematic plan view of a TFT substrate observed by a CCD camera of the exposure apparatus according to Embodiment 1.
- FIG. It is a schematic diagram which shows the exposure process of the exposure apparatus which concerns on Embodiment 1.
- FIG. It is a plane schematic diagram of a conventional photomask. It is a schematic diagram which shows the exposure process of the conventional exposure apparatus.
- the substrate on which the thin film transistor element (TFT) is arranged is also referred to as a TFT substrate.
- the substrate on which the color filter (CF) is disposed is also referred to as a CF substrate.
- FIG. 1 is a schematic plan view of a photomask according to the first embodiment.
- a light reflecting portion (reflecting portion 17) is provided in a portion between the transmitting portion 15 and the transmitting portion 15 (a light shielding portion in the conventional photomask), and the transmitting portion 15 and the reflecting portion are reflected.
- the portions 17 are provided alternately.
- the length of the transmission part 15 and the length of the reflection part 17 (the horizontal length shown in FIG. 1) are substantially the same, and the width of the transmission part 15 and the width of the reflection part 17 (FIG. 1).
- the vertical length shown in FIG. For example, a film having a high light reflectivity can be applied to the reflecting portion 17.
- an aluminum film or the like is preferably applied.
- One important item in the alignment division of the alignment film is to reverse the light irradiation angle for each half-pixel.
- the photomask 11 of Embodiment 1 decomposes the irradiation direction of light from a light source into two directions in an exposure process for orientation division by adding a light reflection function to a conventional light shielding portion. Thereby, the process of changing the direction of irradiation, which is the cause of enlarging the exposure equipment for the alignment film, can be performed at a time.
- a light shielding portion 13 is provided at the edge of the photomask 11.
- FIG. 2 is a schematic cross-sectional view showing a usage pattern of the photomask according to the first embodiment.
- FIG. 3 is a schematic diagram showing the exposure apparatus according to the first embodiment.
- the exposure apparatus according to Embodiment 1 is composed of two exposure stage units and a transfer stage unit therebetween, and FIG. 3 shows a part thereof.
- Each exposure stage unit is provided with a plurality of heads. Although the number of heads varies depending on the substrate size, an exposure light source 31 (exposure head unit), a photomask 11, a follow-up CCD (charge-coupled device) camera 41, and the like are installed in each head.
- the photomask 11 is arranged so that its main surface is substantially perpendicular to the substrate surface subjected to exposure.
- an image detection light source 61 (also referred to as a follow-up light source) is provided on the back surface of the substrate 30 (opposite to the exposure light source 31 when viewed from the substrate), and light from the image detection light source 61 is transmitted. It passes through the substrate 30, passes through the photomask 11 through a mirror, and reaches the CCD camera 41.
- the CCD camera 41 for fine adjustment of the photomask is usually arranged in this way, for example, since it can look into the slit of the photomask when it is perpendicular to the photomask. In addition, as long as the CCD camera 41 can capture the pattern edge of the substrate 30 and recognize the edge of the photomask 11, other forms than this form can be adopted as appropriate.
- the substrate 30 is transferred by the stage unit 71.
- the exposure light source 31 (irradiation direction of the ultraviolet rays 21) and the photomask 11 are fixed, and the ultraviolet rays are accurately emitted by causing the photomask 11 to follow the substrate 30 that travels. Irradiate.
- the tracking operation an arbitrary pattern image on the substrate 30 is set in advance, the tracking pattern provided on the photomask 11 is monitored by the CCD camera 41, and the distance between the two pattern edges is always constant. Thus, the photomask 11 is always finely adjusted.
- the CCD camera 41 installed in the exposure apparatus according to the first embodiment captures the pattern edge of the substrate 30, and simultaneously recognizes the edge of the photomask 11, and finely holds the photomask 11 so as to keep the distance between them constant. Adjust the exposure position accuracy by adjusting.
- fine adjustment is performed by the control unit 51 including an image processing circuit. Then, exposure is performed by the exposure light source 31 while finely adjusting the photomask 11.
- FIG. 4 is a schematic plan view of the TFT substrate observed with the CCD camera of the exposure apparatus according to the first embodiment.
- the dotted line indicates the traced pattern edge of the captured photomask.
- a linear or substantially linear (close to a straight line) pattern on the substrate is set as a follow-up pattern, and a slit on the photomask side (actually, a mask pattern) Appear in the image as follows). That is, follow-up exposure is possible if there is a certain linear or substantially linear pattern on the substrate surface.
- FIG. 5 is a schematic diagram showing an exposure process of the exposure apparatus according to the first embodiment.
- the transmitted ultraviolet light (transmitted light 23) is irradiated toward one of the exposure areas
- the reflected light (reflected light 25) is irradiated toward the other of the exposure areas.
- the exposure region can be adjusted as appropriate by adjusting the length and width of the transmissive and reflective portions of the photomask 11 and the irradiation direction of the ultraviolet rays from the light source.
- the ultraviolet light from the light source can be decomposed into transmitted light for normal half-picture elements and reflected light for the remaining half-picture elements, and these can be irradiated to the alignment film at the same time.
- the photomask 11 provided adjacent to the photomask 11 that transmits the transmitted light corresponding to the half-pixel is used.
- the reflected light is radiated, whereby the areas exposed by the transmitted light and the areas exposed by the reflected light are alternately arranged for each half picture element.
- the half-pixel refers to a substantially half region divided in the length direction or the width direction of a pixel indicating any one color, such as R (red), G (green), or B (blue).
- the region where the transmitted light is irradiated by one photomask and the region where the reflected light is irradiated for each half picture element are substantially the same.
- the transmitted light 23 and the reflected light 25 are alternately irradiated from the exposure light source 31a through the photomask 11, and a striped portion is generated. In between, the transmitted light 23 and the reflected light 25 are irradiated from the exposure light source 31b through the photomask 11 in the next exposure stage unit 71b. Further, the stripe-shaped portion irradiated with the transmitted light 23 and the reflected light 25 in the first exposure stage and the stripe-shaped portion irradiated with the transmitted light 23 and the reflected light 25 in the next exposure stage are shaped and large. Are substantially the same. In the first embodiment, ultraviolet light that is light normally used for photo-alignment is used. However, as long as the effect of the present invention is exhibited, light in other wavelength regions can be used. In the first embodiment, the substrate 30 is transported along the substrate flow 81.
- the installation direction of the photomask is made substantially perpendicular to the main surface of the substrate, and the photomask itself is formed with an ultraviolet reflecting film layer such as aluminum on the conventional light shielding portion, so that 2 in one scanning operation.
- an ultraviolet reflecting film layer such as aluminum on the conventional light shielding portion, so that 2 in one scanning operation.
- ultraviolet irradiation in the direction.
- the photomask perpendicular to the substrate, ultraviolet rays are transmitted from the transmission part and directly irradiated onto the substrate.
- the ultraviolet light reflected by the remaining reflecting portion is irradiated from the opposite direction to the former at a position that is exactly half a pixel apart from the transmitting portion, and a method for manufacturing a liquid crystal display device that performs alignment division of the alignment film The purpose of alignment film exposure is satisfied.
- substantially vertical may be substantially vertical to such an extent that it can be said that the preferred effect of the present embodiment is exhibited.
- Comparative Example 1 Using a conventional photomask (shown in FIG. 6) instead of the photomask according to Example 1, the exposure process was performed using four exposure stages 171a, 171b, 171c, and 171d as shown in FIG.
- an exposure lamp means an alignment film exposure lamp
- a follow-up lamp means an image detection lamp for follow-up.
- H in “1000H” and “2000H” means a unit (hour) of the average life of the lamp.
- Numberer of sheets / model means the number of photomasks required for each exposure apparatus.
- the “Effect” column shows the running cost reduction rate.
- Embodiment 1 The facility installation area and facility cost in Embodiment 1 and Comparative Example 1 are shown in Table 2 below.
- “Effect” means the reduction ratio of “Equipment Installation Area” and “Equipment Cost”.
- the running cost including the photomask and the installation area of the equipment can be reduced by about 50%, and the equipment cost can be expected to be reduced by about 33% compared to the conventional case. .
Abstract
Description
この製造方法は、配向分割を行う際に、重複露光領域の範囲を狭くすることによって配向分割を最適化し、配向膜の安定な配向を可能とすることを課題としたものである。 As a conventional method for manufacturing a liquid crystal display device, there is provided a liquid crystal display device in which at least one holding a liquid crystal has a pair of transparent substrates, and an alignment film for regulating the alignment direction of liquid crystal molecules is provided on each substrate. This is a method of manufacturing, and by applying ultraviolet rays through an optical mask, the alignment film is given an alignment regulating force of liquid crystal molecules, and the alignment film is selectively irradiated with ultraviolet rays from different directions, whereby the alignment film A method for manufacturing a liquid crystal display device including performing alignment division, wherein an optical mask having a light-shielding pattern surface provided with a metal-dielectric multilayer film is used, and the multilayer film transmits ultraviolet rays having a specific incident angle. A method of manufacturing a liquid crystal display device characterized by being optimized is disclosed (for example, see Patent Document 1).
An object of this manufacturing method is to optimize the alignment division by narrowing the range of the overlapped exposure region when performing the alignment division, thereby enabling stable alignment of the alignment film.
なお、上記のように、フォトマスクの主面が露光に供される基板面に対して略垂直となるように配置すれば、2方向に分解されて照射される光の基板面に対する角度が同等となり、配向分割を配向方向だけを変えて均一に行うという点で好ましいが、本発明のフォトマスクにおいては、フォトマスクの主面を基板面に対して斜め方向にする等の形態とすることを妨げるものではない。 One preferred form of the photomask of the present invention is a form in which the main surface is arranged and used so as to be substantially perpendicular to the substrate surface subjected to exposure. With such a usage pattern, the light irradiation direction can be decomposed in two directions so as to be substantially symmetric with respect to the normal line of the substrate main surface. As a result, when the substrate is scanned by the exposure apparatus, it is possible to irradiate light in two directions with one scanning operation, and in the alignment division process, the light irradiation angle can be reversed for each half-pixel. It becomes. The point is that the process of changing the direction of irradiation, which is the cause of the enlargement of the exposure equipment in the alignment division, can be performed at one time, and a remarkable effect that cannot be realized with a conventional photomask can be obtained.
As described above, if the photomask main surface is arranged so as to be substantially perpendicular to the substrate surface to be exposed, the angle of light decomposed in two directions and irradiated to the substrate surface is the same. However, in the photomask of the present invention, it is preferable that the main surface of the photomask is inclined with respect to the substrate surface. It does not prevent it.
上記露光装置の好ましい形態としては、小型フォトマスクを複数枚繋ぎ合わすスキャン露光方法を行う形態であり、通常では、基板全体を露光するために数回に分けて、露光前の配向膜が形成された基板上に向けて所定方向から紫外線等の光を照射することになる。本発明の露光装置は、1回の露光操作で実質的に2回の露光を行うことを可能とし、特に、1つの絵素内の配向膜を複数の配向方向に分割する配向分割露光プロセスにおいて、生産工程の効率化と生産スペースの縮小とを実現できるものである。 This invention is also an exposure apparatus provided with the light source which irradiates the light which exposes the photomask and alignment film of this invention.
A preferred form of the above exposure apparatus is a form in which a scan exposure method is performed in which a plurality of small photomasks are joined together. Usually, an alignment film before exposure is formed in several steps to expose the entire substrate. Then, light such as ultraviolet rays is irradiated from a predetermined direction toward the substrate. The exposure apparatus of the present invention makes it possible to perform substantially two exposures in one exposure operation, and particularly in an alignment division exposure process in which an alignment film in one pixel is divided into a plurality of alignment directions. Therefore, the production process can be made more efficient and the production space can be reduced.
上述した本発明のフォトマスク、露光装置及び液晶表示パネルの製造方法のその他の構成は適宜設定すればよく、本発明の効果を阻害しない限り特に限定されるものではない。 The present invention is also a method for producing a liquid crystal display panel comprising a pair of substrates, a liquid crystal layer provided between the substrates, and an alignment film provided on the surface of at least one liquid crystal layer of the substrate, In the manufacturing method, the substrate surface is divided into two or more exposure regions, the alignment film in one of the exposure regions is exposed with light transmitted through the photomask, and the alignment film in the other of the exposure regions is exposed with light reflected from the photomask. It is also a manufacturing method of a liquid crystal display panel including an exposure step of exposing. By these liquid crystal display panel manufacturing methods of the present invention, the running cost can be reduced as described above, and the manufacturing method can be reduced. The exposure area is, for example, one picture element divided into half picture elements, one half picture element having a constant orientation direction, and the other half picture element having a constant orientation direction different from the orientation direction. In this case, one half picture element is used as one exposure area, and the other half picture element is used as another exposure area. The orientation of the alignment film is different for each exposure region, which improves the viewing angle of the liquid crystal display panel. As a preferable form of the method for manufacturing the liquid crystal display panel, there is a form in which the exposure step irradiates light to the main surface of the photomask from an oblique direction with respect to the normal line of the main surface of the substrate to perform transmission and reflection.
Other configurations of the above-described photomask, exposure apparatus, and liquid crystal display panel manufacturing method of the present invention may be set as appropriate, and are not particularly limited as long as the effects of the present invention are not impaired.
実施形態においてカラーフィルタ(CF)が配置される基板は、CF基板ともいう。
以下に実施形態を掲げ、本発明を図面を参照して更に詳細に説明するが、本発明はこれらの実施形態のみに限定されるものではない。 In the embodiment, the substrate on which the thin film transistor element (TFT) is arranged is also referred to as a TFT substrate.
In the embodiment, the substrate on which the color filter (CF) is disposed is also referred to as a CF substrate.
Embodiments will be described below, and the present invention will be described in more detail with reference to the drawings. However, the present invention is not limited only to these embodiments.
図1は、実施形態1に係るフォトマスクの平面模式図である。
実施形態1に係るフォトマスク11においては、透過部15と透過部15との間の部分(従来のフォトマスクにおける遮光部)に光反射部(反射部17)が設けられ、透過部15と反射部17とが交互に設けられている。実施形態1においては、透過部15の長さと反射部17の長さ(図1に示した横の長さ)とは略同一であり、透過部15の幅と反射部17の幅(図1に示した縦の長さ)もまた略同一である。反射部17には、例えば光反射率の高い膜を貼ることにより形成することができ、例えばアルミニウム膜等を貼ることが好適である。配向膜の配向分割において重要な項目の1つは、半絵素毎に光の照射角度を反転させることである。実施形態1のフォトマスク11は、従来の遮光部に光反射の機能を付与することにより、配向分割のための露光プロセスにおける光源からの光の照射方向を2方向に分解する。これにより、配向膜の露光設備が巨大化する原因となっている照射の向きを変えるという工程を一度に実施することができる。なお、フォトマスク11の縁には遮光部13が設けられている。 Embodiment 1
FIG. 1 is a schematic plan view of a photomask according to the first embodiment.
In the
上述したように加工したフォトマスク11を基板30の主面に対して略垂直となるように配置して用いることで、フォトマスク11の主面に入射する紫外線21に対して透過と反射とを行う。 FIG. 2 is a schematic cross-sectional view showing a usage pattern of the photomask according to the first embodiment.
By using the
実施形態1に係る露光装置は、2つの露光ステージ部とその間の搬送ステージ部とから構成されており、図3はその一部を示す。各露光ステージ部に、複数のヘッドが設けられている。ヘッドの数は基板サイズによって異なるが、各ヘッドにそれぞれ露光用光源31(露光ヘッド部)、フォトマスク11及び追従用CCD(charge-coupled device)カメラ41等が設置される。フォトマスク11は、その主面が露光に供される基板面に対して略垂直となるように配置されている。また実施形態1においては基板30の背面(基板から見て露光用光源31の反対側)に画像検出用光源61(追従用光源ともいう。)が設けられ、画像検出用光源61からの光が基板30を通り、鏡を介してフォトマスク11を通り、CCDカメラ41に届く。フォトマスク微調整用のCCDカメラ41は、フォトマスクに垂直方向からであるとフォトマスクのスリットを覗くことができる点から、通常は、例えばこのように配置される。なお、CCDカメラ41が基板30のパターンエッジを捕捉でき、フォトマスク11のエッジを認識できるものである限りこの形態以外の形態を適宜採用することができる。なお、ステージ部71により基板30が搬送される。 FIG. 3 is a schematic diagram showing the exposure apparatus according to the first embodiment.
The exposure apparatus according to Embodiment 1 is composed of two exposure stage units and a transfer stage unit therebetween, and FIG. 3 shows a part thereof. Each exposure stage unit is provided with a plurality of heads. Although the number of heads varies depending on the substrate size, an exposure light source 31 (exposure head unit), a
実施形態1に係る露光装置においては、露光用光源31(紫外線21の照射方向)及びフォトマスク11が固定され、進行してくる基板30に対してフォトマスク11を追従させることで正確に紫外線を照射する。追従の動作は、基板30の任意のパターン画像を予め設定しておき、フォトマスク11に設けられている追従用パターンをCCDカメラ41で監視し、それら2つのパターンエッジの距離が常に一定となるようにフォトマスク11を常時微調整するものである。 (Operation of alignment film exposure device)
In the exposure apparatus according to the first embodiment, the exposure light source 31 (irradiation direction of the ultraviolet rays 21) and the
実施形態1に係る露光装置に設置されているCCDカメラ41によって基板30のパターンエッジを捕捉し、同時にフォトマスク11のエッジを認識し、両者の距離を一定に保持するようにフォトマスク11を微調整することで露光位置精度を保つ。実施形態1においては、微調整は画像処理回路を含む制御部51にて行う。そして、フォトマスク11の微調整をしながら露光用光源31により露光を行う。 (Substrate-Photomask tracking)
The
図5に示されるように、透過した紫外線(透過光23)を露光領域の一方に向けて照射し、反射した光(反射光25)を露光領域の他方に向けて照射する。例えば、フォトマスク11の透過部・反射部の長さ及び幅と光源からの紫外線の照射方向とを調整することにより、露光領域を適宜調整することができる。実施形態1においては、光源からの紫外線を通常の半絵素分の透過光と残りの半絵素分の反射光とに分解し、これらを同時に配向膜に照射することができる。なお、半絵素分の透過光が照射された露光領域に隣接する露光領域には、該半絵素分の透過光を透過したフォトマスク11に隣接して設けられているフォトマスク11からの反射光が照射され、これにより半絵素毎に透過光により露光された領域と反射光により露光された領域とが交互に配置されることになる。半絵素とは、例えばR(赤)、G(緑)又はB(青)等の、いずれかの単色を示す絵素の長さ方向又は幅方向で区切られた略半分の領域をいう。また、実施形態1においては、フォトマスク一つにより透過光が照射される領域と、反射光が半絵素ごとに照射される領域とは、略同一である。実施形態1においては、1回目の露光ステージ部71aにおいて、露光用光源31aからフォトマスク11を介して透過光23と反射光25とが交互に照射されてストライプ状の部分が生じるが、該部分どうしの間に、次の露光ステージ部71bで露光用光源31bからフォトマスク11を介して透過光23と反射光25とが照射される。また1回目の露光ステージで透過光23と反射光25とが照射されるストライプ状部分と次の露光ステージで透過光23と反射光25とが照射されるストライプ状部分とは、その形状・大きさが略同一である。なお、実施形態1では光配向に通常用いられる光である紫外線を用いているが、本発明の効果を発揮する限り、この他の波長領域の光を用いることが可能である。なお、実施形態1では、基板の流れ81に沿って基板30が搬送される。 FIG. 5 is a schematic diagram showing an exposure process of the exposure apparatus according to the first embodiment.
As shown in FIG. 5, the transmitted ultraviolet light (transmitted light 23) is irradiated toward one of the exposure areas, and the reflected light (reflected light 25) is irradiated toward the other of the exposure areas. For example, the exposure region can be adjusted as appropriate by adjusting the length and width of the transmissive and reflective portions of the
実施例1に係るフォトマスクの代わりに従来のフォトマスク(図6に示したもの)を用いて図7に示したように4つの露光ステージ171a、171b、171c、171dにより露光工程を行った。 Comparative Example 1
Using a conventional photomask (shown in FIG. 6) instead of the photomask according to Example 1, the exposure process was performed using four
13、113:遮光部
15、115:透過部
17:反射部
21、121:紫外線
23:透過光
25:反射光
30、130:基板
31、31a、31b、131a、131b、131c、131d、:露光用光源
41:CCDカメラ
51:制御部
61:画像検出用光源
71、71a、71b、171a、171b、171c、171d:ステージ部
81、181:基板の流れ 11, 111:
81, 181: Flow of substrate
Claims (6)
- 基板面内の露光領域毎に配向膜を露光するのに用いられるフォトマスクであって、
該フォトマスクは、フォトマスクの主面に入射する光に対して透過と反射とを行うものであり、透過した光を露光領域の一方に向けて照射し、反射した光を露光領域の他方に向けて照射することを特徴とするフォトマスク。 A photomask used to expose an alignment film for each exposure region in a substrate surface,
The photomask transmits and reflects light incident on the main surface of the photomask, irradiates the transmitted light toward one of the exposure areas, and applies the reflected light to the other exposure area. A photomask characterized by irradiating toward. - 前記フォトマスクは、その主面が露光に供される基板面に対して略垂直となるように配置して用いるものであることを特徴とする請求項1に記載のフォトマスク。 2. The photomask according to claim 1, wherein the photomask is used by being arranged so that a main surface thereof is substantially perpendicular to a substrate surface to be exposed.
- 請求項1又は2に記載のフォトマスク及び配向膜を露光する光を照射する光源を備えることを特徴とする露光装置。 An exposure apparatus comprising a light source for irradiating light for exposing the photomask and the alignment film according to claim 1.
- 一対の基板、基板間に設けられた液晶層及び基板の少なくとも一方の液晶層側の表面に設けられた配向膜を備える液晶表示パネルを製造するための方法であって、
該製造方法は、請求項3に記載の露光装置を用いて配向膜を露光する工程を含むことを特徴とする液晶表示パネルの製造方法。 A method for producing a liquid crystal display panel comprising a pair of substrates, a liquid crystal layer provided between the substrates, and an alignment film provided on the surface of at least one liquid crystal layer of the substrate,
The manufacturing method includes a step of exposing the alignment film using the exposure apparatus according to claim 3. - 一対の基板、基板間に設けられた液晶層及び基板の少なくとも一方の液晶層側の表面に設けられた配向膜を備える液晶表示パネルを製造するための方法であって、
該製造方法は、基板面内を2以上の露光領域に分割し、フォトマスクを透過した光によって露光領域の一方における配向膜を露光し、フォトマスクを反射した光によって露光領域の他方における配向膜を露光する露光工程を含むことを特徴とする液晶表示パネルの製造方法。 A method for producing a liquid crystal display panel comprising a pair of substrates, a liquid crystal layer provided between the substrates, and an alignment film provided on the surface of at least one liquid crystal layer of the substrate,
The manufacturing method divides the substrate surface into two or more exposure regions, exposes the alignment film in one of the exposure regions with light transmitted through the photomask, and aligns the alignment film in the other of the exposure regions with light reflected from the photomask. The manufacturing method of the liquid crystal display panel characterized by including the exposure process which exposes. - 前記露光工程は、基板主面の法線に対して斜め方向から光をフォトマスク主面に照射して透過と反射とを行うことを特徴とする請求項4又は5に記載の液晶表示パネルの製造方法。 6. The liquid crystal display panel according to claim 4, wherein the exposure step performs transmission and reflection by irradiating light on the photomask main surface from an oblique direction with respect to a normal line of the substrate main surface. Production method.
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CN106527055B (en) * | 2016-12-19 | 2018-03-30 | 武汉华星光电技术有限公司 | Exposure sources and exposure method |
CN108873486B (en) * | 2018-05-24 | 2020-11-27 | 南京中电熊猫液晶显示科技有限公司 | Mask plate for substrate photo-alignment and photo-alignment method |
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JPH10282499A (en) * | 1997-04-09 | 1998-10-23 | Agency Of Ind Science & Technol | Formation of oriented film and exposure device |
JP2000081621A (en) * | 1998-07-07 | 2000-03-21 | Fujitsu Ltd | Manufacture of liquid crystal display device |
JP2003043492A (en) * | 2001-08-01 | 2003-02-13 | Fujitsu Ltd | Liquid crystal display device, exposure device for alignment layer and treating method for alignment layer |
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