WO2011109145A2

WO2011109145A2 - Eu2+-activated aluminates nanobelts, whiskers, and powders, methods of making the same, and uses thereof

Info

Publication number: WO2011109145A2
Application number: PCT/US2011/024268
Authority: WO
Inventors: Zhengwei Pan; Feng Liu; Xufan Li
Original assignee: University of Georgia; University of Georgia Research Foundation Inc
Current assignee: University of Georgia; University of Georgia Research Foundation Inc
Priority date: 2010-03-01
Filing date: 2011-02-10
Publication date: 2011-09-09
Anticipated expiration: 2012-09-01
Also published as: WO2011109145A3; US20120319049A1; US9039933B2

Abstract

Embodiments of the present disclosure relate to visible luminescent phosphors, visible luminescent nanobelt phosphors, methods of making visible luminescent phosphors, methods of making visible luminescent nanobelt phosphors, mixtures of visible luminescent phosphors, methods of using visible luminescent phosphors, waveguides including visible luminescent phosphors, white light emitting phosphors, and the like.

Description

Eu -ACTIVATED ALUMINATES NANOBELTS, WHISKERS, AND POWDERS, METHODS OF MAKING THE SAME, AND USES THEREOF

CROSS-REFERENCE TO RELATED APPLICATIONS This application claims priority to U.S. provisional application entitled, "Eu²⁺- Activated Aluminates Nanobelts, Whiskers, and Powders, Methods of Making the Same, and Uses Thereof," having serial number 61/309, 140, filed on March 1 , 2010, which is entirely incorporated herein by reference.

GOVERNMENT SUPPORT

This invention(s) was made with government support under Grant No.: NSF

DMR0955908, which was awarded by the National Science Foundation. The government has certain rights in the invention(s).

BACKGROUND

Luminescent materials, which underwent almost 100 years' research and development, are currently indispensable in many important applications including fluorescent lighting, display devices, X-ray imaging, scintillators, and biological imaging [Adv. Funct. Mater. 13: 511 ; Yen, W. M., Weber, M. J. Inorganic Phosphors: Compositions, Preparation and Optical Properties. 2003, CRC Press LLC]. The luminescent materials used in these applications are generally in the form of powders. Recently, a series of oxide and nitride luminescent materials, such as ZnO, Sn0₂ and GaN, were made into one-dimensional (1 -D) nanowires and nanobelts that can be used as the building blocks for miniaturized nanophotonic circuits [Science 305 : 1269]. Such nanophotonic circuits have the functions of light creation, routing and detection, laying the ground for the fabrication of highly integrated light-based devices such as optical computers. Due to the limited optical performance of ZnO, Sn0₂ and GaN (such as limited luminescent colors and defect-related emission), however, further

development of nanowires circuitry needs new types of luminescent nanowires that should have rich luminescent colors and emit characteristic light. Rare-earth (RE)-activated phosphors with diversiform luminescence apparently meets this material need.

RE-activated phosphors are one of the most important families of luminescent materials. In RE-activated phosphors, the RE ions are usually doped into the hosts in either trivalent (RE³⁺) or divalent (RE²⁺) states. Most of the doped RE³⁺ ions have characteristic atomic-like emission spectra, which are attributed to the 4 ¹— >4 ¹ intraconfigurational transitions, due to the well-shielded 4f shell. The RE²⁺-activated phosphors, in contrast, typically exhibit broad emission bands, which are generally attributed to the parity-allowed 4f^~l5d→4f interconfigurational transitions whose wavelengths depend strongly on the host lattice.

RE²⁺-activated phosphors, particularly Eu²⁺-activated phosphors, are receiving increasing attention for their tunable band-like emission and broad excitation range, as well as their many important practical applications. For example, the emissions from Eu²⁺ ions in different hosts can be tuned from near-UV to red, while the excitation can be extended from blue light to even the X-ray region [Res. Rep. 23: 201]. The tunable and broad emission and excitation bands of the Eu²⁺-activated phosphors could fill up the spectral gaps in the emission spectrum of current white phosphor-converted LEDs (pc-LEDs) to improve their color quality for general illumination [Proc. SPIE 3938: 30]. The defect-related charge trapping phenomenon followed by normal

transitions in some Eu²⁺-activated phosphors has led to such important applications as information storage, long persistent luminescence, electroluminescence, and high-energy radiation detection. Besides the normal

transition, some Eu²⁺-doped alkaline earth compounds also show an extremely broad and red-shifted anomalous emission band originated from a impurity-trapped exciton (ITE) state, which is constructed by a hole on the impurity and a trapped conduction electron on the nearby lattice sites [Phys. Rev. B 32: 8465].

SUMMARY

Embodiments of the present disclosure relate to visible luminescent phosphors, methods of making visible luminescent phosphors, mixtures of visible luminescent phosphors, methods of using visible luminescent phosphors, waveguides including visible luminescent phosphors, white light emitting phosphors, and the like.

An embodiment of the visible luminescent phosphors includes, among others, an europium aluminate phosphor having a material having the formula: (M_zEui._zO)_x(Al₂0₃)_y, wherein M = Ba, Sr or a combination thereof; and 0 < z < 0.99, 1 < x < 5, and 1 < y < 5.

An embodiment of the method of making a phosphor nanobelt includes, among others, mixing an amount of each of EU2O3 and AI2O3 with an amount of either of SrO or BaO, ground it with an amount of graphite powder to form a mixture; and heating the mixture to about 1350-1550 °C for about 1-3 hours under about 1-50 Torr of flowing argon to form a phosphor nanobelt. An embodiment of the method of making a phosphor whisker, among others, includes: mixing an amount of each of Eu₂0₃ and AI2O3 with an amount of either of SrO or BaO, ground it with an amount of graphite powder and a catalyst selected from the group consisting of: Fe₂03, NiO, Si0₂, and Ge0₂, to fonn a mixture; and heating the mixture to about 1350-1550 °C for about 1-3 hours under about 1-50 Torr of flowing argon to form a phosphor whisker.

An embodiment of the method of making a phosphor powder, among others, includes: mixing an amount of each of EU2O3 and AI2O3 with an amount of either of SrO or BaO, ground it with an amount of graphite powder to form a mixture; and heating the mixture along side an amount of AI2O3 powder, to about 1350-1550 °C for about 1-3 hours under about 1 -50 Torr of flowing argon to form a phosphor powder.

An embodiment of the waveguide, among others, includes: a europium aluminate phosphor having a material of formula: (M_zEui_-zO)_x(Al₂0₃)_y, wherein M = Ba, Sr, or a combination thereof; and 0<z<0.99, l <x<5, and l<y<5.

An embodiment of the white light emitting phosphor mixture, among others, includes: (EuO)(Al₂0₃)₃, (Eu0)(Al₂0₃), and (EuO)₄(Al₂0₃)5.

An embodiment of the white light emitting phosphor mixture, among others, includes: (Sro_.9Euo.iO)(Al₂0₃)3, (Sr_{0 9}Eu₀ iO)(Al₂0₃), and (Sro 9Euo_.,0)₄(Al₂0₃)₅.

An embodiment of the white light emitting phosphor mixture, among others, includes: (Ba₀.7 Eu₀250)(A1₂0₃)₃, (Bao_.9₉Euo oiOXAi20₃), (Ba_0.99Euo_.oiO)₄(Al₂0₃)₅, and

(Bao_.75Euo_.250)4(Al₂0₃)₅.

The above brief description of various embodiments of the present disclosure is not intended to describe each embodiment or every implementation of the present disclosure. Rather, a more complete understanding of the disclosure will become apparent and appreciated by reference to the following description and claims in view of the accompanying drawings. Further, it is to be understood that other embodiments may be utilized and structural changes may be made without departing from the scope of the present disclosure.

BRIEF DESCRIPTION OF THE DRAWINGS

Further aspects of the present disclosure will be more readily appreciated upon review of the detailed description of its various embodiments, described below, when taken in conjunction with the accompanying drawings. FIG. 1 is the schematic diagram of a tube furnace system used to synthesize europium aluminate, strontium europium aluminate, and barium europium aluminate, nanobelts, whiskers and powders.

FIG. 2 shows the digital images of (a) blue, (b) green, and (c) orange luminescent europium aluminate nanobelts taken under a digital optical microscope with a 365 nm ultraviolet lamp irradiation.

FIG. 3 shows the digital images of (a) green and (b) orange luminescent europium aluminate powders taken under a digital optical microscope with a 365 nm ultraviolet lamp irradiation.

FIG. 4 shows the transmission electron microscope images of (a) blue, (b) green, and (c) orange luminescent europium aluminate nanobelts.

FIG. 5 shows the X-ray diffraction patterns of (a) blue luminescent EuAl₆Oi₀, (b) green luminescent EUAI2O4, and (c) orange luminescent EU4AI10O19 nanobelts and whiskers.

FIG. 6 shows the room-temperature excitation and emission spectra of (a) blue luminescent EuAleOio, (b) green luminescent EUAI2O4, and (c) orange luminescent EU4AI 10O19 nanobelts and powders.

FIG. 7 shows the light generation and propagation on individual (a) orange luminescent EU4AI10O10 nanobelt struck by a blue laser beam, (b) blue luminescent ΕιιΑΙβΟιο nanobelt struck by a focused X-ray beam, (c) green luminescent EUAI2O4 nanobelt struck by a focused x-ray beam, and (d) orange luminescent Eu₄Ali₀Oio nanobelt struck by a focused x- ray beam.

FIGS. 8A and B show the white light generated by the combination of the blue, green, and orange luminescent europium aluminates.

FIG. 9 shows the digital images of (a) blue, (b) green, and (c) yellow luminescent strontium europium aluminate nanobelts taken under a digital optical microscope with a 365 nm ultraviolet lamp irradiation.

FIG. 10 shows the digital images of (a) yellow and (b) green luminescent strontium europium aluminate powders taken under a digital optical microscope with a 365 nm ultraviolet lamp irradiation.

FIG. 1 1 shows the scanning electron microscope images of (a) blue, (b) green and (c) yellow luminescent strontium europium aluminate nanobelts and the transmission electron microscope images of (d) blue, (e) green and (f) yellow luminescent strontium europium aluminate nanobelts. FIG. 12 shows the scanning electron microscope images of Ge-catalyzed (a) blue and (b, c) yellow luminescent strontium europium aluminate whiskers.

FIG. 13 shows the X-ray diffraction patterns of (a) blue luminescent Sr_0.9Eu₀ iAl₆Oi₀, (b) green luminescent Sr₀.₉Euo_.iAl₂04, and (c) yellow luminescent Sr_{3 6}Euo 4Ali oOi ₉, nanobelts, whiskers, and powders.

FIG. 14 shows the room-temperature excitation and emission spectra of (a) blue luminescent Sro gEuo iAleCho, (b) green luminescent Sr_{0 9}Euo ιΑ1₂0₄, and (c) yellow luminescent Sr_{3 6}Euo 4Al]oOi9, nanobelts, whiskers, and powders.

FIG. 15 shows the digital images of (a) blue, (b) green, (c) yellow, and (d) red luminescent barium europium aluminate nanobelts taken under a digital optical microscope with a 365 nm ultraviolet lamp irradiation.

FIG. 16 shows the digital images of (a) yellow and (b) red luminescent barium europium aluminate powders taken under a digital optical microscope with a 365 nm ultraviolet lamp irradiation.

FIG. 17 shows the scanning electron microscope images of (a) blue, (b) green, (c) yellow, and (d) red luminescent, barium europium aluminate nanobelts.

FIG. 18 shows the X-ray diffraction patterns of (a) blue luminescent

Bao_.75Euo_.25Al₆Oio, (b) green luminescent Ba₀ 99Euo.cn AI2O4, (c) yellow luminescent

Ba₃ 96Euo o4 lioOi9, and (d) red luminescent BasEuAlioO] 9 nanobelts and powders.

FIG. 19 shows the room-temperature excitation and emission spectra of (a) blue luminescent Ba₀ 75EU0.25AI6O10, (b) green luminescent Bao 99Euo_.cn AI2O4, (c) yellow luminescent Ba₃ ^Euo _.04AI10O19, and (d) red luminescent Ba3EuAlioOi₉ nanobelts and powders.

FIG. 20 illustrates prototype white LED packages. FIGS. 20a to c illustrate digital images of three prototype white LED packages {Wl, W2 and W3) operated under forward bias current of 20 mA. FIG. 20d illustrates emission spectra of the three prototype white LED packages under forward bias current of 20 mA. FIG. 20e illustrates the chromaticity coordinates on CIE 1931 diagram.

DETAILED DESCRIPTION

Before the present disclosure is described in greater detail, it is to be understood that this disclosure is not limited to particular embodiments described, and as such may, of course, vary. It is also to be understood that the terminology used herein is for the purpose of describing particular embodiments only, and is not intended to be limiting, since the scope of the present disclosure will be limited only by the appended claims.

Where a range of values is provided, it is understood that each intervening value, to the tenth of the unit of the lower limit unless the context clearly dictates otherwise, between the upper and lower limit of that range and any other stated or intervening value in that stated range, is encompassed within the disclosure. The upper and lower limits of these smaller ranges may independently be included in the smaller ranges and are also encompassed within the disclosure, subject to any specifically excluded limit in the stated range. Where the stated range includes one or both of the limits, ranges excluding either or both of those included limits are also included in the disclosure.

Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this disclosure belongs. Although any methods and materials similar or equivalent to those described herein can also be used in the practice or testing of the present disclosure, the preferred methods and materials are now described.

All publications and patents cited in this specification are herein incorporated by reference as if each individual publication or patent were specifically and individually indicated to be incorporated by reference and are incorporated herein by reference to disclose and describe the methods and/or materials in connection with which the publications are cited. The citation of any publication is for its disclosure prior to the filing date and should not be construed as an admission that the present disclosure is not entitled to antedate such publication by virtue of prior disclosure. Further, the dates of publication provided could be different from the actual publication dates that may need to be independently confirmed.

As will be apparent to those of skill in the art upon reading this disclosure, each of the individual embodiments described and illustrated herein has discrete components and features which may be readily separated from or combined with the features of any of the other several embodiments without departing from the scope or spirit of the present disclosure. Any recited method can be carried out in the order of events recited or in any other order that is logically possible.

Embodiments of the present disclosure will employ, unless otherwise indicated, techniques of chemistry, physics, and the like, which are within the skill of the art.

The following examples are put forth so as to provide those of ordinary skill in the art with a complete disclosure and description of how to perform the methods and use the probes disclosed and claimed herein. Efforts have been made to ensure accuracy with respect to numbers (e.g., amounts, temperature, etc.), but some errors and deviations should be accounted for. Unless indicated otherwise, parts are parts by weight, temperature is in °C, and pressure is at or near atmospheric. Standard temperature and pressure are defined as 20 °C and 1 atmosphere.

Before the embodiments of the present disclosure are described in detail, it is to be understood that, unless otherwise indicated, the present disclosure is not limited to particular materials, reagents, reaction materials, manufacturing processes, or the like, as such can vary. It is also to be understood that the terminology used herein is for purposes of describing particular embodiments only, and is not intended to be limiting. It is also possible in the present disclosure that steps can be executed in different sequence where this is logically possible.

As used herein, the term "comprising," which is synonymous with "including" or "containing," is inclusive, open-ended, and does not exclude additional unrecited elements or method steps.

It must be noted that, as used in the specification and the appended claims, the singular forms "a," "an," and "the" include plural referents unless the context clearly dictates otherwise. Thus, for example, reference to "a compound" includes a plurality of compounds. In this specification and in the claims that follow, reference will be made to a number of terms that shall be defined to have the following meanings unless a contrary intention is apparent.

Discussion:

Embodiments of the present disclosure relate to visible luminescent phosphors, methods of making visible luminescent phosphors, mixtures of visible luminescent phosphors, methods of using visible luminescent phosphors, waveguides including visible luminescent phosphors, white light emitting phosphors, and the like. The visible luminescent phosphors (also referred to as "phosphors") of the present disclosure are rare-earth-activated

luminescent aluminates. In particular, embodiments of the phosphors disclosed herein are Eu²⁺-activated luminescent europium aluminates, Eu²⁺-activated luminescent strontium europium aluminates, and Eu²⁺-activated luminescent barium europium aluminates. The phosphors can be efficiently excited by a wide range of wavelengths from blue light to ultraviolet, X-ray, and to e-beam. Embodiments of the present disclosure are capable of emitting light in any visible color. The wavelength of emission can be adjusted by selectively adjusting the manufacturing parameters, such as temperature and/or pressure. In particular, the wavelength for emission bands associated with these phosphors is about 400 nm to 900 nm. The morphology of the visible luminescent phosphors can include forms such as a nanobelt, a whisker, a powder, or a combination thereof. Embodiments of the phosphors can be used in LEDs and nanophotonic circuitry (e.g., waveguides), for example.

In general, the phosphors of the present disclosure include a family of compositions generally described by: (M_zEui__zO)_x(Al₂03)_y, wherein M = Ba, Sr, or a combination thereof; and 0 < z < 0.99, 1 < x < 5, and 1 < y < 5.

In an embodiment, the Eu²⁺-activated luminescent europium aluminates (EAO) disclosed herein are (EuO)_x(Al₂03)_y, where 1 < x < 5 and 1 < y < 5, and in particular, x = 1 or 4 and y = 1 , 3, or 5. Under excitation, the Eu²⁺-activated luminescent europium aluminates can emit intense and broad bands in blue, green, and orange spectral regions, where the specific spectral regions can be selected by adjusting the manufacturing process. Specific embodiments of the europium aluminates can include: (EuO)(Al₂03)3 [i e., EuAleOio], (EuO)(Al₂0₃) [i.e., EuAl₂0₄], and (Eu0)4(Al₂O₃)₅ [i.e., Eu₄Ali₀Oi₉]. Under excitation at room temperature, EuA Oio, EuAl₂C>4, and EU4AI10O19 exhibit intense band emissions in blue (emission peak = about 425 nm, FWHM = 30 nm), green (emission peak = about 525 nm, FWHM = 88 nm), and orange (emission peak = about 645 nm, FWHM = 153 nm) spectral regions, respectively.

In an embodiment, the Eu²⁺-activated luminescent strontium europium aluminates (SEAO) disclosed herein are represented by the general formula: (Sr_zEui._zO)_x(Al₂0₃)_y, where 0.1 < z < 0.99, 1 < x <5, and 1 < y < 5. Under excitation, the Eu²⁺-activated luminescent strontium europium aluminates can emit intense and broad bands in blue, green, and yellow spectral regions, where the specific spectral regions can be selected by adjusting the manufacturing process. In an embodiment, the Eu²⁺-activated luminescent strontium europium aluminates can include: (Sr_0.9Euo iO)(Al₂0₃)3, (Sr₀.₉Euo ιΟ)(Α1₂θ₃), and

(Sro_.9Euo_.iO)4(Al₂0₃)₅, with respective luminescent colors (under excitation at room temperature) of blue (emission peak = about 426 nm, FWHM = 35 nm), green (emission peak = about 520 nm, FWHM = 87 nm), and yellow (emission peak = about 600 nm, FWHM = 144 nm).

In an embodiment, the Eu ⁺-activated luminescent barium europium aluminates (BEAO) disclosed herein are represented by the general formula: (Ba_zEui__zO)_x(Al₂03)_y, where 0.1 < z < 0.99, 1 < x < 5, and 1 < y < 5. Under excitation, the Eu²⁺-activated luminescent barium europium aluminates can emit intense and broad bands in blue, green, yellow and red spectral regions, where the specific spectral regions can be selected by adjusting the manufacturing process. In an embodiment, the Eu²⁺-activated luminescent barium europium aluminates can include: (Bao_.75Euo.250)(Al20₃)₄, (Bao_.99Euo _.01O AI2O₃), (Ba₀.99Euo οιΟ)4(Α1₂θ3)₅, and (Bao_.75Euo_.250)4(Al203)₅ with respective luminescent colors (under excitation at room temperature) of blue (emission peak = about 433 nm, FWHM = 44 nm), green (emission peak = about 500 nm, FWHM = 73 nm), yellow (emission peak = about 595 nm, FWHM = 131 nm) and red (emission peak = 732 nm, FWHM = 157 nm).

In an embodiment, the Eu²⁺-activated luminescent strontium europium aluminates (SEAO) disclosed herein are (Sr₂Eui._zO)_x(Al₂0₃)y, wherein 0.1 < z < 0.99, 1 < x < 5, and 1 < y < 5, and in particular, z = 0.9, x = 1 or 4, and y = 1, 3 or 5. Under excitation, the Eu²⁺- activated luminescent strontium europium aluminates can emit intense and broad bands in blue, green, and yellow spectral regions, where the specific spectral regions can be selected by adjusting the manufacturing process. In an embodiment, the Eu²⁺-activated luminescent strontium europium aluminates can include: (Sr₀ 9Eu₀ iO)(Al₂03)3 [i.e., Sro 9Eu_0.iAl₆Oi o], (Sr₀.₉Eu₀ iO)(Al₂0₃) [i.e., Sr₀.₉Euo iAl₂0₄], and (Sr₀.₉Euo iO)₄(Al₂0₃)₅ [i.e., Sr₃.₆Eu_0.4AlioOi9] . Under excitation at room temperature, Sro ₉Euo_.iAl60io, Sr₀.9Euo_.iAl₂0₄, and Sr3 ₆Euo_.4Ali₀Oi 9 emit intense and broadband emissions in blue (emission peak = about 426 nm, FWHM = 35 nm), green (emission peak = about 520 nm, FWHM = 87 nm), and yellow (emission peak = about 600 nm, FWHM = 144 nm) spectral regions, respectively.

In another embodiment, Eu²⁺-activated phosphors can be prepared by combining both BaO and SrO as alkaline-earth containing starting materials.

In an embodiment, the Eu²⁺-activated luminescent barium europium aluminates (BEAO) disclosed herein are (Ba_zEu₁__zO)_x(Al₂0₃)y, where 0.1 < z < 0.99, 1 < x <5, and 1 < y < 5, and in particular, z = 0.75 or 0.99, x = 1 or 4, and y = 1, 4 or 5. Under excitation, the Eu ⁺-activated luminescent barium europium aluminates can emit intense and broad bands in blue, green, yellow, and red spectral regions, where the specific spectral regions can be selected by adjusting the manufacturing process. In an embodiment, the barium europium aluminates can include: (Bao 75EU0 ₂5θ)(Α1₂θ3)₄ [i.e., Ba₀ 75EU0.25AI6O10],

(Ba_0.99Euo_.oiO)(Al₂0₃) [i.e., Ba_0.99Eu_0.oiAl₂0₄], (Ba₀.99Euo_.oiO)4(Al₂0₃)5 [i.e.,

Ba₃ 96EU0 04AI10O19], and (Bao 75Euo_.250)₄(Al₂03)5 [i.e., Ba₃EuAl|₀Oi9] . Under excitation, Bao.75Euo 25Al60i o, Bao.99Eu₀.oi Al204, Ba3_.9₆Euo_.o Al₁oOi9, and Ba₃EuAli oOi9 emit intense and broadband emissions in blue (emission peak = about 433 nm, FWHM = 44 nm), green (emission peak = about 500 nm, FWHM = 73 nm), yellow (emission peak = about 595 nm, FWHM = 131 nm) and red (emission peak = about 774 nm, FWHM = 218 nm) spectral regions, respectively. In an embodiment, the europium-activated luminescent nanobelts can be fabricated by a thermal evaporation-based technique in a well-controlled tube furnace system. A certain amount of the source oxides, such as Ε¾(¾, AI2O3, SrO, or BaO, are mixed and ground with graphite powder. The approximate ratios of the components and the approximate value of various processing conditions are described in Tables 1 , 3, and 4, where approximate is equivalent to the term "about", as defined herein. The mixture is then heated in a tube (e.g., an alumina tube) at about 1350- 1550 °C for about 1 -3 hours under about 1 -50 Torr of flowing inert gas (e.g., argon). The inert flow rate, e.g., argon flow rate, can be about 50- 150 standard cubic centimeter per minute (seem). The nanobelts are grown on the alumina substrates located at the downstream position of the processing tube. In an embodiment, the nanobelt has a rectangular cross-section. The nanobelt can have a length of about 10 micrometers to 2 millimeters, a width of about 200 to 600 nm, and a thickness of about 50 to 300 nm.

In an embodiment, the europium-activated luminescent whiskers disclosed herein are generally fabricated in the presence of a catalyst. The catalysts can include metals Fe and Ni, or semiconductors Ge and Si. Like the nanobelt, the whiskers are grown by thermal evaporation of a mixture of source oxides (e.g., Eu₂0₃, Α1₂(¾, SrO, and/or BaO), catalyst oxide (e.g., Fe₂03, NiO, Si0₂, or Ge0₂), and graphite powders. The approximate ratios of the components and the approximate value of various processing conditions are described in Tables 1 , 3 and 4, where approximate is equivalent to the term "about", as defined herein. The whiskers are grown on the alumina substrates located at the downstream position of the alumina processing tube via a mechanism called vapor-liquid-solid (Wagner, R. S., Ellis, W. C. (1964), "Vapor-liquid-solid mechanism of single crystal growth", Appl. Phys. Lett. 4: 89). The nanowhiskers are grown on the alumina substrates located at the downstream position of the processing tube. The nanowhiskers can have a diameter of about 0.5 to 5 micrometers and length of about 0.01 to 0.5 millimeters or up to about 1 millimeter.

In an embodiment, the europium-activated luminescent powders disclosed herein are fabricated by placing additional A1₂0₃ powder adjacent to the mixture of source oxides (e.g., EU2O3, A1₂0₃, SrO, or BaO) and graphite powders. The approximate ratios of the components and the approximate value of various processing conditions are described in Tables 1 , 3, and 4, where approximate is equivalent to the term "about", as defined herein. The vapor generated from the oxide-graphite mixture reacts with A1₂0₃ to form the luminescent powder at the A1₂0₃ site. Individually, each of the europium aluminates can be excited by a light source and then the europium aluminate emits energy at a wavelength, as mentioned above. The light source can be an e-beam (emission wavelength < 0.01 nm), an X-ray beam (about 0.01 - 10 nm), a vacuum-ultraviolet light source (e.g., about 112 - 200 nm from a deuterium lamp), an ultraviolet light source (e.g., about 250 - 390 nm from a xenon arc lamp), a laser beam (e.g., about 355 nm from a Nd-YAG laser or about 488 nm from an argon laser), LED (e.g., UV LED or blue LED), or a combination thereof.

When excited by an ultraviolet light (e.g., about 250-390 nm), the mixture of the three europium aluminates disclosed herein, i.e., blue-emitting EuALjOio, green-emitting EuAl₂04, and orange-emitting Eu₄AlioOi₉, can create a D65 daylight illuminant. The D65 illuminant corresponds roughly to a mid-day sun in Western Europe and North Europe, hence it is also called a daylight illuminant. According to the International Commission on Illumination (CIE) "D65 is intended to represent average daylight and has a correlated color temperature of approximately 6500 K". In a specific embodiment, the three europium aluminates disclosed herein can therefore be used as the phosphors for white pc-LEDs.

When excited by an ultraviolet light (e.g., about 250-390 nm), the mixture of the three strontium europium aluminates, i.e., blue-emitting Sro 9EU0 iAl₆Oi₀, green-emitting Sro_.gEuo 1AI2O4, and yellow-emitting Sr_{3 6}Euo.₄AlioOi9, can create a D65 daylight illuminant. In a specific embodiment, the three strontium europium aluminates disclosed herein can therefore be used as the phosphors for white LEDs in particular, pc-LEDs.

When excited by an ultraviolet light (e.g., about 250-390 nm), the mixture of the four barium europium aluminates, i.e., blue-emitting Bao 7sEuo_.25Al₆0io, green-emitting

Bao 99EU0 01AI2O4, yellow-emitting

and red-emitting Ba₃EuAlioOi₉, can create a D65 daylight illuminant. In a specific embodiment, the four barium europium aluminates disclosed herein can therefore be used as the phosphors for white LEDs in particular, pc-LEDs.

When excited by a blue LED (e.g., about 430-480 nm), the yellow-emitting

Ba₃ 96Eu₀ 04AI10O19 disclosed herein emits intense yellow light and the mixing of the blue and yellow light creates white light with color correlated temperature (CCT )< 4000 K and color rendering index (CRI) > 80, which is suitable for indoor illumination. The yellow-emitting Ba₃ 9₆Eu_0.o₄ lioOi9 disclosed herein alone can therefore be used as the phosphor for phosphor-conversion white LEDs (pc-white LEDs) in particular, for indoor illumination. When struck by a focused e-beam, an X-ray beam, or a laser beam, intense blue, green, orange, yellow, or red light is generated and the nanobelt or whisker can function as a waveguide for the propagation and routing of the generated light. Therefore embodiments of the present disclosure can be used as the building blocks for the construction of nanophotonic circuitry.

Since the Eu²⁺-activated luminescent aluminates disclosed herein can be excited by high energy sources (e.g., e-beam, X-ray and vacuum ultraviolet), the aluminates may be used as phosphors in plasma display panels and scintillating devices.

EXAMPLES

Now having described the embodiments of the present disclosure, in general, the examples describe some additional embodiments of the present disclosure. While embodiments of the present disclosure are described in connection with the examples and the corresponding text and figures, there is no intent to limit embodiments of the present disclosure to these descriptions. On the contrary, the intent is to cover all alternatives, modifications, and equivalents included within the spirit and scope of embodiments of the present disclosure.

Example 1

Method of Preparation of Luminescent Aluminates Nanobelts, Whiskers, and Powders

Synthesis of luminescent nanobelts: The synthesis is based on thermal evaporation of oxide-graphite powders under controlled conditions in a well-controlled tube furnace system (See FIG. 1 ). The furnace system contains a high-temperature tube furnace with a maximum temperature of 1700 °C, a high-purity alumina tube with OD of 1 .75 inch and ID of 1.5 inch, an argon gas supply and control system, a mechanical pump, and a pressure monitoring and control system. A certain amounts of oxide powders (EU2O3, AI2O3, SrO, or BaO) are mixed and ground with a certain amount (e.g., the approximate ratios of the components and the approximate value of various processing conditions are described in Tables 1 , 3, and 4, where approximate is equivalent to the term "about", as defined herein) of graphite powders. The mixture is placed in an alumina crucible that is then inserted into the center of a 1 .5 inch ID alumina tube. In this tube furnace system, the temperature, alumina tube chamber pressure, gas flow rate, and evaporation time can be precisely controlled and adjusted. Several alumina plates with sizes of about 5 -cm long and 1 -cm wide are placed at the downstream region of the alumina tube to act as the nanobelts growth substrates. High-purity argon is used as the carrier gas. Before the heating, the alumina tube is pumped to about 2^χ 10^"3 Torr. The furnace is then heated to the reaction temperature to start the growth. The preferred growth condition is as follows: furnace temperature, about 1350-1500 °C; argon flow rate, about 50-150 seem; reaction chamber pressure, about 1-50 Torr; evaporation time, about 1 -3 hours. After the reaction, the furnace is naturally cooled down to room temperature. The functions of the graphite powder are two fold: (i) carbothermal reduction of the high-melting point oxide powders to efficiently provide Eu-, A1-, ST-, or Ba-containing species and (ii) retaining a weakly reducing environment in the reaction chamber to make Eu ion in divalent state. The function of the argon gas is to carry the oxide vapor to the downstream region. The temperature gradient profile (top inset in FIG. 1 ; the profile was measured when the furnace temperature is set at 1450 °C) at the furnace hearth area (the area where the growth substrates are located and growth occurs) plays a role in controlling the product morphology, compositions, crystal structures ,and/or luminescence properties. For example, in growing europium aluminates nanobelts, the orange-emitting nanobelts are grown at about 1200-1400 °C, while the green-emitting nanobelts are formed at about 1000-1200 °C (see the bottom inset in FIG. 1 ; the image was taken under a 365 nm ultraviolet lamp illumination). Moreover, the properties of the products are also determined by the growth parameters, especially the relative ratio of the source powders, the argon flow rate, and the reaction chamber pressure.

Synthesis of luminescent whiskers: The synthesis of luminescent whiskers uses the same setup as depicted in FIG. 1 . The procedure and parameters are the same as those used for nanobelts synthesis, except that a small amount (e.g., about 1 mol%) of catalyst oxide powder (e.g., Fe₂(¾, NiO, Si0₂, or Ge0₂) is mixed into the oxide-graphite mixture. The whiskers are grown on the alumina substrates. The whisker is characteristic of having a catalyst particle at its tip.

Synthesis of luminescent powders: The synthesis of luminescent powders uses the same setup as depicted in FIG. 1. The procedure and parameters are the same as those used for nanobelts synthesis, except that a certain amount (e.g., about 0.1 g) of additional A1₂G^"3 powder is placed downstream adjacent to the oxide-graphite mixture (FIG. 1 ). The Al₂(¾ powder reacts with the vapor generated from the oxide-graphite mixture to form Eu²⁺- containing luminescent powders. The formation of Eu²⁺-containing aluminates powders on the A1₂0₃ powder site does not affect the growth of nanobelts and whiskers on the

downstream alumina substrates. Example 2

Preparation and Characterization of Europium Aiuminate Nanobelts, Whiskers and Powders

The europium aiuminate (EAO) nanobelts are prepared by the general method of Example 1. Based on the processing conditions (Table 1), three kinds of EAO nanobelts with luminescence colors (under excitation) of blue, green, and orange are fabricated. When the Eu₂0₃/Ai₂0₃/graphite ratios are about (0.1-l )/(0.1-0.4)/l , orange luminescent EAO nanobelts are formed in the about 1200-1400 °C region and green luminescent EAO nanobelts are grown in the about 1000-1200 °C region (FIG. 1). When more AI2O₃ powder is added into the source, the growth of the orange and green luminescent EAO nanobelts are suppressed; instead, a third type of blue luminescent EAO nanobelts are grown in the whole growth region from about 1400° to 1000 °C.

Table 1 . Processing parameters for blue-, green-, and orange-color emitting europium aluminates nanobelts.

In the conditions of growing green and orange luminescent EAO nanobelts, when additional AI2O3 powder is placed adjacent to the oxide-graphite mixture, orange luminescent EAO powder is formed at the AI2O3 site. When the argon flow rate is increased to about 100-200 seem, however, green luminescent EAO powder is formed.

FIG. 2 shows the digital images of (a) blue, (b) green, and (c) orange luminescent europium aiuminate nanobelts taken under a digital optical microscope with a 365 nm ultraviolet lamp irradiation. FIG. 3 shows the digital images of (a) green and (b) orange luminescent europium aiuminate powders taken under a digital optical microscope with a 365 nm ultraviolet lamp irradiation. FIG. 4 shows the transmission electron microscope images of (a) blue, (b) green, and (c) orange luminescent europium aiuminate nanobelts. The nanobelts have widths of about 200 to 600 nanometers, thicknesses of about 50 to 300 nm, and lengths of about 10 μηι to 2 mm.

Quantitative composition analyses using a energy-dispersive X-ray spectroscope (EDS) show that the compositions of the EAO can be represented by (EuO)_x(Al20₃)_y, wherein the x and y values vary for different luminescence color products. For the blue luminescent EAO, the x and y values are 1 and 3, respectively; accordingly, the composition of the blue luminescent EAO is (EuO)(Al₂03)3, i.e., EuAleOio. For the green luminescent EAO (including nanobelts and powders), the x and y values are 1 and 1 , respectively;

accordingly, the composition of the green luminescent EAO is (EuO)(Al₂03), i. e., EuAl₂0₄. For the orange luminescent EAO (including nanobelts and powders), the x and y values are 4 and 5, respectively; accordingly, the composition of the orange luminescent EAO is

(EuO)₄(Al₂0₃)₅, i.e., Eu₄Al₁₀Oi ₉.

FIG. 5 shows the X-ray diffraction patterns of (a) blue luminescent EuAl₆Oio, (b) green luminescent EUAI2O4 (including nanobelts and powders), and (c) orange luminescent EU4AI10O19 (including nanobelts and powders). The green luminescent EuAl₆Oio can be indexed using the isostructural monoclinic SrAl₂04 (PDF #74-0794). However, no corresponding isostructural phases are available for the blue luminescent EuAl₆Oio and orange luminescent EU4AI10O19 in the ICDD (International Centre for Diffraction Data) database and other commonly available database.

Complementary structural analyses using regular X-ray diffraction, synchrotron X-ray microdiffraction, high-resolution transmission electron microscopy, and electron diffraction show that the blue luminescent EuAleOio, green luminescent EuAl₂04, and orange luminescent Eu₄Ali₀Oi9 nanobelts have, respectively, tetragonal, monoclinic, and hexagonal crystal structures with new lattice parameters. Table 2 lists the structural information of the three europium aluminate nanobelts.

Table 2. Structural information of europium aluminate nanobelts

The EAO phosphors can be effectively excited by a wide range of wavelengths ranging from blue light to ultraviolet, X-ray, and to e-beam, and emit intense characteristic blue, green and orange lights of Eu²⁺ ions. FIG. 6 shows the room-temperature excitation and emission spectra of the (a) blue luminescent EuAl₆Oio, (b) green luminescent EUAI2O4, and (c) orange luminescent EU4AI10O19 nanobelts and powders. The emission spectra (solid line) are excited by 350 nm ultraviolet light. The excitation spectra (dashed line) are monitoring at 430 nm for blue luminescent EuAl₄Oio, 530 nm for green luminescent E11AI2O4, and 640 nm for orange luminescent Eu₄Ali₀Oi9. The blue luminescence with typical full-width at half-maximum (FWHM) is attributed to the localized 4f5d→4f transition of Eu²⁺ active centers. The green luminescence also originates from the 4f5d→4f transition of Eu²⁺ active centers but has a larger FWHM, probably due to the formation of a more delocalized Eu²⁺ chain in the host. The orange luminescence, in contrast, features an unusual, extremely wide emission band and large stokes shift that are characteristic of the anomalous impurity-trapped exciton (1TE) luminescence [J. Phys.: Condens. Mater. 15: 2645].

When individual EAO nanobelt or whisker is struck by a focused e-beam, an X-ray beam, or a laser beam, intense blue, green or orange light is generated, and the nanobelt or whisker can also function as a waveguide for the propagation and routing of the generated light.

FIG. 7 shows the light generation and propagation on individual (a) orange luminescent Eu₄Ali₀Oio nanobelt struck by a blue laser beam, (b) blue luminescent EuAl₆Oio nanobelt struck by a focused X-ray beam, (c) green luminescent EUAI2O4 nanobelt struck by a focused X-ray beam, and (d) orange luminescent Eu₄AlioOio nanobelt struck by a focused X-ray beam. The insert in FIG. 7a is the magnified image of the emitting tip of the nanobelts. The diameter of the X-ray beam is about 0.5μηι and the positions of the X-ray beam in FIG. 7b-d are indicated by white dashed circles. The images were taken when room light was off.

Since the emission bands of the blue, green, and orange luminescent EAO phosphors cover the whole visible region, the mixture of these three aluminates can provide phosphors for white LEDS, in particular, white light pc-LEDs.

FIG. 8a shows the emission spectra (dashed lines) of the blue, green, and orange luminescent europium aluminates excited by 360 nm ultraviolet light, as well as the combined emission spectrum (solid line) of these three emission bands. FIG. 8b is the related CIE chromaticity diagram, in which the three open triangles respectively represent the chromaticity points of the blue, green and orange luminescent aluminates, and the open circle represents the chromaticity point of the combined emission. The position of the combined emission is perfectly superposed with the position of the standard D65 daylight illuminant which has a correlated color temperature of about 6500 K. The solid curve is the black-body radiation locus.

Example 3

Preparation and Characterization of Strontium Europium Aluminate Nanobelts, Whiskers and Powders

The strontium europium aluminate (SEAO) nanobelts are prepared by the general method of Example 1. Based on the processing conditions (Table 3), three kinds of SEAO nanobelts with luminescence colors (under excitation) of blue, green, and yellow are fabricated. When the SrO/Eu₂0₃/Al₂0₃/graphite ratios are about (0.5-1 )/(0.1 - 1 )/(0. l-0.4)/l , yellow luminescent SEAO nanobelts are formed in the about 1200-1400 °C region and green luminescent SEAO nanobelts are grown in the about 1000-1200 °C region. When more A1₂0₃ powder is added into the source, the growth of the orange and green luminescent nanobelts are suppressed; instead, a third type of blue luminescent SEAO nanobelts are grown in the whole growth region from about 1400° to 1000 °C.

Table 3. Processing parameters for blue-, green-, and yellow-color emitting strontium europium aluminate nanobelts and whiskers.

In the conditions of growing SEAO nanobelts, when a small amount (e.g., about 1 mol%) of catalyst oxide such as Fe₂0₃, NiO, Si0₂, or Ge0₂ is added into the oxide-graphite mixture, straight SEAO whiskers will be grown with Fe, Ni, Si, or Ge as the catalyst.

In the conditions of growing green and yellow luminescent SEAO nanobelts, when additional A1₂0₃ powder is placed adjacent to the oxide-graphite mixture, yellow luminescent SEAO powder is formed at the A1₂0₃ site. When the argon flow rate is increased to about 100-200 seem, however, green luminescent SEAO powder is formed.

FIG. 9 shows the digital images of (a) blue, (b) green, and (c) yellow luminescent strontium europium aluminate nanobelts taken under a digital optical microscope with a 365 nm ultraviolet lamp irradiation. FIG. 10 shows the digital images of (a) green and (b) yellow luminescent strontium europium aluminate powders taken under a digital optical microscope with a 365 nm ultraviolet lamp irradiation.

FIG. 1 1 shows the scanning electron microscope images of (a) blue, (b) green and (c) yellow luminescent strontium europium aluminate nanobelts and the transmission electron microscope images of (d) blue, (e) green and (f) yellow luminescent strontium europium aluminate nanobelts. The nanobelts have widths of about 200 to 600 nanometers, thicknesses of about 50 to 300 nm, and lengths of about 10 μηι to 2 mm.

FIG. 12 shows the scanning electron microscope images of Ge-catalyzed (a) blue and (b, c) yellow luminescent strontium europium aluminate whiskers. The morphological feature of the catalytically grown whiskers is that each whisker terminates with a catalyst particle (see FIG. 12c). The whiskers have diameters of about 0.5 to 5 μιτι and length of up to about 1 mm.

Quantitative composition analyses using a energy-dispersive X-ray spectroscope (EDS) show that the compositions of the SEAO phosphors can be represented by (Sr_zEui_ _zO)_x(Al₂0₃)_y, wherein z is a value of around 0.9 and the x and y values vary for different luminescence color products. For the blue luminescent SEAO, the x and y values are 1 and 3, respectively; accordingly, the composition of the blue luminescent SEAO is

(Sr_0.9Eu_0.i O)(Al₂0₃)₃, i.e., Sro_.9Eu_0.iAl₆Oio. For the green luminescent SEAO (including nanobelts and powders), the x and y values are 1 and 1 , respectively; accordingly, the composition of the green luminescent SEAO is (Sro_.9Euo ₁OXAI₂O3), i.e., Sro.₉Euo_.iAl₂0₄. For the yellow luminescent SEAO (including nanobelts and powders), the x and y values are 4 and 5, respectively; accordingly, the composition of the yellow luminescent SEAO is (Sr_{0 9}Eu₀ iO)₄(Al₂0₃)₅, i.e., Sr₃.₆Euo.₄Alio0₁₉.

FIG. 13 shows the X-ray diffraction patterns of (a) blue luminescent Sro_.9Euo_.iAl₆Oio (including nanobelts and whiskers), (b) green luminescent Sro ₉Euo 1AI2O4 (including nanobelts, whiskers and powders), and (c) yellow luminescent Sr₃ 6Euo 4AI10O19 (including nanobelts, whiskers and powders). The patterns of the blue luminescent Sr₀.9EU0_.1 Al₆O₁₀, green luminescent Sro 9EU0.1AI2O4, and yellow luminescent Sr_3.6Euo.₄AlioOi9 are the same as the patterns of the blue luminescent EuAleOio, green luminescent EUAI2O4, and orange luminescent EU4AI10O19, respectively. The green luminescent Sro_.9Euo_.iAl₂0₄ can be indexed as monoclinic SrAl₂0₄ (PDF #74-0794). However, no corresponding isostructural phases are available for the blue luminescent Sr₀ 9Euo _.iAl₆Oio and yellow luminescent Sr₃ 6EU0_.4AI10O19 in the ICDD database and other commonly available database.

Complementary structural analyses using regular X-ray diffraction, synchrotron X-ray microdiffraction, high-resolution transmission electron microscopy, and electron diffraction show that the blue luminescent Sro_.9Euo_.iAl₆Oio, green luminescent Sr_0.9Euo 1 AI2O4, and yellow luminescent Sr3 6Euo 4AI10O19 nanobelts and whiskers have, respectively, tetragonal, monoclinic, and hexagonal crystal structures with new lattice parameters.

The SEAO phosphors can be effectively excited by a wide range of wavelengths ranging from blue light to ultraviolet, X-ray, and to e-beam, and emit intense characteristic blue, green and yellow lights of Eu²⁺ ions.

FIG. 14 shows the room-temperature excitation and emission spectra of the (a) blue luminescent Sro_.9Euo_.iAl₆Oio, (b) green luminescent Sro.9Euo_.iAl₂0₄, and (c) yellow luminescent Sr3 6EU0_.4AI10O19 nanobelts, whiskers and powders. The emission spectra (solid line) are excited by 350 nm ultraviolet light. The excitation spectra (dashed line) are monitoring at about 430 nm for blue luminescent Sro_.9Euo ιΑΙ_όΟιο, about 530 nm for green luminescent Sr₀.9Euo_.iAl₂0₄, and about 590 nm for yellow luminescent Sr3_.6Eu₀.4AlioOi 9.

Example 4

Preparation and Characterization of Barium Europium Aluminate Nanobelts,

Whiskers and Powders

The barium europium aluminate (BEAO) nanobelts are prepared by the general method of Example 1. The fabrication of the BEAO compounds is very sensitive to the processing parameters, especially to the chamber pressure and Ar flow rate. Based on the processing conditions (Table 4), four kinds of BEAO nanobelts with luminescence colors (under excitation) of blue, green, yellow, and red are fabricated. Under the typical conditions of BaO/Eu₂0₃/Al₂03/graphite mass ratios of about (0.5-l)/(0.1 -l )/(0.1-0.5)/l and evaporation temperatures of about 1350-1500 °C, red luminescent BEAO nanobelts are formed when pressure is about 15-50 Torr and Ar flow rate is about 50-60 seem, yellow luminescent BEAO nanobelts are formed when pressure is about 5-10 Torr and Ar flow rate is about 60-100 seem, and green luminescent BEAO nanobelts are formed when pressure is about 5-15 Torr and Ar flow rate is about 100-150 seem. When more A1₂0₃ powder is added into the source, blue luminescent BEAO nanobelts are obtained under a pressure about 5-15 Torr and argon flow rate of about 50-100 seem.

Table 4. Processing parameters for blue-, green-, yellow, and red-color emitting barium europium aluminate nanobelts and whiskers.

In the conditions of growing yellow and red luminescent BEAO nanobelts, when additional AI2O3 powder is placed adjacent to the oxide-graphite mixture, yellow and red luminescent BEAO powders are formed at the AI2O3 sites, respectively.

FIG. 1 5 shows the digital images of (a) blue, (b) green, (c) yellow, and (d) red luminescent barium europium aluminate nanobelts taken under a digital optical microscope with a 365 nm ultraviolet lamp irradiation.

FIG. 17 shows the scanning electron microscope images of (a) blue, (b) green, (c) yellow, and (d) red luminescent barium europium aluminate nanobelts. The nanobelts have widths of about 200 to 600 nanometers, thicknesses of about 50 to 300 nm, and lengths of about 10 μηι to 2 mm.

Quantitative composition analyses using a energy-dispersive X-ray spectroscope (EDS) show that the compositions of the BEAO phosphors can be represented by (Ba_zEui_ zO)_x(Al₂03)y, wherein z is either 0.75 (for blue and red luminescent BEAO) or 0.99 (for green and yellow luminescent BEAO), and the x and y values vary for different luminescence color products. For the blue luminescent BEAO, z = 0.75, x = 1 , and y = 4; accordingly, the composition of the blue luminescent BEAO is (Β%75Ευο.25θ)(Αΐ2θ₃)₄, i.e., Bao 75Euo 25Al60io. For the green luminescent BEAO, z = 0.99, x = 1 , and y = 1 ; accordingly, the composition of the green luminescent BEAO is (Bao.99Euo_.oiO)(Al₂0₃), i.e., Bao.₉9Euo oi Al₂04. For the yellow luminescent BEAO (including nanobelts and powders), z = 0.99, x = 4, and y = 5; accordingly, the composition of the yellow luminescent BEAO is (Bao_.99Euo_.oiO)₄(Al₂0₃)5, i.e., Ba3_.9₆Euo_.o₄AlioOi₉. For the red luminescent BEAO (including nanobelts and powders), z = 0.75, x = 4, and y = 5; accordingly, the composition of the yellow luminescent BEAO is (Ba₀.75Euo.₂50)4(Al₂0₃)5, i.e., Ba₃EuAl₁₀Oi₉.

FIG. 18 shows the X-ray diffraction patterns of (a) blue luminescent

Bao.75Euo 25Al₆0i o, (b) green luminescent Bao.99Euo oiAl20₄, (c) yellow luminescent

Ba_3.96Euo_.o4AlioOi9 (including nanobelts and powders), and (d) red luminescent Ba₃EuAl| ₀Oi 9 (including nanobelts and powders). The green luminescent Ba₀.99Euo 01AI2O4 can be indexed as hexagonal BaAl₂0₄ (PDF #72-387). However, no corresponding isostructural phases are available for the blue luminescent Bao_.75Euo_.2sAl₆0io, yellow luminescent Ba₃ 96EU0_.04AI10O19, and red luminescent Ba₃EuAlioOi₉ in the ICDD database and other commonly available database.

Complementary structural analyses using regular X-ray diffraction, synchrotron X-ray microdiffraction, high-resolution transmission electron microscopy, and electron diffraction show that the blue luminescent Bao_.7sEuo_.25Al₆Oio, yellow luminescent Ba_3.96Euo_.o₄Ali₀Oi₉, and red luminescent Ba₃EuAlioOi 9 nanobelts have, respectively, tetragonal, hexagonal, and hexagonal crystal structures with new lattice parameters.

The BEAO phosphors can be effectively excited by a wide range of wavelengths ranging from blue light to ultraviolet, X-ray, and to e-beam, and emit intense characteristic blue, green, yellow, and red lights of Eu²⁺ ions.

FIG. 19 shows the room-temperature excitation and emission spectra of (a) blue luminescent Bao 75Euo_.25Al60io, (b) green luminescent Bao_.9₉Euo 01 AI2O4, (c) yellow luminescent Ba^Euo cwAlioOig, and (d) red luminescent Ba₃EuAlioOi₉ nanobelts and powders. The emission spectra (solid line) are excited by 350 nm ultraviolet light. The excitation spectra (dashed line) are monitoring at 430 nm for blue luminescent

Bao 75EU0 25AI6O10, 500 nm for green luminescent Bao.₉9Euo.oiAl20₄, 580 nm for yellow luminescent Ba₃ 96EU0_.04AI10O19, and 730 nm for red luminescent Ba₃EuAlioOi9.

Since the emission bands of the blue, green, yellow, and red luminescent BEAO phosphors cover the whole visible region, the mixture of these four aluminates can provide phosphors for white light pc-LEDs. Significantly, because of the wide emission band of the yellow luminescent Ba₃ 96EU0 04AI10O19 (e.g., about 500 nm to 700 nm), exciting the yellow luminescent Ba_3.96Eu_0.o₄ l]oOi₉ alone with a 470 nm blue LED can generate warm white light with CCT < 4000 K and CRI > 80, which is suitable for indoor illumination. FIGS. 20a-c show three prototype white LED packages, labeled as Wl, W2 and W3, which were fabricated by encapsulating InGaN blue LED chip ( _max = 470 nm) with a layer of Ba₃ 9₆Euo.o4AlioOi9. The color qualities of the three white LED packages were tuned by adj usting the thickness of Ba₃ 96Euo_.o₄Al]oOi9 layer. The as-fabricated white LED packages emit bright white light under forward bias current of 20 mA. The white light gets warmer from Wl to W3. FIG. 20d shows the emission spectra of the three white LED packages. The spectra were normalized at 470 nm and were offset along y-axis for clarity. For each spectrum, two emission bands were clearly resolved at 470 nm and 580 nm, corresponding to the emission peaks of blue LED chip and Ba₃ 96EU0.04AI10O1 , respectively. The relative intensity of yellow emission band increases with the Ba_3.96Euo_.o4AlioOi9 layer thickness from Wl to W3, which results in white light with different color qualities. FIG. 20e shows the chromaticity coordinates of the three white lights on Commission Internationale de l'Eclairage (CIE). The three dots indicate the color points of the three white LED packages. The solid curve is the Planckian locus. The white light from Wl is located at (0.359, 0.359) with CCT = 4500 K and CRI = 81 . The white light from W2 is located at (0.388, 0.389) with CCT = 3900 K and CRI = 82. The white light from W3 is located at (0.415, 0.423) with CCT = 3500 K and CRI = 78. The color quality of W2 perfectly meets the demand for indoor illumination.

The complete disclosures of the patents, patent documents, and publications cited herein are incorporated by reference in their entirety as if each were individually incorporated. Various modifications and alterations to embodiments of this disclosure will become apparent to those skilled in the art without departing from the scope and spirit of this disclosure. It should be understood that this disclosure is not intended to be unduly limited by the illustrative embodiments and examples set forth herein and that such examples and embodiments are presented by way of example only with the scope of the disclosure intended to be limited only by the claims set forth herein as follows.

It should be noted that ratios, concentrations, amounts, and other numerical data may be expressed herein in a range format. It is to be understood that such a range format is used for convenience and brevity, and thus, should be interpreted in a flexible manner to include not only the numerical values explicitly recited as the limits of the range, but also to include all the individual numerical values or sub-ranges encompassed within that range as if each numerical value and sub-range is explicitly recited. To illustrate, a concentration range of "about 0.1 % to about 5%" should be interpreted to include not only the explicitly recited concentration of about 0.1 wt% to about 5 wt%, but also include individual concentrations (e.g., 1 %, 2%, 3%, and 4%) and the sub-ranges (e.g., 0.5%, 1.1 %, 2.2%, 3.3%, and 4.4%) within the indicated range. In an embodiment, the term "about" can include traditional rounding according to significant figures of the numerical value. In addition, the phrase "about 'x' to 'y'" includes "about 'x' to about 'y"\

Many variations and modifications may be made to the above-described embodiments. All such modifications and variations are intended to be included herein within the scope of this disclosure and protected by the following claims.

Claims

What is claimed is:

1. A europium aluminate phosphor comprising:

a material having the formula: (M_zEui_-zO)_x(Al₂0₃)_y, wherein M = Ba, Sr, or a combination thereof; and 0 < z < 0.99, 1 < x < 5, and 1 < y < 5.

2. The phosphor of claim 1 , wherein Eu is in a divalent state.

3. The phosphor of claim 1 , wherein the phosphor is in the form of one of the following: a nanobelt, a whisker, or a powder.

4. The phosphor of claim 1, wherein the phosphor has the characteristic that it is activated by a wavelength from a blue light wavelength to ultraviolet light wavelength, an X- ray wavelength, or an e-beam wavelength.

5. The phosphor of claim 1 , wherein the formula is (EuO)_x(Al 0₃)_y, wherein x = 1 or 4, y = 1 , 3, or 5.

6. The phosphor of claim 5, wherein the phosphor is (EuO)(Al₂0₃)3, wherein the phosphor has the characteristic that it emits intense blue light under excitation.

7. The phosphor of claim 6, wherein the phosphor has a tetragonal crystal structure.

8. The phosphor of claim 5, wherein the phosphor is (EuO)(Al₂0₃), wherein the phosphor has the characteristic that it emits intense and broad green light under excitation.

9. The phosphor of claim 5, wherein the phosphor is (EuO^A Ch^, wherein the phosphor has the characteristic that it emits intense and broad orange light under excitation.

10. The phosphor of claim 9, wherein the phosphor has a hexagonal crystal structure.

1 1. The phosphor of claim 1 , wherein the formula is (Sr_zEui__zO)_x(Al₂0₃)_y, wherein z is 0.9, x is 1 or 4, y is 1 , 3, or 5.

12. The phosphor of claim 11, wherein the phosphor is

wherein the phosphor has the characteristic that it emits intense blue light under excitation.

13. The phosphor of claim 12, wherein the phosphor has a tetragonal crystal structure.

14. The phosphor of claim 11 wherein the phosphor is (Sro gEuo 1 O AI2O₃), wherein the phosphor has the characteristic that it emits intense and broad green light under excitation.

15. The phosphor of claim 11 wherein the phosphor is (Sro 9EU0 ιΟ)₄(Α1₂θ₃)₅, wherein the phosphor has the characteristic that it emits intense and broad yellow light under excitation.

16. The phosphor of claim 15, wherein the phosphor has a hexagonal crystal structure.

17. The phosphor of claim 1 , wherein the formula is (Ba_zEui__zO)_x(Al₂0₃)_y, wherein z is 0.75 or 0.99, x is 1 or 4, y is 1 , 4, or 5.

18. The phosphor of claim 17, wherein the phosphor is (Ba₀ 75Euo.250)(Al₂0₃)₃, wherein the phosphor has the characteristic that it emits intense blue light under excitation.

19. The phosphor of claim 18, wherein the phosphor has a tetragonal crystal structure.

20. The phosphor of claim 17, wherein the phosphor is (Bao ₉₉Euo oi O)(Ai20₃), wherein the phosphor has the characteristic that it emits intense and broad green light under excitation.

21. The phosphor of claim 17, wherein the phosphor is (Bao Euo_.oi O)₄(Al₂03)5, wherein the phosphor has the characteristic that it emits intense and broad yellow light under excitation.

22. The phosphor of claim 21 , wherein the phosphor emits a white light when excited by a 430-480 nm blue LED.

23. The phosphor of claim 21 , wherein the phosphor has a hexagonal crystal structure.

24. The phosphor of claim 17 wherein the phosphor is (Bao 75Eu_0.250)4(Al₂0₃)₅, wherein the phosphor has the characteristic that it emits intense and broad red light under excitation.

25. The phosphor of claim 24, wherein the phosphor has a hexagonal crystal structure.

26. A method of making a phosphor nanobelt, comprising:

mixing an amount of each of Eu₂0₃ and AI2O3 with an amount of either of SrO or BaO, ground it with an amount of graphite powder to form a mixture; and

heating the mixture to about 1350-1550 °C for about 1 -3 hours under about 1-50 Torr of flowing argon to form a phosphor nanobelt.

27. The method of claim 26, wherein the phosphor nanobelt has a composition selected from the group consisting of: (EuO)(Al₂03)3, (EuO)(Al₂0₃) (EuO)4(Al₂0₃)₅, and a combination thereof.

28. The method of claim 26, wherein the phosphor nanobelt has a composition selected from the group consisting of: (Sro_.gEuo iO)(Al₂0₃)3, (Sr₀.9Euo _.1OXAI2O3),

(Sro_. Euo_.iO)4(Al₂0₃)₅, and a combination thereof.

29. The method of claim 26, wherein the phosphor nanobelt has a composition selected from the group consisting of: (Ba₀.75Eu_{0 25}0)(A1₂0₃)3, (Bao_.9 Euo_.oiO)(Al₂0₃),

(Bao.99Euo_.oiO)₄(Al₂0₃)5, (Bao 75Euo_.250)4(Al₂0₃)5, and a combination thereof.

30. A method of making a phosphor whisker, comprising:

mixing an amount of each of EU2O3 and A1₂0₃ with an amount of either of SrO or BaO, ground it with an amount of graphite powder and a catalyst selected from the group consisting of: Fe₂0₃, NiO, S1O2, and Ge0₂, to form a mixture; and

heating the mixture to about 1350-1550 °C for about 1-3 hours under about 1-50 Torr of flowing argon to form a phosphor whisker.

31. The method of claim 30, wherein the phosphor whisker has a composition selected from the group consisting of: (EuO)(Al₂0₃)3, (EuO)(Al₂0₃) (EuO)₄(Al₂03)5, and a combination thereof.

32. The method of claim 30, wherein the phosphor whisker has a composition selected from the group consisting of: (Sro gEuo iO)(Al₂0₃)₃, (Sr₀ 9Eu₀ i O)(Al₂0₃),

(Sr₀.9Eu₀ ιΟ)₄(Αΐ2θ₃)₅, and a combination thereof.

33. The method of claim 30, wherein the phosphor whisker has a composition selected from the group consisting of: (Ba₀ 75EU0 25θ)(Α1₂0₃)₃, (Ba₀ 99Eu_{0 0}iO)(Al₂O₃),

(Ba₀.99Euo oiO)4(Al₂0₃)5, (Ba₀.75E110 250)4(A1₂0₃)₅, and a combination thereof.

34. A method of making a phosphor powder, comprising:

mixing an amount of each of Eu₂0₃ and A1₂0₃ with an amount of either of SrO or BaO, ground it with an amount of graphite powder to form a mixture; and

heating the mixture along side an amount of A1₂0₃ powder, to about 1350-1550 °C for about 1 -3 hours under about 1 -50 Torr of flowing argon to form a phosphor powder.

35. The method of claim 34, wherein the phosphor powder has a composition selected from the group consisting of: (EuO)(Al₂0₃)₃, (EuO)(Al₂0₃) (EuO)₄(Al₂0₃)₅, and a combination thereof.

36. The method of claim 34, wherein the phosphor powder has a composition selected from the group consisting of: (SrogEuo iO)(Al₂0₃)₃, (Sr_{0 9}Eu₀ iO)(Al₂0₃),

(SrogEuo i O)4(Al₂0₃)5, and a combination thereof.

37. The method of claim 34, wherein the phosphor powder has a composition selected from the group consisting of: (Ba₀ 75Eu_{0 2}5O)(Al₂O₃)₃, (Ba₀ 99Eu₀ oi O)(Al₂0₃),

(Bao 99Eu₀ oiO)4(Al₂0₃)₅, (Bao 75Euo.2sO)4(Al₂0₃)₅, and a combination thereof.

38. A waveguide comprising,

a europium aluminate phosphor having a material of formula: (M_zEiii__zO)_x(Al₂0₃)_y, wherein M = Ba, Sr, or a combination thereof; and 0<z<0.99, l <x<5, and l<y<5.

39. The waveguide of claim 38, wherein the europium aluminate phosphor is in the form of a nanobelt or a whisker.

40. The waveguide of claim 38, wherein the waveguide is adapted to generate light, propagate light, and route light.

41. A white light emitting phosphor mixture comprising: (EuO)(Al₂0₃)₃, (EuO)(Al₂0₃), and (EuO)₄(Al₂0₃)₅.

42. A white light emitting phosphor mixture comprising: (Sr₀ EU0 ] 0)(A1₂0₃)₃, (Sr_{0 9}Eu₀ iO)(Al₂0₃), and (Sr_0.9Eu_a,O)4(Al₂O₃)₅.

43. A white light emitting phosphor mixture comprising: (Ba₀ 75EU0 25 ) (A1₂0₃)₃, (Ba_{0 99}Euo oi O)(Al₂0₃), (Bao_.ggEuo oiO)₄(Al₂0₃)₅, and (Ba_{0 75}Euo 250) (Al₂0₃)₅.

A white light emitting phosphor comprising (Ba₀ 99Euo oiO)4(Al₂0₃)5