WO2011107577A3 - Modified zinc salts of c4-8-alkane dicarboxylic acids and use thereof as polymerization catalysts - Google Patents

Modified zinc salts of c4-8-alkane dicarboxylic acids and use thereof as polymerization catalysts Download PDF

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Publication number
WO2011107577A3
WO2011107577A3 PCT/EP2011/053259 EP2011053259W WO2011107577A3 WO 2011107577 A3 WO2011107577 A3 WO 2011107577A3 EP 2011053259 W EP2011053259 W EP 2011053259W WO 2011107577 A3 WO2011107577 A3 WO 2011107577A3
Authority
WO
WIPO (PCT)
Prior art keywords
dicarboxylic acids
alkane dicarboxylic
polymerization catalysts
modified zinc
zinc salts
Prior art date
Application number
PCT/EP2011/053259
Other languages
German (de)
French (fr)
Other versions
WO2011107577A2 (en
Inventor
Tobias Heinz Steinke
Anna Katharina Ott
Hans-Helmut Görtz
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Priority to CN201180022211XA priority Critical patent/CN102869444A/en
Priority to EP11709662A priority patent/EP2542341A2/en
Publication of WO2011107577A2 publication Critical patent/WO2011107577A2/en
Publication of WO2011107577A3 publication Critical patent/WO2011107577A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/02—Aliphatic polycarbonates
    • C08G64/0208—Aliphatic polycarbonates saturated
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/41—Preparation of salts of carboxylic acids
    • C07C51/412—Preparation of salts of carboxylic acids by conversion of the acids, their salts, esters or anhydrides with the same carboxylic acid part
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C55/00—Saturated compounds having more than one carboxyl group bound to acyclic carbon atoms
    • C07C55/02—Dicarboxylic acids
    • C07C55/12—Glutaric acid
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C55/00—Saturated compounds having more than one carboxyl group bound to acyclic carbon atoms
    • C07C55/02—Dicarboxylic acids
    • C07C55/14—Adipic acid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/20—General preparatory processes
    • C08G64/32—General preparatory processes using carbon dioxide
    • C08G64/34—General preparatory processes using carbon dioxide and cyclic ethers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/14—Other (co) polymerisation, e.g. of lactides, epoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/34—Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
    • B01J2531/26—Zinc

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)

Abstract

The invention relates to zinc salts of C4-8-alkane dicarboxylic acids, which can be obtained by reacting C4-8-alkane dicarboxylic acids with surface-modified zinc oxide particles, wherein the surface-modified zinc oxide particles can be obtained by treating zinc oxide particles with organosilanes, silazanes and/or polysiloxanes and subsequently heat treating and/or UV irradiating the treated zinc oxide particles, and to the use thereof as polymerization catalysts for producing polyalkylene carbonates.
PCT/EP2011/053259 2010-03-05 2011-03-04 Modified zinc salts of c4-8-alkane dicarboxylic acids and use thereof as polymerization catalysts WO2011107577A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201180022211XA CN102869444A (en) 2010-03-05 2011-03-04 Modified zinc salts of C4-8-alkane dicarboxylic acids and use thereof as polymerization catalysts
EP11709662A EP2542341A2 (en) 2010-03-05 2011-03-04 Modified zinc salts of c4-8-alkane dicarboxylic acids and use thereof as polymerization catalysts

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP10155603.3 2010-03-05
EP10155603 2010-03-05

Publications (2)

Publication Number Publication Date
WO2011107577A2 WO2011107577A2 (en) 2011-09-09
WO2011107577A3 true WO2011107577A3 (en) 2011-12-29

Family

ID=44118868

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2011/053259 WO2011107577A2 (en) 2010-03-05 2011-03-04 Modified zinc salts of c4-8-alkane dicarboxylic acids and use thereof as polymerization catalysts

Country Status (3)

Country Link
EP (1) EP2542341A2 (en)
CN (1) CN102869444A (en)
WO (1) WO2011107577A2 (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101640244B1 (en) 2013-10-30 2016-07-15 주식회사 엘지화학 Preparation method of organic zinc catalyst and poly(alkylene carbonate) resin
KR101639363B1 (en) 2013-11-04 2016-07-14 주식회사 엘지화학 Preparation method of organic zinc catalyst
US9732187B2 (en) 2013-11-18 2017-08-15 Lg Chem, Ltd. Manufacturing method of polyalkylene carbonate resin
KR101729300B1 (en) 2014-06-13 2017-04-21 주식회사 엘지화학 Organic zinc catalyst, preparation method of the catalyst and production method of poly(alkylene carbonate) resin over the catalyst
KR101870315B1 (en) 2015-03-09 2018-06-22 주식회사 엘지화학 Organic zinc catalyst, preparation method of the catalyst, and preparation method of poly(alkylene carbonate) resin using the catalyst
KR20220125214A (en) 2020-01-08 2022-09-14 스미토모 세이카 가부시키가이샤 organic zinc catalyst

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003029325A1 (en) * 2001-09-27 2003-04-10 Basf Aktiengesellschaft Method for producing aliphatic polycarbonates
EP1508599A1 (en) * 2003-08-22 2005-02-23 Degussa AG Surface-modified zinc oxide
WO2006092442A1 (en) * 2005-03-03 2006-09-08 Grillo-Werke Ag Surface-modified zinc oxide particles

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4960862A (en) * 1989-03-31 1990-10-02 Air Products And Chemicals, Inc. Regeneration of metallo-organic catalyst for carbon dioxide-epoxide copolymerization
US4943677A (en) * 1989-06-08 1990-07-24 Air Products And Chemicals, Inc. Making poly(alkylene carbonates) of controlled molecular weight
JPH06509321A (en) 1991-02-05 1994-10-20 サンスマート　インコーポレイテッド Visually transparent ultraviolet solar screening agent and method of making the same
DE19737547A1 (en) * 1997-08-28 1999-03-04 Buna Sow Leuna Olefinverb Gmbh Catalyst system for the production of polyalkylene carbonates
DE10212680A1 (en) 2002-03-22 2003-10-09 Degussa Nanoscale zinc oxide, process for its production and use

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003029325A1 (en) * 2001-09-27 2003-04-10 Basf Aktiengesellschaft Method for producing aliphatic polycarbonates
EP1508599A1 (en) * 2003-08-22 2005-02-23 Degussa AG Surface-modified zinc oxide
WO2006092442A1 (en) * 2005-03-03 2006-09-08 Grillo-Werke Ag Surface-modified zinc oxide particles

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
GERRIT LUINSTRA: "Poly(Propylene Carbonate), Old Copolymers of Propylene Oxide and Carbon Dioxide with New Interests: Catalysis and Material Properties", POLYMER REVIEWS, vol. 48, no. 1, 1 January 2008 (2008-01-01), pages 192 - 219, XP055007274, ISSN: 1558-3724, DOI: 10.1080/15583720701834240 *
REE M ET AL: "New findings in the catalytic activity of zinc glutarate and its application in the chemical fixation of CO2 into polycarbonates and their derivatives", CATALYSIS TODAY, ELSEVIER, NL, vol. 115, no. 1-4, 30 June 2006 (2006-06-30), pages 134 - 145, XP025116549, ISSN: 0920-5861, [retrieved on 20060630], DOI: 10.1016/J.CATTOD.2006.02.068 *

Also Published As

Publication number Publication date
EP2542341A2 (en) 2013-01-09
CN102869444A (en) 2013-01-09
WO2011107577A2 (en) 2011-09-09

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