WO2011097468A3 - Acid separation by acid retardation on an ion exchange resin in an electrochemical system - Google Patents

Acid separation by acid retardation on an ion exchange resin in an electrochemical system Download PDF

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Publication number
WO2011097468A3
WO2011097468A3 PCT/US2011/023730 US2011023730W WO2011097468A3 WO 2011097468 A3 WO2011097468 A3 WO 2011097468A3 US 2011023730 W US2011023730 W US 2011023730W WO 2011097468 A3 WO2011097468 A3 WO 2011097468A3
Authority
WO
WIPO (PCT)
Prior art keywords
acid
ion exchange
exchange resin
electrochemical system
retardation
Prior art date
Application number
PCT/US2011/023730
Other languages
French (fr)
Other versions
WO2011097468A2 (en
Inventor
Ryan J. Gilliam
Nigel Antony Knott
Michael Kostowskyj
Original Assignee
Calera Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US12/952,665 external-priority patent/US20110079515A1/en
Application filed by Calera Corporation filed Critical Calera Corporation
Publication of WO2011097468A2 publication Critical patent/WO2011097468A2/en
Publication of WO2011097468A3 publication Critical patent/WO2011097468A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Treatment Of Water By Ion Exchange (AREA)

Abstract

A method and system of separating an acid from an acid-salt solution produced in an electrochemical system using an ion exchange resin bed, by processing the acid-salt solution through the ion exchange resin bed such that the acid is retarded at the bottom of the bed and a de-acidified salt solution is recovered from the top of the bed. After removing the salt solution from the bed, the acid is recovered by back-flushing the resin bed with water.
PCT/US2011/023730 2010-02-05 2011-02-04 Acid separation by acid retardation on an ion exchange resin in an electrochemical system WO2011097468A2 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US30187810P 2010-02-05 2010-02-05
US61/301,878 2010-02-05
US12/952,665 2010-11-23
US12/952,665 US20110079515A1 (en) 2009-07-15 2010-11-23 Alkaline production using a gas diffusion anode with a hydrostatic pressure

Publications (2)

Publication Number Publication Date
WO2011097468A2 WO2011097468A2 (en) 2011-08-11
WO2011097468A3 true WO2011097468A3 (en) 2013-07-18

Family

ID=44356084

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2011/023730 WO2011097468A2 (en) 2010-02-05 2011-02-04 Acid separation by acid retardation on an ion exchange resin in an electrochemical system

Country Status (1)

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WO (1) WO2011097468A2 (en)

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KR20100023813A (en) 2007-05-24 2010-03-04 칼레라 코포레이션 Hydraulic cements comprising carbonate compounds compositions
US20100239467A1 (en) 2008-06-17 2010-09-23 Brent Constantz Methods and systems for utilizing waste sources of metal oxides
KR20100105860A (en) 2007-12-28 2010-09-30 칼레라 코포레이션 Methods of sequestering co2
JP5373079B2 (en) 2008-07-16 2013-12-18 カレラ コーポレイション Use of CO2 in electrochemical systems
US9061940B2 (en) 2008-09-30 2015-06-23 Calera Corporation Concrete compositions and methods
US7815880B2 (en) 2008-09-30 2010-10-19 Calera Corporation Reduced-carbon footprint concrete compositions
US8869477B2 (en) 2008-09-30 2014-10-28 Calera Corporation Formed building materials
AU2009287462B2 (en) 2008-09-30 2011-10-06 Arelac, Inc. CO2-sequestering formed building materials
US9133581B2 (en) 2008-10-31 2015-09-15 Calera Corporation Non-cementitious compositions comprising vaterite and methods thereof
CN101918614A (en) 2009-02-10 2010-12-15 卡勒拉公司 With hydrogen and electro catalytic electrode low-voltage alkaline production
US8883104B2 (en) 2009-03-02 2014-11-11 Calera Corporation Gas stream multi-pollutants control systems and methods
US8906156B2 (en) 2009-12-31 2014-12-09 Calera Corporation Cement and concrete with reinforced material
CA2785143C (en) 2009-12-31 2014-10-14 Calera Corporation Methods and compositions using calcium carbonate
WO2012149173A2 (en) 2011-04-28 2012-11-01 Calera Corporation Methods and compositions using calcium carbonate and stabilizer
US8691175B2 (en) 2011-04-28 2014-04-08 Calera Corporation Calcium sulfate and CO2 sequestration
US9200375B2 (en) 2011-05-19 2015-12-01 Calera Corporation Systems and methods for preparation and separation of products
SA112330516B1 (en) 2011-05-19 2016-02-22 كاليرا كوربوريشن Electrochemical hydroxide systems and methods using metal oxidation
WO2013049401A2 (en) 2011-09-28 2013-04-04 Calera Corporation Cement and concrete with calcium aluminates
TWI633206B (en) 2013-07-31 2018-08-21 卡利拉股份有限公司 Electrochemical hydroxide systems and methods using metal oxidation
WO2015164589A1 (en) 2014-04-23 2015-10-29 Calera Corporation Methods and systems for utilizing carbide lime or slag
US9957621B2 (en) 2014-09-15 2018-05-01 Calera Corporation Electrochemical systems and methods using metal halide to form products
CA2963981A1 (en) 2014-11-10 2016-05-19 Calera Corporation Measurement of ion concentration in presence of organics
WO2016149365A1 (en) 2015-03-16 2016-09-22 Calera Corporation Ion exchange membranes, electrochemical systems, and methods
EP3767011A1 (en) 2015-10-28 2021-01-20 Calera Corporation Electrochemical, halogenation, and oxyhalogenation systems and methods
WO2017147388A1 (en) 2016-02-25 2017-08-31 Calera Corporation On-line monitoring of process/system
US10847844B2 (en) 2016-04-26 2020-11-24 Calera Corporation Intermediate frame, electrochemical systems, and methods
US10619254B2 (en) 2016-10-28 2020-04-14 Calera Corporation Electrochemical, chlorination, and oxychlorination systems and methods to form propylene oxide or ethylene oxide
US10556848B2 (en) 2017-09-19 2020-02-11 Calera Corporation Systems and methods using lanthanide halide
CN107937446A (en) * 2017-12-22 2018-04-20 天津大学 A kind of technique using maize straw as waste ethanol
CN108220486A (en) * 2017-12-28 2018-06-29 天津大学 A kind of method for detaching saccharic acid using sour Retarding resin
US10590054B2 (en) 2018-05-30 2020-03-17 Calera Corporation Methods and systems to form propylene chlorohydrin from dichloropropane using Lewis acid
WO2021173784A1 (en) 2020-02-25 2021-09-02 Arelac, Inc. Methods and systems for treatment of limestone to form vaterite
CN116018195A (en) 2020-06-30 2023-04-25 艾瑞莱克公司 Method and system for forming vaterite from calcined limestone using an electric kiln

Citations (7)

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US3067007A (en) * 1960-01-27 1962-12-04 Dow Chemical Co Separation of strong polybasic acids from their salts
US4889633A (en) * 1987-08-05 1989-12-26 Ciba-Geigy Corporation Process for treating aqueous fluids containing organic compounds and salts of polyvalent inorganic acids
US5587083A (en) * 1995-04-17 1996-12-24 Chemetics International Company Ltd. Nanofiltration of concentrated aqueous salt solutions
US5792441A (en) * 1996-10-11 1998-08-11 Pulp And Paper Research Institute Of Canada Fixed-resin bed technologies for the treatment of the chlorine dioxide generator effluent and feeds stream
US20090308760A1 (en) * 2004-12-23 2009-12-17 Diamond Innovations, Inc. Electrochemical dissolution of conductive composites
US20090317488A1 (en) * 2006-10-03 2009-12-24 Tris Pharma, Inc Formulations Containing an Ionic Mineral-Ion Exchange Resin Complex and Uses Thereof
WO2010008896A1 (en) * 2008-07-16 2010-01-21 Calera Corporation Low-energy 4-cell electrochemical system with carbon dioxide gas

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3067007A (en) * 1960-01-27 1962-12-04 Dow Chemical Co Separation of strong polybasic acids from their salts
US4889633A (en) * 1987-08-05 1989-12-26 Ciba-Geigy Corporation Process for treating aqueous fluids containing organic compounds and salts of polyvalent inorganic acids
US5587083A (en) * 1995-04-17 1996-12-24 Chemetics International Company Ltd. Nanofiltration of concentrated aqueous salt solutions
US5792441A (en) * 1996-10-11 1998-08-11 Pulp And Paper Research Institute Of Canada Fixed-resin bed technologies for the treatment of the chlorine dioxide generator effluent and feeds stream
US20090308760A1 (en) * 2004-12-23 2009-12-17 Diamond Innovations, Inc. Electrochemical dissolution of conductive composites
US20090317488A1 (en) * 2006-10-03 2009-12-24 Tris Pharma, Inc Formulations Containing an Ionic Mineral-Ion Exchange Resin Complex and Uses Thereof
WO2010008896A1 (en) * 2008-07-16 2010-01-21 Calera Corporation Low-energy 4-cell electrochemical system with carbon dioxide gas

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Publication number Publication date
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