WO2011097222A3 - Processes for producing ethanol from acetaldehyde - Google Patents
Processes for producing ethanol from acetaldehyde Download PDFInfo
- Publication number
- WO2011097222A3 WO2011097222A3 PCT/US2011/023331 US2011023331W WO2011097222A3 WO 2011097222 A3 WO2011097222 A3 WO 2011097222A3 US 2011023331 W US2011023331 W US 2011023331W WO 2011097222 A3 WO2011097222 A3 WO 2011097222A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- acetaldehyde
- processes
- producing ethanol
- feed stream
- ethanol
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/16—Clays or other mineral silicates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
- B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
- B01J23/626—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
- C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
- C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Processes for forming an ethanol mixture by hydrogenating an acetaldehyde feed stream in the presence of a catalyst. The acetaldehyde feed stream comprises acetaldehyde and at least one of acetic acid and ethanol. Preferably the acetaldehyde feed stream is a by-product stream from a vinyl acetate synthesis process.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201180001857.XA CN102413921B (en) | 2010-02-02 | 2011-02-01 | By the method for acetaldehyde production ethanol |
EP11703342A EP2531292A2 (en) | 2010-02-02 | 2011-02-01 | Processes for producing ethanol from acetaldehyde |
Applications Claiming Priority (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US30081510P | 2010-02-02 | 2010-02-02 | |
US61/300,815 | 2010-02-02 | ||
US33269910P | 2010-05-07 | 2010-05-07 | |
US61/332,699 | 2010-05-07 | ||
US12/852,269 | 2010-08-06 | ||
US12/852,269 US8304586B2 (en) | 2010-02-02 | 2010-08-06 | Process for purifying ethanol |
US12/915,625 US8344186B2 (en) | 2010-02-02 | 2010-10-29 | Processes for producing ethanol from acetaldehyde |
US12/915,625 | 2010-10-29 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2011097222A2 WO2011097222A2 (en) | 2011-08-11 |
WO2011097222A3 true WO2011097222A3 (en) | 2011-10-06 |
Family
ID=45915413
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2011/023331 WO2011097222A2 (en) | 2010-02-02 | 2011-02-01 | Processes for producing ethanol from acetaldehyde |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP2531292A2 (en) |
CN (1) | CN102413921B (en) |
SA (1) | SA111320169B1 (en) |
WO (1) | WO2011097222A2 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8846988B2 (en) | 2010-07-09 | 2014-09-30 | Celanese International Corporation | Liquid esterification for the production of alcohols |
US9000233B2 (en) | 2011-04-26 | 2015-04-07 | Celanese International Corporation | Process to recover alcohol with secondary reactors for hydrolysis of acetal |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8304586B2 (en) * | 2010-02-02 | 2012-11-06 | Celanese International Corporation | Process for purifying ethanol |
US8907141B2 (en) | 2011-04-26 | 2014-12-09 | Celanese International Corporation | Process to recover alcohol with secondary reactors for esterification of acid |
CN103739445B (en) * | 2013-12-02 | 2016-06-29 | 江苏苏博特新材料股份有限公司 | A kind of preparation method of allyl alcohol |
CN107285997B (en) * | 2016-03-30 | 2022-04-22 | 长春美禾科技发展有限公司 | Method for improving ultraviolet transmittance of ethylene glycol |
WO2022149090A1 (en) * | 2021-01-07 | 2022-07-14 | Superbrewed Food, Inc. | Methods of producing low-acetal ethanol |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4398039A (en) * | 1981-05-18 | 1983-08-09 | The Standard Oil Company | Hydrogenation of carboxylic acids |
US5243095A (en) * | 1992-04-24 | 1993-09-07 | Engelhard Corporation | Hydrogenation catalyst, process for preparing and process for using said catalyst |
US6049008A (en) * | 1995-06-15 | 2000-04-11 | Engelhard Corporation | Shaped hydrogenation catalyst and processes for their preparation and use |
Family Cites Families (39)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2425389A (en) | 1947-08-12 | Manufacture of vinyl esters | ||
US2859241A (en) | 1958-11-04 | Production of vinyl esters | ||
US2549416A (en) | 1948-02-04 | 1951-04-17 | Du Pont | Preparation of alcohols |
US2882244A (en) | 1953-12-24 | 1959-04-14 | Union Carbide Corp | Molecular sieve adsorbents |
US3130007A (en) | 1961-05-12 | 1964-04-21 | Union Carbide Corp | Crystalline zeolite y |
US4052467A (en) | 1967-11-08 | 1977-10-04 | Phillips Petroleum Company | Catalytic reduction of aldehydes to alcohols |
CH576926A5 (en) | 1973-03-21 | 1976-06-30 | Hoffmann La Roche | |
US4048096A (en) | 1976-04-12 | 1977-09-13 | E. I. Du Pont De Nemours And Company | Surface impregnated catalyst |
US4429056A (en) * | 1980-04-21 | 1984-01-31 | National Distillers And Chemical Corporation | Manufacture of oxygenated compounds |
US4451677A (en) | 1981-08-20 | 1984-05-29 | Davy Mckee (London) Limited | Multistage aldehyde hydrogenation |
US5004845A (en) | 1981-08-20 | 1991-04-02 | Davy Mckee (London) Limited | Hydrogenation of aldehydes |
US4426541A (en) | 1982-03-16 | 1984-01-17 | Exxon Research & Engineering Co. | Process for production of aliphatic alcohols |
US5001259A (en) | 1984-05-03 | 1991-03-19 | Hoechst Celanese Corporation | Methanol carbonylation process |
US5026908A (en) | 1984-05-03 | 1991-06-25 | Hoechst Celanese Corporation | Methanol carbonylation process |
US5144068A (en) | 1984-05-03 | 1992-09-01 | Hoechst Celanese Corporation | Methanol carbonylation process |
US4626604A (en) | 1985-09-11 | 1986-12-02 | Davy Mckee (London) Limited | Hydrogenation process |
CA1299195C (en) | 1986-06-16 | 1992-04-21 | G. Paull Torrence | Addition of hydrogen to carbon monoxide feed gas in producing acetic acid by carbonylation of methanol |
US4876402A (en) | 1986-11-03 | 1989-10-24 | Union Carbide Chemicals And Plastics Company Inc. | Improved aldehyde hydrogenation process |
US4762817A (en) | 1986-11-03 | 1988-08-09 | Union Carbide Corporation | Aldehyde hydrogenation catalyst |
DE4025245A1 (en) | 1990-08-09 | 1992-02-13 | Huels Chemische Werke Ag | METHOD FOR PRODUCING SATURATED ALCOHOLS FROM ALDEHYDES |
US5185308A (en) | 1991-05-06 | 1993-02-09 | Bp Chemicals Limited | Catalysts and processes for the manufacture of vinyl acetate |
US5599976A (en) | 1995-04-07 | 1997-02-04 | Hoechst Celanese Corporation | Recovery of acetic acid from dilute aqueous streams formed during a carbonylation process |
DE19613791C2 (en) | 1996-04-04 | 2002-01-31 | Celanese Chem Europe Gmbh | Catalyst, process for its production and process for the production of vinyl acetate |
US5691267A (en) | 1996-04-16 | 1997-11-25 | Hoechst Celanese Corporation | Two step gold addition method for preparing a vinyl acetate catalyst |
IN192600B (en) | 1996-10-18 | 2004-05-08 | Hoechst Celanese Corp | |
DE19734974A1 (en) | 1997-08-13 | 1999-02-25 | Hoechst Ag | Production of supported catalyst for vinyl acetate production |
US6627770B1 (en) | 2000-08-24 | 2003-09-30 | Celanese International Corporation | Method and apparatus for sequesting entrained and volatile catalyst species in a carbonylation process |
US6657078B2 (en) | 2001-02-07 | 2003-12-02 | Celanese International Corporation | Low energy carbonylation process |
US7115772B2 (en) | 2002-01-11 | 2006-10-03 | Celanese International Corporation | Integrated process for producing carbonylation acetic acid, acetic anhydride, or coproduction of each from a methyl acetate by-product stream |
US7005541B2 (en) | 2002-12-23 | 2006-02-28 | Celanese International Corporation | Low water methanol carbonylation process for high acetic acid production and for water balance control |
US7208624B2 (en) | 2004-03-02 | 2007-04-24 | Celanese International Corporation | Process for producing acetic acid |
EP1741692A1 (en) * | 2005-07-06 | 2007-01-10 | BP Chemicals Limited | Process for the conversion of hydrocarbons to C2-oxygenates |
US8501652B2 (en) | 2008-07-31 | 2013-08-06 | Celanese International Corporation | Catalysts for making ethanol from acetic acid |
US20100030002A1 (en) | 2008-07-31 | 2010-02-04 | Johnston Victor J | Ethylene production from acetic acid utilizing dual reaction zone process |
US7608744B1 (en) | 2008-07-31 | 2009-10-27 | Celanese International Corporation | Ethanol production from acetic acid utilizing a cobalt catalyst |
US7863489B2 (en) * | 2008-07-31 | 2011-01-04 | Celanese International Corporation | Direct and selective production of ethanol from acetic acid utilizing a platinum/tin catalyst |
US8309772B2 (en) * | 2008-07-31 | 2012-11-13 | Celanese International Corporation | Tunable catalyst gas phase hydrogenation of carboxylic acids |
US7816565B2 (en) | 2008-07-31 | 2010-10-19 | Celanese International Corporation | Direct and selective production of acetaldehyde from acetic acid utilizing a supported metal catalyst |
US20100030001A1 (en) | 2008-07-31 | 2010-02-04 | Laiyuan Chen | Process for catalytically producing ethylene directly from acetic acid in a single reaction zone |
-
2011
- 2011-02-01 EP EP11703342A patent/EP2531292A2/en not_active Withdrawn
- 2011-02-01 WO PCT/US2011/023331 patent/WO2011097222A2/en active Application Filing
- 2011-02-01 CN CN201180001857.XA patent/CN102413921B/en not_active Expired - Fee Related
- 2011-02-02 SA SA111320169A patent/SA111320169B1/en unknown
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4398039A (en) * | 1981-05-18 | 1983-08-09 | The Standard Oil Company | Hydrogenation of carboxylic acids |
US5243095A (en) * | 1992-04-24 | 1993-09-07 | Engelhard Corporation | Hydrogenation catalyst, process for preparing and process for using said catalyst |
US6049008A (en) * | 1995-06-15 | 2000-04-11 | Engelhard Corporation | Shaped hydrogenation catalyst and processes for their preparation and use |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8846988B2 (en) | 2010-07-09 | 2014-09-30 | Celanese International Corporation | Liquid esterification for the production of alcohols |
US9000233B2 (en) | 2011-04-26 | 2015-04-07 | Celanese International Corporation | Process to recover alcohol with secondary reactors for hydrolysis of acetal |
Also Published As
Publication number | Publication date |
---|---|
WO2011097222A2 (en) | 2011-08-11 |
EP2531292A2 (en) | 2012-12-12 |
CN102413921B (en) | 2016-05-18 |
CN102413921A (en) | 2012-04-11 |
SA111320169B1 (en) | 2014-09-02 |
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