WO2011080198A3 - Coating method for structured catalysts - Google Patents

Coating method for structured catalysts Download PDF

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Publication number
WO2011080198A3
WO2011080198A3 PCT/EP2010/070593 EP2010070593W WO2011080198A3 WO 2011080198 A3 WO2011080198 A3 WO 2011080198A3 EP 2010070593 W EP2010070593 W EP 2010070593W WO 2011080198 A3 WO2011080198 A3 WO 2011080198A3
Authority
WO
WIPO (PCT)
Prior art keywords
coating method
structured catalysts
support
applying
carrier material
Prior art date
Application number
PCT/EP2010/070593
Other languages
French (fr)
Other versions
WO2011080198A2 (en
Inventor
Nariman Boumendjel
John Graham Buglass
Yvette Louise Jenkins
Gerardus Petrus Lambertus Niesen
David Schaddenhorst
Ronald Jan Schoonebeek
Thijmen Simon Van Klei
Original Assignee
Shell Internationale Research Maatschappij B.V.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij B.V. filed Critical Shell Internationale Research Maatschappij B.V.
Publication of WO2011080198A2 publication Critical patent/WO2011080198A2/en
Publication of WO2011080198A3 publication Critical patent/WO2011080198A3/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0215Coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063Titanium; Oxides or hydroxides thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46Ruthenium, rhodium, osmium or iridium
    • B01J23/462Ruthenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74Iron group metals
    • B01J23/75Cobalt
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0215Coating
    • B01J37/0221Coating of particles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0215Coating
    • B01J37/0221Coating of particles
    • B01J37/0223Coating of particles by rotation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0215Coating
    • B01J37/0225Coating of metal substrates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0234Impregnation and coating simultaneously
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/024Multiple impregnation or coating
    • B01J37/0242Coating followed by impregnation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/024Multiple impregnation or coating
    • B01J37/0244Coatings comprising several layers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74Iron group metals
    • B01J23/745Iron
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/40Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)

Abstract

The invention relates to a method for applying a layer comprising a carrier material to a highly porous support, said method comprising the following steps: (a) applying a mixture comprising a liquid and a carrier material to a highly porous support having a size of at least 1 mm and a porosity within the range of between 50 and 98 volume%; (b) centrifuging and spinning the support; (c) drying and/or calcining the support.
PCT/EP2010/070593 2009-12-29 2010-12-22 Coating method for structured catalysts WO2011080198A2 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
EP09180864 2009-12-29
EP09180864.2 2009-12-29
EP09180868.3 2009-12-29
EP09180868 2009-12-29

Publications (2)

Publication Number Publication Date
WO2011080198A2 WO2011080198A2 (en) 2011-07-07
WO2011080198A3 true WO2011080198A3 (en) 2011-10-06

Family

ID=44226878

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2010/070593 WO2011080198A2 (en) 2009-12-29 2010-12-22 Coating method for structured catalysts

Country Status (1)

Country Link
WO (1) WO2011080198A2 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104722327B (en) * 2013-12-18 2018-05-22 武汉凯迪工程技术研究总院有限公司 It is a kind of for metal base monolithic film catalyst of Fiscber-Tropscb synthesis and preparation method thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5723403A (en) * 1993-07-29 1998-03-03 Institut Francais Du Petrole Production process for catalysts on supports including a centrifuging step for the support after coating
US20020009407A1 (en) * 2000-02-18 2002-01-24 Kostantinos Kourtakis Reticulated ceramic foam catalysts for synthesis gas production
US20050040090A1 (en) * 2001-12-21 2005-02-24 Yong Wang Carbon nanotube-containing structures, methods of making, and processes using same
WO2005084807A1 (en) * 2004-02-24 2005-09-15 Advanced Technology Products, Inc. Method and apparatus for the removal of excess coating material form a honeycomb body
WO2008006786A2 (en) * 2006-07-10 2008-01-17 Shell Internationale Research Maatschappij B.V. Process for hydrocarbon synthesis, hydrocarbon synthesis catalyst material and method of supporting said catalyst material
US20080200328A1 (en) * 2005-05-25 2008-08-21 Hans-Jurgen Eberle Method and Device For Applying Washcoat Suspensions to a Molded Article
US20090000475A1 (en) * 2007-06-29 2009-01-01 Curtis Robert Fekety Zeolite membrane structures and methods of making zeolite membrane structures

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ZA814841B (en) 1980-07-23 1983-02-23 British Petroleum Co Process for the production of lower hydrocarbons and oxygenated derivatives thereof by the catalytic conversion of carbon monoxide and hydrogen
US4409131A (en) 1982-02-22 1983-10-11 Maine Preparation of CoMo and NiMo catalyst using cobalt or nickel complexes that are stable in basic solution
US5783604A (en) 1992-07-02 1998-07-21 Garcia Nunez; Maria Rosalia Germicidal compositions containing iodine compounds
US5502019A (en) 1994-07-15 1996-03-26 Philip Morris Incorporated Conversion of carbon monoxide using cobalt-based metal oxide catalysts
FR2747054B1 (en) 1996-04-09 1998-05-22 Inst Francais Du Petrole PROCESS FOR THE CONVERSION OF SYNTHESIS GAS IN THE PRESENCE OF A CATALYST BASED ON COBALT AND TITANIUM
US5863856A (en) 1997-04-22 1999-01-26 Exxon Research And Engineering Company Preparation of high activity catalysts the catalysts and their use
WO2001076734A1 (en) 2000-04-07 2001-10-18 Phillips Petroleum Company Process for preparing fischer-tropsch catalyst
MY140160A (en) 2004-01-28 2009-11-30 Shell Int Research Heat exchanger for carrying out an exothermic reaction

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5723403A (en) * 1993-07-29 1998-03-03 Institut Francais Du Petrole Production process for catalysts on supports including a centrifuging step for the support after coating
US20020009407A1 (en) * 2000-02-18 2002-01-24 Kostantinos Kourtakis Reticulated ceramic foam catalysts for synthesis gas production
US20050040090A1 (en) * 2001-12-21 2005-02-24 Yong Wang Carbon nanotube-containing structures, methods of making, and processes using same
WO2005084807A1 (en) * 2004-02-24 2005-09-15 Advanced Technology Products, Inc. Method and apparatus for the removal of excess coating material form a honeycomb body
US20080200328A1 (en) * 2005-05-25 2008-08-21 Hans-Jurgen Eberle Method and Device For Applying Washcoat Suspensions to a Molded Article
WO2008006786A2 (en) * 2006-07-10 2008-01-17 Shell Internationale Research Maatschappij B.V. Process for hydrocarbon synthesis, hydrocarbon synthesis catalyst material and method of supporting said catalyst material
US20090000475A1 (en) * 2007-06-29 2009-01-01 Curtis Robert Fekety Zeolite membrane structures and methods of making zeolite membrane structures

Also Published As

Publication number Publication date
WO2011080198A2 (en) 2011-07-07

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