WO2011078780A1 - Method for manufacturing a nanowire structure - Google Patents

Method for manufacturing a nanowire structure Download PDF

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Publication number
WO2011078780A1
WO2011078780A1 PCT/SE2010/051461 SE2010051461W WO2011078780A1 WO 2011078780 A1 WO2011078780 A1 WO 2011078780A1 SE 2010051461 W SE2010051461 W SE 2010051461W WO 2011078780 A1 WO2011078780 A1 WO 2011078780A1
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WIPO (PCT)
Prior art keywords
nanowires
substrate
population
nanowire
electrical
Prior art date
Application number
PCT/SE2010/051461
Other languages
French (fr)
Inventor
Lars Samuelson
Knut Deppert
Jonas Ohlsson
Martin Magnusson
Original Assignee
Qunano Ab
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Publication date
Application filed by Qunano Ab filed Critical Qunano Ab
Priority to CN201080064565.6A priority Critical patent/CN102770367B/en
Priority to KR1020127019100A priority patent/KR101914651B1/en
Priority to US13/518,259 priority patent/US9305766B2/en
Priority to EP10839901.5A priority patent/EP2516323B1/en
Priority to JP2012545905A priority patent/JP5753192B2/en
Publication of WO2011078780A1 publication Critical patent/WO2011078780A1/en
Priority to HK13105396.4A priority patent/HK1178507A1/en
Priority to US15/067,968 priority patent/US9954060B2/en

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
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    • B82B3/00—Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
    • B82B3/0009—Forming specific nanostructures
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    • B—PERFORMING OPERATIONS; TRANSPORTING
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Definitions

  • the present invention relates to manufacturing of nanowire devices, in particular nanowire devices comprising nanowires aligned and protruding in a predetermined direction from a substrate.
  • nanowire based semiconductor devices offer unique properties due to the one-dimensional nature of the nanowires, improved flexibility in materials combinations due to less lattice matching restrictions and opportunities for novel device architectures.
  • Suitable methods for growing semiconductor nanowires are known in the art and one basic process is nanowire formation on semiconductor substrates by particle-assisted growth or the so-called VLS (vapor-liquid- solid) mechanism, which is disclosed in e.g. US
  • Particle-assisted growth can be achieved by for instance use of chemical beam epitaxy (CBE), metalorganic chemical vapor deposition (MOCVD),
  • nanowire growth is not limited to VLS processes, for example the WO 2007/ 102781 shows that semiconductor nanowires may be grown on semiconductor substrates without the use of a particle as a catalyst. Nanowires have been utilised to realise devices such as solar cells, field effect transistors, light emitting diodes, thermoelectric elements, etc which in many cases outperform conventional devices based on planar technology.
  • an MOCVD system is a complex vacuum system, which significantly
  • the nanowires are grown on substrates which needs to withstand
  • one object of the invention is to provide alternative methods for producing nanowire semiconductor devices that overcome the above- mentioned drawbacks of prior art. More particularly, it is an object to provide nanowires that have well-defined and controlled orientation independently of what substrate they are arranged on.
  • the method comprises the steps of providing nanowires and applying an electric field over the population of nanowires, whereby an electric polarization in the nanowires makes them align along the electrical field.
  • the nanowires are dispersed in a fluid (gas or liquid) during the steps of providing and aligning.
  • an electric dipole in the wires may be induced to provide further directionality to and to enhance the alignment.
  • a dipole may be induced by a pn-junction in the axial direction of the wire; by a Schottky diode between semiconductor and metallic sections of the wire; or by piezoelectric effects; and the effect may be enhanced by illuminating the wire during alignment, effectively inducing an open circuit photo voltage between the ends of the wire.
  • the magnitude of this light induced dipole is essentially independent of the illumination strength, since the open circuit voltage of a photodiode varies only logarithmically with illumination.
  • the nanowires When aligned, the nanowires can be fixated, preferably in contact with a substrate.
  • the electrical field can be utilised to bring the nanowires in contact with the substrate, or an opposed surface.
  • Charged nanowires are attracted to an oppositely charged surface in a uniform electric field.
  • Uncharged nanowires are attracted to regions with higher electric fields, in the case of a field gradient.
  • nanowires in a field gradient will experience both effects, either in the opposite or in the same direction.
  • the force due to charge on the wire depends only on the charge and the electric field strength.
  • the force due to the gradient depends on the field strength the wire dimensions and on the electric polarizability.
  • nanowires with pn-junctions and/or illumination of the nanowires with light of a pre-determined wavelength(s) may assist in aligning the nanowires and/or enables selective alignment of one or more sub-populations of nanowires.
  • the method may be performed in a continuous process, such as a roll-to-roll process wherein said population of nanowires are repeatedly provided and deposited in a pre-determined configuration along the substrate.
  • One advantage of the present invention is that nanowires can be produced separately from the deposition of the nanowires onto a substrate. Hence a continuous process can be used. This simplifies the manufacturing of nanowire devices and improves the yield.
  • Nanowires deposited with the method described here may be aligned vertically, with only a small angle away from the normal, or with a large spread of angles.
  • the key is that the wires have a clear preferential direction, so that the majority of the wires have the same end toward the substrate.
  • the vertical alignment may be more important, and the up/down orientation less so.
  • Fig. 1 schematically illustrates alignment of a nanowire in accordance with the invention.
  • Fig. 2 schematically illustrates the concept of classifying wires in an electric field gradient. Long and thin wires are more strongly attracted towards higher electric fields than shorter thicker ones. For charged wires of the right dimension, the forces due to charge and to gradient can be made to cancel.
  • Fig. 3a schematically illustrates the dimensions and alignment angles of a nanowire in an electric field.
  • Fig. 3b illustrates the concepts of a nanowire oriented "up” and “down” with respect to the electric field.
  • Fig. 4 compares the theoretical alignment energy due to polarization (green, dashed) , light induced dipole (red, solid), and their sum (purple, dotted) for wires of two different dimensions but at the same electric field ( 1000 V/cm).
  • the alignment of the longer wire (4b) is stronger than for the shorter one (4a), but the light induced dipole is too weak to be important.
  • Fig. 5 compares the theoretical alignment energy due to polarization (green, dashed) , light induced dipole (red, solid), and their sum (purple, dotted) for wires of the same dimension but at different electric fields (1000 V/cm and 300 V/cm, respectively).
  • the alignment is stronger than at lower field (5b), but in the latter case the light induced dipole is strong enough to dominate the alignment and provide a preferential direction.
  • Fig. 6 illustrates the alignment energy for the "up” (red, solid) and “down” (green, dashed) directions for the same wire as in 4a at varying electric fields.
  • the "up” energy is greater than 10 kT (i.e., to overcome the Brownian rotation energy of 1 kT), but where the "down" energy is low.
  • the "up” energy is greater than 10 kT (i.e., to overcome the Brownian rotation energy of 1 kT), but where the "down” energy is low.
  • Fig. 7 schematically illustrates the regimes where wire alignment of different kinds is at play.
  • the axes are not necessarily linear and the borders between the regimes are not to be seen as neither as sharp nor as simply shaped as the drawing suggests.
  • Fig. 8 illustrates some of the primary ways to apply the invention.
  • the components can be rearranged in many ways, and in different sequences too complex to illustrate here.
  • wire size classification may be used in combination with illumination at different wavelengths and in series with vertical alignment to selectively deposit wires according to both size and composition.
  • the method of the present invention comprises the steps of providing nanowires and applying an electrical field over the nanowires, whereby an electrical dipole and/or dipole moment in the nanowires makes them align along the electrical field.
  • the aligned nanowires In order to manufacture a structure comprising aligned nanowires, the aligned nanowires have to be fixated in aligned position. Furthermore, the nanowires are preferably connected electrically and/or optically in one or both ends. Thus, the aligned nanowires are preferably deposited onto a substrate.
  • the pre-fabricated nanowires may be dispersed in a fluid before applying the electric field, and accordingly the fluid containing the nanowires can be applied to the substrate before applying the electrical field.
  • the nanowires can be pre-fabricated before being provided for alignment.
  • Nanowires can be fabricated using one of the afore-mentioned methods where nanowires are epitaxially grown on substrates. After growth the nanowires are removed from their substrate and preferably dispersed in a fluid (gas or liquid). The nanowires can also be fabricated using liquid solution-based chemistry or gas-phase synthesis where the nanowires grow from seed particles. In these processes the nanowires can remain in the remainder of the liquid or gas, respectively or be transferred to a suitable fluid, which also may be a liquid or a gas.
  • Unipolar nanowires, nanowires with axial pn-junctions, nanowires with radial pn-junctions, heterostructure nanowires, etc. may be used and are generally fabricated using one of the above-mentioned techniques.
  • Nanowires with axial pn- junctions are grown in a in a single process, where the seed particle contains a dopant for one polarity, and where the opposite polarity is achieved when the dopant is exhausted or in a more complex process, where dopants and source materials are explicitly introduced during the process.
  • Nanowires with radial pn- junctions are grown in a two-stage process, where growth conditions are changed to give radial growth, but otherwise similar to the fabrication of nanowires with axial pn-junctions. Nanowires may be given a net electric charge either during growth or in a separate step.
  • the electric dipole in the nanowires can, by way of example, be accomplished by one or a combination of the following:
  • An electric field will induce an electric polarization in any conducting, semiconducting or insulating nanowire, and the nanowires will orient themselves along the electric field (fig. 1).
  • the nanowire will be oriented along the
  • a unipolar ly doped nanowire with an axial gradient in the doping will be preferentially oriented, since the more highly p(n)-doped end will be more easily charged positively (negatively) , directing this end up (down) in the electric field.
  • a nanowire comprising a p-doped end and an n-doped end forming a a p II -junction in-between will be more easily polarizable than an unipolar nanowire.
  • the p-doped end will become positively charged and the n-doped end will be negatively charged when exposed to the electrical field, and hence the nanowire will be oriented in an unequivocal direction with the p-doped end pointing in the direction of the electric field.
  • nanowires having different band gaps can be selectively aligned since wires that do not absorb the light will have a much weaker dipole.
  • the pn-junction used for alignment may be a functional part when used in a device comprising the aligned nanowires.
  • the nanowires may comprise additional functional sections that are not intentionally used for alignment.
  • E ⁇ j scales as the square of the wire diameter but does not depend on its length
  • the alignment is weak or non-existent, meaning that the alignment energy is on the order of or below kT, which is the average energy of Brownian rotation per wire; k is the Boltzmann constant and T is the absolute temperature (300 K).
  • Deposition of the aligned nanowires can, by way of example, be done by one or a combination of the following:
  • Nanowires with a net charge will move in the electric field; thus
  • negatively charged nanowires will move downward, where a substrate can be placed.
  • a sheath flow may be introduced to prevent deposition on one side; b. substrates may be placed on both sides of the nanowires for deposition of oppositely aligned wires; and c. the distance between electrodes can be made smaller than the wire length, forcing the wires to touch the substrate, either by moving the plates closer or by designing in a constriction in the flow of nanowire- containing fluid.
  • Dipoles with or without net charge will move in an electric field gradient, such that the wires are attracted towards higher fields. This effect can be used both for deposition and for classification of nanowires (fig. 2).
  • the gradient force can be balanced by a force due to the charged, allowing further control of size and material dependent classification.
  • the field gradient will influence deposition; in combination with wavelength- selective dipole generation, wires can be selectively placed according to composition and/ or size.
  • a structured electrode behind the substrate e.g., a bed of nails or array of ridges, will produce a pattern or dots or stripes; an alternating potential will produce areas with oppositely oriented wires.
  • Deposition may be locally enhanced or inhibited by patterns of surface charge on the substrate; the deposition may be made self- limiting when the charged areas are neutralized by the charges from the deposited wires
  • Wires may be deposited through thermophoresis, wherein wires suspended in a fluid will move towards lower temperature regions in a thermal gradient, i.e. , deposited on a cold wall and/or repelled from a hot wall.
  • Intensely focused (laser) light and magnetic fields can in some cases be used to trap nanowires locally, e.g., by the optical tweezer or magnetic trap effects.
  • the electric field may be generated using two opposed electrodes, for example two parallel plates, and applying a voltage between the electrodes.
  • the substrate used can also function as one of the electrodes.
  • the substrate for example in the form of a web, foil or sheet may be fed between the electrodes (or over one of the electrodes if the substrate is used as one electrode) and a pulsating or periodic voltage may be applied to the electrodes to generate a varying electrical field and hence a varying orientation of the aligned nanowires.
  • nanowires can be deposited:
  • substrates in form of webs, foils, or sheets preferably in a roll-to-roll process, wherein the substrate is passed through a point, stripe or region of deposition, much like a printing press;
  • the wire-containing liquid in the case of wires dispersed in a liquid, as a colloidal suspension, can be applied to the substrate, and the wires be aligned
  • the sticky material may be very thin, so that only the wire ends are stuck;
  • the sticky material has a thickness of the same order as the length of the nanowires.
  • the liquid may comprise monomers to make the polymer on the substrate gradually thicker, thereby encapsulating the nanowires
  • the polarity/ direction of the nanowires may vary in, e.g., stripes or checkerboard patterns
  • the nanowires are of different types and sorted by inducing the electrical dipoles in a wavelength selective way;
  • nanowire in this patent application is meant any elongated structure with at least one dimension smaller than 1 ⁇ . Typical examples include, but are not limited to:
  • semiconductor nanowires with a diameter of 50 - 500 nm and a length of 1 - 10 ⁇ , produced by, e.g., MOCVD growth, liquid solution chemistry, gas phase growth.
  • Typical materials are III-V or III-N semiconductors (GaAs, InP, GaSb, GalnN and related alloys), Silicon, Germanium, or II-VI
  • nanowires may be made from magnetic, superconducting or normal metals
  • biological nanofibers e.g., cellulose, proteins, macromolecules and
  • PV cells where the light-absorption and charge- separation takes place in the nanowires alone, i.e. where the nanowires contain pn- junctions or other rectifying mechanisms.
  • PV devices include a densely packed array of nanowires, where the majority of the wires are vertically aligned and connected with the same polarity. It would also include a transparent contact either from the top or through a transparent substrate, connecting all the wire ends in parallel.
  • LEDs Light emitting diodes
  • Such LED devices would include an array of nanowires, which may be contacted either with the same polarity or with random polarity. In the latter case, the structure would function as a rectifier, suited for connection directly to AC voltage. An LED array would also not need to be extremely dense, if the objective is to produce large area light emitting surfaces, for example ceramic tiles or even wallpaper.
  • the nanowires constitute part of the rectifying mechanism, and the other part(s) are in the substrate; the substrate is, e.g., p-type and the wires n-type.
  • the substrate is, e.g., p-type and the wires n-type.
  • Such a PV device would be made from densely packed nanowires, but here the up/down orientation of the wires is less important, and consequently the processing simpler.
  • the density of the wires may be lower than in example 1 above, if the carrier diffusion length in the substrate is large enough.
  • the substrate is, e.g., p-type and the wires n-type.
  • the substrate is, e.g., p-type and the wires n-type.
  • PV cells where the nanowires constitute part of the rectifying mechanism, and the other part(s) are in the matrix surrounding the wires after
  • PV device e.g., p-type wires in an n-type conducting oxide or polymer.
  • a PV device may be fabricated on very simple substrates.
  • PV cells where the substrate itself is a photovoltaic cell, and where the nanowires are designed to absorb light above or below the bandgap of the substrate, thereby creating a tandem photovoltaic cell.
  • the nanowire part of the tandem cell may be fabricated according to example 1 , 3 or 5 above.
  • the nanowires may be arranged in patterns, e.g. stripes, to allow for spectrally resolved light absorption by means of a prism, to achieve multi-junction PV functionality; or light emission with adjustable color temperature where each stripe is contacted separately.
  • the nanowires also give a built-in nanostructuring of the top surface, which may be advantageous for both light absorption in the case of PV cells and for light emission in the case of LEDs.
  • Thermoelectric cells wherein the one-dimensional character of nanowires is used to improve the way thermal gradients can be used to generate electrical power. Furthermore, by the controlled deposition of separate fields of n-doped and p-doped nanowires a Peltier element is formed, which can be used for cooling or heating applications, in the conversion of electrical power to thermal gradients.
  • Batteries where one or both electrodes are prepared by this method and thus are constructed out of a nanowire structure.
  • the small diameter of the nanowires makes them insensitive to strain and thus to changes in diameter that are accompanied with the volume change during battery cycling.
  • Fuel cells, electrolysis or photolysis cells where the main material is comprised out of nanowire structures which gives them advantages over other materials in terms of insensitivity to process-induced strain, surface- to-volume ratio, as well as process fluid interaction with the structures.
  • Microelectronic or data storage devices may be formed in nanowires which are deposited from the aerosol phase.
  • a device for classifying nanowires according to size and/or material wherein a flow of charged or uncharged nanowires passes through an electric field gradient.
  • Longer, thinner and more polarizable wires are subjected to stronger attractive forces towards higher electric field regions, and can thus be classified in a manner reminiscent of a mass spectrometer.
  • forces may be balanced for greater selectivity.
  • Nanocomposite materials where nanowires are dispersed in, e.g., a polymer matrix, leading to, e.g., enhanced mechanical strength, increased electrical conductivity, improved gas permeability properties, etc.
  • n a n o c o m po s i t e s may also be sensitive to applied external forces and thus used as sensors.

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Abstract

The present invention provides a method for aligning nanowires which can be used to fabricate devices comprising nanowires that has well-defined and controlled orientation independently on what substrate they are arranged on. The method comprises the steps of providing nanowires (1) and applying an electrical field (E) over the population of nanowires (1), whereby an electrical dipole moment of the nanowires makes them align along the electrical field (E). Preferably the nanowires are dispersed in a fluid during the steps of providing and aligning. When aligned, the nanowires can be fixated, preferably be deposition on a substrate (2). The electrical field can be utilised in the deposition. Pn-junctions or any net charge introduced in the nanowires (1) may assist in the aligning and deposition process. The method is suitable for continuous processing, e.g. in a roll-to-roll process, on practically any substrate materials and not limited to substrates suitable for particle assisted growth.

Description

METHOD FOR MANUFACTURING A NANOWIRE STRUCTURE
Technical field of the invention
The present invention relates to manufacturing of nanowire devices, in particular nanowire devices comprising nanowires aligned and protruding in a predetermined direction from a substrate.
Background of the invention
Over recent years the interest in semiconductor nanowires has increased. In comparison with conventional planar technology nanowire based semiconductor devices offer unique properties due to the one-dimensional nature of the nanowires, improved flexibility in materials combinations due to less lattice matching restrictions and opportunities for novel device architectures. Suitable methods for growing semiconductor nanowires are known in the art and one basic process is nanowire formation on semiconductor substrates by particle-assisted growth or the so-called VLS (vapor-liquid- solid) mechanism, which is disclosed in e.g. US
7,335,908. Particle-assisted growth can be achieved by for instance use of chemical beam epitaxy (CBE), metalorganic chemical vapor deposition (MOCVD),
metalorganic vapor phase epitaxy (MOVPE) , molecular beam epitaxy (MBE) , laser ablation and thermal evaporation methods. However, nanowire growth is not limited to VLS processes, for example the WO 2007/ 102781 shows that semiconductor nanowires may be grown on semiconductor substrates without the use of a particle as a catalyst. Nanowires have been utilised to realise devices such as solar cells, field effect transistors, light emitting diodes, thermoelectric elements, etc which in many cases outperform conventional devices based on planar technology.
Although having advantageous properties and performance the processing of nanowire devices was initially costly. One important breakthrough in this respect was that methods for growing group III-V semiconductor nanowires, and others, on Si-substrates has been demonstrated, which is important since it provides a compatibility with existing Si processing and non- affordable III-V substrates can be replaced by cheaper Si substrates.
When producing semiconductor nanowire devices comprising nanowires grown on a semiconductor substrate utilizing the above mentioned techniques a number of limitations are experienced:
- an MOCVD system is a complex vacuum system, which significantly
contributes to the production cost for the device; - growth is performed in batches, with inherent variations between individual batches;
- growth of a large number of nanowires over a large surface yields
variations between nanowires in the same batch;
- the nanowires are grown on substrates which needs to withstand
temperatures of 400-700 °C; and
- to align nanowires in the vertical direction, or any other direction, on the semiconductor substrate requires controlled epitaxial growth.
Summary of the invention
In view of the foregoing one object of the invention is to provide alternative methods for producing nanowire semiconductor devices that overcome the above- mentioned drawbacks of prior art. More particularly, it is an object to provide nanowires that have well-defined and controlled orientation independently of what substrate they are arranged on.
Hence a method for aligning nanowires is provided. The method comprises the steps of providing nanowires and applying an electric field over the population of nanowires, whereby an electric polarization in the nanowires makes them align along the electrical field. Preferably the nanowires are dispersed in a fluid (gas or liquid) during the steps of providing and aligning.
In addition to the polarization to make wires align in the electric field, an electric dipole in the wires may be induced to provide further directionality to and to enhance the alignment. Such a dipole may be induced by a pn-junction in the axial direction of the wire; by a Schottky diode between semiconductor and metallic sections of the wire; or by piezoelectric effects; and the effect may be enhanced by illuminating the wire during alignment, effectively inducing an open circuit photo voltage between the ends of the wire. The magnitude of this light induced dipole is essentially independent of the illumination strength, since the open circuit voltage of a photodiode varies only logarithmically with illumination.
When aligned, the nanowires can be fixated, preferably in contact with a substrate. The electrical field can be utilised to bring the nanowires in contact with the substrate, or an opposed surface. Charged nanowires are attracted to an oppositely charged surface in a uniform electric field. Uncharged nanowires are attracted to regions with higher electric fields, in the case of a field gradient.
Charged wires in a field gradient will experience both effects, either in the opposite or in the same direction. The force due to charge on the wire depends only on the charge and the electric field strength. The force due to the gradient depends on the field strength the wire dimensions and on the electric polarizability. Thus, by arranging the two forces in opposite directions, nanowires can be classified according to length, size and composition. The gradient force on its own may also be used for classification, in which case only a difference in that force is used to guide wires in different directions.
Having nanowires with pn-junctions and/or illumination of the nanowires with light of a pre-determined wavelength(s) may assist in aligning the nanowires and/or enables selective alignment of one or more sub-populations of nanowires.
The method may be performed in a continuous process, such as a roll-to-roll process wherein said population of nanowires are repeatedly provided and deposited in a pre-determined configuration along the substrate.
Thanks to the invention it is possible to produce nanowire devices comprising aligned nanowires in a cost-efficient way and without being limited by the limitations of epitaxial methods.
One advantage of the present invention is that nanowires can be produced separately from the deposition of the nanowires onto a substrate. Hence a continuous process can be used. This simplifies the manufacturing of nanowire devices and improves the yield.
Nanowires deposited with the method described here may be aligned vertically, with only a small angle away from the normal, or with a large spread of angles. In the latter case, the key is that the wires have a clear preferential direction, so that the majority of the wires have the same end toward the substrate. In the former case, the vertical alignment may be more important, and the up/down orientation less so.
Embodiments of the invention are defined in the dependent claims. Other objects, advantages and novel features of the invention will become apparent from the following detailed description of the invention when considered in conjunction with the accompanying drawings and claims.
Brief description of the drawings
Preferred embodiments of the invention will now be described with reference to the accompanying drawings, wherein
Fig. 1 schematically illustrates alignment of a nanowire in accordance with the invention.
Fig. 2 schematically illustrates the concept of classifying wires in an electric field gradient. Long and thin wires are more strongly attracted towards higher electric fields than shorter thicker ones. For charged wires of the right dimension, the forces due to charge and to gradient can be made to cancel.
Fig. 3a schematically illustrates the dimensions and alignment angles of a nanowire in an electric field.
Fig. 3b illustrates the concepts of a nanowire oriented "up" and "down" with respect to the electric field.
Fig. 4 compares the theoretical alignment energy due to polarization (green, dashed) , light induced dipole (red, solid), and their sum (purple, dotted) for wires of two different dimensions but at the same electric field ( 1000 V/cm). The alignment of the longer wire (4b) is stronger than for the shorter one (4a), but the light induced dipole is too weak to be important.
Fig. 5 compares the theoretical alignment energy due to polarization (green, dashed) , light induced dipole (red, solid), and their sum (purple, dotted) for wires of the same dimension but at different electric fields (1000 V/cm and 300 V/cm, respectively). At higher field (5a, same as 4b) the alignment is stronger than at lower field (5b), but in the latter case the light induced dipole is strong enough to dominate the alignment and provide a preferential direction.
Fig. 6 illustrates the alignment energy for the "up" (red, solid) and "down" (green, dashed) directions for the same wire as in 4a at varying electric fields. There is a wide range of fields where the "up" energy is greater than 10 kT (i.e., to overcome the Brownian rotation energy of 1 kT), but where the "down" energy is low. For very thin and long wires (not shown) , there exists no region where directionality is important.
Fig. 7 schematically illustrates the regimes where wire alignment of different kinds is at play. The axes are not necessarily linear and the borders between the regimes are not to be seen as neither as sharp nor as simply shaped as the drawing suggests.
Fig. 8 illustrates some of the primary ways to apply the invention. Naturally, the components can be rearranged in many ways, and in different sequences too complex to illustrate here. For example, wire size classification may be used in combination with illumination at different wavelengths and in series with vertical alignment to selectively deposit wires according to both size and composition. Detailed description of embodiments
The method of the present invention comprises the steps of providing nanowires and applying an electrical field over the nanowires, whereby an electrical dipole and/or dipole moment in the nanowires makes them align along the electrical field.
In order to manufacture a structure comprising aligned nanowires, the aligned nanowires have to be fixated in aligned position. Furthermore, the nanowires are preferably connected electrically and/or optically in one or both ends. Thus, the aligned nanowires are preferably deposited onto a substrate.
The pre-fabricated nanowires may be dispersed in a fluid before applying the electric field, and accordingly the fluid containing the nanowires can be applied to the substrate before applying the electrical field.
The electric field is in the following directed "upwards" if not otherwise explicitly stated in order to illustrate the principles of the invention, however not limited to this.
The nanowires can be pre-fabricated before being provided for alignment.
Semiconductor nanowires can be fabricated using one of the afore-mentioned methods where nanowires are epitaxially grown on substrates. After growth the nanowires are removed from their substrate and preferably dispersed in a fluid (gas or liquid). The nanowires can also be fabricated using liquid solution-based chemistry or gas-phase synthesis where the nanowires grow from seed particles. In these processes the nanowires can remain in the remainder of the liquid or gas, respectively or be transferred to a suitable fluid, which also may be a liquid or a gas.
Unipolar nanowires, nanowires with axial pn-junctions, nanowires with radial pn-junctions, heterostructure nanowires, etc. may be used and are generally fabricated using one of the above-mentioned techniques. Nanowires with axial pn- junctions are grown in a in a single process, where the seed particle contains a dopant for one polarity, and where the opposite polarity is achieved when the dopant is exhausted or in a more complex process, where dopants and source materials are explicitly introduced during the process. Nanowires with radial pn- junctions are grown in a two-stage process, where growth conditions are changed to give radial growth, but otherwise similar to the fabrication of nanowires with axial pn-junctions. Nanowires may be given a net electric charge either during growth or in a separate step.
The electric dipole in the nanowires can, by way of example, be accomplished by one or a combination of the following:
1. An electric field will induce an electric polarization in any conducting, semiconducting or insulating nanowire, and the nanowires will orient themselves along the electric field (fig. 1).
a. For unipolar nanowires, the nanowire will be oriented along the
electrical field, but with no preferred direction for a seed particle end. b. A unipolar ly doped nanowire with an axial gradient in the doping will be preferentially oriented, since the more highly p(n)-doped end will be more easily charged positively (negatively) , directing this end up (down) in the electric field.
2. A nanowire comprising a p-doped end and an n-doped end forming a a p II -junction in-between will be more easily polarizable than an unipolar nanowire.
a. The p-doped end will become positively charged and the n-doped end will be negatively charged when exposed to the electrical field, and hence the nanowire will be oriented in an unequivocal direction with the p-doped end pointing in the direction of the electric field.
b. The same effect will apply to a unipolarly doped nanowire where a Schottky diode is formed between the wire and its seed particle.
3. Illumination of a nanowire containing a pn-junction will induce a strong electric dipole with the same polarity as the electric dipole formed by the electric field, greatly enhancing the effect of the pn-junction itself (fig. 1).
4. By illumination with light in different pre-determined wavelength regions, nanowires having different band gaps can be selectively aligned since wires that do not absorb the light will have a much weaker dipole.
The pn-junction used for alignment may be a functional part when used in a device comprising the aligned nanowires. In addition the nanowires may comprise additional functional sections that are not intentionally used for alignment.
How effectively a wire is aligned depends on its dimensions, composition, the external electric field, and whether or not a dipole is induced, e.g., through illumination. The following general rules apply for electric field alignment. The numbers given are based on a simplified theoretical model and should not be seen as limiting for the validity of the general statements. Figures 3 - 7 illustrate these rules.
1. In the simplified model,
a. the alignment energy due to an (induced) dipole (Ed) scales as the electric field to the first degree;
b. E<j scales as the square of the wire diameter but does not depend on its length;
c. the alignment energy due to polarization of the wire material (Ep) scales as the square of the electric field;
d. Ep scales as the cube of the wire aspect ratio (length divided by
diameter) .
2. At low electric fields, typically below 100 V/cm, the alignment is weak or non-existent, meaning that the alignment energy is on the order of or below kT, which is the average energy of Brownian rotation per wire; k is the Boltzmann constant and T is the absolute temperature (300 K).
3. At high electric fields, typically above 10 kV/cm, all elongated objects are aligned without regard to direction, meaning that the alignment energy due to polarization (Ep) is much greater than kT.
4. Thinner and longer objects are more readily aligned than wide and short ones.
5. Under illumination or other sources of a potential difference between the wire ends, i.e., a dipole, there exists a regime where Ed is both greater than Ep and much greater than kT, leading to orientation with a preferential direction; this effect is greater for wider wires than for thinner ones (Fig. 7).
Deposition of the aligned nanowires can, by way of example, be done by one or a combination of the following:
1. Nanowires with a net charge will move in the electric field; thus
negatively charged nanowires will move downward, where a substrate can be placed.
2. Random diffusion of uncharged dipoles, which is particularly useful when the distance between the plate capacitors is small, where
a. a sheath flow may be introduced to prevent deposition on one side; b. substrates may be placed on both sides of the nanowires for deposition of oppositely aligned wires; and c. the distance between electrodes can be made smaller than the wire length, forcing the wires to touch the substrate, either by moving the plates closer or by designing in a constriction in the flow of nanowire- containing fluid.
Dipoles with or without net charge will move in an electric field gradient, such that the wires are attracted towards higher fields. This effect can be used both for deposition and for classification of nanowires (fig. 2).
a. Longer and thinner wires are subjected to a stronger force due to the field gradient and will this move faster toward the regions with higher fields.
b. The electric polarizability is different for different materials.
c. For charged wires the gradient force can be balanced by a force due to the charged, allowing further control of size and material dependent classification.
On a patterned substrate electrode, the field gradient will influence deposition; in combination with wavelength- selective dipole generation, wires can be selectively placed according to composition and/ or size.
A structured electrode behind the substrate, e.g., a bed of nails or array of ridges, will produce a pattern or dots or stripes; an alternating potential will produce areas with oppositely oriented wires.
Deposition may be locally enhanced or inhibited by patterns of surface charge on the substrate; the deposition may be made self- limiting when the charged areas are neutralized by the charges from the deposited wires
Wires may be deposited through thermophoresis, wherein wires suspended in a fluid will move towards lower temperature regions in a thermal gradient, i.e. , deposited on a cold wall and/or repelled from a hot wall.
In the case of magnetic nanowires, they are easily collected and
controlled with magnetic fields. Charged nanoparticles suspended in a flow of fluid (in effect generating an electric current) are also affected by magnetic fields.
Intensely focused (laser) light and magnetic fields can in some cases be used to trap nanowires locally, e.g., by the optical tweezer or magnetic trap effects.
Apart from the above, other things such as ultrasound, microwaves, etc. , may be of use to inhibit or improve wire deposition. The electric field may be generated using two opposed electrodes, for example two parallel plates, and applying a voltage between the electrodes. The substrate used can also function as one of the electrodes. In a continuous process the substrate, for example in the form of a web, foil or sheet may be fed between the electrodes (or over one of the electrodes if the substrate is used as one electrode) and a pulsating or periodic voltage may be applied to the electrodes to generate a varying electrical field and hence a varying orientation of the aligned nanowires.
According to the invention, nanowires can be deposited:
1. on any insulating, semiconducting or metallic substrate, which is
substantially flat;
2. on substrates in form of webs, foils, or sheets, preferably in a roll-to-roll process, wherein the substrate is passed through a point, stripe or region of deposition, much like a printing press;
3. in the case of wires dispersed in a liquid, as a colloidal suspension, the wire-containing liquid can be applied to the substrate, and the wires be aligned
a. during drying/ evaporation of the liquid
b. during or prior to solidification/ polymerization of the liquid
4. on substrates coated with a polymer, metal, liquid or other material to enhance nanowire sticking and/or electrical contacting, wherein
a. the sticky material may be very thin, so that only the wire ends are stuck; or
b. the sticky material has a thickness of the same order as the length of the nanowires; and
c. if the nanowires are dispersed in a liquid, the liquid may comprise monomers to make the polymer on the substrate gradually thicker, thereby encapsulating the nanowires;
5. on substrates patterned with extruding shapes, varying stickiness,
surface charges, etc. , to enhance or locally inhibit nanowire deposition;
6. on functional substrates, where the nanowires are intended to enhance or modify the function;
7. in complex functional patterns of dots, stripes, etc. , produced by a
structured electrode behind the substrate or by a structure in the
(conducting) substrate itself, wherein a. the polarity/ direction of the nanowires may vary in, e.g., stripes or checkerboard patterns; and
b. the nanowires are of different types and sorted by inducing the electrical dipoles in a wavelength selective way;
8. on both sides of a substrate, where the wires on either side may be of different types and deposited by different means, including any of the means described above;
9. in a continuous process, where contact or adhesion layers, insulation oxides or polymers, etc., are deposited on the substrate upstream or downstream the nanowires.
By the term "nanowire" in this patent application is meant any elongated structure with at least one dimension smaller than 1 μπι. Typical examples include, but are not limited to:
1. semiconductor nanowires with a diameter of 50 - 500 nm and a length of 1 - 10 μπι, produced by, e.g., MOCVD growth, liquid solution chemistry, gas phase growth. Typical materials are III-V or III-N semiconductors (GaAs, InP, GaSb, GalnN and related alloys), Silicon, Germanium, or II-VI
semiconductors (ZnO, ZnS, CdS, CdSe and related alloys);
2. metal nanowires produced by, e.g., electrodeposition in anodized
aluminum templates, whisker growth, gas phase growth. Such nanowires may be made from magnetic, superconducting or normal metals;
3. insulating, high bandgap semiconductor, or high-TC superconductor nanowires, either manufactured or naturally occurring;
4. carbon nanotubes; or
5. biological nanofibers, e.g., cellulose, proteins, macromolecules and
bacteria.
Devices to be produced with this method, however not limited to this:
1. Photovoltaic (PV) cells where the light-absorption and charge- separation takes place in the nanowires alone, i.e. where the nanowires contain pn- junctions or other rectifying mechanisms. Such PV devices include a densely packed array of nanowires, where the majority of the wires are vertically aligned and connected with the same polarity. It would also include a transparent contact either from the top or through a transparent substrate, connecting all the wire ends in parallel. Light emitting diodes (LEDs) where the light-emission and charge recombination takes place in the nanowires alone, i.e. where the nanowires contain pn-junctions or other rectifying mechanisms. Such LED devices would include an array of nanowires, which may be contacted either with the same polarity or with random polarity. In the latter case, the structure would function as a rectifier, suited for connection directly to AC voltage. An LED array would also not need to be extremely dense, if the objective is to produce large area light emitting surfaces, for example ceramic tiles or even wallpaper.
PV cells where the nanowires constitute part of the rectifying mechanism, and the other part(s) are in the substrate; the substrate is, e.g., p-type and the wires n-type. Such a PV device would be made from densely packed nanowires, but here the up/down orientation of the wires is less important, and consequently the processing simpler. In addition, the density of the wires may be lower than in example 1 above, if the carrier diffusion length in the substrate is large enough.
LEDs where the nanowires constitute part of the rectifying mechanism, and the other part(s) are in the substrate; the substrate is, e.g., p-type and the wires n-type. Just as in examples 2 and 3 above, such an LED
arrangement relaxes the need for both alignment and density.
PV cells where the nanowires constitute part of the rectifying mechanism, and the other part(s) are in the matrix surrounding the wires after
deposition, e.g., p-type wires in an n-type conducting oxide or polymer. Such a PV device may be fabricated on very simple substrates.
LEDs where the nanowires constitute part of the rectifying mechanism, and the other part(s) are in the matrix surrounding the wires after
deposition, e.g., p-type wires in an n-type conducting oxide or polymer. Just as in examples 2 - 5 above, such an LED arrangement relaxes the need for both alignment and density.
PV cells where the substrate itself is a photovoltaic cell, and where the nanowires are designed to absorb light above or below the bandgap of the substrate, thereby creating a tandem photovoltaic cell. The nanowire part of the tandem cell may be fabricated according to example 1 , 3 or 5 above.
In all of the above examples of PV cells or LEDs, the nanowires may be arranged in patterns, e.g. stripes, to allow for spectrally resolved light absorption by means of a prism, to achieve multi-junction PV functionality; or light emission with adjustable color temperature where each stripe is contacted separately.
In all of the above examples of PV cells or LEDs, the nanowires also give a built-in nanostructuring of the top surface, which may be advantageous for both light absorption in the case of PV cells and for light emission in the case of LEDs.
. Thermoelectric cells, wherein the one-dimensional character of nanowires is used to improve the way thermal gradients can be used to generate electrical power. Furthermore, by the controlled deposition of separate fields of n-doped and p-doped nanowires a Peltier element is formed, which can be used for cooling or heating applications, in the conversion of electrical power to thermal gradients.
Batteries where one or both electrodes are prepared by this method and thus are constructed out of a nanowire structure. The small diameter of the nanowires makes them insensitive to strain and thus to changes in diameter that are accompanied with the volume change during battery cycling.,
Fuel cells, electrolysis or photolysis cells where the main material is comprised out of nanowire structures which gives them advantages over other materials in terms of insensitivity to process-induced strain, surface- to-volume ratio, as well as process fluid interaction with the structures.
Microelectronic or data storage devices may be formed in nanowires which are deposited from the aerosol phase.
Templates for growth of functional material films on simple substrates, where the aligned nanowires provide the crystal structure for growth of, e.g., compound semiconductors on Silicon or even on non-crystalline surfaces
(metal, glass, etc.).
A device for classifying nanowires according to size and/or material, wherein a flow of charged or uncharged nanowires passes through an electric field gradient. Longer, thinner and more polarizable wires are subjected to stronger attractive forces towards higher electric field regions, and can thus be classified in a manner reminiscent of a mass spectrometer. For charged wires, forces may be balanced for greater selectivity.
Nanocomposite materials, where nanowires are dispersed in, e.g., a polymer matrix, leading to, e.g., enhanced mechanical strength, increased electrical conductivity, improved gas permeability properties, etc. Such n a n o c o m po s i t e s may also be sensitive to applied external forces and thus used as sensors.
17. Field emission electron sources where simple or heterostructure-designed nanowires are deposited into arrays for field-emission applications.
18. Antireflective or light filtering surfaces or smart windows.
1 . Surfaces with enhanced mechanical sticking ability, due to the gecko effect.
20. Surfaces with enhanced or reduced heat emission.
21. Chemical or biological sensors.
All references to upward, vertical, horizontal, lengthwise, etc. are introduced for the ease of understanding only, and should not be considered as limiting to specific orientation. Further the dimensions of the structures and axes in the drawings are not necessarily to scale.
While the invention has been described in connection with what is presently considered to be the most practical and preferred embodiments, it is to be understood that the invention is not to be limited to the disclosed embodiments, on the contrary, it is intended to cover various modifications and equivalent
arrangements within the appended claims.

Claims

1. A method of aligning nanowires on a substrate during manufacture of a nanowire structure, comprising the steps of:
- providing a population of nanowires ( 1); and
- applying an electric field (E) over the population of nanowires ( 1), whereby an electric dipole in the nanowires makes them align along the electric field (E),
characterized in that
each nanowire of at least a sub-population of the nanowires (1) comprises one of
i) a pn-junction, where the electric dipole is formed from an n-side to a p-side of the pn-junction;
ii) a Schottky diode, where the electric dipole is formed from an n-side to a p- side of the Schottky diode;
iii) piezoelectric portions, where the electric dipole is formed by charge
separation due to a built-in piezoelectric field;
and where the positively charged end of each wire is forced in the direction of the electric field (E).
2. The method of claim 1, wherein the electrical field (E) induces an electrical dipole in the nanowires (1) by separation of positive and negative charge carriers towards opposite ends of the nanowires (1), which contributes to the electrical dipole moment being formed along the nanowires (1).
3. The method of any of claims 1-2, further comprising illuminating at least a sub-population of nanowires (1) with light in pre-determined wavelength region that contributes to formation of the electrical dipole moment of the nanowires.
4. The method of claim 3, wherein the population of nanowires ( 1) comprises a plurality of sub-populations of nanowires, the nanowires of each sub- population having different bandgaps, and the method further comprises selectively illuminating the population of nanowires with light in different wavelength regions in order to selectively align nanowires having different bandgaps.
5. The method of any of claims 1-4, wherein the nanowires are provided dispersed in a fluid.
6. The method of any of claims 1-5, further comprising fixating of the
nanowires ( 1) in an aligned position.
7. The method of any of claims 1-6, further comprising deposition of the
nanowires (1) on a substrate (2)
8. The method of claim 7, wherein each nanowire of at least a sub-population of nanowires carry a net charge, and the electrical field (E) exerts a force on the nanowires carrying a net charge, whereby the nanowires carrying a net charge migrate towards, and are deposited on, the substrate (2).
9. The method of claim 7 or 8, wherein each nanowire of at least a sub- population of the nanowires is uncharged, and the electrical field (E) exerts a force on the uncharged nanowires due to the electrical dipole, whereby the uncharged nanowires migrate towards, and are deposited on, the substrate (2).
10. The method of any of claims 7-9, wherein each nanowire of at least a sub- population of the nanowires is uncharged, and the nanowires being uncharged migrate towards, and are deposited on, the substrate (2) by means of diffusion.
1 1. The method of any of claims 7- 10, wherein the substrate comprises an adhesion layer.
12. The method of any of claims 7- 10, wherein the nanowires are deposited in a continuous process.
13. The method of claim 12, wherein said population of nanowires are
repeatedly provided and deposited in a pre-determined configuration along the substrate (2) in a roll-to-roll process.
14. The method of any of claims 7- 13, further comprising depositing an
insulating polymer to fill a space between the nanowires.
15. The method of any of claims 7- 14, further comprising depositing an
electrode material that electrically connects to one end of the aligned nanowires opposed to the substrate (2).
16. The method of claim 1, wherein the electrical field is applied by a first electrode and a second electrode arranged on opposite sides of said population of nanowires and at least one of the electrodes is textured.
17. The method of claim 1, wherein the nanowires are subjected to a field
gradient, whereby longer and thinner wires are subjected to a stronger force due to the field gradient and will thus move faster toward the regions with higher fields.
18 A device for classifying nanowires according to size and/or material,
comprising means for providing an electric field gradient, and means for passing a flow of charged or uncharged nanowires through said field gradient, whereby longer, thinner and more polarizable wires are subjected to stronger attractive forces towards higher electric field regions, and can thus be classified.
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