WO2011071380A1 - Method for manufacturing a multilayer structure with a lateral pattern for application in the xuv wavelength range, and bf and lmag structures manufactured according to this method - Google Patents
Method for manufacturing a multilayer structure with a lateral pattern for application in the xuv wavelength range, and bf and lmag structures manufactured according to this method Download PDFInfo
- Publication number
- WO2011071380A1 WO2011071380A1 PCT/NL2010/050832 NL2010050832W WO2011071380A1 WO 2011071380 A1 WO2011071380 A1 WO 2011071380A1 NL 2010050832 W NL2010050832 W NL 2010050832W WO 2011071380 A1 WO2011071380 A1 WO 2011071380A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- multilayer structure
- lateral
- pattern
- layers
- boron carbide
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 42
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 11
- 230000003287 optical effect Effects 0.000 claims abstract description 13
- 238000001127 nanoimprint lithography Methods 0.000 claims abstract description 10
- 230000005670 electromagnetic radiation Effects 0.000 claims abstract description 3
- 239000000463 material Substances 0.000 claims description 32
- INAHAJYZKVIDIZ-UHFFFAOYSA-N boron carbide Chemical compound B12B3B4C32B41 INAHAJYZKVIDIZ-UHFFFAOYSA-N 0.000 claims description 19
- 229910052580 B4C Inorganic materials 0.000 claims description 17
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 12
- 229910052799 carbon Inorganic materials 0.000 claims description 11
- 230000000737 periodic effect Effects 0.000 claims description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 10
- 239000011651 chromium Substances 0.000 claims description 9
- 229910052746 lanthanum Inorganic materials 0.000 claims description 9
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 8
- 229910052710 silicon Inorganic materials 0.000 claims description 7
- 229910052721 tungsten Inorganic materials 0.000 claims description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 6
- 229910052706 scandium Inorganic materials 0.000 claims description 6
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 claims description 6
- 239000010703 silicon Substances 0.000 claims description 6
- 230000007704 transition Effects 0.000 claims description 6
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 6
- 239000010937 tungsten Substances 0.000 claims description 6
- 229910052804 chromium Inorganic materials 0.000 claims description 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 4
- 239000011733 molybdenum Substances 0.000 claims description 4
- 229910052759 nickel Inorganic materials 0.000 claims description 4
- 238000001020 plasma etching Methods 0.000 claims description 4
- 238000005530 etching Methods 0.000 claims description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 2
- 229910039444 MoC Inorganic materials 0.000 claims description 2
- 229910052796 boron Inorganic materials 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- 238000009616 inductively coupled plasma Methods 0.000 claims description 2
- 229910052741 iridium Inorganic materials 0.000 claims description 2
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 229910052750 molybdenum Inorganic materials 0.000 claims description 2
- HBVFXTAPOLSOPB-UHFFFAOYSA-N nickel vanadium Chemical compound [V].[Ni] HBVFXTAPOLSOPB-UHFFFAOYSA-N 0.000 claims description 2
- 239000004033 plastic Substances 0.000 claims description 2
- 229920003023 plastic Polymers 0.000 claims description 2
- 229910052702 rhenium Inorganic materials 0.000 claims description 2
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims description 2
- 230000005855 radiation Effects 0.000 description 8
- 239000006185 dispersion Substances 0.000 description 7
- 238000010894 electron beam technology Methods 0.000 description 5
- 238000002310 reflectometry Methods 0.000 description 5
- 230000007423 decrease Effects 0.000 description 4
- 238000001459 lithography Methods 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- 238000000206 photolithography Methods 0.000 description 2
- 241000446313 Lamella Species 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- 238000003491 array Methods 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000025 interference lithography Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000005329 nanolithography Methods 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y10/00—Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/24—Coupling light guides
- G02B6/26—Optical coupling means
- G02B6/34—Optical coupling means utilising prism or grating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/08—Mirrors
- G02B5/0891—Ultraviolet [UV] mirrors
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F1/00—Originals for photomechanical production of textured or patterned surfaces, e.g., masks, photo-masks, reticles; Mask blanks or pellicles therefor; Containers specially adapted therefor; Preparation thereof
- G03F1/22—Masks or mask blanks for imaging by radiation of 100nm or shorter wavelength, e.g. X-ray masks, extreme ultraviolet [EUV] masks; Preparation thereof
- G03F1/24—Reflection masks; Preparation thereof
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/0002—Lithographic processes using patterning methods other than those involving the exposure to radiation, e.g. by stamping
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21K—TECHNIQUES FOR HANDLING PARTICLES OR IONISING RADIATION NOT OTHERWISE PROVIDED FOR; IRRADIATION DEVICES; GAMMA RAY OR X-RAY MICROSCOPES
- G21K1/00—Arrangements for handling particles or ionising radiation, e.g. focusing or moderating
- G21K1/06—Arrangements for handling particles or ionising radiation, e.g. focusing or moderating using diffraction, refraction or reflection, e.g. monochromators
- G21K1/062—Devices having a multilayer structure
Definitions
- the invention relates to a method for manufacturing a multilayer structure with a lateral pattern, in particular of an optical grating for application in an optical device for electromagnetic radiation with a wavelength in the wavelength range between 0.1 nro and 100 nm, comprising the steps of (i) providing a multilayer structure, and (ii) arranging a
- the wavelength range between 0.1 nm and 10 m comprises the hard X-ray range ⁇ wavelength between 0.1 nm and 10 nm) and the so-called XUV range ⁇ wavelength between 10 nm and 100 nm) which includes the range around a wavelength of 13.5 nm, referred to in literature as EUV radiation, as well as
- Such an optical grating is for instance applied in the production of semiconductor circuits within the technical field of nanolithography .
- a particular example of such an optical grating is a so-called nano-Bragg-Fresnel (BF) structure, which forms a combination of a reflective optical element, a Bragg grating , a so-called nano-Bragg-Fresnel (BF) structure, which forms a combination of a reflective optical element, a Bragg grating , a so-called nano-Bragg-Fresnel (BF) structure, which forms a combination of a reflective optical element, a Bragg
- BF nano-Bragg-Fresnel
- LMAG lamellar multilayer amplitude grating
- DOV photolithography encounters problems of a fundamental nature at resolution levels in the structure to be
- Both methods have the drawback that the width of a lamella in a periodic lateral pattern amounts to a minimum of several hundred nanometres, while the period amounts to at least one pm.
- step (ii) of arranging the lateral pattern is performed by means of a method for nano- imprint lithography (NIL) .
- the method for nano-imprint lithography for instance comprises at least the steps of (a) providing a stamp with a stamp pattern corresponding to the lateral three-dimensional pattern to be arranged, (b) applying a layer of a curable resist material to the multilayer
- step (c) arranging the stamp pattern, using the stamp, in the layer of resist material applied according to step (b) , and curing this material, and (d) removing from the multilayer structure material not, or at least substantially not covered by resist material in accordance with the stamp pattern while forming the lateral three-dimensional pattern in the multilayer structure.
- a metal layer is deposited, prior to step (b) or following step ⁇ c) , onto the multilayer structure which is flat or provided with a lateral pattern, and is subsequently applied as etching mask.
- the stamp to be provided according to the invention is for instance manufactured from Si or S1O 2 (quartz) , in which the stamp pattern is arranged in accordance with a per se known method, for instance by means of electron beam
- EBL lithography
- laser interference lithography lithography
- the layer of resist material is removed using a solvent, and the multilayer structure provided with a three-dimensional pattern can be subjected to a subsequent process step.
- step (d) is for instance performed in accordance with a method for reactive ion etching (RIE) , by means of an inductively coupled plasma (ICP) or according to a Bosch-type etching method.
- RIE reactive ion etching
- ICP inductively coupled plasma
- the lateral three-dimensional pattern to be formed in the multilayer structure in step (d) is given a parallel, widening wedge-shaped or narrowing wedge-shaped form from the surface of the multilayer structure.
- the resist material to be applied according to step (b) is preferably a UV-curable plastic which in cured state has a relatively low viscosity, for instance a polymethyl
- PMMA methacrylate
- step (ii) of arranging the lateral pattern is followed by step (iii) of applying a cover layer over the three-dimensional pattern.
- the invention also relates to a multilayer structure with a periodic lateral pattern manufactured according to the above described method, wherein the period is smaller than 1 ⁇ .
- the invention also relates to a BF structure manufactured according to the above described method, wherein the
- multilayer structure comprises a stack of layers of a first material from a first group comprising carbon (C) and silicon (Si) and of layers of a second material from a second group comprising the materials from the groups of transition elements from the fourth, fifth and sixth period of the periodic system of elements.
- the layers of the second material are selected from the group of transition elements comprising cobalt (Co) , nickel (Ni) , molybdenum (Mo) , tungsten (W) , rhenium (Re) and iridium (Ir) .
- an optical element becomes available which can be applied for wavelength selection, focusing and collimation of radiation in the wavelength range between 0.1 nm and 100 nm with an efficiency which is not achievable with a prior art
- the invention further relates to an LMAG structure manufactured according to the above described method, wherein the multilayer structure comprises a stack of layers of a first material from a first group comprising boron (B), boron carbide (B 4 C) , carbon (C) , silicon (Si) and scandium (Sc) , and of layers of a second material from a second group comprising the materials from the groups of transition elements from the fourth, fifth and sixth period of the periodic system of elements.
- B boron
- B 4 C boron carbide
- C carbon
- Si silicon
- Sc scandium
- the multilayer structure is selected from the group comprising stacks of layers of tungsten and silicon (W/Si) , tungsten and boron carbide (W/B 4 C) , molybdenum and boron carbide (M0/B 4 C) , lanthanum and boron carbide (La/B 4 C) , chromium and carbon (Cr/C) , iron and scandium (Fe/Sc), chromium and scandium (Cr/Sc) , nickel and carbon (Ni/C) and nickel vanadium and carbon (NiV/C)
- a multilayer structure comprising a stack of layers of lanthanum and boron carbide (La B4C) the layers of lanthanum and boron carbide are separated by layers of lanthanum boride (LaB) , these layers functioning as diffusion barrier.
- La B4C lanthanum and boron carbide
- an optical element becomes available which can be applied for wavelength selection, focusing and collimation of radiation in the wavelength range between 0.1 nm and 100 nm with an efficiency which is not achievable with a prior art
- FIG. 1 shows a schematic representation of the application of an LMAG structure 1 according to the invention as monochromator .
- LMAG structure 1 is formed by a substrate 2, for instance of Si0 2 , having thereon a
- a beam of XUV radiation (represented by arrow 5) with a wavelength ⁇ 0 is incident upon the surface of LMAG-structure 1 at an angle ⁇ > to the surface of LMAG-structure 1.
- the incident beam is diffracted by LMAG-structure 1 in an exiting zeroth order beam I 0 , first order beams Ii, I-i, second order beams I2, I-2 and higher order beams (not shown) . It has been found that using an LMAG structure 1
- a monochromator can be provided which has a markedly lower dispersion (higher resolution) than with a flat, otherwise identical multilayer structure without lateral structure, wherein the reflectivity of the LMAG structure decreases to only slight extent compared to the reflectivity of the flat multilayer structure.
- An LMAG structure 1 according to fig. 1 is constructed from a periodic stack of 150 layers 3 consisting of Cr (layer thickness 2.125 nm, roughness 0.312 nm) and layers 4
- An LMAG structure 1 according to fig. 1 is constructed from a periodic stack of 400 layers 3 consisting of W (layer thickness 0.715 nm, roughness 0.248 nm) and layers 4
Landscapes
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- General Physics & Mathematics (AREA)
- Nanotechnology (AREA)
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Optics & Photonics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Manufacturing & Machinery (AREA)
- Spectroscopy & Molecular Physics (AREA)
- General Engineering & Computer Science (AREA)
- High Energy & Nuclear Physics (AREA)
- Mathematical Physics (AREA)
- Theoretical Computer Science (AREA)
- Diffracting Gratings Or Hologram Optical Elements (AREA)
- Shaping Of Tube Ends By Bending Or Straightening (AREA)
- Exposure Of Semiconductors, Excluding Electron Or Ion Beam Exposure (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2012543036A JP5782451B2 (en) | 2009-12-11 | 2010-12-08 | Method for manufacturing a multilayer structure having a lateral pattern for use in the XUV wavelength range, and a BF structure and an LMAG structure manufactured by this method |
US13/515,127 US20130220971A1 (en) | 2009-12-11 | 2010-12-08 | Method for manufacturing a multilayer structure with a lateral pattern for application in the xuv wavelength range, and bf and lmag structures manufactured according to this method |
EP10796182.3A EP2510397B1 (en) | 2009-12-11 | 2010-12-08 | Method for manufacturing a multilayer structure with a lateral pattern for application in the xuv wavelength range, and bf and lmag structures manufactured according to this method |
CN2010800560817A CN102792222A (en) | 2009-12-11 | 2010-12-08 | Method for manufacturing a multilayer structure with a lateral pattern for application in the XUV wavelength range, and BF and LMAG structures manufactured according to this method |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL2003950A NL2003950C2 (en) | 2009-12-11 | 2009-12-11 | METHOD FOR MANUFACTURING A MULTI-LAYER STRUCTURE WITH A LATERAL PATTERN FOR USE IN THE XUV WAVE LENGTH AREA AND BT AND LMAG STRUCTURES MANUFACTURED BY THIS METHOD. |
NL2003950 | 2009-12-11 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2011071380A1 true WO2011071380A1 (en) | 2011-06-16 |
Family
ID=42307776
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/NL2010/050832 WO2011071380A1 (en) | 2009-12-11 | 2010-12-08 | Method for manufacturing a multilayer structure with a lateral pattern for application in the xuv wavelength range, and bf and lmag structures manufactured according to this method |
Country Status (6)
Country | Link |
---|---|
US (1) | US20130220971A1 (en) |
EP (1) | EP2510397B1 (en) |
JP (1) | JP5782451B2 (en) |
CN (1) | CN102792222A (en) |
NL (1) | NL2003950C2 (en) |
WO (1) | WO2011071380A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103018819A (en) * | 2012-11-09 | 2013-04-03 | 浙江大学 | Method for preparing high polymer micro-nano fiber bragg grating based on nanoimprint lithography |
US20130220971A1 (en) * | 2009-12-11 | 2013-08-29 | Panalytical B.V. | Method for manufacturing a multilayer structure with a lateral pattern for application in the xuv wavelength range, and bf and lmag structures manufactured according to this method |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101827814B1 (en) * | 2016-04-15 | 2018-02-12 | 한국기계연구원 | Manufacturing method of three dimension structure using the nano imprinting means |
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- 2010-12-08 US US13/515,127 patent/US20130220971A1/en not_active Abandoned
- 2010-12-08 EP EP10796182.3A patent/EP2510397B1/en active Active
- 2010-12-08 CN CN2010800560817A patent/CN102792222A/en active Pending
- 2010-12-08 WO PCT/NL2010/050832 patent/WO2011071380A1/en active Application Filing
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20130220971A1 (en) * | 2009-12-11 | 2013-08-29 | Panalytical B.V. | Method for manufacturing a multilayer structure with a lateral pattern for application in the xuv wavelength range, and bf and lmag structures manufactured according to this method |
CN103018819A (en) * | 2012-11-09 | 2013-04-03 | 浙江大学 | Method for preparing high polymer micro-nano fiber bragg grating based on nanoimprint lithography |
CN103018819B (en) * | 2012-11-09 | 2014-05-21 | 浙江大学 | Method for preparing high polymer micro-nano fiber bragg grating based on nanoimprint lithography |
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JP2013513940A (en) | 2013-04-22 |
EP2510397B1 (en) | 2015-01-14 |
JP5782451B2 (en) | 2015-09-24 |
NL2003950C2 (en) | 2011-06-15 |
CN102792222A (en) | 2012-11-21 |
EP2510397A1 (en) | 2012-10-17 |
US20130220971A1 (en) | 2013-08-29 |
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