WO2011057400A1 - Compressible dual resin thermoplastic welding rod and method for electric resistance thermoplastic welding - Google Patents

Compressible dual resin thermoplastic welding rod and method for electric resistance thermoplastic welding Download PDF

Info

Publication number
WO2011057400A1
WO2011057400A1 PCT/CA2010/001791 CA2010001791W WO2011057400A1 WO 2011057400 A1 WO2011057400 A1 WO 2011057400A1 CA 2010001791 W CA2010001791 W CA 2010001791W WO 2011057400 A1 WO2011057400 A1 WO 2011057400A1
Authority
WO
WIPO (PCT)
Prior art keywords
inner core
thermoplastic
thermoplastic resin
welding rod
resin
Prior art date
Application number
PCT/CA2010/001791
Other languages
French (fr)
Inventor
Robert Pinder
Original Assignee
Powercore International Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Powercore International Ltd. filed Critical Powercore International Ltd.
Priority to US13/509,550 priority Critical patent/US20120231272A1/en
Publication of WO2011057400A1 publication Critical patent/WO2011057400A1/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/70General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/73General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset
    • B29C66/739General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset
    • B29C66/7392General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of at least one of the parts being a thermoplastic
    • B29C66/73921General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of at least one of the parts being a thermoplastic characterised by the materials of both parts being thermoplastics
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/02Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
    • B29C65/34Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement"
    • B29C65/3404Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement" characterised by the type of heated elements which remain in the joint
    • B29C65/342Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement" characterised by the type of heated elements which remain in the joint comprising at least a single wire, e.g. in the form of a winding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/02Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
    • B29C65/34Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement"
    • B29C65/3472Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement" characterised by the composition of the heated elements which remain in the joint
    • B29C65/3476Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement" characterised by the composition of the heated elements which remain in the joint being metallic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/02Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
    • B29C65/34Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement"
    • B29C65/3472Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement" characterised by the composition of the heated elements which remain in the joint
    • B29C65/3476Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement" characterised by the composition of the heated elements which remain in the joint being metallic
    • B29C65/348Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement" characterised by the composition of the heated elements which remain in the joint being metallic with a polymer coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/01General aspects dealing with the joint area or with the area to be joined
    • B29C66/05Particular design of joint configurations
    • B29C66/10Particular design of joint configurations particular design of the joint cross-sections
    • B29C66/11Joint cross-sections comprising a single joint-segment, i.e. one of the parts to be joined comprising a single joint-segment in the joint cross-section
    • B29C66/112Single lapped joints
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/01General aspects dealing with the joint area or with the area to be joined
    • B29C66/05Particular design of joint configurations
    • B29C66/10Particular design of joint configurations particular design of the joint cross-sections
    • B29C66/11Joint cross-sections comprising a single joint-segment, i.e. one of the parts to be joined comprising a single joint-segment in the joint cross-section
    • B29C66/112Single lapped joints
    • B29C66/1122Single lap to lap joints, i.e. overlap joints
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/01General aspects dealing with the joint area or with the area to be joined
    • B29C66/05Particular design of joint configurations
    • B29C66/10Particular design of joint configurations particular design of the joint cross-sections
    • B29C66/13Single flanged joints; Fin-type joints; Single hem joints; Edge joints; Interpenetrating fingered joints; Other specific particular designs of joint cross-sections not provided for in groups B29C66/11 - B29C66/12
    • B29C66/131Single flanged joints, i.e. one of the parts to be joined being rigid and flanged in the joint area
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/50General aspects of joining tubular articles; General aspects of joining long products, i.e. bars or profiled elements; General aspects of joining single elements to tubular articles, hollow articles or bars; General aspects of joining several hollow-preforms to form hollow or tubular articles
    • B29C66/51Joining tubular articles, profiled elements or bars; Joining single elements to tubular articles, hollow articles or bars; Joining several hollow-preforms to form hollow or tubular articles
    • B29C66/52Joining tubular articles, bars or profiled elements
    • B29C66/522Joining tubular articles
    • B29C66/5221Joining tubular articles for forming coaxial connections, i.e. the tubular articles to be joined forming a zero angle relative to each other
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/48Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
    • B29C65/4805Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding characterised by the type of adhesives
    • B29C65/481Non-reactive adhesives, e.g. physically hardening adhesives
    • B29C65/4815Hot melt adhesives, e.g. thermoplastic adhesives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/48Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
    • B29C65/50Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding using adhesive tape, e.g. thermoplastic tape; using threads or the like
    • B29C65/5057Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding using adhesive tape, e.g. thermoplastic tape; using threads or the like positioned between the surfaces to be joined
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/82Testing the joint
    • B29C65/8207Testing the joint by mechanical methods
    • B29C65/8246Pressure tests, e.g. hydrostatic pressure tests
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/70General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/71General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the composition of the plastics material of the parts to be joined
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/70General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/73General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset
    • B29C66/731General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the intensive physical properties of the material of the parts to be joined
    • B29C66/7315Mechanical properties
    • B29C66/73151Hardness
    • B29C66/73152Hardness of different hardness, i.e. the hardness of one of the parts to be joined being different from the hardness of the other part
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913Rod, strand, filament or fiber
    • Y10T428/2933Coated or with bond, impregnation or core
    • Y10T428/2936Wound or wrapped core or coating [i.e., spiral or helical]

Definitions

  • the present invention relates generally to thermoplastic welding and, in particular, to thermoplastic welding using thermoplastic welding rod.
  • thermoplastic welding technology enables thermoplastic components to be electrofused, or welded, together.
  • HEWR homogenous electrofusion welding rod
  • the present invention provides a novel compressible dual resin electrofusion welding rod (DREWR) and method of welding using this DREWR.
  • the DREWR comprises a soft inner core and a hard outer coating with a resistance wire wrapped around the inner core or otherwise embedded within the outer coating. Due to the soft inner core, the DREWR is easily compressible when cold, unlike conventional HEWR which is not compressible unless heated. Accordingly, the compressible DREWR is able to deform and dimensionally adapt to the surfaces or objects that are to be conjoined, unlike the harder HEWR which, if not seated or positioned precisely, may leave an unwanted gap or space between the surfaces or objects to be joined.
  • the deformability of the rod is made possible by the concentric hard outer coating and soft inner core.
  • the first thermoplastic in the soft inner core may be made of thermoplastic vulcanizate (TPV) while the second thermoplastic resin of the outer coating may be made of a high-density polyethylene (HDPE) .
  • TPV thermoplastic vulcan
  • the compressible dual resin electrofusion welding rod enables a novel method of welding thermoplastics. While this novel method may be used in a broad range of applications, it is particularly useful in welding a pipe spigot to a pipe bell.
  • a method of thermoplastic welding entails providing a compressible dual resin thermoplastic welding rod having an inner core made of a soft first thermoplastic resin, a resistance wire wrapped around the inner core, and an outer coating surrounding the inner core and wire, the outer coating being made of a second thermoplastic resin that is harder than the first thermoplastic resin of the inner core.
  • the method further involves positioning the welding rod at an interface of two surfaces to join and heating the resistance wire to weld the two surfaces together.
  • a compressible dual resin thermoplastic welding rod includes an inner core made of a soft first thermoplastic resin, a resistance wire wrapped around the inner core, and an outer coating surrounding the inner core and wire.
  • the outer coating is made of a second thermoplastic resin that is harder than the first thermoplastic resin of the inner core.
  • the first thermoplastic is made of thermoplastic vulcanizate (TPV) while the second thermoplastic resin is made of a high-density polyethylene (HDPE) .
  • a method of manufacturing a compressible dual resin thermoplastic welding rod entails providing a substantially cylindrical inner core made of a soft first thermoplastic resin, wrapping a resistance wire around the inner core, and coating the inner core and wire with a second thermoplastic resin that is harder than the first thermoplastic resin of the inner core.
  • FIG. 1 is a front view of a homogenous electrofusion welding rod (HEWR) ;
  • FIG. 2 is a front view of the same HEWR, depicting substantial resistance to compression or deformation when cold;
  • FIG. 3 is a cross-sectional view of a pipe spigot misaligned within a pipe bell and the resulting gap that is likely to be created when using the generally incompressible HEWR;
  • FIG. 4 is a front view of a dual resin electrofusion welding rod (DREWR) in accordance with embodiments of the present invention
  • FIG. 5 is a front view of the same DREWR, depicting its cold-state compressibility
  • FIG. 6 is a cross-sectional view of a pipe spigot misaligned within a pipe bell, depicting how the compressible dual resin electrofusion welding rod compensates for the misalignment by deforming to the non-uniform annular gap between the spigot and the bell;
  • FIG. 7 is a flowchart depicting steps of a method of thermoplastic welding in accordance with embodiments of the present invention.
  • FIG. 8 is a flowchart depicting steps of a method of manufacturing a compressible dual resin thermoplastic welding rod in accordance with embodiments of the present invention.
  • the present invention is directed to a compressible dual resin electrofusion welding rod and a method of using this rod to perform thermoplastic welding.
  • a method of manufacturing this novel dual resin electrofusion welding rod is also disclosed herein .
  • a novel compressible dual resin electrofusion welding rod also referred to herein as a "compressible dual resin thermoplastic welding rod” or simply as the “welding rod”
  • This dual resin welding rod 10 includes an inner core 12 made of a soft first thermoplastic resin.
  • the DREWR also includes a resistance wire 14 wrapped around the inner core and an outer coating 16 surrounding the inner core and wire.
  • the outer coating is made of a second thermoplastic resin that is harder than the first thermoplastic resin of the inner core.
  • the dual resin welding rod is compressible even when cold, unlike its homogeneous (single resin) counterpart (depicted in FIG. 1) which not compressible when cold, as shown in FIG. 2.
  • both the inner core 12a and the outer coating 12b are made of the same thermoplastic material.
  • the first thermoplastic resin is thermoplastic vulcanizate (TPV) .
  • the second thermoplastic resin is high-density polyethylene (HDPE) .
  • the welding rod is made of thermoplastic vulcanizate (TPV) in the inner core and high- density polyethylene (HDPE) for the outer coating.
  • the welding rod has a relatively thin annular outer coating that is smaller in dimension than the radius of the inner core.
  • a radius of the inner core is greater than an annular thickness of the outer coating.
  • the novel dual resin electrofusion welding rod disclosed in this application enables an innovative method for thermoplastic welding.
  • this innovative method entails a step 100 of providing a compressible dual resin thermoplastic welding rod having an inner core made of a soft first thermoplastic resin, a resistance wire wrapped around the inner core and an outer coating surrounding the inner core and wire, the outer coating being made of a second thermoplastic resin that is harder than the first thermoplastic resin of the inner core.
  • the method then involves a step 110 of positioning the welding rod at an interface of two surfaces to join and then (at step 120) heating the resistance wire to weld the two surfaces together.
  • This method can be applied to a broad range of thermoplastic welding applications.
  • One such application where this novel technology is especially useful is in the context of welding pipes, particularly pipe spigots to pipe bells as shown by way of example in FIG. 6.
  • Welding a pipe spigot 20 to a respective pipe bell 22 is technically difficult using the conventional HEWR 24 because this rigid, generally non-pliable, non-malleable rod does not deform or adapt to the imperfections of the pipe spigot or pipe bell. This is depicted in FIG. 3. Clamping (not shown but well understood in the art) is sometimes necessary to ensure a proper weld.
  • FIG. 3 Clamping (not shown but well understood in the art) is sometimes necessary to ensure a proper weld.
  • the novel technology disclosed herein provides a deformable (malleable, pliable) dual resin welding rod 26 that conforms to the dimensional imperfections of the pipe spigot 20 and pipe bell 22, thereby providing a much better weld and a much more solid and reliable fluid-tight seal.
  • the welding rod is positioned in an annular gap between an outer diameter of a pipe spigot and an inner diameter of a pipe bell. Even if the pipe spigot is improperly aligned relative to the pipe bell as depicted in FIG. 6, the compressible nature of this dual resin welding rod compensates for this misalignment and provides for a good seal.
  • this novel compressible dual resin thermoplastic welding rod may be manufactured according to the following method: first, at step 200, a substantially cylindrical inner core made of a soft first thermoplastic resin is produced (moulded and/or machined) to the correct diameter and length. Then, at step 210, this inner core is wrapped with a resistance wire of a suitable gauge and cut to an appropriate length. Finally, at step 220, the inner core and wire are encapsulated in an outer (annular) coating made of a second thermoplastic resin that is harder than the first thermoplastic resin of the inner core.
  • the first thermoplastic resin may be thermoplastic vulcanizate (TPV) and the second thermoplastic resin may be high-density polyethylene (HDPE) , although other materials may be substituted as will be appreciated by those of ordinary skill in the art.
  • TPV thermoplastic vulcanizate
  • HDPE high-density polyethylene
  • the welding rod may have an additional middle annular band, thus effectively creating a triple resin electrofusion welding rod (with an inner core made of a first resin, a middle annular band made of a second resin and an outer coating made of a third resin.
  • the inner core could be hollow, i.e. the inner core rather than being a solid cylinder could be tubular with an axial air gap extending along the central axis.
  • the inner core could be removed altogether such that the welding rod is tubular in construction and is composed solely of one annular resin component. Even if the annular resin component is hard/stiff HDPE, it would be compressible because it is annular and has no internal core. [0037] Another variant would be to put the HDPE in the inside (as the inner core) and the PVT on the outside (as the outer coating) .
  • both the inner core and outer coating could be made of the same (or similar) compressible material, e.g. both the inner core and the outer coating could be made of TPV.
  • the outer coating may be made of a harder TPV than the inner core.
  • this novel dual resin rod can be made into a cylindrical coil to create a wide fusion bond (as in the bell and spigot drawing shown in FIG. 6) whereas a compression gasket has to be made into a single ring.
  • Another innovative aspect of this technology is that two coils may be placed in a bell to create a sealed air void between the two, once welded. In this manner, an air pressure test can be performed when assembling the pipe to ensure that there is a good seal. This can all be accomplished from the outside with simple tools, something that is impossible now with pre-existing technology.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Lining Or Joining Of Plastics Or The Like (AREA)
  • Branch Pipes, Bends, And The Like (AREA)

Abstract

An innovative method of thermoplastic electrofusion welding uses a novel compressible dual resin thermoplastic welding rod. This welding rod comprises an inner core made of a soft first thermoplastic resin, a resistance wire wrapped around the inner core, and an outer coating surrounding the inner core and wire. The outer coating is made of a second thermoplastic resin that is harder than the first thermoplastic resin of the inner core. The first thermoplastic may be made of thermoplastic vulcanizate (TPV). The second thermoplastic resin may be made of a high-density polyethylene (HDPE). Because of its compressibility, this dual resin electrofusion welding rod greatly facilitates the seating of parts that are to be welded together.

Description

COMPRESSIBLE DUAL RESIN THERMOPLASTIC WELDING ROD AND METHOD FOR ELECTRIC RESISTANCE THERMOPLASTIC WELDING
TECHNICAL FIELD
[0001] The present invention relates generally to thermoplastic welding and, in particular, to thermoplastic welding using thermoplastic welding rod.
BACKGROUND
[0002] Thermoplastic welding technology enables thermoplastic components to be electrofused, or welded, together.
[0003] Some notable improvements in this field of technology are disclosed in United States Patent 5,407,520 (Butts et al.) entitled "Welding rod" and in United States Patent 5,407,514 (Butts et al . ) entitled "Method for welding thermoplastic materials". These patent disclose an improved welding rod having a solid homogeneous core of thermoplastic material and a resistance element comprised of a plurality of wires. The welding rod is positioned between members of the thermoplastic material to be welded and a current and pressure is applied to the resistance element causing the thermoplastic material of the solid core and the adjacent thermoplastic members to fuse and form a unitary weld. Simultaneously the electrical resistance element is embedded in the weld, mechanically reinforcing and strengthening the connection. These patents also disclose a method for electric fusion welding of thermoplastic members wherein the welding rod is pre-attached to one of the thermoplastic members.
[0004] One problem that has arisen in the use of homogenous electrofusion welding rod (HEWR) is positioning of the rod. Because the HEWR is made of a hard (stiff) thermoplastic resin, the rod may not seat properly between uneven thermoplastic part surfaces to be joined. As a result of imprecise positioning, some of the HEWR may not come into contact with the two parts to be joined, thereby causing localized overheating or an incomplete fusion bond due to imperfect contact.
[0005] Furthermore, parts must fit together with close machined tolerances to allow the HEWR to fit between parts prior to welding (when cold) and then must be clamped to ensure contact during the welding process. In some cases, high tolerance machining and clamping is not possible.
[0006] For example, large diameter plastic bell and spigot plastic pipe often varies slightly in diameter and roundness, thus resulting in poor contact around the mating surface, i.e. at the interface. This makes fluid-tight seals hard to achieve .
[0007] Accordingly, making a good fusion bond using a homogeneous electrofusion welding rod (HEWR) is extremely difficult. This has remained a technical problem for which an adequate solution has, until now, yet to be devised.
SUMMARY
[0008] The present invention provides a novel compressible dual resin electrofusion welding rod (DREWR) and method of welding using this DREWR. The DREWR comprises a soft inner core and a hard outer coating with a resistance wire wrapped around the inner core or otherwise embedded within the outer coating. Due to the soft inner core, the DREWR is easily compressible when cold, unlike conventional HEWR which is not compressible unless heated. Accordingly, the compressible DREWR is able to deform and dimensionally adapt to the surfaces or objects that are to be conjoined, unlike the harder HEWR which, if not seated or positioned precisely, may leave an unwanted gap or space between the surfaces or objects to be joined. The deformability of the rod is made possible by the concentric hard outer coating and soft inner core. For example, the first thermoplastic in the soft inner core may be made of thermoplastic vulcanizate (TPV) while the second thermoplastic resin of the outer coating may be made of a high-density polyethylene (HDPE) .
[0009] As will be elaborated below, the compressible dual resin electrofusion welding rod enables a novel method of welding thermoplastics. While this novel method may be used in a broad range of applications, it is particularly useful in welding a pipe spigot to a pipe bell.
[0010] In accordance with one main aspect of the present invention, a method of thermoplastic welding entails providing a compressible dual resin thermoplastic welding rod having an inner core made of a soft first thermoplastic resin, a resistance wire wrapped around the inner core, and an outer coating surrounding the inner core and wire, the outer coating being made of a second thermoplastic resin that is harder than the first thermoplastic resin of the inner core. The method further involves positioning the welding rod at an interface of two surfaces to join and heating the resistance wire to weld the two surfaces together.
[0011] In accordance with another main aspect of the present invention, a compressible dual resin thermoplastic welding rod includes an inner core made of a soft first thermoplastic resin, a resistance wire wrapped around the inner core, and an outer coating surrounding the inner core and wire. The outer coating is made of a second thermoplastic resin that is harder than the first thermoplastic resin of the inner core. In certain embodiments, the first thermoplastic is made of thermoplastic vulcanizate (TPV) while the second thermoplastic resin is made of a high-density polyethylene (HDPE) .
[0012] In accordance with yet another aspect of the present invention, a method of manufacturing a compressible dual resin thermoplastic welding rod entails providing a substantially cylindrical inner core made of a soft first thermoplastic resin, wrapping a resistance wire around the inner core, and coating the inner core and wire with a second thermoplastic resin that is harder than the first thermoplastic resin of the inner core.
BRIEF DESCRIPTION OF THE DRAWINGS
[0013] Further features and advantages of the present technology will become apparent from the following detailed description, taken in combination with the appended drawings, in which:
[0014] FIG. 1 is a front view of a homogenous electrofusion welding rod (HEWR) ;
[0015] FIG. 2 is a front view of the same HEWR, depicting substantial resistance to compression or deformation when cold;
[0016] FIG. 3 is a cross-sectional view of a pipe spigot misaligned within a pipe bell and the resulting gap that is likely to be created when using the generally incompressible HEWR;
[0017] FIG. 4 is a front view of a dual resin electrofusion welding rod (DREWR) in accordance with embodiments of the present invention;
[0018] FIG. 5 is a front view of the same DREWR, depicting its cold-state compressibility; [0019] FIG. 6 is a cross-sectional view of a pipe spigot misaligned within a pipe bell, depicting how the compressible dual resin electrofusion welding rod compensates for the misalignment by deforming to the non-uniform annular gap between the spigot and the bell;
[0020] FIG. 7 is a flowchart depicting steps of a method of thermoplastic welding in accordance with embodiments of the present invention; and
[0021] FIG. 8 is a flowchart depicting steps of a method of manufacturing a compressible dual resin thermoplastic welding rod in accordance with embodiments of the present invention.
[0022] It will be noted that throughout the appended drawings, like features are identified by like reference numerals .
DETAILED DESCRIPTION
[0023] In general, and by way of overview, the present invention is directed to a compressible dual resin electrofusion welding rod and a method of using this rod to perform thermoplastic welding. A method of manufacturing this novel dual resin electrofusion welding rod is also disclosed herein .
[0024] DUAL RESIN ELECTROFUSION WELDING ROD (DREWR)
[0025] As depicted by way of example in FIG. 4, a novel compressible dual resin electrofusion welding rod (DREWR) , also referred to herein as a "compressible dual resin thermoplastic welding rod" or simply as the "welding rod", is generally designated by reference numeral 10. This dual resin welding rod 10 includes an inner core 12 made of a soft first thermoplastic resin. The DREWR also includes a resistance wire 14 wrapped around the inner core and an outer coating 16 surrounding the inner core and wire. The outer coating is made of a second thermoplastic resin that is harder than the first thermoplastic resin of the inner core. As shown in FIG. 5, the dual resin welding rod is compressible even when cold, unlike its homogeneous (single resin) counterpart (depicted in FIG. 1) which not compressible when cold, as shown in FIG. 2. In other words, in the conventional homogeneous welding rod depicted in FIG. 1 and FIG. 2, both the inner core 12a and the outer coating 12b are made of the same thermoplastic material.
[0026] In one embodiment, the first thermoplastic resin is thermoplastic vulcanizate (TPV) . In one embodiment, the second thermoplastic resin is high-density polyethylene (HDPE) . In the best mode known to Applicant as of the time of filing this application, the welding rod is made of thermoplastic vulcanizate (TPV) in the inner core and high- density polyethylene (HDPE) for the outer coating.
[0027] As will be appreciated, other resins may be substituted to achieve similarly beneficial effects.
[0028] As shown in the figures, the welding rod has a relatively thin annular outer coating that is smaller in dimension than the radius of the inner core. In other words, a radius of the inner core is greater than an annular thickness of the outer coating.
[0029] METHOD OF THERMOPLASTIC WELDING
[0030] The novel dual resin electrofusion welding rod disclosed in this application enables an innovative method for thermoplastic welding. As depicted in the flowchart presented in FIG. 7 , this innovative method entails a step 100 of providing a compressible dual resin thermoplastic welding rod having an inner core made of a soft first thermoplastic resin, a resistance wire wrapped around the inner core and an outer coating surrounding the inner core and wire, the outer coating being made of a second thermoplastic resin that is harder than the first thermoplastic resin of the inner core. The method then involves a step 110 of positioning the welding rod at an interface of two surfaces to join and then (at step 120) heating the resistance wire to weld the two surfaces together.
[0031] This method can be applied to a broad range of thermoplastic welding applications. One such application where this novel technology is especially useful is in the context of welding pipes, particularly pipe spigots to pipe bells as shown by way of example in FIG. 6. Welding a pipe spigot 20 to a respective pipe bell 22 is technically difficult using the conventional HEWR 24 because this rigid, generally non-pliable, non-malleable rod does not deform or adapt to the imperfections of the pipe spigot or pipe bell. This is depicted in FIG. 3. Clamping (not shown but well understood in the art) is sometimes necessary to ensure a proper weld. In contrast, as depicted in FIG. 6, the novel technology disclosed herein provides a deformable (malleable, pliable) dual resin welding rod 26 that conforms to the dimensional imperfections of the pipe spigot 20 and pipe bell 22, thereby providing a much better weld and a much more solid and reliable fluid-tight seal. As shown in FIG. 6, the welding rod is positioned in an annular gap between an outer diameter of a pipe spigot and an inner diameter of a pipe bell. Even if the pipe spigot is improperly aligned relative to the pipe bell as depicted in FIG. 6, the compressible nature of this dual resin welding rod compensates for this misalignment and provides for a good seal.
[0032] METHOD OF MANUFACTURING THE DREWR
[0033] As depicted in the flowchart presented in FIG. 8, this novel compressible dual resin thermoplastic welding rod may be manufactured according to the following method: first, at step 200, a substantially cylindrical inner core made of a soft first thermoplastic resin is produced (moulded and/or machined) to the correct diameter and length. Then, at step 210, this inner core is wrapped with a resistance wire of a suitable gauge and cut to an appropriate length. Finally, at step 220, the inner core and wire are encapsulated in an outer (annular) coating made of a second thermoplastic resin that is harder than the first thermoplastic resin of the inner core. As noted above, the first thermoplastic resin may be thermoplastic vulcanizate (TPV) and the second thermoplastic resin may be high-density polyethylene (HDPE) , although other materials may be substituted as will be appreciated by those of ordinary skill in the art.
[0034] As will be appreciated by those of ordinary skill in the art, many refinements and modifications may be made to this novel technology without departing from the inventive concept (s) presented herein.
[0035] For example, the welding rod may have an additional middle annular band, thus effectively creating a triple resin electrofusion welding rod (with an inner core made of a first resin, a middle annular band made of a second resin and an outer coating made of a third resin.
[0036] Another possible variation, the inner core could be hollow, i.e. the inner core rather than being a solid cylinder could be tubular with an axial air gap extending along the central axis. As another possible variation, the inner core could be removed altogether such that the welding rod is tubular in construction and is composed solely of one annular resin component. Even if the annular resin component is hard/stiff HDPE, it would be compressible because it is annular and has no internal core. [0037] Another variant would be to put the HDPE in the inside (as the inner core) and the PVT on the outside (as the outer coating) .
[0038] In another embodiment, both the inner core and outer coating could be made of the same (or similar) compressible material, e.g. both the inner core and the outer coating could be made of TPV. In one specific embodiment, the outer coating may be made of a harder TPV than the inner core.
[0039] In addition, this novel dual resin rod can be made into a cylindrical coil to create a wide fusion bond (as in the bell and spigot drawing shown in FIG. 6) whereas a compression gasket has to be made into a single ring.
[0040] Another innovative aspect of this technology is that two coils may be placed in a bell to create a sealed air void between the two, once welded. In this manner, an air pressure test can be performed when assembling the pipe to ensure that there is a good seal. This can all be accomplished from the outside with simple tools, something that is impossible now with pre-existing technology.
[0041] Although there are a number of possible variations, the dual resin welding rod with the solid inner core of PVT and outer coating of HDPE that has been described above is believed to be the best overall solution and the most cost- effective. The variants are presented solely to illustrate the broad applicability of the inventive concept (s) presented herein .
[0042] The embodiments of the invention described above are intended to be exemplary only. As will be appreciated by those of ordinary skill in the art, to whom this specification is addressed, many obvious variations can be made to the embodiments present herein without departing from the spirit and scope of the invention. The scope of the exclusive right sought by the applicant is therefore intended to be limited solely by the appended claims.

Claims

CLAIMS :
1. A method of thermoplastic welding, the method comprising :
providing a compressible dual resin thermoplastic welding rod having:
an inner core made of a soft first thermoplastic resin;
a resistance wire wrapped around the inner core; and an outer coating surrounding the inner core and wire, the outer coating being made of a second thermoplastic resin that is harder than the first thermoplastic resin of the inner core; and
positioning the welding rod at an interface of two surfaces to join; and
heating the resistance wire to weld the two surfaces together .
2. The method as claimed in claim 1 wherein positioning comprises positioning the welding rod in an annular gap between an outer diameter of a pipe spigot and an inner diameter of a pipe bell.
3. The method as claimed in claim 1 or claim 2 wherein the first thermoplastic resin is thermoplastic vulcanizate (TPV) .
4. The method as claimed in any one of claims 1 to 3 wherein the second thermoplastic resin is high-density polyethylene (HDPE) .
The method as claimed in any one of claims 1 to 4 wherein a radius of the inner core is greater than an annular thickness of the outer coating.
A compressible dual resin thermoplastic welding rod comprising :
an inner core made of a soft first thermoplastic resin; a resistance wire wrapped around the inner core; and an outer coating surrounding the inner core and wire, the outer coating being made of a second thermoplastic resin that is harder than the first thermoplastic resin of the inner core.
The welding rod as claimed in claim 6 wherein the first thermoplastic resin is thermoplastic vulcanizate (TPV) .
The welding rod as claimed in claim 6 or claim 7 wherein the second thermoplastic resin is high-density polyethylene (HDPE) .
The welding rod as claimed in any one of claims 6 to 8 wherein a radius of the inner core is greater than an annular thickness of the outer coating.
A method of manufacturing a compressible dual resin thermoplastic welding rod, the method comprising:
providing a substantially cylindrical inner core made of a soft first thermoplastic resin;
wrapping a resistance wire around the inner core; and coating the inner core and wire with a second thermoplastic resin that is harder than the first thermoplastic resin of the inner core.
11. The method as claimed in claim 10 wherein the first thermoplastic resin is thermoplastic vulcanizate (TPV) .
12. The method as claimed in claim 10 or claim 11 wherein the second thermoplastic resin is high-density polyethylene (HDPE) .
13. The method as claimed in any one of claims 10 to 12 wherein the second thermoplastic resin is high-density polyethylene (HDPE) .
PCT/CA2010/001791 2009-11-11 2010-11-10 Compressible dual resin thermoplastic welding rod and method for electric resistance thermoplastic welding WO2011057400A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US13/509,550 US20120231272A1 (en) 2009-11-11 2010-11-10 Compressible dual resin thermoplastic welding rod and method for electric resistance thermoplastic welding

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US26015309P 2009-11-11 2009-11-11
US61/260,153 2009-11-11

Publications (1)

Publication Number Publication Date
WO2011057400A1 true WO2011057400A1 (en) 2011-05-19

Family

ID=43991133

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CA2010/001791 WO2011057400A1 (en) 2009-11-11 2010-11-10 Compressible dual resin thermoplastic welding rod and method for electric resistance thermoplastic welding

Country Status (2)

Country Link
US (1) US20120231272A1 (en)
WO (1) WO2011057400A1 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102012100932A1 (en) 2012-02-06 2013-08-08 Fsave Solartechnik Gmbh Module, particularly for thermal storage tank for fluid, has wall that is closed in circumferential direction, coupling area, in which module is firmly coupled with another module by welding, and holding area or support area for loading bag
EP2835610A1 (en) 2013-08-05 2015-02-11 FSAVE Solartechnik GmbH Module for a thermal storage tank
DE202014105052U1 (en) 2014-10-22 2016-01-25 Enertracting Gmbh Thermal storage tank

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10723080B1 (en) * 2016-01-22 2020-07-28 Infiltrator Water Technologies, Llc Making a plastic tank having a weld joint by using a resilient clamp

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5407514A (en) * 1988-02-03 1995-04-18 E. O. Butts Consultants Ltd. Method for welding thermoplastic materials
US5571435A (en) * 1995-04-26 1996-11-05 Neeco, Inc. Welding rod having parallel electrical pathways
US6149756A (en) * 1996-03-05 2000-11-21 Uponor Innovation Ab Method for joining plastic pipes, a joint ring used in the joining and a pipe joint provided with the method

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20010048223A1 (en) * 1996-05-28 2001-12-06 C & S Intellectual Properties, Llc Method of and joint for coupling thermoplastic pipes

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5407514A (en) * 1988-02-03 1995-04-18 E. O. Butts Consultants Ltd. Method for welding thermoplastic materials
US5571435A (en) * 1995-04-26 1996-11-05 Neeco, Inc. Welding rod having parallel electrical pathways
US6149756A (en) * 1996-03-05 2000-11-21 Uponor Innovation Ab Method for joining plastic pipes, a joint ring used in the joining and a pipe joint provided with the method

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
"ANTEC 2006 Plastics: Annual Technical Conference Proceedings. (2006).", SOCIETY OF PLASTICS ENGINEERS., article JOURDAIN, E. ET AL.: "Development of New TPV Materials with Enhanced Scratch Resistance." *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102012100932A1 (en) 2012-02-06 2013-08-08 Fsave Solartechnik Gmbh Module, particularly for thermal storage tank for fluid, has wall that is closed in circumferential direction, coupling area, in which module is firmly coupled with another module by welding, and holding area or support area for loading bag
EP2835610A1 (en) 2013-08-05 2015-02-11 FSAVE Solartechnik GmbH Module for a thermal storage tank
DE202014105052U1 (en) 2014-10-22 2016-01-25 Enertracting Gmbh Thermal storage tank

Also Published As

Publication number Publication date
US20120231272A1 (en) 2012-09-13

Similar Documents

Publication Publication Date Title
US4176274A (en) Method of coupling plastic pipes by welding and a connection piece for coupling same
US5398974A (en) Pipe connecting member
TW266185B (en) Process for the fusion jointing of plastics pipes and socket for carrying out the process
US8327900B2 (en) Induction connecting sleeve for connecting weldable thermoplastic elements by means of fusion
US20120231272A1 (en) Compressible dual resin thermoplastic welding rod and method for electric resistance thermoplastic welding
US7338085B2 (en) Fusion-bonded processed product of resin member, method for producing same and method for fusion-bonding resin members
KR101620244B1 (en) Glow plug with pressure sensor
US20210178703A1 (en) Connection structure of resin tube and resin joint and connection method therof
WO2011044080A4 (en) Heat-fusible gasket and method of manufacture
JPH04501986A (en) Welding sleeve and its manufacturing method
GB2314597A (en) Electrofusion fitting for a plastics pipe with gripping means
CN110366481B (en) Resin pipe member, method for producing same, resin pipe joint, and resin pipe
JP7365176B2 (en) fitting
JP3028211B2 (en) valve
JPH02309090A (en) Synthetic resin pipe joint and manufacture thereof
JPH11153274A (en) Tubular joint
WO1995015253A1 (en) Joining of hollow elongate members
AU2016232970A1 (en) Induction connection sleeve
JP2001116182A (en) Resin pipe joint with electrothermal fusion joint
EP1787055B1 (en) Electrofusion coupler
CA2127668A1 (en) Electric welding sleeve
RU216344U1 (en) Electrofusion coupling
JP2017020653A (en) Transition fitting
JP2005201386A (en) Resin joint and piping method of resin-made tube
JPH05172289A (en) Electric fusion attach pipe fitting and manufacture thereof

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 10829410

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

WWE Wipo information: entry into national phase

Ref document number: 13509550

Country of ref document: US

122 Ep: pct application non-entry in european phase

Ref document number: 10829410

Country of ref document: EP

Kind code of ref document: A1