WO2011047185A1 - Edge sealant composition with reactive or unsaturated polyolefins - Google Patents
Edge sealant composition with reactive or unsaturated polyolefins Download PDFInfo
- Publication number
- WO2011047185A1 WO2011047185A1 PCT/US2010/052718 US2010052718W WO2011047185A1 WO 2011047185 A1 WO2011047185 A1 WO 2011047185A1 US 2010052718 W US2010052718 W US 2010052718W WO 2011047185 A1 WO2011047185 A1 WO 2011047185A1
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- WIPO (PCT)
- Prior art keywords
- styrene
- weight
- amount
- total composition
- edge seal
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 36
- 239000000565 sealant Substances 0.000 title claims abstract description 35
- 229920000098 polyolefin Polymers 0.000 title claims abstract description 26
- 229920000642 polymer Polymers 0.000 claims abstract description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000000945 filler Substances 0.000 claims abstract description 14
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000002274 desiccant Substances 0.000 claims abstract description 13
- 238000007789 sealing Methods 0.000 claims abstract description 13
- 229910000077 silane Inorganic materials 0.000 claims abstract description 13
- 239000002516 radical scavenger Substances 0.000 claims abstract description 10
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 5
- 239000012963 UV stabilizer Substances 0.000 claims abstract description 4
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 4
- 239000000758 substrate Substances 0.000 claims description 20
- 150000001875 compounds Chemical class 0.000 claims description 15
- -1 styrene-ethylene-butylene- styrene Chemical class 0.000 claims description 14
- 229920002367 Polyisobutene Polymers 0.000 claims description 13
- 230000032683 aging Effects 0.000 claims description 12
- 229920002943 EPDM rubber Polymers 0.000 claims description 10
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 150000004760 silicates Chemical class 0.000 claims description 6
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 6
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 claims description 6
- 229920005549 butyl rubber Polymers 0.000 claims description 5
- 239000011521 glass Substances 0.000 claims description 5
- 229920001083 polybutene Polymers 0.000 claims description 5
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical class [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 claims description 5
- 239000003707 silyl modified polymer Substances 0.000 claims description 5
- 229920006132 styrene block copolymer Polymers 0.000 claims description 5
- 239000006229 carbon black Substances 0.000 claims description 4
- 235000019241 carbon black Nutrition 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 4
- 239000002808 molecular sieve Substances 0.000 claims description 4
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 4
- 229920001897 terpolymer Polymers 0.000 claims description 4
- 239000005995 Aluminium silicate Substances 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 235000012211 aluminium silicate Nutrition 0.000 claims description 3
- 239000012965 benzophenone Substances 0.000 claims description 3
- 150000008366 benzophenones Chemical class 0.000 claims description 3
- 150000001565 benzotriazoles Chemical class 0.000 claims description 3
- 239000011575 calcium Substances 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 235000012241 calcium silicate Nutrition 0.000 claims description 3
- 229920005555 halobutyl Polymers 0.000 claims description 3
- 125000004968 halobutyl group Chemical group 0.000 claims description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000000391 magnesium silicate Substances 0.000 claims description 3
- 235000012243 magnesium silicates Nutrition 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 239000010445 mica Substances 0.000 claims description 3
- 229910052618 mica group Inorganic materials 0.000 claims description 3
- 150000002989 phenols Chemical class 0.000 claims description 3
- 239000000454 talc Substances 0.000 claims description 3
- 229910052623 talc Inorganic materials 0.000 claims description 3
- 150000003568 thioethers Chemical class 0.000 claims description 3
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 2
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- 239000000292 calcium oxide Substances 0.000 claims description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 239000004571 lime Substances 0.000 claims description 2
- 150000003017 phosphorus Chemical class 0.000 claims description 2
- 239000010457 zeolite Substances 0.000 claims description 2
- VSKJLJHPAFKHBX-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 VSKJLJHPAFKHBX-UHFFFAOYSA-N 0.000 claims 4
- GJKZSOHUVOQISW-UHFFFAOYSA-N buta-1,3-diene;2-methylbuta-1,3-diene;styrene Chemical compound C=CC=C.CC(=C)C=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 GJKZSOHUVOQISW-UHFFFAOYSA-N 0.000 claims 4
- FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical compound C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 claims 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims 2
- 235000006708 antioxidants Nutrition 0.000 claims 2
- 239000010419 fine particle Substances 0.000 claims 2
- VLJQDHDVZJXNQL-UHFFFAOYSA-N 4-methyl-n-(oxomethylidene)benzenesulfonamide Chemical compound CC1=CC=C(S(=O)(=O)N=C=O)C=C1 VLJQDHDVZJXNQL-UHFFFAOYSA-N 0.000 claims 1
- 230000004888 barrier function Effects 0.000 claims 1
- 239000007767 bonding agent Substances 0.000 claims 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims 1
- 150000001718 carbodiimides Chemical class 0.000 claims 1
- 239000004611 light stabiliser Substances 0.000 claims 1
- 239000011164 primary particle Substances 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 claims 1
- 235000015112 vegetable and seed oil Nutrition 0.000 claims 1
- 239000008158 vegetable oil Substances 0.000 claims 1
- 238000000518 rheometry Methods 0.000 abstract description 3
- 230000004580 weight loss Effects 0.000 description 12
- 230000015556 catabolic process Effects 0.000 description 9
- 238000006731 degradation reaction Methods 0.000 description 9
- MARUHZGHZWCEQU-UHFFFAOYSA-N 5-phenyl-2h-tetrazole Chemical compound C1=CC=CC=C1C1=NNN=N1 MARUHZGHZWCEQU-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 238000012668 chain scission Methods 0.000 description 4
- 239000008393 encapsulating agent Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000010409 thin film Substances 0.000 description 4
- BFMKFCLXZSUVPI-UHFFFAOYSA-N ethyl but-3-enoate Chemical compound CCOC(=O)CC=C BFMKFCLXZSUVPI-UHFFFAOYSA-N 0.000 description 3
- 239000003999 initiator Substances 0.000 description 3
- 229910044991 metal oxide Inorganic materials 0.000 description 3
- 150000004706 metal oxides Chemical class 0.000 description 3
- 239000004812 Fluorinated ethylene propylene Substances 0.000 description 2
- 239000002033 PVDF binder Substances 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- KTSFMFGEAAANTF-UHFFFAOYSA-N [Cu].[Se].[Se].[In] Chemical compound [Cu].[Se].[Se].[In] KTSFMFGEAAANTF-UHFFFAOYSA-N 0.000 description 2
- 229910021417 amorphous silicon Inorganic materials 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 229910021419 crystalline silicon Inorganic materials 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 238000011534 incubation Methods 0.000 description 2
- 238000003475 lamination Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229920009441 perflouroethylene propylene Polymers 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 229920002742 polystyrene-block-poly(ethylene/propylene) -block-polystyrene Polymers 0.000 description 2
- 229920000346 polystyrene-polyisoprene block-polystyrene Polymers 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 229920002620 polyvinyl fluoride Polymers 0.000 description 2
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 description 2
- PRBHEGAFLDMLAL-UHFFFAOYSA-N 1,5-Hexadiene Natural products CC=CCC=C PRBHEGAFLDMLAL-UHFFFAOYSA-N 0.000 description 1
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- JBRZTFJDHDCESZ-UHFFFAOYSA-N AsGa Chemical compound [As]#[Ga] JBRZTFJDHDCESZ-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 108700042658 GAP-43 Proteins 0.000 description 1
- 229910001218 Gallium arsenide Inorganic materials 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical class Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 description 1
- 229920002402 Oppanol® B 100 Polymers 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 229920013640 amorphous poly alpha olefin Polymers 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 229920005557 bromobutyl Polymers 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 229920005556 chlorobutyl Polymers 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 229920000840 ethylene tetrafluoroethylene copolymer Polymers 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical compound C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical class [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000013008 moisture curing Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- SJYNFBVQFBRSIB-UHFFFAOYSA-N norbornadiene Chemical compound C1=CC2C=CC1C2 SJYNFBVQFBRSIB-UHFFFAOYSA-N 0.000 description 1
- 238000010943 off-gassing Methods 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 238000010525 oxidative degradation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 229920013730 reactive polymer Polymers 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical class [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/12—Materials for stopping leaks, e.g. in radiators, in tanks
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C27/00—Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
- C03C27/06—Joining glass to glass by processes other than fusing
- C03C27/10—Joining glass to glass by processes other than fusing with the aid of adhesive specially adapted for that purpose
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
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- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/08—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
- C08L51/085—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds on to polysiloxanes
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/02—Polysilicates
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- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/04—Homopolymers or copolymers of ethene
- C09J123/08—Copolymers of ethene
- C09J123/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C09J123/0869—Acids or derivatives thereof
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- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J151/06—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/048—Encapsulation of modules
- H01L31/0481—Encapsulation of modules characterised by the composition of the encapsulation material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C08L23/22—Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefins
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
Definitions
- the present invention relates to edge sealant compositions having reactive or unsaturated polyolefins, and more particularly, edge sealants having reactive or unsaturated polyolefins that can be used in solar modules.
- Photovoltaic solar panels or modules generally include a photovoltaic device that is laminated and/or sandwiched between a plurality of layers.
- the majority of photovoltaic devices are rigid wafer-based crystalline silicon cells or thin film modules having cadmium telluride (Cd-Te), amorphous silicon, or copper-indium-diselenide (CulnSe 2 ) deposited on a substrate.
- the thin film solar modules may be either rigid or flexible. Flexible thin film cells and modules are created by depositing the photoactive layer and any other necessary substance on a flexible substrate. Photovoltaic devices are connected electrically to one another and to other solar panels or modules to form an integrated system.
- edge sealants have the property of having a low rate of moisture transmission, MVT.
- Edge sealants in solar modules are exposed to high temperatures, for example, in the lamination step during construction of the solar module. Accordingly, it is desirable that these edge sealants have thermal stability. Most of edge sealants are polyolefinic in nature. Therefore, the dominant degradation mechanism during high temperature exposure is random chain scission. Once these free radicals are formed (as a consequence of random chain scission), the degradation propagates. In addition to this, the applications where sealants will be exposed to thermal/photo initiators (such as encapsulants, for example, EVA, in solar modules), those initiators would tend to degrade sealants. This may have detrimental ramifications (e.g. strength loss, loss of adhesion to glass) with respect to sealants' bulk and surface properties. Accordingly, there is room in the art for an edge sealant that exhibits good thermal stability in high temperature conditions and resistance to degradation (long term stability in the field) upon exposure to initiators (encapsulant) in solar modules.
- a solar module includes a photovoltaic device that has an edge seal.
- the sealant composition of the edge seal includes an unsaturated or reactive polyolefin, an olefinic polymer, a silane modified polyolefin, inert fillers, a water scavenger or desiccant, an antioxidant, and a UV stabilizer. These components are balanced to produce a sealant having desirable sealing characteristics, high weatherability, desired rheology, low conductivity, and good thermal stability.
- FIG. 1 is a top view of an embodiment of a solar module having a border seal composition according to the principles of the present invention
- FIG. 2 is a cross-sectional view of a portion of an embodiment of a solar module having a border seal composition according to the present invention
- FIG. 3 is a bar graph showing weight loss upon seven days of incubation in 180 °C air circulated ovens for unsaturated or reactive polymers.
- FIG. 4 is a bar graph showing weight loss upon seven days of incubation in 180 °C air circulated ovens for unreactive polyisobutenes (PIBs).
- an exemplary solar module employing a sealant composition according to the principles of the present invention is generally indicated by reference number 10.
- the solar module 10 may take various forms without departing from the scope of the present invention and generally includes at least one photovoltaic cell 12 located within a chamber 13 defined by a first substrate 14 and a second substrate 16. While a plurality of photovoltaic cells 12 are illustrated, it should be appreciated that any number of photovoltaic cells 12 may be employed.
- the photovoltaic cell 12 is operable to generate an electrical current from sunlight striking the photovoltaic cell 12. Accordingly, the photovoltaic cell 12 may take various forms without departing from the scope of the present invention.
- the photovoltaic cell 12 may be a thin film cell with a layer of cadmium telluride (Cd-Te), amorphous silicon, or copper- indium-diselenide (CulnSe 2 ).
- the photovoltaic cell 12 may be a crystalline silicon wafer embedded in a laminating film or gallium arsenide deposited on germanium or another substrate.
- Other types of photovoltaic devices 12 that may be employed include organic semiconductor cells having conjugate polymers as well as dye-sensitized metal oxides including wet metal oxides and solid metal oxides.
- the photovoltaic device 12 may be either rigid or flexible.
- the photovoltaic cells 12 are linked either in series or in parallel or combinations thereof.
- the current produced by the photovoltaic devices 12 are communicated via bus bars or other conductive materials or layers to wires or lead lines 15 that exit the solar module 10.
- the lead lines 15 communicate with a junction box 17 in order to distribute the electrical current generated by the solar module 10 to a power circuit.
- the first substrate 14, or front panel is formed from a material operable to allow wavelengths of sunlight to pass therethrough.
- the first substrate 14 is glass or a plastic film such as polyvinylflouride.
- the second substrate 16, or back panel is selected to provide additional strength to the solar module 10.
- the second substrate 16 is a plastic such as fluorinated ethylene-propylene copolymer (FEP), poly(ethylene-co- tetrafluoroethylene) (ETFE), polyvinylidene fluoride (PVDF), polyvinyl fluoride (PVF), poly(tetrafluoroethylene) (PTFE) and combinations of these with other polymeric materials.
- FEP fluorinated ethylene-propylene copolymer
- ETFE poly(ethylene-co- tetrafluoroethylene)
- PVDF polyvinylidene fluoride
- PVDF polyvinyl fluoride
- PTFE poly(tetrafluoroethylene)
- the photovoltaic cells 12 are encapsulated by a laminate layer 19 that is preferably cross-linkable ethyl vinyl acetate (EVA).
- EVA cross-linkable ethyl vinyl acetate
- the laminate layer 19 is used to partially encapsulate the photovoltaic device 12 to protect the photovoltaic device 12 from contamination, mechanical stress, and from the environment.
- a border or edge seal 18 is located near an edge of the solar module 10 between the first substrate 14 and the second substrate 16.
- the border seal 18 may have various widths.
- a second border seal (not shown) may also be included.
- the second border seal may be comprised of, for example, for example, a silicone, an MS polymer, a Silanated Polyurethane, a butyl, or a polysulfide.
- the border seal 18 is operable to seal the laminate layer 19 and photovoltaic devices 12.
- the border seal 18 must have sufficient weatherability to withstand exposure to outside environments including prolonged ultra-violet radiation exposure, have low moisture and vapor transmission (MVT), and have low conductivity.
- the border seal 20 is comprised of a sealant composition having the unique characteristics of high weatherability with low conductivity and MVT, as will be described in greater detail below, as well as good thermal stability and oxidative stability.
- the sealant composition of the border seal 18 includes an unsaturated or reactive polyolefin, an olefinic polymer, a silane modified polyolefin, inert fillers, a water scavenger, an antioxidant, and a UV stabilizer. These components are balanced to produce a sealant having desirable sealing characteristics, high weatherability, desired rheology, low conductivity, and good thermal stability.
- the unsaturated or reactive polyolefins are selected from the group EPDMs, polyolefin acrylates, and halobutyls.
- the olefinic polymers are selected from the group comprising polyisobutylene, polybutene, butyl rubber (polyisobutylene-isoprene), styrene block copolymers, especially SBS, SIS, SEBS, SEPS, SIBS, SPIBS, also in modified form, and amorphous copolymers and/or terpolymers of a-olefins (APAO).
- APAO amorphous copolymers and/or terpolymers of a-olefins
- the modified polymer to be selected from the group comprising polyisobutylene, polybutene, butyl rubber (polyisobutylene-isoprene), styrene block copolymers, especially SBS, SIS, SEBS, SEPS, SIBS, SPIBS, also in modified form, and amorphous copolymers and/or terpolymers of ⁇ -olefins (APAO), the polymer being modified with at least one group of formula (1 ) which is a terminal group or is distributed statistically within the chain
- R 1 and R 2 are the same or different and are an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms or an aralkyi group having 7 to 20 carbon atoms, X is a hydroxyl group or a hydrolyzable group,
- a is 0,1 ,2 or 3 and b is 0,1 or 2, the sum of a and b being greater than or equal to 1 , and where n is a whole number between 0 and 18, m is a whole number between 0 and 4 and R 3 is
- the fillers prefferably be selected from the group comprising ground and precipitated chalks, silicates, lime, silicon oxides and carbon blacks.
- the invention also provides for the chalks to be surface-treated.
- the invention furthermore provides for the silicates to be selected from the group comprising talc, kaolin, mica, silicon oxides, silicas and calcium or magnesium silicates.
- the desiccants or water scavengers prefferably be selected from molecular sieves (zeolites) of types 3A to 10A.
- the sealing compound either as a one- part sealing compound or as a two-part sealing compound.
- a one- part sealing compound all the components are mixed together during the production process.
- a two-part sealing compound some components form one part and the other components form the other part. The two parts of the compound are then mixed together immediately prior to application.
- the invention also provides for the aging resistors to be selected from the group comprising sterically hindered phenols, thioethers, mercapto compounds, phosphorus esters, benzotriazoles, benzophenones, HALS and antiozonants.
- the sealing compound can be employed for fabricating insulating glass for windows, conservatories, structural and roof glazing, for glazing in land-bound vehicles, watercraft and aircraft, and for manufacturing solar modules, including thermoelectric solar modules.
- the sealing compound with unsaturated or reactive polyolefin in addition to a silane modified polymer is designed to cure during lamination to provide additional structural strength.
- the reactive and/or unsaturation sites were observed to react with free radicals formed upon high temperature exposure leading to minimal degradation (if any) and improved thermal stability.
- the edge seal exhibits low MVTR and can cross-link upon reaction with free radicals, where the free radicals may be the result of thermal or thermo-oxidative degradation or reaction with peroxides contained in encapsulants in the solar module.
- the edge sealant exhibits less than 10% weight loss upon aging in an air circulated oven at 180 degree C for 7 days, an accelerated aging test as a measure of thermal and thermo-oxidative stability. More preferably, the edge sealant exhibits less than 7.5% weight loss upon aging in an air circulated oven at 180 degrees C for 7 days.
- EPDM polymers which contain an unsaturated polymeric backbone comprised of monomers of ethylene and propylene with a small but significant amount of at least one non-conjugated diene, such as norbornadiene, dicyclopentadiene, and/or 1 ,5-hexadiene.
- non-conjugated diene such as norbornadiene, dicyclopentadiene, and/or 1 ,5-hexadiene.
- the significance is that with the various EPDM polymers, a preferential duality exists: While the backbone is fully saturated and thereby highly stable and non-reactive toward most moieties including peroxides and other oxidants, the presence of occasional double bonds in the side chains allows for crosslinking, and should these side chain bonds cleave, the backbone remains intact.
- EPDM also affords reactivity and saturated backbone without inclusion of halogens such as chlorine or bromine. Offgassing of hydrochroric and hydrobromic acids is not possible with EPDM.
- Unsaturate reactive polyolefins such as EPDMs, polyolefin acrylates, and halobutyls of Molecular weight Mn 100 - 100,000 Da preferabaly 100 - 500,000 Da
- Olefinic polymer Polyethylene, polypropylene, polybutene, polyisobutene, butyl rubber
- Silanes DFDA-5451 NT (silane grafted PE from Dow Chemical), DFDA-5481 NT (moisture curing catalyst from Dow Chemical),
- amorphous poly alpha olefins such as and not restricted to Vestoplast 206, Vestoplast 2412
- alkoxy silanes such as and not restricted to Vestoplast 206, Vestoplast 2412
- Inert fillers ground and precipitated chalks, silicates, silicon oxides, and Carbon black, CaC0 3 , Ca(OH) 2 , titanium dioxide
- Water scavenger such as CaO or desiccant such as molecular sieves, silica gel, and calcium sulfate Aging Resistors: Hindered phenols, hindered amines, thioethers, mercapto compounds, phosphorous esters
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Ceramic Engineering (AREA)
- Geochemistry & Mineralogy (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Electromagnetism (AREA)
- General Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Sealing Material Composition (AREA)
- Photovoltaic Devices (AREA)
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13/501,927 US20120199199A1 (en) | 2009-10-14 | 2010-10-14 | Edge sealant composition with reactive or unsaturated polyolefins |
KR1020127012003A KR20120085803A (en) | 2009-10-14 | 2010-10-14 | Edge sealant composition with reactive or unsaturated polyolefins |
CN2010800568607A CN102742143A (en) | 2009-10-14 | 2010-10-14 | Edge sealant composition with reactive or unsaturated polyolefins |
JP2012534367A JP2013509694A (en) | 2009-10-14 | 2010-10-14 | Edge sealant composition containing a reactive or unsaturated polyolefin |
EP10824116.7A EP2489117A4 (en) | 2009-10-14 | 2010-10-14 | Edge sealant composition with reactive or unsaturated polyolefins |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US25154209P | 2009-10-14 | 2009-10-14 | |
US61/251,542 | 2009-10-14 | ||
US67925010A | 2010-03-19 | 2010-03-19 | |
US12/679,250 | 2010-03-19 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2011047185A1 true WO2011047185A1 (en) | 2011-04-21 |
Family
ID=43876550
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2010/052718 WO2011047185A1 (en) | 2009-10-14 | 2010-10-14 | Edge sealant composition with reactive or unsaturated polyolefins |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP2489117A4 (en) |
JP (1) | JP2013509694A (en) |
KR (1) | KR20120085803A (en) |
CN (1) | CN102742143A (en) |
WO (1) | WO2011047185A1 (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013089666A (en) * | 2011-10-14 | 2013-05-13 | Kyocera Corp | Photoelectric conversion module |
WO2013144755A1 (en) | 2012-03-30 | 2013-10-03 | Saes Getters S.P.A. | Sealant composition |
JP2013213122A (en) * | 2012-03-31 | 2013-10-17 | Aica Kogyo Co Ltd | Hot melt sealing composition |
JP2014019837A (en) * | 2012-07-23 | 2014-02-03 | Aica Kogyo Co Ltd | Hot-melt sealing composition |
GB2507878A (en) * | 2012-10-22 | 2014-05-14 | Polyseam Ltd | Sealant composition |
CN109206653A (en) * | 2018-09-06 | 2019-01-15 | 常州斯威克光伏新材料有限公司 | The preparation method of polyolefin encapsulating film for solar cell module |
IT201900011268A1 (en) * | 2019-07-10 | 2021-01-10 | Piavevetro Srl | STRUCTURE FOR THERMOELECTRIC AND PHOTOVOLTAIC PANEL |
Families Citing this family (8)
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CN102965033B (en) * | 2012-11-02 | 2014-07-16 | 铜陵祥云消防科技有限责任公司 | Nano-mica powder modified compound adhesive for packaging |
CN104766897B (en) * | 2014-01-08 | 2021-07-02 | 明尼苏达矿业制造特殊材料(上海)有限公司 | Solar cell module |
JP2015213132A (en) * | 2014-05-07 | 2015-11-26 | パナソニックIpマネジメント株式会社 | Solar battery module |
MY187469A (en) * | 2014-10-30 | 2021-09-23 | Dow Global Technologies Llc | Pv module with film layer comprising micronized silica gel |
CN106928883B (en) * | 2015-12-31 | 2019-02-26 | 比亚迪股份有限公司 | A kind of sealant tape composition and sealant tape and its application |
EP3287276A1 (en) * | 2016-08-26 | 2018-02-28 | Sika Technology Ag | Reactive polyolefin hot-melt adhesive with lower reactivation temperature and use thereof in deep draw vacuum lamination |
CN114316809B (en) * | 2022-01-10 | 2023-10-20 | 南亚新材料科技股份有限公司 | Sealant for lithium battery and preparation method thereof |
CN114605947B (en) * | 2022-01-27 | 2023-05-02 | 北京东方雨虹防水技术股份有限公司 | Silane-modified hot-melt pressure-sensitive adhesive and preparation method thereof |
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US20040216778A1 (en) * | 2002-08-21 | 2004-11-04 | Ferri Louis Anthony | Solar panel including a low moisture vapor transmission rate adhesive composition |
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US20040059069A1 (en) * | 1996-06-18 | 2004-03-25 | Sefan Grimm | Reactive hotmelt adhesive composition for insulating glass |
DE19624236A1 (en) * | 1996-06-18 | 1998-01-08 | Henkel Teroson Gmbh | Reactive hot melt adhesive composition for insulating glass |
WO1998030649A1 (en) * | 1997-01-14 | 1998-07-16 | Asahi Glass Company Ltd. | Adhesive for glass |
JP2007308350A (en) * | 2006-05-22 | 2007-11-29 | Kaneka Corp | Double-glazed unit |
DE102007045104A1 (en) * | 2007-09-20 | 2009-04-02 | Kömmerling Chemische Fabrik GmbH | Sealant for the production of double or multi-pane insulating glass or solar modules |
-
2010
- 2010-10-14 CN CN2010800568607A patent/CN102742143A/en active Pending
- 2010-10-14 KR KR1020127012003A patent/KR20120085803A/en not_active Application Discontinuation
- 2010-10-14 EP EP10824116.7A patent/EP2489117A4/en not_active Withdrawn
- 2010-10-14 JP JP2012534367A patent/JP2013509694A/en active Pending
- 2010-10-14 WO PCT/US2010/052718 patent/WO2011047185A1/en active Application Filing
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US5855972A (en) * | 1993-11-12 | 1999-01-05 | Kaeding; Konrad H | Sealant strip useful in the fabrication of insulated glass and compositions and methods relating thereto |
US20030166756A1 (en) * | 2000-01-28 | 2003-09-04 | Nobuhiro Hasegawa | Curable composition |
US20030162882A1 (en) * | 2000-03-28 | 2003-08-28 | Stefan Grimm | Reactive hot-melt-type adhesive granulate for insulating glass |
US20040216778A1 (en) * | 2002-08-21 | 2004-11-04 | Ferri Louis Anthony | Solar panel including a low moisture vapor transmission rate adhesive composition |
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Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013089666A (en) * | 2011-10-14 | 2013-05-13 | Kyocera Corp | Photoelectric conversion module |
WO2013144755A1 (en) | 2012-03-30 | 2013-10-03 | Saes Getters S.P.A. | Sealant composition |
US8962975B2 (en) | 2012-03-30 | 2015-02-24 | Saes Getters S.P.A. | Sealant composition |
JP2013213122A (en) * | 2012-03-31 | 2013-10-17 | Aica Kogyo Co Ltd | Hot melt sealing composition |
JP2014019837A (en) * | 2012-07-23 | 2014-02-03 | Aica Kogyo Co Ltd | Hot-melt sealing composition |
GB2507878A (en) * | 2012-10-22 | 2014-05-14 | Polyseam Ltd | Sealant composition |
GB2507878B (en) * | 2012-10-22 | 2015-04-15 | Polyseam Ltd | Sealant compositions |
US9683142B2 (en) | 2012-10-22 | 2017-06-20 | Polyseam Limited | Compositions |
CN109206653A (en) * | 2018-09-06 | 2019-01-15 | 常州斯威克光伏新材料有限公司 | The preparation method of polyolefin encapsulating film for solar cell module |
IT201900011268A1 (en) * | 2019-07-10 | 2021-01-10 | Piavevetro Srl | STRUCTURE FOR THERMOELECTRIC AND PHOTOVOLTAIC PANEL |
Also Published As
Publication number | Publication date |
---|---|
JP2013509694A (en) | 2013-03-14 |
EP2489117A1 (en) | 2012-08-22 |
EP2489117A4 (en) | 2014-12-31 |
KR20120085803A (en) | 2012-08-01 |
CN102742143A (en) | 2012-10-17 |
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